CN1410578A - Production technology of high silicon manganese-silicon alloy - Google Patents
Production technology of high silicon manganese-silicon alloy Download PDFInfo
- Publication number
- CN1410578A CN1410578A CN02114376.5A CN02114376A CN1410578A CN 1410578 A CN1410578 A CN 1410578A CN 02114376 A CN02114376 A CN 02114376A CN 1410578 A CN1410578 A CN 1410578A
- Authority
- CN
- China
- Prior art keywords
- silicon
- manganese
- liquid
- ferrosilicon
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 229910000676 Si alloy Inorganic materials 0.000 title claims abstract description 15
- FHTCLMVMBMJAEE-UHFFFAOYSA-N bis($l^{2}-silanylidene)manganese Chemical compound [Si]=[Mn]=[Si] FHTCLMVMBMJAEE-UHFFFAOYSA-N 0.000 title claims description 14
- 238000005516 engineering process Methods 0.000 title claims description 9
- 239000007788 liquid Substances 0.000 claims abstract description 26
- PYLLWONICXJARP-UHFFFAOYSA-N manganese silicon Chemical compound [Si].[Mn] PYLLWONICXJARP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 238000007670 refining Methods 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 7
- 238000006477 desulfuration reaction Methods 0.000 claims description 6
- 230000023556 desulfurization Effects 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 238000010079 rubber tapping Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052710 silicon Inorganic materials 0.000 abstract description 3
- 239000010703 silicon Substances 0.000 abstract description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract description 2
- 235000011941 Tilia x europaea Nutrition 0.000 abstract description 2
- 239000003610 charcoal Substances 0.000 abstract description 2
- 239000000571 coke Substances 0.000 abstract description 2
- 239000004571 lime Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 239000011572 manganese Substances 0.000 description 4
- 229910000616 Ferromanganese Inorganic materials 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910000720 Silicomanganese Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
Landscapes
- Silicon Compounds (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Abstract
The existing technique of 'one step method' is adopted for producing the manganese-silicon alloy with high silicon that utilizes the dregs rich in manganese, silica, coke, charcoal and lime to manufacture the alloy in ore hot furnace. The one step method possesses the drawbacks of high requirement for the raw materials, high production cost and difficult operation. In the invention, two electric furnaces are used for matching the production process. One electric furnace produces general liquid manganese-silicon and the other produces liquid ferrosilicon. Then, the manganese-silicon and ferrosilicon are mixed together outside furnaces in hot condition. With phosphor removal agent and desulphurized being added in the said admixture, refining and pouring produces the commodity of the alloy.
Description
Technical field
The present invention relates to a kind of smelting process for production of high silicomanganese silicon.
Background technology
High silicon manganese-silicon alloy is the reductive agent of alloying constituent, complex deoxidization sweetening agent and smelting low carbon ferromanganese in steel-making and the casting.Existing high silicon manganese-silicon alloy production technique is with rich manganese slag, silica, coke, charcoal, lime, single stage method production in the hot stove in ore deposit, this production technique is high to raw-material requirement, the production cost height, and operation is difficulty, the production difficulty is big, therefore, develop a kind of new high silicon manganese-silicon alloy production technique, can control production cost preferably, operation has easily become current important topic again.
Summary of the invention
It is low to the purpose of this invention is to provide a kind of cost, easy-operating MANUFACTURE OF SILICO-FERROMANGANESE WITH HIGH-SILICON technology.
The objective of the invention is to realize in the following way: a kind of production technology of high silicon manganese-silicon alloy, adopt two electric furnaces to form a complete production network, an electric furnace is produced common liquid manganese-silicon, another electric furnace is produced liquid ferrosilicon, carrying out the outer heat of stove then converts, and add dephosphorization and desulfurization agent refining, cast, form the commodity high silicon manganese-silicon alloy at last;
The composition of liquid ferrosilicon requires: Si 〉=65%, P≤0.04%, S≤0.02%,
The composition of liquid manganese-silicon requires: Si 〉=18%, Mn 〉=66%, P≤0.1%, S≤0.01%;
Liquid manganese-silicon is blended in the liquid ferrosilicon, add the dephosphorization and desulfurization agent, ladle-to-ladle repeatedly or shaking ladle between two hot metal ladle then, liquid manganese-silicon and liquid ferrosilicon are fully reacted, carry out bottom pouring after calm 5-15 minute, tapping a blast furnace from two electric furnaces should be controlled in 80 minutes to the duration of pouring.
The present invention has satisfied the requirement of users at home and abroad to high silicon manganese-silicon alloy composition Si 〉=25%, Mn 〉=55%, C≤0.5%, P≤0.1%, S≤0.01%, and production cost is low, has the market competitiveness.Description of drawings
Fig. 1 is a process flow sheet of the present invention;
Embodiment
The present invention will be further described below in conjunction with accompanying drawing;
As shown in Figure 1, a kind of production technology of high silicon manganese-silicon alloy, adopt two electric furnaces to form a complete production network, an electric furnace is produced common liquid manganese-silicon, another electric furnace is produced liquid ferrosilicon, carry out the outer heat of stove then and convert, and add dephosphorization and desulfurization agent refining, cast, form the commodity high silicon manganese-silicon alloy at last;
The composition of liquid ferrosilicon requires: Si 〉=65%, P≤0.04%, S≤0.02%,
The composition of liquid manganese-silicon requires: Si 〉=18%, Mn 〉=66%, P≤0.1%, S≤0.01%;
Liquid manganese-silicon is blended in the liquid ferrosilicon, add the dephosphorization and desulfurization agent, ladle-to-ladle repeatedly or shaking ladle between two hot metal ladle then, liquid manganese-silicon and liquid ferrosilicon are fully reacted, carry out bottom pouring after calm 5-15 minute, tapping a blast furnace from two electric furnaces should be controlled in 80 minutes to the duration of pouring.
Claims (3)
1, a kind of production technology of high silicon manganese-silicon alloy, it is characterized in that: adopt two electric furnaces to form a complete production network, an electric furnace is produced common liquid manganese-silicon, another electric furnace is produced liquid ferrosilicon, carrying out the outer heat of stove then converts, and add dephosphorization and desulfurization agent refining, cast, form the commodity high silicon manganese-silicon alloy at last.
2, production technology of high silicon manganese-silicon alloy according to claim 1 is characterized in that:
The composition of liquid ferrosilicon requires: Si 〉=65%, P≤0.04%, S≤0.02%,
The composition of liquid manganese-silicon requires: Si 〉=18%, Mn 〉=66%, P≤0.1%, S≤0.01%.
3, production technology of high silicon manganese-silicon alloy according to claim 1, it is characterized in that: liquid manganese-silicon is blended in the liquid ferrosilicon, add the dephosphorization and desulfurization agent, ladle-to-ladle repeatedly or shaking ladle between two hot metal ladle then, liquid manganese-silicon and liquid ferrosilicon are fully reacted, carry out bottom pouring after calm 5-15 minute, tapping a blast furnace from two electric furnaces should be controlled in 80 minutes to the duration of pouring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021143765A CN1153840C (en) | 2002-08-29 | 2002-08-29 | Production technology of high silicon manganese-silicon alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021143765A CN1153840C (en) | 2002-08-29 | 2002-08-29 | Production technology of high silicon manganese-silicon alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1410578A true CN1410578A (en) | 2003-04-16 |
| CN1153840C CN1153840C (en) | 2004-06-16 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021143765A Expired - Lifetime CN1153840C (en) | 2002-08-29 | 2002-08-29 | Production technology of high silicon manganese-silicon alloy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1153840C (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100415909C (en) * | 2006-08-17 | 2008-09-03 | 偏关县晋电化工有限责任公司 | Production method of silicomangan of sintering powder by rotary kiln and hot filling in ore-smelting electric furnace |
| CN102071331A (en) * | 2011-02-15 | 2011-05-25 | 江苏大学 | Smelting preparation method of high-purity high-silicon manganese-silicon alloy |
| CN102367518A (en) * | 2011-09-29 | 2012-03-07 | 云南文山斗南锰业股份有限公司 | Preparation method of manganese-silicon alloy |
| CN102766775A (en) * | 2012-07-30 | 2012-11-07 | 五矿（湖南）铁合金有限责任公司 | Production method of low-carbon high-silica silicomanganese |
| CN103710543A (en) * | 2013-12-27 | 2014-04-09 | 广西铁合金有限责任公司 | Method for producing low-carbon high-silicon manganese-silicon alloy from manganese-containing industrial waste slag through two-step method |
| CN105112662A (en) * | 2015-08-10 | 2015-12-02 | 云南文山斗南锰业股份有限公司 | Method for preparing high-silicon silicon-manganese alloy |
| CN105112661A (en) * | 2015-08-10 | 2015-12-02 | 云南文山斗南锰业股份有限公司 | Method for preparing silicomanganese with high silicon |
-
2002
- 2002-08-29 CN CNB021143765A patent/CN1153840C/en not_active Expired - Lifetime
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100415909C (en) * | 2006-08-17 | 2008-09-03 | 偏关县晋电化工有限责任公司 | Production method of silicomangan of sintering powder by rotary kiln and hot filling in ore-smelting electric furnace |
| CN102071331A (en) * | 2011-02-15 | 2011-05-25 | 江苏大学 | Smelting preparation method of high-purity high-silicon manganese-silicon alloy |
| CN102071331B (en) * | 2011-02-15 | 2012-08-29 | 江苏大学 | Smelting preparation method of high-purity high-silicon manganese-silicon alloy |
| CN102367518A (en) * | 2011-09-29 | 2012-03-07 | 云南文山斗南锰业股份有限公司 | Preparation method of manganese-silicon alloy |
| CN102766775A (en) * | 2012-07-30 | 2012-11-07 | 五矿（湖南）铁合金有限责任公司 | Production method of low-carbon high-silica silicomanganese |
| CN103710543A (en) * | 2013-12-27 | 2014-04-09 | 广西铁合金有限责任公司 | Method for producing low-carbon high-silicon manganese-silicon alloy from manganese-containing industrial waste slag through two-step method |
| CN103710543B (en) * | 2013-12-27 | 2016-04-06 | 广西铁合金有限责任公司 | Utilize the method for producing low carbon and high silicon manganese-silicon containing manganese industrial residue two step method |
| CN105112662A (en) * | 2015-08-10 | 2015-12-02 | 云南文山斗南锰业股份有限公司 | Method for preparing high-silicon silicon-manganese alloy |
| CN105112661A (en) * | 2015-08-10 | 2015-12-02 | 云南文山斗南锰业股份有限公司 | Method for preparing silicomanganese with high silicon |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1153840C (en) | 2004-06-16 |
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| C06 | Publication | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: WUKUANG(HUNAN)FERRUM ALLOY CO., LTD. Free format text: FORMER OWNER: HUNAN FERROALLOY GROUP CO., LTD. Effective date: 20080620 |
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| C41 | Transfer of patent application or patent right or utility model | ||
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Effective date of registration: 20080620 Address after: Xin Xiang West Road, Xiangxiang, Hunan Patentee after: MINMETALS (HUNAN) FERROALLOYS Co.,Ltd. Address before: Xiangxiang city of Hunan Province Patentee before: Hunan Iron Alloy Group Co.,Ltd. |
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| CX01 | Expiry of patent term | ||
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Granted publication date: 20040616 |