CN205991701U - A kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide - Google Patents
A kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide Download PDFInfo
- Publication number
- CN205991701U CN205991701U CN201620922869.6U CN201620922869U CN205991701U CN 205991701 U CN205991701 U CN 205991701U CN 201620922869 U CN201620922869 U CN 201620922869U CN 205991701 U CN205991701 U CN 205991701U
- Authority
- CN
- China
- Prior art keywords
- atmosphere
- cobalto
- pure phase
- cobaltic oxide
- conveyer device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(2+);cobalt(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000005118 spray pyrolysis Methods 0.000 title claims abstract description 19
- 239000007789 gas Substances 0.000 claims abstract description 43
- 238000002156 mixing Methods 0.000 claims abstract description 31
- 239000007921 spray Substances 0.000 claims abstract description 29
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000001301 oxygen Substances 0.000 claims abstract description 26
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 26
- 238000002485 combustion reaction Methods 0.000 claims abstract description 17
- -1 body of heater Chemical compound 0.000 claims abstract description 3
- 238000000197 pyrolysis Methods 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 abstract description 11
- 239000010941 cobalt Substances 0.000 abstract description 11
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 11
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000000889 atomisation Methods 0.000 description 2
- 150000001868 cobalt Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000009275 open burning Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
This utility model discloses a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide, including body of heater, spray gun, burner, one branch is connect on spray gun, branch sets first gas mixing match instrument, spray gun gas regulation conveyer device, first gas mixing match instrument mixing compressed air and oxygen；Burner additional combustion air atmosphere adjustment device；High temperature combustion zone below burner is provided with burning zone atmosphere and adjusts conveyer device, and burning zone atmosphere adjusts conveyer device and connects second gas mixing match instrument, second gas mixing match instrument mixing compressed air and oxygen；In furnace bottom conveyance conduit position increase transportation section atmosphere adjustment device.Beneficial effect：Atmosphere is controlled using multistage, is adjusted by different section atmosphere, play the effect adjusting furnace atmosphere, ensure the abundant reaction of material in stove in time, prevent burning.The regulation simple and easy to control of this equipment, output Cobalto-cobaltic oxide is pure phase, without cobalt protoxide phase.
Description
Technical field
This utility model is related to prepare the technical field of Cobalto-cobaltic oxide, particularly a kind of pure phase Cobalto-cobaltic oxide of preparing
Spray pyrolysis stove.
Background technology
Cobalto-cobaltic oxide is one of main precursor of current battery positive electrode, is widely used in mobile phone, notebook, fills
The preparation of the secondary cell of the equipment such as electric treasured.In commercial production, conventional wet chemistry synthetic method prepares Cobalto-cobaltic oxide at present,
It is also adopted by individually spray pyrolysis method.
Produce in preparation process in spray pyrolysis, it is a common problem that, prepared Cobalto-cobaltic oxide（Co3O4）Contain
There is 1%～10% about cobalt protoxide（CoO）.The presence of cobalt protoxide is for prepared cell positive material chemical property
And its all there is considerable influence in preparation technology.
Utility model content
The problem existing for above-mentioned existing spray pyrolysis process units, this utility model provides a kind of adjustment, controls oxygen
The spray pyrolysis stove of content.
The technical solution of the utility model is：A kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide, including body of heater, spray
Rifle, burner, meet a branch on spray gun, and branch sets first gas mixing match instrument, spray gun gas regulation conveyer device, and first
Gas proportion mixing instrument mixing compressed air and oxygen；Burner additional combustion air atmosphere adjustment device；High temperature below burner
Combustion zone is provided with burning zone atmosphere and adjusts conveyer device, and burning zone atmosphere adjusts conveyer device and connects second gas mixing match
Instrument, second gas mixing match instrument mixing compressed air and oxygen；Adjust in furnace bottom conveyance conduit position increase transportation section atmosphere
Device.
Described spray gun gas regulation conveyer device, combustion air atmosphere adjustment device, burning zone atmosphere adjust conveyer device,
The gas oxygen molar content of transportation section atmosphere adjustment device output is 22%～80%.
The gas flow rate that described burning zone atmosphere adjusts conveyer device is 5～50m/h.
The oxygen flow of described transportation section atmosphere adjustment device is 1m/h～50 m/h.
It is in 10～60 ° of angles that described burning zone atmosphere adjusts conveyer device with pyrolysis oven horizontal line.
Described body of heater is tubular structure.
Described spray gun spout is distributed in furnace interior top, has multiple spouts.
Described burner has multiple, is distributed on burning zone, circumferentially arranges.
The beneficial effects of the utility model are：Atmosphere is controlled using multistage.Gathered pyrolysis oven, gas proportion mixing instrument,
Spray gun gas regulation conveyer device, burning zone atmosphere adjust conveyer device, combustion air atmosphere adjustment device, transportation section atmosphere tune
Regulating device.Adjusted by above-mentioned difference section atmosphere, play the effect adjusting furnace atmosphere it is important to play thing in timely guarantee stove
The abundant reaction expected, the effect preventing burning.This utility model equipment regulation simple and easy to control, and practical function is substantially, output
Cobalto-cobaltic oxide is pure phase, without cobalt protoxide phase.
