CN204769857U - Get rid of drip washing device of soil heavy metal - Google Patents
Get rid of drip washing device of soil heavy metal Download PDFInfo
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Abstract
Description
技术领域technical field
本实用新型涉及工业固体废物重金属污染治理领域,具体是去除土壤重金属的淋洗装置。The utility model relates to the field of industrial solid waste heavy metal pollution control, in particular to a leaching device for removing heavy metals from soil.
背景技术Background technique
土壤重金属淋洗技术根据修复原理不同可分类为:原位化学淋洗、异位化学淋洗。在实地场地修复过程中,土壤淋洗就是利用淋洗剂将吸附在土壤上的重金属转移至液相,再收集废液进行处理。化学淋洗对于小面积的重污染土壤修复效果较好。Soil heavy metal leaching technology can be classified according to different remediation principles: in-situ chemical leaching and ex-situ chemical leaching. In the field restoration process, soil leaching is to use leaching agent to transfer the heavy metals adsorbed on the soil to the liquid phase, and then collect the waste liquid for treatment. Chemical leaching is more effective for remediation of small areas of heavily polluted soil.
原位淋洗技术适用于透水性较强的砂性土壤中,且污染物分层应位于不透水层之上,保证淋洗液不会污染地下水。然后将淋洗液从收集井中用泵抽出,淋洗液经收集,进行重金属的去除及淋洗液的回收利用。该技术成本较低,工艺简单,但修复效率低,并且容易对地下水造成污染,也不适宜应用在溶洞地区。In-situ leaching technology is suitable for sandy soil with strong water permeability, and the pollutant layer should be located above the impermeable layer to ensure that the eluent will not pollute the groundwater. Then the eluent is pumped out from the collection well, and the eluent is collected for the removal of heavy metals and the recycling of the eluate. This technology has low cost and simple process, but the repair efficiency is low, and it is easy to cause pollution to groundwater, and it is not suitable for application in karst cave areas.
土壤异位化学淋洗需经挖掘、迁移等步骤,再集中到淋洗装置集中进行处理。淋洗液中的污染物需进行无害化处理,处理后的土壤要进行回填工作。异位淋洗技术包括土柱淋洗法、振荡淋洗法、搅拌淋洗法。土柱淋洗法主要通过土壤柱淋洗的形式去除污染土壤中的重金属,异位淋洗技术不会污染地下水,搅拌淋洗是使淋洗液与土壤在振荡或搅拌反应器中长时间充分混合,去除淋洗液中的重金属,这种技术修复效率较高,二次污染风险小,但成本也较高。Soil ectopic chemical leaching needs to go through steps such as excavation and migration, and then be concentrated in the leaching device for centralized treatment. The pollutants in the eluent need to be harmlessly treated, and the treated soil needs to be backfilled. Ectopic leaching techniques include soil column leaching, oscillation leaching, and stirring leaching. The soil column leaching method mainly removes heavy metals in polluted soil through soil column leaching. The ectopic leaching technology will not pollute the groundwater. The agitation leaching is to make the eluent and the soil fully in the shaking or stirring reactor for a long time. Mixing to remove heavy metals in the eluent, this technology has high repair efficiency and low risk of secondary pollution, but the cost is also high.
目前还没有见可自助调节淋洗条件、提高重金属去除率、解决淋洗液回收及处理问题的去除土壤重金属锌的淋洗装置的相关报导。At present, there are no relevant reports on a leaching device for removing heavy metal zinc from soil that can self-adjust the leaching conditions, improve the removal rate of heavy metals, and solve the problems of eluent recovery and treatment.
实用新型内容Utility model content
本实用新型所要解决的技术问题是提供一种新的去除土壤重金属的淋洗装置,该装置能够有效去除污染土壤中重金属,并可自助调节淋洗条件处理污染土壤,提高重金属去除率,同时解决了淋洗液回收及处理问题,并且保留土壤肥力。The technical problem to be solved by this utility model is to provide a new leaching device for removing heavy metals from soil, which can effectively remove heavy metals in polluted soil, and can self-adjust leaching conditions to treat polluted soil, improve the removal rate of heavy metals, and solve the problem of The problem of eluent recovery and disposal is solved, and soil fertility is preserved.
