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CN201065399Y - Air flow bed coal gasification reactor - Google Patents

Air flow bed coal gasification reactor Download PDF

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Publication number
CN201065399Y
CN201065399Y CN 200720032288 CN200720032288U CN201065399Y CN 201065399 Y CN201065399 Y CN 201065399Y CN 200720032288 CN200720032288 CN 200720032288 CN 200720032288 U CN200720032288 U CN 200720032288U CN 201065399 Y CN201065399 Y CN 201065399Y
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CN
China
Prior art keywords
gas cylinder
cooling
water
reaction zone
interior gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN 200720032288
Other languages
Chinese (zh)
Inventor
门长贵
张勇
贺根良
郑化安
郑亚兰
徐宏伟
徐红东
李璞
薛薇
崔意华
韦孙昌
朱春鹏
林益安
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xi'an Origin Chemical Technologies Co., Ltd.
Original Assignee
NORTHWEST RESEARCH INSTITUTE OF CHEMICAL INDUSTRY
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN 200720032288 priority Critical patent/CN201065399Y/en
Application granted granted Critical
Publication of CN201065399Y publication Critical patent/CN201065399Y/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • C10J3/845Quench rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/485Entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/52Ash-removing devices
    • C10J3/526Ash-removing devices for entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/74Construction of shells or jackets
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crucibles And Fluidized-Bed Furnaces (AREA)

Abstract

The utility model discloses a coal gasification reactor of entrained flow bed, comprising a high-temperature reaction part and a cooling and deslagging part, wherein, a pressure measuring port and a temperature measuring port are arranged on the side of the high-temperature reaction part; a plurality of refractory material layers are arranged on the inner wall of the reaction part; the refractory material near the slag hole of the furnace body is laid into a conical slope; a plurality of gas cylinders are arranged in a quenching zone; the lower parts of the gas cylinders are extended into a water bath zone; the internal gas cylinder is used for quenching the raw gas with cooling water; a plurality of strip openings are arranged on the external gas cylinder and are arranged circumferentially around the upper part of the external gas cylinder for discharging the raw gas out of the reactor. The utility model has the advantages of strong adaptability of coal, solid-state deslagging operation for the high ash melting point coal, liquid-state deslagging operation for the low ash melting point coal, less moisture and dust content of the produced raw gas, low requirement for related equipment, obvious reduction of corrosion and flushing to equipment components, long service life of whole device, low failure rate and great improvement of productivity.

Description

A kind of air-flow bed coal-gasification reactor
Technical field
The utility model belongs to the clean comprehensive utilization technique of energy field, relates to a kind of air-flow bed coal-gasification reactor.
Background technology
Industrialized airflow bed gasification furnace is a raw material with coal water slurry or dry coal powder, and the mode of pure oxygen gasification is main, and the type of furnace is the full cold hearth based on full hot wall stove, half water wall or the water-cooled wall type of refractory materials formation.For the existing above-mentioned gasification type of furnace, the normal gasification mode that adopts slag, as full hot wall vapourizing furnace, service temperature can arrive 1350 ℃-1500 ℃ high temperature, the fluid slag that produces is to the erosion of device and wash away more serious, cause whole device shorter work-ing life, influence the normal production cycle, and with unsafe factor; And cold wall vapourizing furnace, because heat dissipation capacity is big, liquid slag very easily Quench is solidified, and it is stifled to produce dross and slag in the stove, and equipment damages problems such as causing the vapourizing furnace parking easily; Moreover the service temperature height of vapourizing furnace, the temperature after the Quench of coal gas is also high, and raw gas is bigger at the flow velocity of shock chamber, and it is bigger to go out moisture content and amount of dust that the vapourizing furnace raw gas carries secretly, and the processing load of follow-up workshop section is big, the weak effect of the washing, purifying of coal gas.The coal resource of present domestic high ash melting point, ash-rich is than horn of plenty, if adopt the slag gasification, the efficient of gasification is relatively poor, these coal resources that how to gasify efficiently, and the present gasification type of furnace can't realize.
In sum, prior art constructions is reasonable inadequately, can't realize that cleaning utilize efficiently to existing coal resources, the suffered erosion of major parts and wash away more seriously in process of production, and the reactor trim apparatus life-span is short, the failure rate height, production efficiency is low.
Summary of the invention
The purpose of this utility model provides a kind of air-flow bed coal-gasification reactor, solve the suffered erosion of the major parts that exists in the prior art and wash away more serious, the problem that the equipment life that causes is short.
The technical scheme that the utility model adopted is, a kind of air-flow bed coal-gasification reactor, comprise pyroreaction part and cooling deslagging part, described pyroreaction partly comprises reaction zone, the upper end of reaction zone is provided with material inlet, and the side of reaction zone is equipped with pressure tap and temperature-measuring port, and the lower end of reaction zone is provided with slag notch, the inwall of reaction zone is lined with refractory materials, and the lower end of refractory materials is provided with the refractory materials loading plate;
Described cooling deslagging partly comprises slag notch, refractory materials adopts tapered slope to lay near the slag notch, slag notch is connected with the upper end of interior gas cylinder, interior gas cylinder connects quench zone downwards, quench zone inserts the water-bath district by interior gas cylinder downwards, the shell place of the upper end correspondence of interior gas cylinder has entrance of cooling water, entrance of cooling water is connected with chiller, the upper end of interior gas cylinder and the overflow port of chiller communicate, shell inboard by the entrance of cooling water lower edge is provided with cooling garden dish, the upper end inner ring opening diameter of cooling garden dish is suitable with the external diameter of interior gas cylinder, have the raw gas outlet on the shell of cooling garden dish lower surface, the lower surface of cooling garden dish is equipped with outer gas cylinder, outer gas cylinder and the concentric suit of interior gas cylinder also leave spacing formation air guide channel, the upper end edge circumference of outer gas cylinder has several windows, and all below the water surface in water-bath district, the following bottom in water-bath district is provided with slag-drip opening for the lower end outlet of interior gas cylinder and the lower end outlet of outer gas cylinder.
The lower end of gas cylinder outlet horizontal plane is higher than the lower end outlet horizontal plane of outer gas cylinder in described.
The window of described outer airway upper end is a marking shape window.
Be lined with multiple layer refractory in the described reaction zone.
The beneficial effects of the utility model are, the erosion that each parts is suffered and washing away obviously alleviates, and prolong whole device lifetime, and gasification efficiency obviously improves.
Structure of the present utility model is more reasonable, and failure rate obviously reduces, and production efficiency obviously improves.
Description of drawings
Fig. 1 is a structural representation of the present utility model;
Fig. 2 is the structural representation of a kind of embodiment marking shape window of the present utility model.
Among the figure, 1, material inlet, 2, reaction zone, 3, pressure tap, 4, temperature-measuring port, 5, refractory materials, 6, slag notch, 7, the refractory materials loading plate, 8, chiller, 9, entrance of cooling water, 10, marking shape window, 11, the raw gas outlet, 12, quench zone, 13, interior gas cylinder, 14, outer gas cylinder, 15, water-bath district, 16, slag-drip opening, 17, cooling garden dish, 18, air guide channel, 19, shell, 20, overflow port.
Embodiment
Below in conjunction with the drawings and specific embodiments the utility model is elaborated.
As shown in Figure 1, the utility model comprises pyroreaction part and cooling deslagging part, pyroreaction partly comprises reaction zone 2, the upper end of reaction zone 2 is equipped with material inlet 1, the side of reaction zone 2 is equipped with pressure tap 3 and temperature-measuring port 4, the inwall of reaction zone 2 is lined with refractory materials 5, and the lower surface of refractory materials 5 is equipped with refractory materials loading plate 7, and the lower end of reaction zone 2 is provided with slag notch 6;
The cooling deslagging partly comprises slag notch 6, slag notch 6 place's refractory materialss 5 adopt tapered slope to lay, slag notch 6 is connected with the upper end of interior gas cylinder 13, interior gas cylinder 13 connects quench zone 12 downwards, quench zone 12 inserts water-bath district 15 by interior gas cylinder 13 downwards, shell 19 places of the upper end correspondence of interior gas cylinder 13 have entrance of cooling water 9, entrance of cooling water 9 is connected with chiller 8, the overflow port 20 of the upper end of interior gas cylinder 13 and chiller 8 communicates, shell 19 inboards by entrance of cooling water 9 lower edges are provided with cooling garden dish 17, the inner ring opening diameter of cooling garden dish 17 is suitable with the external diameter of interior gas cylinder 13, the cooling garden is coiled and is had raw gas outlet 11 on the shell 19 of 17 lower surfaces, the lower surface of cooling garden dish 17 is equipped with outer gas cylinder 14, outer gas cylinder 14 and interior gas cylinder 13 concentric suits also leave spacing formation air guide channel 18, the upper end edge circumference of outer gas cylinder 14 has several marking shape windows 10, all below the water surface in water-bath district 15, the following bottom in water-bath district 15 is equipped with slag-drip opening 16 for the lower end outlet of interior gas cylinder 13 and the lower end outlet of outer gas cylinder 14.
Be lined with resistant to elevated temperatures refractory materials 5 in the shell 19 of reaction zone, wherein refractory materials 5 inwardly is followed successively by heat-resistant felt, high-temperature-resistant thermal-insulation layer refractory brick, thermal insulation layer refractory brick, side towards the fire refractory brick by furnace wall shell 19.They are used for keeping the interior high-temperature high-pressure state of stove, play good erosion resistant and insulation effect.
Pressure tap 3 and temperature-measuring port 4 can install and measure instrument respectively, and reaction zone 2 is monitored at any time.
Gas cylinder 13 in water coolant inserts by the overflow port 20 with refractory materials loading plate 7 belows plays a part to cool for interior gas cylinder 13 and quench zone 12.
As shown in Figure 2, window shape is arranged to the long strip shape opening, and its effect is to reduce the flow velocity of raw gas, makes the moisture content that carries in the raw gas, thin ash fall into water-bath district 15 by downward inertia, and the rough coal band of gas water band ash of discharge reduces as far as possible.The number of marking shape window 10 can change shape and quantity according to demand.
Slip process refinement and oxygen enrichment pressurize together and enter reaction zone 2 from material inlet 1, under high-temperature and high-pressure conditions, react, the operational condition of the reaction zone 2 of gasifying reactor is: 1250 ℃-1650 ℃ of temperature of reaction, reaction pressure is: raw gas and lime-ash that 0.1-20MPa produces enter quench zone 12, water quick cooling, cooling, mixing and moistening are cooled, help raw gas and lime-ash in the separating of water-bath district 15, lime-ash enters the bottom in water-bath district 15, discharges from slag-drip opening 16.Raw gas descends along interior gas cylinder 13 and enters water-bath district 15 through overcooling, rises along air guide channel 18, discharges this reactor through marking shape window 10 from raw gas outlet 11.
Air-flow bed coal-gasification reactor coal adaptability of the present utility model is strong, can adopt the dry ash extraction operation for the coal of high ash melting point; Can adopt the slag tap operation for low-ash-fusion coal.The lime-ash that the utility model produces in process of production falls into water-bath district 15 basically, the parts of whole reactor is corroded and wash away obviously alleviate, and prolong whole device lifetime, and failure rate reduces, and production efficiency obviously improves.

Claims (5)

1. air-flow bed coal-gasification reactor, comprise pyroreaction part and cooling deslagging part, it is characterized in that: described pyroreaction partly comprises reaction zone (2), the upper end of reaction zone (2) is provided with material inlet (1), the side of reaction zone (2) is provided with pressure tap (3) and temperature-measuring port (4), there is slag notch (6) lower end of reaction zone (2), and the inwall of reaction zone (2) is lined with refractory materials (5), and the lower end of refractory materials (5) is provided with refractory materials loading plate (7);
Described cooling deslagging partly comprises slag notch (6), slag notch (6) refractory liner adopts tapered slope, slag notch (6) is connected with the upper end of interior gas cylinder (13), interior gas cylinder (13) connects quench zone (12) downwards, quench zone (12) inserts water-bath district (15) by interior gas cylinder (13) downwards, the shell (19) of the upper end correspondence of interior gas cylinder (13) locates to have entrance of cooling water (9), entrance of cooling water (9) is connected with chiller (8), the overflow port (20) of the upper end of interior gas cylinder (13) and chiller (8) communicates, shell (19) installed inside by entrance of cooling water (9) lower edge has cooling garden dish (17), the upper end inner ring opening diameter of cooling garden dish (17) is suitable with the external diameter of interior gas cylinder (13), have raw gas outlet (11) on the shell (19) of cooling garden dish (17) lower surface, the lower surface of cooling garden dish (17) is equipped with outer gas cylinder (14), the concentric suit of outer gas cylinder (14) and interior gas cylinder (13) also leaves spacing formation air guide channel (18), the upper end edge circumference of outer gas cylinder (14) has several windows (10), all below the water surface of water-bath district (15), the following bottom of water-bath district (15) is provided with slag-drip opening (16) for the lower end outlet of interior gas cylinder (13) and the lower end outlet of outer gas cylinder (14).
2. air-flow bed coal-gasification reactor as claimed in claim 1 is characterized in that: the lower end of gas cylinder (13) outlet horizontal plane is higher than the lower end outlet horizontal plane of outer gas cylinder (14) in described.
3. air-flow bed coal-gasification reactor as claimed in claim 1 is characterized in that: the window (10) on the described outer airway is a marking shape window.
4. air-flow bed coal-gasification reactor as claimed in claim 1 is characterized in that: described reaction zone is lined with multiple layer refractory in (2).
5. air-flow bed coal-gasification reactor as claimed in claim 1 is characterized in that: the operational condition of described reactor is: gasification temperature is that 1250 ℃-1650 ℃, vapor pressure is 0.1-20MPa.
CN 200720032288 2007-07-20 2007-07-20 Air flow bed coal gasification reactor Expired - Lifetime CN201065399Y (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102471708A (en) * 2009-07-27 2012-05-23 蒂森克虏伯伍德有限公司 Gasification reactors for the production of raw gases containing CO or H2
CN101735858B (en) * 2009-12-24 2013-02-20 西北化工研究院 Mixed atomizer cooling protection system for entrained-flow reactor
CN103031156A (en) * 2012-12-13 2013-04-10 新奥科技发展有限公司 Dry-process slag discharge device and method for entrained flow bed
CN103361125A (en) * 2013-07-29 2013-10-23 煤炭科学研究总院 Semi-radiant semi-chill flow radiation syngas cooler apparatus
CN104498105A (en) * 2014-12-09 2015-04-08 西北化工研究院 Chilling type single waste pan reactor
CN104531228A (en) * 2014-12-18 2015-04-22 广东正鹏生物质能源科技有限公司 Device and method for implementing efficient purification of biomass gas in furnace
CN108410517A (en) * 2017-02-09 2018-08-17 通用电气公司 Gasify chilling train
CN113403111A (en) * 2021-07-30 2021-09-17 山西阳煤化工机械(集团)有限公司 Energy-saving low-consumption gasification furnace and coal gasification method

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102471708A (en) * 2009-07-27 2012-05-23 蒂森克虏伯伍德有限公司 Gasification reactors for the production of raw gases containing CO or H2
CN102471708B (en) * 2009-07-27 2014-06-25 蒂森克虏伯伍德有限公司 Gasification reactors for the production of raw gases containing CO or H2
CN101735858B (en) * 2009-12-24 2013-02-20 西北化工研究院 Mixed atomizer cooling protection system for entrained-flow reactor
CN103031156B (en) * 2012-12-13 2014-11-05 新奥科技发展有限公司 Dry-process slag discharge device and method for entrained flow bed
CN103031156A (en) * 2012-12-13 2013-04-10 新奥科技发展有限公司 Dry-process slag discharge device and method for entrained flow bed
CN103361125B (en) * 2013-07-29 2014-12-31 煤炭科学技术研究院有限公司 Semi-radiant semi-chill flow radiation syngas cooler apparatus
CN103361125A (en) * 2013-07-29 2013-10-23 煤炭科学研究总院 Semi-radiant semi-chill flow radiation syngas cooler apparatus
CN104498105A (en) * 2014-12-09 2015-04-08 西北化工研究院 Chilling type single waste pan reactor
CN104498105B (en) * 2014-12-09 2017-02-22 西北化工研究院 Chilling type single waste pan reactor
CN104531228A (en) * 2014-12-18 2015-04-22 广东正鹏生物质能源科技有限公司 Device and method for implementing efficient purification of biomass gas in furnace
CN104531228B (en) * 2014-12-18 2017-06-20 广东正鹏生物质能源科技有限公司 The device and method of high-efficient purification in a kind of achievable biomass gas stove
CN108410517A (en) * 2017-02-09 2018-08-17 通用电气公司 Gasify chilling train
CN108410517B (en) * 2017-02-09 2021-10-15 气体产品与化学公司 Gasification quench system
CN113403111A (en) * 2021-07-30 2021-09-17 山西阳煤化工机械(集团)有限公司 Energy-saving low-consumption gasification furnace and coal gasification method

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Owner name: XI'AN YUANCHUANG CHEMICAL INDUSTRY TECHNOLOGY CO.,

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Effective date: 20130830

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Address after: 710061, west two floor, Qujiang campus, Xi'an Jiao Tong University, Yanta Road, 99, Yanta District, Shaanxi, Xi'an

Patentee after: Xi'an Origin Chemical Technologies Co., Ltd.

Address before: 710600 No. 1 Railway Station Street, Lintong District, Shaanxi, Xi'an

Patentee before: The Northwest Research Institute of Chemical Industry

CX01 Expiry of patent term

Granted publication date: 20080528

CX01 Expiry of patent term