Brief description
Fig. 1 is structural representation of the present utility model；
Labelling in Fig. 1：1 is body of heater；2 is first gas mixing match instrument；3 is spray gun gas regulation conveyer device；4 is spray
Rifle；5 is combustion air atmosphere adjustment device；6 is burner；7 is second gas mixing match instrument；8 is defeated for the regulation of burning zone atmosphere
Send device；9 is transportation section atmosphere adjustment device.
Specific embodiment
As shown in figure 1, a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide, including the body of heater 1 of tubular structure, spray gun
4th, burner 6, meet a branch on spray gun 4, and branch sets first gas mixing match instrument 2, spray gun gas regulation conveyer device 3,
First gas mixing match instrument 2 mixing compressed air and oxygen；The additional combustion air atmosphere adjustment device 5 of burner 6；Under burner 6
The high temperature combustion zone of side is provided with burning zone atmosphere and adjusts conveyer device 8, and burning zone atmosphere adjusts conveyer device 8 and connects second gas
Mixing match instrument 7, second gas mixing match instrument 7 mixing compressed air and oxygen；Increase conveying in furnace bottom conveyance conduit position
Section atmosphere adjustment device 9.It is in 10～60 ° of angles that described burning zone atmosphere adjusts conveyer device 8 with pyrolysis oven horizontal line.
Spray gun 4 spout is distributed in body of heater 1 inside top, has multiple spouts.Burner 6 has multiple, is distributed on burning zone, in circle
Week arrangement.The particular number of spray gun 4 spout and burner 6 depending on body of heater 1 internal volume it is ensured that the inside effectively utilizes of body of heater,
Guarantee the abundant pyrolysis of cobalt salt again.
Compressed air is mixed so that oxygen mole content is in mixed gas through first gas mixing match instrument 2 with oxygen
22%～80%, enter spray gun 4 after spray gun gas regulation conveyer device 3.It is laggard that mixed gas contact atomization with cobalt salt solution
Enter in body of heater 1.Adjust combustion air atmosphere adjustment device 5 so that combustion air flow simultaneously：Oxygen flow is than for 5:1, highest
Less than 1:2, Main Function is partial pressure of oxygen in regulating stove.Additionally, compressed air and oxygen are through second gas mixing match instrument
7 open burning zone atmosphere adjusts conveyer device 8, and adjustment oxygen mole content is 22%～80%, and gas flow rate is 5～50m/h,
The burning of material can be prevented.Open transportation section atmosphere adjustment device 9, described oxygen flow is 1m/h～50 m/h, further
Ensure the abundant of reaction and eliminate cobalt protoxide phase.
The utility model proposes increasing oxygen content in spray gun.Conventional spray gun is in atomization course of reaction due to reaction
Diffusion time is not enough, leads to next secondary response of normoxic condition incomplete.Therefore, by first gas mixing match instrument 2
Supplemental oxygen, then enter spray gun 4 after spray gun gas regulation conveyer device 3 is adjusted so that pyrolytic reaction is more abundant.
This utility model adjusts in combustion air oxygen content so that combustion-supporting sky also by combustion air atmosphere adjustment device 5
Throughput：Oxygen flow, than increasing, increases entirety oxygen content in stove, promotes reaction further so that reaction completely, limits meanwhile
The generation of oxygenerating Asia cobalt.
In actual production process, it is frequently present of the cobalt protoxide due to producing in residing time in furnace length.For this reason, this
Utility model provides burning zone atmosphere and adjusts conveyer device 8, the product that purging high temperature section easy-sintering stops in time, and has been produced
Raw cobalt protoxide eliminates.
This utility model also in furnace bottom conveyance conduit position increase transportation section atmosphere adjustment device 9, is carried out to furnace bottom blanking
Oxygen-enriched protection again, eliminates the sub- on a small quantity cobalt phase that furnace burdening burning brings, has fundamentally prevented the generation of cobalt protoxide.
Above-mentioned spray gun gas regulation conveyer device 3, combustion air atmosphere adjustment device 5, burning zone atmosphere adjust conveying
Device 8, transportation section atmosphere adjustment device 9, what basic structure was gas flow adjusting means and pressure-regulating device combines knot
Structure, for the gas pressure needed for proportioning relevant device and Flow-rate adjustment, plays the mixing supplying rated condition by design condition
The effect of gas.
This utility model is by the analysis of the thermodynamic model of Cobalto-cobaltic oxide thermal decomposition process and production application, real
Apply the equipment design in spray gun, furnace atmosphere, high temperature section, furnace bottom section key position, efficiently solve existing Cobalto-cobaltic oxide
It is also easy to produce the problem of cobalt protoxide in production process under the conditions of spray pyrolysis process.
