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CN1675429A - Method of dyeing or printing cellulose-containing fibre materials using disperse dyes - Google Patents

Method of dyeing or printing cellulose-containing fibre materials using disperse dyes Download PDF

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Publication number
CN1675429A
CN1675429A CNA038194805A CN03819480A CN1675429A CN 1675429 A CN1675429 A CN 1675429A CN A038194805 A CNA038194805 A CN A038194805A CN 03819480 A CN03819480 A CN 03819480A CN 1675429 A CN1675429 A CN 1675429A
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hydrogen
alkyl
halogen
alkoxyl
unsubstituted
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CN100404751C (en
Inventor
P·谢布利
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BASF Schweiz AG
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Ciba Spezialitaetenchemie Holding AG
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8228—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye
    • D06P3/8233—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye using dispersed dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257—(Meth)acrylic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5271—Polyesters; Polycarbonates; Alkyd resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/54—Substances with reactive groups together with crosslinking agents
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/6033—Natural or regenerated cellulose using dispersed dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/6033—Natural or regenerated cellulose using dispersed dyes
    • D06P3/6041—Natural or regenerated cellulose using dispersed dyes using specified dyes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)

Abstract

A method of dyeing or printing cellulose-containing fibre materials using disperse dyes that comprises treating the fibre material with an aqueous composition comprising a watersoluble or water-dispersible polyester resin and a water-soluble or water-dispersible acrylate binder produces level dyeings and prints having good allround fastness properties and is advantageously suitable for cellulose-containing fibre blends, for example blends consisting of polyester and cellulose.

Description

Use DISPERSE DYES that the fibrous material of cellulose is dyeed or method of printing
The present invention relates to the method that a kind of fibrous material that uses DISPERSE DYES to cellulose, the especially blended fiber of cellulose dye.
Generation has the water-soluble reactive colour of abundant durability to the color of scourability, is generally used for the hydrophilic fibre cellulose fiber is dyeed or prints.In this course, the fibre-active radical reaction of the alcoholates group of come-at-able cellulose fibre and REACTIVE DYES on the surface, the fiber/dye bond of formation covalency.On the contrary, hydrophobic polyester fiber migrates into the hydrophobic fibre from moisture dye formulations with water-fast disperse dyeing or printing, DISPERSE DYES.Because the different in kind of cellulose fiber peacekeeping polyester fiber, so the dyeing condition that uses also naturally can be different.
The increase of weaving and knit goods scope causes increasing with chances synthetic fiber so that the form use of blended fiber is natural.By using this batch mixing can significantly reduce natural material,, also can improve quality and its comfort in actual use of fabric simultaneously as the use of cotton.Along with increasing that huge kind blended fiber is used, need to use special colouring method, in this colouring method, need consider performance and its performance of each fibre fractionation with respect to dye well coexistence dyeing chemistry product.
Known have two types method to be used for blended fiber is dyeed basically: two dye bath methods, wherein each component of blended fiber in this method, is only carried out a dying operation to all fibres component that exists by independent dyeing and single dye bath method.Single dye bath method is complicated more, and this is especially because condition need be complementary with the most responsive fibre fractionation, and selects the dyestuff that is used for dyeing and usually the fiber that uses is had different affinitys.On the contrary, under most of occasions, single dye bath method can provide the saving of certain degree ground with regard to the chemicals of resource such as water, energy and use.
In recent years, needs and the expansion to the blended fiber be made up of cellulose and polyester had stable growth.
The blended fiber of being made up of cellulose and polyester is normally with the mixture dyeing of REACTIVE DYES and DISPERSE DYES, promptly for each types of fibers with at least a suitable dyestuff.
Come from different dyestuff kinds, want combination with one another dyestuff together, except the fiber to respective type has similar affinity, also should have identical or similar at least tone, uniform outward appearance is arranged so that guarantee fabric.
The unique suitable method that is used to print the blended fiber of being made up of cellulose and polyester is a COAT PRINTING, and wherein the suitable adhesive resin guarantees that pigment is attached on the fiber.
Therefore, still need to be suitable for simultaneously the method for simplifying that the blended fiber to fibrous material, the especially cellulose of cellulose dyes and prints.It should be can dye to various fibers simultaneously and especially can produce to have good, comprehensive durability, for example sufficient fastness rate and the level dyeing of moisture-proof fully or single dye bath method of printed matter.
Therefore, the present invention relates to a kind of DISPERSE DYES of using the fibrous material of cellulose is dyeed or method of printing, it comprises with the Aquo-composition that contains water-soluble or water dispersible mylar and water-soluble or water dispersible acrylic ester adhesive handles described fibrous material.
The suitable DISPERSE DYES that is used for the inventive method is referring to Colour Index, " DISPERSE DYES " literary composition of the third edition (1987 revised edition for the third time comprises up to 85 adding and revision).This dyestuff comprises, for example, do not contain carboxyl and/or do not contain sulfonic nitro, amino, amino ketones, ketoninime, methine, poly-methine, diphenylamines, quinoline, benzimidazole, xanthene, oxazines and coumarine dye, especially anthraquinone and azo dyes are such as single-or two-azo dyes.
