CN201105498Y - A sequential injection mold device with internal vibration - Google Patents
A sequential injection mold device with internal vibration Download PDFInfo
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- CN201105498Y CN201105498Y CNU2007200552036U CN200720055203U CN201105498Y CN 201105498 Y CN201105498 Y CN 201105498Y CN U2007200552036 U CNU2007200552036 U CN U2007200552036U CN 200720055203 U CN200720055203 U CN 200720055203U CN 201105498 Y CN201105498 Y CN 201105498Y
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Abstract
本实用新型是一种内振动顺序注塑模具装置。包括置于热流道板(3)内的加热体(6)及置于热流道板(3)外的加热圈(1),加热圈(1)通过热嘴(18)、热嘴垫套(2)与加热体(6)连接,加热体(6)上还装设有往复直线运动机构(A),加热体(6)的外侧装设隔片(7)。本实用新型通过加热体(6)对热流道板(3)内的塑料进行加热;往复直线运动机构(A)进行来回运动,实现对熔融的高聚物进行振动;隔片(7)使熔融的高聚物于喷嘴隔开,控制往复直线运动机构(A)的来回运动的频率,以使熔体按顺序进入型腔的不同位置,以达到顺序浇注的作用。本实用新型注塑装置能有效减少产品缺陷,提高产品机械性能,增加产品竞争力,降低生产成本,增加经济效益和社会效益。
The utility model relates to an internal vibration sequential injection mold device. It includes the heating body (6) placed inside the hot runner plate (3) and the heating ring (1) placed outside the hot runner plate (3), the heating ring (1) passes through the hot nozzle (18), the hot nozzle gasket ( 2) Connect with the heating body (6), the heating body (6) is also equipped with a reciprocating linear motion mechanism (A), and the outside of the heating body (6) is equipped with a spacer (7). The utility model heats the plastic in the hot runner plate (3) through the heating body (6); the reciprocating linear motion mechanism (A) moves back and forth to realize the vibration of the molten high polymer; the spacer (7) makes the melting The high polymer is separated from the nozzle, and the frequency of the back and forth motion of the reciprocating linear motion mechanism (A) is controlled, so that the melt enters different positions of the cavity in order to achieve the effect of sequential pouring. The injection molding device of the utility model can effectively reduce product defects, improve product mechanical properties, increase product competitiveness, reduce production costs, and increase economic and social benefits.
Description
技术领域:Technical field:
本实用新型是一种内振动顺序注塑模具装置,特别是一种用于注塑大型模具制品的内振动顺序注塑模具装置,属于注塑模具装置的改造技术。The utility model relates to an internal vibration sequential injection mold device, in particular to an internal vibration sequential injection mold device for injection molding large-scale mold products, which belongs to the transformation technology of the injection mold device.
背景技术:Background technique:
现在大型模具采用多浇口,模具加热都是采用热流道外加热,其存在的缺点是电能消耗较大。此外,传统注塑在熔体充填时,由于模壁温度(40℃~50℃)一般较低,注塑制件总是显示出特征:皮和芯层形态。对于无定形聚合物,一般是冷模表面附件形成一层薄层定向材料,但是对于多相或结晶聚合物,常常出现三种主要的区域:表层、亚表皮层、芯层。在模腔内熔体的流动存在速度梯度,致使高分子链的两端处于不同的速度场中,高分子链得到取向。在冷却阶段中,这种取向被冻结下来,形成贴近表皮层取向大,中心处取向小的结构。对于结晶和非结晶聚合物,取向作用对制品的机械性能有重要的影响,沿取向方向的机械性能大大提高。同时,由于高分子成型的复杂,塑料制件也易形成各种缺陷:飞边、熔接痕、气穴、缩凹、喷射、滞流等。Now large-scale molds use multiple gates, and the mold is heated outside the hot runner. The disadvantage is that it consumes a lot of power. In addition, when the traditional injection molding is filled with the melt, because the mold wall temperature (40 ° C ~ 50 ° C) is generally low, the injection molded parts always show the characteristics: the shape of the skin and the core layer. For amorphous polymers, it is common to form a thin layer of oriented material near the surface of the cold die, but for heterogeneous or crystalline polymers, three main regions often occur: skin, subskin, and core. There is a velocity gradient in the flow of the melt in the mold cavity, so that the two ends of the polymer chain are in different velocity fields, and the polymer chain is oriented. During the cooling stage, this orientation is frozen, forming a structure with a large orientation close to the epidermis and a small orientation in the center. For crystalline and non-crystalline polymers, the orientation effect has an important impact on the mechanical properties of the product, and the mechanical properties along the orientation direction are greatly improved. At the same time, due to the complexity of polymer molding, plastic parts are also prone to various defects: flashes, weld marks, air pockets, shrinkage, jetting, stagnation, etc.
