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CN1675985B - Farm film - Google Patents

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Publication number
CN1675985B
CN1675985B CN2005100598694A CN200510059869A CN1675985B CN 1675985 B CN1675985 B CN 1675985B CN 2005100598694 A CN2005100598694 A CN 2005100598694A CN 200510059869 A CN200510059869 A CN 200510059869A CN 1675985 B CN1675985 B CN 1675985B
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film
agricultural
micropores
thermoplastic resin
microns
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CN1675985A (en
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德永一丸
高泽孝
大林厚
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Mitsubishi Chemical Agri Dream Co Ltd
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Mitsubishi Chemical Agri Dream Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/14Greenhouses
    • A01G9/1407Greenhouses of flexible synthetic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/25Greenhouse technology, e.g. cooling systems therefor

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Protection Of Plants (AREA)
  • Laminated Bodies (AREA)
  • Greenhouses (AREA)

Abstract

本发明提供用于塑料棚中栽培、塑料隧道栽培等的内铺或外铺用的、防雾性和透湿性优异的农用薄膜。本发明涉及农用薄膜,其特征在于,其具有在热塑性树脂薄膜上利用具有刺状突起的针进行穿孔加工而得到的多个微细孔;或者其是具有多个微细孔的热塑性树脂,其特征在于,所述微细孔的形状是具有刺部的有刺形状,并且优选具有多个该微细孔的薄膜在555nm处的总透光率大于等于70%。

Figure 200510059869

The present invention provides an agricultural film excellent in anti-fogging properties and moisture permeability, which is used for inner or outer laying of cultivation in plastic sheds, cultivation in plastic tunnels, and the like. The present invention relates to an agricultural film, characterized in that it has a plurality of fine holes obtained by perforating a thermoplastic resin film with a needle having a thorn-like protrusion; or it is a thermoplastic resin with a plurality of fine holes, characterized in that , the shape of the micropores is a thorny shape with thorns, and preferably the total light transmittance at 555 nm of the film having a plurality of such micropores is greater than or equal to 70%.

Figure 200510059869

Description

农用薄膜Agricultural film

技术领域technical field

本发明涉及用于塑料棚中栽培和塑料隧道栽培等的内铺或外铺用的农用薄膜,尤其涉及防雾性和透湿性优异的农用薄膜。The present invention relates to an agricultural film for inner or outer covering of cultivation in plastic sheds and plastic tunnels, and in particular to an agricultural film excellent in anti-fog and moisture permeability.

背景技术Background technique

以往加速培育农作物的方法主要是在氯乙烯类树脂薄膜或烯烃类树脂薄膜等农用薄膜覆盖下,栽培植物,即塑料棚中栽培和塑料隧道栽培。In the past, the method of accelerating the cultivation of crops was mainly to cultivate plants under the cover of agricultural films such as vinyl chloride resin films or olefin resin films, that is, cultivation in plastic sheds and cultivation in plastic tunnels.

在这样的塑料棚中栽培和塑料隧道栽培等中,塑料棚和塑料隧道内的温度、湿度等对农作物的生长有很大的影响,所以有必要根据气候进行调整。In such plastic shed cultivation and plastic tunnel cultivation, etc., the temperature and humidity in the plastic shed and plastic tunnel have a great influence on the growth of crops, so it is necessary to adjust it according to the climate.

特别是近年来在大型塑料棚中栽培中,除固定铺展于大棚骨架的外铺用农用薄膜以外,在大棚内部,还使用内铺用农用薄膜作为所谓的遮荫材料或进一步覆盖农作物形状的整体遮荫材料。Especially in the cultivation of large-scale plastic greenhouses in recent years, in addition to the agricultural film for outer laying that is fixedly spread on the frame of the greenhouse, the agricultural film for inner laying is also used as a so-called shading material or as a whole that further covers the shape of the crops inside the greenhouse. shade material.

特别是这种内铺用农用薄膜,如果透湿性(透气性)低,则暖空气中的水蒸气充满薄膜内部,有可能导致作物遭受湿度过大的伤害。另外,水蒸气附着于薄膜内形成水滴,结果造成薄膜透明性下降,所以透湿性(透气性)和防雾性变得必要。In particular, if the moisture permeability (air permeability) of this kind of agricultural film for inner laying is low, the water vapor in the warm air will fill the inside of the film, which may cause damage to crops due to excessive humidity. In addition, water vapor adheres to the inside of the film to form water droplets, and as a result, the transparency of the film decreases, so moisture permeability (breathability) and anti-fogging properties become necessary.

另外,作为外铺用农用薄膜,优选除了具有防虫、防雨性以外,还具有透气性(透湿性)的薄膜,但现在尚未得到具有这样透气性的外铺用农用薄膜。外铺用农用薄膜的防雾性是重要的性能,以前,采取塑料棚铺展时在内侧面喷涂防雾剂的方法、在薄膜内侧面掺入表面活性剂的方法以及在薄膜内侧面涂布含有其它特殊无机微粒的涂布层的方法等,但这些方法需要花费人力和成本,而且得不到充分的防雾性。In addition, agricultural films for coverings are preferably films that have air permeability (moisture permeability) in addition to insect repellency and rain resistance, but agricultural films for coverings that have such air permeability have not yet been obtained. The anti-fogging property of the agricultural film used for spreading outside is an important performance. In the past, the method of spraying anti-fogging agent on the inner side when the plastic shed was spread, the method of mixing surfactants on the inner side of the film, and the method of coating the inner side of the film with There are other methods of coating layers of special inorganic fine particles, etc., but these methods require manpower and cost, and sufficient anti-fog properties cannot be obtained.

以前,在内铺用农用薄膜中使用具有透气性的农用材料无纺织物。无纺织物的透气性优异,但由白色不透明的原材料组成,所以存在透光率低的缺点,而在成长期光照对作物十分必要,所以不能使用这种原材料。Previously, non-woven fabrics of agricultural materials with air permeability were used in agricultural films for inlays. Non-woven fabrics have excellent air permeability, but they are composed of white opaque raw materials, so they have the disadvantage of low light transmittance, and they cannot be used because light is necessary for crops during the growth period.

