CN1695750A - Pyrotechnic aerosol, dry powder fire extinguishing agent composite fire extinguishing device - Google Patents
Pyrotechnic aerosol, dry powder fire extinguishing agent composite fire extinguishing device Download PDFInfo
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- CN1695750A CN1695750A CN 200510082726 CN200510082726A CN1695750A CN 1695750 A CN1695750 A CN 1695750A CN 200510082726 CN200510082726 CN 200510082726 CN 200510082726 A CN200510082726 A CN 200510082726A CN 1695750 A CN1695750 A CN 1695750A
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- 239000000443 aerosol Substances 0.000 title claims abstract description 58
- 239000000843 powder Substances 0.000 title claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 title claims description 38
- 239000002131 composite material Substances 0.000 title claims description 6
- 238000001816 cooling Methods 0.000 claims abstract description 33
- 239000000126 substance Substances 0.000 claims abstract description 17
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 12
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004005 microsphere Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 6
- 235000010333 potassium nitrate Nutrition 0.000 claims abstract description 6
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 6
- 238000007789 sealing Methods 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 3
- 238000002485 combustion reaction Methods 0.000 claims description 16
- 239000002826 coolant Substances 0.000 claims description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 230000003139 buffering effect Effects 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000011257 shell material Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910001234 light alloy Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008275 solid aerosol Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
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- Fire-Extinguishing Compositions (AREA)
Abstract
Description
所属技术领域Technical field
本发明涉及一种新型灭火装置,是一种综合利用烟火热气溶胶和干粉灭火剂复合灭火效能的灭火装置。The invention relates to a novel fire extinguishing device, which is a fire extinguishing device which comprehensively utilizes the combined fire extinguishing efficiency of pyrotechnic aerosol and dry powder fire extinguishing agent.
技术背景technical background
气溶胶灭火装置是近年来迅速发展起来的新型灭火器材,由于它体积小、灭火效果好被广泛应用。众所周知,灭火气溶胶是一种由烟火药燃烧产生的N2、CO2、H2O蒸汽等气体与金属氧化物微粒构成的气——固型气溶胶,气溶胶中不可避免地存在一定比例地有害气体如CO、NO、HCN、NH3等。一般烟火气溶胶灭火剂燃烧产物温度通常在800~1000℃之间,而为保证不对被保护空间物品产生热损害,实际使用的烟火气溶胶灭火装置要求气溶胶出口温度控制在100~200℃,因此烟火气溶胶灭火装置中一般都设计有吸热、降温和净化过滤装置,例如CN2313619Y中公开的一种气溶胶灭火装置中采用铁球、石球构成吸热降温层;CN1319441中用金属及非金属材料构成冷却层,用以降低气溶胶温度;CN2558404Y中采用了化学降温材料(氨盐、碳酸盐、氯化物及其混合物)进行阻火降温;但这类技术虽然可以降温,但却是一种消极的技术措施,没有尽可能利用气溶胶降温过程释放的能量。Aerosol fire extinguishing device is a new type of fire extinguishing equipment developed rapidly in recent years. It is widely used because of its small size and good fire extinguishing effect. As we all know, fire extinguishing aerosol is a gas-solid aerosol composed of N 2 , CO 2 , H 2 O vapor and metal oxide particles produced by the combustion of pyrotechnic powder. Harmful gases such as CO, NO, HCN, NH 3 and so on. Generally, the temperature of the combustion product of pyrotechnic aerosol fire extinguishing agent is usually between 800-1000°C, and in order to ensure that no thermal damage is caused to the objects in the protected space, the actual use of pyrotechnic aerosol fire extinguishing devices requires that the aerosol outlet temperature be controlled at 100-200°C. Therefore heat absorption, cooling and purification filter devices are generally designed in the pyrotechnic aerosol fire extinguishing device, for example, iron balls and stone balls are used to form the heat absorption and cooling layer in a kind of aerosol fire extinguishing device disclosed in CN2313619Y; The metal material constitutes the cooling layer to reduce the temperature of the aerosol; CN2558404Y adopts chemical cooling materials (ammonia salts, carbonates, chlorides and mixtures thereof) to prevent fire and reduce the temperature; although this type of technology can reduce the temperature, it is A negative technical measure that does not utilize the energy released during the aerosol cooling process as much as possible.
