CN208721921U - A kind of novel glasses eyeglass - Google Patents
A kind of novel glasses eyeglass Download PDFInfo
- Publication number
- CN208721921U CN208721921U CN201821462781.6U CN201821462781U CN208721921U CN 208721921 U CN208721921 U CN 208721921U CN 201821462781 U CN201821462781 U CN 201821462781U CN 208721921 U CN208721921 U CN 208721921U
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- China
- Prior art keywords
- protective layer
- layer
- external protection
- interior
- novel glasses
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011521 glass Substances 0.000 title claims abstract description 19
- 239000010410 layer Substances 0.000 claims abstract description 47
- 239000011241 protective layer Substances 0.000 claims abstract description 43
- 239000011248 coating agent Substances 0.000 claims abstract description 21
- 238000000576 coating method Methods 0.000 claims abstract description 21
- 239000012528 membrane Substances 0.000 claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000006096 absorbing agent Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 4
- 230000003667 anti-reflective effect Effects 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 2
- 238000002834 transmittance Methods 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 27
- 238000003618 dip coating Methods 0.000 description 7
- 238000007654 immersion Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000003682 fluorination reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- DFUYAWQUODQGFF-UHFFFAOYSA-N 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane Chemical compound CCOC(F)(F)C(F)(F)C(F)(F)C(F)(F)F DFUYAWQUODQGFF-UHFFFAOYSA-N 0.000 description 1
- SQEGLLMNIBLLNQ-UHFFFAOYSA-N 1-ethoxy-1,1,2,3,3,3-hexafluoro-2-(trifluoromethyl)propane Chemical compound CCOC(F)(F)C(F)(C(F)(F)F)C(F)(F)F SQEGLLMNIBLLNQ-UHFFFAOYSA-N 0.000 description 1
- 208000020564 Eye injury Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 229940045180 ethyl perfluoroisobutyl ether Drugs 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Eyeglasses (AREA)
- Surface Treatment Of Optical Elements (AREA)
Abstract
The utility model discloses a kind of novel glasses eyeglass, belong to optometric technology field, including resin material substrate, and the membrane system on substrate interior surface and outer surface, it is characterized by: wherein the membrane system of inner surface successively includes interior stiffening layer from inside to outside, inner protective layer and interior protective layer, the membrane system of outer surface successively includes outer stiffening layer from inside to outside, external protection and external protection coating, the interior stiffening layer or outer stiffening layer, with a thickness of 3 μm~5 μm, the inner protective layer or external protection, with a thickness of 0.2 μm~0.4 μm, the interior protective layer or external protection coating, with a thickness of 0.005 μm~0.01 μm.The utility model, design science, reasonable, novelty, the diversified design of eyeglass stiffening layer, protective layer and protective layer generate different novel effects, and structure is simple, good transmittance, comfortable wearing, acts on safe and reliable.
Description
Technical field
The utility model relates to optometric technology field more particularly to novel glasses eyeglasses.
Background technique
To make eyeglass, surface is not scratched sanding in use, keeps good transparent clarity for a long time, and eyeglass exists
One layer of stiffened film layer of surface dip-coating and heating cure, make the lens surface hardness by the raising of base's egative film when production, hard resistance to
Mill, ensure that the service life of glasses.But the only this eyeglass with stiffened film layer, can not fully meet in use
Actual demand.
Utility model content
In order to solve the problems, such as above-mentioned eyeglass in actual use, the utility model aim is, provides a kind of novel glasses
Eyeglass is equipped with stiffening layer, protective layer and protective layer.
Above technical problems of the utility model are mainly solved by the following technical scheme: a kind of novel glasses
Membrane system on eyeglass, including resin material substrate and substrate interior surface and outer surface, it is characterised in that: wherein inner surface
Membrane system successively includes interior stiffening layer, inner protective layer and interior protective layer from inside to outside, and the membrane system of outer surface successively includes from inside to outside
Outer stiffening layer, external protection and external protection coating, the interior stiffening layer or outer stiffening layer, with a thickness of 3 μm~5 μm, the interior protection
Layer or external protection, with a thickness of 0.2 μm~0.4 μm, the interior protective layer or external protection coating, with a thickness of 0.005 μm~0.01 μm.
The interior stiffening layer and outer stiffening layer are silica stiffened film.
The inner protective layer or external protection, for the anti-blue light film containing blue-light absorbers or/and ultraviolet absorbing agent or/
With antiultraviolet film.
The inner protective layer is the anti-reflection antireflective film of anti-reflection anti-reflection blue light or/and ultraviolet light.
The external protection, for reflection blue light or/and the reflectance coating of ultraviolet light.
The inner protective layer or external protection are multi-layer silica dioxide or/and zirconium dioxide film.
The interior protective layer or external protection coating, the antifog membrane structure being formed by curing for high-hard, transparent anti-fogging liquid.
The interior protective layer or external protection coating are titanium oxide film layer.
The interior protective layer or external protection coating are the fluoride film layer structure containing fluorine element surface treating agent.
The substrate is resin material.
The utility model spectacle lens, design science, reasonable, novel, the diversification of eyeglass stiffening layer, protective layer and protective layer
Design, generates different novel effects, and structure is simple, good transmittance, comfortable wearing, acts on safe and reliable.
Detailed description of the invention
Fig. 1 is a kind of novel spectacle lens schematic diagram of the utility model；
In above-mentioned attached drawing: O- eyeglass；Stiffening layer in A1-；A2- inner protective layer；Protective layer in A3-；The outer stiffening layer of B1-；B2-
External protection；B3- external protection coating.
Specific embodiment
Embodiment 1
As shown in Figure 1, the novel glasses eyeglass of the utility model, including spherical surface or sized non-spherical resin material base O, in institute
It states and all has membrane system in the inner surface and the outer surface of substrate 1, wherein the membrane system of inner surface successively includes interior stiffening layer from inside to outside
A1, inner protective layer A2 and interior protective layer A3, the membrane system of outer surface from inside to outside successively include outer stiffening layer B1, external protection B2 and
External protection coating B3.The interior stiffening layer A1 or outer stiffening layer B1, effect is to improve lens surface hardness, (micro- with a thickness of 3~5 μm
Rice), the inner protective layer A2 or external protection B2, effect are that protection human eye avoids injuring by ultraviolet light and blue light, with a thickness of
0.2~0.4 μm, the interior protective layer A3 or external protection coating B3, effect be protection glass by dirty (oil) dirt, moisture, fog and
The pollution such as bacterium, with a thickness of 0.005~0.01 μm.
In the present embodiment, first in substrate O surface dip-coating silica hardening liquid stiffened: being linked into resin lens on hanger
Substrate slowly drops in silica hardening liquid immersion liquid slot, hanger after moving to above resin lens dip-coating pulling machine immersion liquid slot
Falling speed is 2~3mm(millimeters per second), slot interior dipping 5~10S(of residence time seconds), rise pull rate 2~3mm per second, mention
Time 30S is drawn, after eyeglass lifts out immersion liquid slot, is sent to the titanium dioxide of dry solidification lens surface institute dip-coating in far-infrared baking oven
Silicon hardening liquid obtains the silica stiffened film of stiffening layer A1 or outer stiffening layer B1 in eyeglass.
Secondly, by vacuum coating equipment, it is coated with inner protective layer A2 or external protection B2 respectively on the surface stiffened eyeglass O,
The external protection B2 is multi-layer silica dioxide, zirconium dioxide film, forms the anti-blue light film or anti-of reflection blue light or ultraviolet light
Antiultraviolet film.The inner protective layer A2 is multi-layer silica dioxide, zirconium dioxide film, forms the increasing of transmission blue light or ultraviolet light
Saturating antireflective film avoids the blue light at side rear or ultraviolet light from reflecting by eyeglass inner surface into human eye, plays anti-blue light or antiultraviolet
Effect combines the transmission of ordinary ray of the front after reflection blue light or antiultraviolet.
