CN1958815A - Biological extract technology for ore of cobalt nickel oxide - Google Patents
Biological extract technology for ore of cobalt nickel oxide Download PDFInfo
- Publication number
- CN1958815A CN1958815A CNA2005101168602A CN200510116860A CN1958815A CN 1958815 A CN1958815 A CN 1958815A CN A2005101168602 A CNA2005101168602 A CN A2005101168602A CN 200510116860 A CN200510116860 A CN 200510116860A CN 1958815 A CN1958815 A CN 1958815A
- Authority
- CN
- China
- Prior art keywords
- ore
- cobalt
- nickel
- organic acid
- nickel oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- KSHLPUIIJIOBOQ-UHFFFAOYSA-N [O--].[O--].[O--].[O--].[Co++].[Ni++] Chemical compound [O--].[O--].[O--].[O--].[Co++].[Ni++] KSHLPUIIJIOBOQ-UHFFFAOYSA-N 0.000 title claims description 18
- 238000005516 engineering process Methods 0.000 title description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 51
- 150000007524 organic acids Chemical class 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 31
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 27
- 238000002386 leaching Methods 0.000 claims abstract description 21
- 239000010941 cobalt Substances 0.000 claims abstract description 17
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 17
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 238000000926 separation method Methods 0.000 claims abstract description 9
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 15
- 230000000035 biogenic effect Effects 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- 241000233866 Fungi Species 0.000 claims description 13
- 239000002609 medium Substances 0.000 claims description 9
- 235000011149 sulphuric acid Nutrition 0.000 claims description 9
- 239000001117 sulphuric acid Substances 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 7
- 241000220317 Rosa Species 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- -1 organic acid metal complex Chemical class 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 241000894006 Bacteria Species 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 244000061456 Solanum tuberosum Species 0.000 claims description 4
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 claims description 3
- 238000012258 culturing Methods 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 244000005700 microbiome Species 0.000 claims description 3
- 150000002815 nickel Chemical class 0.000 claims description 3
- 235000015097 nutrients Nutrition 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
- 244000017020 Ipomoea batatas Species 0.000 claims description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 2
- 240000003183 Manihot esculenta Species 0.000 claims description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 239000001963 growth medium Substances 0.000 claims description 2
- 238000011081 inoculation Methods 0.000 claims description 2
- 230000000050 nutritive effect Effects 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 229910052620 chrysotile Inorganic materials 0.000 claims 1
- CWBIFDGMOSWLRQ-UHFFFAOYSA-N trimagnesium;hydroxy(trioxido)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].O[Si]([O-])([O-])[O-].O[Si]([O-])([O-])[O-] CWBIFDGMOSWLRQ-UHFFFAOYSA-N 0.000 claims 1
- 229910000480 nickel oxide Inorganic materials 0.000 abstract description 10
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract description 10
- 238000011084 recovery Methods 0.000 abstract description 6
- 229910000428 cobalt oxide Inorganic materials 0.000 abstract 3
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 abstract 3
- 238000010170 biological method Methods 0.000 abstract 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 abstract 1
- 229940044175 cobalt sulfate Drugs 0.000 abstract 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 abstract 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 abstract 1
- 238000003723 Smelting Methods 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- CZAYMIVAIKGLOR-UHFFFAOYSA-N [Ni].[Co]=O Chemical compound [Ni].[Co]=O CZAYMIVAIKGLOR-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- HIRWGWMTAVZIPF-UHFFFAOYSA-N nickel;sulfuric acid Chemical compound [Ni].OS(O)(=O)=O HIRWGWMTAVZIPF-UHFFFAOYSA-N 0.000 description 1
- 229910052611 pyroxene Inorganic materials 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 230000004763 spore germination Effects 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
This invention relates to a biological method for leaching ores of nickel oxide and cobalt oxide. The method comprises: leaching ores of nickel oxide and cobalt oxide by using leaching organism derived organic acid, dissociating the leaching solution containing nickel and cobalt, passing through a separation resin, and separating nickel and cobalt from the eluate by a resin to obtain nickel sulfate and cobalt sulfate products. The method has such advantages as short process, simple equipment, low investment, low cost, no pollution and high recovery rate. The method can treat low-grade ores of nickel oxide and cobalt oxide that cannot be treated by traditional separation process, thus expanding the utility range of resources and increase the recovery rate of nickel and cobalt.
