CN1724608A - Anti-fog coating for glass - Google Patents
Anti-fog coating for glass Download PDFInfo
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- CN1724608A CN1724608A CN 200410053314 CN200410053314A CN1724608A CN 1724608 A CN1724608 A CN 1724608A CN 200410053314 CN200410053314 CN 200410053314 CN 200410053314 A CN200410053314 A CN 200410053314A CN 1724608 A CN1724608 A CN 1724608A
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- ethylene glycol
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- monomethyl ether
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Abstract
Description
(一)技术领域(1) Technical field
本发明涉及一种玻璃防雾涂料。The invention relates to a glass anti-fog coating.
(二)技术背景(2) Technical background
玻璃防雾处理在国内外是玻璃深加工方面的一个研究热点，市场需求极大。国内外现在主要的研究是在玻璃表面沉积导电膜，通过导电膜加热防雾或者在玻璃表面涂覆防雾膜进行防雾。防雾膜处理相对而言制备工艺简单、设备投资低、成本低而更具有生产实用价值。目前对防雾涂料及其制备工艺已有一些研究报道，但至今仍未推广应用。从产品市场角度来看，一些关键问题还未得到解决，如防雾性能不理想、防雾膜强度低和耐久性差。Glass anti-fog treatment is a research hotspot in glass deep processing at home and abroad, and the market demand is huge. The main research at home and abroad is to deposit a conductive film on the surface of the glass, heat the conductive film to prevent fogging, or apply an antifogging film on the surface of the glass to prevent fogging. Anti-fog film treatment is relatively simple in preparation process, low in equipment investment, low in cost and more practical in production. At present, there are some research reports on anti-fog coatings and their preparation process, but they have not been popularized and applied so far. From the perspective of the product market, some key issues have not been resolved, such as unsatisfactory anti-fog performance, low strength and poor durability of the anti-fog film.
(三)发明内容(3) Contents of the invention
为克服现有防雾涂料的不足，本发明采用醚、酸和脂类有机化合物聚合得到一种具有优良防雾性能的玻璃防雾涂料。In order to overcome the deficiencies of the existing anti-fog coatings, the invention uses ether, acid and lipid organic compounds to polymerize to obtain a glass anti-fog coating with excellent anti-fog performance.
本发明所述的玻璃防雾涂料，其特征在于包含按重量计的下列组分的原料在自由基引发剂存在下，在50～80℃和惰性气体保护下聚合反应制得：The glass anti-fog coating of the present invention is characterized in that the raw materials comprising the following components by weight are prepared by polymerization reaction at 50-80°C under the protection of an inert gas in the presence of a free radical initiator:
1000份 乙二醇单甲醚，1000 parts Ethylene glycol monomethyl ether,
43～128份 甲基丙烯酸甲酯，43～128 parts methyl methacrylate,
115～192份 丙烯酸，115-192 parts of acrylic acid,
72～108份 乙二醇。72 to 108 parts of ethylene glycol.
上述的原料优选由下列组分组成：按重量计，The above-mentioned raw materials are preferably composed of the following components: by weight,
1000份 乙二醇单甲醚，1000 parts Ethylene glycol monomethyl ether,
43～128份 甲基丙烯酸甲酯，43～128 parts methyl methacrylate,
115～192份 丙烯酸，115-192 parts of acrylic acid,
72～108份 乙二醇，72～108 parts of ethylene glycol,
1～90份的丙烯酸丁酯。1-90 parts of butyl acrylate.
所述的自由基引发剂与乙二醇单甲醚的重量比优选为0.008～0.08∶1。自由基引发剂优选为过氧类自由基引发剂，如过氧化二苯甲酰(BPO)、过氧化苯甲酸叔丁酯、过氧化二异丙苯、过氧化二碳酸二异丙酯等。The weight ratio of the free radical initiator to ethylene glycol monomethyl ether is preferably 0.008˜0.08:1. The free radical initiator is preferably a peroxy free radical initiator, such as dibenzoyl peroxide (BPO), tert-butyl peroxybenzoate, dicumyl peroxide, diisopropyl peroxydicarbonate and the like.
所述的惰性气体为氮气或氩气。The inert gas is nitrogen or argon.
所述的反应时间优选为5～10小时。The reaction time is preferably 5-10 hours.
上述得到的防雾涂料可以按下述方法制备成防雾膜：The anti-fog coating obtained above can be prepared into an anti-fog film as follows:
将涂料均匀涂刷在玻璃上，在90-120℃烘箱内固化1-2小时。Brush the paint evenly on the glass, and cure it in an oven at 90-120°C for 1-2 hours.
依本发明所述方法得到的防雾膜透明、平整，不影响玻璃的透明度。将上述制得防雾玻璃置于30℃水汽中，玻璃表面不起水雾大于15分钟。The anti-fogging film obtained by the method of the invention is transparent and smooth without affecting the transparency of the glass. The above-prepared anti-fog glass was placed in water vapor at 30°C, and the surface of the glass was free from water mist for more than 15 minutes.
本发明所述的玻璃防雾涂料制备工艺简单、成本低，防雾抑雾性能优良。The glass anti-fog coating of the invention has simple preparation process, low cost and excellent anti-fog and anti-fog performance.
(四)具体实施方式(4) Specific implementation methods
下面结合具体实施例对本发明作进一步说明，但本发明的保护范围并不限于此。The present invention will be further described below in conjunction with specific examples, but the protection scope of the present invention is not limited thereto.
实施例1Example 1
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.5g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.5g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例2Example 2
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶10g∶11.5g∶7.2g.0.8g∶9g。Raw material preparation: Ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 10g: 11.5g: 7.2g. 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例3Example 3
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶12.8g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 12.8g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例4Example 4
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶15.1g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 15.1g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例5Example 5
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶19.2g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 19.2g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例6Example 6
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶9g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 9g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例7Example 7
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶10.8g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 10.8g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例8Example 8
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶2g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 2g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例9Example 9
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例10Example 10
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BP0(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例11Example 11
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g∶5g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g: 5g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例12Example 12
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在50℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out for 10 hours at a temperature of 50° C. under the protection of nitrogen at a speed of 200 rpm.
实施例13Example 13
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在80℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out for 10 hours at a temperature of 80° C. under the protection of nitrogen at a speed of 200 rpm.
实施例14Example 14
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例15Example 15
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例16Example 16
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例17Example 17
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例18Example 18
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例19Example 19
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例20Example 20
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶4.3g∶11.5g∶7.2g∶5g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 5g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例21Example 21
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶10g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 10g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例22Example 22
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶10g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 10g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在60℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out at a temperature of 60° C. under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例23Example 23
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶10g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 10g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例24Example 24
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶10g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 10g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例25Example 25
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶10g∶11.5g∶7.2g∶0.8g∶9g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 10g: 11.5g: 7.2g: 0.8g: 9g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应8小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 8 hours.
实施例26Example 26
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶10g∶16.5g∶9.2g∶0.9g∶8g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 10g: 16.5g: 9.2g: 0.9g: 8g.
涂料制备：将各组分按一定比例混合后，在60℃温度和氮气保护下，以200转/分速度进行搅拌反应9小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out for 9 hours at a temperature of 60° C. under the protection of nitrogen at a speed of 200 rpm.
实施例27Example 27
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶11g∶12.5g∶7.2g∶8g∶7g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 11g: 12.5g: 7.2g: 8g: 7g.
涂料制备：将各组分按一定比例混合后，在60℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out at a temperature of 60° C. under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例28Example 28
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶10g∶17.5g∶8.2g∶3g∶2g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 10g: 17.5g: 8.2g: 3g: 2g.
涂料制备：将各组分按一定比例混合后，在80℃温度和氮气保护下，以200转/分速度进行搅拌反应6小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out for 6 hours at a temperature of 80° C. under the protection of nitrogen at a speed of 200 rpm.
实施例29Example 29
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO∶丙烯酸丁酯(重量比)为100g∶10g∶11.5g∶7.2g∶0.8g∶1g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO: butyl acrylate (weight ratio) is 100g: 10g: 11.5g: 7.2g: 0.8g: 1g.
涂料制备：将各组分按一定比例混合后，在80℃温度和氮气保护下，以200转/分速度进行搅拌反应5小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 80° C. under nitrogen protection at a speed of 200 rpm for 5 hours.
实施例30Example 30
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO(重量比)为100g∶4.3g∶11.5g∶7.2g∶0.8g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 0.8g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应9小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out for 9 hours at a temperature of 70° C. under the protection of nitrogen at a speed of 200 rpm.
实施例31Example 31
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO(重量比)为100g∶10g∶11.5g∶9g∶1.8g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO (weight ratio) is 100g: 10g: 11.5g: 9g: 1.8g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例32Example 32
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO(重量比)为100g∶12.8g∶11.5g∶7.2g∶0.8g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO (weight ratio) is 100g: 12.8g: 11.5g: 7.2g: 0.8g.
涂料制备：将各组分按一定比例混合后，在50℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out for 10 hours at a temperature of 50° C. under the protection of nitrogen at a speed of 200 rpm.
实施例33Example 33
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO(重量比)为100g∶6g∶15.1g∶7.2g∶4g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO (weight ratio) is 100g: 6g: 15.1g: 7.2g: 4g.
涂料制备：将各组分按一定比例混合后，在50℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out for 10 hours at a temperature of 50° C. under the protection of nitrogen at a speed of 200 rpm.
实施例34Example 34
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO(重量比)为100g∶7g∶19.2g∶8g∶6g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO (weight ratio) is 100g: 7g: 19.2g: 8g: 6g.
涂料制备：将各组分按一定比例混合后，在80℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out for 10 hours at a temperature of 80° C. under the protection of nitrogen at a speed of 200 rpm.
实施例35Example 35
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶BPO(重量比)为100g∶4.3g∶11.5g∶9g∶0.8g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: BPO (weight ratio) is 100g: 4.3g: 11.5g: 9g: 0.8g.
涂料制备：将各组分按一定比例混合后，在80℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components in a certain proportion, the stirring reaction was carried out for 10 hours at a temperature of 80° C. under the protection of nitrogen at a speed of 200 rpm.
实施例36Example 36
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶过氧化苯甲酸叔丁酯(重量比)为100g∶4.3g∶11.5g∶10.8g∶0.8g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: tert-butyl peroxybenzoate (weight ratio) is 100g: 4.3g: 11.5g: 10.8g: 0.8g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例37Example 37
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶过氧化苯甲酸叔丁酯(重量比)为100g∶9g∶15g∶7.2g∶2g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: tert-butyl peroxybenzoate (weight ratio) is 100g: 9g: 15g: 7.2g: 2g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例38Example 38
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶过氧化苯甲酸叔丁酯(重量比)为100g∶12.8g∶19.2g∶8.2g∶8g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: tert-butyl peroxybenzoate (weight ratio) is 100g: 12.8g: 19.2g: 8.2g: 8g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例39Example 39
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶过氧化二异丙苯(重量比)为100g∶4.3g∶15.5g∶9.2g∶3g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: dicumyl peroxide (weight ratio) is 100g: 4.3g: 15.5g: 9.2g: 3g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例40Example 40
原料配制：乙二醇单甲醚∶甲基丙烯酸甲酯∶丙烯酸∶乙二醇∶过氧化二异丙苯(重量比)为100g∶4.3g∶11.5g∶7.2g∶8g。Raw material preparation: ethylene glycol monomethyl ether: methyl methacrylate: acrylic acid: ethylene glycol: dicumyl peroxide (weight ratio) is 100g: 4.3g: 11.5g: 7.2g: 8g.
涂料制备：将各组分按一定比例混合后，在70℃温度和氮气保护下，以200转/分速度进行搅拌反应10小时。Coating preparation: After mixing the components according to a certain ratio, the stirring reaction was carried out at a temperature of 70° C. and under the protection of nitrogen at a speed of 200 rpm for 10 hours.
实施例41Example 41
将实施例1～40制得涂料均匀涂刷在玻璃上，分别在90-120℃烘箱内固化1-2小时。Paint the coatings prepared in Examples 1-40 evenly on the glass, and cure them in an oven at 90-120° C. for 1-2 hours.
将上述制得防雾玻璃置于30℃水汽中，观察玻璃表面的起雾情况。The anti-fog glass prepared above was placed in water vapor at 30°C, and the fogging on the glass surface was observed.
实验结果发现，各防雾玻璃表面不起水雾均大于15分钟。According to the experimental results, all the anti-fog glass surfaces are free from water mist for more than 15 minutes.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410053314 CN1724608A (en) | 2004-07-22 | 2004-07-22 | Anti-fog coating for glass |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 200410053314 CN1724608A (en) | 2004-07-22 | 2004-07-22 | Anti-fog coating for glass |
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| CN1724608A true CN1724608A (en) | 2006-01-25 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103773153A (en) * | 2014-01-20 | 2014-05-07 | 南通钰成光电科技有限公司 | Anti-fog coating material for glass lampshade and preparation method thereof |
| TWI457424B (en) * | 2006-09-28 | 2014-10-21 | Ind Science & Technology Network Inc | Nanoengineered composite defog coating |
| CN106995683A (en) * | 2017-04-21 | 2017-08-01 | 常州梦泰照明科技有限公司 | A kind of preparation method of glass for vehicle window antifoggant |
-
2004
- 2004-07-22 CN CN 200410053314 patent/CN1724608A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI457424B (en) * | 2006-09-28 | 2014-10-21 | Ind Science & Technology Network Inc | Nanoengineered composite defog coating |
| CN103773153A (en) * | 2014-01-20 | 2014-05-07 | 南通钰成光电科技有限公司 | Anti-fog coating material for glass lampshade and preparation method thereof |
| CN106995683A (en) * | 2017-04-21 | 2017-08-01 | 常州梦泰照明科技有限公司 | A kind of preparation method of glass for vehicle window antifoggant |
| CN106995683B (en) * | 2017-04-21 | 2019-04-19 | 安徽中胶工业材料有限公司 | A kind of preparation method of window glass antifogging agent |
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