CN1690177A - Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same - Google Patents
Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same Download PDFInfo
- Publication number
- CN1690177A CN1690177A CN 200410013731 CN200410013731A CN1690177A CN 1690177 A CN1690177 A CN 1690177A CN 200410013731 CN200410013731 CN 200410013731 CN 200410013731 A CN200410013731 A CN 200410013731A CN 1690177 A CN1690177 A CN 1690177A
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- CN
- China
- Prior art keywords
- oil
- crude oil
- emulsified
- orinoco crude
- minutes
- Prior art date
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- 239000003921 oil Substances 0.000 title claims abstract description 39
- 239000000654 additive Substances 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 239000000295 fuel oil Substances 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 51
- 230000000996 additive effect Effects 0.000 claims abstract description 33
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims abstract description 19
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 17
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 17
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005642 Oleic acid Substances 0.000 claims abstract description 17
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 17
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 17
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 17
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000010779 crude oil Substances 0.000 claims description 36
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 15
- 125000003917 carbamoyl group Chemical class [H]N([H])C(*)=O 0.000 claims description 15
- 239000012286 potassium permanganate Substances 0.000 claims description 15
- 229960004418 trolamine Drugs 0.000 claims description 15
- 239000000446 fuel Substances 0.000 claims description 14
- 230000004048 modification Effects 0.000 claims description 11
- 238000012986 modification Methods 0.000 claims description 11
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- 239000010762 marine fuel oil Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 230000003068 static effect Effects 0.000 claims description 10
- 238000003786 synthesis reaction Methods 0.000 claims description 10
- 238000000151 deposition Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 125000005608 naphthenic acid group Chemical group 0.000 claims description 5
- 238000010008 shearing Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000005496 tempering Methods 0.000 claims description 5
- -1 carbonyl amine Chemical class 0.000 abstract 2
- 239000010747 number 6 fuel oil Substances 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 1
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- Liquid Carbonaceous Fuels (AREA)
Abstract
A modifying additive of soluble oil, modifying bunker fuel oil, and the manufacturing technique. Soluble oil is used early at home and abroad, but poor stability, being easily layered and demulsified in use affects the service effect. The component of modifying additive of soluble oil contains naphthenic acid, and the related additive also contains oleic acid, carbonyl amine, triethanolamine, isoamyl alcohol or methanol, kalii permangana, spans-80, and the weight ratio being that, naphthenic acid 39, oleic acid 15, carbonyl amine 5, triethanolamine 8 to 15, isoamyl alcohol or methanol 12 to 20, kalii permangana 5, and spans-80 10 to 15. The product can apply in bunker fuel.
Description
Technical field: the present invention relates to a kind of emulsified orinoco crude oil property-modifying additive and modification marine fuel oil thereof, also comprise the complete processing of this additive and oil fuel.
Background technology: oil in water emulsion is at home and abroad early utilized, and in use there is poor stability in oil in water emulsion, and easily layering, breakdown of emulsion influence result of use.
Summary of the invention: the purpose of this invention is to provide a kind of good stability, not stratified, not the emulsified orinoco crude oil property-modifying additive of breakdown of emulsion, modification marine fuel oil and manufacture craft.
The object of the present invention is achieved like this:
The emulsified orinoco crude oil property-modifying additive, its composition comprises: naphthenic acid, described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, and its ratio of weight and number is naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 8～15, primary isoamyl alcohol or methyl alcohol 12～20, potassium permanganate 5, Arlacel-80 10～15.
The complete processing of above-mentioned emulsified orinoco crude oil property-modifying additive, successively naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 are poured in the tempering tank by above-mentioned described parts by weight, under 10 ℃～30 ℃ temperature, stirred 10 minutes, its temperature is risen between 50 ℃～80 ℃, static 30 minutes, filter.
Above-mentioned emulsified orinoco crude oil is in the application of making on the modification marine fuel oil, and the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0
#Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0
#Solar oil 22.7, oli oil property-modifying additive 1.5.
The complete processing of above-mentioned emulsified orinoco crude oil modification marine fuel oil, described emulsified orinoco crude oil are filtered earlier before entering synthesis reactor, fine filtering again, leach diameter and be the particle between 10 μ m～30 μ m, smart more at last filter is by the pressure forced filtration of filter, make its particle diameter between 1 μ m～5 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered.
The invention has the advantages that:
1. emulsified orinoco crude oil property-modifying additive of the present invention is mainly used to allocate the emulsified orinoco crude oil modification marine diesel fuel that Venezuela produces, it is water in oil liquid that the emulsified orinoco crude oil property-modifying additive can change emulsified orinoco crude oil oil-in-water liquid modifying, improve intensity of combustion, be convenient to igniting.
2. this product uses this fuel not only capable of saving fuel, but also can improve mechanical efficiency as marine diesel fuel, reduces exhaust emissions.
3. the complete processing of this additive is simple, easily operation, and by the oil fuel good stability that this additive is made, surpass 1 year its steady time, and have and never degenerate, and not stratified, breakdown of emulsion can not reduce characteristics such as oil pour point.
The specific embodiment of the present invention:
Embodiment 1:
Emulsified orinoco crude oil property-modifying additive and complete processing thereof, its composition comprises: naphthenic acid, described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, its ratio of weight and number is a naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 8, primary isoamyl alcohol or methyl alcohol 12, potassium permanganate 5, Arlacel-80 10, its complete processing is: press above-mentioned described parts by weight successively with naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 is poured in the tempering tank, under 10 ℃ temperature, stirred 10 minutes, its temperature is risen to 50 ℃, static 30 minutes, filter barrelling.