还提出了几种在由合成树脂薄膜形成的无孔薄膜上设有透气孔和透水孔的农用薄膜。例如实开平5-74249号公报公开了设有直径小于等于1.5mm的透气孔并且透气孔的总面积占薄膜表面积的10%~60%的农用薄膜。实公平5-10598号公报公开了一种内铺遮荫用的农用有孔薄膜,其为了消除在外铺覆盖材料内侧面凝聚的水滴落到内铺遮荫布上后形成水流,即所谓的金鱼缸现象,在合成树脂薄膜上每1m2的面积上设有至少1个直径为1mm~4mm的通透孔,作为去除水的通透孔。并且作为其穿孔方法,还提出了用针穿孔的针穿孔法。There have also been proposed several agricultural films in which air-permeable holes and water-permeable holes are provided on a non-porous film formed of a synthetic resin film. For example, Japanese Unexamined Patent Publication No. 5-74249 discloses an agricultural film provided with vent holes with a diameter of 1.5 mm or less and the total area of the vent holes accounts for 10% to 60% of the surface area of the film. Publication No. 5-10598 discloses a kind of agricultural perforated film for shading in the inner shop. In order to eliminate the water droplets condensed on the inner side of the outer covering material and fall on the shade cloth in the inner shop to form water flow, the so-called gold For the fish tank phenomenon, at least one through hole with a diameter of 1 mm to 4 mm is provided on every 1 m 2 area of the synthetic resin film as a through hole for removing water. And as the perforation method, a needle perforation method of perforating with a needle has also been proposed.

但是以往的穿孔薄膜存在相互矛盾的问题,即为了达到防水和保温性,有必要减小孔的大小,然而这样会造成不能充分透气的缺点,但如果为确保透气性而增大透气孔的大小,则会出现降低防水防虫效果以及保温效果的问题。However, the conventional perforated films have contradictory problems, that is, in order to achieve waterproof and heat retention, it is necessary to reduce the size of the holes, but this will cause the disadvantage of not being able to breathe fully, but if the size of the air holes is increased to ensure air permeability , there will be problems that reduce the waterproof and insect-proof effect and the heat preservation effect.

发明内容Contents of the invention

本发明的目的是提供透明性不降低并且具有透湿性(透气性)、防雾性、防液滴附着性、保温性和防水防虫效果的农用薄膜。The object of the present invention is to provide an agricultural film having moisture permeability (breathability), anti-fogging properties, anti-droplet adhesion, heat retention and waterproof and insect-proof effects without reducing transparency.

本发明人等发现如果使用热塑性树脂薄膜上具有多个用特殊形状的针进行穿孔加工而形成的微细孔的有孔树脂薄膜,能实现上述本发明的目的,从而完成了本发明。The inventors of the present invention found that the object of the present invention can be achieved by using a thermoplastic resin film having a plurality of micropores formed by punching with a needle of a special shape, and completed the present invention.

即,本发明的主旨是(1)农用薄膜,其特征在于,具有多个利用具有刺状突起的针在热塑性树脂薄膜上进行穿孔加工而得的微细孔;或(2)农用薄膜,其特征在于,其是具有多个微细孔的热塑性树脂薄膜,并且该微细孔的形状是具有刺部的有刺形状;或(3)农用薄膜,其特征在于,其是具有多个微细孔的热塑性树脂薄膜,此微细孔通过针进行穿孔而得到,膜的一面的表面粗糙度Ra1和膜的另一面的表面粗糙度Ra2的关系是Ra1<Ra2,Ra2面是塑料棚或塑料隧道铺展时作为内侧的内侧面;或(4)如(1)或(2)所述的农用薄膜,其特征在于,具有多个微细孔,此微细孔是利用具有刺状突起的针从热塑性树脂薄膜的两侧进行穿孔加工而得到的;或(5)如(1)或(2)所述的农用薄膜,其特征在于,其是具有多个通过针穿孔而得的微细孔的热塑性树脂薄膜,膜的两面具有微小突起;或(6)如(1)~(5)任一项所述的农用薄膜,其特征在于,具有多个微细孔的薄膜在555nm的总透光率大于或等于70%;或(7)如(1)~(6)任一项所述的农用薄膜,其特征在于,构成热塑性树脂薄膜的树脂是氯乙烯类树脂或烯烃类树脂;或(8)如(1)~(7)任一项所述的农用薄膜,其特征在于,所述热塑性树脂薄膜是由至少具有外层、中间层、内层的三层或三层以上的多层结构构成的树脂薄膜,构成外层和/或内层的树脂至少含有金属茂类聚乙烯树脂。That is, the gist of the present invention is (1) an agricultural film characterized in that it has a plurality of fine holes obtained by perforating a thermoplastic resin film with a needle having a thorn-like protrusion; or (2) an agricultural film characterized in that In that, it is a thermoplastic resin film with a plurality of micropores, and the shape of the micropores is a thorny shape with thorns; or (3) an agricultural film, characterized in that it is a thermoplastic resin film with a plurality of micropores For thin film, the tiny hole is obtained by punching a needle. The relationship between the surface roughness Ra1 of one side of the film and the surface roughness Ra2 of the other side of the film is Ra1<Ra2. Inner side; or (4) the agricultural film as described in (1) or (2), characterized in that it has a plurality of micropores, and the micropores are made from both sides of the thermoplastic resin film by needles having thorn-like protrusions. or (5) the agricultural film as described in (1) or (2), which is characterized in that it is a thermoplastic resin film with a plurality of micropores obtained by piercing with needles, and the two sides of the film have Micro protrusions; or (6) the agricultural film as described in any one of (1) to (5), characterized in that the total light transmittance at 555 nm of the film with a plurality of micro pores is greater than or equal to 70%; or ( 7) The agricultural film as described in any one of (1) to (6), wherein the resin constituting the thermoplastic resin film is vinyl chloride resin or olefin resin; or (8) such as (1) to (7) ) according to any one of the agricultural films, characterized in that the thermoplastic resin film is a resin film having at least three or more layers of an outer layer, an intermediate layer, and an inner layer, and constitutes an outer layer And/or the resin of the inner layer contains at least a metallocene-based polyethylene resin.

利用本发明,能得到透明性不降低并且具有透湿性(透气性)、防雾性、防液滴附着性、保温性和防水防虫效果的农用薄膜。Utilizing the present invention, an agricultural film having moisture permeability (breathability), anti-fogging properties, anti-droplet adhesion, heat retention, and waterproof and insect-proof effects can be obtained without reducing transparency.

附图说明Description of drawings

图1a表示形成本发明微细孔用的具有刺状突起的针的正面图。Fig. 1a is a front view of a needle having thorn-like protrusions for forming micropores of the present invention.

图1b表示形成本发明微细孔用的具有刺状突起的针的侧面图。Fig. 1b is a side view of a needle having thorn-like protrusions for forming micropores of the present invention.

图2利用形成本发明微细孔用的针进行薄膜加工的示意图。Fig. 2 is a schematic diagram of thin film processing using the needle for forming micropores of the present invention.

图3在本发明的热塑性树脂薄膜上形成的微细孔的形状的示意图。Fig. 3 is a schematic view showing the shape of micropores formed in the thermoplastic resin film of the present invention.

图4在本发明的热塑性树脂薄膜上形成的微细孔的形状的横截面的示意图。Fig. 4 is a schematic diagram of a cross-sectional view of the shape of micropores formed in the thermoplastic resin film of the present invention.

图5本发明的设有多个具有刺部的有刺形状的微细孔的热塑性树脂薄膜的示意图。Fig. 5 is a schematic diagram of a thermoplastic resin film provided with a plurality of thorn-shaped micropores having thorns according to the present invention.

具体实施方式Detailed ways

下面详细说明本发明。The present invention will be described in detail below.

本发明的农用薄膜(透湿性薄膜、防雾性薄膜)是在热塑性树脂薄膜上设有多个微细孔的有孔树脂薄膜。The agricultural film (moisture-permeable film, anti-fog film) of the present invention is a porous resin film in which a plurality of micropores are provided in a thermoplastic resin film.

构成热塑性树脂薄膜的树脂可以使用例如氯乙烯类树脂、聚乙烯、乙烯-醋酸乙烯酯共聚物、聚丙烯等聚烯烃类树脂、聚对苯二酸乙二酯等聚酯类树脂、聚甲基丙烯酸甲酯树脂、含氟树脂等以前作为农用薄膜、透湿性薄膜、防雾性薄膜的材料的任一种已知的热塑性树脂。优选使用软质的氯乙烯类树脂、聚烯烃类树脂。As the resin constituting the thermoplastic resin film, for example, polyolefin resins such as vinyl chloride resin, polyethylene, ethylene-vinyl acetate copolymer, and polypropylene, polyester resins such as polyethylene terephthalate, polymethyl Methyl acrylate resins, fluorine-containing resins, and other thermoplastic resins known conventionally as materials for agricultural films, moisture-permeable films, and anti-fogging films. It is preferable to use soft vinyl chloride resin and polyolefin resin.

聚烯烃类树脂包括α-烯烃的均聚物、以α-烯烃为主要成分的不同种类单体的共聚物、α-烯烃与共轭双烯或非共轭双烯等多不饱和化合物、丙烯酸、甲基丙烯酸、醋酸乙烯酯等的共聚物等,可举出例如高密度、低密度或线型低密度聚乙烯、聚丙烯、乙烯-丙烯共聚物、乙烯-丁烯共聚物、乙烯-4-甲基-1-戊烯共聚物、乙烯-醋酸乙烯酯共聚物、乙烯-丙烯酸共聚物等。其中,从透明性和耐候性以及价格方面考虑,优选密度为0.910~0.935的低密度聚乙烯、乙烯-α-烯烃共聚物以及醋酸乙烯酯的含量小于或等于30重量%的乙烯-醋酸乙烯酯共聚物用作农用薄膜。Polyolefin resins include homopolymers of α-olefins, copolymers of different types of monomers with α-olefins as the main component, polyunsaturated compounds such as α-olefins and conjugated dienes or non-conjugated dienes, acrylic acid, Copolymers of methacrylic acid, vinyl acetate, etc., such as high-density, low-density or linear low-density polyethylene, polypropylene, ethylene-propylene copolymer, ethylene-butene copolymer, ethylene-4- Methyl-1-pentene copolymer, ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, etc. Among them, low-density polyethylene with a density of 0.910 to 0.935, ethylene-α-olefin copolymers, and ethylene-vinyl acetate with a vinyl acetate content of 30% by weight or less are preferred in terms of transparency, weather resistance, and price. Copolymers are used as agricultural films.

本发明优选的状态之一是根据其需要一定强度的使用部位、使用年数设有多个微细孔并保持高强度的农用薄膜。作为该高强度的农用薄膜,优选构成该热塑性树脂薄膜的树脂的至少一种成分使用茂金属类聚乙烯树脂,即以茂金属为催化剂共聚合而得到的乙烯-α-烯烃共聚合树脂。该物质通常被称为茂金属聚乙烯,是乙烯和1-丁烯、1-己烯、4-甲基-1-戊烯、辛烯等α-烯烃的共聚物,利用已知的制法可制得。One of the preferred aspects of the present invention is an agricultural film that is provided with a plurality of micropores and maintains high strength according to the usage site requiring a certain strength and the number of years of use. As the high-strength agricultural film, at least one component of the resin constituting the thermoplastic resin film is preferably a metallocene polyethylene resin, that is, an ethylene-α-olefin copolymer resin obtained by copolymerization using a metallocene as a catalyst. The substance is commonly called metallocene polyethylene, which is a copolymer of ethylene and alpha-olefins such as 1-butene, 1-hexene, 4-methyl-1-pentene, octene, etc. Can be made.

茂金属类聚乙烯树脂进一步优选具有以下物理性质的物质。利用JIS-K7210测定的MFR为0.01g/10分钟~10g/10分钟,优选0.1g/10分钟~5g/10分钟;利用JIS-K7112测定的密度为0.880g/cm3~0.930g/cm3,优选0.880g/cm3~0.920g/cm3,利用凝胶渗透色谱(GPC)测得的分子量分布(重均分子量/数均分子量)为1.5~3.5,优选1.5~3.0。The metallocene-based polyethylene resin is further preferably one having the following physical properties. The MFR measured by JIS-K7210 is 0.01g/10 minutes to 10g/10 minutes, preferably 0.1g/10 minutes to 5g/10 minutes; the density measured by JIS-K7112 is 0.880g/cm 3 to 0.930g/cm 3 , preferably 0.880g/cm 3 to 0.920g/cm 3 , and the molecular weight distribution (weight average molecular weight/number average molecular weight) measured by gel permeation chromatography (GPC) is 1.5 to 3.5, preferably 1.5 to 3.0.