Preferably, the DISPERSE DYES that is used for the inventive method is equivalent to following formula:
Figure A0381948000091
Wherein:
R 1Be halogen, nitro or cyano group,
R 2Be hydrogen, halogen, nitro or cyano group,
R 3Be hydrogen, halogen or cyano group,
R 4Be hydrogen, halogen, C 1-C 4Alkyl or C 1-C 4Alkoxyl,
R 5Be hydrogen, halogen or C 2-C 4Alkanoylamino and
R 6And R 7Be hydrogen independently of one another, allyl, or unsubstituted or by hydroxyl, cyano group, C 1-C 4Alkoxyl, C 1-C 4Alkoxy-C 1-C 4Alkoxyl, C 2-C 4Alkanoyloxy, C 1-C 4The C that alkoxy carbonyl, phenyl or phenoxy group replace 1-C 4Alkyl;
Wherein:
R 8Be hydrogen, phenyl or benzenesulfonyl, the phenyl ring in phenyl and the benzenesulfonyl are unsubstituted or by C 1-C 4Alkyl, sulfo group or by C 1-C 4Alkylsulfonyloxy replaces,
R 9Be unsubstituted or C 1-C 4The amino that alkyl replaces, or hydroxyl,
R 10Be hydrogen or C 1-C 4Alkoxyl,
R 11Be hydrogen, C 1-C 4Alkoxyl, phenoxy group or group-O-C 6H 5-SO 2-NH-(CH 2) 3-O-C 2H 5,
R 12Be hydrogen, hydroxyl or nitro and
R 13Be hydrogen, hydroxyl or nitro;
Wherein:
R 14Be C unsubstituted or that replaced by hydroxyl or phenyl 1-C 4Alkyl, or phenyl,
R 15Be C 1-C 4Alkyl,
R 16Be cyano group,
R 17Be formula-(CH 2) 3-O-(CH 2) 2-O-C 6H 5Group, phenyl, or the C that is replaced by hydroxyl or phenyl 1-C 4Alkyl,
R 18Be halogen, nitro or cyano group and
R 19Be hydrogen, halogen, nitro, trifluoromethyl or cyano group;
Figure A0381948000111
Wherein:
R 20Be C 1-C 4Alkyl,
R 21Be unsubstituted or by C 1-C 4The C that alkoxyl replaces 1-C 4Alkyl and
R 22Be group-COOCH 2CH 2OC 6H 5And R 23Be hydrogen, or
R 22Be hydrogen and R 23Be-N=N-C 6H 5
Wherein:
Ring A and B are unsubstituted or by halogen list-or many-replacement;
Figure A0381948000113
Wherein:
R 24Be unsubstituted or by hydroxyl, C 1-C 4Alkoxyl, C 1-C 4Alkoxy-C 1-C 4Alkoxyl, C 2-C 4Alkanoyloxy or C 1-C 4The C that alkoxy carbonyl replaces 1-C 4Alkyl;
Figure A0381948000122
Wherein:
R 25Be C 1-C 4Alkyl,
R 26Be unsubstituted or by C 1-C 4The C that alkoxyl replaces 1-C 4Alkyl,
R 27Be hydrogen, C 1-C 4Alkoxy or halogen and
R 28Be hydrogen, nitro, halogen or phenylsulfonyloxy;
Figure A0381948000123
Wherein:
R 29, R 30, R 31And R 32Be hydrogen or halogen independently of one another,
R 33Be hydrogen, halogen, C 1-C 4Alkyl or C 1-C 4Alkoxyl,
R 34Be hydrogen, halogen or acylamino-and
R 35And R 36Be hydrogen independently of one another, or C unsubstituted or that replaced by hydroxyl, cyano group, acetoxyl group or phenoxy group 1-C 4Alkyl;
Or the dyestuff of following formula:
Figure A0381948000131
Wherein:
R 37It is hydrogen or halogen;
Figure A0381948000132
Wherein:
R 38Be hydrogen, C 1-C 4Alkyl, oxolane-2-base, or unsubstituted or at moieties by C 1-C 4The C that alkoxyl replaces 1-C 4Alkoxy carbonyl;
Wherein:
R 39Be hydrogen, or unsubstituted or at phenyl moiety by C 1-C 4Alkyl or C 1-C 4The thiophenyl that alkoxyl replaces,
R 40Be hydrogen, hydroxyl, amino, or phenylcarbonyl group amino, wherein phenyl moiety is unsubstituted or by C 1-C 4Alkyl replaces,
R 41Be hydrogen, halogen, cyano group or thiophenyl, phenoxy group or phenyl, wherein back each among the three all be unsubstituted or at phenyl moiety by C 1-C 4Alkyl or by C 1-C 4Alkoxyl replace and
R 42Be unsubstituted or at phenyl moiety by halogen, C 1-C 4Alkyl or C 1-C 4The phenyl that alkoxyl replaces;
Figure A0381948000141
Wherein:
R 43Be hydrogen or C 1-C 4Alkyl,
R 44And R 45Be hydrogen independently of one another, halogen, nitro or cyano group,
R 46Be hydrogen, halogen, C 1-C 4Alkyl or C 1-C 4Alkoxyl,
R 47Be hydrogen, halogen or C 2-C 4Alkanoylamino and
R 48And R 49Be hydrogen independently of one another, or unsubstituted or by hydroxyl, cyano group, C 1-C 4Alkoxyl, C 1-C 4Alkoxy-C 1-C 4Alkoxyl, C 2-C 4Alkanoyloxy or C 1-C 4The C that alkoxy carbonyl, phenyl or phenoxy group replace 1-C 4Alkyl; Or
Wherein:
R 50Be hydrogen or C 1-C 4Alkyl,
R 51Be phenyl or phenylcarbonyl group, the phenyl moiety of the two each all can be by C 1-C 4Alkyl replaces,
R 52And R 53Be hydrogen independently of one another, C 1-C 4Alkyl or C 1-C 4Alkoxyl and
R 54Be hydrogen or C 1-C 4Alkyl.
The example of the DISPERSE DYES that is used for the inventive method that can mention comprises the dyestuff of following formula:
Figure A0381948000152
Figure A0381948000153
Figure A0381948000154
Figure A0381948000155
Figure A0381948000158
Figure A0381948000161
Figure A0381948000164
Figure A0381948000173
Figure A0381948000174
Figure A0381948000181
Figure A0381948000182
Figure A0381948000183
Figure A0381948000192
Figure A0381948000193
Figure A0381948000194
Figure A0381948000195
Figure A0381948000201
Figure A0381948000203
Figure A0381948000205
Figure A0381948000211
Figure A0381948000212
Figure A0381948000213
With
Figure A0381948000223
Figure A0381948000231
Figure A0381948000234
With
Figure A0381948000235
With
The DISPERSE DYES that is used for the inventive method can be used separately or use with the form of mixtures of two or more DISPERSE DYES.
Preferred formula (1), (3), (4), (6), (8), (11), (12), DISPERSE DYES, the especially formula (3) of (13) and (14), (6), (8), (12), the DISPERSE DYES of (13) and (14).
Special preferred formula (3b), (3c), (3d), (3e), (3f), (3g), (6a), (6c), (8c), (8d), (12a), (12b), (12c), (12d), (13b), (13d), (13e) and DISPERSE DYES (14a).
More special preferred formula (1d), (1e), (1f), (1g), (1h), (1i), (1j), (1k), (4a), (6b), (8a), (8b), (8c), (8d), (11b), (13a), (13b), (13c), (13d), DISPERSE DYES (13e) and (13f).
The DISPERSE DYES of formula (1)-(14) is known or can be similar to known compound and prepares according to standard method, for example by usual diazotization, coupling, addition and condensation reaction preparation.
Suitable acrylic ester adhesive is the known adhesive of textiles pigment printing, comprise, for example, acrylate copolymer, as poly-(methyl) acrylate and (methyl) acrylate and suitable comonomer, such as acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, mesaconic acid, citraconic acid, vinylacetic acid, the vinyl fluoroacetic acid, the vinyl propionic acid, crotonic acid, aconitic acid, allyl acetic acid, the allyl fluoroacetic acid, allyl malonic acid, 2-acrylamide-2-methyl propane sulfonic acid, glutaconate or allyl succinic acid are perhaps with the ester of this acid, (methyl) acrylamide, the N-vinyl pyrrolidone, the N-vinyl formamide, the N-vinyl acetamide, (methyl) acrolein, N-vinyl-N-first is for acetamide, caprolactam, the mixed polymer of styrene derivative or vinyl phosphonate; The polyamide derivative; Synthetic resin dispersion; The vinyl mixed polymer; Diamides/aldehyde precondensate product; The mixed polymer that contains the N-vinyl lactam, and butadiene-based polymer.In the suitable acrylic ester adhesive water soluble medium or dissolve in contain can be miscible with water organic solvent, in case of necessity in the water-bearing media of exogenously added alkali.Described acrylic ester adhesive preferably uses with the form of aqueous formulation.This acrylic ester adhesive industrial can acid form or with partially or completely the neutralization form obtain, as Primal (Rohm ﹠amp; Haas), Neocryl (NeoResins), Carbocet (BF Goodrich), Joncryl (Johnson Polymers) or ALCOPRINT (Ciba Spezialitatenchemie) adhesive.
The suitable dispersible mylar of water-soluble or water-dilutable/water is that coatings industry is known, and wherein they are used to prepare the water based paint of environmental sound as adhesive.This mylar is referring to, US-A-4054614 for example.They preferably use with the form of aqueous formulation, and are the commercially available prod, as Dynapol (Degussa), Bayhydrol (Bayer) or Worlee Pol (Worlee) resin.
The weight ratio of mylar and acrylic ester adhesive in the composition (in the dry weight form) is, as 4: 1-1: 1, preferred 2: 1-1: 1.
In addition, also can use and the crosslinking agent of the hydroxyl reaction of acrylic ester adhesive and mylar.This crosslinking agent can with acrylic ester adhesive and mylar or before or after be applied on the fibrous material.Preferably, they are present in the Aquo-composition used according to the invention in addition, and are applied to fibrous material with acrylic ester adhesive and mylar.
Suitable crosslinking agent comprises, for example water miscible melamine, formaldehyde-melamine, and formaldehyde-urea resin or precondensate product are such as trimethylolmelamine, hexamethylolmelamine or dimethylol urea, or (in advance) condensation product and/or the water miscible organic sulfonate such as the naphthalene sulfonate salt of water miscible formaldehyde and formamide, thiocarbamide, guanidine, cyanamide, dicyandiamide, or the glyoxylurea derivative, as shown in the formula compound:
Figure A0381948000251
Especially the N-hydroxymethyl derivative of nitrogen-containing compound is as not the carbamide condensation product or the N-methylolurea compound of etherificate or etherificate.
The compound of following formula:
Figure A0381948000252
With
Figure A0381948000253
It is the example of the carbamide condensation product of etherificate or etherificate not.The N-methylolurea compound of etherificate or etherificate is not, for example, not etherificate or the formaldehyde of etherificate and the product of urea or urea derivative subsequently, the example of suitable urea derivative is ring-type ethylidene-or propylidene-urea (wherein also can comprise the substituting group such as hydroxyl in alkylidene), urones and triazone resin unsubstituted or that replace.
This N-methylolurea examples for compounds comprises unmodified and N-methylol-hydroxy ethylene urea product, for example compound of following formula modification:
Figure A0381948000261
Figure A0381948000262
With
Figure A0381948000263
With methylolation product based on propylidene urea or ethylidene-urea-melamine.
Preferred cross-linking agents comprises unmodified and N-methylol-hydroxy ethylene carbamide compound modification, based on the methylolation product of propylidene urea or ethylidene-urea-melamine, and the carbamide condensation product of etherificate or etherificate not especially.Also can use the mixture of two or more different water-soluble cross-linkers, for example the mixture of forming by unetherified carbamide condensation product and the carbamide condensation product that has only the part etherificate.
