CN1919799A - Natural biological solubility calcium product, preparation method and use - Google Patents
Natural biological solubility calcium product, preparation method and use Download PDFInfo
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- CN1919799A CN1919799A CN 200510047089 CN200510047089A CN1919799A CN 1919799 A CN1919799 A CN 1919799A CN 200510047089 CN200510047089 CN 200510047089 CN 200510047089 A CN200510047089 A CN 200510047089A CN 1919799 A CN1919799 A CN 1919799A
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- solubility calcium
- marine organisms
- hydrochloric acid
- housing
- calcium
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- 239000011575 calcium Substances 0.000 title claims abstract description 79
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title description 2
- 239000003337 fertilizer Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000001413 amino acids Chemical class 0.000 claims abstract description 9
- 238000005507 spraying Methods 0.000 claims abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 56
- 239000000047 product Substances 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000009835 boiling Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000000354 decomposition reaction Methods 0.000 claims description 7
- 238000005194 fractionation Methods 0.000 claims description 7
- 239000006210 lotion Substances 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 7
- 238000010790 dilution Methods 0.000 claims description 6
- 239000012895 dilution Substances 0.000 claims description 6
- 238000000746 purification Methods 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
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- 238000004519 manufacturing process Methods 0.000 abstract description 8
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- 229940087458 alcaine Drugs 0.000 abstract 2
- 102000011782 Keratins Human genes 0.000 abstract 1
- 108010076876 Keratins Proteins 0.000 abstract 1
- 230000001680 brushing effect Effects 0.000 abstract 1
- 239000013522 chelant Substances 0.000 abstract 1
- 238000007865 diluting Methods 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 15
- 239000012535 impurity Substances 0.000 description 12
- 239000012141 concentrate Substances 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 241000237502 Ostreidae Species 0.000 description 6
- 230000008030 elimination Effects 0.000 description 6
- 238000003379 elimination reaction Methods 0.000 description 6
- 235000020636 oyster Nutrition 0.000 description 6
- 230000000740 bleeding effect Effects 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- MBLBDJOUHNCFQT-LXGUWJNJSA-N aldehydo-N-acetyl-D-glucosamine Chemical compound CC(=O)N[C@@H](C=O)[C@@H](O)[C@H](O)[C@H](O)CO MBLBDJOUHNCFQT-LXGUWJNJSA-N 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical group [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011573 trace mineral Substances 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
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- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
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- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
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- 150000003839 salts Chemical class 0.000 description 2
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- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 206010006956 Calcium deficiency Diseases 0.000 description 1
- 229910017518 Cu Zn Inorganic materials 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
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- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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Abstract
The invention discloses a soluble calcium product and manufacturing method, which comprises the following steps: purifying marine biological case; grinding; decomposing through alcaine; diluting through water; separating alcaine under high temperature; purifying; condensing; extracting organic soluble calcium, multiple microelements, keratin and chitin; adding plant surface activity reinforcer directly according to utility; spraying or brushing on the plant; fitting for chelate fertilizer with amino acid and or other middle microelement.
Description
Technical field: the present invention discloses a kind of marine organisms housing and produces and mainly contain solubility calcium product and production method and purposes, and the marine organisms housing that relates to utilization is produced the solubility calcium liquid fertilizer.
Background technology: along with Agricultural Development, growth in the living standard, social economy move towards internationalization, millions upon millions of peasants be badly in need of changing single pursuit volume increase the old customs idea, produce wholesome green organic products, just can go to the world, move towards fairly comfortable life.Numerous for this reason scientific workers are that the fundamental interests of agricultural is set out, and what research old customs idea caused hardens with the improper soil acidity of chemical fertilizer, are harmful to the transformation of the agricultural-food inferior of health of human body with improper residual exceed standard etc. of agricultural chemicals.
A lot of scientific research personnel have confirmed that calcium is the plant essential element, and calcium to supply with human body by plant materials (produce calcium content high melon and fruit vegetables) be the mankind's optimal approach of replenishing the calcium, calcium is again promoting agent, can regulate plant materials desired nutritional some element that can also neutralize simultaneously and reach detoxification, be to improve the agricultural byproducts quality improvers.Marine organisms shell (oyster shells, shell, shrimp shell, crab shell) contains organic calcium, contains in magnesium, manganese, iron, copper, zinc, boron, the molybdenum etc. outside the trace element, also contains distinctive keratoprotein and chitin, and plant absorbing is fast, effect is remarkable.But existing some areas utilize marine organisms housing such as oyster shells to produce calcium, all be to carry out roast after oyster is cleaned to be ground into Powdered, most of organic calcium, keratoprotein, chitin have all lost, the calcium major part of Xing Chenging is an inorganic oxide calcium like this, be not easy to use, improper use is prone to negative interaction.Also have plenty of and will carry out seasoning after the cleaning of marine organisms shell, be ground into Powdered, such organic calcium tissue and decompose slowly, the plant absorbing rate is very low, and occurs salt damage easily, is unfavorable for plant-growth.