实用新型内容:Utility model content:
本实用新型的目的在于考虑上述问题而提供一种内置加热,减少能源消耗的内振动顺序注塑模具装置。本实用新型内振动顺序注塑模具装置的振动顺序注塑由于采用定时时间器控制浇口,使模具内的熔体按顺序进入型腔的不同位置,可以排除两个浇口之间熔接痕现象,所以制品的强度和表观质量得到很大提升。The purpose of the utility model is to consider the above problems and provide a built-in heating and reduce energy consumption internal vibration sequential injection mold device. The vibration sequence injection molding of the internal vibration sequence injection molding device of the utility model adopts a timing timer to control the gate, so that the melt in the mold enters different positions of the cavity in sequence, and the phenomenon of weld marks between the two gates can be eliminated, so The strength and apparent quality of the product are greatly improved.
本实用新型内振动顺序注塑模具装置的技术方案是:包括有置于热流道板内的加热体及置于热流道板外的加热圈,加热圈通过热嘴、热嘴垫套与加热体连接,其中加热体上还装设有往复直线运动机构,加热体的外侧装设有与之一起运动的隔片。The technical scheme of the internal vibration sequential injection mold device of the utility model is: it includes a heating body placed inside the hot runner plate and a heating ring placed outside the hot runner plate, and the heating ring is connected to the heating body through the hot nozzle and the hot nozzle pad cover , wherein the heating body is also equipped with a reciprocating linear motion mechanism, and the outer side of the heating body is equipped with a spacer that moves with it.
上述往复直线运动机构)包括有电磁块、挡块,电磁块通过挡块及连接件与加热体连接,电磁块置于控制其吸合的电磁铁的旁侧。The above-mentioned reciprocating linear motion mechanism) includes an electromagnetic block and a stopper, the electromagnetic block is connected with the heating body through the stopper and the connector, and the electromagnetic block is placed on the side of the electromagnet that controls its attraction.
上述往复直线运动机构或包括有由电机驱动的凸轮,凸轮推动与加热体连接的滑轮运动。The above-mentioned reciprocating linear motion mechanism may include a cam driven by a motor, and the cam pushes the pulley connected with the heating body to move.
上述隔片包括有隔离腔室的腔室隔片及搅拌振动的搅拌隔片,加热体包括有加热棒体及置于加热棒体中部通孔内的发热元件,腔室隔片及搅拌隔片固定在加热棒体的外侧壁上。The spacer includes a chamber spacer for isolating the chamber and a stirring spacer for stirring and vibrating, the heating body includes a heating rod body and a heating element placed in the through hole in the middle of the heating rod body, the chamber spacer and the stirring spacer It is fixed on the outer wall of the heating rod body.
上述腔室隔片及搅拌隔片直接做出在加热棒体的外侧,与加热棒体做成一体结构。The chamber spacer and the stirring spacer are directly made on the outside of the heating rod body, and are made into an integral structure with the heating rod body.
上述加热圈的外侧设有感温圈。A temperature-sensing ring is provided outside the heating ring.
上述热流道板上设有喷嘴,喷嘴的两侧分别通过固定件连接有隔热垫圈及通过紧定件连接有中央垫圈;热流道板的下侧分别通过连接有第二隔热垫圈,通过第二紧定件连接有第二垫圈。The above hot runner plate is provided with nozzles, and the two sides of the nozzles are respectively connected with heat insulating gaskets through fixing parts and the central gasket through fasteners; the lower side of the hot runner plate is respectively connected with a second heat insulating The two fasteners are connected with a second washer.
上述连接件及第二紧定件为销钉,固定件、紧定件、第二固定件为内六角螺钉。The above-mentioned connecting piece and the second fastening piece are pins, and the fixing piece, the fastening piece and the second fastening piece are hexagon socket head cap screws.
本实用新型与现有技术相比,具有如下优点:Compared with the prior art, the utility model has the following advantages:
1)本实用新型内振动顺序注塑模具装置区别于现有的多浇口外加热热流道模具,采用内置加热的结构,减少能源消耗,可以有效的利用能源,降低能源损失。1) The internal vibration sequence injection mold device of the utility model is different from the existing multi-gate external heating hot runner mold, and adopts a built-in heating structure to reduce energy consumption, effectively use energy and reduce energy loss.
2)本实用新型内振动顺序注塑模具装置的振动频率的范围很大,电磁的频率可能在100次/分钟,机械--凸轮型的频率范围可以扩大。2) The scope of the vibration frequency of the vibration sequence injection mold device in the utility model is very large, the electromagnetic frequency may be 100 times/minute, and the frequency range of the mechanical-cam type can be expanded.
3)本实用新型内振动顺序注塑模具装置使熔体在振动场中的表观粘度与振动频率、振幅、口模温度和注塑螺杆转速均有关,随着振动频率的增加,表观粘度先降至最低值,然后回升到一定程度后基本保持不变,但始终低于未施加振动时的表观粘度;振幅越大,振动场对表观粘度的影响就越大;当口模温度超过熔点时,振动场对表观粘度的影响有所增大;螺杆转速越大,振动场对表观粘度的影响就越小。3) The internal vibration sequence injection mold device of the utility model makes the apparent viscosity of the melt in the vibration field related to the vibration frequency, amplitude, die temperature and injection screw speed. With the increase of the vibration frequency, the apparent viscosity first decreases to the lowest value, then rises to a certain level and remains basically unchanged, but is always lower than the apparent viscosity when no vibration is applied; the larger the amplitude, the greater the impact of the vibration field on the apparent viscosity; when the die temperature exceeds the melting point , the effect of the vibration field on the apparent viscosity increases; the greater the screw speed, the smaller the effect of the vibration field on the apparent viscosity.
4)本实用新型内振动顺序注塑模具装置的运用还起到阀的作用,改变各个浇口的开启时间,通过调节各个注塑工艺参数,来达到注塑产品的质量,注塑时的压力和熔体温度均可设置得低很多,这样既可减少制品的内应力,又可防止高温对制品带来的降解威胁,还可以有效地消除了制品熔接痕和气泡,使制品的强度和表观质量得到很大提升。4) The application of the internal vibration sequence injection mold device of the utility model also plays the role of a valve, changing the opening time of each gate, and adjusting the parameters of each injection molding process to achieve the quality of the injection molding product, the pressure and melt temperature during injection molding It can be set much lower, which can not only reduce the internal stress of the product, but also prevent the degradation threat brought by high temperature to the product. It can also effectively eliminate the weld line and air bubbles of the product, so that the strength and appearance quality of the product can be greatly improved. big boost.
5)本实用新型内振动顺序注塑模具装置不仅在产品的注射阶段能改善高聚物的流动充填,而且在保压阶段,运用多浇口的压力差和频率,能有效的改变产品的成型质量,减少产品的缺陷,提高机械性能。5) The internal vibration sequence injection mold device of this utility model can not only improve the flow filling of high polymer in the injection stage of the product, but also effectively change the molding quality of the product in the pressure holding stage by using the pressure difference and frequency of multiple gates , Reduce product defects and improve mechanical properties.
6)本实用新型内振动顺序注塑模具装置利用“频率一温度等效原理来加工热敏性聚合物,可以有有效地降低注塑压力和温度,从而降低能耗,提高产率。6) The internal vibration sequence injection mold device of the utility model uses the principle of "frequency-temperature equivalence" to process heat-sensitive polymers, which can effectively reduce injection pressure and temperature, thereby reducing energy consumption and increasing productivity.
本实用新型振动顺序注塑新装置能有效的减少产品的缺陷,提高产品的机械性能,增加产品的竞争力,降低生产成本,增加经济效益和社会效益。The new vibration sequence injection molding device of the utility model can effectively reduce product defects, improve product mechanical properties, increase product competitiveness, reduce production cost, and increase economic and social benefits.
