CN201345398Y - Regeneration and utilization system for waste lead-acid storage batteries and lead-containing waste - Google Patents
Regeneration and utilization system for waste lead-acid storage batteries and lead-containing waste Download PDFInfo
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
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Abstract
一种废铅酸蓄电池及含铅废物再生利用系统,其特征在于所述再生利用系统包括:拆解单元、铅冶炼回收单元、废气处理单元和废液处理单元,所述铅冶炼回收单元包括全封闭熔炼炉,所述废气处理单元包括收尘装置和脱硫装置;所述废液处理单元包括废水处理设备和脱水装置。该废铅酸蓄电池及含铅废物再生利用系统能有效减少污染物的排放、实现废铅酸蓄电池及含铅废物最大限度处理利用,并可实现再生资源回收,该再生利用系统所产生的污染物量低,废水、气、渣均可实现最少化并实现达标排放,处理能耗低并可生产出高附加值的再生铅资源,循环用于蓄电池再生产。
A waste lead-acid battery and lead-containing waste recycling system, characterized in that the recycling system includes: a dismantling unit, a lead smelting recovery unit, a waste gas treatment unit and a waste liquid treatment unit, and the lead smelting recovery unit includes a full The smelting furnace is closed, and the waste gas treatment unit includes a dust collection device and a desulfurization device; the waste liquid treatment unit includes a waste water treatment device and a dehydration device. The waste lead-acid battery and lead-containing waste recycling system can effectively reduce the discharge of pollutants, realize the maximum treatment and utilization of waste lead-acid battery and lead-containing waste, and realize the recovery of renewable resources. The amount of pollutants produced by the recycling system Low, waste water, gas, and slag can be minimized and discharged up to the standard, the energy consumption of the treatment is low, and high value-added recycled lead resources can be produced, which can be recycled for battery regeneration.
Description
技术领域 technical field
本实用新型属于含铅废物的无害处理及资源再生技术,具体的涉及一种用于废铅酸蓄电池及含铅废物的无公害处理及资源再生的再生利用系统。The utility model belongs to the harmless treatment and resource regeneration technology of lead-containing waste, in particular to a recycling system for pollution-free treatment and resource regeneration of waste lead-acid batteries and lead-containing waste.
背景技术 Background technique
铅资源是重要的有色金属矿产资源,随着世界范围内需求量的日益增加,矿产原生铅生产面临着工业开采储量匮乏、采选冶炼工艺污染相对严重等多方面的压力。为解决一次资源的严重短缺,同时也从降低原料和选冶成本,以及满足需求增长的考虑出发,铅资源生产不得不越来越依靠铅的二次资源——再生铅的生产,其中废铅酸蓄电池已成为再生铅的主要来源。另一方面,随着我国社会经济的快速发展,汽车保有量的日益增加,以及各种使用铅酸蓄电池的工具及设备的日益增多,报废的铅酸蓄电池的合理处置已成为一项重要的环保议题。根据《国家危险废物名录》:废铅酸蓄电池及含铅废物属于危险废物。对其不当的处置将导致含铅酸液和固体废渣的无序流失,必然造成环境空气、土壤、地表和地下水资源的严重污染,进而通过食物链威胁人类身体健康。Lead resources are important non-ferrous metal mineral resources. With the increasing demand worldwide, the production of primary lead in minerals is facing various pressures such as the lack of industrial mining reserves and relatively serious pollution in mining, dressing and smelting processes. In order to solve the serious shortage of primary resources, and also to reduce the cost of raw materials and dressing and smelting, and to meet the consideration of demand growth, the production of lead resources has to rely more and more on the secondary resource of lead—the production of recycled lead, of which lead waste Acid batteries have become a major source of secondary lead. On the other hand, with the rapid development of my country's social economy, the increasing number of automobiles, and the increasing number of tools and equipment using lead-acid batteries, the reasonable disposal of scrapped lead-acid batteries has become an important environmental protection issue. According to the "National List of Hazardous Wastes": waste lead-acid batteries and lead-containing wastes are hazardous wastes. Improper disposal of it will lead to the disorderly loss of lead-containing acid liquid and solid waste residue, which will inevitably cause serious pollution of ambient air, soil, surface and groundwater resources, and then threaten human health through the food chain.
全国含铅废物年产生量表 截止至2008年底National annual production scale of lead-containing waste as of the end of 2008
根据资料显示全国含铅废料产生量约在100万吨以上,并呈增长趋势。国内再生铅生产从总体水平看,再生铅企业数量多、规模小、能耗高、污染重、工艺技术落后、金属回收和综合利用率低。传统的再生铅生产设备采用落后的熔炼设备,大部分没有采取环保治理措施,环境污染严重。如何实施废铅料在一定地区范围内就地规范处理,降低能源消耗及过程污染,率先实行铅资源在本地区的循环利用,是当今社会有待解决的重要问题。According to data, the amount of lead-containing waste produced nationwide is about 1 million tons or more, and it is showing an increasing trend. From the overall level of domestic secondary lead production, there are many secondary lead enterprises, small scale, high energy consumption, heavy pollution, backward technology, low metal recovery and comprehensive utilization rate. Traditional secondary lead production equipment adopts outdated smelting equipment, most of which have not taken environmental protection measures, resulting in serious environmental pollution. How to standardize the treatment of waste lead materials in a certain area, reduce energy consumption and process pollution, and take the lead in implementing the recycling of lead resources in this area is an important problem to be solved in today's society.
从秉持可持续发展和循环经济的理念出发,结合国家现行的资源再生鼓励政策,以汽车、电动车等更换蓄电池所产生的废蓄电池及蓄电池制造厂产生的含铅废料为再生铅原料,通过废铅酸蓄电池及含铅废物环保再生利用技术工艺,获得再生铅资源;并通过合金的配制进而获得特定规格的再生铅合金产品,使再生铅回归铅资源消耗使用领域,是实现含铅废物包括铅酸蓄电池的无害处理及资源再生的技术研发重点。Starting from the concept of sustainable development and circular economy, combined with the country's current resource regeneration encouragement policy, waste batteries produced by replacing batteries of automobiles and electric vehicles and lead-containing waste produced by battery manufacturers are used as raw materials for regenerated lead. Lead-acid batteries and lead-containing waste environmental protection recycling technology to obtain regenerated lead resources; and through the preparation of alloys to obtain specific specifications of regenerated lead alloy products, so that regenerated lead can return to the field of lead resource consumption and use, which is the realization of lead-containing waste including lead. The harmless treatment of acid batteries and the focus of technology research and development of resource regeneration.
实用新型内容 Utility model content
本实用新型提供了一种能有效减少污染物的排放、实现废铅酸蓄电池及含铅废物最大限度处理,并可实现再生资源回收的废铅酸蓄电池及含铅废物再生利用系统,该再生利用系统所产生的污染物量低,废水、气、渣均可实现最少化并实现达标排放,处理能耗低并可生产出高附加值的再生铅资源,循环用于蓄电池再生产。The utility model provides a recycling system for waste lead-acid batteries and lead-containing wastes that can effectively reduce the discharge of pollutants, realize the maximum treatment of waste lead-acid batteries and lead-containing wastes, and realize the recovery of renewable resources. The amount of pollutants produced by the system is low, waste water, gas, and slag can be minimized and discharged up to standards, the treatment energy consumption is low, and high value-added recycled lead resources can be produced, which can be recycled for battery regeneration.
本实用新型主要采用的技术方案如下:The technical scheme that the utility model mainly adopts is as follows:
一种废铅酸蓄电池及含铅废物再生利用系统,其特征在于所述再生利用系统包括:拆解单元、铅冶炼回收单元、废气处理单元和废液处理单元,所述铅冶炼回收单元包括全封闭熔炼炉,所述废气处理单元包括收尘装置和脱硫装置;所述废液处理单元包括废水处理设备和脱水装置。A waste lead-acid battery and lead-containing waste recycling system, characterized in that the recycling system includes: a dismantling unit, a lead smelting recovery unit, a waste gas treatment unit and a waste liquid treatment unit, and the lead smelting recovery unit includes a full The smelting furnace is closed, and the waste gas treatment unit includes a dust collection device and a desulfurization device; the waste liquid treatment unit includes a waste water treatment device and a dehydration device.
具体的讲,所述全封闭熔炼炉为全封闭负压熔炼竖炉。Specifically, the fully enclosed smelting furnace is a fully enclosed negative pressure smelting shaft furnace.
所述铅冶炼回收单元还包括一位于全封闭熔炼炉后的合金炉,所述全封闭熔炼炉产生的废气通过输送管路与废气处理单元中收尘装置连接,该收尘装置后设置脱硫装置。The lead smelting recovery unit also includes an alloy furnace located behind the fully enclosed smelting furnace, the waste gas generated by the fully enclosed smelting furnace is connected to the dust collection device in the waste gas treatment unit through the conveying pipeline, and a desulfurization device is arranged behind the dust collection device .
所述脱硫装置包括两级脱硫装置,采用碱液湿法喷淋脱硫工艺。The desulfurization device includes a two-stage desulfurization device, which adopts a lye wet spraying desulfurization process.