本实用新型以如下技术方案解决上述技术问题:The utility model solves the above technical problems with the following technical solutions:
本实用新型去除土壤重金属的淋洗装置,它包括土壤破碎筛分设备、多级筛分设备、搅拌淋洗设备、泥浆缓冲池、淋洗液储槽,土壤破碎筛分设备的出口端接多级筛分设备的入口端,多级筛分设备的出口端和淋洗液储槽的输出端接入搅拌淋洗设备的入口,搅拌淋洗设备的出口连接泥浆缓冲池,泥浆缓冲池的泥浆出口经渣浆泵与板框压滤机连接,泥浆缓冲池的上清液出口与淋洗液净化设备的入口端连接,淋洗液净化设备的出口端经蠕动泵与淋洗液储槽连接。所述淋洗液储槽的进口端并联连接酸液添加设备。The utility model is a leaching device for removing heavy metals in soil, which includes soil crushing and screening equipment, multi-stage screening equipment, stirring and rinsing equipment, mud buffer pool, leaching liquid storage tank, and the outlet terminal of the soil crushing and screening equipment is multi-connected. The inlet of the multi-stage screening equipment, the outlet of the multi-stage screening equipment and the output of the eluent storage tank are connected to the inlet of the stirring and washing equipment, and the outlet of the stirring and washing equipment is connected to the mud buffer tank, and the mud in the mud buffer tank The outlet is connected to the plate and frame filter press through the slurry pump, the supernatant outlet of the mud buffer tank is connected to the inlet of the eluent purification equipment, and the outlet of the eluent purification equipment is connected to the eluent storage tank through a peristaltic pump . The inlet end of the eluent storage tank is connected in parallel with acid solution adding equipment.
所述多级筛分设备包括上下排列的第一级筛网和第二级筛网,第一级筛网小于土壤破碎筛分设备的筛网孔隙,并大于第二级筛网孔隙。The multi-stage screening equipment includes a first-stage screen and a second-stage screen arranged up and down. The first-stage screen is smaller than the screen aperture of the soil crushing and screening equipment and larger than the second-stage screen aperture.
所述土壤破碎筛分设备的筛网孔隙为5-15mm,多级筛分设备的第一级筛网孔隙为2mm-4mm,第二级筛网孔隙为0.5mm-0.8mm。The screen mesh aperture of the soil crushing and screening equipment is 5-15mm, the first-stage screen mesh aperture of the multi-stage screening equipment is 2mm-4mm, and the second-stage screen mesh aperture is 0.5mm-0.8mm.
所述淋洗液净化设备的入口端并联连接板框压滤机的出水口。The inlet end of the eluent purification equipment is connected in parallel with the water outlet of the plate and frame filter press.
所述搅拌淋洗设备的进料通过计量泵控制。The feeding of the stirring and washing equipment is controlled by a metering pump.
本实用新型装置能够有效去除污染土壤中重金属锌,并可自助调节淋洗条件处理污染土壤,提高重金属去除率,处理后土壤可以继续作为农用或商用土地,做到无害化处理,同时解决了淋洗液回收及处理问题。The utility model device can effectively remove the heavy metal zinc in the polluted soil, and can self-adjust the leaching conditions to treat the polluted soil, improve the removal rate of the heavy metal, and the treated soil can continue to be used as agricultural or commercial land to achieve harmless treatment, and at the same time solve the problem of Eluent recovery and disposal issues.
附图说明Description of drawings
图1是本实用新型去除土壤重金属的淋洗装置的结构示意图。Fig. 1 is the structure schematic diagram of the rinsing device of the utility model for removing soil heavy metals.
图中:土壤破碎筛分设备1,多级筛分设备2,第一级筛网2-1,第二级筛网2-2,搅拌淋洗设备3,搅拌电机3-1,搅拌桨3-2,泥浆缓冲池4,板框压滤机5,淋洗液储槽6,淋洗液净化设备7,Na2S净化7-1,活性炭净化7-2,计量泵8,蠕动泵9,酸液添加设备10,渣浆泵11。In the figure: soil crushing and screening equipment 1, multi-stage screening equipment 2, first-level screen 2-1, second-level screen 2-2, stirring and washing equipment 3, stirring motor 3-1, stirring paddle 3 -2, mud buffer tank 4, plate and frame filter press 5, eluent storage tank 6, eluent purification equipment 7, Na 2 S purification 7-1, activated carbon purification 7-2, metering pump 8, peristaltic pump 9 , acid liquid adding equipment 10, slurry pump 11.
具体实施方式Detailed ways
如图1所示,本实用新型装置由土壤破碎筛分设备1、多级筛分设备2、搅拌淋洗设备3、泥浆缓冲池4、板框压滤机5、淋洗液储槽6、淋洗液净化设备7、计量泵8、蠕动泵9、酸液添加设备10和渣浆泵11等部件构成,其中土壤破碎筛分设备1采用锤石破碎筛分机,多级筛分设备2设有上下排列的第一级筛网2-1和第二级筛网2-2,第一级筛网2-1的孔隙要大于第二级筛网2-2的孔隙,并且小于土壤破碎筛分设备1的孔隙。土壤破碎筛分设备1的筛网孔隙要求在5-15mm,多级筛分设备的第一级筛网孔隙要求在2mm-4mm(5-10目,第二级筛网孔隙要求在0.5mm-0.8mm(20-35目)。As shown in Figure 1, the utility model device consists of soil crushing and screening equipment 1, multi-stage screening equipment 2, stirring and washing equipment 3, mud buffer tank 4, plate and frame filter press 5, eluent storage tank 6, The eluent purification equipment 7, the metering pump 8, the peristaltic pump 9, the acid liquid addition equipment 10 and the slurry pump 11 are composed of components, among which the soil crushing and screening equipment 1 adopts a hammerstone crushing and screening machine, and the multi-stage screening equipment 2 is equipped with There are a first-stage screen 2-1 and a second-stage screen 2-2 arranged up and down, the pores of the first-stage screen 2-1 are larger than the pores of the second-stage screen 2-2, and smaller than the soil crushing screen Sub-device 1 porosity. The pore size of the screen for soil crushing and screening equipment 1 is required to be 5-15mm, the pore size of the first-stage screen for multi-stage screening equipment is required to be 2mm-4mm (5-10 mesh, the pore size of the second-stage screen is required to be 0.5mm- 0.8mm (20-35 mesh).
本实例中的土壤破碎筛分设备1的孔隙为10mm,多级筛分设备中第一级筛网2-1的孔隙为8目(2.4mm),第二级筛网的孔隙为20目(0.8mm)。The porosity of the soil crushing and screening equipment 1 in this example is 10mm, and the porosity of the first-stage screen cloth 2-1 is 8 orders (2.4mm) in the multistage screening equipment, and the porosity of the second-stage screen cloth is 20 orders ( 0.8mm).