Claims (8)
1. a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide, including body of heater（1）, spray gun（4）, burner（6）, its feature
It is：In spray gun（4）On meet a branch, branch sets first gas mixing match instrument（2）, spray gun gas regulation conveyer device（3）,
First gas mixing match instrument（2）Mixing compressed air and oxygen；Burner（6）Add combustion air atmosphere adjustment device（5）；Burn
Mouth（6）The high temperature combustion zone of lower section is provided with burning zone atmosphere and adjusts conveyer device（8）, burning zone atmosphere regulation conveyer device（8）
Connect second gas mixing match instrument（7）, second gas mixing match instrument（7）Mixing compressed air and oxygen；In furnace bottom conveying
Pipeline location increases transportation section atmosphere adjustment device（9）.
2. a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide according to claim 1, is characterized in that：Spray gun gas
Adjust conveyer device（3）, combustion air atmosphere adjustment device（5）, burning zone atmosphere adjust conveyer device（8）, transportation section atmosphere
Adjusting means（9）The gas oxygen molar content of output is 22%～80%.
3. a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide according to claim 1, is characterized in that：Described burning
Section atmosphere adjusts conveyer device（8）Gas flow rate be 5～50m/h.
4. a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide according to claim 1, is characterized in that：Described conveying
Section atmosphere adjustment device（9）Oxygen flow be 1m/h～50 m/h.
5. a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide according to claim 1, is characterized in that：Described burning
Section atmosphere adjusts conveyer device（8）It is in 10～60 ° of angles with pyrolysis oven horizontal line.
6. a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide according to claim 1, is characterized in that：Described body of heater
（1）For tubular structure.
7. a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide according to claim 1, is characterized in that：Described spray gun
（4）Spout is distributed in body of heater（1）Inside top, has multiple spouts.
8. a kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide according to claim 1, is characterized in that：Described burner
（6）Have multiple, be distributed on burning zone, circumferentially arrange.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620922869.6U CN205991701U (en) | 2016-08-23 | 2016-08-23 | A kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620922869.6U CN205991701U (en) | 2016-08-23 | 2016-08-23 | A kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN205991701U true CN205991701U (en) | 2017-03-01 |
Family
ID=58107085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201620922869.6U Expired - Fee Related CN205991701U (en) | 2016-08-23 | 2016-08-23 | A kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN205991701U (en) |
-
2016
- 2016-08-23 CN CN201620922869.6U patent/CN205991701U/en not_active Expired - Fee Related
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101338910B (en) | Oxygen-enriched and all-oxygen combustion roller kiln combustion control method | |
| CN201416899Y (en) | Solid fuel supply device of non-metal industrial furnace | |
| CN202447776U (en) | Mesh belt type protective atmosphere brazing furnace | |
| CN103299131A (en) | Combustion detoxifying device | |
| CN102174336A (en) | Hearth temperature control device and control method for multi-nozzle opposed coal water slurry gasification furnace | |
| CN201875734U (en) | Combustion supporting air heating and energy-saving device and ceramic firing kiln | |
| CN103072960B (en) | Production method of nano silicon nitride powder | |
| CN102923711A (en) | Automatic control starting method of polycrystalline silicon reduction furnace | |
| CN109319787B (en) | Reduction device and process for efficiently producing polycrystalline silicon | |
| CN102520736B (en) | Load control method of coal nozzles of dry pulverized coal gasification furnace | |
| CN205991701U (en) | A kind of spray pyrolysis stove preparing pure phase Cobalto-cobaltic oxide | |
| CN106197025B (en) | A kind of spray pyrolysis stove for preparing pure phase cobaltosic oxide | |
| CN115650612A (en) | Cement kiln system adopting hydrogen energy coupling to replace fuel and operation method thereof | |
| CN203307054U (en) | Device for producing calcium carbides by adopting oxygen heat method | |
| CN204593438U (en) | A kind of oxygenation pre-mixing apparatus of ceramic oxygen-enriched combustion technology | |
| CN106591526A (en) | Flow-free combustion control system for blast furnace hot blast stove | |
| CN109539812A (en) | A kind of sleeve kiln intelligent gas controlling device and control method | |
| CN101307259A (en) | Gas producing device and method | |
| CN202072492U (en) | Flameless chemical-looping combustion oxidation furnace | |
| CN203927980U (en) | A kind of carbon baking furnace petroleum coke combustion device | |
| CN203530395U (en) | Flame combustion device for purple impure copper smelting furnace | |
| CN203794848U (en) | Saturation temperature regulating device of gas producer | |
| CN103423589B (en) | Liquid oxygen vaporizing system for technology of preparing methanol with coke oven gas and technology | |
| CN206269137U (en) | A kind of self carburization burner | |
| CN218579657U (en) | Production device of N2 and CO2 mixed gas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170301 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |