CN1221990A - Fully sealed maintenance-free lead-acid battery for motorcycle - Google Patents
Fully sealed maintenance-free lead-acid battery for motorcycle Download PDFInfo
- Publication number
- CN1221990A CN1221990A CN97119841A CN97119841A CN1221990A CN 1221990 A CN1221990 A CN 1221990A CN 97119841 A CN97119841 A CN 97119841A CN 97119841 A CN97119841 A CN 97119841A CN 1221990 A CN1221990 A CN 1221990A
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- weight
- alloying component
- described storage
- grid
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- 239000002253 acid Substances 0.000 title claims abstract description 11
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 26
- 229910052802 copper Inorganic materials 0.000 claims abstract description 14
- 238000005275 alloying Methods 0.000 claims description 24
- 229910052791 calcium Inorganic materials 0.000 claims description 24
- 229910052718 tin Inorganic materials 0.000 claims description 23
- 229910052684 Cerium Inorganic materials 0.000 claims description 13
- 229910052797 bismuth Inorganic materials 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 239000003792 electrolyte Substances 0.000 claims description 5
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 claims description 4
- UOBYKYZJUGYBDK-UHFFFAOYSA-N 2-naphthoic acid Chemical compound C1=CC=CC2=CC(C(=O)O)=CC=C21 UOBYKYZJUGYBDK-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000011149 active material Substances 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000956 alloy Substances 0.000 abstract description 3
- 229910052745 lead Inorganic materials 0.000 abstract description 3
- 239000007832 Na2SO4 Substances 0.000 abstract description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract description 2
- 235000011152 sodium sulphate Nutrition 0.000 abstract description 2
- 239000013543 active substance Substances 0.000 abstract 3
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 235000011149 sulphuric acid Nutrition 0.000 abstract 2
- 229920002972 Acrylic fiber Polymers 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 1
- 229920005552 sodium lignosulfonate Polymers 0.000 abstract 1
- 239000011575 calcium Substances 0.000 description 15
- 239000006071 cream Substances 0.000 description 4
- 239000007773 negative electrode material Substances 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000882 Ca alloy Inorganic materials 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002142 lead-calcium alloy Substances 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Battery Electrode And Active Subsutance (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Secondary Cells (AREA)
Abstract
A full-enclosed lead-acid accumulator without maintenance for motorcycle is disclosed. The slab lattice alloy of its anode contains Pb, Ca, Sn, Al and Cu. The active substance of its anode is prepared from powdered Pb, H2SO4 solution, PTEE, heterographite, Na2SO4 and acrylic fibre. The slab lattice alloy of its cathode contains Pb, Ca, Sn and Al. The active substance of its cathode is prepared from powdered Pb, H2SO4 solution, BaSO4, sodium lignosulfonate alpha or beta naphthalene acid and Owen W. Its advantages are no early capacity drop, not softening and dropping of active substance, and excellent high-multiplication discharge and low-temp start performance.
Description
The present invention relates to the full-sealed lead-acid accumulator field, particularly a kind of fully closed maintenance-free lead accumulator that is suitable for the motorcycle use.
Lead acid accumulator is T﹠B, and the application of lead acid accumulator has been opened up in the appearance of fully closed maintenance-free battery in recent years, is widely used in stored-program control exchange, electric power system, locomotive and railway signal system, battle wagon and UPS uninterrupted power supply.Shortcomings such as yet the lead accumulator that uses on motorcycle is also relatively backward, and it is low to exist energy, and starting performance is poor, and especially cold-start performance is poor, and leakage and life-span are short.In addition, the time of motorcycle from the buyer's hand that dispatches from the factory can not be estimated.But the user generally needs to use after having bought car at once, and the user can not purchase special charging device again.Have, the charging voltage of general motorcycle design is controlled by the motorcycle rotating speed again.So just caused easy overvoltage when in the rural area and the male sex, using, and in city and women easily under-voltage situation during use, thereby motorcycle battery is had higher requirement.
Purpose of the present invention, be intended to propose a kind of employing novel positive and negative alloy material for slab lattice and plate railings of anode and cathode surface reactive material, and the fully sealed maintenance-free lead-acid battery for motorcycle made of their combination, to overcome weak point of the prior art, satisfy the instructions for use of motorcycle.
Purpose of the present invention can realize by following proposal.
Fully sealed maintenance-free lead-acid battery for motorcycle comprises housing, pole, and plate railings of anode and cathode, surface reactive material and electrolyte the invention is characterized in:
The alloying component of said anode plate grid (weight) is: 0.05-0.12%Ca, 0.2-0.8%Sn, 0.01-0.05%Al, 0.02-0.1%Cu, 0.02-0.2%Bi, 0.02-0.08%Ce, surplus Pb;
Said anodal surface reactive material, adding proportion by the Pb powder is 1.25g/cm
3H
2SO
4Solution, and 0.5-0.8%PTFE, 0.1-0.3% opposite sex graphite, 0.05-0.1%Na
2SO
4, the 0.01-0.03% acrylic staple fibre is made;
The alloying component of said negative electrode grid (weight) is: 0.08-0.12%Ca, 0.1-0.8%Sn, 0.02-0.3%Al, surplus Pb;
Said negative terminal surface active material, adding proportion by the Pb powder is 1.25g/cm
3H
2SO
4Solution, and 0.1-0.5%BaSO
4, the 0.05-0.5% marasperse BS, the 0.05-0.5% alpha-or beta-naphthoic acid, 0.01-0.08% Laplace Irving W makes;
Said electrolyte adopts concentration to be: 1.285-1.30g/cm
3H
2SO
4Solution.
