CN1745640A - Preparation containing natural anophelifuge essence - Google Patents
Preparation containing natural anophelifuge essence Download PDFInfo
- Publication number
- CN1745640A CN1745640A CNA2005100949506A CN200510094950A CN1745640A CN 1745640 A CN1745640 A CN 1745640A CN A2005100949506 A CNA2005100949506 A CN A2005100949506A CN 200510094950 A CN200510094950 A CN 200510094950A CN 1745640 A CN1745640 A CN 1745640A
- Authority
- CN
- China
- Prior art keywords
- oil
- natural anophelifuge
- essence
- anophelifuge essence
- metadelphene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims description 8
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003921 oil Substances 0.000 claims abstract description 15
- 235000019198 oils Nutrition 0.000 claims abstract description 15
- 235000019501 Lemon oil Nutrition 0.000 claims abstract description 4
- 241000208181 Pelargonium Species 0.000 claims abstract description 4
- 239000010630 cinnamon oil Substances 0.000 claims abstract description 4
- 239000010501 lemon oil Substances 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 244000165852 Eucalyptus citriodora Species 0.000 claims description 4
- 235000004722 Eucalyptus citriodora Nutrition 0.000 claims description 4
- 239000010632 citronella oil Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 3
- 235000011613 Pinus brutia Nutrition 0.000 claims description 3
- 241000018646 Pinus brutia Species 0.000 claims description 3
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 3
- 244000223014 Syzygium aromaticum Species 0.000 claims description 3
- 239000010648 geranium oil Substances 0.000 claims description 3
- 235000019717 geranium oil Nutrition 0.000 claims description 3
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 claims description 3
- 239000001738 pogostemon cablin oil Substances 0.000 claims description 3
- 239000010668 rosemary oil Substances 0.000 claims description 3
- 229940058206 rosemary oil Drugs 0.000 claims description 3
- 239000000077 insect repellent Substances 0.000 abstract description 9
- 241000255925 Diptera Species 0.000 abstract description 8
- 230000001846 repelling effect Effects 0.000 abstract description 4
- 229960001673 diethyltoluamide Drugs 0.000 abstract 2
- 241000251468 Actinopterygii Species 0.000 abstract 1
- 241001529821 Agastache Species 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 description 9
- 238000012360 testing method Methods 0.000 description 5
- 241000256173 Aedes albopictus Species 0.000 description 4
- 239000008280 blood Substances 0.000 description 3
- 210000004369 blood Anatomy 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- 235000010894 Artemisia argyi Nutrition 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 244000030166 artemisia Species 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 230000001537 neural effect Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 239000004597 plastic additive Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A mosquito repellent is prepared from diethyltoluamide DEET and the natural mosquito repelling essence containing the active components chosen from lemon oil, cinnamon oil, agastache oil, fish pelargonium oil, etc.
Description
Technical field
The present invention relates to a kind of mosquito repellent.
Background technology
Insect can bring danger even cause life to threaten to the mankind.Various insects are all being perplexed people and many animals except the destruction (as the harvest that destroys) that meeting causes surrounding enviroment in varying degrees, even life entity infects and dangerous epiphytotics propagation.
Insecticide is the primary armament that is used for tackling these insects traditionally, but its toxicity can cause the problem of environmental protection aspect in various degree.Therefore use the preventive measure of non-insecticide more and more to come into one's own.And insect mosquito repellent a kind of material that comes to this, when insect when differentiating its acceptor, thereby the flight path that changes it makes it away from original target.This has just significantly reduced the touch opportunity of insect and acceptor, thereby greatly reduces acceptor by the possibility of insect-borne infection or influence.
At present, the major part that concerns between the expelling parasite mechanism of pest repellant and the chemical constitution can't explain that still the pest repellant that different insects adopted belongs to diverse material.Traditional synthetic culicifuge comprises Metadelphene (DEET), repefral (DMP), vegetable oil, dimethyl phthalate etc.
Metadelphene (DEET) is the nineteen forty-two exploitation, and it has the repellent action of wide spectrum.As the mosquito repellent active ingredient that cost performance is the highest, be widely used at present.But a large amount of the use has the neural report of potential murder by poisoning.
Repefral (DMP) was brought into use from nineteen thirty, as plastic additive, with the composite repellant that can be used as of other repellants, but because excitant is bigger, had not now recommended to use.
It is also very long that vegetable oil is used for the applicating history of mosquito repellent.Citronella oil, eucalyptus citriodora oil, Chinese mugwort wet goods are traditional good side of mosquito repellent among the people.One-tenth branch in the vegetable oil disturbs the insect olfaction reaction information, thereby the target localization ability of obscuring insect is to reach repelling effect.
Summary of the invention
The purpose of this invention is to provide a kind of preparation that contains natural anophelifuge essence, its repelling effect is good, safety is higher.
Technical scheme of the present invention is: a kind of preparation that contains natural anophelifuge essence, it includes Metadelphene, natural anophelifuge essence.
The weight percent content of described Metadelphene in total prescription is 2.0%～10.0%, and the weight percent content of described natural anophelifuge essence in total prescription is 0.5%～6.0%.
It also includes weight percent content is 30%～40% ethanol.
Contain at least two kinds in the following material in the described natural anophelifuge essence: patchouli oil, lemon oil, cinnamon oil, pelargonium oil, lavender oil, citronella oil, eucalyptus citriodora leaf oil, cloves oil, geranium oil, rosemary oil, pine needle oil.
The present invention compared with prior art has following advantage:
Adopt Metadelphene DEET, natural anophelifuge essence composite, reaching under the situation of same repelling effect, reduce the addition of Metadelphene DEET greatly, thereby make product safer, and because the natural anophelifuge essence composition contains two kinds or two kinds of later compositions that are selected from patchouli oil, lemon oil, cinnamon oil, pelargonium oil, lavender oil, citronella oil, eucalyptus citriodora leaf oil, cloves oil, geranium oil, rosemary oil, the pine needle oil, so have natural fragrance.
Efficacy testing
(1) for examination worm kind and strain
Aedes albopictus (Aedes albopictus), the normal strain of indoor long-term raising, the back of sprouting wings was not sucked blood female adult mosquito in 4～5 days for measuring.
(2) assay method (GB/T 17322.10-1998)
1, attack test
Growing * wide * high for putting into 300 examination worms in the mosquito cage of 40cm * 30cm * 40cm; after waiting to try worm recovery normal activity; the back of the hand is exposed 4cm * 4cm skin; all the other total points are tightly covered; hand stretches in the mosquito cage and places 2min; the examination worm that comes to stop falling is qualified for attack more than 30 persons, and this person and this cage mosquito can be used for repellency test.
2, repellency test
At respectively the draw skin area of 5cm * 5cm of the both hands back of 3 attack eligibles, wherein a hand is a blank, and the another hand is evenly smeared by the dosage of 1.5 ц L/cm2, wherein expose for surveying coating skin 4cm * 4cm, tightly cover remainder.Smear repellant after 2 hours, hand is stretched into be placed with 2min in the qualified mosquito cage of attack, observe and to have or not mosquito to come to suck blood, later on once, make repellant and lost efficacy as long as have a mosquito to come to suck blood promptly to declare every test half an hour.
3, result
The result after tested, this pharmaceutical formulation sample can reach 9 hours to effective mosquito repellent guard time of aedes albopictus, and the sample that does not add anophelifuge essence in contrast has only 7 hours to effective mosquito repellent guard time of aedes albopictus.
(3), analysis and summary
From above instance analysis as can be seen, do not improving Metadelphene (DEET) consumption, promptly do not increasing under the situation of product toxicity, effectively composite by natural anophelifuge essence and DEET can significantly improve the mosquito repellent usefulness of product.
Embodiment
The present invention is further elaborated below in conjunction with concrete case study on implementation, but these cases never are as any restriction of the present invention.
Contain Metadelphene DEET 5.0%, natural anophelifuge essence 3.0%, propane diols 10.0%, solubilizer (for example polysorbas20 or APEO 40 hydrogenated castor greases) 1.0%, menthol 0.3%, alcohol 40.0%, surplus is a deionized water, more than all be weight percentage.
Claims (4)
1. preparation that contains natural anophelifuge essence, it is characterized in that: it includes Metadelphene, natural anophelifuge essence.
2, according to according to the described preparation that contains natural anophelifuge essence of claim 1, it is characterized in that: the weight percent content of described Metadelphene in total prescription is 2.0%～10.0%, and the weight percent content of described natural anophelifuge essence in total prescription is 0.5%～6.0%.
3, according to according to the described preparation that contains natural anophelifuge essence of claim 2, it is characterized in that: it also includes weight percent content is 30%～40% ethanol.
4, according to according to the described preparation that contains natural anophelifuge essence of claim 1, it is characterized in that: contain at least two kinds in the following material in the described natural anophelifuge essence: patchouli oil, lemon oil, cinnamon oil, pelargonium oil, lavender oil, citronella oil, eucalyptus citriodora leaf oil, cloves oil, geranium oil, rosemary oil, pine needle oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2005100949506A CN1745640A (en) | 2005-10-18 | 2005-10-18 | Preparation containing natural anophelifuge essence |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2005100949506A CN1745640A (en) | 2005-10-18 | 2005-10-18 | Preparation containing natural anophelifuge essence |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1745640A true CN1745640A (en) | 2006-03-15 |
Family
ID=36165487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005100949506A Pending CN1745640A (en) | 2005-10-18 | 2005-10-18 | Preparation containing natural anophelifuge essence |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1745640A (en) |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101810203A (en) * | 2010-04-15 | 2010-08-25 | 上海应用技术学院 | Solid mosquito repelling agent and preparation method thereof |
| CN101843914A (en) * | 2010-04-30 | 2010-09-29 | 吴杰 | Composition with air disinfection function |
| CN102512609A (en) * | 2011-12-27 | 2012-06-27 | 浙江景岳堂药业有限公司 | Essential oil with anti-inflammatory, analgesic, cooling, itching-relieving and mosquito-dispelling functions |
| CN102551580A (en) * | 2012-01-12 | 2012-07-11 | 杭州国光旅游用品有限公司 | Multifunctional moist towelette |
| CN101700214B (en) * | 2009-11-25 | 2012-08-01 | 中国人民武装警察部队后勤学院 | Mosquito repelling liquid |
| CN101669529B (en) * | 2009-10-19 | 2012-08-15 | 广州百花香料股份有限公司 | Perfumed mosquito repellent composition |
| CN101558770B (en) * | 2009-05-14 | 2013-04-24 | 西北农林科技大学无公害农药研究服务中心 | Plant source mosquito incense synergistic agent |
| CN103931668A (en) * | 2014-04-08 | 2014-07-23 | 许银亚 | Liquid mosquito-repellent incense |
| CN104336090A (en) * | 2014-09-28 | 2015-02-11 | 句容市石狮冲压件厂 | Special outdoor mosquito repellent and preparation method thereof |
| CN106137842A (en) * | 2016-08-03 | 2016-11-23 | 南安辰光日用化工品有限公司 | A kind of anophelifuge floral water containing plant component |
| CN106172520A (en) * | 2016-07-31 | 2016-12-07 | 黄劼 | Mosquito-repellent water |
| CN106215210A (en) * | 2016-07-31 | 2016-12-14 | 唐玥琳 | Anthelmintic air freshener |
| CN106265168A (en) * | 2016-10-11 | 2017-01-04 | 济南大学 | A kind of preparation method of natural composite plant mosquito-driving liquid antibacterial, antipruritic |
| CN106342955A (en) * | 2016-08-30 | 2017-01-25 | 四川达文西科技有限公司 | Health-care and tranquilizing repellent liquid |
| CN106342942A (en) * | 2016-07-27 | 2017-01-25 | 天峨县全盛蜂业科技有限公司 | Plant-sourced mosquito-repellent incense and preparation method thereof |
| CN106376620A (en) * | 2016-08-30 | 2017-02-08 | 四川达文西科技有限公司 | Tranquillizing mosquito-repellent liquid |
| CN106880517A (en) * | 2015-12-15 | 2017-06-23 | 林康艺 | A kind of mosquito-proof essential oil composition and preparation method thereof |
| CN106879647A (en) * | 2015-12-15 | 2017-06-23 | 林康艺 | A kind of clear novel mosquito repellent incense liquid |
| CN107223671A (en) * | 2017-06-05 | 2017-10-03 | 福建春辉生物工程有限公司 | A kind of antibacterial type is refreshed oneself mosquito-repellent incense |
| CN107455398A (en) * | 2016-09-07 | 2017-12-12 | 安徽香杰香精科技有限公司 | A kind of antifatigue mosquito repellent compound essential oil |
| CN107638313A (en) * | 2017-09-04 | 2018-01-30 | 上海千紫香料有限公司 | A kind of mosquito-repellent essential oil and preparation method thereof |
| CN108078814A (en) * | 2016-11-21 | 2018-05-29 | 广州环亚化妆品科技有限公司 | A kind of plant fragrance fluid composition with mosquito repellent function and its application in cosmetics |
| CN108850005A (en) * | 2018-05-27 | 2018-11-23 | 贵州省雷山县萌牛文创发展有限公司 | A kind of anophelifuge and preparation method thereof with Miao ethnic group's characteristic |
| CN108969445A (en) * | 2018-10-10 | 2018-12-11 | 南通季德胜科技有限公司 | It is a kind of can mosquito repellent detumescence strong skin water and method |
| CN109090109A (en) * | 2018-06-06 | 2018-12-28 | 钱龙风 | A kind of mosquito repellent pastes with oneself |
| CN110433102A (en) * | 2019-09-06 | 2019-11-12 | 上海中华药业有限公司 | A kind of mosquito repellent lotion and preparation method thereof |
| CN112262858A (en) * | 2020-09-30 | 2021-01-26 | 深圳市妇幼保健院 | Mosquito-repellent essential oil |
-
2005
- 2005-10-18 CN CNA2005100949506A patent/CN1745640A/en active Pending
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101558770B (en) * | 2009-05-14 | 2013-04-24 | 西北农林科技大学无公害农药研究服务中心 | Plant source mosquito incense synergistic agent |
| CN101669529B (en) * | 2009-10-19 | 2012-08-15 | 广州百花香料股份有限公司 | Perfumed mosquito repellent composition |
| CN101700214B (en) * | 2009-11-25 | 2012-08-01 | 中国人民武装警察部队后勤学院 | Mosquito repelling liquid |
| CN101810203A (en) * | 2010-04-15 | 2010-08-25 | 上海应用技术学院 | Solid mosquito repelling agent and preparation method thereof |
| CN101843914A (en) * | 2010-04-30 | 2010-09-29 | 吴杰 | Composition with air disinfection function |
| CN101843914B (en) * | 2010-04-30 | 2013-04-03 | 吴杰 | Composition with air disinfection function |
| CN102512609A (en) * | 2011-12-27 | 2012-06-27 | 浙江景岳堂药业有限公司 | Essential oil with anti-inflammatory, analgesic, cooling, itching-relieving and mosquito-dispelling functions |
| CN102551580B (en) * | 2012-01-12 | 2014-09-10 | 杭州国光旅游用品有限公司 | Multifunctional moist towelette |
| CN102551580A (en) * | 2012-01-12 | 2012-07-11 | 杭州国光旅游用品有限公司 | Multifunctional moist towelette |
| CN103931668A (en) * | 2014-04-08 | 2014-07-23 | 许银亚 | Liquid mosquito-repellent incense |
| CN104336090A (en) * | 2014-09-28 | 2015-02-11 | 句容市石狮冲压件厂 | Special outdoor mosquito repellent and preparation method thereof |
| CN106879647A (en) * | 2015-12-15 | 2017-06-23 | 林康艺 | A kind of clear novel mosquito repellent incense liquid |
| CN106880517A (en) * | 2015-12-15 | 2017-06-23 | 林康艺 | A kind of mosquito-proof essential oil composition and preparation method thereof |
| CN106342942A (en) * | 2016-07-27 | 2017-01-25 | 天峨县全盛蜂业科技有限公司 | Plant-sourced mosquito-repellent incense and preparation method thereof |
| CN106172520A (en) * | 2016-07-31 | 2016-12-07 | 黄劼 | Mosquito-repellent water |
| CN106215210A (en) * | 2016-07-31 | 2016-12-14 | 唐玥琳 | Anthelmintic air freshener |
| CN106137842A (en) * | 2016-08-03 | 2016-11-23 | 南安辰光日用化工品有限公司 | A kind of anophelifuge floral water containing plant component |
| CN106342955A (en) * | 2016-08-30 | 2017-01-25 | 四川达文西科技有限公司 | Health-care and tranquilizing repellent liquid |
| CN106376620A (en) * | 2016-08-30 | 2017-02-08 | 四川达文西科技有限公司 | Tranquillizing mosquito-repellent liquid |
| CN107455398A (en) * | 2016-09-07 | 2017-12-12 | 安徽香杰香精科技有限公司 | A kind of antifatigue mosquito repellent compound essential oil |
| CN106265168A (en) * | 2016-10-11 | 2017-01-04 | 济南大学 | A kind of preparation method of natural composite plant mosquito-driving liquid antibacterial, antipruritic |
| CN108078814A (en) * | 2016-11-21 | 2018-05-29 | 广州环亚化妆品科技有限公司 | A kind of plant fragrance fluid composition with mosquito repellent function and its application in cosmetics |
| CN107223671A (en) * | 2017-06-05 | 2017-10-03 | 福建春辉生物工程有限公司 | A kind of antibacterial type is refreshed oneself mosquito-repellent incense |
| CN107638313A (en) * | 2017-09-04 | 2018-01-30 | 上海千紫香料有限公司 | A kind of mosquito-repellent essential oil and preparation method thereof |
| CN108850005A (en) * | 2018-05-27 | 2018-11-23 | 贵州省雷山县萌牛文创发展有限公司 | A kind of anophelifuge and preparation method thereof with Miao ethnic group's characteristic |
| CN109090109A (en) * | 2018-06-06 | 2018-12-28 | 钱龙风 | A kind of mosquito repellent pastes with oneself |
| CN108969445A (en) * | 2018-10-10 | 2018-12-11 | 南通季德胜科技有限公司 | It is a kind of can mosquito repellent detumescence strong skin water and method |
| CN110433102A (en) * | 2019-09-06 | 2019-11-12 | 上海中华药业有限公司 | A kind of mosquito repellent lotion and preparation method thereof |
| CN112262858A (en) * | 2020-09-30 | 2021-01-26 | 深圳市妇幼保健院 | Mosquito-repellent essential oil |
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