Summary of the invention:
Purpose of the present invention will solve how effectively extract organic calcium, various trace elements, keratoprotein, chitin etc. in the marine organisms housing exactly, they dissociate out and form solubility to make him, be convenient to utilize, thereby provide a kind of marine organisms housing to produce method and the goods that mainly contain materials such as solubility calcium, provide a kind of especially and produce fertilizer goods and preparation method and purposes based on solubility calcium with the marine organisms housing.
The present invention produces the method for solubility calcium product with the marine organisms housing, may further comprise the steps and finish: marine organisms housing (oyster shells, shell, shrimp shell, crab shell etc.) is purified, pulverizes, it is characterized in that: pulverize the back and decompose with hydrochloric acid, thin up (can decide as the case may be by amount of water, as long as reach the Chengdu of dilution), heat the fractionation evaporation again and reclaim hydrochloric acid, remaining material is purified to filter and is removed not dissolved solids, and filtrate is the goods that mainly contain solubility calcium.If again filtrate is made the concentrated solution that contains the 10-25% solubility calcium through concentrating, perhaps concentrate and make lotion or the solid that contains the 25-36% solubility calcium, be more convenient for storing transportation.The marine organisms housing is also preferably by heat drying, can degreasing, desalination, expanded tissue, adjust physics and chemistry structure and performance, and the optimum temps of heating is 200-350 ℃.The marine organisms housing is made marine organisms housing powder and hydrochloric acid through purification, heat drying, pulverizing and is mixed by the mole proportioning and carry out decomposition reaction, the reaction Best Times is 20-30 minute like this, when reaction proceeds to 20-30 minute, add the water that marine organisms shell powder and hydrochloric acid mixture 3-4 doubly measure, heat carried out fractionation to 105-110 ℃ of boiling 60-90 minute, hydrochloric acid is isolated in evaporation, and reclaim hydrochloric acid and recycle.Can reach best effect like this.In order to remove other organic strange taste in the course of processing, extract the method for solubility calcium product in the marine organisms housing of ocean of the present invention, be preferably in when adding entry, the 1-2% activated carbon that also adds marine organisms shell powder and hydrochloric acid mixture amount, so that the absorption strange taste, and together get rid of with activated carbon at the purification filtration procedure.The solubility calcium product that refines in the marine organisms housing of the present invention is characterized in that: the marine organisms housing is purified pulverizing, decomposition, water dilution dissolving, and evaporation separation hydrochloric acid, and make liquid or lotion or the solid articles that contains solubility calcium.Goods are preferably the concentrated solution that contains the 10-25% solubility calcium, perhaps contain the lotion or the solid of 25-36% solubility calcium.If add bio-surfactant, synergistic agent, directly be used on the plant, do fertilizer for spraying on leaf surface or dash fertilising.If be mixed, do plant leaf surface and spray fertilizer or dash fertilising with chelating amino acids or with the little fertilizer of various chelating amino acids.Just this solubility calcium product can add bio-surfactant, synergistic agent etc., and the goods of formation directly are used on the plant, does fertilizer for spraying on leaf surface or dashes the fertilising use.Same this solubility calcium product, can also with chelating amino acids or with the little fertile compounding of various chelating amino acids, the goods of formation are done plant leaf surface and are sprayed fertilizer or dash fertilising.
Goods of the present invention: contain solubility calcium Ca 〉=1-36%, through concentrating the highest solubility calcium Ca 〉=36% that contains.Form: oily, light coffee color can be liquid or colloid or solid.
Concentrate good other compositions of goods: N 〉=0.2% P 〉=0.2% K 〉=0.1% magnesium 〉=0.4% zinc 〉=75ppm boron 〉=98PPm iron 〉=160PPm molybdenum 〉=2PPm copper 〉=18PPm
Usage quantity: with containing solubility calcium is 20% concentrated solution, dilute 500-800 times of liquid and does and spray, and dilution 800-1000 doubly does liquid towards executing, irritate root manure.