所述收尘装置与全封闭熔炼炉间设置有烟尘输送通道;所述脱硫装置与废液处理单元设置向废液处理单元输送脱硫废液的通道。A flue dust delivery channel is set between the dust collection device and the fully enclosed melting furnace; the desulfurization device and the waste liquid treatment unit are provided with a channel for transporting desulfurized waste liquid to the waste liquid treatment unit.
所述再生利用系统还包括一塑料回收处理单元,所述塑料回收处理单元包括一清洗装置。The recycling system also includes a plastic recycling processing unit, and the plastic recycling processing unit includes a cleaning device.
所述清洗装置与所述废液处理单元间设置有清洗液输送通道。A cleaning liquid delivery channel is provided between the cleaning device and the waste liquid processing unit.
所述废液处理单元包括一用于收集拆解单元废液、冲洗地面产生废液和脱硫装置产生废液的原水池,原水池后依次设置反应槽、沉降槽、过滤塔、中和槽和放流槽及在线监测装置。The waste liquid treatment unit includes a raw water pool for collecting waste liquid from the dismantling unit, washing the ground to produce waste liquid, and desulfurization device to produce waste liquid. After the raw water pool, a reaction tank, a settling tank, a filter tower, a neutralization tank, and a Release tank and on-line monitoring device.
所述废液处理单元还包括混合槽和脱水装置,所述混合槽与沉降槽间设置有沉降物输送通道。The waste liquid treatment unit also includes a mixing tank and a dehydration device, and a sediment conveying channel is arranged between the mixing tank and the settling tank.
所述脱水装置为SP脱水机,该脱水机与所述废液处理单元间设置脱水污泥输送通道。The dehydration device is an SP dehydrator, and a dewatered sludge transport channel is set between the dehydrator and the waste liquid treatment unit.
拆解单元用于废铅酸蓄电池的切割拆解,其可利用专用的铅酸蓄电池切割拆解设备,使废铅酸蓄电池中的极板、塑料、橡胶、隔板及电解液(硫酸)进行分类处理,分别送入之后的不同处理和回收单元。该拆解单元可设置在专门的铅酸蓄电池拆解车间内,地面全部经环氧树脂防腐、防渗处理,防止废酸的腐蚀、渗漏而造成土地的污染。The dismantling unit is used for cutting and dismantling waste lead-acid batteries. It can use special lead-acid battery cutting and dismantling equipment to make the plates, plastics, rubber, separators and electrolyte (sulfuric acid) in waste lead-acid batteries Sorted processing, sent to different processing and recycling units. The dismantling unit can be set in a special lead-acid battery dismantling workshop, and the ground is all treated with epoxy resin for anticorrosion and anti-seepage to prevent land pollution caused by waste acid corrosion and leakage.
铅冶炼回收单元中的全封闭熔炼炉可以回收熔炼拆解出来的极板及其他含铅废料,生产再生铅。例如可将拆解出来的极板及其他含铅废料计量后,由箕斗提升机提升至熔炼炉炉顶并倒入炉内;将焦碳按比例由提升机进行入熔炼炉,并配入废铁,炉内温度升至1200℃以上,熔炼的物料完全熔化,并在炭的还原作用下,生成再生铅。熔炼渣和再生铅进入炉缸,由于铅的比重较大,在炉缸里可自然分成铅层和渣层,铅层经虹吸管流入铅模,铸成铅锭,炉渣流入铸锭模铸成渣块。The fully enclosed smelting furnace in the lead smelting recovery unit can recycle and smelt disassembled plates and other lead-containing waste to produce secondary lead. For example, the disassembled plates and other lead-containing wastes can be measured and then lifted to the top of the melting furnace by the skip elevator and poured into the furnace; the coke is carried into the melting furnace by the elevator in proportion and mixed into For scrap iron, the temperature in the furnace rises above 1200°C, the smelted material is completely melted, and under the reduction action of charcoal, secondary lead is generated. The smelting slag and recycled lead enter the furnace hearth. Due to the large proportion of lead, they can be naturally divided into lead layer and slag layer in the hearth. The lead layer flows into the lead mold through the siphon tube and is cast into lead ingots. The slag flows into the ingot mold and is cast into slag. piece.
