[go: up one dir, main page]

CN1305965C - Cation asphalt anti-collapse agent emulsion and its producing method and using method - Google Patents

Cation asphalt anti-collapse agent emulsion and its producing method and using method Download PDF

Info

Publication number
CN1305965C
CN1305965C CNB2005102004506A CN200510200450A CN1305965C CN 1305965 C CN1305965 C CN 1305965C CN B2005102004506 A CNB2005102004506 A CN B2005102004506A CN 200510200450 A CN200510200450 A CN 200510200450A CN 1305965 C CN1305965 C CN 1305965C
Authority
CN
China
Prior art keywords
asphalt
slump
water
agent
latex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB2005102004506A
Other languages
Chinese (zh)
Other versions
CN1715333A (en
Inventor
倪红霞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Karamay Aoze Industry And Trade LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CNB2005102004506A priority Critical patent/CN1305965C/en
Publication of CN1715333A publication Critical patent/CN1715333A/en
Application granted granted Critical
Publication of CN1305965C publication Critical patent/CN1305965C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

一种阳离子沥青防塌剂乳胶，其按重量百分比组成为40%至56%的沥青，0至10%的软化点调节剂，0.7%至3.0%的乳化分散剂，0至16%的降滤失剂，其余为水。本发明阳离子沥青防塌剂乳胶具有沥青含量高(大于40%)、带正电水溶性好(好比墨水加入水中效果一样，均匀、无沉淀)、防塌降滤失效果好、成本低的特点，利用本发明，既解决了沥青难溶于水基钻井液体系的问题，又利用沥青自身的粘附、防漏、防塌等特点，来解决钻井工业中井壁剥失、散塌、垮塌等现象，其水溶性好，沥青含量高，封堵降滤失效果好，且具有一定的软化点，是目前水溶性较好的沥青类防塌降滤失剂，具有广阔的应用前景。本发明的生产方法和使用方法便于操作，易于实施。A cationic asphalt anti-slump agent latex, which is composed of 40% to 56% asphalt by weight percentage, 0 to 10% softening point regulator, 0.7% to 3.0% emulsifying dispersant, and 0 to 16% filter reducer Lost agent, the rest is water. The cationic asphalt anti-slump agent latex of the present invention has the characteristics of high asphalt content (greater than 40%), good positively charged water solubility (like the effect of adding ink to water, uniform and no precipitation), good anti-slump and filtration loss reduction effects, and low cost. , using the present invention not only solves the problem that asphalt is insoluble in water-based drilling fluid system, but also utilizes the characteristics of asphalt itself such as adhesion, leakage prevention, and anti-slump to solve the problem of well wall stripping, loosening, and collapse in the drilling industry. Phenomenon, it has good water solubility, high bitumen content, good plugging fluid loss control effect, and has a certain softening point. It is currently a bitumen anti-slump fluid loss control agent with good water solubility, and has broad application prospects. The production method and application method of the invention are convenient to operate and easy to implement.

Description

阳离子沥青防塌剂乳胶及其生产方法和使用方法Cationic asphalt anti-slump agent latex, production method and application method thereof

技术领域technical field

本发明涉及油田钻井液生产中使用的水溶性沥青类防塌降滤失剂，是一种阳离子沥青防塌剂乳胶及其生产方法和使用方法。The invention relates to a water-soluble bitumen anti-slump agent used in oilfield drilling fluid production, and is a cationic asphalt anti-slump agent latex and its production method and use method.

背景技术Background technique

在油田钻井液生产中，所使用的沥青类防塌降滤失剂目前有磺化沥青、天然沥青，应用效果较好，但唯独水溶性较差，软化点较高，在现场使用时不好将沥青直接加入水基钻井液中，而石油钻井工程使用的钻井液体系中90％为水基钻井液体系，且随着钻井工程的复杂难度日益增大及环保要求的逐渐提高，对水溶性防塌降滤失剂需求愈加强烈，而传统的磺化沥青、天然沥青，其水溶性都较差(对比见表1)，磺化沥青含量大于等于25％，有65％溶于水，单价6500元/吨，而天然沥青虽然沥青含量高，但几乎不溶于水，且软化点在80℃以上，仅使用在3500米以上的地层，使用范围较窄。In oilfield drilling fluid production, asphalt-based anti-slump and fluid loss agents currently include sulfonated asphalt and natural asphalt, which have good application effects, but only have poor water solubility and high softening point, so they are not suitable for field use. It is best to add asphalt directly into the water-based drilling fluid, and 90% of the drilling fluid system used in petroleum drilling is water-based drilling fluid system, and with the increasing complexity and difficulty of drilling engineering and the gradual improvement of environmental protection requirements, the water-soluble The demand for anti-slump and fluid loss reducing agents is becoming stronger and stronger, while traditional sulfonated asphalt and natural asphalt have poor water solubility (see Table 1 for comparison). The content of sulfonated asphalt is greater than or equal to 25%, and 65% is soluble in water. The unit price is 6,500 yuan/ton. Although natural asphalt has a high asphalt content, it is almost insoluble in water, and its softening point is above 80°C. It is only used in formations above 3,500 meters, and its use range is relatively narrow.

发明内容Contents of the invention

本发明提供了一种阳离子沥青防塌剂乳胶及其生产方法和使用方，其水溶性好，沥青含量高，封堵降滤失效果好，且具有一定的软化点，既解决了沥青难溶于水基钻井液体系的问题，又解决了钻井工业中井壁剥失、散塌、垮塌等现象。The invention provides a cationic asphalt anti-slump agent latex and its production method and usage. It has good water solubility, high asphalt content, good effect of plugging and reducing fluid loss, and has a certain softening point, which not only solves the problem of insoluble asphalt Based on the problems of the water-based drilling fluid system, it also solves the problems of well wall stripping, loosening, and collapse in the drilling industry.

本发明的技术方案之一是通过以下措施来实现的：一种阳离子沥青防塌剂乳胶，其按重量百分比组成为40％至56％的沥青，0至10％的软化点调节剂，0.7％至3.0％的乳化分散剂，0％至16％的降滤失剂，其余为水；其中，上述软化点调节剂为氯化钙、碳酸钙、氧化钙和碳酸氢钙中的一种或一种以上，上述乳化分散剂为氯化三甲基十八烷基胺、二甲基双十二烷基氯化铵、氯化双十八烷基二甲基铵、氯化二甲基双十六—十八烷基铵、双十六烷基二甲基烷基氯化铵中的—种或一种以上，上述降滤失剂为NF98-7双聚胺盐、磺化褐煤、腐殖酸钾、磺化栲胶中的一种或一种以上。One of the technical solutions of the present invention is achieved by the following measures: a cationic asphalt anti-slump agent latex, which consists of 40% to 56% asphalt by weight percentage, 0 to 10% softening point regulator, 0.7% to 3.0% emulsifying dispersant, 0% to 16% fluid loss control agent, and the rest are water; wherein, the above-mentioned softening point regulator is one or one of calcium chloride, calcium carbonate, calcium oxide and calcium bicarbonate More than one kind, the above-mentioned emulsifying dispersant is trimethyl octadecylamine chloride, dimethyl didodecyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, dimethyl didecyl chloride One or more of hexa-octadecyl ammonium, dihexadecyl dimethyl ammonium chloride, the above-mentioned fluid loss reducer is NF98-7 bispolyamine salt, sulfonated lignite, humic One or more of potassium nitrate and sulfonated tannin extract.

本发明的技术方案之二是通过以下措施来实现的：一种上述阳离子沥青防塌剂乳胶生产方法，其按下述步骤进行：首先将所需量的沥青及水分别进行加热，沥青升温120-150℃，水升温60-90℃，当水温60-90℃时，将所需要量的软化点调节剂、乳化分散剂及降滤失剂，按顺续每5-10分钟内加入一种，且搅拌均匀，待水温恒温在70-80℃、沥青温度恒温在120-150℃时，进行充分乳化，得到阳离子沥青防塌剂乳胶。The second technical solution of the present invention is achieved by the following measures: a method for producing the above-mentioned cationic asphalt anti-slump agent latex, which is carried out according to the following steps: first, the required amount of asphalt and water are respectively heated, and the asphalt is heated up for 120 -150°C, the water temperature rises to 60-90°C, when the water temperature is 60-90°C, add the required amount of softening point regulator, emulsifying dispersant and fluid loss reducer in sequence every 5-10 minutes , and stir evenly, when the water temperature is constant at 70-80°C and the asphalt temperature is constant at 120-150°C, fully emulsify to obtain cationic asphalt anti-slump agent latex.

本发明的技术方案之三是通过以下措施来实现的：一种上述阳离子沥青防塌剂乳胶生产方法，其按下述步骤进行：首先将所需量的软化点调节剂、乳化分散剂及降滤失剂溶解在所需量的热水中，水温要保持恒温在70-80℃，同时将沥青加热保持恒温120-150℃，其次进行过滤，进行充分乳化，得到阳离子沥青防塌剂乳胶。The third technical solution of the present invention is achieved by the following measures: a method for producing the above-mentioned cationic asphalt anti-slump agent latex, which is carried out according to the following steps: first, the required amount of softening point regulator, emulsifying dispersant and reducing agent The fluid loss agent is dissolved in the required amount of hot water. The water temperature should be kept at a constant temperature of 70-80°C. At the same time, the asphalt is heated to maintain a constant temperature of 120-150°C. Then, it is filtered and fully emulsified to obtain a cationic asphalt anti-slump agent latex.

本发明的技术方案之四是通过以下措施来实现的：一种上述阳离子沥青防塌剂乳胶的使用方法，其按下述步骤进行：在钻井过程中，按每1000千克水基泥浆中加入上述阳离子沥青防塌剂乳胶20-50千克。The fourth technical solution of the present invention is achieved by the following measures: a method for using the above-mentioned cationic asphalt anti-slump agent latex, which is carried out according to the following steps: in the drilling process, add the above-mentioned Cationic asphalt anti-slump agent latex 20-50 kg.

本发明阳离子沥青防塌剂乳胶具有沥青含量高(大于40％)、带正电水溶性好(好比墨水加入水中效果一样，均匀、无沉淀)、防塌降滤失效果好、成本低的特点，利用本发明，既解决了沥青难溶于水基钻井液体系的问题，又利用沥青自身的粘附、防漏、防塌等特点，来解决钻井工业中井壁剥失、散塌、垮塌等现象，其水溶性好，沥青含量高，封堵降滤失效果好，且具有一定的软化点，是目前水溶性较好的沥青类防塌降滤失剂，具有广阔的应用前景。本发明的生产方法和使用方法便于操作，易于实施。The cationic asphalt anti-slump agent emulsion of the present invention has the characteristics of high asphalt content (greater than 40%), good positively charged water solubility (like the effect of adding ink to water, uniform and no precipitation), good anti-slump and filtration loss reduction effects, and low cost. , using the present invention not only solves the problem that asphalt is insoluble in water-based drilling fluid system, but also utilizes the characteristics of asphalt itself such as adhesion, leakage prevention, and anti-slump to solve the problem of well wall stripping, loosening, and collapse in the drilling industry. Phenomenon, it has good water solubility, high bitumen content, good plugging fluid loss control effect, and has a certain softening point. It is currently a bitumen anti-slump fluid loss control agent with good water solubility, and has broad application prospects. The production method and application method of the invention are convenient to operate and easy to implement.

具体实施方式Detailed ways

本发明不受下述实施例的限制，可根据本发明的技术方案与实际情况来确定具体的实施方式。The present invention is not limited by the following examples, and specific implementation methods can be determined according to the technical solutions of the present invention and actual conditions.

下面结合实施例对本发明作进一步描述：The present invention will be further described below in conjunction with embodiment:

实施例1，该阳离子沥青防塌剂乳胶按重量百分比组成为56％沥青，2％软化点调节剂，1.0％乳化分散剂，2％降滤失剂，其余为水；对该阳离子沥青防塌剂乳胶检测得到如下表的结果： 项目 指标 沥青软化点℃ 100 外观 棕黑色胶状物 水分散性 均匀分散，无漂浮固状物 相对抑制性 0.380 胶体稳定性，％ 99 电动电位，mv 25 沥青含量，％ 55 Example 1, the cationic asphalt anti-slump agent latex is composed of 56% asphalt by weight percentage, 2% softening point regulator, 1.0% emulsifying dispersant, 2% fluid loss reducer, and the rest are water; the cationic asphalt anti-slump agent The agent latex detection obtains the result of following table: project index Bitumen softening point ℃ 100 Exterior Brown-black jelly water dispersibility Evenly dispersed, no floating solids relative inhibition 0.380 Colloid stability, % 99 zeta potential, mv 25 Asphalt content, % 55

实施例2，该阳离子沥青防塌剂乳胶按重量百分比组成为52％沥青，4％软化点调节剂，0.8％乳化分散剂，4％降滤失剂，其余为水；对该阳离子沥青防塌剂乳胶检测得到如下表的结果： 项目 指标 沥青软化点℃ 81 外观 棕黑色胶状物 水分散性 均匀分散，无漂浮固状物 相对抑制性 0.420 胶体稳定性，％ 98 电动电位，mv 26 沥青含量，％ 51 Embodiment 2, the cationic asphalt anti-slump agent emulsion is composed of 52% asphalt by weight percentage, 4% softening point regulator, 0.8% emulsifying dispersant, 4% fluid loss reducer, and the rest are water; the cationic asphalt anti-slump agent The latex test obtained the results in the following table: project index Bitumen softening point ℃ 81 Exterior Brown-black jelly water dispersibility Evenly dispersed, no floating solids relative inhibition 0.420 Colloid stability, % 98 zeta potential, mv 26 Asphalt content, % 51

实施例3，该阳离子沥青防塌剂乳胶按重量百分比组成为50％沥青，9％软化点调节剂，0.7％乳化分散剂，其余为水：对该阳离子沥青防塌剂乳胶检测得到如下表的结果： 项目 指标 沥青软化点℃ 72 外观 棕黑色胶状物 水分散性 均匀分散，无漂浮固状物 相对抑制性 0.45 胶体稳定性，％ 99 电动电位，mv 29 沥青含量，％ 49 Embodiment 3, this cationic asphalt anti-slump agent latex is composed of 50% asphalt by weight percentage, 9% softening point regulator, 0.7% emulsifying dispersant, all the other are water: this cationic asphalt anti-slump agent latex detects and obtains the following table result: project index Bitumen softening point ℃ 72 Exterior Brown-black jelly water dispersibility Evenly dispersed, no floating solids relative inhibition 0.45 Colloid stability, % 99 zeta potential, mv 29 Asphalt content, % 49

实施例4，该阳离子沥青防塌剂乳胶按重量百分比组成为48％沥青，8％软化点调节剂，1.2％乳化分散剂，7％降滤失剂，其余为水；对该阳离子沥青防塌剂乳胶检测得到如下表的结果： 项目     指标 沥青软化点℃     63 外观 棕黑色胶状物 水分散性 均匀分散，无漂浮固状物 相对抑制性 0.50 胶体稳定性，％ 99 电动电位，mv 27 沥青含量，％ 47 Embodiment 4, the cationic asphalt anti-slump agent latex is composed of 48% asphalt by weight percentage, 8% softening point regulator, 1.2% emulsifying dispersant, 7% fluid loss reducer, and the rest are water; the cationic asphalt anti-slump agent The latex test obtained the results in the following table: project index Bitumen softening point ℃ 63 Exterior Brown-black jelly water dispersibility Evenly dispersed, no floating solids relative inhibition 0.50 Colloid stability, % 99 zeta potential, mv 27 Asphalt content, % 47