Suitable crosslinking agent is industrial known, for example commodity ALCOPRINR by name Product (Ciba Spezialitatenchemie).
If desired, can use crosslinking catalyst in addition.
The crosslinking catalyst that is suitable for the inventive method comprises, as, usually be used as any reagent of the catalyst of giving wrinkle resistant and shrinkproof performance, such as by Textilhilfsmittelkatalog, 1991, Konradin Verlag R.Kohlhammer, Leinfelden-Echterdingen, 1991 known those.The example of suitable crosslinking catalyst comprises inorganic acid, as phosphoric acid; Lewis acid is as zinc chloride, zirconium oxychloride, NaBF 4, AlCl 3, MgCl 2Ammonium salt is as ammonium sulfate, ammonium chloride; And the hydrochloride of hydrohalide, especially organic amine, as CH 3-CH 2-CH 2-NH-CH 3HCl.The preferred lewis acid that uses ammonium salt or contain magnesium especially uses ammonium chloride or magnesium chloride.
For the flexibility that increases dyeing or print the back fibrous material, and therefore obtain certain feel, Aquo-composition used according to the invention can comprise the reagent of giving the soft feel performance in addition.The reagent of giving soft feel is known in textile industry.They are softening agents of nonionic, anionic, cationic or both sexes.The particularly important is polysiloxane emulsion, the α of high molecular normally, ω-dimethicone.Be preferably based on the reagent of giving soft feel of silicone emulsion.The reagent of this soft feel industrial be known, ULTRATEX for example (Ciba Spezialittenchemie AG).
Preferred those of the fibrous material of cellulose comprise cellulosic blended fiber, as cellulose/polyester or cellulose/nylon blend, especially cellulose/cotton/polyester fiber blends.
Fibrous material can be the form processing of great kind, as is fiber, long filament, yarn, chip material, woven fabric or knitted fabric form, preferred woven fabric or knitted fabric.
Handling fibrous material with Aquo-composition can carry out or carry out simultaneously with it before dyeing or print steps.When handling and dyeing when carrying out simultaneously, colouring compositions, for example dye liquor or printing paste also comprise the said components that is present in the Aquo-composition, in addition such as acrylic ester adhesive and mylar.Preferably handled with Aquo-composition before material touches DISPERSE DYES, this is as the preliminary treatment before reality dyeing or print steps.Other preferred embodiment, except before dyeing or the print steps or with its carry out simultaneously first handle, also comprise the other processing of carrying out with Aquo-composition, this processing is the finishing processing of carrying out after dyeing or print steps.Advantageously, by using this post processing, can eliminate any washing and towards Xian's step.
Pretreatment fluid as aftertreatment fluid, can be applied on the fibrous material by many modes, for example according to consumption method (exhaust method), preferably by the pad dyeing method.
When handling with Aquo-composition as the preliminary treatment before dyeing or print steps, advantageously, fibrous material with the pretreatment fluid dipping is carried out drying steps, for example descended dry 0.5-10 minute, especially descended dry 1-4 minute, then at 100-120 ℃ at 80-140 ℃, make the polymerization masterbatch that is applied to fiber carry out condensation, for example, at 140-210 ℃ of following condensation 0.5-10 minute, especially at 150-180 ℃ of condensation 0.5-4 minute.
When after dyeing or print steps, choosing wantonly when carrying out post processing with Aquo-composition, advantageously, fibrous material with the aftertreatment fluid dipping is carried out drying steps, for example descended dry 0.5-10 minute at 80-140 ℃, especially descended dry 1-4 minute at 100-120 ℃, make the polymerization masterbatch that is applied to fiber carry out condensation then, for example, at 140-210 ℃ of following condensation 0.5-10 minute, especially at 150-180 ℃ of condensation 0.5-4 minute.
The amount of the said components (with dry weight basis) that is comprised in the Aquo-composition used according to the invention for example is (in the weight of treatment fluid) shown below:
Acrylic ester adhesive: 2-20 weight %, preferred 5-20 weight %
Mylar: 2-20 weight %, preferred 5-20 weight %
Crosslinking agent: 0-5 weight %
Softening agent: 0-10 weight %
The fibrous material of cellulose can for example according to thermosol method, consumption method or continuity method, dye with DISPERSE DYES according to the conventional process that becomes known for polyester fiber is dyeed.Preferred consumption method.Liquor ratio depends on device parameter, substrate and appearance form, but can select in very wide scope, for example 1: 4-1: in 100 the scope, preferably 1: 6-1: in 25 the scope.
Useful is that the DISPERSE DYES that will use was converted into dye formulations before using.For this reason, the dyestuff grinding is made that its particle mean size is the 0.1-10 micron.Grinding can be carried out in the presence of dispersant.For example, dried dye is ground with dispersant, perhaps knead into paste form, then vacuumize or spray drying with dispersant.The gained preparation can be used for preparing printing paste and dye bath after adding entry.
Under the printing situation, should use usual thickener, as modification or unmodified natural products, alginate for example, dextrin, gum Arabic, crystal gum, carob pod fruit powder, bassora gum, carboxymethyl cellulose, hydroxyethylcellulose, starch or synthetic products, for example polyacrylamide, polyacrylic acid or its copolymer, perhaps polyvinyl alcohol.
Printing also can be carried out according to the ink jet printing method.In several years of past, use the ink jet printing method to form the existing significantly increase of importance of printing textile.This method comprises independent droplet of ink is sprayed on the base material from nozzle in a controlled manner.For this reason, mainly use the continous inkjet method and become to drip method (drop-on-demand method) as required.In the continous inkjet method, drop continuously forms, and the unwanted drop of printing operation is discharged in the recipient and is recycled usually.And becoming to drip as required in the method, drop forms as required and is used for printing, that is to say, has only just to produce drop when printing operation needs.