附图说明:Description of drawings:
图1为本实用新型内振动顺序注塑模具装置的结构示意图;Fig. 1 is the structural representation of the internal vibration sequence injection mold device of the utility model;
图2为本实用新型中隔片(7)装在加热体(6)上的结构示意图;Fig. 2 is the structural representation that spacer (7) is contained on the heating body (6) in the utility model;
图3为本实用新型中腔室隔片(71)的结构示意图;Fig. 3 is the structural representation of chamber partition (71) in the utility model;
图4为本实用新型中搅拌隔片(72)的结构示意图;Fig. 4 is the structural representation of stirring spacer (72) in the utility model;
图5为本实用新型中隔片(7)与加热体(6)做为一体的结构示意图;Fig. 5 is the structure schematic diagram that partition (7) and heating body (6) are integrated in the utility model;
图6为图5中A-A的剖面图;Fig. 6 is the sectional view of A-A in Fig. 5;
图7为图5中B-B的剖面图;;Fig. 7 is the sectional view of B-B in Fig. 5;;
图8为本实用新型中往复直线运动机构(A)的结构示意图。Fig. 8 is a structural schematic diagram of the reciprocating linear motion mechanism (A) in the present invention.
具体实施方式:Detailed ways:
实施例:Example:
本实用新型内振动顺序注塑模具装置的结构示意图如图1所示,包括有置于热流道板3内的加热体6及置于热流道板3外的加热圈1,加热圈1通过热嘴18、热嘴垫套2与加热体6连接,其中加热体6上还装设有往复直线运动机构A,加热体6的外侧装设有与之一起运动的隔片7。The structural diagram of the internal vibration sequential injection mold device of the utility model is shown in Figure 1, including a
上述往复直线运动机构A包括有电磁块4、挡块5,电磁块4通过挡块5及连接件8与加热体6连接,电磁块4置于控制其吸合的电磁铁的旁侧。上述加热圈1的外侧设有感温圈17。The above-mentioned reciprocating linear motion mechanism A includes an electromagnetic block 4 and a
上述热流道板3上设有喷嘴21,喷嘴21的两侧分别通过固定件10连接有隔热垫圈9及通过紧定件12连接有中央垫圈11;热流道板3的下侧分别通过连接有第二隔热垫圈13,通过第二紧定件16连接有第二垫圈15。The
上述连接件8及第二紧定件16为销钉,固定件10、紧定件12、第二固定件14为内六角螺钉。The connecting
上述往复直线运动机构A还可以是图8所示的结构,包括有由电机驱动的凸轮19,凸轮19推动与加热体6连接的滑轮20运动。The above-mentioned reciprocating linear motion mechanism A can also be the structure shown in FIG. 8 , including a
上述隔片7的结构示意图如图2、3、4所示,包括有隔离腔室的腔室隔片71及搅拌振动的搅拌隔片72,加热体6包括有加热棒体61及置于加热棒体61中部通孔内的发热元件,腔室隔片71及搅拌隔片72固定在加热棒体61的外侧壁上。The structural representation of above-mentioned
此外,上述腔室隔片71及搅拌隔片72还可以直接做出在加热棒体61的外侧,与加热棒体61做成一体结构,如图5、6、7所示,In addition, the
用本实用新型内振动顺序注塑模具装置进行注塑,其包括如下工艺步骤:Injection molding is carried out with the vibration sequence injection mold device in the utility model, which comprises the following process steps:
1)加热圈1接通电源,将热量传递到加热体6,以对热流道板3内的塑料进行加热;1) The
2)加热体6上的往复直线运动机构A进行来回运动,实现对热流道板3内的熔融的高聚物进行振动;2) The reciprocating linear motion mechanism A on the
3)装在加热体6上的隔片7使熔融的高聚物于喷嘴隔开,控制往复直线运动机构A的来回运动的频率,以使隔片7按规定时间控制浇口的打开及关闭,使模具热流道板3内的熔体按顺序进入型腔的不同位置,以达到顺序浇注的作用。3) The
上述往复直线运动机构A的来回运动的频率通过电磁开关或利用定时时间器控制,以控制浇口的注塑顺序。The frequency of the back and forth motion of the above-mentioned reciprocating linear motion mechanism A is controlled by an electromagnetic switch or a timing timer to control the injection sequence of the gates.