发明内容Contents of the invention
本发明的目的是为了克服现有技术中的不足,提供一种阻火降温式高效烟火气溶胶灭火装置。它采用新型的降温材料,能有效降低燃气出口温度,并利用燃气作为干粉灭火剂的喷洒和分散动力源,将热气溶胶和冷气溶胶相结合,增加了气溶胶中灭火组分的含量,提高了灭火效果。The object of the present invention is to provide a high-efficiency pyrotechnic aerosol fire extinguishing device of fire-blocking and cooling type in order to overcome the deficiencies in the prior art. It adopts a new type of cooling material, which can effectively reduce the gas outlet temperature, and uses gas as the power source for spraying and dispersing dry powder fire extinguishing agent, combines hot aerosol and cold aerosol, increases the content of fire extinguishing components in aerosol, and improves the Fire extinguishing effect.
本发明解决其技术问题所采用的技术方案是:与现有技术相比,本装置不仅采用了新的烟火气溶胶灭火剂和冷却剂,还特别设计了干粉灭火剂组件,首次实现了化学和物理相结合的气溶胶形成方法。热气溶胶灭火剂药柱采用等截面压铸,点火药为黑火药,点火方式为电点火。点火器接收到启动信号后点燃黑火药并引燃灭火剂药柱,药柱燃烧产生的高温灭火气溶胶进入化学冷却室,化学冷却室内填充有直径2~3mm的硝酸钾和碳酸钾混合物制造的微球,硝酸钾保证气溶胶充分燃烧、完全氧化还原,从而降低气溶胶灭火剂的毒性,降低气溶胶灭火剂的颗粒,碳酸钾分解吸热降低气溶胶灭火剂温度。在化学冷却室通过不同温度条件下特定的氧化或还原催化剂的作用尽可能减少灭火气溶胶中有害气体的含量,同时充分利用气溶胶降温过程的余热,增加灭火物质的产出量。经过充分氧化或还原,较低温度的灭火气溶胶进入物理冷却室,物理冷却室内填充0.5~1mm的三氧化二铝微球,可使灭火气溶胶进一步冷却至低于150℃,达到使用要求。物理冷却室还有过滤功能,过滤掉较大的固体残渣,净化灭火气溶胶。热气溶胶灭火剂从物理冷却室喷出时仍然具有较高的压力,可以利用其动能带动干粉灭火剂,以较高的速度从喷口喷出,喷撒在燃烧物表面起到多重灭火效果,以提高灭火效率。The technical solution adopted by the present invention to solve its technical problems is: compared with the prior art, this device not only adopts a new pyrotechnic aerosol fire extinguishing agent and coolant, but also specially designs a dry powder fire extinguishing agent assembly, realizing the chemical and Physically combined aerosol-forming methods. The hot aerosol fire extinguishing agent powder column adopts equal cross-section die-casting, the ignition powder is black powder, and the ignition method is electric ignition. After the igniter receives the start signal, the black powder is ignited and the fire extinguishing agent powder column is ignited. The high temperature fire extinguishing aerosol produced by the powder column combustion enters the chemical cooling chamber, which is filled with a mixture of potassium nitrate and potassium carbonate with a diameter of 2 to 3 mm. Microspheres and potassium nitrate ensure that the aerosol is fully burned and completely oxidized and reduced, thereby reducing the toxicity of the aerosol fire extinguishing agent and reducing the particles of the aerosol fire extinguishing agent. Potassium carbonate decomposes and absorbs heat to reduce the temperature of the aerosol fire extinguishing agent. In the chemical cooling chamber, the content of harmful gases in the fire extinguishing aerosol is reduced as much as possible through the action of specific oxidation or reduction catalysts under different temperature conditions, and at the same time, the waste heat of the aerosol cooling process is fully utilized to increase the output of fire extinguishing substances. After full oxidation or reduction, the lower temperature fire extinguishing aerosol enters the physical cooling chamber, and the physical cooling chamber is filled with 0.5-1mm aluminum oxide microspheres, which can further cool the fire extinguishing aerosol to below 150°C, meeting the use requirements. The physical cooling chamber also has a filtering function to filter out larger solid residues and purify the fire extinguishing aerosol. When the hot aerosol fire extinguishing agent is sprayed from the physical cooling chamber, it still has a high pressure, and its kinetic energy can be used to drive the dry powder fire extinguishing agent to spray out from the nozzle at a high speed, and it can be sprayed on the surface of the burning object to achieve multiple fire extinguishing effects. Improve fire extinguishing efficiency.
本发明的有益效果是:The beneficial effects of the present invention are:
1.采用硝酸钾和碳酸钾混合物作为进一步氧化和冷却剂,可降低灭火气溶胶的毒性,增加灭火物质的产出量,降低气溶胶的温度。1. Using a mixture of potassium nitrate and potassium carbonate as a further oxidation and cooling agent can reduce the toxicity of the fire extinguishing aerosol, increase the output of fire extinguishing substances, and reduce the temperature of the aerosol.
2.物理冷却室后设置了干粉灭火剂组件,充分利用热气溶胶的动能,带动干粉灭火剂一起从出口喷出,产生多重灭火效果,提高了灭火效率。2. A dry powder fire extinguishing agent assembly is installed behind the physical cooling chamber, making full use of the kinetic energy of the hot aerosol to drive the dry powder fire extinguishing agent to spray out from the outlet together, producing multiple fire extinguishing effects and improving fire extinguishing efficiency.
附图说明Description of drawings
图1是烟火气溶胶、干粉灭火剂复合灭火装置结构示意图。Fig. 1 is a structural schematic diagram of a composite fire extinguishing device of pyrotechnic aerosol and dry powder fire extinguishing agent.
图中:1.点火器;2.端盖;3.外壳;4.燃烧室(气溶胶灭火剂);5.中间连接件;6.滤网;7.化学冷却室(化学冷却剂);8.物理冷却室(物理冷却剂);9.干粉灭火剂;10.压力缓冲室;11.密封膜;12喷口。In the figure: 1. Igniter; 2. End cover; 3. Shell; 4. Combustion chamber (aerosol fire extinguishing agent); 5. Intermediate connector; 6. Filter screen; 7. Chemical cooling chamber (chemical coolant); 8. Physical cooling chamber (physical coolant); 9. Dry powder fire extinguishing agent; 10. Pressure buffer chamber; 11. Sealing film; 12 nozzles.
具体实施方式Detailed ways
在图1中,点火器(1)、端盖(2)、外壳(3)、燃烧室(4)、中间连接件(5)、滤网(6)、化学冷却室(7)、物理冷却室(8)、干粉灭火剂(9)、压力缓冲室(10)、密封膜(11)、喷口(12)依次轴向排列组成烟火气溶胶、干粉灭火剂复合灭火装置。外壳(3)为圆筒型结构,并采用焊接加工工艺制造,具有较高的耐压能力。其端盖(2)采用螺纹结构,与圆筒状外壳(3)连接,为保证气体发生器的整体气密性,连接处采用紫铜高温高压密封垫密封,两个外壳(3)由中间连接件螺纹连接,喷口与外壳之间亦采用螺纹连接。点火器(1)可采用通用的电点火器,采用螺纹连接从端盖轴心处插入至燃烧室(4)底部点火,使得燃烧室(4)内气溶胶灭火剂尽量沿轴向作层面燃烧,从而降低产气速度和燃烧室(4)内压力。In Fig. 1, igniter (1), end cover (2), shell (3), combustion chamber (4), intermediate connector (5), filter screen (6), chemical cooling chamber (7), physical cooling The chamber (8), the dry powder fire extinguishing agent (9), the pressure buffer chamber (10), the sealing film (11), and the nozzle (12) are axially arranged in sequence to form a pyrotechnic aerosol and dry powder fire extinguishing agent composite fire extinguishing device. The shell (3) is a cylindrical structure, and is manufactured by welding process, so it has high pressure resistance. The end cover (2) adopts a threaded structure and is connected with the cylindrical shell (3). In order to ensure the overall airtightness of the gas generator, the joint is sealed with a copper high-temperature and high-pressure gasket, and the two shells (3) are connected by the middle The parts are threaded, and the spout and the shell are also threaded. The igniter (1) can be a common electric igniter, which is inserted from the shaft center of the end cover to the bottom of the combustion chamber (4) to ignite by threaded connection, so that the aerosol fire extinguishing agent in the combustion chamber (4) can burn as much as possible along the axial direction , thereby reducing the gas production rate and the internal pressure of the combustion chamber (4).