Description
Technical field
The present invention relates to a kind of bioleaching process of ore of cobalt nickel oxide, particularly a kind of technology of utilizing the multiple organic acid mixture of fungi deutero-to leach ore of cobalt nickel oxide.
Background technology
Nickel resources in the world is nickel oxide ore more than 60%, and the associated valuable metals cobalt.The treatment process of traditional nickel oxide ore can only be handled high-grade nickel oxide ore, and its principle process is that ore reduction, ore grinding, pyrometallurgical smelting or sulfuric acid high pressure leach.There are shortcomings such as energy consumption height, environmental pollution is heavy, metal recovery rate is low in the former; Though the latter has finished commerical test abroad and has carried out industrial scale applications, but can not solve its running cost height all the time, problems such as complex process and calcium magnesium vitriol blocking pipe, and adopt traditional technology to develop low-grade nickel oxide ore and do not have economic worth.The explored nickel minerals of China produces in the resource, and some is low-grade nickel oxide ore, adopts existing conventional process techniques exploitation, no economic benefit.Therefore, be necessary to provide a kind of novel process.
Summary of the invention
The purpose of this invention is to provide a kind of new ore of cobalt nickel oxide extraction process, this technology is different from traditional dressing and smelting process, promptly do not need high melt through high energy consumption, novel process flue dust and toxic gas that exhaust emission is not big, this technical process is short, equipment simple, reduced investment, cost are low, pollution-free, high-recovery has fully utilized low-grade cobalt nickel oxide mineral products resource, can obtain favorable economic benefit.
For achieving the above object, the present invention takes following technical scheme: a kind of bioleaching process of ore of cobalt nickel oxide, and it may further comprise the steps:
(1) preparation of multiple biogenic organic acid mixture
Cultivated in the fungi liquid medium within 5～6 days, 33～37 ℃ of culture temperature stir 100～120 rev/mins of revolutions, obtain multiple biogenic organic acid mixture;
(2) the nickel cobalt in the ore leaches
Adopt the multiple biogenic organic acid mixture in (1) to soak the ore deposit, soaking the ore deposit temperature is normal temperature;
(3) purification of nickel and cobalt containing leach liquor
Leach liquor in (2) is added dilute sulphuric acid regulator solution pH value, and the pH value dissociates the organic acid metal complex at 0.5-1.7, crosses strong acid type cationic resin, obtains nickeliferous behind the wash-out and sulphuric acid soln cobalt.
(4) the nickel cobalt reclaims
Use nickel cobalt separation resin to obtain nickel and cobalt liquor respectively the elute soln in (3), obtain single nickel salt and rose vitriol product then.
(5) organic acid reuse
After the organic acid that disintegrates down concentrated, return the leaching of ore.
The source of bacterial classification can be: contain the waste water of glucide of black-koji mould such as the sewage of sugar refinery discharging, or putrid fruit fruit juice etc. all can.The solid medium that adopts during seed selection can be potato sucrose substratum (potato also can use starch-containing abundant material such as cassava, sweet potato, corn to replace), inserts the fungi that contains black-koji mould and carry out seed selection in solid medium.The liquid nutrient medium of enlarged culturing can adopt the improved Bei Keshi of examining fungi culture medium, and wherein the nutritive substance of Jia Ruing is: NaNO
33g/L, KCl 0.5g/L, K
2HPO
41g/L, MgSO
47H
2O 0.5g/L, W-Gum 20g/L.The spore concentration of inoculation is about 10
4Individual/ml-10
6Individual/ml; Through cultivation, spore germination, aerial mycelium, bacterium liquid contains the black-koji mould mycelium, 33～37 ℃ of described microorganism optimum growth temps.
It can be agitation leach that nickel cobalt in the ore leaches in the step, also can be dump leaching.The ore reduction of agitation leach is ground to granularity less than 74 microns, the leaching pulp density is 5%-35% (weight percent), the ore reduction granularity of dump leaching is-10mm to soak the ore deposit with the clear liquid that contains multiple biogenic organic acid mixture of fungi deutero-or multiple organic acid composition.The kind of fungi is single black-koji mould, and this bacterium produces the acid amount greatly, is good acid-producing bacteria kind.