本实用新型工作时,可控制电磁块4的动作,使加热体6往复运动,也可以用机械凸轮来驱动,根据注塑回路的时间来设计凸轮的轨迹,通过电机的转动速率来控制振动的频率。When the utility model works, the action of the electromagnetic block 4 can be controlled to make the
熔体在振动场中的表观粘度与振动频率、振幅、口模温度和注塑螺杆转速均有关,随着振动频率的增加,表观粘度先降至最低值,而后回升到一定程度后基本保持不变,但始终低于未施加振动时的表观粘度;振幅越大,振动场对表观粘度的影响就越大;当口模温度超过熔点时,振动场对表观粘度的影响有所增大,利用粘度的降低,可以降低注塑温度,注塑压力,有利于高聚物的塑料的成型,得以注塑出好的产品。塑料制件也减少了各种缺陷:飞边、熔接痕、气穴、缩凹、喷射、滞流等。The apparent viscosity of the melt in the vibration field is related to the vibration frequency, amplitude, die temperature and injection screw speed. As the vibration frequency increases, the apparent viscosity first drops to the lowest value, and then rises to a certain level and then basically maintains constant, but always lower than the apparent viscosity without vibration; the greater the amplitude, the greater the effect of the vibration field on the apparent viscosity; when the die temperature exceeds the melting point, the effect of the vibration field on the apparent viscosity increases Large, using the reduction of viscosity, the injection temperature and injection pressure can be reduced, which is beneficial to the molding of high polymer plastics, and good products can be injection molded. Plastic parts also reduce various defects: flash, weld lines, air pockets, sinking, jetting, stagnation, etc.
通过改变振动频率,聚合物高分子在注塑过程中的物理、化学状态的急剧变化和塑料熔体流动方向的改变,使得成型过程中塑料熔体会产生有规律的剪切作用、取向现象、结晶现象,消除熔接痕和残余内应力,这些均对注塑件的强度产生有利。在剪切力作用下,聚合物大分子键角和键长改变并被迫产生拉伸形变。当剪切作用增强,能量超过大分子键能时,会引起大分子断裂降解,从而降低注塑件的力学性能。而有规律的振动能阻止注塑件的力学性能下降。聚合物高分子的取向使得分子链沿受力方向排列,导致各向异性特点。聚合物高分子的取向受充填速度、加工工艺和材料属性以及纤维等填充剂的影响。对于纤维增强塑料而言,其纤维取向的影响更大,不可忽略。运用振动注塑,有利于高分子的取向,有利于提高产品的机械性能。根据自由体积理论可知,高分子链的运动是通过链段的运动和扩散而逐步达到整体运动的。高分子链很大,易结成网状,而缠节点之间则构成空穴。当引入振动力场时,一方面,振动增加了高分子链之间的相互剪切摩擦,产生大量的耗散热,增加了高分子的热运动能,空穴也随着增加和胀大,分子问的相互作用力减少,导致高分子链的蠕动能力增强;另一方面,振动不断对聚合物熔体进行挤压和释放,增加了分子的取向,分子间空穴增大,分子链重心偏移,也降低了分子间的相互作用力,从而使聚合物熔体的流动性增加。宏观上则表现为聚合物熔体的粘度减小,流率增大,弹性减小,挤出压力降低.能耗降低。由此而改善了塑料的挤出加工过程,使制品的性能得到一定程度的提高。By changing the vibration frequency, the sharp change of the physical and chemical state of the polymer polymer during the injection molding process and the change of the flow direction of the plastic melt will cause regular shearing, orientation, and crystallization of the plastic melt during the molding process. Phenomenon, eliminate weld marks and residual internal stress, which are beneficial to the strength of injection molded parts. Under the action of shear force, the bond angles and bond lengths of polymer macromolecules change and are forced to produce tensile deformation. When the shear action is enhanced and the energy exceeds the bond energy of the macromolecules, it will cause the macromolecules to break and degrade, thereby reducing the mechanical properties of the injection molded parts. And regular vibration can prevent the mechanical properties of injection molded parts from declining. The orientation of the polymer macromolecules makes the molecular chains align along the direction of the force, resulting in anisotropic characteristics. The orientation of the polymer polymer is affected by the filling speed, processing technology and material properties, as well as fillers such as fibers. For fiber-reinforced plastics, the influence of fiber orientation is greater and cannot be ignored. The use of vibration injection molding is conducive to the orientation of polymers and the improvement of mechanical properties of products. According to the free volume theory, the movement of polymer chains gradually reaches the overall movement through the movement and diffusion of chain segments. The polymer chains are very large and easy to form a network, while the intertwined nodes form cavities. When the vibration force field is introduced, on the one hand, the vibration increases the mutual shear friction between the polymer chains, generates a large amount of heat dissipation, increases the thermal kinetic energy of the polymer, and the holes also increase and expand, and the molecules On the other hand, the vibration continuously squeezes and releases the polymer melt, which increases the orientation of the molecules, increases the intermolecular cavities, and shifts the center of gravity of the molecular chains. The shift also reduces the interaction force between molecules, thereby increasing the fluidity of the polymer melt. Macroscopically, it shows that the viscosity of the polymer melt decreases, the flow rate increases, the elasticity decreases, the extrusion pressure decreases, and the energy consumption decreases. As a result, the extrusion process of the plastic is improved, and the performance of the product is improved to a certain extent.