Advantageously, for example, can or utilize heat energy (so-called bubbling spray gun) to produce drop by means of the pressure ink gun.For method of the present invention, preferably according to the continous inkjet method or the method for become dripping as required print.The preparation of required DISPERSE DYES printing ink and print process program are referring to, US-A-6284004 for example.
Except comprising aforesaid component, pretreatment fluid or dye composite can also comprise other component, as stabilizing agent, such as ultraviolet absorber, light stabilizer, antioxidant or the like.
Treatment in accordance with the present invention makes cellulose fibre can use disperse dyeing.Thereby the dyeing and the printing process of blended fiber have been simplified in fact.Therefore, can use a kind of dyestuff (DISPERSE DYES) simultaneously all components of blended fiber to be dyeed, that is to say, except polyester components dyeing, use identical dyestuff also will dye to cellulosic component without a doubt with cellulose/cotton/polyester fiber blends.
In addition, method of the present invention satisfies very important demand,, when it is used for blended fiber, keeps the stainability of polyester components fully that is.In addition, be applied to acrylic ester adhesive matrix on the fiber and mylar under the condition of the high-temp dyeing process that is common to polyester, as can intactly keeping in following 30 minutes, and be without prejudice at 130 ℃.
The dyeing or the printed matter that use method of the present invention to obtain have good fastness rate and sufficient wet fastness properties, such as fastness to washing, and water-fast, seawater, anti-cross dyeing and absorption of perspiration.In addition, with regard to fiber and pigmented section, can obtain dyeing uniformly.
Following examples are intended to illustrate the present invention, rather than limit the invention to the embodiment that these specifically provide.
Embodiment 1:
A) to carrying out pad dyeing by the cotton textile fabric of forming of 100% bleaching with liquid, aqueous (liquid is inhaled slurry rate 70%) of containing following additive, each additive is aqueous formulation, and its amount is as follows:
Acrylic ester adhesive (the ALCOPRINT of 100g/l PB-HC),
The methylol of 10g/l-melamine crosslinked resin (ALCOPRINT PFL),
Washable softening agent (the ULTRATEX of 50g/l FSA),
Water-soluble polyester resin (the Worlee of 100g/l Pol 192)
Then with impregnate fabric 120 ℃ of dryings 2 minutes.And further make the polymerization masterbatch that applies 180 ℃ of following condensations 2 minutes.
B) 10g is incorporated in the dye liquor that 100ml contains following composition according to a) pretreated fabric:
0.1g the DISPERSE DYES of formula (4b),
0.1g DISPERSE DYES (UNIVADIN DP),
0.1g degasser (ALBEGAL FFD),
0.1 ammonium sulfate,
With pH regulator to 4.5, and in pressure vessel, be heated to 130 ℃ with acetic acid,diluted.130 ℃ after following 30 minutes, with liquid cools, remove dyeing, cold rinse was scrubbed under 95 ℃ 15 minutes in the presence of wetting agent, washes once more, drying, and by xeothermic solid shape finishing (under 180 ℃, carrying out 30 seconds).
Obtain showing the orange product that dye of high homogeneity and fully comprehensive durability.
Embodiment 2:
As described in embodiment 1, experimentize, but be to use, equally also obtain showing the orange product that dye of high homogeneity and fully comprehensive durability by woven fabric rather than spun cotton fabric that 50% cotton/50% cotton/polyester fiber blends is formed.
Embodiment 3:
A) textile fabric of being made up of the cotton of 100% bleaching is carried out pad dyeing with liquid, aqueous (liquid is inhaled slurry rate 70%) of containing following additive, each additive is aqueous formulation, and its amount is as follows:
Acrylic ester adhesive (the ALCOPRINT of 100g/l PB-HC),
The methylol of 10g/l-melamine crosslinked resin (ALCOPRINT PFL),
Water-soluble polyester resin (the Worlee of 100g/l Pol 192),
14.3g/l dye formulation, wherein comprise the active material of the formula (4b) that 43 weight % grind very carefully.
Then with impregnate fabric 120 ℃ of dryings 2 minutes, make the polymerization masterbatch that applies further 180 ℃ of following condensations 2 minutes, cold punching Xian scrubbed 5 minutes at 95 ℃ afterwards, carried out towards Xian once more afterwards.Obtain the uniformly orange cotton of dying, it shows the fastness rate of height, sufficient resistance to water and the degree of anti-the wiping.
Embodiment 4:
As described in embodiment 3, experimentize, but be to use, equally also obtain showing the orange product that dye of high homogeneity and fully comprehensive durability by woven fabric rather than spun cotton fabric that 50% cotton/50% cotton/polyester fiber blends is formed.
Embodiment 5:
A) textile fabric of being made up of the cotton of 100% bleaching is carried out pad dyeing with liquid, aqueous (liquid is inhaled slurry rate 70%) of containing following additive, each additive is aqueous formulation, and its amount is as follows:
Acrylic ester adhesive (the ALCOPRINT of 100g/l PB-HC),
The methylol of 10g/l-melamine crosslinked resin (ALCOPRINT PFL),
Water-soluble polyester resin (the Worlee of 100g/l Pol 192),
14.3g/l dyeing recipe, wherein comprise the active material of the formula (12a) that 43 weight % grind very carefully.
Then with impregnate fabric 120 ℃ of dryings 2 minutes, make the polymerization masterbatch that applies further 200 ℃ of following condensations 2 minutes.With comprising the liquid, aqueous of following additive fabric is carried out pad dyeing (liquid is inhaled slurry rate 70%) then, each additive is aqueous formulation, and its amount is as follows:
Acrylic ester adhesive (the ALCOPRINT of 100g/l PB-HC),
The methylol methylol of 20g/l-melamine crosslinked resin (ALCOPRINT PFL),
Water-soluble polyester resin (the Worlee of 100g/l Pol 192).
Then with impregnate fabric 120 ℃ of dryings 2 minutes, make the polymerization masterbatch that applies further 200 ℃ of following condensations 2 minutes, without other washing with towards Xian's step, promptly obtain uniform yellow and dye cotton, it shows fastness rate and sufficient resistance to water, washability and the degree of anti-wiping of height.
Embodiment 6:
As described in embodiment 5, experimentize, but be to use, equally also obtain showing the orange product that dye of high homogeneity and fully comprehensive durability by woven fabric rather than spun cotton fabric that 50% cotton/50% cotton/polyester fiber blends is formed.
Embodiment 7:
State as embodiment 1 and to experimentize, and use following prescription carry out preliminary treatment (step a):
Acrylate thickener (the ALCOPRINT of 24g/l PTF),
Acrylic ester adhesive (the ALCOPRINT of 100g/l PB-HC),
Washable softening agent (the ULTRATEX of 50g/l FSA),
Water-soluble polyester resin (the Worlee of 100g/l Pol 192),
30% the ammonium hydroxide of 5g/l,
Use serigraphy paraffin paper to apply printing paste, then with impregnate fabric 120 ℃ of dryings 2 minutes, make the polymerization masterbatch that applies in addition 180 ℃ of following condensations 2 minutes, subsequently as the b among the embodiment 1) as described in fabric is dyeed, use serigraphy paraffin paper to apply on the position of dyestuff, equally also obtaining showing the orange product that dye of high homogeneity and fully comprehensive durability.
Embodiment 8-59:
As described in embodiment 1, experimentize, but use formula (1a), (1b), (1c), (1d), (1e), (1f1, (1g), (1h), (1i), (1j), (1k), (2a), (2b), (2c), (2d), (2e), (20, (2g), (3a), (3b), (3c), (3d), (3e), (3f), (3g), (4a), (5a), (6a), (6b), (6c), (7), (8a), (8b), (8c), (8d), (9a), (9b), (10a), (11a), (11b), (11c), (12a), (12b), (12c), (12d), (13a), (13b), (13c), (13d), (13e), the dyestuff of a kind of rather than formula (4b) in the dyestuff (13f) and (14a) also obtains having the product that dye of respective color color and luster, and it demonstrates the uniformity of height and fully comprehensive durability.
Embodiment 60-111:
As described in embodiment 2, experimentize, but use formula (1a), (1b), (1c), (1d), (1e), (10, (1g), (1h), (1i), (1j), (1k), (2a), (2b), (2c), (2d), (2e), (2f), (2g), (3a), (3b), (3c), (3d), (3e), (3f), (3g), (4a), (5a), (6a), (6b), (6c), (7), (8a), (8b), (8c), (8d), (9a), (9b), (10a), (11a), (11b), (11c), (12a), (12b), (12c), (12d), (13a), (13b), (13c), (13d), (13e), the dyestuff of a kind of rather than formula (4b) in the dyestuff (13f) and (14a) also obtains having the product that dye of respective color color and luster, and it demonstrates the uniformity of height and fully comprehensive durability.
Embodiment 112-163:
As described in embodiment 3, experimentize, but use formula (1a), (1b), (1c), (1d), (1e), (10, (19), (1h), (1i), (1j), (1k), (2a), (2b), (2c), (2d), (2e), (2f), (2g), (3a), (3b), (3c), (3d), (3e), (3f), (3g), (4a), (5a), (6a), (6b), (6c), (7), (8a), (8b), (8c), (8d), (9a), (9b), (10a), (11a), (11b), (11c), (12a), (12b), (12c), (12d), (13a), (13b), (13c), (13d), (13e), the dyestuff of a kind of rather than formula (4b) in the dyestuff (13f) and (14a) also obtains having the product that dye of respective color color and luster, and it demonstrates the uniformity of height and fully comprehensive durability.
Embodiment 164-215:
As described in embodiment 4, experimentize, but use formula (1a), (1b), (1c), (1d), (1e), (10, (1g), (1h), (1i), (1j), (1k), (2a), (2b), (2c), (2d), (2e), (2f), (2g), (3a), (3b), (3c), (3d), (3e), (3f), (3g), (4a), (5a), (6a), (6b), (6c), (7), (8a), (8b), (8c), (8d), (9a), (9b), (10a), (11a), (11b), (11c), (12a), (12b), (12c), (12d), (13a), (13b), (13c), (13d), (13e), the dyestuff of a kind of rather than formula (4b) in the dyestuff (13f) and (14a) also obtains having the product that dye of respective color color and luster, and it demonstrates the uniformity of height and fully comprehensive durability.
Embodiment 216-267:
As described in embodiment 5, experimentize, but use formula (1a), (1b), (1c), (1d), (1e), (10, (1g), (1h), (1i), (1j), (1k), (2a), (2b), (2c), (2d), (2e), (2f), (2g), (3a), (3b), (3c), (3d), (3e), (3f), (3g), (4a), (5a), (6a), (6b), (6c), (7), (8a), (8b), (8c), (8d), (9a), (9b), (10a), (11a), (11b), (11c), (12a), (12b), (12c), (12d), (13a), (13b), (13c), (13d), (13e), the dyestuff of a kind of rather than formula (4b) in the dyestuff (13f) and (14a) also obtains having the product that dye of respective color color and luster, and it demonstrates the uniformity of height and fully comprehensive durability.
Embodiment 268-319:
As described in embodiment 6, experimentize, but use formula (1a), (1b), (1c), (1d), (1e), (10, (19), (1h), (1i), (1j), (1k), (2a), (2b), (2c), (2d), (2e), (2f), (2g), (3a), (3b), (3c), (3d), (3e), (3f), (3g), (4a), (5a), (6a), (6b), (6c), (7), (8a), (8b), (8c), (8d), (9a), (9b), (10a), (11a), (11b), (11c), (12a), (12b), (12c), (12d), (13a), (13b), (13c), (13d), (13e), the dyestuff of a kind of rather than formula (4b) in the dyestuff (13f) and (14a) also obtains having the product that dye of respective color color and luster, and it demonstrates the uniformity of height and fully comprehensive durability.
Embodiment 320-371:
As described in embodiment 7, experimentize, but use formula (1a), (1b), (1c), (1d), (1e), (10, (19), (1h), (1i), (1j), (1k), (2a), (2b), (2c), (2d), (2e), (2f), (2g), (3a), (3b), (3c), (3d), (3e), (3f), (3g), (4a), (5a), (6a), (6b), (6c), (7), (8a), (8b), (8c), (8d), (9a), (9b), (10a), (11a), (11b), (11c), (12a), (12b), (12c), (12d), (13a), (13b), (13c), (13d), (13e), the dyestuff of a kind of rather than formula (4b) in the dyestuff (13f) and (14a) also obtains having the product that dye of respective color color and luster, and it demonstrates the uniformity of height and fully comprehensive durability.

Claims (10)

1. one kind is used DISPERSE DYES that the fibrous material of cellulose is dyeed or method of printing, and it comprises with the Aquo-composition that contains water-soluble or water dispersible mylar and water-soluble or water dispersible acrylic ester adhesive handles described fibrous material.
2. according to the process of claim 1 wherein that DISPERSE DYES is equivalent to following formula:
Figure A038194800002C1
Wherein:
R 1Be halogen, nitro or cyano group,
R 2Be hydrogen, halogen, nitro or cyano group,
R 3Be hydrogen, halogen or cyano group,
R 4Be hydrogen, halogen, C 1-C 4Alkyl or C 1-C 4Alkoxyl,
R 5Be hydrogen, halogen or C 2-C 4Alkanoylamino and
R 6And R 7Be hydrogen independently of one another, allyl, or unsubstituted or by hydroxyl, cyano group, C 1-C 4Alkoxyl, C 1-C 4Alkoxy-C 1-C 4Alkoxyl, C 2-C 4Alkanoyloxy, C 1-C 4The C that alkoxy carbonyl, phenyl or phenoxy group replace 1-C 4Alkyl;
Figure A038194800002C2
Wherein:
R 8Be hydrogen, phenyl or benzenesulfonyl, the phenyl ring in phenyl and the benzenesulfonyl are unsubstituted or by C 1-C 4Alkyl, sulfo group or by C 1-C 4Alkylsulfonyloxy replaces,
R 9Be unsubstituted or C 1-C 4The amino that alkyl replaces, or hydroxyl,
R 10Be hydrogen or C 1-C 4Alkoxyl,
R 11Be hydrogen, C 1-C 4Alkoxyl, phenoxy group or group-O-C 6H 5-SO 2-NH-(CH 2) 3-O-C 2H 5,
R 12Be hydrogen, hydroxyl or nitro and
R 13Be hydrogen, hydroxyl or nitro;
Figure A038194800003C1
Wherein:
R 14Be C unsubstituted or that replaced by hydroxyl or phenyl 1-C 4Alkyl, or phenyl,
R 15Be C 1-C 4Alkyl,
R 16Be cyano group,
R 17Be formula-(CH 2) 3-O-(CH 2) 2-O-C 6H 5Group, phenyl, or the C that is replaced by hydroxyl or phenyl 1-C 4Alkyl,
R 18Be halogen, nitro or cyano group and
R 19Be hydrogen, halogen, nitro, trifluoromethyl or cyano group;
Wherein:
R 20Be C 1-C 4Alkyl,
R 21Be unsubstituted or by C 1-C 4The C that alkoxyl replaces 1-C 4Alkyl and
R 22Be group-COOCH 2CH 2OC 6H 5And R 23Be hydrogen, or
R 22Be hydrogen and R 23Be-N=N-C 6H 5
Wherein:
Ring A and B are unsubstituted or by halogen list-or many-replacement;
Figure A038194800004C2
Wherein:
R 24Be unsubstituted or by hydroxyl, C 1-C 4Alkoxyl, C 1-C 4Alkoxy-C 1-C 4Alkoxyl, C 2-C 4Alkanoyloxy or C 1-C 4The C that alkoxy carbonyl replaces 1-C 4Alkyl;
Wherein:
R 25Be C 1-C 4Alkyl,
R 26Be unsubstituted or by C 1-C 4The C that alkoxyl replaces 1-C 4Alkyl,
R 27Be hydrogen, C 1-C 4Alkoxy or halogen and
R 28Be hydrogen, nitro, halogen or phenylsulfonyloxy;
Wherein:
R 29, R 30, R 31And R 32Be hydrogen or halogen independently of one another,
R 33Be hydrogen, halogen, C 1-C 4Alkyl or C 1-C 4Alkoxyl,
R 34Be hydrogen, halogen or acylamino-and
R 35And R 36Be hydrogen independently of one another, or C unsubstituted or that replaced by hydroxyl, cyano group, acetoxyl group or phenoxy group 1-C 4Alkyl;
Or the dyestuff of following formula:
Wherein:
R 37It is hydrogen or halogen;
Figure A038194800005C3
Wherein:
R 38Be hydrogen, C 1-C 4Alkyl, oxolane-2-base, or unsubstituted or at moieties by C 1-C 4The C that alkoxyl replaces 1-C 4Alkoxy carbonyl;
Wherein:
R 39Be hydrogen, or unsubstituted or at phenyl moiety by C 1-C 4Alkyl or C 1-C 4The thiophenyl that alkoxyl replaces,
R 40Be hydrogen, hydroxyl, amino, or phenylcarbonyl group amino, wherein phenyl moiety is unsubstituted or by C 1-C 4Alkyl replaces,
R 41Be hydrogen, halogen, cyano group or thiophenyl, phenoxy group or phenyl, wherein back each among the three all be unsubstituted or at phenyl moiety by C 1-C 4Alkyl or by C 1-C 4Alkoxyl replace and