Soak the ore deposit after 10 days, nickel cobalt leaching yield is respectively more than 63% and 51%.This technology is fine to the selection leaching effect of nickel and cobalt, and iron is had only a small amount of leaching, has reduced subsequent steps such as heavy iron.
Description of drawings
Fig. 1 is the process flow diagram of an embodiment of the present invention
Among Fig. 1,1 is bacterial classification collection operation, 2 is strain improvement, the mycelium of picking black spore is transferred and is cultivated that to obtain biogenic organic acid be biological relieving haperacidity operation 3, add nickel oxide ores and carry out nickel oxide ore leaching operation 4,5 carry out the sulfuric acid displacement operation of dissociating for adding sulfuric acid in the leach liquor, 6 is the purification and impurity removal operation, can carry out ion-exchange by resin cation (R.C.), 7 is nickel cobalt separation circuit, and 8 is nickel cobalt product, among the figure, 9 is the organic acid storage tank, and 10 is the residual body storage bay of biogenic organic acid mixture microorganism after filtering.
Embodiment
As shown in Figure 1,
The invention will be further described below in conjunction with embodiment
Embodiment 1:
This novel process is applied to the Yunnan ore of cobalt nickel oxide, and metalliferous mineral mainly is a noumeite in the ore, secondly is nickel-containing limonite.Gangue mineral mainly is peridotites, serpentine, pyroxene etc.The nickel cobalt contents is respectively nickel 0.93%, cobalt 0.015%, iron 7.09% in the ore.
(1) preparation of multiple biogenic organic acid mixture
The acquisition of original strain: the sugared waste water that contains black-koji mould is drawn flat board and is obtained several bacterial colonys and multiple fungi through preparation fungus solids substratum (film solid media is the potato sucrose substratum).Picking grows the mycelium of black spore, the cultivation of transferring.
The acquisition of exclusive bacterium: use modified version to examine the Bei Keshi liquid nutrient medium, fungi is carried out enlarged culturing.Cultivated in the fungi liquid medium within 5～6 days, 33～35 ℃ of culture temperature stir 100～120 rev/mins of revolutions, obtain multiple biogenic organic acid mixture, use millipore filter to filter the clear liquid that obtains containing multiple organic acid composition.
(2) the nickel cobalt in the ore leaches
The clear liquid that contains multiple organic acid composition in the employing (1) stirs and soaks the ore deposit, pulp density 5%, revolution 100/ minute, extraction temperature normal temperature, extraction time 5-7 days, leaching yield was 50～80%, carry out solid-liquid separation then, discarded stable the storing up of solid residue, leach liquor enters next step operation.
(3) dissociate under the organic acid metal complex compound acidic conditions
Add dilute sulphuric acid regulator solution pH value to 0.5～1.7, the organic acid metal complex is almost completely dissociated, cross strong acidic ion resin (can adopt the resin trade mark is the 732# strongly acidic styrene type cation exchange resin), organic acid combines with hydrogen ion with the organic acid form and flows out earlier, use the dilute sulphuric acid wash-out again, obtain the elute soln (its pH value is 2～3) of sulfur acid nickel and rose vitriol.
(4) the nickel cobalt reclaims
Elute soln pH value in the step (3) is adjusted to 1～1.7, uses nickel cobalt separation resin (as WP-1, the extraordinary ion exchange resin of WP-2 inorganic type, can buy on the market) to obtain nickel and cobalt liquor respectively, crystallization obtains single nickel salt and rose vitriol product then.The rate of recovery is 85～95%
(5) organic acid reuse
After the organic acid that disintegrates down concentrated, return ore and leach.
Embodiment 2:
This novel process is applied to the Yunnan ore of cobalt nickel oxide and carries out dump leaching, and metalliferous mineral is the same in the ore.
(1) preparation of multiple biogenic organic acid mixture
With (1) among the embodiment 1.
(2) the nickel cobalt in the ore leaches
Ore reduction is arrived granularity less than 10mm; Build heap then, build in the heap process, build stack height 1～3m in order to keep ore to form multiple hole, draughty heap naturally as far as possible; Spray the leaching ore with the clear liquid that contains multiple organic acid composition in (1), spray rate is 5-10L/m
2.h.
(3) dissociate under the organic acid metal complex compound acidic conditions
Add dilute sulphuric acid regulator solution pH value to 0.5～about 1.7, the organic acid metal complex is almost completely dissociated, cross strong acidic ion resin, organic acid combines with hydrogen ion with the organic acid form and flows out earlier, use the dilute sulphuric acid wash-out again, obtain the solution of sulfur acid nickel and rose vitriol.
(4) the nickel cobalt reclaims
(3) elute soln pH value is adjusted to 0.5～2.0, uses nickel cobalt separation resin to obtain nickel and cobalt liquor respectively, crystallization obtains solid sulphuric acid nickel and rose vitriol product then.
(5) organic acid reuse
After the organic acid that disintegrates down concentrated, return ore and leach.
Effect of the present invention is: except being conducive to environmental protection, can also be used to develop traditional selecting and smelting technology can not The low-grade nickel oxide cobalt ore that utilizes produces resource, enlarges the scope of utilizing that the nickel cobalt ore produces resource, improves the nickel cobalt and combines Close the rate of recovery.
Claims (9)
1, a kind of bioleaching process of ore of cobalt nickel oxide, it is characterized in that: it may further comprise the steps:
(1), the preparation of multiple biogenic organic acid mixture
Cultivated in the fungi liquid medium within 5～6 days, 33～37 ℃ of culture temperature stir 100～120 rev/mins of revolutions, obtain multiple biogenic organic acid mixture;
(2), the nickel cobalt in the ore leaches
Adopt the multiple biogenic organic acid mixture in (1) to soak the ore deposit, soaking the ore deposit temperature is normal temperature;
(3), the purification of nickel and cobalt containing leach liquor
Leach liquor in (2) is added dilute sulphuric acid regulator solution pH value, and the pH value dissociates the organic acid metal complex at 0.5-1.7, crosses strong acidic ion resin, obtains nickeliferous behind the wash-out and sulphuric acid soln cobalt;
(4), the nickel cobalt reclaims
Use nickel cobalt separation resin to obtain nickel and cobalt liquor respectively the elute soln in (3), obtain single nickel salt and rose vitriol product then;
(5) organic acid reuse
After the organic acid that disintegrates down concentrated, return the leaching of ore.
2, the bioleaching process of a kind of ore of cobalt nickel oxide according to claim 1, after it is characterized in that the described multiple biogenic organic acid mixture that soaks the ore deposit use filters through millipore filter, the clear liquid that contains multiple organic acid composition that obtains is delivered to the leaching operation.
3, the bioleaching process of a kind of ore of cobalt nickel oxide according to claim 1 and 2, it is characterized in that: described preparation to multiple biogenic organic acid mixture is to insert the fungi that contains black-koji mould to carry out in the solid medium that the sucrose of potato or cassava or sweet potato or corn is made, the liquid nutrient medium of enlarged culturing is the improved Bei Keshi of examining fungi culture medium, and wherein the nutritive substance of Jia Ruing is: NaNO
33g/L, KCl 0.5g/L, K
2HPO
41g/L, MgSO
47H
2O 0.5g/L, W-Gum 20g/L; Bacterium liquid contains the black-koji mould mycelium, and the spore concentration of inoculation is 10
4Individual/ml-10
7Individual/ml; 33～37 ℃ of described microorganism optimum growth temps.
4, the bioleaching process of a kind of ore of cobalt nickel oxide according to claim 1 and 2, it is characterized in that: nickel and cobalt leach and comprise agitation leach in the described ore, agitation leach is less than 74 microns with the ore reduction grind size, leaching pulp density is the 5%-35% weight percent, and the pH value is between 3.0-3.5.
5, the bioleaching process of a kind of ore of cobalt nickel oxide according to claim 3, it is characterized in that: nickel and cobalt leach and comprise agitation leach in the described ore, agitation leach is less than 74 microns with the ore reduction grind size, leaching pulp density is the 5%-35% weight percent, and the pH value is between 3.0-3.5.
6, the bioleaching process of a kind of ore of cobalt nickel oxide according to claim 1 and 2, its feature dump leaching are that ore reduction is arrived granularity less than 10mm; Build heap then, build in the heap process in order to keep ore to form multiple hole, draughty heap naturally as far as possible, build stack height 1～3m, spray rate is 5～10L/ (m
2H).
7, the bioleaching process of a kind of ore of cobalt nickel oxide according to claim 3, its feature dump leaching are that ore reduction is arrived granularity less than 10mm; Build heap then, build in the heap process in order to keep ore to form multiple hole, draughty heap naturally as far as possible, build stack height 1～3m, spray rate is 5～10L/ (m
2H).
8, a kind of bioleaching process that contains ore of cobalt nickel oxide according to claim 1 and 2 is characterized in that: described nickel-containing mineral comprise noumeite claim again nepouite (Ni, Mg)
3Si
2O
5(OH)
4, nickel-containing limonite (Fe, Ni) O (OH) .nH
2O, health nickel serpentine (Ni, Mg)
8(OH)
4[Si
4O
10] 6H
2O, nickel chrysotile Ni
6Si
4O
10(OH)
8, thunder nickel serpentine (Mg, Ni, Fe
2+)
3Si
2O
5(OH)
4Deng.
9, a kind of bioleaching process that contains ore of cobalt nickel oxide according to claim 1 and 2 is characterized in that: obtaining the nickeliferous and employed separation resin of sulphuric acid soln cobalt behind the described wash-out is strong acid type cationic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101168602A CN100554444C (en) | 2005-10-31 | 2005-10-31 | A kind of bioleaching process of ore of cobalt nickel oxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101168602A CN100554444C (en) | 2005-10-31 | 2005-10-31 | A kind of bioleaching process of ore of cobalt nickel oxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1958815A true CN1958815A (en) | 2007-05-09 |
| CN100554444C CN100554444C (en) | 2009-10-28 |
Family
ID=38070671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101168602A Expired - Fee Related CN100554444C (en) | 2005-10-31 | 2005-10-31 | A kind of bioleaching process of ore of cobalt nickel oxide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100554444C (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2395599C2 (en) * | 2007-07-09 | 2010-07-27 | Татьяна Викторовна Башлыкова | Procedure for processing silicate cobalt-nickel ore |
| CN101434920B (en) * | 2007-11-13 | 2010-11-10 | 北京有色金属研究总院 | An strain of low temperature leaching-ore bacteria and process for using the same for low temperature heap leaching of nickel sulfide ore |
| CN101457292B (en) * | 2007-12-10 | 2012-01-25 | 北京有色金属研究总院 | Process for recovering nickel ion from biochemical lixivium of laterite nickel mine by using room temperature ion liquid |
| CN102719669A (en) * | 2012-07-06 | 2012-10-10 | 中国矿业大学(北京) | Process for vulcanizing and modifying low-grade oxidized copper ore by using biological vulcanizing agent |
| CN103509946A (en) * | 2012-06-14 | 2014-01-15 | 中国科学院过程工程研究所 | Method for vulcanizing low-grade oxidized nickel ore with microbiological method |
| CN104531992A (en) * | 2014-12-23 | 2015-04-22 | 中南大学 | Application of ferric phosphate for reinforcement of bacterial leaching out of nickel sulphide ores |
| CN104745813A (en) * | 2013-12-31 | 2015-07-01 | 北京有色金属研究总院 | Method for comprehensively recovering nickel and magnesium in bio-leaching process of high-magnesium low-nickel sulfide ore |
| CN106222410A (en) * | 2016-08-30 | 2016-12-14 | 合肥常青机械股份有限公司 | Prevent locking nut plate of side longitudinal cracking and preparation method thereof |
| CN106222408A (en) * | 2016-08-29 | 2016-12-14 | 芜湖常瑞汽车部件有限公司 | The preparation method of the right front door snap close fixed plate that tensile strength high-alloy steel materials is made |
| CN106222409A (en) * | 2016-08-29 | 2016-12-14 | 合肥常青机械股份有限公司 | Seat belt fixed plate that process route reasonable efficiency quality is high and preparation method thereof |
| CN106244896A (en) * | 2016-08-29 | 2016-12-21 | 芜湖常瑞汽车部件有限公司 | Good automobile front lamp support of the big tensile strength of outer wall hardness and preparation method thereof |
| CN106282466A (en) * | 2016-08-29 | 2017-01-04 | 合肥常青机械股份有限公司 | Along inner panel reinforcing plate and preparation method thereof under door in hardness height dense structure automobile |
| CN106282749A (en) * | 2016-08-30 | 2017-01-04 | 合肥常青机械股份有限公司 | Reduce surface roughness oil filler liner plate reducing the raising of allowance intensity and preparation method thereof |
| CN106319332A (en) * | 2016-08-30 | 2017-01-11 | 合肥常青机械股份有限公司 | Empennage support glossy in surface, attractive, free of dark lines and good in mechanical property, and preparation method thereof |
| CN106319331A (en) * | 2016-08-29 | 2017-01-11 | 合肥常青机械股份有限公司 | Rear door left hinge reinforcing plate with good-corrosion-resistance easy-to-weld welding zone and preparation method thereof |
| CN108004401A (en) * | 2017-11-30 | 2018-05-08 | 武汉理工大学 | A kind of method that high-phosphorus iron ore dephosphorization is carried out using Aspergillus niger strain zymotic fluid |
| CN110055415A (en) * | 2019-04-17 | 2019-07-26 | 吉林吉恩镍业股份有限公司 | A method of metallic nickel in laterite is extracted using microorganism |
| WO2023244964A1 (en) | 2022-06-14 | 2023-12-21 | Cemvita Factory, Inc. | Process |
-
2005
- 2005-10-31 CN CNB2005101168602A patent/CN100554444C/en not_active Expired - Fee Related
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2395599C2 (en) * | 2007-07-09 | 2010-07-27 | Татьяна Викторовна Башлыкова | Procedure for processing silicate cobalt-nickel ore |
| CN101434920B (en) * | 2007-11-13 | 2010-11-10 | 北京有色金属研究总院 | An strain of low temperature leaching-ore bacteria and process for using the same for low temperature heap leaching of nickel sulfide ore |
| CN101457292B (en) * | 2007-12-10 | 2012-01-25 | 北京有色金属研究总院 | Process for recovering nickel ion from biochemical lixivium of laterite nickel mine by using room temperature ion liquid |
| CN103509946A (en) * | 2012-06-14 | 2014-01-15 | 中国科学院过程工程研究所 | Method for vulcanizing low-grade oxidized nickel ore with microbiological method |
| CN102719669A (en) * | 2012-07-06 | 2012-10-10 | 中国矿业大学(北京) | Process for vulcanizing and modifying low-grade oxidized copper ore by using biological vulcanizing agent |
| CN102719669B (en) * | 2012-07-06 | 2016-12-21 | 中国矿业大学(北京) | The technique of biological vulcanizing agent sulfide modifier low grade copper oxide ore |
| CN104745813A (en) * | 2013-12-31 | 2015-07-01 | 北京有色金属研究总院 | Method for comprehensively recovering nickel and magnesium in bio-leaching process of high-magnesium low-nickel sulfide ore |
| CN104745813B (en) * | 2013-12-31 | 2017-02-15 | 北京有色金属研究总院 | Method for comprehensively recovering nickel and magnesium in bio-leaching process of high-magnesium low-nickel sulfide ore |
| CN104531992A (en) * | 2014-12-23 | 2015-04-22 | 中南大学 | Application of ferric phosphate for reinforcement of bacterial leaching out of nickel sulphide ores |
| CN106244896A (en) * | 2016-08-29 | 2016-12-21 | 芜湖常瑞汽车部件有限公司 | Good automobile front lamp support of the big tensile strength of outer wall hardness and preparation method thereof |
| CN106222409A (en) * | 2016-08-29 | 2016-12-14 | 合肥常青机械股份有限公司 | Seat belt fixed plate that process route reasonable efficiency quality is high and preparation method thereof |
| CN106222408A (en) * | 2016-08-29 | 2016-12-14 | 芜湖常瑞汽车部件有限公司 | The preparation method of the right front door snap close fixed plate that tensile strength high-alloy steel materials is made |
| CN106282466A (en) * | 2016-08-29 | 2017-01-04 | 合肥常青机械股份有限公司 | Along inner panel reinforcing plate and preparation method thereof under door in hardness height dense structure automobile |
| CN106319331A (en) * | 2016-08-29 | 2017-01-11 | 合肥常青机械股份有限公司 | Rear door left hinge reinforcing plate with good-corrosion-resistance easy-to-weld welding zone and preparation method thereof |
| CN106282749A (en) * | 2016-08-30 | 2017-01-04 | 合肥常青机械股份有限公司 | Reduce surface roughness oil filler liner plate reducing the raising of allowance intensity and preparation method thereof |
| CN106319332A (en) * | 2016-08-30 | 2017-01-11 | 合肥常青机械股份有限公司 | Empennage support glossy in surface, attractive, free of dark lines and good in mechanical property, and preparation method thereof |
| CN106222410A (en) * | 2016-08-30 | 2016-12-14 | 合肥常青机械股份有限公司 | Prevent locking nut plate of side longitudinal cracking and preparation method thereof |
| CN108004401A (en) * | 2017-11-30 | 2018-05-08 | 武汉理工大学 | A kind of method that high-phosphorus iron ore dephosphorization is carried out using Aspergillus niger strain zymotic fluid |
| CN110055415A (en) * | 2019-04-17 | 2019-07-26 | 吉林吉恩镍业股份有限公司 | A method of metallic nickel in laterite is extracted using microorganism |
| WO2023244964A1 (en) | 2022-06-14 | 2023-12-21 | Cemvita Factory, Inc. | Process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100554444C (en) | 2009-10-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1958815A (en) | Biological extract technology for ore of cobalt nickel oxide | |
| Groudev | Use of heterotrophic microorganisms in mineral biotechnology | |
| CN102719657B (en) | Method for recycling heavy metal in electroplating sludge | |
| CN106834699B (en) | A kind of method of copper-contained sludge harmless treatment and higher value application | |
| CN101434909B (en) | Penicillium, as well as preparation method and application | |
| GB2606659A (en) | Method and system for biologically treating acidic mine wastewater while recovering iron ion | |
| CN103993171B (en) | A kind of method of adding nonionogenic tenside promotion chalcopyrite Bioleaching | |
| CN112279478A (en) | Method for recovering phosphorus in excess sludge in form of vivianite | |
| CN1244687C (en) | Biological heap leaching process for cobaltous nickelous sulfide ore containing arsenic | |
| CN1277939C (en) | Method of leaching copper in copper containing pyrite using bacteria | |
| CN101497942A (en) | Biological leaching-solvent extraction-electrodeposition recovering method for heavy metal copper in sludge | |
| Yang et al. | Pretreatment of deep-sea bacteria for reverse flotation of magnesite tailings: Cleaner production, behavior and mechanism | |
| CN1260376C (en) | Combined heap leaching process for copper ore | |
| Lv et al. | Bioleaching of silicon in electrolytic manganese residue using single and mixed silicate bacteria | |
| CN107746959A (en) | A kind of two step bioleaching process and device of total head recovery valuable metals in waste circuit board | |
| CN113046552B (en) | Method for leaching weathering crust leaching type rare earth ore by using plant extract | |
| CN101837962A (en) | Method for leaching phosphorus from low-grade phosphate ore by thiobacillus thiooxidans | |
| CN100562566C (en) | Combined Chemical and Biological Heap Leaching Process of Medium Thermophilic Bacteria and Low Grade Primary Copper Sulfide Ore | |
| CN102643769A (en) | Extreme acidophilus thiobacillus and application of same in copper pyrite infusion | |
| CA3259374A1 (en) | Process | |
| US5256544A (en) | Microbial solubilization of phosphate | |
| CN107760866B (en) | Method for strengthening bacterial leaching of molybdenite with nonionic surfactant | |
| CN112680600B (en) | Process for recovering copper and enriching precious metals from sponge copper slag through biological oxidation | |
| Sinharoy et al. | Indium removal by Aspergillus niger fungal pellets in the presence of selenite and tellurite | |
| CN102206751A (en) | Method for continuously recovering copper from printed circuit boards by microbial metabolites under action of micro electric field |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190703 Address after: 101407 No. 11 Xingke East Street, Yanqi Economic Development Zone, Huairou District, Beijing Patentee after: Research Institute of engineering and Technology Co., Ltd. Address before: 100088, 2, Xinjie street, Beijing Patentee before: General Research Institute for Nonferrous Metals |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210422 Address after: 101407 No.11, Xingke East Street, Yanqi Economic and Technological Development Zone, Huairou District, Beijing Patentee after: Youyan resources and Environment Technology Research Institute (Beijing) Co.,Ltd. Address before: 101407 Beijing city Huairou District Yanqi Economic Development Zone Branch Hing Street No. 11 Patentee before: YOUYAN ENGINEERING TECHNOLOGY RESEARCH INSTITUTE Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20091028 Termination date: 20201031 |