本发明中农用薄膜的优选状态是,将聚烯烃类树脂组合物形成的基体膜制成由至少具有铺展时作为外侧的外层、中间层、内层的三层或三层以上的多层薄膜。铺展时成为外侧的外层的树脂成分或者外层和内层的树脂成分使用含有45重量%~100重量%、优选55重量%~95重量%的乙烯-α-烯烃共聚合树脂的树脂组合物,所述乙烯-α-烯烃共聚树脂是以茂金属为催化剂共聚合得到的。中间层或中间层和内层优选使用含有45重量%~100重量%、优选55重量%~98重量%的乙烯-醋酸乙烯酯共聚物的树脂组合物。In the preferred state of the agricultural film in the present invention, the base film formed of the polyolefin resin composition is made into a multilayer film having at least three or more layers of an outer layer, an intermediate layer, and an inner layer when it is spread out. . A resin composition containing 45% by weight to 100% by weight, preferably 55% by weight to 95% by weight, of an ethylene-α-olefin copolymer resin is used as the resin component of the outer layer or the resin components of the outer layer and the inner layer when spread. , the ethylene-alpha-olefin copolymer resin is obtained by copolymerization using a metallocene as a catalyst. The middle layer or the middle layer and the inner layer preferably use a resin composition containing 45% by weight to 100% by weight, preferably 55% by weight to 98% by weight of an ethylene-vinyl acetate copolymer.

这里所说的外层是指作为农用薄膜使用时成为外侧的层,内层是指使用时成为内侧的层。The outer layer referred to here refers to the outer layer when used as an agricultural film, and the inner layer refers to the inner layer when used.

对于多层结构的树脂薄膜的制造方法,没有特别的限定,可以使用已知的制造方法,多层结构中层的厚度比没有特别的限定,例如,具有3层结构的情况下,从成型性、透明性和强度的角度考虑,优选层的厚度比在1/0.5/1到1/5/1的范围,更优选1/2/1到1/4/1的范围。另外,外层与内层的比例没有特别的限定,从所得薄膜的卷曲性考虑,优选为同等程度的比例。There is no particular limitation on the method for producing the resin film of the multilayer structure, and known production methods can be used. The thickness ratio of the layers in the multilayer structure is not particularly limited. For example, in the case of a three-layer structure, from the aspects of formability, From the viewpoint of transparency and strength, the thickness ratio of the layer is preferably in the range of 1/0.5/1 to 1/5/1, more preferably in the range of 1/2/1 to 1/4/1. In addition, the ratio of the outer layer to the inner layer is not particularly limited, but it is preferably an equivalent ratio from the viewpoint of curlability of the obtained film.

热塑性树脂薄膜的厚度为10微米~1000微米,优选20微米~200微米。如果过薄,穿孔后的薄膜的强度容易不充分。如果过厚,使穿孔加工变得困难,所以不是优选的。The thickness of the thermoplastic resin film is 10 microns to 1000 microns, preferably 20 microns to 200 microns. If it is too thin, the strength of the perforated film tends to be insufficient. If it is too thick, the punching process will become difficult, so it is not preferable.

在本发明所使用的热塑性树脂薄膜中,根据其用途可以配合任意已知的添加剂。例如,增塑剂、防紫外线剂、光稳定剂、保温剂、润滑剂等其他各种添加剂。Any known additives may be blended in the thermoplastic resin film used in the present invention according to the application. For example, various additives such as plasticizers, UV protection agents, light stabilizers, heat insulating agents, lubricants, etc.

另外,本发明的农用薄膜上可以形成此外的其他涂膜。例如,在薄膜外层上可以形成防尘性涂膜,如果在薄膜内层再形成防雾性涂膜,与本发明的微细孔产生的效果具有协同效果,得到很好的防雾效果。作为防雾涂膜,可以采用已知的各种农用薄膜的涂布防雾涂膜,不过优选例如硅溶胶和/或氧化铝溶胶等无机溶胶和以热塑性树脂等粘结剂用树脂为主要成分的组合物等。热塑性树脂可以例举疏水性或亲水性的丙烯酸树脂、聚氨酯树脂等。In addition, other coating films may be formed on the agricultural film of the present invention. For example, a dust-proof coating can be formed on the outer layer of the film. If an anti-fog coating is formed on the inner layer of the film, it will have a synergistic effect with the effect of the micropores of the present invention, and a good anti-fog effect will be obtained. As the anti-fog coating film, coating anti-fog coating films of various known agricultural films can be used, but inorganic sols such as silica sol and/or alumina sol, and binder resins such as thermoplastic resins as main components are preferable. composition etc. Examples of thermoplastic resins include hydrophobic or hydrophilic acrylic resins, polyurethane resins, and the like.

作为应用本发明的农用薄膜可以举出塑料棚中栽培或塑料隧道栽培中内铺用或外铺用薄膜、直接覆盖植物的全遮荫薄膜、其他复膜等,特别优选内铺用或外铺用薄膜。As the agricultural film to which the present invention is applied, there can be mentioned the film for inner or outer laying in cultivation in plastic shed or plastic tunnel cultivation, the full shade film directly covering plants, other lamination films, etc., especially preferably inner laying or outer laying Use film.

本发明的特征在于,该热塑性树脂薄膜上设有的微细孔是特殊的微细孔。具体地说,该特殊的微细孔是利用特殊的针通过穿孔法制得的,此方法应用了主要作为无纺织物和织物、人工皮革的质感加工用的机械针刺加工法。The present invention is characterized in that the micropores provided in the thermoplastic resin film are special micropores. Specifically, the special micropores are formed by a piercing method using a special needle, which applies a mechanical needling process mainly used for texture processing of non-woven fabrics, fabrics, and artificial leather.

具体而言,如图1的简图所示,所述微细孔是利用外周至少有1个微小的刺1c的特殊形状的针1刺到热塑性树脂薄膜上所得的。Specifically, as shown in the schematic diagram of FIG. 1, the micropores are obtained by piercing the thermoplastic resin film with a special-shaped needle 1 having at least one tiny thorn 1c on the outer periphery.

图1是针1的放大图,图1a表示正面图,图1b表示侧面图。针1从基部1a朝向最前端变尖,在其最前端有微小宽度(W)的切刃1b。最前端的微小宽度与树脂薄膜上形成的孔的基本部分的大小有关,优选为10微米~300微米,更优选30微米~150微米。Fig. 1 is an enlarged view of the needle 1, Fig. 1a shows a front view, and Fig. 1b shows a side view. The needle 1 is tapered from the base 1a toward the most distal end, and has a cutting edge 1b of a small width (W) at the most distal end. The minute width at the tip is related to the size of the basic part of the pores formed in the resin film, and is preferably 10 to 300 microns, more preferably 30 to 150 microns.

本发明使用的特殊的针1,在接近最前端的针外周的一部分设有一个或多于1个的微小的刺1c,优选两个或多于两个。刺是朝着相对针轴接近直角的方向突出的,刺的形状也是从基部朝向最前端,形成尖状,例如在距离针的最前端300微米~1000微米处设置1个刺1c,则优选在800微米~2000微米处再设置1个刺。刺1c本身的长度优选为1微米~300微米。The special needle 1 used in the present invention is provided with one or more, preferably two or more, tiny thorns 1c on a part of the outer periphery of the needle near the front end. The thorn protrudes toward a direction close to a right angle with respect to the needle axis, and the shape of the thorn is also from the base toward the front end, forming a pointed shape. For example, a thorn 1c is set at a distance from the front end of the needle 300 microns to 1000 microns, then preferably at Set another thorn at 800 microns to 2000 microns. The length of the spines 1c itself is preferably 1 micrometer to 300 micrometers.

如图2所示,优选多个这些具有刺的针1安装在辊体2上形成针辊2,将此针辊押在置于平面上或缠绕在其他辊体上的被加工用热塑性树脂薄膜3上旋转,由此能在热塑性树脂薄膜上形成多个微细孔。根据必要的微细孔的数量和间隔,用多个针辊对树脂薄膜3进行加工,或者也可以采用数次将树脂薄膜押在针辊上而进行加工的方法。本发明优选的状态之一如后面所述,是对树脂薄膜从两面进行穿孔加工的方法,该方法能减轻膜的卷曲。此种情况下,两面可以同时进行加工,但通常每次进行单面穿孔加工的方法简便。As shown in Figure 2, preferably a plurality of these needles 1 with thorns are installed on the roller body 2 to form a needle roller 2, and this needle roller is pressed against the processed thermoplastic resin film placed on a plane or wound on other roller bodies 3, so that a plurality of microscopic holes can be formed on the thermoplastic resin film. The resin film 3 may be processed with a plurality of needle rolls depending on the number and spacing of the required fine pores, or may be processed by pressing the resin film against the needle rolls several times. One of the preferred aspects of the present invention is a method of perforating a resin film from both sides as will be described later, and this method can reduce curling of the film. In this case, both sides can be processed at the same time, but it is usually easier to process one side at a time.

图3表示在热塑性树脂薄膜上利用特殊形状的针设置的每个微细孔的形状的简图。微细孔的形状可以利用显微镜等放大工具来确认。由于刺1c的存在,本发明的薄膜上所形成的微细孔4的形状不是由普通针所形成的圆形的孔形状,而是如图3的简图所示,在类圆形的基本孔4a周围具有一个或多于一个的微小的刺状切损部位4b的类似星形形状。形成一个或多于一个该刺状切损部位,优选形成两个或两个以上的刺状切损部位,多数情况下刺状切损部位的个数与使用的针1上的刺1c的个数相同或大于刺1c的个数。Fig. 3 is a schematic diagram showing the shape of each micropore formed on a thermoplastic resin film by using a needle of a special shape. The shape of the micropores can be confirmed using a magnifying tool such as a microscope. Due to the existence of thorns 1c, the shape of the micropores 4 formed on the film of the present invention is not the circular hole shape formed by ordinary needles, but as shown in the schematic diagram of Figure 3, in the basic hole of a quasi-circle 4a has a star-like shape with one or more than one tiny spiny incision site 4b surrounding it. Form one or more than one thorn-shaped incision site, preferably form two or more thorn-shaped incision sites. In most cases, the number of thorn-shaped incision sites is the same as the number of thorns 1c on the needle 1 used. The number is the same as or greater than the number of spines 1c.

本发明得到优异的防雾效果和透湿效果的机理还不明确,但推测是由于间隙大的基本孔部分与间隙小的刺状切损部位连接所产生的形状的协同效果。The mechanism of the excellent anti-fog effect and moisture permeability effect of the present invention is not clear, but it is presumed to be due to the synergistic effect of the shape produced by the connection of the basic hole part with a large gap and the thorn-shaped cut part with a small gap.

对于微细孔的直径,优选基本孔4a的最大直径小于或等于500微米,优选小于或等于200微米,并且最小直径大于或等于10微米,优选大于或等于20微米。刺状切损部位4b的长度优选为0.05微米~50微米,更优选0.1微米~20微米。Regarding the diameter of the fine pores, it is preferable that the maximum diameter of the basic pores 4a is less than or equal to 500 microns, preferably less than or equal to 200 microns, and the smallest diameter is greater than or equal to 10 microns, preferably greater than or equal to 20 microns. The length of the thorn-shaped cut site 4b is preferably 0.05 micron to 50 micron, more preferably 0.1 micron to 20 micron.

图5表示本发明的设有多个微细孔的薄膜的示意图。Fig. 5 is a schematic view showing a film provided with a plurality of micropores of the present invention.

带刺的针在刺入树脂薄膜并拔出时,具有刺钩到切损部位周围的薄膜和使刺状切损部位4b的周围的切片4c顺着针刺入的方向而突起的作用。所以,具有通过本发明的特殊针的穿孔法得到的多个微细孔的薄膜从薄膜的截面观察具有特殊的形状。When the barbed needle penetrates the resin film and pulls it out, it has the function of hooking the film around the incision site and making the slice 4c around the thorn-shaped incision site 4b protrude along the direction in which the needle penetrates. Therefore, a film having a plurality of micropores obtained by the method of piercing with a special needle of the present invention has a special shape when viewed from the cross section of the film.

图4是本发明的薄膜上设有的微细孔的横截面图的简图,树脂薄膜3中,微细孔的刺状切损部位4b周围的一部分切片4c具有顺着针刺方向的若干突起的形状。Fig. 4 is a schematic diagram of a cross-sectional view of the micropores provided on the film of the present invention. In the resin film 3, a part of the slice 4c around the puncture-shaped cut site 4b of the micropores has some protrusions along the acupuncture direction. shape.

其结果是,具有本发明的微细孔的薄膜中,针刺入一侧的薄膜表面(图4中的P)的表面粗糙度Ra1与反面的薄膜表面(图4中的Q)粗糙度Ra2比较,Ra1<Ra2。此种情况下,Ra1接近原来薄膜的表面粗糙度。另外,根据薄膜厚度的不同,表面粗糙度Ra2不同,其是薄膜厚度(Ha)与顺着针刺入方向的薄膜表面的突起高度(Hc)的关系为Hc/Ha=0.4~2,优选0.5~1程度的表面粗糙度。As a result, in the film having micropores of the present invention, the surface roughness Ra1 of the film surface (P in FIG. 4 ) on the side where the needle penetrates is compared with the roughness Ra2 of the film surface (Q in FIG. 4 ) on the opposite side. , Ra1<Ra2. In this case, Ra1 is close to the surface roughness of the original film. In addition, depending on the thickness of the film, the surface roughness Ra2 is different, which is that the relationship between the film thickness (Ha) and the protrusion height (Hc) on the film surface along the needle penetration direction is Hc/Ha=0.4~2, preferably 0.5 Surface roughness of ~1 degree.

使用本发明的农用薄膜时,基本上是薄膜的任意一面都可以作为内侧面,不过优选的使用方法是,如果在具有防雾性的一侧或在湿度大的一侧配置表面粗糙度大的一面(Ra2),则能得到理想的效果。When using the agricultural film of the present invention, basically any side of the film can be used as the inner side, but the preferred method of use is if the side with anti-fogging properties or the side with high humidity are arranged with a side with a large surface roughness. On one side (Ra2), the desired effect can be obtained.

本发明的农用薄膜的其他的优选状态是使用从两侧对热塑性树脂薄膜进行刺针加工得到的双面穿孔加工薄膜。从两侧进行穿孔加工能降低薄膜朝一个方向卷曲的卷曲性。另外,两侧的穿孔加工可以采取同样的条件,也可以采取不同的条件(孔的大小、密度)。Another preferred aspect of the agricultural film of the present invention is a double-side perforated film obtained by punching a thermoplastic resin film from both sides. Perforating from both sides can reduce the curling of the film in one direction. In addition, the same conditions may be adopted for the perforation process on both sides, or different conditions (size and density of holes) may be adopted.

本发明热塑性树脂薄膜上设有的多个微细孔在单位面积上的个数,根据设置的孔的面积的不同而不同,但优选为了显示防雾性和透湿性,同时满足其他物理性质,优选每1平方英寸(6.45平方厘米)设有800~8000个(即,每1平方厘米125~1250个),更优选每1平方英寸设有1500~6000个(即,每1平方厘米230~930个)。The number per unit area of the plurality of micropores provided on the thermoplastic resin film of the present invention varies according to the area of the provided holes, but preferably in order to show anti-fogging properties and moisture permeability while satisfying other physical properties, preferably There are 800 to 8000 pieces per 1 square inch (6.45 square centimeters) (ie, 125 to 1250 pieces per 1 square centimeter), more preferably 1500 to 6000 pieces per 1 square inch (ie, 230 to 930 pieces per 1 square centimeter). indivual).

另外,为了作为农用薄膜使用,设有本发明的特殊形状的微细孔的热塑性树脂薄膜更优选具有透明性。具体而言,具有多个微细孔的薄膜在555纳米处的总透光率大于或等于70%,优选大于或等于75%。该值是根据众所周知的测定方法测定的。In addition, in order to use as an agricultural film, it is more preferable that the thermoplastic resin film provided with the micropore of the special shape of this invention has transparency. Specifically, the total light transmittance at 555 nanometers of the film with a plurality of micropores is greater than or equal to 70%, preferably greater than or equal to 75%. This value is measured according to a well-known measuring method.

实施例Example

下面,基于本发明进行详细说明,但只要不超出上述的主旨,本发明并不限定于下面的例子。Hereinafter, the present invention will be described in detail, but the present invention is not limited to the following examples unless the above-mentioned gist is exceeded.

(1)基体膜的调制(1) Modulation of base film

试验用的热塑性树脂薄膜是使用以下2种聚烯烃类树脂(用三层吹胀模头形成的三层结构)的层合薄膜(0.05毫米厚)作为基体膜。The thermoplastic resin film used in the test was a laminated film (0.05 mm thick) of the following two kinds of polyolefin resins (three-layer structure formed by a three-layer inflation die) as a base film.

薄膜1:以如下膜为基体膜。含有适量的农用薄膜中通常使用的各种添加剂,例如保温剂(水滑石)、紫外线吸收剂、光稳定剂等,外层树脂是线型低密度聚乙烯(LLDPE)和低密度聚乙烯(LDPE),中间层树脂是醋酸乙烯酯含量为15重量%的醋酸乙烯酯类树脂,内层树脂是醋酸乙烯酯含量为5重量%的醋酸乙烯酯类树脂。Film 1: The following film is used as the base film. Contains an appropriate amount of various additives commonly used in agricultural films, such as thermal insulation (hydrotalcite), ultraviolet absorbers, light stabilizers, etc., and the outer resin is linear low-density polyethylene (LLDPE) and low-density polyethylene (LDPE) ), the middle layer resin is a vinyl acetate resin with a vinyl acetate content of 15% by weight, and the inner layer resin is a vinyl acetate resin with a vinyl acetate content of 5% by weight.

薄膜2:以如下膜为基体膜。含有适量的保温剂(水滑石)、紫外线吸收剂、光稳定剂等各种添加剂,外层树脂和内层树脂是以用茂金属作为催化剂制造的聚乙烯树脂(MePE)为主要成分(90重量%)的聚乙烯树脂,中间层树脂是醋酸乙烯酯含量为15重量%的醋酸乙烯酯类树脂。Film 2: The following film is used as the base film. It contains various additives such as thermal insulation agent (hydrotalcite), ultraviolet absorber, and light stabilizer. The outer layer resin and inner layer resin are mainly composed of polyethylene resin (MePE) produced with metallocene as a catalyst (90 wt. %) polyethylene resin, the middle layer resin is a vinyl acetate resin with a vinyl acetate content of 15% by weight.

(2)针加工方法(2) Needle processing method

作为实施例,准备如下的薄膜。通过以图2所示的辊上有多个图1所示形状的刺的针进行的穿孔方法,对上述基体膜1实施穿孔处理,分别按在每1平方英寸形成1200个孔(实施例1)、2030个孔(实施例2)、4060个孔(实施例3)、6190个孔(实施例4)。As an example, the following films were prepared. By the perforation method carried out with a plurality of thorn needles of the shape shown in FIG. 1 on the roller shown in FIG. ), 2030 holes (embodiment 2), 4060 holes (embodiment 3), 6190 holes (embodiment 4).

同样,作为实施例利用下述方法准备通过特殊的针刺针实施了穿孔处理的薄膜。利用与上述相同的特殊的针刺针的穿孔方法,在相同的条件下对上述基体膜2从两侧实施穿孔处理,分别在每1平方英寸形成2030个孔(实施例5)、4060个孔(实施例6)。Similarly, as an example, a film perforated with a special needling needle was prepared by the following method. Using the same special needle-punching method as above, under the same conditions, the above-mentioned base film 2 is perforated from both sides to form 2030 holes (Example 5) and 4060 holes per square inch, respectively. (Example 6).

另外,作为比较例,准备下述薄膜。在热塑性树脂薄膜上不进行针刺穿孔加工的薄膜1(比较例1);一直以来作为内铺用的农用材料的市售无纺织物(三井化学塑料社制:商品名“无天露”,比较例2);使用通常的热熔针以10厘米×20厘米作为1个间隔在热塑性树脂薄膜上做点式穿孔,得到孔径为2毫米的薄膜(比较例3);不进行针刺穿孔加工的薄膜2(比较例4)。In addition, the following films were prepared as comparative examples. A film 1 (comparative example 1) that does not perform needle punching on a thermoplastic resin film; a commercially available non-woven fabric (manufactured by Mitsui Chemicals Plastics Co., Ltd.: trade name "No-Tempor", Comparative example 2); using a common hot-melt needle to do point perforation on the thermoplastic resin film at an interval of 10 cm × 20 cm, to obtain a film with a hole diameter of 2 mm (comparative example 3); no needle punching process Film 2 (Comparative Example 4).

(3)评价方法(3) Evaluation method

对所得的薄膜进行下面的评价试验。结果见表1。The resulting film was subjected to the following evaluation tests. The results are shown in Table 1.

1.透明性试验1. Transparency test

利用分光光度计(日立制作所U-2000型)测定实施例或比较例所得的薄膜在555毫微米的总透光率,并给出其值。The total light transmittance at 555 nanometers of the films obtained in Examples or Comparative Examples was measured with a spectrophotometer (Hitachi, Ltd. U-2000), and the values were given.

2.防雾性试验2. Anti-fog test

在三重县一志郡的圃园,搭建简易的管状大棚,覆盖上述得到的薄膜。值得注意的是,本发明得到的薄膜以表面粗糙度大的一面作为内侧。In the garden of Ichi-gun, Mie Prefecture, a simple tubular greenhouse was built and covered with the film obtained above. It is worth noting that the film obtained by the present invention has the side with a larger surface roughness as the inner side.

评价方法是经过一段时间用肉眼观察铺展薄膜内侧水滴的附着情况。评价基准如下。The evaluation method is to observe with the naked eye the adhesion of water droplets inside the spread film over a period of time. The evaluation criteria are as follows.

◎    薄膜内侧无水滴附着或水滴之间结合,呈薄膜状扩展◎ There is no water drop attached to the inner side of the film or the combination of water droplets, and it expands in the form of a film

○    能观察到薄膜表面附着的水滴之间的集合体,其面积未达到薄膜表面的2/3但大于等于1/2○ Aggregates between water droplets attached to the surface of the film can be observed, and its area does not reach 2/3 of the film surface but is greater than or equal to 1/2

○×  能观察到薄膜表面附着的水滴之间的集合体,但其面积未达到薄膜表面的1/2○× Aggregates between water droplets attached to the surface of the film can be observed, but its area does not reach 1/2 of the surface of the film

△    能观察到薄膜表面附着的水滴之间的集合体,但不是薄膜状部分的形状△ Aggregates between water droplets attached to the surface of the film can be observed, but not the shape of the film-like part

×    不能观察到薄膜表面附着的水滴之间的集合体× Aggregates between water droplets attached to the surface of the film cannot be observed

3.透湿性(防止水滴积存)试验3. Moisture permeability (prevent water droplet accumulation) test

在三重县一志郡的圃园搭建的正面宽度16米、梁高8米、进深21米的屋顶型的塑料棚内,覆盖实施例或比较例所得的薄膜作为内铺水平遮荫屏,经过一段时间后从薄膜上部用肉眼观察水滴的蓄积状况。评价基准如下。In the roof-shaped plastic shed with a front width of 16 meters, a beam height of 8 meters, and a depth of 21 meters in the garden of Ichi County, Mie Prefecture, the film covered in the examples or comparative examples is used as a horizontal shade screen in the interior. After a period of time, the state of accumulation of water droplets was visually observed from the top of the film. The evaluation criteria are as follows.

◎    内铺膜上部完全没有水滴,或干燥◎ There is no water drop on the upper part of the inner film, or it is dry

○    内铺膜上部有水分。但内铺膜不松弛○ There is moisture on the upper part of the inner film. But the lining membrane does not relax

○×  内铺膜上部有水分。内铺膜松弛。不必除去水分。○× There is moisture on the upper part of the inner film. The lining membrane is loose. It is not necessary to remove moisture.

△    内铺膜上部有水分。内铺膜松弛。必须除去水分。△ There is moisture on the upper part of the inner film. The lining membrane is loose. Moisture must be removed.

×    内铺膜上部水分较多,由于此重量薄膜破裂。× There is more moisture in the upper part of the inner film, and the film ruptures due to this weight.

4.撕裂强度试验4. Tear strength test

按照JIS-K6732法测定实施例或比较例所得的薄膜在MD方向的撕裂强度,作为测定温度0℃的爱拉门道夫(Elmendorf)撕裂强度(g),并给出其值。The tear strength in the MD direction of the films obtained in Examples or Comparative Examples was measured in accordance with JIS-K6732, and its value was given as Elmendorf tear strength (g) at a measurement temperature of 0°C.

5.所得微细孔的形状5. The shape of the resulting micropores

实施例1~6所得的微细孔的形状(正面图)如图3所示,在类圆形的基本孔4a的周围具有多个(2~4个)刺状切损部位4b。基本孔4a的直径约为80微米,含有刺状切损部位4b的直径约为85微米~110微米。The shape (front view) of the micropores obtained in Examples 1 to 6 is as shown in FIG. 3 , and has a plurality (2 to 4) of puncture-like incisions 4 b around the substantially circular basic hole 4 a. The diameter of the basic hole 4a is about 80 microns, and the diameter of the thorn-shaped cutting damage part 4b is about 85 microns to 110 microns.

微细孔的横断面的形状如图4简略所示,薄膜厚度Ha(=50微米)加上突起高度Hc的厚度(Ha+Hc)为80微米~90微米。The shape of the cross-section of the micropore is schematically shown in FIG. 4, and the thickness (Ha+Hc) of the film thickness Ha (=50 micrometers) plus the protrusion height Hc is 80 micrometers to 90 micrometers.

对于薄膜的触感,针刺一侧的薄膜表面的表面粗糙度(Ra1)大,而另一面(Ra2)与以前的薄膜表面一样平滑。所以Ra1<Ra2。Regarding the feel of the film, the surface roughness (Ra1) of the film surface on the needle-punched side was large, while the other side (Ra2) was as smooth as the previous film surface. So Ra1<Ra2.