R 42Be unsubstituted or at phenyl moiety by halogen, C 1-C 4Alkyl or C 1-C 4The phenyl that alkoxyl replaces;
Figure A038194800006C2
Wherein:
R 43Be hydrogen or C 1-C 4Alkyl,
R 44And R 45Be hydrogen independently of one another, halogen, nitro or cyano group,
R 46Be hydrogen, halogen, C 1-C 4Alkyl or C 1-C 4Alkoxyl,
R 47Be hydrogen, halogen or C 2-C 4Alkanoylamino and
R 48And R 49Be hydrogen independently of one another, or unsubstituted or by hydroxyl, cyano group, C 1-C 4Alkoxyl, C 1-C 4Alkoxy-C 1-C 4Alkoxyl, C 2-C 4Alkanoyloxy or C 1-C 4The C that alkoxy carbonyl, phenyl or phenoxy group replace 1-C 4Alkyl; Or
Figure A038194800007C1
Wherein:
R 50Be hydrogen or C 1-C 4Alkyl,
R 51Be phenyl or phenylcarbonyl group, the phenyl moiety of the two each all can be by C 1-C 4Alkyl replaces,
R 52And R 53Be hydrogen independently of one another, C 1-C 4Alkyl or C 1-C 4Alkoxyl and
R 54Be hydrogen or C 1-C 4Alkyl.
3. according to the method for claim 1 or 2, wherein Aquo-composition comprises crosslinking agent in addition.
4. according to each method of claim 1-3, wherein Aquo-composition comprises the reagent of giving the soft feel performance in addition.
5. according to each method of claim 1-4, wherein with Aquo-composition handle fibrous material described material with carry out as preliminary treatment before DISPERSE DYES contacts.
6. according to the method for claim 5, wherein in pre-treatment step with the impregnated fibrous material dries of Aquo-composition and make the polymer master batch condensation that applies.
7. according to each method of claim 1-6, wherein after dyeing course, further handle described fibrous material with Aquo-composition.
8. according to each method of claim 1-7, wherein the fibrous material of cellulose is a blended fiber.
9. according to each method of claim 1-8, the blended fiber formed by cellulose and polyester of the fibrous material of cellulose wherein.
10. according to each method of claim 1-9, wherein the weight ratio of mylar and acrylic resin is 4 in the composition: 1-1: 1.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103459709A (en) * 2011-03-31 2013-12-18 国际人造丝公司 Disperse dyeing of textile fibers
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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127315A (en) * 2010-12-24 2011-07-20 上海宜连化工科技有限公司 Blue disperse dye composition with high light fastness and application thereof
WO2013130429A1 (en) 2012-02-29 2013-09-06 Celanese International Corporation Production of dyed cotton fibers
WO2013130352A2 (en) 2012-03-01 2013-09-06 Ticona Llc Polyarylene sulfide fibers containing an emulsion copolymer coating
WO2013148295A2 (en) 2012-03-30 2013-10-03 Celanese International Corporation Disperse dyeing of textile fibers
US20150275423A1 (en) * 2014-04-01 2015-10-01 Randolph L. Finley Ring dyed materials and method of making the same
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US11008700B2 (en) * 2017-03-29 2021-05-18 Huntsman International Llc Process for printing cellulose containing textile fibre material
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Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3510241A (en) * 1966-11-16 1970-05-05 Allied Chem Coloration of aromatic polyesters
JPS5029552B2 (en) * 1972-07-25 1975-09-23
DE2551432B2 (en) * 1975-11-15 1978-10-19 Hoechst Ag, 6000 Frankfurt Process for pad dyeing and printing of materials made from optionally regenerated cellulose and mixtures thereof with polyester or modified cellulose
US4054614A (en) * 1976-02-23 1977-10-18 Celanese Corporation Water soluble polyester coating compositions
DE2901823C2 (en) * 1979-01-18 1983-12-08 Basf Ag, 6700 Ludwigshafen Process for printing textile materials
JPS56148981A (en) * 1980-03-25 1981-11-18 Donkurofuto Karaazu Ando Chem Sublimable dyestuff transfer printing method and composition
US4702742A (en) * 1984-12-10 1987-10-27 Canon Kabushiki Kaisha Aqueous jet-ink printing on textile fabric pre-treated with polymeric acceptor
KR920701562A (en) * 1989-02-08 1992-08-12 한스 게오르그 우르바흐, 한스 오이흐너 Dyeing and printing method of blended polyester and natural fiber materials
JPH0762258A (en) * 1993-08-26 1995-03-07 Sumitomo Chem Co Ltd Benzodifuranone-containing red coloring composition and method for coloring hydrophobic material using the same
US5554734A (en) * 1994-06-20 1996-09-10 Ciba-Geigy Corporation AZO dyes containing a bridge member based on stibene and morpholino-substituted triazine
US6113656A (en) * 1995-01-17 2000-09-05 Milliken & Company Method of dyeing low pill polyester
TW515859B (en) * 1997-12-17 2003-01-01 Ciba Sc Holding Ag Process for ink-jet printing textile fibre materials

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