1. the present invention discloses a kind of production method of natural biological solubility calcium liquid fertilizer and its purposes is provided.Solve seashell and changed into the higher liquid solubility calcium of degree of ionization that plant very easily absorbs.
2. concrete technical solution of the present invention is as follows:
A. marine organisms housing (as oyster shell, crab shell, shrimp shell, other various shells, being called for short seashell) is removed impurity, is cleaned, and through heat drying, favourable purification is deviate from grease, deviate from salt, and expanded tissue is adjusted the physics and chemistry structure; Trickle bio-soluble calcium powder is made in the marine organisms housing pulverizing that purifies.
B. bio-soluble calcium powder and hydrochloric acid carry out decomposition reaction by the mixing of mole coordination ratio, add 3-4 water doubly when reaction preferably proceeds to 20-30 minute, can add the activated carbon of water yield 1-2% simultaneously; Heat preferably to the 105-110 ℃ of high temperature and to carry out fractionation in boiling 60-90 minute, just can remove hydrochloric acid, through filtering, aging best 18-30 hour of settling tank takes out top liquid and carries out just can obtaining desired concn organic soluble calcium product in technological processs such as vacuum concentration pan concentrate again.
The main points of optimal process of the present invention:
Characteristics such as A. the present invention selects for use hydrochloric acid to do seashell decomposition agent rate of decomposition height, (soluble ion attitude calcium concn height) easy, the no waste of technology (non-environmental-pollution) of making the product grade height, cost are low.
B. water that interpolation 3-4 doubly measures in the seashell resolvent (mixture of viscous form) among the present invention and the activated carbon capping pressure-raising of water yield 1-2% are heated to 105-110 ℃ of high temperature steaming 60-90 minute (dilution, release solubility thing) and carry out the slaking fractionation.
C. the depickling of this technology takes to evaporate circumfluence method, the whole backflow hydrochloric acid of recovery utilizes, controlled atmospheric pollution again, saves cost; Take distillation earlier to remove hydrochloric acid, help the operation of following step greatly, avoid the corrosion of acidic substance, guarantee that the product of producing does not contain acid group, and guaranteed that the dregs that obtain do not contain acid group, have effectively avoided the pollution to environment yet the operation engineering.
D. filter after the fractionation in this technology, depickling, improved the purification amount of solubility calcium greatly and solved the seashell slag and utilized (slag that acid-base neutralisation is good can do crop replenish the calcium fertilizer) thoroughly to solve contaminate environment hidden danger again
E. filtered liquid precipitates the aging 18-30 hour pure liquid above later the extraction once more in this technology in digestion tank, has improved product purity (impurity that thoroughly separates different specific weight)
The present invention also provides a kind of further goods and using method of biological solubility calcium:
A. spray, dash and execute, irritate root adding plant surface promoting agent, synergistic agent etc. in the biological solubility calcium, can be directly used in after the dilution in proportion to do on the plant.
B. with biological solubility calcium and chelating amino acids or with each seed amino acid isochela mixture chelating in, micro-chelating fertile mixes (prescription) do spray, towards executing, irritate root.
Positively effect of the present invention is:
The fertile degree of ionization height of biological solubility calcium liquid, plant very easily absorbs, contain the high-concentration Ca element, contain various trace elements, keratoprotein, crust element, improve absorption ability of nutrient, the various physiological barrier diseases that strengthening immunity and diseases and insect pests resistance, effectively preventing plant calcium deficiency cause, strengthen cell tissue, improve resistance, degrading pesticide, chemical fertilizer are residual, improve quality, improve output, to reach the increasing both production and income value-added effect remarkable, is the emerging fertilizer of ecological, environmental protective.
Description of drawings: accompanying drawing has been represented a kind of process flow sheet of the present invention.
Embodiment:
Embodiment one, the oyster shells of getting 10 kilograms of clean impurity eliminations react through wearing into the hydrochloric acid of powder face (crossing 30 mesh sieves) with 1.5 times of weight in ceramic pot after the seasoning, reaction adds 80 kg of water when carrying out 25 minutes and adds a cover and heat 015 ± 2 ℃ of boiling 60 minutes under the pressure-raising condition, steam bleeding is got rid of hydrochloric acid, remaining liquid filtering is removed impurity, after the liquid that obtains was put only and purified in 12 hours, heating concentrated the flowing product of the present invention that obtains containing solubility calcium 10%.It is as follows that goods are other attachment component content of oily of light coffee color:
| N | P | K | Mg | Mn | Fe | Cu | Zn | B | Mo |
| 0.2％ | 0.2％ | 0.1％ | 0.4％ | 120ppm | 160ppm | 18ppm | 75ppm | 98ppm | 2ppm |
Embodiment two, the oyster shells of getting 10 kilograms of clean impurity eliminations are worn into powder face (crossing 30 mesh sieves) after baking oven (250 ℃) drying, the hydrochloric acid of throwing in the acid-proof ceramics retort with 1.5 times of weight reacts, the activated carbon that reaction adds 80 kg of water and 0.3 kilogram when carrying out 30 minutes is added a cover and is heated 105 ± 2 ℃ of boilings 60 minutes under the pressure-raising condition, the liquid that the liquid of steam bleeding depickling, filtration impurity elimination was put above extracting in 25 hours only is goods of the present invention, also can heat to concentrate the concentrated liquid goods that obtain containing solubility calcium 15%.
Embodiment three, get 10 kilograms and clean the scallop shells remove surface impurity and after baking oven (350 ℃) drying, wear into powder face (crossing 30 mesh sieves), the hydrochloric acid of throwing in the acid-proof ceramics retort with 1.5 times of weight reacts, the activated carbon that reaction adds 80 kg of water and 0.5 kilogram when carrying out 30 minutes is added a cover and is heated 110 ± 2 ℃ of boilings 60 minutes under the pressure-raising condition, the liquid that the liquid of steam bleeding depickling, filtration impurity elimination was put above extracting in 12 hours only is goods of the present invention, also can heat to concentrate to obtain the concentrated liquid goods.
Embodiment four, get 10 kilograms of shrimp shells of clean removing surface impurities and after baking oven (150 ℃) drying, wear into powder face (crossing 30 mesh sieves), the hydrochloric acid of throwing in the acid-proof ceramics retort with 1.5 times of weight reacts, the activated carbon that reaction adds 80 kg of water and 0.4 kilogram when carrying out 30 minutes is added a cover and is heated 108 ± 2 ℃ of boilings 60 minutes under the pressure-raising condition, the liquid that the liquid of steam bleeding depickling, filtration impurity elimination was put above extracting in 12 hours only is goods of the present invention, also can heat to concentrate the lotion goods that obtain containing solubility calcium 28%.
Embodiment five, get 10 kilograms clean to remove surface impurities Carapax Eriocheir sinensis after baking oven (250 ℃) drying, wear into powder face (crossing 30 mesh sieves), the hydrochloric acid of throwing in the acid-proof ceramics retort with 1.5 times of weight reacts, the activated carbon that reaction adds 80 kg of water and 0.25 kilogram when carrying out 30 minutes is added a cover and is heated 107 ± 2 ℃ of boilings 60 minutes under the pressure-raising condition, the liquid that the liquid of steam bleeding depickling, filtration impurity elimination was put above extracting in 12 hours only is goods of the present invention, also can heat to concentrate the solid articles that obtains containing solubility calcium 36%.
Embodiment six,
On the identical basis of its farming, water and fertilizer condition, 3 groups of processing are set at random
Promptly contrast the bio-soluble calcareous fertilisers that (CK), inorganic calcium powder (CaO) and the embodiment of the invention five obtain, CK is a blade face spray clear water, inorganic calcium powder root amount of application is a 70kg/ mu, the consumption of biological solubility calcium product of the present invention is for being 70kg/ mu, take 1: 600 times to convert the waterleaf face and spray, the experiment triplicate.
Biological solubility calcium product of the present invention is to the susceptible restraining effect in cucumber field
| Investigation strain number | Susceptible progression | Diseased plant rate % | ||||
| 0 | 1 | 2 | 3 | |||
| Control group | 100 | 78 | 9 | 7 | 6 | 22 |
| The calcium oxide group | 100 | 85 | 6 | 4 | 5 | 15 |
| Solubility calcium product of the present invention | 100 | 95 | 2 | 2 | 1 | 5 |
Annotate: goods of the present invention are strong restraining effect again to cucumber downy mildew
Biological solubility calcium product of the present invention is to the Tomato Quality influence
| Soluble solid % | Solubility total reducing sugar % | Titratable total acid % | Vitamins C mg/100g | Dry-matter % | |
| Contrast | 4.32 | 3.1 | 0.35 | 13.7 | 4.86 |
| Calcium oxide | 5 | 3.35 | 0.39 | 17.4 | 5.21 |
| Solubility calcium product of the present invention | 5.25 | 3.7 | 0.35 | 21.91 | 5.51 |
| Solubility calcium product of the present invention increases and decreases % than control group | 21.5 | 19 | 0 | 60 | 13.4 |
Annotate: goods of the present invention have positive effect to improving Tomato Quality
Biological solubility calcium product of the present invention is to the Kidney bean production-increasing function
| The first replicated plot output Kg | The second replicated plot output Kg | The 3rd repeats cell production Kg | Cell production Kg | Solubility calcium product of the present invention increases and decreases % than control group | |
| Contrast | 18.4 | 17 | 16.8 | 17.4 | 0 |
| Calcium oxide | 18.8 | 18.3 | 18.7 | 18.6 | 6.9 |
| Solubility calcium product of the present invention | 19.5 | 19.8 | 20.3 | 19.9 | 14.4 |
Annotate: goods of the present invention are to the Kidney bean obvious effect of increasing production
Claims (8)
1. the marine organisms housing is produced the method for solubility calcium product, be that the marine organisms housing is purified, pulverizes, it is characterized in that: pulverize the back and decompose with hydrochloric acid, thin up, heat the fractionation evaporation again and reclaim hydrochloric acid, remaining material is purified to filter and is removed not dissolved solids, and filtrate being contained the liquid of solubility calcium.
2. marine organisms housing according to claim 1 is produced the method for solubility calcium product, it is characterized in that: filtrate makes the concentrated solution that contains the 10-25% solubility calcium through concentrating, and perhaps makes the lotion or the solid that contain the 25-36% solubility calcium.
3. marine organisms housing according to claim 1 is produced the method for solubility calcium product, it is characterized in that: the marine organisms housing is made the bio-soluble calcium powder through purification, high temperature drying, pulverizing, mix by the mole proportioning with hydrochloric acid again and carry out decomposition reaction, when reaction proceeds to 20-30 minute, add the water that marine organisms housing powder and hydrochloric acid mixture 3-4 doubly measure, heat carried out fractionation to 105-110 ℃ of boiling 60-90 minute, evaporation separates hydrochloric acid, and reclaim hydrochloric acid and recycle.
4. get the method for making solubility calcium product according to claim 1 or 2 or 3 described marine organisms housings, it is characterized in that: the 1-2% activated carbon that adds marine organisms housing powder and hydrochloric acid mixture amount.
5. the solubility calcium product that refines in the marine organisms housing is characterized in that: with the purification of marine organisms housing, pulverizing, hydrochloric acid decomposition, water dilution dissolving, and evaporate separation hydrochloric acid, make the liquid or lotion or the solid articles that contain solubility calcium.
6. solubility calcium product according to claim 4 is characterized in that: goods are the concentrated solution that contains the 10-25% solubility calcium, perhaps contain the lotion or the solid of 25-36% solubility calcium.
7. want 5 or 6 described solubility calcium products according to right, it is characterized in that: add bio-surfactant, synergistic agent, directly be used on the plant, do fertilizer for spraying on leaf surface or dash fertilising.
8. according to claim 5 or 6 described solubility calcium products, it is characterized in that: be mixed with chelating amino acids or with the little fertilizer of various chelating amino acids, do plant leaf surface and spray fertilizer or dash fertilising.
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| CN 200510047089 CN1919799A (en) | 2005-08-22 | 2005-08-22 | Natural biological solubility calcium product, preparation method and use |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106566845A (en) * | 2016-11-10 | 2017-04-19 | 南京农业大学 | Biological surfactant produced by Enterobacter hormaechei and applications thereof |
| CN107082711A (en) * | 2016-08-31 | 2017-08-22 | 青岛海洋本草生物科技有限公司 | A kind of compound farmland auxiliary agent and preparation method thereof |
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2005
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107082711A (en) * | 2016-08-31 | 2017-08-22 | 青岛海洋本草生物科技有限公司 | A kind of compound farmland auxiliary agent and preparation method thereof |
| CN106566845A (en) * | 2016-11-10 | 2017-04-19 | 南京农业大学 | Biological surfactant produced by Enterobacter hormaechei and applications thereof |
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