从薄膜两侧进行针刺加工的实施例5、6具有薄膜不发生卷曲的优点。Examples 5 and 6 in which needle punching is performed from both sides of the film have the advantage that the film does not curl.

表1Table 1

  实施例1Example 1   实施例2Example 2   实施例3Example 3   实施例4Example 4   实施例5Example 5   实施例6Example 6   比较例1Comparative example 1   比较例2Comparative example 2   比较例3Comparative example 3   比较例4Comparative example 4   基体膜Matrix membrane   薄膜1Film 1   薄膜1Film 1   薄膜1Film 1   薄膜1Film 1   薄膜2Film 2   薄膜2Film 2   薄膜1Film 1   无纺织物Non-woven fabric   薄膜1Film 1   薄膜2Film 2 穿孔加工Perforation 特殊针孔1200(个/平方英寸)1200 special pinholes (pieces/square inch) 特殊针孔2030(个/平方英寸)Special pinhole 2030 (pieces/square inch) 特殊针孔4060(个/平方英寸)Special pinhole 4060 (pieces/square inch) 特殊针孔6190(个/平方英寸)Special pinhole 6190 (pieces/square inch)   特殊针孔2030(个/平方英寸)两面加工Special pinhole 2030 (pieces/square inch) double-sided processing   特殊针孔4060(个/平方英寸)两面加工Special pinhole 4060 (pieces/square inch) double-sided processing 无针孔no pinholes 点式穿孔1个/200cm2孔径2mmPoint perforation 1 / 200cm 2 hole diameter 2mm 无针孔no pinholes   1.透明性试验总透光率(%)(555纳米)1. Transparency test total light transmittance (%) (555 nm) 9090 9090 9090 9090 9090 9090 9090 5050 9090 9090   2.防雾性试验1个月后3个月后6个月后2. Anti-fog test after 1 month, 3 months, 6 months ◎◎○◎◎○ ◎◎◎◎◎◎ ◎◎◎◎◎◎ ◎◎◎◎◎◎ ◎◎◎◎◎◎ ◎◎◎◎◎◎ ○○×△○○×△ ◎◎◎◎◎◎ ○○×△○○×△ ◎◎◎◎◎◎   3.透湿性试验1个月后3个月后6个月后3. Moisture permeability test after 1 month, 3 months, 6 months ◎◎◎◎◎◎ ◎◎◎◎◎◎ ◎◎◎◎◎◎ ◎◎◎◎◎◎ ◎◎◎◎◎◎ ◎◎◎◎◎◎ △△×△△× △△△△△△ ◎○○◎○○ △△×△△×   4.撕裂强度0℃的爱拉门道夫(g)MD方向4. Eramendorf (g) MD direction of tear strength at 0°C 150150 100100 9090 8080 760760 615615 520520 400400 300300 800800

Claims (8)

1.农用薄膜,其特征在于,其是具有多个微细孔的热塑性树脂薄膜,并且该微细孔的形状是具有刺部的有刺形状,所述微细孔的基本孔的最大直径小于或等于500微米并且最小直径大于或等于10微米,所述刺部的长度为0.05微米~50微米。1. Agricultural film, it is characterized in that, it is the thermoplastic resin film that has a plurality of micropores, and the shape of this micropore is the barbed shape that has thorn part, and the maximum diameter of the basic hole of described micropore is less than or equal to 500mm microns and the minimum diameter is greater than or equal to 10 microns, and the length of the spines is 0.05 microns to 50 microns. 2.如权利要求1所述的农用薄膜,其特征在于,所述微细孔利用具有刺状突起的针在热塑性树脂薄膜上进行穿孔加工而得,所述的针在其最前端有微小宽度的切刃,所述微小宽度为10微米~300微米,所述刺状突起的长度为1微米~300微米。2. The agricultural film according to claim 1, wherein the micropores are obtained by perforating the thermoplastic resin film with a needle having a thorn-like protrusion, and the needle has a small width at its front end. For the cutting edge, the tiny width is 10 microns to 300 microns, and the length of the thorn-like protrusion is 1 micron to 300 microns. 3.如权利要求1或2所述的农用薄膜,其特征在于,膜的一面的表面粗糙度Ra1和膜的另一面的表面粗糙度Ra2的关系是Ra1<Ra2,Ra2面是塑料棚或塑料隧道铺展时作为内侧的内侧面。3. The agricultural film as claimed in claim 1 or 2, characterized in that, the relationship between the surface roughness Ra1 on one side of the film and the surface roughness Ra2 on the other side of the film is Ra1<Ra2, and the Ra2 surface is made of plastic or plastic. The inside face that acts as the inside when the tunnel is running. 4.如权利要求1所述的农用薄膜,其特征在于,具有多个微细孔,所述微细孔是利用具有刺状突起的针从热塑性树脂薄膜的两侧进行穿孔加工而得到的。4. The agricultural film according to claim 1, which has a plurality of micropores obtained by perforating from both sides of the thermoplastic resin film with a needle having a thorn-like protrusion. 5.如权利要求1所述的农用薄膜,其特征在于,其是具有多个通过针穿孔而得的微细孔的热塑性树脂薄膜,膜的两面具有由于针穿孔而得的微小突起。5. The agricultural film according to claim 1, which is a thermoplastic resin film having a plurality of microscopic holes perforated by needles, and has microprotrusions perforated by the needles on both sides of the film. 6.如权利要求1或2所述的农用薄膜,其特征在于,具有多个所述微细孔的薄膜在555nm的总透光率大于或等于70%。6. The agricultural film according to claim 1 or 2, characterized in that the total light transmittance at 555 nm of the film having a plurality of micropores is greater than or equal to 70%. 7.如权利要求1或2所述的农用薄膜,其特征在于,构成所述热塑性树脂薄膜的树脂是氯乙烯树脂或烯烃树脂。7. The agricultural film according to claim 1 or 2, wherein the resin constituting the thermoplastic resin film is vinyl chloride resin or olefin resin. 8.如权利要求1或2所述的农用薄膜,其特征在于,所述热塑性树脂薄膜是由至少具有外层、中间层、内层的三层或三层以上的多层结构构成的树脂薄膜,构成外层和/或内层的树脂至少含有金属茂聚乙烯树脂。8. The agricultural film as claimed in claim 1 or 2, characterized in that, said thermoplastic resin film is a resin film made of at least three layers or more than three layers of an outer layer, an intermediate layer, and an inner layer , the resin constituting the outer layer and/or the inner layer contains at least a metallocene polyethylene resin.
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