Then, the present embodiment is being coated with inner protective layer A2 or external protection B2 lens surface, dip-coating high-hard, transparent are antifog
Liquid: first by the high-hard, transparent anti-fogging liquid of model zhfw-01A or other anti-fogging liquids, being added in stainless steel dip tank, then
Eyeglass is suspended on above dip-coating hanger with hanging tag 40 one group, is sent to above anti-fogging liquid dip tank, hanger, which slowly falls, makes mirror
Piece enters dip-coating anti-fogging liquid in dip tank, and falling speed 2~3mm per second, slot is interior to impregnate 5~10S of residence time, rises lifting speed
2~3mm of degree per second, lifts time 30S, and eyeglass is sent to dry solidification lens antifogging in far-infrared baking oven after lifting out immersion liquid slot
Film layer, 80~100 DEG C of solidification temperature, 30~60min(of curing time point), by above-mentioned production process, formed in eyeglass O
The antifog membrane structure of protective layer A3 and external protection coating B3.
Embodiment 2
The present embodiment is similar to Example 1, the difference is that, the eyeglass O membrane system inner protective layer A2 or external protection
B2, anti-blue light or antiultraviolet film layer, are the film layers containing blue-light absorbers or ultraviolet absorbing agent, and the blue-light absorbers are adopted
With Ou Wende (OMNISTAB) blue light or ultraviolet radiation absorption agent series products or outstanding it is full of (JADEWIN) blue light or ultraviolet light is inhaled
Agent series products or other blue-light absorbers products are received, by absorbing blue light or ultraviolet light, and its energy are converted into harmless
Energy (such as thermal energy, visible light) form and discharge, achieve the purpose that prevent blue light or ultraviolet light to eye injury.
Embodiment 3
The present embodiment is similar to Example 1, is a difference in that: protective layer A3 or external protection coating B3 in the eyeglass O membrane system,
It is to be coated with titanium deoxid film on the surface eyeglass O and formed, nano-titanium dioxide has very strong " Superhydrophilic ", in its table
Face is not easy to form droplet, and nano-titanium dioxide can act on hydrocarbon under visible light, ultraviolet light irradiation.Benefit
With such a effect, nanometer titanium dioxide titanium lamina is made to be adhered to the surface of eyeglass O, using titanium dioxide light-catalyzed reaction just
The organic pollutant for being adsorbed on titania surface can be decomposed into CO2And O2, together can be by rain drop erosion with remaining inorganic matter
Completely, to realize self-cleaning function, the substance of any pickup on the surface, including greasy dirt, bacterium under the irradiation of light, due to
The catalytic action of nano-titanium dioxide, can make these hydrocarbon materials further aoxidize become gas or be easy to by
The substance wiped.Titanium deoxid film has Superhydrophilic and super permanent under light illumination, therefore, with anti-fog function, such as
One layer of thin film of titanium oxide is coated on eyeglass O, even if moisture or Water vapor condensation in air, condensed water will not form list
A water droplet, but form moisture film and equably spread over surface, so the mist of light scattering will not occur for surface.When rain is broken through,
On surface, the rainwater of attachment can also spread rapidly the water droplet that not will form dispersion sight thus as uniform moisture film.
Embodiment 4
The present embodiment is similar to Example 1, the difference is that: protective layer A3 or external protection coating in the eyeglass O membrane system
B3 is fluorinated liquid mixture and prepares and impregnate drying processing method such as with eyeglass for the fluoride film layer containing fluorine element surface treating agent
Under: service precision is respectively 0.001g(grams), electronic balance each one of 0.01g, will 1. ethylperfluoro isobutyl ether, 2. ethyl
Perfluorobutyl ether, 3. fluorine element surface treating agent (OPTOOLDSX, Daikin Ind Ltd) press the recipe ratio of 80:20:2 respectively
Example, according to weighing addition is 1. 2. 3. sequentially carried out, is stirred 1 hour, after preparing after adding each ingredient, is rolled over using 0.45 μm
Folded filter core is filtered, and fluorination liquid mixture is made.Plated film lens are impregnated into 20s in above-mentioned fluorination liquid mixture, after taking-up
60 DEG C of heat treatment 2h(hours in an oven), interior protective layer A3 or external protection coating B3 fluoride film layer is made, contains fluorine element surface
The fluoride film layer of inorganic agent has excellent water-proof and oil-proof performances.
In addition to the above, the utility model can also have other embodiment, not set out act, all uses one by one herein
The technical solution that equivalent substitution or equivalent transformation is formed, belongs to the protection scope of the requires of the utility model.
Claims (10)
1. the membrane system on a kind of novel glasses eyeglass, including resin material substrate (O) and substrate (O) the inner surface and the outer surface,
It is characterized by: wherein the membrane system of inner surface successively includes interior stiffening layer (A1), inner protective layer (A2) and interior protection from inside to outside
Layer (A3), the membrane system of outer surface successively include outer stiffening layer (B1), external protection (B2) and external protection coating (B3), institute from inside to outside
Interior stiffening layer (A1) or outer stiffening layer (B1) are stated, with a thickness of 3 μm~5 μm, the inner protective layer (A2) or external protection (B2) are thick
Degree is 0.2 μm~0.4 μm, the interior protective layer (A3) or external protection coating (B3), with a thickness of 0.005 μm~0.01 μm.
2. a kind of novel glasses eyeglass according to claim 1, it is characterised in that: the interior stiffening layer (A1) and outer stiffening layer
It (B1) is silica stiffened film.
3. a kind of novel glasses eyeglass according to claim 1, it is characterised in that: the inner protective layer (A2) or external protection
It (B2), is anti-blue light film or/and antiultraviolet film containing blue-light absorbers or/and ultraviolet absorbing agent.
4. a kind of novel glasses eyeglass according to claim 1, it is characterised in that: the inner protective layer (A2) subtracts to be anti-reflection
The anti-reflection antireflective film of anti-blue light or/and ultraviolet light.
5. a kind of novel glasses eyeglass according to claim 1, it is characterised in that: the external protection (B2) is blue for reflection
The reflectance coating of light or/and ultraviolet light.
6. a kind of according to claim 1,4 or 5 novel glasses eyeglass, it is characterised in that: the inner protective layer (A2) is outer
Protective layer (B2) is multi-layer silica dioxide or/and zirconium dioxide film.
7. a kind of novel glasses eyeglass according to claim 1, it is characterised in that: the interior protective layer (A3) or external protection coating
(B3), the antifog membrane structure being formed by curing for high-hard, transparent anti-fogging liquid.
8. a kind of novel glasses eyeglass according to claim 1, it is characterised in that: the interior protective layer (A3) or external protection coating
It (B3), is titanium oxide film layer.
9. a kind of novel glasses eyeglass according to claim 1, it is characterised in that: the interior protective layer (A3) or external protection coating
It (B3) is the fluoride film layer structure containing fluorine element surface treating agent.
10. a kind of novel glasses eyeglass according to claim 1, it is characterised in that: the substrate (O) is resin material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821462781.6U CN208721921U (en) | 2018-09-05 | 2018-09-05 | A kind of novel glasses eyeglass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821462781.6U CN208721921U (en) | 2018-09-05 | 2018-09-05 | A kind of novel glasses eyeglass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN208721921U true CN208721921U (en) | 2019-04-09 |
Family
ID=65981413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201821462781.6U Expired - Fee Related CN208721921U (en) | 2018-09-05 | 2018-09-05 | A kind of novel glasses eyeglass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN208721921U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112195439A (en) * | 2020-09-16 | 2021-01-08 | 贵州省装备制造业协会 | Forming process of antifogging film of antifogging goggles lens |
| WO2021232218A1 (en) * | 2020-05-19 | 2021-11-25 | Carl Zeiss Vision International Gmbh | Spectacle lens with antifogging properties |
-
2018
- 2018-09-05 CN CN201821462781.6U patent/CN208721921U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021232218A1 (en) * | 2020-05-19 | 2021-11-25 | Carl Zeiss Vision International Gmbh | Spectacle lens with antifogging properties |
| CN112195439A (en) * | 2020-09-16 | 2021-01-08 | 贵州省装备制造业协会 | Forming process of antifogging film of antifogging goggles lens |
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| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190409 Termination date: 20200905 |
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| CF01 | Termination of patent right due to non-payment of annual fee |