实施例5，该阳离子沥青防塌剂乳胶按重量百分比组成为46％沥青，6％软化点调节剂，1.5％乳化分散剂，10％降滤失剂，其余为水；对该阳离子沥青防塌剂乳胶检测得到如下表的结果： 项目 指标 沥青软化点℃ 52 外观 棕黑色胶状物 水分散性 均匀分散，无漂浮固状物 相对抑制性 0.39 胶体稳定性，％ 99 电动电位，mv 26 沥青含量，％ 45 Embodiment 5, the cationic asphalt anti-slump agent emulsion is composed of 46% asphalt by weight percentage, 6% softening point regulator, 1.5% emulsifying dispersant, 10% fluid loss reducer, and the rest are water; the cationic asphalt anti-slump agent The latex test obtained the results in the following table: project index Bitumen softening point ℃ 52 Exterior Brown-black jelly water dispersibility Evenly dispersed, no floating solids relative inhibition 0.39 Colloid stability, % 99 zeta potential, mv 26 Asphalt content, % 45

实施例6，该阳离子沥青防塌剂乳胶按重量百分比组成为45％沥青，2.0％乳化分散剂，12％降滤失剂，其余为水：对该阳离子沥青防塌剂乳胶检测得到如下表的结果： 项目 指标 沥青软化点℃ 50 外观 棕黑色胶状物 水分散性 均匀分散，无漂浮固状物 相对抑制性 0.30 胶体稳定性，％ 99 电动电位，mv 28 沥青含量，％   44 Example 6, the cationic asphalt anti-slump agent latex is composed of 45% asphalt by weight percentage, 2.0% emulsifying dispersant, 12% fluid loss control agent, and the rest is water: the detection of this cationic asphalt anti-slump agent latex results in the following table result: project index Bitumen softening point ℃ 50 Exterior Brown-black jelly water dispersibility Evenly dispersed, no floating solids relative inhibition 0.30 Colloid stability, % 99 zeta potential, mv 28 Asphalt content, % 44

实施例7，该阳离子沥青防塌剂乳胶按重量百分比组成为42％沥青，2.5％乳化分散剂，14％降滤失剂，其余为水：对该阳离子沥青防塌剂乳胶检测得到如下表的结果： 项目 指标 沥青软化点℃ 45 外观 棕黑色胶状物 水分散性 均匀分散，无漂浮固状物 相对抑制性 0.33 胶体稳定性，％ 99 电动电位。mv 24 沥青含量，％ 41 Example 7, the cationic asphalt anti-slump agent latex is composed of 42% asphalt by weight percentage, 2.5% emulsifying dispersant, 14% fluid loss control agent, and the rest is water: the detection of this cationic asphalt anti-slump agent latex results in the following table result: project index Bitumen softening point ℃ 45 Exterior Brown-black jelly water dispersibility Evenly dispersed, no floating solids relative inhibition 0.33 Colloid stability, % 99 zeta potential. mv twenty four Asphalt content, % 41

实施例8，该阳离子沥青防塌剂乳胶按重量百分比组成为40％沥青，10％软化点调节剂，3.0％乳化分散剂，16％降滤失剂，其余为水；对该阳离子沥青防塌剂乳胶检测得到如下表的结果： 项目 指标 沥青软化点℃ 40 外观 棕黑色胶状物 水分散性 均匀分散，无漂浮固状物 相对抑制性 0.340 胶体稳定性，％ 99 电动电位，mv 23 沥青含量，％ 40 Embodiment 8, the cationic asphalt anti-slump agent latex is composed of 40% asphalt by weight percentage, 10% softening point regulator, 3.0% emulsifying dispersant, 16% fluid loss reducer, and the rest are water; the cationic asphalt anti-slump agent The latex test obtained the results in the following table: project index Bitumen softening point ℃ 40 Exterior Brown-black jelly water dispersibility Evenly dispersed, no floating solids relative inhibition 0.340 Colloid stability, % 99 zeta potential, mv twenty three Asphalt content, % 40

在上述实施例1至实施例8中，上述软化点调节剂为氯化钙、碳酸钙、氧化钙和碳酸氢钙中的一种或一种以上，上述乳化分散剂为氯化三甲基十八烷基胺、二甲基双十二烷基氯化铵、氯化双十八烷基二甲基铵、氯化二甲基双十六—十八烷基铵、双十六烷基二甲基烷基氯化铵中的一种或一种以上，上述降滤失剂为NF98-7双聚胺盐、磺化褐煤、腐殖酸钾、磺化栲胶中的一种或一种以上。In above-mentioned embodiment 1 to embodiment 8, above-mentioned softening point adjusting agent is one or more in calcium chloride, calcium carbonate, calcium oxide and calcium bicarbonate, and above-mentioned emulsifying dispersant is trimethyldecyl chloride Octylamine, dimethyl didodecyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, dimethyl dihexadecyl ammonium chloride, dihexadecyl ammonium chloride One or more of methyl alkyl ammonium chloride, the above-mentioned fluid loss control agent is one or one of NF98-7 bispolyamine salt, sulfonated lignite, potassium humate, and sulfonated tannin extract above.