燃烧室(4)、化学冷却室(7)和物理冷却室(8)串连排列于圆筒型外壳(3)内,它们之间用滤网(6a、6b、6c、6d)隔开,滤网由多层24目不锈钢和带孔钢板组成。燃烧室(4)内装填烟火气溶胶灭火剂。气溶胶灭火剂产生的气体无毒,低腐蚀性,符合大气安全标准。化学冷却室(7)内装填化学冷却剂,选用直径2~3mm的硝酸钾和碳酸钾混合物制造的微球,在此室里一方面可使气溶胶二次充分燃烧氧化,从而降低气溶胶产物中的CO、NO、HCN、NH3等有毒气体,另一方面二次燃烧氧化还原还增加了大量有利于灭火的气溶胶气体,完成气溶胶能量得到了最大程度的利用。物理冷却室(8)内装填物理冷却剂,选用直径0.5~1mm三氧化二铝微球,气溶胶灭火剂在此室得到了充分的过滤、吸附和降温。物理冷却室(8)后设置干粉灭火剂组件(9),具有较高压力的灭火气溶胶带动干粉灭火剂,进入其后的压力缓冲室,当压力超过密封膜(11)破膜压力后,密封膜破裂,最后带有干粉灭火剂的灭火气溶胶以较高的速度由排气口(12)喷出。The combustion chamber (4), the chemical cooling chamber (7) and the physical cooling chamber (8) are arranged in series in the cylindrical shell (3), separated by screens (6a, 6b, 6c, 6d) between them, The filter screen is composed of multi-layer 24 mesh stainless steel and perforated steel plate. The pyrotechnic aerosol fire extinguishing agent is filled in the combustion chamber (4). The gas produced by the aerosol fire extinguishing agent is non-toxic, low corrosive, and meets atmospheric safety standards. The chemical cooling chamber (7) is filled with chemical coolant, and microspheres made of a mixture of potassium nitrate and potassium carbonate with a diameter of 2 to 3 mm are selected. On the one hand, in this chamber, the aerosol can be fully burned and oxidized for the second time, thereby reducing the aerosol product. CO, NO, HCN, NH 3 and other toxic gases in the combustion, on the other hand, the secondary combustion redox also increases a large amount of aerosol gas that is beneficial to fire extinguishing, and the aerosol energy is utilized to the greatest extent. The physical cooling chamber (8) is filled with a physical coolant, aluminum oxide microspheres with a diameter of 0.5 to 1 mm are selected, and the aerosol fire extinguishing agent is fully filtered, adsorbed and cooled in this chamber. A dry powder fire extinguishing agent assembly (9) is arranged behind the physical cooling chamber (8), and the fire extinguishing aerosol with relatively high pressure moves the dry powder fire extinguishing agent into the subsequent pressure buffer chamber. When the pressure exceeds the rupture pressure of the sealing membrane (11), The sealing film ruptures, and finally the fire extinguishing aerosol with dry powder fire extinguishing agent is ejected by the exhaust port (12) at a higher speed.
该装置的灭火机理:灭火时,启动点火器(1),通过黑火药点燃气溶胶灭火剂药柱(4),药剂在燃烧室充分燃烧,气溶胶在化学冷却室内充分氧化、还原,在化学冷却室、物理冷却室得到充分冷却、降温、过滤,最后带动干粉灭火剂从喷口喷出符合要求的气溶胶、干粉复合灭火剂进行有效灭火。灭火机制既有化学抑制作用(消耗燃烧反应必需的自由基),也有物理隔离作用(气溶胶中的惰性成分将燃料和空气隔开)。The fire extinguishing mechanism of this device: when extinguishing a fire, start the igniter (1), ignite the aerosol fire extinguishing agent grain (4) through the black powder, the agent is fully burned in the combustion chamber, the aerosol is fully oxidized and reduced in the chemical cooling chamber, The cooling chamber and physical cooling chamber are fully cooled, cooled, and filtered, and finally the dry powder fire extinguishing agent is driven to spray out the aerosol and dry powder composite fire extinguishing agent that meet the requirements from the nozzle to effectively extinguish the fire. Fire suppression mechanisms are both chemical inhibition (consuming the free radicals necessary for the combustion reaction) and physical isolation (inert components in the aerosol separate the fuel from the air).
本发明中,整个壳体设计为可重复使用结构,每次使用后将烟火气溶胶、干粉灭火剂复合灭火装置壳体内反应物残渣清理干净,更换化学药剂即可重复使用。壳体材料选用钢材或其它高强度轻质合金材料。In the present invention, the entire shell is designed as a reusable structure. After each use, the pyrotechnic aerosol and dry powder fire extinguishing agent composite fire extinguishing device shell is cleaned of reactant residues, and the chemical agent can be replaced for repeated use. The shell material is made of steel or other high-strength light alloy materials.
本发明中,输出气溶胶的平均温度低于100℃。In the present invention, the average temperature of the output aerosol is lower than 100°C.
Claims (7)
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| CN 200510082726 CN1695750A (en) | 2005-07-11 | 2005-07-11 | Pyrotechnic aerosol, dry powder fire extinguishing agent composite fire extinguishing device |
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| CN 200510082726 CN1695750A (en) | 2005-07-11 | 2005-07-11 | Pyrotechnic aerosol, dry powder fire extinguishing agent composite fire extinguishing device |
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Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008086680A1 (en) * | 2007-01-05 | 2008-07-24 | Shaanxi J&R Fire Fighting Co., Ltd | Bi-directional horizontal spraying aerosol fire-extinguishing apparatus |
| CN101850164A (en) * | 2009-04-02 | 2010-10-06 | 湖北卫东机械化工有限公司 | Hand-thrown aerosol fire extinguisher |
| CN102179026A (en) * | 2010-09-16 | 2011-09-14 | 陕西坚瑞消防股份有限公司 | Fire extinguishing composition generating extinguishant by pyrolysis |
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| CN113134209B (en) * | 2020-01-20 | 2025-07-11 | 湖北及安盾消防科技有限公司 | Fire extinguishing equipment |
| RU2763285C2 (en) * | 2020-06-26 | 2021-12-28 | Фей Зуан Лимитед | Fire extinguishing aerosol generator |
| CN114177559A (en) * | 2021-12-15 | 2022-03-15 | 中国矿业大学 | Fire CO synchronous disposal method coupling suffocation fire extinguishing and catalytic oxidation |
| CN114534635A (en) * | 2022-02-25 | 2022-05-27 | 安徽理工大学 | Gas generator for non-pressure storage type dry powder fire extinguisher |
| CN114602097A (en) * | 2022-03-17 | 2022-06-10 | 湖南神州防务科技有限公司 | Fighting part for fire extinguishing bomb for high-rise building |
| WO2024174380A1 (en) * | 2023-02-22 | 2024-08-29 | 湖北及安盾消防科技有限公司 | Aerosol fire extinguishing device provided with gas flow dividing disc and fire extinguishing method thereof |
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