振动顺序注塑由于采用定时时间器控制浇口,使模具内的熔体按顺序进入型腔的不同位置,可以排除两个浇口之间熔接痕现象,所以制品的强度和表观质量得到很大提升,同时因为程序控制阀的运用,熔体在型腔中运行很少受冷料因素的影响,所以相对普通注塑而言,注塑时的压力和熔体温度都较普通浇口可设置得低很多,这样也减少了制品内应力的存在,并防止高温对制品带来的降解影响。另外,因为程序控制阀的运用可降低注塑压力,所以对同样的制品而言,相同的形状,相同的投影面积,不同的注塑压力要求不同的锁模力,所以运用程序控制阀的模具来制造制品对注塑机锁模力的要求较普通浇口模具对注塑机的要求要低很多。Vibration sequential injection molding uses a timing timer to control the gate, so that the melt in the mold enters different positions in the cavity in sequence, which can eliminate the weld line between the two gates, so the strength and apparent quality of the product are greatly improved. At the same time, due to the application of the program control valve, the melt running in the cavity is rarely affected by the cold material factor, so compared with ordinary injection molding, the pressure and melt temperature during injection molding can be set lower than ordinary gates This also reduces the existence of internal stress in the product and prevents the degradation of the product caused by high temperature. In addition, because the application of the program control valve can reduce the injection pressure, for the same product, the same shape, the same projected area, and different injection pressures require different clamping forces, so the mold of the program control valve is used to manufacture The requirements of the product on the clamping force of the injection molding machine are much lower than that of the ordinary gate mold on the injection molding machine.
以本实用新型用于保险杠的注塑为例,其分析的结果对比如下:Taking the injection molding that the utility model is used for bumper as an example, the results of its analysis are compared as follows:
1)顺序注塑成型比普通注塑成型所用的注塑时间少0.136s;1) The injection time of sequential injection molding is 0.136s less than that of ordinary injection molding;
2)顺序注塑成型比普通注塑成型的熔接痕明显少很多。在普通注塑成型的两条很长的熔接痕在顺序注塑成型没有出现,说明顺序注塑成型对消除熔接痕有很显著的效果。2) Sequential injection molding has significantly fewer weld lines than ordinary injection molding. The two very long weld lines in ordinary injection molding do not appear in sequential injection molding, indicating that sequential injection molding has a significant effect on eliminating weld lines.
3)顺序注塑成型比普通注塑成型的气泡明显少很多。特别是在普通注塑成型中由两股熔体会合时所产生的气泡没有在顺序注塑成型出现。3) Sequential injection molding has significantly fewer bubbles than ordinary injection molding. Especially in ordinary injection molding, the bubbles produced when two melts meet do not appear in sequential injection molding.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101264654B (en) * | 2007-08-06 | 2010-05-19 | 广东工业大学 | A sequential injection mold device with internal vibration and its injection molding process |
| CN115179518A (en) * | 2022-06-24 | 2022-10-14 | 南通顺驰橡胶制品有限公司 | A kind of preparation method of antibacterial butyl rubber inner tube |
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| CN101264654B (en) * | 2007-08-06 | 2010-05-19 | 广东工业大学 | A sequential injection mold device with internal vibration and its injection molding process |
| CN115179518A (en) * | 2022-06-24 | 2022-10-14 | 南通顺驰橡胶制品有限公司 | A kind of preparation method of antibacterial butyl rubber inner tube |
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