该全封闭熔炼炉采用全封闭负压熔炼竖炉,熔炼时,该竖炉为连续操作,每隔一段时间将含铅原料和辅料投入竖炉内,炉口在投料时瞬间开启,其余时间关闭,由于炉内负压操作,短暂的炉口开闭不会造成炉内烟气的逸散。同时采用竖炉熔炼的新工艺,可降低资源的消耗,提高综合利用率,该熔炼竖炉采用低料柱操作,料柱在2~2.5米范围内调整,提高了铅和碳元素还原反应速率,提高了铅的回收率,也降低了焦碳和废铁的投加量。将收集的铅尘和水渣滤饼回收到熔炼炉中继续熔炼,可提炼再生铅,提高了总体铅回收率。The fully enclosed smelting furnace adopts a fully enclosed negative pressure smelting shaft furnace. During smelting, the shaft furnace operates continuously. The lead-containing raw materials and auxiliary materials are put into the shaft furnace at regular intervals. , Due to the negative pressure operation in the furnace, the short-term opening and closing of the furnace mouth will not cause the escape of flue gas in the furnace. At the same time, the new technology of shaft furnace smelting can reduce the consumption of resources and improve the comprehensive utilization rate. The smelting shaft furnace adopts low material column operation, and the material column can be adjusted within the range of 2 to 2.5 meters, which improves the reduction reaction rate of lead and carbon elements. , Improve the recovery rate of lead, and also reduce the dosage of coke and scrap iron. Recycling the collected lead dust and slag filter cake to the smelting furnace to continue smelting can extract secondary lead and improve the overall lead recovery rate.
该铅冶炼回收单元还可包括合金炉,用于对再生铅进行提纯,并可再根据客户的需求,配制添加锑、锡、砷、硒、钙、铝等金属元素生产各种规格的再生合金铅,循环用于蓄电池再生产。The lead smelting recovery unit can also include an alloy furnace to purify the secondary lead, and then prepare and add antimony, tin, arsenic, selenium, calcium, aluminum and other metal elements to produce secondary alloys of various specifications according to the needs of customers Lead, recycled for battery regeneration.
铅冶炼回收单元在熔炼时排放的烟气主要成分为烟尘、铅尘和SO2,通过除尘装置进行除尘,然后采用脱硫装置进行烟气脱硫,所述脱硫装置是两级脱硫装置,采用碱液湿法喷淋脱硫工艺,脱硫后的烟气可实现达标排放。而除尘装置回收的粉尘可以再次送入全封闭熔炼炉进行熔炼。The main components of the flue gas emitted by the lead smelting recovery unit during smelting are smoke dust, lead dust and SO 2 , and the dust is removed by the dust removal device, and then the flue gas is desulfurized by the desulfurization device. The desulfurization device is a two-stage desulfurization device. Wet spray desulfurization process, the flue gas after desulfurization can be discharged up to the standard. The dust recovered by the dust removal device can be sent to the fully enclosed melting furnace again for melting.
在整个废铅酸蓄电池及含铅废物再生利用系统产生的废水和铅酸蓄电池废液可通过废液处理单元进行处理。废电解液、脱硫系统排水、冲洗地面的污水全部收集到废液处理单元的原水池,通过废水处理系统处理达标后回用于生产厂房地面冲洗和冲洗废塑料,节约了有限的新鲜水资源,也减少了企业的污染物排放。Waste water and lead-acid battery waste liquid generated in the entire waste lead-acid battery and lead-containing waste recycling system can be treated by the waste liquid treatment unit. The waste electrolyte, the desulfurization system drainage, and the sewage from washing the ground are all collected into the raw water pool of the waste liquid treatment unit. After the waste water treatment system reaches the standard, it can be reused for washing the floor of the production plant and washing waste plastics, saving limited fresh water resources. It also reduces the pollutant discharge of enterprises.
本实用新型的有益效果在于,该废铅酸蓄电池及含铅废物再生利用系统能有效减少污染物的排放、实现废铅酸蓄电池及含铅废物最大限度处理,并可实现再生资源回收,该再生处理系统所产生的污染物量低,废水、气、渣均可实现最少化并实现达标排放,处理能耗低并可生产出高附加值的再生铅资源,循环用于蓄电池再生产。The beneficial effect of the utility model is that the waste lead-acid battery and lead-containing waste recycling system can effectively reduce the discharge of pollutants, realize the maximum treatment of waste lead-acid battery and lead-containing waste, and realize the recovery of renewable resources. The amount of pollutants produced by the treatment system is low, waste water, gas, and slag can be minimized and discharged up to standards, the treatment energy consumption is low, and high value-added recycled lead resources can be produced, which can be recycled for battery regeneration.
附图说明 Description of drawings
图1是本实用新型具体实施方式的系统组成框架图;Fig. 1 is the system composition frame diagram of the specific embodiment of the present utility model;
图2是本实用新型另一具体实施方式的系统组成框架图。Fig. 2 is a system composition frame diagram of another specific embodiment of the present invention.