上述实施例1至实施例8中的阳离子沥青防塌剂乳胶可分别选用以下二种生产方法得到：The cationic asphalt anti-collapse agent latex in above-mentioned embodiment 1 to embodiment 8 can select following two kinds of production methods to obtain respectively:

其生产方法之一是：首先将所需量的沥青及水分别进行加热，沥青升温120-150℃，水升温60-90℃，当水温60-90℃时，将所需要量的软化点调节剂、乳化分散剂及降滤失剂，按顺续每5-10分钟内加入一种，且搅拌均匀，待水温恒温在70-80℃、沥青温度恒温在120-150℃时，进行充分乳化，得到阳离子沥青防塌剂乳胶。One of its production methods is: firstly heat the required amount of asphalt and water separately, the temperature of the asphalt is raised to 120-150°C, the temperature of the water is raised to 60-90°C, and when the water temperature is 60-90°C, the softening point of the required amount is adjusted Add one kind of agent, emulsifying dispersant and fluid loss reducer in sequence every 5-10 minutes, and stir evenly, and fully emulsify when the water temperature is constant at 70-80°C and the asphalt temperature is constant at 120-150°C , to obtain cationic asphalt anti-slump agent latex.

其生产方法之二是：首先将所需量的软化点调节剂、乳化分散剂及降滤失剂溶解在所需量的热水中，水温要保持恒温在70-80℃，同时将沥青加热保持恒温120-150℃，其次进行过滤，进行充分乳化，得到阳离子沥青防塌剂乳胶。The second production method is: first dissolve the required amount of softening point regulator, emulsifying dispersant and fluid loss reducer in the required amount of hot water, keep the water temperature at 70-80°C, and heat the asphalt at the same time Maintain a constant temperature of 120-150°C, and then filter and fully emulsify to obtain cationic asphalt anti-slump agent latex.

上述实施例1至实施例8所得到的本发明阳离子沥青防塌剂乳胶的使用方法是：在钻井过程中，按每1000千克水基泥浆中加入上述阳离子沥青防塌剂乳胶20千克或30千克或40千克或50千克。The using method of the cationic asphalt anti-collapse agent emulsion of the present invention obtained in the above-mentioned embodiment 1 to embodiment 8 is: in the drilling process, add 20 kilograms or 30 kilograms of the above-mentioned cationic asphalt anti-slump agent emulsion in every 1000 kilograms of water-based mud Or 40kg or 50kg.

通过上述实施例得出本发明阳离子沥青防塌剂乳的主要技术指标如下表： 项目 指标 沥青软化点℃ 40-100 外观 棕黑色胶状物 水分散性 均匀分散，无漂浮固状物 相对抑制性 ≤1.0 胶体稳定性，％ ≥95 电动电位，mv ＞20 沥青含量，％ ≥40 Draw the main technical index of cationic asphalt anti-collapse agent emulsion of the present invention by above-mentioned embodiment as following table: project index Bitumen softening point ℃ 40-100 Exterior Brown-black jelly water dispersibility Evenly dispersed, no floating solids relative inhibition ≤1.0 Colloid stability, % ≥95 zeta potential, mv >20 Asphalt content, % ≥40

通过上述的检测结果可知本发明阳离子沥青防塌剂乳中，沥青含量大于40％，带正电水溶性好(好比墨水加入水中效果一样，均匀、无沉淀)，防塌降滤失效果好，是一种见效速度快的防塌降失水剂，具有广阔的应用前景。It can be seen from the above test results that in the cationic asphalt anti-slump agent emulsion of the present invention, the asphalt content is greater than 40%, and the positively charged water solubility is good (the effect is the same as adding ink to water, evenly and without precipitation), and the effect of preventing slumping and reducing fluid loss is good. It is an anti-slump fluid loss agent with quick effect and has broad application prospects.

本发明阳离子沥青防塌剂乳与同类其它产品如磺化沥青干粉的对照检测结果如下表： 主要技术指标对比 磺化沥青干粉 本发明 状态 干粉 胶体 沥青含量，％ ≥25 ≥40 水溶性，％ ≥65 100 正电性，mv 无 ＞20 沥青软化点，℃ 无 40℃、60℃……100℃ 价格 6400元/吨 5700元/吨 防塌速度及效果 干粉有升温溶解过程，且软化点值不明确，致使防塌效果缓慢 胶体短频快的象浆糊一样作用于井壁，且软化点与井温相对应，防塌效果好 The contrast test results of cationic asphalt anti-collapse agent emulsion of the present invention and other products of the same kind such as sulfonated asphalt dry powder are as follows: Comparison of main technical indicators Sulfonated asphalt dry powder this invention state dry powder colloid Asphalt content, % ≥25 ≥40 Water solubility, % ≥65 100 positive charge, mv none >20 Bitumen softening point, ℃ none 40°C, 60°C...100°C price 6400 yuan / ton 5700 yuan / ton Anti-collapse speed and effect The dry powder has a heating and dissolving process, and the softening point value is not clear, resulting in a slow anti-slump effect The colloid acts on the well wall like a paste in short frequency and fast, and the softening point corresponds to the well temperature, and the anti-slump effect is good

由上表对比得知本发明阳离子沥青防塌剂乳胶具有以下特点：Know that cationic asphalt anti-slump agent latex of the present invention has the following characteristics by comparison of the above table:

1、本发明阳离子沥青防塌剂乳胶的沥青含量大约是磺化沥青干粉1.6倍；1. The asphalt content of the cationic asphalt anti-slump agent emulsion of the present invention is about 1.6 times that of the sulfonated asphalt dry powder;

2、本发明阳离子沥青防塌剂乳胶的水溶性是100％，而磺化沥青干粉是65％的水溶；2. The water solubility of the cationic asphalt anti-slump agent latex of the present invention is 100%, while the sulfonated asphalt dry powder is 65% water soluble;

3、本发明阳离子沥青防塌剂乳胶的电动电位为大于20mv，显正电；而磺化沥青干粉则为零。3. The zeta potential of the cationic asphalt anti-slump agent emulsion of the present invention is greater than 20mv, which is positive; while the sulfonated asphalt dry powder is zero.

4、本发明阳离子沥青防塌剂乳胶具有一定的软化点，此系列产品分40℃、60℃…100℃软化点的产品，而磺化沥青干粉则无。4. The cationic asphalt anti-slump agent latex of the present invention has a certain softening point. This series of products are divided into products with a softening point of 40°C, 60°C...100°C, while the sulfonated asphalt dry powder has no softening point.

5、本发明阳离子沥青防塌剂乳胶的价格为5700元/吨，而磺化沥青干粉则为6500元/吨。5. The price of cationic asphalt anti-slump agent latex of the present invention is 5700 yuan/ton, while the price of sulfonated asphalt dry powder is 6500 yuan/ton.

6、本发明阳离子沥青防塌剂乳胶处理事故比磺化沥青千粉见效速度快。6. The cationic asphalt anti-slump agent emulsion of the present invention is faster than sulfonated asphalt dry powder in dealing with accidents.

上述实施例中的阳离子沥青防塌剂乳胶和目前钻井液使用的沥青类防塌降滤失剂的检测方法都采用国标或国家行业标准进行的，具体如下：GB/r 4507-84沥青软化点测试方法(环球法)、GB6678-2003化工产品采样总则、GB/T260石油产品水分测定法、SY/T5490-90钻井液试验用钠膨润土、SY/T5664-94钻井液用页岩抑制剂磺化沥青FT1、SY/T5621-93钻井液测试程序、SY/T5559钻井液用处理剂通用试验方法。The cationic asphalt anti-slump agent latex in the above examples and the asphalt-based anti-slump fluid loss reducer used in drilling fluids are all tested using national standards or national industry standards, specifically as follows: GB/r 4507-84 Bitumen softening point Test method (ring and ball method), GB6678-2003 General Rules for Sampling Chemical Products, GB/T260 Moisture Determination Method for Petroleum Products, SY/T5490-90 Sodium Bentonite for Drilling Fluid Test, SY/T5664-94 Sulfonation of Shale Inhibitor for Drilling Fluid Bitumen FT1, SY/T5621-93 Drilling Fluid Test Procedures, SY/T5559 Drilling Fluid Treatment Agent General Test Method.

Claims (5)

1.一种阳离子沥青防塌剂乳胶，其特征在于按重量百分比组成为40％至56％的沥青，0至10％的软化点调节剂，0.7％至3.0％的乳化分散剂，0至16％的降滤失剂，其余为水；其中，上述软化点调节剂为氯化钙、碳酸钙、氧化钙和碳酸氢钙中的一种或一种以上，上述乳化分散剂为氯化三甲基十八烷基胺、二甲基双十二烷基氯化铵、氯化双十八烷基二甲基铵、氯化二甲基双十六-十八烷基铵、双十六烷基二甲基烷基氯化铵中的一种或一种以上，上述降滤失剂为NF98-7双聚胺盐、磺化褐煤、腐殖酸钾、磺化栲胶中的一种或一种以上。1. a kind of cationic asphalt antislumping agent latex, it is characterized in that by weight percent, it is composed of 40% to 56% asphalt, 0 to 10% softening point regulator, 0.7% to 3.0% emulsifying dispersant, 0 to 16% % fluid loss reducer, and the rest is water; wherein, the above-mentioned softening point regulator is one or more of calcium chloride, calcium carbonate, calcium oxide and calcium bicarbonate, and the above-mentioned emulsifying dispersant is trimethyl chloride Dimethyl octadecyl ammonium, dimethyl didodecyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, dimethyl dihexadecyl ammonium chloride, dihexadecane One or more of base dimethyl alkyl ammonium chloride, the above-mentioned fluid loss control agent is one or more of NF98-7 bispolyamine salt, sulfonated lignite, potassium humate, sulfonated tannin extract more than one. 2.一种根据权利要求1所述阳离子沥青防塌剂乳胶的生产方法，其特征在于按下述步骤进行：首先将所需量的沥青及水分别进行加热，沥青升温120-150℃，水升温60-90℃，当水温60-90℃时，将所需要量的软化点调节剂、乳化分散剂及降滤失剂，按顺序每5-10分钟内加入一种，且搅拌均匀，待水温恒温在70-80℃、沥青温度恒温在120-150℃时，进行充分乳化，得到阳离子沥青防塌剂乳胶。2. a kind of production method according to the described cationic asphalt antislumping agent latex of claim 1, it is characterized in that carry out by following steps: first the required amount of asphalt and water are heated respectively, asphalt heats up 120-150 ℃, water Raise the temperature to 60-90°C. When the water temperature is 60-90°C, add the required amount of softening point regulator, emulsifying dispersant and fluid loss reducer in order every 5-10 minutes, and stir evenly. When the water temperature is constant at 70-80°C and the asphalt temperature is constant at 120-150°C, fully emulsify to obtain the cationic asphalt anti-slump agent latex. 3.一种根据权利要求1所述阳离子沥青防塌剂乳胶的生产方法，其特征在于按下述步骤进行：首先将所需量的软化点调节剂、乳化分散剂及降滤失剂溶解在所需量的热水中，水温要保持恒温在70-80℃，同时将沥青加热保持恒温120-150℃，其次进行过滤，进行充分乳化，得到阳离子沥青防塌剂乳胶。3. a kind of production method according to the described cationic asphalt antislumping agent latex of claim 1, it is characterized in that carry out by following steps: first the softening point regulator of required amount, emulsifying dispersant and fluid loss control agent are dissolved in In the required amount of hot water, the water temperature should be kept at a constant temperature of 70-80°C, and the asphalt should be heated at a constant temperature of 120-150°C, followed by filtration and full emulsification to obtain cationic asphalt anti-slump agent latex. 4.一种根据权利要求1所述的阳离子沥青防塌剂乳胶的使用方法，其特征在于按下述步骤进行：在钻井过程中，按每1000千克水基泥浆中加入上述阳离子沥青防塌剂乳胶20-50千克。4. a method for using cationic asphalt anti-slump agent latex according to claim 1, characterized in that it is carried out in the following steps: in the drilling process, add above-mentioned cationic asphalt anti-slump agent in every 1000 kilograms of water-based mud Latex 20-50 kg. 5.一种根据权利要求2或3所述的生产方法得到的阳离子沥青防塌剂乳胶的使用方法，其特征在于按下述步骤进行：在钻井过程中，按每1000千克水基泥浆中加入上述阳离子沥青防塌剂乳胶20-50千克。5. a method for using the cationic asphalt anti-slump agent latex obtained according to the production method described in claim 2 or 3, is characterized in that it is carried out by the following steps: in the drilling process, add 20-50 kg of the above-mentioned cationic asphalt anti-slump agent latex.
CNB2005102004506A 2005-08-05 2005-08-05 Cation asphalt anti-collapse agent emulsion and its producing method and using method Expired - Lifetime CN1305965C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2005102004506A CN1305965C (en) 2005-08-05 2005-08-05 Cation asphalt anti-collapse agent emulsion and its producing method and using method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2005102004506A CN1305965C (en) 2005-08-05 2005-08-05 Cation asphalt anti-collapse agent emulsion and its producing method and using method

Publications (2)

Publication Number Publication Date
CN1715333A CN1715333A (en) 2006-01-04
CN1305965C true CN1305965C (en) 2007-03-21

Family

ID=35821512

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2005102004506A Expired - Lifetime CN1305965C (en) 2005-08-05 2005-08-05 Cation asphalt anti-collapse agent emulsion and its producing method and using method

Country Status (1)

Country Link
CN (1) CN1305965C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101747876A (en) * 2008-12-16 2010-06-23 西部钻探克拉玛依钻井工艺研究院 Potassium carbonate polyamine drilling fluid
CN103215017A (en) * 2013-04-11 2013-07-24 中国石油大学(华东) Electronpositive borehole wall stabilizer applied to oil and gas drilling and preparation method of electronpositive borehole wall stabilizer
CN101747873B (en) * 2008-12-12 2013-12-11 西部钻探克拉玛依钻井工艺研究院 Latex sealing fluid and preparation method thereof
US12049585B2 (en) 2018-12-12 2024-07-30 Chevron Phillips Chemical Company Lp Wellbore drilling compositions

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101108963B (en) * 2006-07-19 2010-12-29 西部钻探克拉玛依钻井工艺研究院 Modified product of native asphalt bitumen used as drilling fluid anti-sloughing agentand method of manufacturing the same
CN101831281B (en) * 2010-05-19 2013-04-24 濮阳市诚信钻采助剂有限公司 High-dispersion modified asphalt powder and preparation method thereof
CN103525099B (en) * 2012-07-03 2015-10-28 华东理工大学 Compound Asphalt Emulsifier Containing Gemini Surfactant
CN103509538A (en) * 2013-10-14 2014-01-15 辉县市日新化工厂 Novel polymer while-drilling lost circulation additive and preparation method thereof
MX2019008472A (en) * 2017-01-17 2019-09-18 Avantium Knowledge Centre Bv Asphalt composition comprising humins obtained from dehydration of carbohydrates.
CN113698918B (en) * 2020-05-23 2022-10-21 中石化石油工程技术服务有限公司 Resource utilization method for rock debris of synthetic base drilling fluid
CN113336963A (en) * 2021-06-09 2021-09-03 巴州三元石油助剂有限公司 Cationic emulsified asphalt for drilling fluid, preparation method and softening point blending method thereof
CN118834673B (en) * 2023-04-25 2025-09-19 中国石油化工股份有限公司 Emulsified asphalt plugging anti-collapse agent and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85100586A (en) * 1985-04-01 1986-07-30 鞍山钢铁公司 Petroleum Asphalt Emulsion
US4671883A (en) * 1983-01-14 1987-06-09 Sandoz Ltd. Fluid loss control additives for oil-based well-working fluids
CN1053631A (en) * 1991-02-11 1991-08-07 大庆石油管理局井下作业公司 Temperarily blocking agent for water soluble stratum
US6376455B1 (en) * 1998-01-09 2002-04-23 Goldschmidt Rewo Gmbh & Co. Kg Quaternary ammonium compounds, compositions containing them, and uses thereof
CN1461788A (en) * 2002-05-29 2003-12-17 德阳市海天高新技术材料制造有限公司 Oil gas layer protective agent for petroleum orilling well

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4671883A (en) * 1983-01-14 1987-06-09 Sandoz Ltd. Fluid loss control additives for oil-based well-working fluids
CN85100586A (en) * 1985-04-01 1986-07-30 鞍山钢铁公司 Petroleum Asphalt Emulsion
CN1053631A (en) * 1991-02-11 1991-08-07 大庆石油管理局井下作业公司 Temperarily blocking agent for water soluble stratum
US6376455B1 (en) * 1998-01-09 2002-04-23 Goldschmidt Rewo Gmbh & Co. Kg Quaternary ammonium compounds, compositions containing them, and uses thereof
CN1461788A (en) * 2002-05-29 2003-12-17 德阳市海天高新技术材料制造有限公司 Oil gas layer protective agent for petroleum orilling well

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101747873B (en) * 2008-12-12 2013-12-11 西部钻探克拉玛依钻井工艺研究院 Latex sealing fluid and preparation method thereof
CN101747876A (en) * 2008-12-16 2010-06-23 西部钻探克拉玛依钻井工艺研究院 Potassium carbonate polyamine drilling fluid
CN101747876B (en) * 2008-12-16 2013-07-24 西部钻探克拉玛依钻井工艺研究院 Potassium carbonate polyamine drilling fluid
CN103215017A (en) * 2013-04-11 2013-07-24 中国石油大学(华东) Electronpositive borehole wall stabilizer applied to oil and gas drilling and preparation method of electronpositive borehole wall stabilizer
US12049585B2 (en) 2018-12-12 2024-07-30 Chevron Phillips Chemical Company Lp Wellbore drilling compositions

Also Published As

Publication number Publication date
CN1715333A (en) 2006-01-04

Similar Documents

Publication Publication Date Title
CN1305965C (en) Cation asphalt anti-collapse agent emulsion and its producing method and using method
CN106634878B (en) Drilling fluid additive composition and its application and the water-base drilling fluid suitable for high pressure-bearing plugging while drilling and its application
CN105907380B (en) The compositions of additives of drilling fluid and the class oil base drilling fluid suitable for shale gas horizontal well
CN103820100B (en) Gelled acid used for acid fracturing of high-temperature fractured-vuggy type carbonate reservoir
CN104559997B (en) A kind of shale gas pressure break slippery water and preparation method thereof
CN112409611B (en) Mussel bionic gel composition, self-repairing gel and plugging agent as well as preparation method and application of self-repairing gel and plugging agent
CN105802593B (en) High-density water-based drilling fluid suitable for shale gas horizontal well
CN106010482B (en) It is adapted to the environment-friendly type water base drilling fluid of shale gas horizontal well
WO2015109917A1 (en) Thickener for shale gas fracturing fluid, fracturing fluid and preparation method and use thereof
CN106800919A (en) It is a kind of to protect water-base drilling fluid of Thief zone reservoir and its preparation method and application
CN112358864B (en) Nano emulsion acid system and preparation method and application thereof
CN105754569B (en) A low-permeability reservoir water injection well pretreatment agent and preparation method thereof
CN117210208B (en) Multiple double-effect collapse-preventing environment-friendly high-performance drilling fluid and preparation method thereof
CN107325804A (en) A kind of pressure break antiswelling stabilizing agent
CN108728053A (en) A kind of low solid phase salt-water drilling fluid environmentally friendly heat and salinity tolerance closure fluid loss additive and preparation method thereof
CN104610935A (en) Plugging agent while drilling for oil-based drilling fluids, and preparation method thereof
CN105037903A (en) Wax-bearing crude oil rheological aid
CN111876138B (en) Carbon-based tackifier and its preparation method and application
CN108424754B (en) High-temperature-resistant high-calcium salt drilling fluid and preparation method thereof
CN111574978A (en) Jelly plugging agent, preparation method and application thereof
CN105441041B (en) A kind of drilling fluid cationic sealing agent and preparation method thereof
CN105038735A (en) Environment-friendly microemulsion capable of being dispersed into nano liquid drops in situ and preparation method thereof
CN107903880A (en) A kind of preparation method of drilling fluid high temperature resistance sulfonation modifying pitch fluid loss additive
CN108130065A (en) A kind of nano-complex for being used to improve high temperature flooding polymers long-time stability
CN110982094B (en) Reactive solvent and application

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: AOZE BUSINESS CO., LTD., KELAMAYI CITY

Free format text: FORMER OWNER: NI HONGXIA

Effective date: 20081010

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20081010

Address after: No. 10 Tian Shan Road, Xinjiang, Karamay

Patentee after: Karamay AOZE industry and trade LLC

Address before: Supply 4-22, new town, Xinjiang, Karamay

Patentee before: Ni Hongxia

CI01 Publication of corrected invention patent application

Correction item: Patentee

Correct: Karamay Aoze Industrial & Trading Co., Ltd.

False: Karamay AOZE industry and trade limited liability company

Number: 45

Page: 1071

Volume: 24

ERR Gazette correction

Free format text: CORRECT: PATENTEE; FROM: AOZE BUSINESS CO., LTD., KELAMAYI CITY TO: KARAMAY CITY AOZE INDUSTRY AND TRADE CO.,LTD.

CX01 Expiry of patent term

Granted publication date: 20070321

CX01 Expiry of patent term