本实用新型各部件的连接结构见图1所示,土壤破碎筛分设备1的出口端接多级筛分设备2的入口端,多级筛分设备2的出口端和淋洗液储槽6的输出端接入搅拌淋洗设备3的入口,搅拌淋洗设备3的物料进入通过计量泵8控制,搅拌淋洗设备3中通过搅拌电机3-1带动搅拌桨3-2转动混合物料,搅拌淋洗设备3的出口连接泥浆缓冲池4,泥浆缓冲池4的泥浆出口经渣浆泵11与板框压滤机5连接,泥浆缓冲池4的上清液出口与淋洗液净化设备7的入口端连接,淋洗液净化设备7的出口端经蠕动泵9与淋洗液储槽6连接,淋洗液储槽6的进口端并联连接酸液添加设备10;淋洗液净化设备7的入口端并联连接板框压滤机5的出水口。The connection structure of each part of the utility model is shown in Figure 1, the outlet end of the soil crushing and screening equipment 1 is connected to the inlet end of the multi-stage screening equipment 2, the outlet end of the multi-stage screening equipment 2 and the eluent storage tank 6 The output end of the mixer is connected to the entrance of the stirring and washing equipment 3, and the material entering of the stirring and washing equipment 3 is controlled by the metering pump 8. In the stirring and washing equipment 3, the stirring motor 3-1 drives the stirring paddle 3-2 to rotate the mixed material, stirring The outlet of the washing equipment 3 is connected to the mud buffer tank 4, the mud outlet of the mud buffer tank 4 is connected to the plate and frame filter press 5 through the slurry pump 11, and the supernatant liquid outlet of the mud buffer tank 4 is connected to the eluent purification device 7. The inlet end is connected, and the outlet end of the eluent purification equipment 7 is connected to the eluent storage tank 6 through a peristaltic pump 9, and the inlet end of the eluent storage tank 6 is connected in parallel with the acid solution addition device 10; the eluent purification equipment 7 The inlet end is connected in parallel with the water outlet of the plate and frame filter press 5 .
所述土壤破碎筛分设备1的主要功能是对污染土壤进行破碎处理,在破碎过程中,使得物料均匀的进入搅拌式淋洗设备中,减少在搅拌过程中因物料粒度不均而造成机械故障。The main function of the soil crushing and screening equipment 1 is to crush the contaminated soil. During the crushing process, the materials can be uniformly entered into the stirring type washing equipment, so as to reduce the mechanical failure caused by the uneven particle size of the materials during the stirring process. .
使用本实用新型装置时,将制备好的淋洗液加入淋洗液储槽6内,顺流进入搅拌淋洗设备3中。淋洗搅拌设备3呈圆形,淋洗液和污染土壤在搅拌设备内进行充分泥水混合。物料经过计量泵8可控制水土比例,淋洗搅拌设备下端设有蝶阀控制污泥进入泥浆缓冲池4。在计量泵8的可调控下,进入淋洗设备中的物料质量可做到科学化控制,保证水土比例。When using the device of the utility model, the prepared eluent is added into the eluent storage tank 6 and enters the stirring and eluting equipment 3 downstream. The rinsing mixing device 3 is circular, and the washing liquid and the polluted soil are fully mixed with mud and water in the mixing device. The proportion of water and soil can be controlled by the material passing through the metering pump 8, and a butterfly valve is installed at the lower end of the washing and stirring equipment to control the sludge entering the mud buffer tank 4. Under the control of the metering pump 8, the quality of the materials entering the rinsing equipment can be scientifically controlled to ensure the ratio of water to soil.
所述淋洗缓冲池4的主要功能为初步对泥水进行初步分离,当淋洗设备下方蝶阀打开后,泥浆进入淋洗缓冲池4内,并在其下端由渣浆泵11送入板框压滤机5进行泥水分离,而上层上清液则进入淋洗液净化设备7中。The main function of the washing buffer pool 4 is to initially separate the mud and water. When the butterfly valve under the washing equipment is opened, the mud enters the washing buffer pool 4 and is sent into the plate and frame pressure by the slurry pump 11 at its lower end. The filter 5 separates the mud and water, and the supernatant in the upper layer enters the eluent purification equipment 7 .
所述淋洗液净化设备7由Na2S净化装置7-1和活性炭净化装置7-2串接连接构成,淋洗液净化设备7的主要功能为储存回收泥水分离后的淋洗液,并且连接淋洗液缓冲池4,对淋洗液进行回收,并进入淋洗液净化设备进行净化、再生,最终重新进入淋洗液储槽6内。The eluate purification equipment 7 is composed of a Na 2 S purification device 7-1 and an activated carbon purification device 7-2 connected in series, and the main function of the eluent purification equipment 7 is to store and recover the eluent after the mud-water separation, and Connect to the eluent buffer tank 4, recover the eluent, and enter the eluent purification equipment for purification and regeneration, and finally re-enter the eluent storage tank 6.
本实用新型采用的泥浆缓冲池4直径为2.5m,高4m。缓冲池中端设有一个带阀门的管道与淋洗液净化设备7连接,底部由渣浆泵11连接与板框压滤机5的进水口。The mud buffer tank 4 that the utility model adopts has a diameter of 2.5m and a height of 4m. A pipeline with a valve is provided at the middle end of the buffer pool to connect with the eluent purification equipment 7, and the bottom is connected with the water inlet of the plate and frame filter press 5 by a slurry pump 11.
板框压滤机5主要功能为对泥浆缓冲池端口的泥浆进行水土分离,在板框压滤机中,泥水由供料泵以一定压力从尾板进料孔给料。借助供料泵提供的压力在过滤介质两侧形成的压力差,实现固液分离,将污泥脱水至含水率约20%,并得到干净土壤的滤饼。The main function of the plate and frame filter press 5 is to separate water and soil from the mud at the port of the mud buffer tank. In the plate and frame filter press, the mud water is fed from the feed hole of the tail plate by the feed pump at a certain pressure. With the help of the pressure provided by the feed pump, the pressure difference formed on both sides of the filter medium realizes solid-liquid separation, dewaters the sludge to a moisture content of about 20%, and obtains a filter cake of clean soil.
本实用新型装置在进料筛分过程中,小于分级振动筛孔隙的土壤进入淋洗设备内,经淋洗过后干净土壤经脱水后回填或他用,而淋洗液则进入净化设备回收再利用,从而完成污染土壤的治理。In the feed screening process of the device of the utility model, the soil smaller than the pores of the graded vibrating screen enters the leaching equipment, and after leaching, the clean soil is dehydrated and backfilled or used for other purposes, while the leaching liquid enters the purification equipment for recycling and reuse. , so as to complete the treatment of polluted soil.
本实用新型装置可适当调整搅拌时间、搅拌速度、水土比例及土壤粒径选择等主要参数,在实际操作过程中有利于针对不同性质土壤进行最优化的淋洗处理。The device of the utility model can properly adjust main parameters such as stirring time, stirring speed, water-soil ratio and soil particle size selection, and is beneficial to optimize leaching treatment for soils with different properties during the actual operation process.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105964670A (en) * | 2016-07-05 | 2016-09-28 | 湖南艾布鲁环保科技有限公司 | Device and method for recycling ex-site chemical elution-remediating eluate for heavy metal contaminated soil |
| CN106269834A (en) * | 2016-10-26 | 2017-01-04 | 南通科技职业学院 | Heavy-metal contaminated soil prosthetic device and restorative procedure thereof |
| CN107774706A (en) * | 2017-11-16 | 2018-03-09 | 安徽金联地矿科技有限公司 | A kind of mining soil prosthetic device and its restorative procedure based on chemical leaching |
| CN108672483A (en) * | 2018-04-23 | 2018-10-19 | 天津大学 | The integrated restorative procedure of fluid conveying reaction and system of organo-mineral complexing contaminated soil |
-
2015
- 2015-06-12 CN CN201520409289.2U patent/CN204769857U/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105964670A (en) * | 2016-07-05 | 2016-09-28 | 湖南艾布鲁环保科技有限公司 | Device and method for recycling ex-site chemical elution-remediating eluate for heavy metal contaminated soil |
| CN106269834A (en) * | 2016-10-26 | 2017-01-04 | 南通科技职业学院 | Heavy-metal contaminated soil prosthetic device and restorative procedure thereof |
| CN106269834B (en) * | 2016-10-26 | 2019-03-26 | 南通科技职业学院 | Heavy-metal contaminated soil prosthetic device and its restorative procedure |
| CN107774706A (en) * | 2017-11-16 | 2018-03-09 | 安徽金联地矿科技有限公司 | A kind of mining soil prosthetic device and its restorative procedure based on chemical leaching |
| CN108672483A (en) * | 2018-04-23 | 2018-10-19 | 天津大学 | The integrated restorative procedure of fluid conveying reaction and system of organo-mineral complexing contaminated soil |
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