Embodiment 2:
Emulsified orinoco crude oil property-modifying additive and complete processing thereof, its composition comprises: naphthenic acid, described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, its ratio of weight and number is a naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 15, primary isoamyl alcohol or methyl alcohol 20, potassium permanganate 5, Arlacel-80 15, its complete processing is: press above-mentioned described parts by weight successively with naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 is poured in the tempering tank, under 30 ℃ temperature, stirred 10 minutes, its temperature is risen to 80 ℃, static 30 minutes, filter barrelling.
Embodiment 3:
Emulsified orinoco crude oil property-modifying additive and complete processing thereof, its composition comprises: naphthenic acid, described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, its ratio of weight and number is a naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 12, primary isoamyl alcohol or methyl alcohol 16, potassium permanganate 5, Arlacel-80 13, its complete processing is: press above-mentioned described parts by weight successively with naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 is poured in the tempering tank, under 20 ℃ temperature, stirred 10 minutes, its temperature is risen to 70 ℃, static 30 minutes, filter barrelling.
Embodiment 4:
Emulsified orinoco crude oil modification marine fuel oil and complete processing thereof, the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0
#Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0
#Solar oil 22.7, oli oil property-modifying additive 1.5, its complete processing is: described emulsified orinoco crude oil filters earlier before entering synthesis reactor, fine filtering leaches the particle that diameter is 10 μ m again, smart more at last filter, pressure forced filtration by filter, making its particle diameter is 1 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered barrelling.
Embodiment 5:
Emulsified orinoco crude oil modification marine fuel oil and complete processing thereof, the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0
#Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0
#Solar oil 22.7, oli oil property-modifying additive 1.5, its complete processing is: described emulsified orinoco crude oil filters earlier before entering synthesis reactor, fine filtering leaches the particle that diameter is 30 μ m again, smart more at last filter, pressure forced filtration by filter, making its particle diameter is 5 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered barrelling.
Embodiment 6:
Emulsified orinoco crude oil modification marine fuel oil and complete processing thereof, the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0
#Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0
#Solar oil 22.7, oli oil property-modifying additive 1.5, its complete processing is: described emulsified orinoco crude oil filters earlier before entering synthesis reactor, fine filtering leaches the particle that diameter is 20 μ m again, smart more at last filter, pressure forced filtration by filter, making its particle diameter is 3 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered barrelling.
Claims (4)
1. emulsified orinoco crude oil property-modifying additive, its composition comprises: naphthenic acid, it is characterized in that: described additive also comprises oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80, and its ratio of weight and number is naphthenic acid 39, oleic acid 15, carboxamide 5, trolamine 8～15, primary isoamyl alcohol or methyl alcohol 12～20, potassium permanganate 5, Arlacel-80 10～15.
2. the complete processing of the described emulsified orinoco crude oil property-modifying additive of claim 1, it is characterized in that: successively naphthenic acid, oleic acid, carboxamide, trolamine, primary isoamyl alcohol or methyl alcohol, potassium permanganate, Arlacel-80 are poured in the tempering tank by above-mentioned described parts by weight, under 10 ℃～30 ℃ temperature, stirred 10 minutes, its temperature is risen between 50 ℃～80 ℃, static 30 minutes, filter.
3. the described emulsified orinoco crude oil of claim 1 is in the application of making on the modification marine fuel oil, and it is characterized in that: the main raw material of described oil fuel comprises emulsified orinoco crude oil, 0
#Solar oil, oli oil property-modifying additive, its ratio of weight and number are emulsified orinoco crude oil 75.8,0
#Solar oil 22.7, oli oil property-modifying additive 1.5.
4. the complete processing of the described emulsified orinoco crude oil modification of claim 3 marine fuel oil, it is characterized in that: described emulsified orinoco crude oil is before entering synthesis reactor, filter earlier, fine filtering again, leach diameter and be the particle between 10 μ m～30 μ m, smart more at last filter, pressure forced filtration by filter, make its particle diameter between 1 μ m～5 μ m, by above-mentioned described parts by weight each raw material is added in synthesis reactor, through high-speed shearing machine continuously stirring 10 minutes, promptly synthetic water-in-oil emulsified fuel, static depositing 30 minutes filtered.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410013731 CN1690177A (en) | 2004-04-30 | 2004-04-30 | Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410013731 CN1690177A (en) | 2004-04-30 | 2004-04-30 | Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1690177A true CN1690177A (en) | 2005-11-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410013731 Pending CN1690177A (en) | 2004-04-30 | 2004-04-30 | Modified additives for orinoco emulsified oil, modified fuel oil for ships and process for preparing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1690177A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7854774B2 (en) | 2006-05-26 | 2010-12-21 | Amyris Biotechnologies, Inc. | Fuel components, fuel compositions and methods of making and using same |
| CN101323802B (en) * | 2008-07-25 | 2011-06-08 | 西安祺祥能源科技发展有限公司 | Stable synergistic of methanol diesel for vehicle |
| US9200296B2 (en) | 2006-05-26 | 2015-12-01 | Amyris Inc. | Production of isoprenoids |
-
2004
- 2004-04-30 CN CN 200410013731 patent/CN1690177A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7854774B2 (en) | 2006-05-26 | 2010-12-21 | Amyris Biotechnologies, Inc. | Fuel components, fuel compositions and methods of making and using same |
| US9200296B2 (en) | 2006-05-26 | 2015-12-01 | Amyris Inc. | Production of isoprenoids |
| US10106822B2 (en) | 2006-05-26 | 2018-10-23 | Amyris, Inc. | Production of isoprenoids |
| CN101323802B (en) * | 2008-07-25 | 2011-06-08 | 西安祺祥能源科技发展有限公司 | Stable synergistic of methanol diesel for vehicle |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |