CN1391439A - Synergistic herbicidal active substance combinations - Google Patents

Abstract

This invention relates to novel synergistic herbicidal compound mixtures comprising Tritosulfuron and commonly known herbicidal active compounds, as well as optional compounds that enhance crop affinity. The synergistic herbicidal compound mixtures of this invention can be used to selectively control weeds in a variety of useful crops, particularly cereal crops (including cereals and maize), with excellent weed control efficacy.

Description

Synergistic herbicidal active compound mixture

The present invention relates to novel synergistic herbicidally active compound mixtures comprising Tritosulfuron and known herbicidally active compounds and optionally crop-compatibility-enhancing compounds, which can be used for the selective control of Weeds and has a very good weed control effect.

As a herbicide with broad-spectrum activity, Tritosulfuron (N-[[[4-methoxy-6-(trifluoromethyl)-1,3,5-triazin-2-yl]amino]carbonyl]-2 -trifluoromethyl-benzenesulfonamide) is the subject of numerous patent applications (cf. DE-A4038430, WO-A97/10714). However, the active compounds have deficiencies in terms of activity.

Surprisingly, it has been found that when Tritosulfuron is mixed with known herbicidal active compounds selected from different structural types, it shows a significant synergistic effect on herbicidal activity, and this broad-spectrum active mixture can be particularly beneficial For the selective control of weeds in useful crops such as wheat and corn.

Surprisingly, it has also been found that the combination of Tritosulfuron with other known herbicidally active compounds can be combined with the application of the following compounds (safeners/antidotes) which increase the compatibility of the crops, and other more favorable effects can be obtained .

The present invention provides compositions characterized in that they contain a synergistically effective amount of a mixture of active compounds comprising

(a) Tritosulfuron

and

(b) One or more compounds selected from the group of herbicides containing the following active compounds:

(5-Trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy)-N-isopropyl-N-(4-fluoro-phenyl)acetamide (Flufenacet, DE-A -3821600), 2-(2-methoxycarbonylbenzenesulfonylaminocarbonyl)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazole- 3-ketone or the sodium salt of the compound (Propoxycarbazone (-sodium salt), EP-A-507171), 2-(2-trifluoromethoxy-benzenesulfonyl-aminocarbonyl)-4-methyl-5- Methoxy-2,4-dihydro-3H-1,2,4-triazol-3-one or the sodium salt of the compound (Flucarbazone (-sodium salt), EP-A-507171), N-(3 , 4-dichlorophenyl) propionamide (propanil, DE-A-1039779), N-2-benzothiazolyl-N, N'-dimethylurea (methylbenzothiazolone, GB-A- 1085430), 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one (metrizinone, DE -A-1795784), 4-(2-chlorophenyl)-N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (Fentrazamide, EP-A-612735), 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)-one (metrizone, DE-A-2138031), 2 -(2-Benzothiazolyloxy)-N-methyl-N-phenylacetamide (Phenylacetamide, DE-A-2822155), 4-amino-6-(1,1-dimethyl Ethyl)-3-(ethylthio)-1,2,4-triazin-5(4H)-one (ethazinone, DE-A-1542873), 5-[4-bromo-1- 1-methylethyl methyl-5-(trifluoromethyl)-1H-pyrazol-3-yl]-2-chloro-4-fluorobenzoate (Fluazolate, WO-A-9206962)

(“Group 1 Active Compounds”)

and optional

(c) One or more compounds selected from the second group of herbicides containing the following active compounds:

2-Chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamide (acetochlor), 5-(2-chloro-4-trifluoro Methyl-phenoxy)-2-nitro-benzoic acid sodium salt (Acifluorfen), 2-Chloro-6-nitro-3-phenoxy-aniline (Aciclofen), 2-Chloro- N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-acetamide (alachlor), N-ethyl-N'-isopropyl-6-methylthio -1,3,5-triazine-2,4-diamine (ametrazine), 4-amino-N-(1,1-dimethyl-ethyl)-4,5-dihydro-3- (1-methyl-ethyl)-5-oxo-1H-1,2,4-triazole-1-carboxamide (Amicarbazone), N-(4,6-dimethoxy-pyrimidine-2- base)-N'-(N-methyl-N-methyl-sulfonyl-sulfamoyl)-urea (acylsulfuron-methyl), 1H-1,2,4-triazol-3-amine (herbicide strong), 6-chloro-4-ethylamino-2-isopropylamino-1,3,5-triazine (atrazine), 2-[2,4-dichloro-5-(2-propane Alkynyloxy)-phenyl]-5,6,7,8-tetrahydro-1,2,4-triazolo-[4,3-a]-pyridine-3(2H)-one (oxazolidine grass), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-[1-methyl-4-(2-methyl-2H-tetrazol-5-yl)-1H -pyrazol-5-yl-sulfonyl]-urea (rimsulfuron-methyl), N-benzyl-2-(4-fluoro-3-trifluoromethyl-phenoxy)butanamide (Beflubutamid), 4-Chloro-2-oxo-3(2H)-benzothiazole acetic acid (Azalea), N-butyl-N-ethyl-2,6-dinitro-4-trifluoromethyl-aniline (Butafluran), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-methoxycarbonyl-phenylmethylsulfonyl)-urea (benzazanthin Long), 2-[2-[4-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)phenoxy ]methyl]-5-ethyl-phenoxy-propionic acid methyl ester (Benzfendizone), 3-(2-chloro-4-methylsulfonyl-benzoyl)-4-phenylthio-bicyclo- [3.2.1]-oct-3-en-2-one (Benzobicyclon), N-benzoyl-N-(3,4-dichloro-phenyl)-DL-aminopropionic acid ethyl ester (new Yanling ), 3-isopropyl-1H-2, 1,3-benzothiadiazin-4(3H)-one (benzazone), 5-(2,4-dichloro-phenoxy)-2 -Nitro-methyl benzoate (methylcarboxyben), 2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxyl)-sodium benzoate (bispyribac), 2 -Bromo-3,3-dimethyl-N-(1-methyl-1-phenyl-ethyl)-butyramide (bromobutyramide), 3,5-dibromo-4-hydroxy-benzene Formaldehyde O-(2,4-dinitro-phenyl)oxime (bromophenol oxime), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), N-butoxy-methyl- 2-Chloro-N-(2,6-diethyl-phenyl)-acetamide (butachlor), [1,1-dimethyl-2-oxo-2-(2-propenyloxy) ]-ethyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)-benzoic acid Ester (Butafenacil-allyl), 2-(1-ethoxyimino-propyl)-3-hydroxy-5-[2,4,6-trimethyl-3-(1-oxo-butyl) -Phenyl]-2-cyclohexen-1-one (butoxycyclone), S-ethylbis-(2-methyl-propyl)-thiocarbamate (butachlor), N , N-diethyl-3-(2,4,6-trimethyl-phenylsulfonyl)-1H-1,2,4-triazole-1-carboxamide (benzoconazole), 2-[ 1-[(3-Chloro-2-propenyl)-oxy-imino]-propyl]-3-hydroxy-5-(tetrahydro-2H-pyran-4-yl)-2-cyclohexene -1-keto (quinoxamate), 2-(4-chloro-2-fluoro-5-(2-chloro-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluoromethyl- 5-Methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (fentrazone), 2,4-dichloro-1-(3-methoxy-4 -Nitro-phenoxy)-benzene (methoxypyramid), 3-amino-2,5-dichloro-benzoic acid (pyrazon), N-(4-chloro-6-methoxy-pyrimidine -2-yl)-N'-(2-ethoxycarbonyl-phenylsulfonyl)-urea (chlorimuron-methyl), 1,3,5-trichloro-2-(4-nitro-phenoxy Base)-Benzene (Phenylsulfonyl), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-chloro-phenylsulfonyl )-urea (chlorsulfuron), N'-(3-chloro-4-methyl-phenyl)-N,N-dimethylurea (chlorotoluron), 2-chloro-3-[2-chloro -5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl]-2-propionic acid ethyl ester (Cinidon -ethyl), N-(4,6-dimethoxy-1,3,5-triazin-2-yl)-N'-(2-(2-methoxy-ethoxy)-phenyl Sulfonyl)-urea (ethersulfuron), 2-[1-[2-(4-chloro-phenoxy)-propoxyamino]butyl]-5-(tetrahydro-2 H-thiopyran- 3-yl)-1,3-cyclohexanedione (Clefoxydim), (E,E)-(+)-2-[1-[[(3-chloro-2-propenyl)-oxyl]- Imino]-propyl]-3-hydroxy-2-cyclohexen-1-one (clethodim), 2-propynyl (R)-2-[4-(5-chloro-3-fluoro- Pyridin-2-yl-oxy)-phenoxy]-propionate (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (diclopyralid), 3-chloro-2- [(5-Ethoxy-7-fluoro[1,2,4]triazolo[1,5-c]pyrimidin-2-yl-sulfonyl)-amino]-benzoic acid methyl ester ), 2-chloro-4-ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazine (cyanazine), N-(4,6-dimethyl Oxy-pyrimidin-2-yl)-N'-(2-cyclopropylcarbonyl-phenyl-sulfonyl)-urea (cyprosulfuron-methyl), 2-(1-ethoxyiminobutyl)- 3-Hydroxy-5-(tetrahydro-2H-thiopyran-3-yl)-2-cyclohexen-1-one (cycloxydim), (R)-2-[4-(4-cyano- 2-fluoro-phenoxy)-phenoxy]-butyl propionate (cyhalofop-ethyl), 2,4-dichloro-phenoxyacetic acid (2,4-D), 3,6-dichloro- 2-Methoxy-benzoic acid (dicamba), (R)-2-(2,4-dichloro-phenoxy)-propionic acid (2,4-propionic acid), 2-[4- (2,4-dichloro-phenoxy)-phenoxy]-propionic acid methyl ester (diclofop), N-(2,6-dichloro-phenyl)-5-ethoxy-7- Fluorine-[1,2,4]-triazolo-[1,5-c]-pyrimidine-2-sulfonamide (pyrimidinesulfonamide), 1,2-dimethyl-3,5-diphenyl- 1H-Pyrazolium Methyl Sulfate (Pyridine) N-(2,4-Difluoro-Phenyl)-2-(3-Trifluoromethyl-Phenoxy)-Pyridine-3-Carboxamide (difluramid), 2-[1-[(3,5-difluoro-phenyl)-amino-carbonyl-hydrazono]-ethyl]-pyridine-3-carboxylic acid (difluoropyrone ), S-(1-methyl-1-phenyl-ethyl) 1-piperidine-thiocarbamate (Pipazol), (S-) 2-chloro-N-(2,4-di Methyl-3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide ((S-) dimenamid), 2-amino-4-(1- Fluoro-1-methyl-ethyl)-6-(1-methyl-2-(3,5-dimethyl-phenoxy)-ethylamino)-1,3,5-triazine (Dimexyflam) , N3, N3-diethyl-2,4-dinitro-6-trifluoromethyl-1,3-diamino-benzene (trolamine), 6,7-dihydro-bipyrido[1 , 2-a: 2′,1′-c]pyrazine dioium (diquat), S,S-dimethyl 2-difluoromethyl-4-isobutyl-6-trifluoromethylpyridine -3,5-dithiocarbamate (dithiopyr), N'-(3,4-dichloro-phenyl)-N,N-dimethyl-urea (diuron), 2- [2-(3-Chloro-phenyl)-oxiranylmethyl]-2-ethyl-1H-indene-1,3(2H)-dione (Epropodan), S-ethyldipropyl Thiocarbamate (endiprid), S-(phenylmethyl) N-ethyl-N-(1,2-dimethyl-propyl)-thiocarbamate (pentachlor ), N-ethyl-N-(2-methyl-2-propenyl)-2,6-dinitro-4-trifluoromethyl-aniline (butenefluridine), 2-ethoxy -1-methyl-2-oxo-ethyl (S)-2-chloro-5-(2-chloro-4-trifluoromethyl-phenoxy)benzoate (Ethoxyfen), N-( 4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-ethoxy-phenoxysulfonyl)-urea (ethoxysulfuron), (R)-2-[4 -(6-Chloro-benzoxazol-2-yl-oxy)-phenoxy]-propionic acid ethyl ester (oxaprop-ethyl), 4-(2-chloro-phenyl)-N- Cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (Fentrazamide), N-benzoyl-N-(3-chloro-4-fluoro- Phenyl)-DL-alanine isopropyl ester (wheat straw fluoroisopropyl ester), N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-L-alanine isopropyl ester ( Wheat straw fluoroisopropyl ester-L), N-benzoyl-N-(3-chloro-4-fluoro-phenoxy)-DL-alanine methyl ester (wheat straw fluoromethyl ester), N-(2, 6-difluoro-phenyl)-8-fluoro-5-methoxy-[1,2,4]-triazolo-[1,5-c]-pyrimidine-2-sulfonamide (Florasulam), ( R)-2-[4-(5-trifluoromethyl-pyridin-2-yl-oxyl)-phenoxy]-propionate butyl butyl ester), 5-(4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl)-2-chloro-4-fluoro-benzoic acid isopropyl ester (Fluazolate), 4,5-Dihydro-3-methoxy-4-methyl-5-oxo-N-[(2-trifluoromethoxyphenyl)-sulfonyl]-1H-1,2,4- Triazole-1-carboxamide sodium salt (Flucarbazone-sodium salt), N-(4-fluoro-phenyl)-N-isopropyl-2-(5-trifluoromethyl-1,3,4-thia Oxadiazol-2-yl-oxy)-acetamide (Flufenacet), N-(2,6-difluoro-phenyl)-5-methyl-1,2,4-triazolo[1,5- a]-Pyrimidine-2-sulfonamide (trimesulfame), [2-chloro-4-fluoro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo Substitute-2H-isoindol-2-yl)-phenoxy]-pentyl acetate (pentyl oxalate), 2-[7-fluoro-3,4-dihydro-3-oxo-4- (2-propynyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydro-1H-isoindole-1,3-dione (propyne Fluramid), 2-[4-chloro-2-fluoro-5-[(1-methyl-2-propynyl)-oxyl]-phenyl]-4,5,6,7-tetrahydro -1H-isoindole-1,3(2H)-dione (Flumipropyn), 3-chloro-4-chloromethyl-1-(3-trifluoromethyl-phenyl)-2-pyrrolidinedione (Fluomizone), Ethoxycarbonylmethyl 5-(2-Chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoate (Cyclofenac), 1 -(4-Chloro-3-(2,2,3,3,3-pentafluoro-propoxymethyl)-phenyl)-5-phenyl-1H-1,2,4-triazole-3 -Formamide (flumitrazone), 1-isopropyl-2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl- 1(2H)-pyrimidinyl)-benzoate (Flupropacil), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(3-methoxycarbonyl-6-tri Fluoromethyl-pyridin-2-yl-sulfonyl)-urea sodium salt (fluridinesulfuron), 9-hydroxy-9H-fluorene-9-carboxylic acid (fluorene butyl ester), (4-amino-3, 5-dichloro-6-fluoro-pyridin-2-yl-oxy)-acetic acid (2-butoxy-1-methyl-ethyl ester, 1-methyl-heptyl ester) (chlorofluoropyroxy Acetic acid, -butoxypropyl, -isoheptyl), 5-methylamino-2-phenyl-4-(3-trifluoromethyl-phenyl)-3(2H)-furanone (furanone ), [(2-chloro-4-fluoro-5-(tetrahydro-3-oxo-1H,3H-[1,3,4]-thiadiazolo-[3,4-a]-pyridazine -1-ylidene)-amino)-phenyl]-methyl thioacetate (dazaflur), 5-(2-chloro-4-trifluoromethyl-propoxy)-N-methylsulfonyl -2-nitro-benzamide (fomesafen), 2-[[[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl] -4-formylamino-N,N-dimethyl-benzamide (Foramsulfuron), 2-amino-4-(hydroxymethylphosphinyl)-butyric acid (ammonium salt) (glufosinate-ammonium (ammonium salt) )), N-phosphonomethylglycine (isopropylammonium salt) (glyphosate, glyphosate isopropylammonium salt), (R)-2-[4-(3-chloro-5-trifluoromethyl -pyridin-2-yl-oxy)-phenoxy]-propionic acid (methyl ester, 2-ethoxy-ethyl ester, butyl ester) (haloxyfop, haloxyfop, haloxyfop-ethyl Haloxyfop, Haloxyfop ethoxyethyl, Haloxyfop butyl), 3-cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4 (1H,3H)-diketone (hexazinone), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4 -Methyl-benzoate (methyl imidazolate), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)- 5-Methyl-pyridine-3-carboxylic acid (Imazamethapyr), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)- 5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazole -2-yl)-quinoline-3-carboxylic acid (imidazoquinolinic acid), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazole- 2-yl)-5-ethyl-pyridine-3-carboxylic acid (imazethapyr), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-chloro-imidazo[ 1,2-a]-pyridin-3-yl-sulfonyl)-urea (pyrazosulfuron), N-(4-methoxy-6-methyl-1,3,5-triazine-2 -yl)-N'-(5-iodo-2-methoxycarbonyl-phenylsulfonyl)-urea sodium salt (Iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodo-benzonitrile (iopronil), N, N-dimethyl-N'-(4-isopropyl-phenyl)-urea (isoproturon), N-(3-(1-ethyl-1-methyl -Propyl)-isoxazol-5-yl)-2,6-dimethoxy-benzamide (isoxachlor), (4-chloro-2-methylsulfonyl-phenyl)-( 5-cyclopropyl-isoxazol-4-yl)-methanone (Isoxachlortole), (5-cyclopropyl-isoxazol-4-yl)-(2-methylsulfonyl-4-trifluoromethane Base-phenyl)-methanone (isoxafluoride), 2-[2-[4-[(3,5-dichloro-2-pyridine)-oxyl]-phenoxy]-1-oxo -Propyl]-isoxazolidine (clomafen), (2-ethoxy-1-methyl-2-oxo-ethyl) 5-(2-chloro-4-trifluoromethyl- Phenoxy)-2-nitro-benzoate (lactofluazifop), N'-(3,4-dichloro-phenyl)-N-methoxy-N-methyl-urea ( Liguron), (4-chloro-2-methyl-phenoxy) acetic acid (2-methyl-4 chloro), 2-(4-chloro-2-methyl-phenoxy)-propionic acid (2-methyl-4 Chloropropionic acid), 2-(2-benzothiazolyloxy)-N-methyl-N-phenyl-acetamide (thiamid), 2-(4-methylsulfonyl-2- Nitro-benzoyl)-1,3-cyclohexanedione (Mesotrione), 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)-one (Metamitron), 2-Chloro-N-(2,6-dimethyl-phenyl)-N-(1H-pyrazol-1-yl-methyl)-acetamide (metafenamide), N' -(4-(3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxyl)-phenyl)-N -Methoxy-N-methyl-urea (pyranuron), N'-(4-bromophenyl)-N-methoxy-N-methylurea (brometriuron), (S)-2 -Chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide (metolachlor, S-isopropyl metolachlor), N-(2,6-dichloro-3-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo[1,5-a] Pyrimidine-2-sulfonamide (sulfentrazone), N'-(3-chloro-4-methoxy-phenyl)-N,N-dimethyl-urea (methoxolone), 4-amino- 6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metrimetrione), N-(4-methoxy-6-methyl-1,3 , 5-triazin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-urea (methsulfuron), S-ethyl-hexahydro-1H-azepine 1- Thioformic acid ester (molinate), 2-(2-naphthyloxy)-N-phenyl-propionamide (naphthylamine), N-butyl-N'-(3,4-dichloro-benzene Base)-N-methyl-urea (oxabulong), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(3-dimethylcarbamoyl-pyridine-2 -yl-sulfonyl)-urea (Nicosulfuron), S-(2-Chloro-benzyl)-N,N-diethyl-thiocarbamate (Pencadan), 4-Dipropyl Amino-3,5-dinitro-benzenesulfonamide (amisulfameline), 3-[2,4-dichloro-5-(2-propynyloxy)-phenyl]-5-(tert Butyl)-1,3,4-oxadiazol-2(3H)-one (propargyloxazone), 3-[2,4-dichloro-5-(1-methyl-ethoxy) -Phenyl]-5-(tert-butyl)-1,3,4-oxadiazol-2(3H)-one (oxadiazol), N-(4,6-dimethyl-pyrimidine-2- Base)-N'-(2-oxetane-3-yl-oxycarbonyl-phenylsulfonyl)-urea (cyclopropoxysulfuron), 3-[1-(3,5-dichloro Phenyl)-1-isopropyl]-2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-one (chloroxazin-4-one), 2-chloro -1-(3-ethoxy-4-nitro-phenoxy)-4-trifluoromethylphenyl (ethoxyfluorfen), 1,1'-dimethyl-4,4'- Bipyridylium salt (paraquat), 1-amino-N-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzene (dimethalin), 4 -(tert-butyl)-N-(1-ethyl-propyl)-2,6-dinitro-aniline (Pendralin), 4-amino-3,5,6-trichloro-pyridine-2-carboxy Acid (aminopyralid), 2-chloro-N-(2,6-diethyl-phenyl)-N-(2-propoxy-ethyl)-acetamide (pretilachlor), N- (4,6-bisdifluoromethoxy-pyrimidin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-urea (fluorosulfuron-methyl), 1-chloro-N- [2-Chloro-4-fluoro-5-[(6S,7aR)-6-fluoro-tetrahydro-1,3-dioxo-1H-pyrrolo[1,2-c]imidazole-2(3H) -yl]-phenyl]-methylsulfonamide (Profluazol), 2-chloro-N-isopropyl-N-phenyl-acetamide (toxachlor), N-(3,4-dichloro-phenyl )-propionamide (propanil), (R)-[2-[[(1-methyl-ethylene)-amino]-oxyl]-ethyl]-2-[4-(6-chloro- 2-quinoxalinyloxy)-phenoxy]-propionate (oxaclod-methyl), 2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-[(1- Methyl-ethoxy)-methyl]-acetamide (propachlor), 2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy- 1H-1,2,4-triazol-1-yl)-carbonyl]-amino]-sulfonyl]-methyl benzoate sodium salt (Propoxycarbazone-sodium salt), S-phenylmethyl N,N-di Propyl-thiocarbamate (trisulfocarb), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-( 3,3,3-Trifluoro-propyl)-phenylsulfonyl)-urea (flusulfuron), [2-chloro-5-(4-chloro-5-difluoromethoxy-1-methyl -1H-pyrazol-3-yl)-4-fluoro-phenoxy]-ethyl acetate (fenfentrazone-ethyl), 1-(3-chloro-4,5,6,7-tetrahydro-pyrazole And[1,5-a]pyridin-2-yl)-5-(methyl-2-propynylamino)-1H-pyrazole-4-carbonitrile (Pyrazogyl), 4-(2,4-dichloro -benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulfonyloxy)-pyrazole (pyrazolate), 4-(2,4-dichloro-benzyl Acyl)-1,3-dimethyl-5-(phenylcarbonyl-methoxy)-pyrazole (benzazole), N-(4,6-dimethoxy-pyrimidin-2-yl)- N'-(4-ethoxy-carbonyl-1-methyl-pyrazol-5-yl-sulfonyl)-urea (pyrazosulfuron), diphenyl ketone O-[2,6-bis- (4,6-dimethoxy-pyrimidin-2-yl-oxyl)-benzoyl]oxime (Pyribenaxime), 6-chloro-3-phenyl-4-pyridazinol (Pyridafol), O-(6-Chloro-3-phenyl-pyridazin-4-yl)S-octylthiocarbonate (Pyridatol), 6-Chloro-3-phenylpyridazin-4-ol (Pyridatol) , 7-[(4,6-dimethoxy-2-pyrimidinyl)-thio]-3-methyl-1(3H)-isobenzofuranone (Pyriftalid), 2-(4,6- Dimethoxy-pyrimidin-2-yl-oxy)-methyl benzoate (pyrimidin), 2-chloro-6-(4,6-dimethoxy-pyrimidin-2-ylthio)- Benzoic acid sodium salt (pyrimachlor), 3,7-dichloro-quinoline-8-carboxylic acid (Quinchlorac), 7-chloro-3-methyl-quinoline-8-carboxylic acid (quinclorac ), 2-[4-(6-chloro-2-quinoxalinyloxy)-phenoxy]-propionic acid (ethyl ester, tetrahydro-2-furyl-methyl ester) (quialofop, quinalofop Quizalofop-ethyl ester, quizalofop-ethyl ethyl ester, quizalofop-p-furyl ester), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(3-ethylsulfonyl -pyridin-2-yl-sulfonyl)-urea (rimsulfuron-methyl), 2-(1-ethoxyiminobutyl)-5-(2-ethylthiopropyl)-3-hydroxyl-2- Cyclohexen-1-one (sethenoxydine), 6-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazine), 2-(2-chloro-4-methyl Sulfonyl-benzoyl)-cyclohexane-1,3-dione (sulfotrione), 2-(2,4-dichloro-5-methyl-sulfonylamino-phenyl)-4- Difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (sulfentrazone), N-phosphonomethyl-glycine-trimethyl Sulfonium (glufosinate), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-ethylsulfonyl-imidazo[1,2-a]pyridine-3- base) sulfonamide (Ethhuanglong), 6-chloro-4-ethylamino-2-tert-butylamino-1,3,5-triazine (tertbutylazine), 2-tert-butylamino-4- Ethylamino-6-methylthio-1,3,5-triazine (Terbuzine), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(3-methoxy -2-thienyl-methyl)-acetamide (dimethenamid), 2-difluoromethyl-5-(4,5-dihydro-thiazol-2-yl)-4-(2-methyl- Propyl)-6-trifluoromethyl-pyridine-3-carboxylic acid methyl ester (thiazazole), 6-(6,7-dihydro-6,6-dimethyl-3H,5H-pyrrolo[2 , 1-c]-1,2,4-thiadiazole-3-ylidene amino)-7-fluoro-4-(2-propynyl)-2H-1,4-benzoxazine-3( 4H)-ketone (Thidiazimin), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxy-carbonyl-thiophene- 3-yl-sulfonyl)-urea (thifensulfuron), 2-(ethoxyimino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2- Cyclohexen-1-one (trimethylbenzotrione), S-(2,3,3-trichloro-2-propenyl) diisopropyl thiocarbamate (metrocam), N-(4 -Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-[2-(2-chloro-ethoxy)-phenylsulfonyl]-urea (ether benzene Sulfururon), N-methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-phenyl Sulfonyl)-urea (trisulfuron), (3,5,6-trichloro)-pyridin-2-yl-oxy-acetic acid (triclopyroxyacetic acid), 2-(3,5-dichloro- Phenyl)-2-(2,2,2-trichloro-ethyl)-oxirane (imazacycline), N-[[(4,6-dimethoxy-2-pyrimidinyl)- Amino]-carbonyl]-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide sodium salt (Trifloxysulfuron), 1-amino-2,6-dinitro-N,N-di Propyl-4-trifluoromethyl-benzene (trifluralin), N-[4-dimethylamino-6-(2,2,2-trifluoro-ethoxy)-1,3,5- Triazin-2-yl]-N'-(2-methoxycarbonyl-phenylsulfonyl)-urea (flusulfuron-methyl), N-[[(4,6-dimethoxy-2-pyrimidine base)amino]carbonyl]-3-(N-methyl-N-methylsulfonylamino)-2-pyridinesulfonamide (see WO-A-92/10660), 2-[[[[(4,6 -Dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]-sulfonyl]-4-[[(methylsulfonyl)amino]methyl]-benzoic acid methyl ester (see DE-A-4335297) , 4-[4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2,4-triazol-1-yl]-2-[( Ethylsulfonyl)amino]-5-fluoro-benzenethiocarbamide (see WO-A-95/30661)

(“Group 2 Active Compounds”)

and/or optionally

(d) A compound that can improve crop compatibility selected from the following group of compounds:

4-Dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane (AD-67), 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrole And[1,2-a]-pyrimidin-6(2H)-one (BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzo Oxazine (hexamethazine), 5-chloro-quinoxaline-8-oxyl-acetic acid 1-methyl-hexyl ester (quinoxyacetic acid-isoheptyl ester), α-(cyano-methoxyimino) -Phenylacetonitrile (Phenylethamide), 2,4-dichlorophenoxyacetic acid (2,4-D), 2,2-dichloro-N-(2-oxo-2-(2-propenyl Amino)-ethyl)-N-(2-propenyl)-acetamide (acetamide), 2,2-dichloro-N,N-di-2-propenyl-acetamide (acrylamide ), N-(4-methyl-phenyl)-N'-(1-methyl-1-phenyl-ethyl)-urea (diuron), 4,6-dichloro-2-phenyl -Pyrimidine (Cyclopyridine), 1-(2,4-dichloro-phenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-ethyl carboxylate (Cyclopyridine Ester), 2-chloro-4-trifluoromethyl-thiazole-5-benzoic acid benzyl ester (Clover), 4-chloro-N-(1,3-dioxolan-2-yl-methyl Oxygen)-α-trifluoro-acetophenone oxime (fluoxim), 3-dichloroacetyl-5-(2-furyl)-2,2-dimethyl-oxazolidine azole, MON-13900), 4,5-dihydro-5,5-diphenyl-3-isoxazole ethyl carboxylate (Isoxadifen-ethyl), (4-chloro-2-methyl-phenoxy) -Acetic acid (MCPA), (+-)-2-(4-chloro-2-methylphenoxy)propionic acid (2-methyl-4-chloropropionic acid), 1-(2,4-dichlorophenyl)- 4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylic acid diethyl ester (diethyl pyrrole diacid), 2-dichloromethyl-2-methyl-1,3 -Dioxolane (oxalane), 1,8-naphthalene dicarboxylic anhydride, α-(1,3-dioxolan-2-yl-methoxyimino)-phenylacetonitrile (oxalanil), 2,2-Dichloro-N-(1,3-dioxolan-2-yl-methyl)-N-(2-propenyl)-acetamide (PPG-1292) and 3-dichloroacetyl - 2,2,5-Trimethyl-oxazolidine (R-29148).

(“Group 3 Active Compounds”)

Particularly preferred active compound mixture components of group 2 are:

2-Chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamide (acetochlor), 2-chloro-N-(methoxymethyl Base)-N-(2,6-diethyl-phenyl)-acetamide (alachlor), 4-amino-N-(1,1-dimethyl-ethyl)-4,5-di Hydrogen-3-(1-methyl-ethyl)-5-oxo-1H-1,2,4-triazole-1-carboxamide (Amicarbazone), N-(4,6-dimethoxy- Pyrimidin-2-yl)-N'-(N-methyl-N-methyl-sulfonyl-sulfamoyl)-urea (acylsulfuron-methyl), 6-chloro-4-ethylamino-2-iso Propylamino-1,3,5-triazine (atrazine), N-benzyl-2-(4-fluoro-3-trifluoromethyl-phenoxy)butanamide (Beflubutamid), 3-iso Propyl-1H-2,1,3-benzothiadiazin-4(3H)-one (benzazone), 5-(2,4-dichloro-phenoxy)-2-nitro-benzene Methyl formate (Methyl carboxyben), 2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxyl)-sodium benzoate (bispyribac), 3,5-dibromo -4-Hydroxy-benzonitrile (bromoxynil), [1,1-dimethyl-2-oxo-2-(2-propenyloxy)]-ethyl 2-chloro-5-(3,6 -Dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)-benzoate (Butafenacil-allyl), 2-(4-chloro- 2-fluoro-5-(2-chloro-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2 , 4-triazol-3-one (fentrazone), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2- Chloro-phenylsulfonyl)-urea (chlorsulfuron), N'-(3-chloro-4-methyl-phenyl)-N,N-dimethylurea (chlorotoluron), 2-chloro- 3-[2-Chloro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl]-2- Ethyl propionate (Cinidon-ethyl), 2-propynyl (R)-2-[4-(5-chloro-3-fluoro-pyridin-2-yl-oxyl)-phenoxy]-propionic acid ester (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (diclopyridine acid), 2-chloro-4-ethylamino-6-(1-cyano-1-methyl-ethyl Amino)-1,3,5-triazine (cyanazine), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-cyclopropylcarbonyl-phenyl-sulfonyl Acyl)-urea (cyprosulfuron), 2,4-dichloro-phenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), (R)-2-(2,4-dichloro-phenoxy)-propionic acid (purified 2,4-propionic acid), 2-[4-(2,4-dichloro-phenoxy)- Phenoxy]-propionic acid methyl ester (milofop), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methylsulfate (Pyrizolium), N-(2 , 4-difluoro-phenyl)-2-(3-trifluoromethyl-phenoxy)-pyridine-3-carboxamide (difluramid), 2-[1-[(3,5- Difluoro-phenyl)-amino-carbonyl-hydrazono]-ethyl]-pyridine-3-carboxylic acid (difluoropyrone), (S-)2-chloro-N-(2,4-dimethyl Base-3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide ((S-)dimethenamid), S-ethyldipropylthioamino Formate (Intetrachlor), (S)-(2-ethoxy-1-methyl-2-oxoethyl)-2-chloro-5-(2-chloro-4-trifluoromethyl -phenoxy)benzoate (Ethoxyfen), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-ethoxy-phenoxysulfonyl)-urea (Ethoxysulfuron-methyl), (R)-2-[4-(6-chloro-benzoxazol-2-yl-oxyl)-phenoxy]-propionic acid ethyl ester spirit), N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-DL-alanine isopropyl ester (wheatgrass fluoroisopropyl ester), N-benzoyl-N-(3 -Chloro-4-fluoro-phenyl)-L-alanine isopropyl ester (Fluoroisopropyl-L), N-benzoyl-N-(3-chloro-4-fluoro-phenoxy) -DL-alanine methyl ester (fedrofluoromethyl ester), N-(2,6-difluoro-phenyl)-8-fluoro-5-methoxy-[1,2,4]-triazolo -[1,5-c]-pyrimidine-2-sulfonamide (Florasulam), 5-(4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl)-2- Chloro-4-fluoro-benzoic acid isopropyl ester (Fluazolate), 4,5-dihydro-3-methoxy-4-methyl-5-oxo-N-[(2-trifluoromethoxybenzene Base)-sulfonyl]-1H-1,2,4-triazole-1-carboxamide sodium salt (Flucarbazone-sodium salt), N-(4-fluoro-phenyl)-N-isopropyl-2- (5-Trifluoromethyl-1,3,4-thiadiazol-2-yl-oxyl)-acetamide (Flufenacet), N-(2,6-difluoro-phenyl)-5-methyl -1,2,4-Triazolo[1,5-a]-pyrimidine-2-sulfonamide (pyrimsulam), ethoxycarbonylmethyl 5-(2-chloro-4-trifluoromethane 1-(4-chloro-3-(2,2,3,3,3-pentafluoro-propoxy) Methyl)-phenyl)-5-phenyl-1H-1,2,4-triazole-3-carboxamide (flumiconazole), N-(4,6-dimethoxy-pyrimidine-2 -yl)-N'-(3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl)-urea sodium salt (fluridinesulfuron), 9-hydroxy-9H-fluorene -9-carboxylic acid (fluorene butyl ester), (4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxyl)-acetic acid (2-butoxy-1-methyl- Ethyl ester, 1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -isoheptyl ester), 5-methylamino-2-phenyl-4-(3-trifluoro Methyl-phenyl)-3(2H)-furanone (furanone), [(2-chloro-4-fluoro-5-(tetrahydro-3-oxo-1H,3H-[1,3, 4]-thiadiazolo-[3,4-a]-pyridazin-1-ylidene)-amino)-phenyl]-methyl thioacetate (Dazofar), 2-[[[[( 4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]-4-formylamino-N,N-dimethyl-benzamide (Formsulfuron), 2 -Amino-4-(hydroxymethylphosphinyl)-butyric acid (ammonium salt) (glufosinate-ammonium (ammonium salt)), N-phosphonomethylglycine (isopropylammonium salt) (glyphosate, glyphosate Phosphine isopropylammonium salt), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4-methyl-benzoic acid Ester (methyl imidazolate), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridine- 3-Carboxylic acid (Imazamethapyr), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl -Pyridine-3-carboxylic acid (imazamox), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-quinone Line-3-carboxylic acid (imidazoquinolinic acid), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5- Ethyl-pyridine-3-carboxylic acid (imazethapyr), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(5-iodo-2 -Methoxycarbonyl-phenylsulfonyl)-urea sodium salt (Iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodo-benzonitrile (iodoxynil), N,N-dimethyl -N'-(4-isopropyl-phenyl)-urea (isoproturon), N-(3-(1-ethyl-1-methyl-propyl)-isoxazol-5-yl) -2,6-dimethoxy-benzamide (clomachlor), (4-chloro-2-methylsulfonyl-phenyl)-(5-cyclopropyl-isoxazol-4-yl )-methanone (Isoxachlortole), (5-cyclopropyl-isoxazol-4-yl)-(2-methylsulfonyl-4-trifluoromethyl-phenyl)-methanone (isoxachlortole ), (4-chloro-2-methyl-phenoxy)acetic acid (2-methyl-4-chloro), 2-(4-chloro-2-methyl-phenoxy)-propionic acid (2-methyl-4-chloro-propionic acid ), 2-(4-methylsulfonyl-2-nitro-benzoyl)-1,3-cyclohexanedione (Mesotrione), 2-chloro-N-(2,6-dimethyl- Phenyl)-N-(1H-pyrazol-1-yl-methyl)-acetamide (metafenamide), (S)-2-chloro-N-(2-ethyl-6-methyl- Phenyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide (metolachlor, S-metolachlor), N-(2,6-dichloro- 3-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulfonamide (sulfentrazone), 4- Amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metrimetrione), N-(4-methoxy-6-methyl-1 , 3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-urea (methsulfuron), N-(4,6-dimethoxy-pyrimidine -2-yl)-N'-(3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl)-urea (nicotinesulfuron), 1-amino-N-(1-ethyl-propane base)-3,4-dimethyl-2,6-dinitro-benzene (dimethalin), N-(4,6-bis-difluoromethoxy-pyrimidin-2-yl)-N' -(2-methoxycarbonyl-phenylsulfonyl)-urea (fluorosulfuron-methyl), 2-chloro-N-isopropyl-N-phenyl-acetamide (toxachlor), N-(3, 4-dichloro-phenyl)-propanamide (propanil), 2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2 , 4-triazol-1-yl)-carbonyl]-amino]-sulfonyl]-methyl benzoate sodium salt (Propoxycarbazone-sodium salt), S-phenylmethyl N,N-dipropyl-thio Carbamate (procarbacarb), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-(3,3,3 -trifluoro-propyl)-phenylsulfonyl)-urea (flusulfuron), [2-chloro-5-(4-chloro-5-difluoromethoxy-1-methyl-1H-pyrazole -3-yl)-4-fluoro-phenoxy]-ethyl acetate (fenfentrazone-ethyl), O-(6-chloro-3-phenyl-pyridazin-4-yl)S-octylthio Carbonate (Pyridachlor), 7-Chloro-3-methyl-quinoline-8-carboxylic acid (quinolanic acid), N-(4,6-dimethoxy-pyrimidin-2-yl) -N'-(3-ethylsulfonyl-pyridin-2-yl-sulfonyl)-urea (rimsulfuron-methyl), 2-(1-ethoxyiminobutyl)-5-(2-ethylthio propyl)-3-hydroxy-2-cyclohexen-1-one (sethenoxydine), 6-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazine) , 2-(2-chloro-4-methylsulfonyl-benzoyl)-cyclohexane-1,3-dione (sulfotrione), N-phosphonomethyl-glycine-trimethylsulfonium ( Glufosinate), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-ethylsulfonyl-imidazo[1,2-a]pyridin-3-yl) Sulfonamide (Etosulfuron), 6-chloro-4-ethylamino-2-tert-butylamino-1,3,5-triazine (tertbutylazine), 2-tert-butylamino-4-ethylamino -6-Methylthio-1,3,5-triazine (Terbutine), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N '-(2-methoxy-carbonyl-thiophen-3-yl-sulfonyl)-urea (thifensulfuron), 2-(ethoxyimino-propyl)-3-hydroxy-5-(2,4 , 6-Trimethyl-phenyl)-2-cyclohexen-1-one (trimethylphenone), S-(2,3,3-trichloro-2-propenyl) diisopropylthio Carbamate (Camba), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-[2-(2-chloro-ethoxy Base)-phenylsulfonyl]-urea (trisulfuron-methyl), N-methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)- N'-(2-methoxycarbonyl-phenylsulfonyl)-urea (tribesulfuron), 2-(3,5-dichloro-phenyl)-2-(2,2,2-trichloro- Ethyl)-oxirane (imazacycline), N-[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3-(2,2,2-tri Fluoroethoxy)-2-pyridinesulfonamide sodium salt (Trifloxysulfuron), 1-amino-2,6-dinitro-N,N-dipropyl-4-trifluoromethyl-benzene (Trifloxyl) .

Particularly preferred active compound mixture components of group 3 are:

5-Chloro-quinoxaline-8-oxyl-acetic acid 1-methyl-hexyl ester (quinoxyacetic acid-isoheptyl ester), 1-(2,4-dichloro-phenyl)-5-trichloromethane Base-1H-1,2,4-triazole-3-ethyl carboxylate (oxaclofen ethyl), 4,5-dihydro-5,5-diphenyl-3-isoxazole carboxylate ethyl ester ( Isoxadifen-ethyl), 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylic acid diethyl ester (pyrrole diacid diethyl esters) and 2,4-dichlorophenoxyacetic acid (2,4-D) and its derivatives.

Compound 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylic acid diethyl ester (diethyl pyrrole diacid), 1-Methylhexyl[(5-chloro-8-quinolinyl)oxy]acetate (isoheptyl quinoxyacetate) and 1-(2,4-dichlorophenyl)-5-(trichloro Methyl)-1H-1,2,4-triazole-3-carboxylic acid ethyl ester (clofenacyl) is disclosed in the following patent applications: DE-A-3939503, EP-A-191736 and DE-A -3525205. 2,4-D is a known herbicide.

Surprisingly, it has now been found that active compound mixtures of the aforementioned Tritosulfuron and the aforementioned active compound of the first group, optionally mixed with the second active compound and/or the third active compound, are particularly effective in the It is active while being very crop tolerant and can be used in various crops, especially wheat, but also for the selective control of weeds in maize and barley.

Surprisingly, the herbicidal activity of the active compound mixture according to the invention formed from Tritosulfuron and the abovementioned compounds of group 1 is significantly higher than the sum of the effects of the individual active compounds.

Therefore, this indicates not only complementary but also unexpectedly synergistic activity. The new active compound mixture is well tolerated by a wide variety of crops, and here the new active compound mixture is also effective in controlling weeds which are otherwise difficult to control. Thus, a valuable new combination of active compounds has been added to the current selection of herbicides.

Furthermore, it has surprisingly been found that the above-mentioned mixture of active compounds consisting of Tritosulfuron and a safener/antidote ("group 3 active compounds"), in admixture with one or more of the above-mentioned active compounds of group 1, especially in Very high herbicidal activity with good crop tolerance and can be used in various crops, especially cereal crops, especially wheat, but also for selective control of weeds in soybeans, potatoes, maize and rice Grass.

Surprisingly, it has also been found that the herbicidally active substance 2,4-dichlorophenoxyacetic acid (2,4-D) and its derivatives can also act as safeners as described above.

And it is surprising that among a large number of known safeners or antidotes that can antagonize the toxic effects of herbicides on crops, especially the above-mentioned active compounds of the third group can almost completely cancel the combination of Tritosulfuron and one or more of the above-mentioned A mixture of active compounds from group 1 has a toxic effect on crops without adversely affecting the herbicidal activity on weeds.

The present invention prefers those particularly preferred group 3 blending components which are particularly advantageous for filling cereal crops, such as rice, wheat, barley and rye.

Very particular preference is given to mixtures of Tritosulfuron and Propoxycarbazone (-sodium salt) in admixture with one or more of the following active compounds:

N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(N-methyl-N-methyl-sulfonyl-sulfamoyl)-urea (acylsulfuron-methyl), 2 , 6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxyl)-sodium benzoate (bispyribac), 2-(4-chloro-2-fluoro-5-(2-chloro -2-ethoxycarbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one ( carfentrazone), 2-chloro-3-[2-chloro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindole-2 -yl)-phenyl]-2-propionic acid ethyl ester (Cinidon-ethyl), 2,4-dichloro-phenoxyacetic acid (2,4-D), (R)-2-(2,4-di Chloro-phenoxy)-propionic acid (perine 2,4-propionic acid), N-(2,4-difluoro-phenyl)-2-(3-trifluoromethyl-phenoxy)-pyridine -3-Carboxamide (difluramid), N-(4-fluoro-phenyl)-N-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazole- 2-yl-oxy)-acetamide (Flufenacet), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(3-methoxycarbonyl-6-trifluoromethyl Sodium salt of -pyridin-2-yl-sulfonyl)-urea (fluridinesulfuron), (4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxyl)-acetic acid ( 2-butoxy-1-methyl-ethyl ester, 1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -isoheptyl ester), N-(4-methoxy Sodium salt of -6-methyl-1,3,5-triazin-2-yl)-N'-(5-iodo-2-methoxycarbonyl-phenylsulfonyl)-urea (Iodosulfuron-methyl -sodium), N, N-dimethyl-N'-(4-isopropyl-phenyl)-urea (isoproturon), 2-(4-chloro-2-methyl-phenoxy)- Propionic acid (2-methyl-4-chloropropionic acid), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metrizinone), N- [[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide sodium salt (Trifloxysulfuron) .

Furthermore, very particular preference is given to mixtures of Tritosulfuron and Flucarbazone (-sodium salt) in admixture with one or more of the following active compounds:

2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxyl)-sodium benzoate (bispyribyl), 3,5-dibromo-4-hydroxy-benzonitrile (bromobenzene Nitrile), 2-(4-chloro-2-fluoro-5-(2-chloro-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2, 4-dihydro-3H-1,2,4-triazol-3-one (fentrazone), 2-chloro-3-[2-chloro-5-(1,3,4,5,6, 7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl]-2-propionic acid ethyl ester (Cinidon-ethyl), 2-propynyl (R)-2 -[4-(5-Chloro-3-fluoro-pyridin-2-yl-oxy)-phenoxy]-propionate (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (clopyralid), 2,4-dichloro-phenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), (R)-2 -[4-(6-Chloro-benzoxazol-2-yl-oxy)-phenoxy]-propionic acid ethyl ester (oxaprop-ethyl-ethyl), N-(2,6-difluoro- Phenyl)-8-fluoro-5-methoxy-[1,2,4]-triazolo-[1,5-c]-pyrimidine-2-sulfonamide (Florasulam), N-(4-fluoro -phenyl)-N-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxyl)-acetamide (Flufenacet), N-(4, Sodium salt of 6-dimethoxy-pyrimidin-2-yl)-N'-(3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl)-urea (fluridine yellow Long), (4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxyl)-acetic acid (2-butoxy-1-methyl-ethyl ester, 1-methyl -heptyl ester) (fluroxypyr, -butoxypropyl, -isoheptyl ester), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo- 1H-imidazol-2-yl)-4-methyl-benzoic acid methyl ester (imazamate), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo -1H-imidazol-2-yl)-5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), N-(4-methoxy-6-methyl-1,3,5 -Triazin-2-yl)-N'-(5-iodo-2-methoxycarbonyl-phenylsulfonyl)-urea sodium salt (Iodosulfuron-methyl-sodium), N,N-dimethyl- N'-(4-isopropyl-phenyl)-urea (isoproturon), (4-chloro-2-methyl-phenoxy)acetic acid (2-methyl-4-chloro), 2-(4-chloro- 2-Methyl-phenoxy)-propionic acid (2-methyl-4-chloropropionic acid), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5(4H) - Ketone (metrizinone), 2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazole-1- Base)-carbonyl]-amino]-sulfonyl]-methyl benzoate sodium salt (Propoxycarbazone-sodium salt), [2-chloro-5-(4-chloro-5-difluoromethoxy-1-methyl -1H-pyrazol-3-yl)-4-fluoro-phenoxy]-ethyl acetate (fenfentrazone-ethyl), N-(4,6-dimethoxy-pyrimidin-2-yl)-N '-(2-Ethylsulfonyl-imidazo[1,2-a]pyridin-3-yl)sulfonamide (Ethsulfuron), N-(4-methoxy-6-methyl-1, 3,5-Triazin-2-yl)-N'-(2-methoxy-carbonyl-thiophen-3-yl-sulfonyl)-urea (thifensulfuron), 2-(ethoxyimino-propane Base)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen-1-one (trimethylbenzotrione), S-(2,3,3-three Chloro-2-propenyl)diisopropylthiocarbamate (metrocam), N-[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3- (2,2,2-Trifluoroethoxy)-2-pyridinesulfonamide sodium salt (Trifloxysulfuron).

The active compound mixtures according to the invention can be applied, for example, to the following plants:

Dicotyledonous weed genera: Sepia genus, Lipea genus, Sorrel genus, Chickweed genus, Matricaria genus, Chamomile genus, Achyranthes genus, Chenopodium genus, Urtica genus, Senecio genus, Amaranthus genus , Purslane, Xanthium, Convolvulaceae, Ipomoea genus, Polygonum, Echinacea, Ragweed, Thistle, Flyricum, Endive, Solanum, Brassica, Argyle , Motherwort, Sesame, Popona, Abutilus, Rumex, Datura, Viola, Mustela, Poppy, Centaurea, Trifolium, Ranunculus and Dandelion.

Dicotyledonous crop genera: cotton, soybean, beet, carrot, bean, pea, nightshade, flax, yam, vetch, tobacco, tomato, arachis, brassica, lettuce genera, cantaloupe and squash.

Monocotyledonous weeds: barnyardgrass, setaria, panicum, crabgrass, timothy, bluegrass, fescue, cricket grass, brachiaria, ryegrass, brome, avena , sedge, sorghum, wheatgrass, bermudagrass, eucalyptus, scutellaria, arrowhead, water chestnut, grass, paspalum, duckbill, cuspidatum, dragon Clawgrass, Bentgrass, Apera, Apera and Grass.

Monocotyledonous crop genera: Oryza, Zea, Triticum, Hordeum, Avena, Rye, Sorghum, Panicum, Saccharum, Bromeliad, Asparagus, and Allium.

However, the use of the active compound mixture according to the invention is not restricted to the genera mentioned above, but extends in the same way to other plants.

According to the invention, it is possible to treat all plants and plant parts. Plants are understood here to mean all plants and plant communities, such as desired and undesired wild plants or crops (including naturally occurring crops). Crops can be plants obtained by conventional breeding and optimization methods or by biotechnology and genetic engineering methods or a combination of the above methods, including transgenic plants and including plant varieties with or without plant variety rights protection. Parts of plants are to be understood as meaning all aboveground and underground parts and plant tissues such as stems, leaves, flowers and roots, examples which may be mentioned are leaves, needles, branches, trunks, flowers, fruiting bodies, fruits and seeds and roots , tubers and rhizomes. Plant parts also include vegetative and generative propagation material, for example seedlings, tubers, rhizomes, cuttings and seeds.

The treatment of plants and plant parts with the active compounds according to the invention is carried out by direct application or by acting on their environment, habitat or storage area by conventional treatment methods, such as dipping, spraying, fumigation, misting, broadcasting, brushing and in In the case of propagation material, especially seeds, one or more coatings may also be applied.

The synergistic effect of the active compound mixture of the present invention is particularly obvious at a certain concentration ratio. However, the weight ratios of the individual active compounds in the active compound mixture can be varied within relatively wide ranges. In general, 0.01-1000 parts by weight, preferably 0.05-500 parts by weight and particularly preferably 0.1-100 parts by weight of a compound of group 1 are used per part by weight of Tritosulfuron.

Likewise, the crop compatibility of the active compound mixture according to the invention is particularly pronounced in a certain concentration ratio range. However, the weight ratios of the individual active compounds in the active compound mixture can be varied within relatively wide ranges. In general, 0.001-1000 parts by weight, preferably 0.01-100 parts by weight and particularly preferably 0.1-10 parts by weight of group 3 are used per part by weight of Tritosulfuron or in admixture with the active compounds of group 1, and optionally with the active compounds of group 2 active compound.

The active compound mixture according to the invention can be converted into customary preparations, such as solutions, emulsions, wettable powders, suspensions, powders, fine powders, pastes, soluble powders, granules, concentrated suspoemulsions, impregnated with active compounds natural and synthetic materials, and microcapsules in polymers.

These formulations are produced by known methods, for example by mixing the active compounds with extenders, i.e. liquid solvents and/or solid carriers, optionally using surfactants, i.e. emulsifiers and/or dispersants and / or blowing agent.

In the case of using water as an extender, for example, an organic solvent can also be used as a co-solvent. Suitable liquid solvents mainly include: aromatic hydrocarbons, such as xylene, toluene or alkylnaphthalene, chlorinated aromatic hydrocarbons and chlorinated aliphatic hydrocarbons, such as chlorobenzene, dichloroethane or methylene chloride, aliphatic hydrocarbons, such as Cyclohexane or paraffins such as petroleum distillates, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethylformamide and dimethylsulfoxide, and water.

Suitable solid carriers are:

For example, ammonium salts and natural mineral powders such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and synthetic mineral powders such as highly disperse silica, alumina and silicates ; suitable solid carriers for granules are: for example, crushed and graded natural rocks, such as calcite, marble, pumice, sepiolite and dolomite, and synthetic granules of inorganic and organic powders, and granules of organic materials, such as sawdust, nuts Husks, cob stems and tobacco stems; suitable emulsifiers and/or foaming agents are, for example, nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, such as alkylarylpolyethylene Glycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolysates; suitable dispersants are, for example, lignosulfurous acid waste liquor and methylcellulose.

Adhesives such as carboxymethylcellulose and natural or synthetic polymers in powder, granular or latex form such as gum arabic, polyvinyl alcohol and polyvinyl acetate, and natural phospholipids such as cephalin and lecithin can also be used in the formulation , and synthetic phospholipids. Other additives may be mineral and vegetable oils.

Possible use of colorants such as inorganic pigments such as iron oxide, titanium oxide and Prussian blue, and organic dyes such as alizarin dyes, azo dyes and metal phthalocyanine dyes, and trace nutrients such as iron, manganese, boron, Salts of copper, cobalt, molybdenum and zinc.

The formulations generally contain 0.1-95%, preferably 0.5-90%, by weight of active compound, including safeners.

In general, the active compound mixtures according to the invention are used in ready-to-mix form. However, the active compounds included in the active compound mixture can also be formulated individually and mixed at the time of use, ie in the form of a tank mix.

The novel active compound mixtures can be used as such or in the form of formulations, and can furthermore be mixed with other known herbicides, where it is also possible to use them in the form of ready-to-use or tank mixes. They can also be mixed with other known active compounds, such as fungicides, insecticides, acaricides, nematicides, bird repellants, growth regulators, plant nutrients and soil conditioners. Depending on the specific purpose of application, especially when applied post-emergence, it may also be preferable to add plant-tolerant mineral or vegetable oils (such as the commercially available product "Rako Binol") or ammonium salts, such as ammonium sulfate or thiocyanate, to the formulation Ammonium as an additional additive.

The novel active compound mixtures according to the invention can be used as such, in the form of their formulations or in the application forms prepared by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. The formulations described above can be applied in a conventional manner, for example by watering, spraying, misting, dusting or broadcasting.

The active compound mixtures according to the invention can be applied both before and after emergence of the plants, ie pre-emergence and post-emergence. The active compound mixture can also be mixed into the soil before sowing.

Herbicide synergy is present when the herbicidal activity of the active compound mixture exceeds the activity of the individual active compounds when applied individually.

The expected activity of a given mixture of two herbicides is calculated according to the following formula (cf. COLBY, S.R.: "Calculation of synergistic and antagonistic effects of herbicidal mixtures", Weeds 15, pp. 20-22, 1967):

If X = % damage of herbicide A at application rate p kg/ha

and Y = % damage of herbicide B applied at q kg/ha

and E = % damage expected for herbicides A and B at application rates p and q kg/ha,

Then E=X+Y-(X*Y/100).

If the actual damage is greater than the calculated expected value, then the activity of the mixture is greater than the sum, that is, it has synergistic activity.

For a three-component herbicidal mixture, the formula is:

E＝X+Y+Z-((X*Y+X*Z+Y*Z)/100)+(X*Y*Z/10000),

in

Z = % damage of herbicide C when the application rate is r kg/ha

Application example:

The customary formulations of the abovementioned active compounds are used. Propoxycarbazone-sodium salt uses 70WG and Tritosulfuron uses 71.4WG formulations. An aqueous spray solution of the active compound added with 0.1% Renex-36 was prepared. Post-emergence/greenhouse test of embodiment A

The test plants were grown in a greenhouse with controlled environmental conditions (temperature and light conditions). When the plants reached a height of 5-15 cm, they were sprayed with the test solution. The concentrations of the spray liquors are chosen so that the specific amount of active compound required in each case is applied with 500 liters of water/ha.

After the spray treatment, the plant containers were kept in a greenhouse under constant light and temperature conditions.

After about three weeks, the degree of injury to the crops was assessed in % injury compared to the development of the untreated control.

The following numbers represent:

0% = no harm (similar to untreated control)

100% = all kills/damage

The active compounds, application rates, test plants and results are listed in the table below, where the abbreviations used in the table stand for the following:

a.i. = active ingredient = active compound

Table A-1 Application rate gai/ha black brome observations Calculated black brome ^* Propoxycarbazone-sodium salt 30 95 Tritosulfuron 158 00 Propoxycarbazone-sodium salt+Tritosulfuron 30+1530+8 100100 9595

Table A-2 Application rate gai/ha Abutilon observations Calculated value of Abutilon ^* Propoxycarbazone-sodium salt 3015 200 Tritosulfuron 3015 400 Propoxycarbazone-sodium salt+Tritosulfuron 30+3015+3030+1515+15 80807070 5240200

Table A-3 Application rate gai/ha Quinoa observations Calculated for quinoa ^* Propoxycarbazone-sodium salt 30 60 Tritosulfuron 8 40 Propoxycarbazone-sodium salt+Tritosulfuron 30+8 100 76

Table A-4 Application rategai/ha Polcoconudvulus observations Calculated Polcoconudvulus ^* Propoxycarbazone-sodium salt 30 0 Tritosulfuron 308 500 Propoxycarbazone-sodium salt+Tritosulfuron 30+3030+8 8040 500

Table A-5 Application rate gai/ha Solanum nigrum observations Solanum Calc ^.* Propoxycarbazone-sodium salt 3015 5050 Tritosulfuron 30158 707030 Propoxycarbazone-sodium salt+Tritosulfuron 30+3015+3030+1515+1530+8   10098989598 8585858565

Table A-6 Application rate gai/ha Chickweed Observations Calculated Chickweed ^* Propoxycarbazone-sodium salt 30 20 Tritosulfuron 8 50 Propoxycarbazone-sodium salt+Tritosulfuron 30+8 100 60

Table A-7 Application rate gai/ha Arabian mother-in-law observations Calculated Arabic nah ^* Propoxycarbazone-sodium salt 30 20 Tritosulfuron 30 40 Propoxycarbazone-sodium salt+Tritosulfuron 30+30 90 52

Table A-8 Application rategai/ha Field Viola observation value Viola field calculated value ^* Propoxycarbazone-sodium salt 3015 6030 Tritosulfuron 15 0 Propoxycarbazone-sodium salt+Tritosulfuron 30+1515+15 9570 6030 ^* Value calculated according to Colby's method

Claims (5)

1. A herbicidal composition characterized in that they contain a synergistically effective amount of a mixture of active compounds comprising (a) Tritosulfuron and (b) One or more compounds selected from the group of herbicides containing the following active compounds: (5-Trifluoromethyl-1,3,4-thiadiazol-2-yl-oxyl)-N-isopropyl-N-(4-fluoro-phenyl)acetamide (Flufenacet), 2- (2-Methoxycarbonylbenzenesulfonylaminocarbonyl)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one or the compound Sodium salt of (Propoxycarbazone(-sodium salt)), 2-(2-trifluoromethoxy-benzenesulfonyl-aminocarbonyl)-4-methyl-5-methoxy-2,4-dihydro-3H -1,2,4-triazol-3-one or the sodium salt of the compound (Flucarbazone (-sodium salt)), N-(3,4-dichlorophenyl) propionamide (propanil), N-2 -Benzothiazolyl-N, N'-dimethylurea (methylbenzothiuron), 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1 , 2,4-triazin-5(4H)-one (metrizinone), 4-(2-chlorophenyl)-N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo Substituent-1H-tetrazole-1-carboxamide (Fentrazamide), 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)-one (metrazone) , 2-(2-Benzothiazolyloxy)-N-methyl-N-phenylacetamide (Mefenacet), 4-amino-6-(1,1-dimethylethyl) -3-(ethylthio)-1,2,4-triazin-5(4H)-one (ethazinone), 5-[4-bromo-1-methyl-5-(trifluoromethyl )-1H-pyrazol-3-yl]-2-chloro-4-fluorobenzoic acid 1-methyl ethyl ester (Fluazolate) (“Group 1 Active Compounds”) and optional (c) One or more compounds selected from the second group of herbicides containing the following active compounds: 2-Chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamide (acetochlor), 5-(2-chloro-4-trifluoro Methyl-phenoxy)-2-nitro-benzoic acid sodium salt (Acifluorfen), 2-Chloro-6-nitro-3-phenoxy-aniline (Aciclofen), 2-Chloro- N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-acetamide (alachlor), N-ethyl-N'-isopropyl-6-methylthio -1,3,5-triazine-2,4-diamine (ametrazine), 4-amino-N-(1,1-dimethyl-ethyl)-4,5-dihydro-3- (1-methyl-ethyl)-5-oxo-1H-1,2,4-triazole-1-carboxamide (Amicarbazone), N-(4,6-dimethoxy-pyrimidine-2- base)-N'-(N-methyl-N-methyl-sulfonyl-sulfamoyl)-urea (acylsulfuron-methyl), 1H-1,2,4-triazol-3-amine (herbicide strong), 6-chloro-4-ethylamino-2-isopropylamino-1,3,5-triazine (atrazine), 2-[2,4-dichloro-5-(2-propane Alkynyloxy)-phenyl]-5,6,7,8-tetrahydro-1,2,4-triazolo-[4,3-a]-pyridine-3(2H)-one (oxazolidine grass), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-[1-methyl-4-(2-methyl-2H-tetrazol-5-yl)-1H -pyrazol-5-yl-sulfonyl]-urea (rimsulfuron-methyl), N-benzyl-2-(4-fluoro-3-trifluoromethyl-phenoxy)butanamide (Beflubutamid), 4-Chloro-2-oxo-3(2H)-benzothiazole acetic acid (Azalea), N-butyl-N-ethyl-2,6-dinitro-4-trifluoromethyl-aniline (Butafluran), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-methoxycarbonyl-phenylmethylsulfonyl)-urea (benzazanthin Long), 2-[2-[4-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)phenoxy ]methyl]-5-ethyl-phenoxy-propionic acid methyl ester (Benzfendizone), 3-(2-chloro-4-methylsulfonyl-benzoyl)-4-phenylthio-bicyclo- [3.2.1]-oct-3-en-2-one (Benzobicyclon), N-benzoyl-N-(3,4-dichloro-phenyl)-DL-aminopropionic acid ethyl ester (new Yanling ), 3-isopropyl-1H-2, 1,3-benzothiadiazin-4(3H)-one (benzazone), 5-(2,4-dichloro-phenoxy)-2 -Nitro-methyl benzoate (methylcarboxyben), 2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxyl)-sodium benzoate (bispyribac), 2 -Bromo-3,3-dimethyl-N-(1-methyl-1-phenyl-ethyl)-butyramide (bromobutyramide), 3,5-dibromo-4-hydroxy-benzene Formaldehyde O-(2,4-dinitro-phenyl)oxime (bromophenol oxime), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), N-butoxy-methyl- 2-Chloro-N-(2,6-diethyl-phenyl)-acetamide (butachlor), [1,1-dimethyl-2-oxo-2-(2-propenyloxy) ]-ethyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)-benzoic acid Ester (Butafenacil-allyl), 2-(1-ethoxyimino-propyl)-3-hydroxy-5-[2,4,6-trimethyl-3-(1-oxo-butyl) -Phenyl]-2-cyclohexen-1-one (butoxycyclone), S-ethylbis-(2-methyl-propyl)-thiocarbamate (butachlor), N , N-diethyl-3-(2,4,6-trimethyl-phenylsulfonyl)-1H-1,2,4-triazole-1-carboxamide (benzoconazole), 2-[ 1-[(3-Chloro-2-propenyl)-oxy-imino]-propyl]-3-hydroxy-5-(tetrahydro-2H-pyran-4-yl)-2-cyclohexene -1-keto (quinoxamate), 2-(4-chloro-2-fluoro-5-(2-chloro-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluoromethyl- 5-Methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (fentrazone), 2,4-dichloro-1-(3-methoxy-4 -Nitro-phenoxy)-benzene (methoxypyramid), 3-amino-2,5-dichloro-benzoic acid (pyrazon), N-(4-chloro-6-methoxy-pyrimidine -2-yl)-N'-(2-ethoxycarbonyl-phenylsulfonyl)-urea (chlorimuron-methyl), 1,3,5-trichloro-2-(4-nitro-phenoxy Base)-Benzene (Phenylsulfonyl), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-chloro-phenylsulfonyl )-urea (chlorsulfuron), N'-(3-chloro-4-methyl-phenyl)-N,N-dimethylurea (chlorotoluron), 2-chloro-3-[2-chloro -5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl]-2-propionic acid ethyl ester (Cinidon -ethyl), N-(4,6-dimethoxy-1,3,5-triazin-2-yl)-N'-(2-(2-methoxy-ethoxy)-phenyl Sulfonyl)-urea (ethersulfuron), 2-[1-[2-(4-chloro-phenoxy)-propoxyamino]butyl]-5-(tetrahydro-2H-thiopyran-3 -yl)-1,3-cyclohexanedione (Clefoxydim), (E,E)-(+)-2-[1-[[(3-chloro-2-propenyl)-oxyl]-ylidene Amino]-propyl]-3-hydroxy-2-cyclohexen-1-one (clethodim), 2-propynyl (R)-2-[4-(5-chloro-3-fluoro-pyridine -2-yl-oxy)-phenoxy]-propionate (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (diclopyralid), 3-chloro-2-[ (5-Ethoxy-7-fluoro[1,2,4]triazolo[1,5-c]pyrimidin-2-yl-sulfonyl)-amino]-benzoic acid methyl ester (sulfazoline sulfonamide salt) , 2-chloro-4-ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazine (cyanazine), N-(4,6-dimethoxy Base-pyrimidin-2-yl)-N'-(2-cyclopropylcarbonyl-phenyl-sulfonyl)-urea (cyprosulfuron-methyl), 2-(1-ethoxyiminobutyl)-3 -Hydroxy-5-(tetrahydro-2H-thiopyran-3-yl)-2-cyclohexen-1-one (cycloxydone), (R)-2-[4-(4-cyano-2 -Fluoro-phenoxy)-phenoxy]-butyl propionate (cyhalofop-methyl), 2,4-dichloro-phenoxyacetic acid (2,4-D), 3,6-dichloro-2 -Methoxy-benzoic acid (dicamba), (R)-2-(2,4-dichloro-phenoxy)-propionic acid (purified 2,4-propionic acid), 2-[4-( 2,4-dichloro-phenoxy)-phenoxy]-propionic acid methyl ester (milofop), N-(2,6-dichloro-phenyl)-5-ethoxy-7-fluoro -[1,2,4]-triazolo-[1,5-c]-pyrimidine-2-sulfonamide (pyrimidinesulfonamide), 1,2-dimethyl-3,5-diphenyl-1H -Pyrazolium methylsulfate (Vertifera), N-(2,4-difluoro-phenyl)-2-(3-trifluoromethyl-phenoxy)-pyridine-3-carboxamide ( diflufenamide), 2-[1-[(3,5-difluoro-phenyl)-amino-carbonyl-hydrazono]-ethyl]-pyridine-3-carboxylic acid (difluoropyrone) , S-(1-methyl-1-phenyl-ethyl) 1-piperidine-thiocarbamate (Pipazol), (S-) 2-chloro-N-(2,4-dimethyl Base-3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide ((S-) dimenamid), 2-amino-4-(1-fluoro -1-methyl-ethyl)-6-(1-methyl-2-(3,5-dimethyl-phenoxy)-ethylamino)-1,3,5-triazine (Dimexyflam), N3, N3-diethyl-2,4-dinitro-6-trifluoromethyl-1,3-diamino-benzene (trolamine), 6,7-dihydro-bipyrido[1, 2-a: 2′,1′-c]pyrazinedioium (diquat), S,S-dimethyl 2-difluoromethyl-4-isobutyl-6-trifluoromethylpyridine- 3,5-dithiocarbamate (dithiopyr), N'-(3,4-dichloro-phenyl)-N,N-dimethyl-urea (diuron), 2-[ 2-(3-Chloro-phenyl)-oxiranylmethyl]-2-ethyl-1H-indene-1,3(2H)-dione (Epropodan), S-ethyldipropylthio Substituted carbamate (endiprid), S-(phenylmethyl) N-ethyl-N-(1,2-dimethyl-propyl)-thiocarbamate (pentachlor) , N-ethyl-N-(2-methyl-2-propenyl)-2,6-dinitro-4-trifluoromethyl-aniline (ethoxyl- 1-Methyl-2-oxo-ethyl (S)-2-chloro-5-(2-chloro-4-trifluoromethyl-phenoxy)benzoate (Ethoxyfen), N-(4 , 6-dimethoxy-pyrimidin-2-yl)-N'-(2-ethoxy-phenoxysulfonyl)-urea (ethoxysulfuron), (R)-2-[4- (6-Chloro-benzoxazol-2-yl-oxy)-phenoxy]-ethyl propionate (oxaprop-ethyl-ethyl), 4-(2-chloro-phenyl)-N-ring Hexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (Fentrazamide), N-benzoyl-N-(3-chloro-4-fluoro-benzene base)-DL-alanine isopropyl ester (wheat straw fluoroisopropyl ester), N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-L-alanine isopropyl ester (wheat straw Fluoroisopropyl ester-L), N-benzoyl-N-(3-chloro-4-fluoro-phenoxy)-DL-alanine methyl ester (flium fluoromethyl ester), N-(2,6 -difluoro-phenyl)-8-fluoro-5-methoxy-[1,2,4]-triazolo-[1,5-c]-pyrimidine-2-sulfonamide (Florasulam), (R )-2-[4-(5-trifluoromethyl-pyridin-2-yl-oxyl)-phenoxy]-butyl propionate ester), 5-(4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl)-2-chloro-4-fluoro-isopropyl benzoate (Fluazolate), 4 , 5-dihydro-3-methoxy-4-methyl-5-oxo-N-[(2-trifluoromethoxyphenyl)-sulfonyl]-1H-1,2,4-tri Azole-1-carboxamide sodium salt (Flucarbazone-sodium salt), N-(4-fluoro-phenyl)-N-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadi Azol-2-yl-oxy)-acetamide (Flufenacet), N-(2,6-difluoro-phenyl)-5-methyl-1,2,4-triazolo[1,5-a ]-pyrimidine-2-sulfonamide (trimesulfame), [2-chloro-4-fluoro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo -2H-isoindol-2-yl)-phenoxy]-pentyl acetate (pentyl oxalate), 2-[7-fluoro-3,4-dihydro-3-oxo-4-( 2-propynyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydro-1H-isoindole-1,3-dione (propynyl fluoride Grass amine), 2-[4-chloro-2-fluoro-5-[(1-methyl-2-propynyl)-oxyl]-phenyl]-4,5,6,7-tetrahydro- 1H-isoindole-1,3(2H)-dione (Flumipropyn), 3-chloro-4-chloromethyl-1-(3-trifluoromethyl-phenyl)-2-pyrrolidinedione ( Flumetrione), Ethoxycarbonylmethyl 5-(2-Chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoate (Cyclofenac), 1- (4-Chloro-3-(2,2,3,3,3-pentafluoro-propoxymethyl)-phenyl)-5-phenyl-1H-1,2,4-triazole-3- Formamide (flumitrazone), 1-isopropyl-2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-benzoate (Flupropacil), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(3-methoxycarbonyl-6-trifluoro Methyl-pyridin-2-yl-sulfonyl)-urea sodium salt (fluridine sulfuron), 9-hydroxy-9H-fluorene-9-carboxylic acid (fluorene butyl ester), (4-amino-3,5 -dichloro-6-fluoro-pyridin-2-yl-oxy)-acetic acid (2-butoxy-1-methyl-ethyl ester, 1-methyl-heptyl ester) (fluroxypyroxyacetic acid , -butoxypropyl, -isoheptyl), 5-methylamino-2-phenyl-4-(3-trifluoromethyl-phenyl)-3(2H)-furanone (furanone) , [(2-chloro-4-fluoro-5-(tetrahydro-3-oxo-1H,3H-[1,3,4]-thiadiazolo-[3,4-a]-pyridazine- 1-ylidene)-amino)-phenyl]-methyl thioacetate (dazaflur), 5-(2-chloro-4-trifluoromethyl-propoxy)-N-methylsulfonyl- 2-Nitro-benzamide (fomesafen), 2-[[[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]- 4-Formylamino-N, N-dimethyl-benzamide (Foramsulfuron), 2-amino-4-(hydroxymethylphosphinyl)-butyric acid (ammonium salt) (glufosinate-ammonium (ammonium salt) ), N-phosphonomethylglycine (isopropylammonium salt) (glyphosate, glyphosate isopropylammonium salt), (R)-2-[4-(3-chloro-5-trifluoromethyl- Pyridin-2-yl-oxy)-phenoxy]-propionic acid (methyl ester, 2-ethoxy-ethyl ester, butyl ester) (haloxyfop, haloxyfop, haloxyfop-p-ethyl Spirit, haloxyfop ethoxyethyl ester, haloxyfop butyl ester), 3-cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4( 1H,3H)-diketone (hexazinone), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4- Methyl-benzoic acid methyl ester (imidazolate), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5 -Methyl-pyridine-3-carboxylic acid (Imazamethapyr), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5 -Methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazole- 2-yl)-quinoline-3-carboxylic acid (imidazoquinolinic acid), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazole-2 -yl)-5-ethyl-pyridine-3-carboxylic acid (imazethapyr), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-chloro-imidazo[1 , 2-a]-pyridin-3-yl-sulfonyl)-urea (pyrazosulfuron), N-(4-methoxy-6-methyl-1,3,5-triazine-2- Base)-N'-(5-iodo-2-methoxycarbonyl-phenylsulfonyl)-urea sodium salt (Iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodo-benzonitrile ( Iodooxynil), N, N-dimethyl-N'-(4-isopropyl-phenyl)-urea (isoproturon), N-(3-(1-ethyl-1-methyl- Propyl)-isoxazol-5-yl)-2,6-dimethoxy-benzamide (isoxachlor), (4-chloro-2-methylsulfonyl-phenyl)-(5 -Cyclopropyl-isoxazol-4-yl)-methanone (Isoxachlortole), (5-cyclopropyl-isoxazol-4-yl)-(2-methylsulfonyl-4-trifluoromethyl -Phenyl)-methanone (isoxafluoride), 2-[2-[4-[(3,5-dichloro-2-pyridine)-oxyl]-phenoxy]-1-oxo- Propyl]-isoxazolidine (clomafen), (2-ethoxy-1-methyl-2-oxo-ethyl)5-(2-chloro-4-trifluoromethyl-benzene Oxygen)-2-nitro-benzoate (lactofluazifop), N'-(3,4-dichloro-phenyl)-N-methoxy-N-methyl-urea ( Gulong), (4-chloro-2-methyl-phenoxy)acetic acid (2-methyl-4-chloro), 2-(4-chloro-2-methyl-phenoxy)-propionic acid (2-methyl-4-chloro propionic acid), 2-(2-benzothiazolyloxy)-N-methyl-N-phenyl-acetamide (thiamid), 2-(4-methylsulfonyl-2-nitro Base-benzoyl)-1,3-cyclohexanedione (Mesotrione), 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)-one ( Metamitron), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(1H-pyrazol-1-yl-methyl)-acetamide (Metrametrachlor), N' -(4-(3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxyl)-phenyl)-N -Methoxy-N-methyl-urea (pyranuron), N'-(4-bromophenyl)-N-methoxy-N-methylurea (brometriuron), (S)-2 -Chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide (metolachlor, S-isopropyl metolachlor), N-(2,6-dichloro-3-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo[1,5-a] -Pyrimidine-2-sulfonamide (sulfentrazone), N'-(3-chloro-4-methoxy-phenyl)-N,N-dimethyl-urea (methoxolone), 4-amino -6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metrimetrione), N-(4-methoxy-6-methyl-1, 3,5-Triazin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-urea (methsulfuron), S-ethyl-hexahydro-1H-azepine 1 - Thioformate (molinate), 2-(2-naphthyloxy)-N-phenyl-propionamide (naphthylamine), N-butyl-N'-(3,4-dichloro- Phenyl)-N-methyl-urea (pyridine), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(3-dimethylcarbamoyl-pyridine- 2-yl-sulfonyl)-urea (nicotinesulfuron), S-(2-chloro-benzyl)-N,N-diethyl-thiocarbamate (turfone), 4-di Propylamino-3,5-dinitro-benzenesulfonamide (amisulfameline), 3-[2,4-dichloro-5-(2-propynyloxy)-phenyl]-5-( tert-butyl)-1,3,4-oxadiazol-2(3H)-one (propargyloxazone), 3-[2,4-dichloro-5-(1-methyl-ethoxy )-phenyl]-5-(tert-butyl)-1,3,4-oxadiazol-2(3H)-one (oxadiazol), N-(4,6-dimethyl-pyrimidine-2 -yl)-N'-(2-oxetan-3-yl-oxycarbonyl-phenylsulfonyl)-urea (cyclopropoxysulfuron), 3-[1-(3,5-di Chlorophenyl)-1-isopropyl]-2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-one (chloroxazin-4-one), 2- Chloro-1-(3-ethoxy-4-nitro-phenoxy)-4-trifluoromethylphenyl (oxyfluorfen), 1,1'-dimethyl-4,4' - bipyridylium salt (paraquat), 1-amino-N-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzene (dimethalin), 4-(tert-butyl)-N-(1-ethyl-propyl)-2,6-dinitro-aniline (Pendralin), 4-amino-3,5,6-trichloro-pyridine-2- Carboxylic acid (aminopyralid), 2-chloro-N-(2,6-diethyl-phenyl)-N-(2-propoxy-ethyl)-acetamide (pretilachlor), N -(4,6-bisdifluoromethoxy-pyrimidin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-urea (fluorosulfuron-methyl), 1-chloro-N -[2-Chloro-4-fluoro-5-[(6S, 7aR)-6-fluoro-tetrahydro-1,3-dioxo-1H-pyrrolo[1,2-c]imidazole-2(3H )-yl]-phenyl]-ylsulfonamide (Profluazol), 2-chloro-N-isopropyl-N-phenyl-acetamide (toxachlor), N-(3,4-dichloro-phenyl )-propionamide (propanil), (R)-[2-[[(1-methyl-ethylene)-amino]-oxyl]-ethyl]-2-[4-(6-chloro- 2-quinoxalinyloxy)-phenoxy]]-propionate (oxaclod-methyl), 2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-[(1 -methyl-ethoxy)-methyl]-acetamide (propachlor), 2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy -1H-1,2,4-triazol-1-yl)-carbonyl]-amino]-sulfonyl]-methyl benzoate sodium salt (Propoxycarbazone-sodium salt), S-phenylmethyl N, N- Dipropyl-thiocarbamate (procarbacarb), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2- (3,3,3-Trifluoro-propyl)-phenylsulfonyl)-urea (flusulfuron), [2-chloro-5-(4-chloro-5-difluoromethoxy-1-methyl Base-1H-pyrazol-3-yl)-4-fluoro-phenoxy]-ethyl acetate (fenfentrazone-ethyl), 1-(3-chloro-4,5,6,7-tetrahydro-pyridine Azolo[1,5-a]pyridin-2-yl)-5-(methyl-2-propynylamino)-1H-pyrazole-4-carbonitrile (Pyrazogyl), 4-(2,4-di Chloro-benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulfonyloxy)-pyrazole (pyrazolate), 4-(2,4-dichloro-benzene Formyl)-1,3-dimethyl-5-(phenylcarbonyl-methoxy)-pyrazole (benzazole), N-(4,6-dimethoxy-pyrimidin-2-yl) -N'-(4-ethoxy-carbonyl-1-methyl-pyrazol-5-yl-sulfonyl)-urea (pyrazosulfuron), diphenyl ketone O-[2,6-bis -(4,6-dimethoxy-pyrimidin-2-yl-oxyl)-benzoyl]oxime (Pyribenaxime), 6-chloro-3-phenyl-4-pyridazinol (Pyridafol) , O-(6-chloro-3-phenyl-pyridazin-4-yl) S-octyl thiocarbonate (pyridate), 6-chloro-3-phenylpyridazin-4-alcohol (Pyridatol ), 7-[(4,6-dimethoxy-2-pyrimidinyl)-thio]-3-methyl-1(3H)-isobenzofuranone (Pyriftalid), 2-(4,6 -dimethoxy-pyrimidin-2-yl-oxy)-methyl benzoate (trimethyridine), 2-chloro-6-(4,6-dimethoxy-pyrimidin-2-ylthio) - Benzoic acid sodium salt (pyrimachlor), 3,7-dichloro-quinoline-8-carboxylic acid (Quinchlorac), 7-chloro-3-methyl-quinoline-8-carboxylic acid (chloromethylquinoline acid), 2-[4-(6-chloro-2-quinoxalinyloxy)-phenoxy]-propionic acid (ethyl ester, tetrahydro-2-furyl-methyl ester) (quizalofop, Quizalofop-ethyl ester, quizalofop ethyl ester, quizalofop-p-furyl ester), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(3-ethylsulfonate Acyl-pyridin-2-yl-sulfonyl)-urea (rimsulfuron-methyl), 2-(1-ethoxyiminobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-2 -cyclohexen-1-one (sethenoxydine), 6-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazine), 2-(2-chloro-4- Methylsulfonyl-benzoyl)-cyclohexane-1,3-dione (sulfotrione), 2-(2,4-dichloro-5-methyl-sulfonylamino-phenyl)-4 -Difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (sulfentrazone), N-phosphonomethyl-glycine-trimethyl Sulfonium (glufosinate), N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-(2-ethylsulfonyl-imidazo[1,2-a]pyridine-3 -yl) sulfonamide (Ethhuanglong), 6-chloro-4-ethylamino-2-tert-butylamino-1,3,5-triazine (tertbutylazine), 2-tert-butylamino-4 -Ethylamino-6-methylthio-1,3,5-triazine (Terbuzine), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(3-methoxy Base-2-thienyl-methyl)-acetamide (dimethenamid), 2-difluoromethyl-5-(4,5-dihydro-thiazol-2-yl)-4-(2-methyl -Propyl)-6-trifluoromethyl-pyridine-3-carboxylic acid methyl ester (thiazolinic acid), 6-(6,7-dihydro-6,6-dimethyl-3H,5H-pyrrolo [2,1-c]-1,2,4-thiadiazole-3-ylideneamino)-7-fluoro-4-(2-propynyl)-2H-1,4-benzoxazine- 3(4H)-ketone (Thidiazimin), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxy-carbonyl- Thiophen-3-yl-sulfonyl)-urea (thifensulfuron), 2-(ethoxyimino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)- 2-Cyclohexen-1-one (trimethylbenzotrione), S-(2,3,3-trichloro-2-propenyl) diisopropylthiocarbamate (metrocam), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-[2-(2-chloro-ethoxy)-phenylsulfonyl]-urea ( Trisulfuron-methyl), N-methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl- Phenylsulfonyl)-urea (trisulfuron), (3,5,6-trichloro)-pyridin-2-yl-oxy-acetic acid (triclopyroxyacetic acid), 2-(3,5-di Chloro-phenyl)-2-(2,2,2-trichloro-ethyl)-oxirane (imazazan), N-[[(4,6-dimethoxy-2-pyrimidinyl )-amino]-carbonyl]-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide sodium salt (Trifloxysulfuron), 1-amino-2,6-dinitro-N,N -Dipropyl-4-trifluoromethyl-benzene (trifluralin), N-[4-dimethylamino-6-(2,2,2-trifluoro-ethoxy)-1,3, 5-triazin-2-yl]-N'-(2-methoxycarbonyl-phenylsulfonyl)-urea (flusulfuron-methyl), N-[[(4,6-dimethoxy-2 -pyrimidinyl)amino]carbonyl]-3-(N-methyl-N-methylsulfonylamino)-2-pyridinesulfonamide (see WO-A-92/10660), 2-[[[[(4 , 6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]-sulfonyl]-4-[[(methylsulfonyl)amino]methyl]-benzoic acid methyl ester (see DE-A- 4335297), 4-[4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2,4-triazol-1-yl]-2- [(Ethylsulfonyl)amino]-5-fluoro-phenylcarbothioamide (see WO-A-95/30661) (“Group 2 Active Compounds”) and/or optionally (d) A compound that can improve crop compatibility selected from the following group of compounds: 4-Dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane (AD-67), 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrole And[1,2-a]-pyrimidin-6(2H)-one (BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzo Oxazine (hexamethazine), 5-chloro-quinoxaline-8-oxyl-acetic acid 1-methyl-hexyl ester (quinoxyacetic acid-isoheptyl ester), α-(cyano-methoxyimino) -Phenylacetonitrile (Phenylethamide), 2,4-dichlorophenoxyacetic acid (2,4-D), 2,2-dichloro-N-(2-oxo-2-(2-propenyl Amino)-ethyl)-N-(2-propenyl)-acetamide (acetamide), 2,2-dichloro-N,N-di-2-propenyl-acetamide (acrylamide ), N-(4-methyl-phenyl)-N'-(1-methyl-1-phenyl-ethyl)-urea (diuron), 4,6-dichloro-2-phenyl -Pyrimidine (Cyclopyridine), 1-(2,4-dichloro-phenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-ethyl carboxylate (Cyclopyridine Ester), 2-chloro-4-trifluoromethyl-thiazole-5-benzoic acid benzyl ester (Clover), 4-chloro-N-(1,3-dioxolan-2-yl-methyl Oxygen)-α-trifluoro-acetophenone oxime (fluoxim), 3-dichloroacetyl-5-(2-furyl)-2,2-dimethyl-oxazolidine azole, MON-13900), 4,5-dihydro-5,5-diphenyl-3-isoxazole ethyl carboxylate (Isoxadifen-ethyl), (4-chloro-2-methyl-phenoxy) -Acetic acid (MCPA), (+-)-2-(4-chloro-2-methylphenoxy)propionic acid (2-methyl-4-chloropropionic acid), 1-(2,4-dichlorophenyl)- 4,5-Dihydro-5-methyl-1H-pyrrole-3,5-dicarboxylic acid diethyl ester (diethyl pyrrole diacid), 2-dichloromethyl-2-methyl-1,3- Dioxolane (oxalane), 1,8-naphthalene dicarboxylic anhydride, α-(1,3-dioxolan-2-yl-methoxyimino)-phenylacetonitrile (oxalane), 2 , 2-dichloro-N-(1,3-dioxolan-2-yl-methyl)-N-(2-propenyl)-acetamide (PPG-1292) and 3-dichloroacetyl- 2,2,5-Trimethyl-oxazolidine (R-29148) ("group 3 active compounds"). 2. The herbicidal compositions according to claim 1, characterized in that they comprise as active compound of group 3 at least one compound which increases crop compatibility, which is selected from the following group of compounds: 5-Chloro-quinoxaline-8-oxyl-acetic acid 1-methyl-hexyl ester (quinoxyacetic acid-isoheptyl ester), 1-(2,4-dichloro-phenyl)-5-trichloromethane Base-1H-1,2,4-triazole-3-ethyl carboxylate (oxaclofen ethyl), 4,5-dihydro-5,5-diphenyl-3-isoxazole carboxylate ethyl ester ( Isoxadifen-ethyl), 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylic acid diethyl ester (pyrrole diacid diethyl esters) and 2,4-dichlorophenoxyacetic acid (2,4-D) and its derivatives. 3. Use of the composition according to claim 1 or 2 for controlling unwanted plants. 4. Method for controlling unwanted plants, characterized in that the compositions according to claim 1 or 2 are applied to the unwanted plants and/or their growing areas. 5. Process for the preparation of herbicidal compositions, characterized in that the compositions according to claim 1 or 2 are mixed with surfactants and/or fillers.