具体实施方式 Detailed ways
如图1所示,该废铅酸蓄电池及含铅废物再生利用系统主要由拆解单元、铅冶炼回收单元、废气处理单元、废液处理单元和塑料回收处理单元组成,塑料回收处理单元包括一清洗装置组成。铅冶炼回收单元包括全封闭熔炼竖炉、合金炉和铸造机,该全封闭熔炼竖炉为全封闭负压熔炼竖炉,用于熔炼含铅废物得到再生铅,合金炉将再生铅熔炼成再生合金铅,可通过铸造机制成各种合金铅制品。废气处理单元由收尘装置和脱硫装置组成,收尘装置由重力收尘装置和布袋收尘装置组成,其后设置二级脱硫装置。废液处理单元由用于收集拆解单元产生废液、冲洗地面产生废液和脱硫装置产生废液的原水池,原水池后依次设置反应槽、沉降槽、过滤塔、中和槽和放流槽及在线监测装置,以及一混合槽和SP脱水机组成,混合槽与沉降槽间设置有沉降物输送通道。该SP脱水机与废液处理单元间设置脱水污泥输送通道。全封闭熔炼炉产生的废气通过输送管路与收尘装置连接,该收尘装置后与全封闭熔炼炉间设置有烟尘输送通道。脱硫装置与废液处理单元设置向废液处理单元输送脱硫废液的通道,清洗装置与废液处理单元间设置有清洗液输送通道。As shown in Figure 1, the waste lead-acid battery and lead-containing waste recycling system is mainly composed of a dismantling unit, a lead smelting recovery unit, a waste gas treatment unit, a waste liquid treatment unit, and a plastic recycling unit. The plastic recycling unit includes a Cleaning device composition. The lead smelting recovery unit includes a fully enclosed smelting shaft furnace, an alloy furnace and a casting machine. The fully enclosed smelting shaft furnace is a fully enclosed negative pressure smelting shaft furnace, which is used to smelt lead-containing waste to obtain recycled lead. The alloy furnace smelts the recycled lead into recycled lead. Alloy lead can be made into various alloy lead products by casting machine. The exhaust gas treatment unit is composed of a dust collection device and a desulfurization device. The dust collection device is composed of a gravity dust collection device and a bag dust collection device, followed by a secondary desulfurization device. The waste liquid treatment unit consists of a raw water pool for collecting waste liquid from the dismantling unit, washing the ground, and desulfurization device. After the raw water pool, a reaction tank, a settling tank, a filter tower, a neutralization tank, and a discharge tank are arranged in sequence. And on-line monitoring device, as well as a mixing tank and SP dehydrator, the sediment transport channel is set between the mixing tank and the settling tank. A dewatered sludge conveying channel is set between the SP dehydrator and the waste liquid treatment unit. The exhaust gas generated by the fully enclosed melting furnace is connected to the dust collecting device through the conveying pipeline, and a dust conveying channel is set between the dust collecting device and the fully enclosed melting furnace. The desulfurization device and the waste liquid treatment unit are provided with channels for transporting desulfurized waste liquid to the waste liquid treatment unit, and a cleaning liquid delivery channel is provided between the cleaning device and the waste liquid treatment unit.
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| CN102329963A (en) * | 2011-09-28 | 2012-01-25 | 界首市骏马工贸有限公司 | Device for high-efficiency and energy-saving separation, extraction and preparation of lead in lead-containing flue dust |
| CN103239979A (en) * | 2013-05-17 | 2013-08-14 | 尚诚德 | Economical method for desulfurizing and dedusting glue gas produced during smelting of secondary lead |
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| CN103239979A (en) * | 2013-05-17 | 2013-08-14 | 尚诚德 | Economical method for desulfurizing and dedusting glue gas produced during smelting of secondary lead |
| CN103239979B (en) * | 2013-05-17 | 2015-04-22 | 尚诚德 | Economical method for desulfurizing and dedusting glue gas produced during smelting of secondary lead |
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| CN104911373A (en) * | 2015-06-29 | 2015-09-16 | 淄博明泰电器科技有限公司 | Closed heating lead smelting system |
| CN109078443A (en) * | 2018-09-21 | 2018-12-25 | 宁夏瑞银有色金属科技有限公司 | A kind of exhaust treatment system and its application method for lead-acid accumulator |
| CN109244582A (en) * | 2018-09-28 | 2019-01-18 | 阳煤集团山西吉天利科技有限公司 | A kind of technique of waste lead accumulator harmless treatment and resource utilization |
| CN109244582B (en) * | 2018-09-28 | 2022-03-11 | 阳煤集团山西吉天利科技有限公司 | Process for harmless treatment and resource utilization of waste lead storage battery |
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