CN1307276C - Environmental protection fire retardant hot-melt film adhesive in user for electric clothes - Google Patents
Environmental protection fire retardant hot-melt film adhesive in user for electric clothes Download PDFInfo
- Publication number
- CN1307276C CN1307276C CNB2005100949099A CN200510094909A CN1307276C CN 1307276 C CN1307276 C CN 1307276C CN B2005100949099 A CNB2005100949099 A CN B2005100949099A CN 200510094909 A CN200510094909 A CN 200510094909A CN 1307276 C CN1307276 C CN 1307276C
- Authority
- CN
- China
- Prior art keywords
- environmental protection
- hot
- user
- melt adhesive
- fire retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000007613 environmental effect Effects 0.000 title claims abstract description 15
- 239000003063 flame retardant Substances 0.000 title claims description 21
- 239000000853 adhesive Substances 0.000 title claims description 12
- 230000001070 adhesive effect Effects 0.000 title claims description 12
- 239000012943 hotmelt Substances 0.000 title claims description 12
- 239000004744 fabric Substances 0.000 claims abstract description 18
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical class [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 150000007973 cyanuric acids Chemical class 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- FIZMUJNNLYRMFF-UHFFFAOYSA-N 1,1,1,12,12,12-hexabromododecane Chemical class BrC(Br)(Br)CCCCCCCCCCC(Br)(Br)Br FIZMUJNNLYRMFF-UHFFFAOYSA-N 0.000 claims description 2
- 239000004831 Hot glue Substances 0.000 abstract description 14
- 238000002485 combustion reaction Methods 0.000 abstract description 9
- -1 2, 3-dibromopropyl Chemical group 0.000 abstract description 8
- DQYHBUIHXMLXFA-UHFFFAOYSA-N 1,1,4,7,10,10-hexabromododecane Chemical compound CCC(Br)(Br)CCC(Br)CCC(Br)CCC(Br)Br DQYHBUIHXMLXFA-UHFFFAOYSA-N 0.000 abstract description 7
- 231100000252 nontoxic Toxicity 0.000 abstract description 4
- 230000003000 nontoxic effect Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 230000009967 tasteless effect Effects 0.000 abstract description 2
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 abstract 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 6
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 235000008708 Morus alba Nutrition 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to an environmental protection combustion stopping hot-melt adhesive film for electric conduction cloth, which is characterized in that according to weight, the environmental protection combustion stopping hot-melt adhesive film is composed of 30% to 50% of hot-melt adhesive, 5% to 10% of Sb2O3, 5 to 10% of ZnB, 10 to 30% of tri (2, 3-dibromopropyl) isotripolycyanate and 10% to 30% of hexabromododecane, and the sum of the weight percentage of the components is 100%. The environmental protection combustion stopping hot-melt adhesive film for electric conduction cloth has good combustion stopping performance, UL94V-O grade can be achieved, the environmental protection combustion stopping hot-melt adhesive film for electric conduction cloth is compounded on the surface of the electric conduction cloth, and the requirement of stopping combustion is easily achieved. The environmental protection combustion stopping hot-melt adhesive film for electric conduction cloth has nontoxic and tasteless materials and conforms to the requirement of environmental protection.
Description
Technical field:
The present invention relates to a kind of hot melt adhesive film, be specifically related to a kind of environmental protection fire retardant hot-melt film adhesive in user that is used for conductive fabric.Be compound in the conductive fabric surface, play fire retardation.
Background technology:
Conductive fabric is applied to electron trade and plays electric action, because therefore the singularity of electron trade be furnished with fire-retardant requirement to conduction.Before effect of the present invention, traditional conductive fabric flame resistant method is that conductive fabric is flooded fire retardant, as polybromodiphenyl ether, but polybromodiphenyl ether when burning syntheticly generate poisonous carcinogens and disabled, and the conductive fabric electrical and thermal conductivity is good, is difficult to realize fire-retardant than general cloth.
Summary of the invention:
The objective of the invention is to overcome above-mentioned deficiency, a kind of environmental protection fire retardant hot-melt film adhesive in user that is used for conductive fabric of realizing fire-retardant requirement and meeting environmental protection again of being easy to is provided.
The object of the present invention is achieved like this: a kind of environmental protection fire retardant hot-melt film adhesive in user that is used for conductive fabric is characterized in that: it is made up of the raw material of following weight part:
30～50 parts of hot melt adhesives
5～10 parts of antimonous oxides
5～10 parts of zinc borates
10～30 parts of three (2, the 3-dibromopropyl) isocyanuric acid esters
10～30 parts of hexabromo dodecanes
The present invention is used for the environmental protection fire retardant hot-melt film adhesive in user of conductive fabric, and described hot melt adhesive adopts polyester or urethane.
Hot melt adhesive plays the melted by heat bonding effect in the raw material of the present invention in fire retardant hot-melt film adhesive in user, has higher softening temperature and good cementability;
Antimonous oxide plays fire retardation in fire retardant hot-melt film adhesive in user, halogen flame is had tangible synergistic effect;
Zinc borate is a kind of inorganic combustion inhibitor, plays fire-retardant synergistic effect in fire retardant hot-melt film adhesive in user, and Heat stability is good eliminates smoke, and is nontoxic, effective with other fire retardant compositional flame-retardant;
Three (2, the 3-dibromopropyl) isocyanuric acid ester plays fire retardation in fire retardant hot-melt film adhesive in user, good flame retardation effect, and volatility is low, and consistency is good, and is durable, fast light, water-fast and nontoxic;
The hexabromo dodecane plays fire retardation in fire retardant hot-melt film adhesive in user, have enough thermostabilitys, and good free-running property is minimum to the hot melt adhesive performance impact;
Three (2, the 3-dibromopropyl) isocyanuric acid esters and hexabromo dodecane are used in combination the performance impact of hot melt adhesive less; Antimonous oxide and three (2, the 3-dibromopropyl) isocyanuric acid ester and hexabromo dodecane are used in combination and have good synergistic function, flame retardant effect obviously improves, because at high temperature decomposing, halogen compounds emits hydrogen halide, except suppressing the burning by Mulberry Extract HO terminating chain lock reactor, also, generate low melting point quantized antimony halides of energy and zirconyl oxyhalides antimony with the antimonous oxide reaction; Three (2, the 3-dibromopropyl) isocyanuric acid esters and antimonous oxide are used in combination, and obviously reduce the material combustion smoke density, reduce environmental pollution.
Therefore, good flame resistance of the present invention can reach the UL94V-O level, it is compound in the conductive fabric surface is easy to realize fire-retardant requirement; Raw materials used in addition nontoxic, tasteless, compliance with environmental protection requirements.
Embodiment:
Embodiment 1;
Step 1, get polyester 50 weight parts and add in the stirrer, be heated to 150 ℃, add antimonous oxide 5 weight parts, zinc borate 5 weight parts, three (2, the 3-dibromopropyl) isocyanuric acid ester 30 weight parts and hexabromo dodecane 10 weight parts again, heating keeps 150 ℃, stir compound;
Step 2, step 1 got compound place granulation in the tablets press, oven dry, hot melt adhesive tablet;
Step 3, step 2 is got hot melt adhesive tablet place and be blow molded into the tubular glued membrane in the blowfilm shaping machine;
Step 4, use side cutter cuts both sides make the tubular glued membrane become biplate shape glued membrane, film thickness 0.08mm.
Embodiment 2:
Step 1, get urethane 30 weight parts and add in the stirrer, be heated to 130 ℃, add antimonous oxide 10 weight parts, zinc borate 10 weight parts, three (2 again, the 3-dibromopropyl) isocyanuric acid ester 20 weight parts and hexabromo dodecane 30 weight parts, heating and keep 130 ℃ of temperature, stir compound, all the other steps are with embodiment one.
Embodiment 3:
Step 1, get urethane 45 weight parts to going in the stirrer, be heated to 130 ℃, add antimonous oxide 8 weight parts, zinc borate 7 weight parts, three (2 again, the 3-dibromopropyl) isocyanuric acid ester 10 weight parts and hexabromo dodecane 30 weight parts, heating and keep 130 ℃ of temperature, stir compound, all the other steps are with embodiment one.
Claims (1)
1, a kind of environmental protection fire retardant hot-melt film adhesive in user that is used for conductive fabric, it is characterized in that: it is made up of the raw material of following weight part:
30～50 parts of polyester or urethane
5～10 parts of antimonous oxides
5～10 parts of zinc borates
10～30 parts of three (2, the 3-dibromopropyl) isocyanuric acid esters
10～30 parts of hexabromo dodecanes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100949099A CN1307276C (en) | 2005-10-19 | 2005-10-19 | Environmental protection fire retardant hot-melt film adhesive in user for electric clothes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100949099A CN1307276C (en) | 2005-10-19 | 2005-10-19 | Environmental protection fire retardant hot-melt film adhesive in user for electric clothes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1760297A CN1760297A (en) | 2006-04-19 |
| CN1307276C true CN1307276C (en) | 2007-03-28 |
Family
ID=36706528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100949099A Expired - Fee Related CN1307276C (en) | 2005-10-19 | 2005-10-19 | Environmental protection fire retardant hot-melt film adhesive in user for electric clothes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1307276C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101435154B (en) * | 2008-12-18 | 2011-07-27 | 浙江三元电子科技有限公司 | Halogen-free flame-retardant conductive fabric and production method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338174B (en) * | 2008-08-14 | 2011-03-09 | 江阴科隆化工材料有限公司 | Environment protection type halogen-free flame-retardant hot-melt adhesive film for conducting cloth |
| CN105469891A (en) * | 2014-08-29 | 2016-04-06 | 上海硅邦电子科技发展有限公司 | Halogen-free flame-retardant mixed liquor and preparation method thereof and flame-retardant conductive fabric and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1273254A (en) * | 1999-05-11 | 2000-11-15 | 福裕化学有限公司 | Flame retardant composition for polypropylene |
| CN1294146A (en) * | 1999-11-02 | 2001-05-09 | 海尔科化工程塑料国家工程研究中心有限公司 | Fire-retarding mother particles and preparing process thereof |
| CN1478123A (en) * | 2000-09-29 | 2004-02-25 | ���ҵ�ۼ���ѧͶ�ʿعɹ�˾ | flame retardant composition |
-
2005
- 2005-10-19 CN CNB2005100949099A patent/CN1307276C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1273254A (en) * | 1999-05-11 | 2000-11-15 | 福裕化学有限公司 | Flame retardant composition for polypropylene |
| CN1294146A (en) * | 1999-11-02 | 2001-05-09 | 海尔科化工程塑料国家工程研究中心有限公司 | Fire-retarding mother particles and preparing process thereof |
| CN1478123A (en) * | 2000-09-29 | 2004-02-25 | ���ҵ�ۼ���ѧͶ�ʿعɹ�˾ | flame retardant composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101435154B (en) * | 2008-12-18 | 2011-07-27 | 浙江三元电子科技有限公司 | Halogen-free flame-retardant conductive fabric and production method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1760297A (en) | 2006-04-19 |
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Granted publication date: 20070328 Termination date: 20151019 |
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