Below in conjunction with embodiments of the invention, fully sealed maintenance-free lead-acid battery for motorcycle is described in detail.
Positive and negative electrode grid of the present invention can have following different composition range or prescription:
The scope of the alloying component of anode plate grid is: 0.05-0.08%Ca, 0.20.4%Sn, 0.01-0.03%Al, 0.02-0.04%Cu, 0.15-0.2%Bi, 0.02-0.04%Ce, surplus Pb.
The scope of the alloying component of anode plate grid is: 0.08-0.10%Ca, 0.4-0.6%Sn, 0.02-0.04%Al, 0.04-0.08%Cu, 0.9-0.15%Bi, 0.04-0.06%Ce, surplus Pb.
The scope of the alloying component of anode plate grid is: 0.10-0.12%Ca, 0.6-0.8%Sn, 0.04-0.05%Al, 0.08-0.10%Cu, 0.02-0.09%Bi, 0.06-0.08%Ce, surplus Pb.
The scope of the alloying component of negative electrode grid is: 0.08-0.10%Ca, 0.5-0.8%Sn, 0.02-0.1%Al, surplus Pb.
The scope of the alloying component of negative electrode grid is: 0.10-0.12%Ca, 0.1-0.5%Sn, 0.01-0.3%Al, surplus Pb.
The alloying component of anode plate grid is: 0.1%Ca, 0.4%Sn, 0.03%Al, 0.08%Cu, 0.1%Bi, 0.06%Ce, surplus Pb.
The alloying component of anode plate grid is: 0.1%Ca, 0.6%Sn, 0.05%Al, 0.08%Cu, 0.04%Bi, 0.07%Ce, surplus Pb.
The alloying component of negative electrode grid is: 0.08%Ca, 0.6%Sn, 0.85%Al, surplus Pb.
The alloying component of negative electrode grid is: 0.1%Ca, 0.1%Sn, 0.12%Al, surplus Pb.
Specific embodiments of the invention please be seen attached list:
| ????1?????2????3????4????5 | ||
| Anode plate grid | ????Ca ????Sn ????Cu ????Bi ????Ce ????Pb | 0.05 0.07 0.09 0.10 0.12 0.2 0.4 0.5 0.6 0.8 0.1 0.08 0.06 0.04 0.02 0.02 0.07 0.10 0.15 0.2 0.08 0.06 0.05 0.04 0.02 surplus surplus surplus surplus surplus |
| Positive active material | PTEF opposite sex graphite polyacrylonitrile fibre Na2SO4 | ????0.5???0.6??0.6??0.7??0.8 ????0.01??0.02?0.02?0.02?0.03 ????0.03??0.02?0.02?0.02?0.01 ????0.05??0.06?0.07?0.09?0.10 |
| It is 1.25g/cm that the Pb powder adds proportion 3H 2SO 4 | ||
| Negative electrode grid | ????Ca ????Sn ????Al ????Pb | 0.08 0.09 0.10 0.11 0.12 0.1 0.3 0.4 0.6 0.8 0.02 0.10 0.15 0.15 0.3 surplus surplus surplus surplus surplus |
| Negative electrode active material | ????BaSO 4Sodium lignosulfonate alpha-or beta-naphthoic acid Laplace Irving W | ????0.1???0.2??0.3??0.3??0.5 ????0.5???0.2??0.3??0.1??0.05 ????0.05??0.3??0.2??0.1??0.05 ????0.01??0.03?0.05?0.07?0.08 |
| It is 1.25g/cm that the Pb powder adds proportion 3H 2SO 4 | ||
| Electrolyte | Employing proportion is 1.285-1.30g/cm 3H 2SO | |
When making 12V8AH start type fully sealed maintenance-free lead-acid battery for motorcycle, select with the technology of the present invention:
The alloying component of its anode plate grid (weight) is: 0.8%Ca, 0.4%Sn, 0.04%Al, 0.02%Cu, 0.08%Bi, 0.05%Ce and surplus Pb.Above component is melted in lead pan, during temperature rise to 520 ℃, cast out anode plate grid.
Its anodal surface reactive material, adding proportion by the Pb powder is 1.25g/cm
3H
2SO
4Solution (convention amount), and 0.56%PTFE, 0.15% different in nature graphite, 0.08Na
2SO
4, 0.02% acrylic staple fibre is made.Mentioned component was closed cream 45 minutes in closing the cream machine, leave standstill 2 hours again after, be applied on the anode plate grid.
The alloying component of its negative electrode grid (weight) is: 0.09%Ca, 0.1-0.8%W, 0.03%Al and surplus Pb.Above component is melted in lead pan, during temperature rise to 520 ℃, cast out negative electrode grid.
Its negative terminal surface active material, adding proportion by the Pb powder is 1.25g/cm
3H
2SO
4Solution (convention amount), and 0.2%BaSO
4, 0.2% marasperse BS, 0.18% alpha-or beta-naphthoic acid, 0.05% Laplace Irving W makes.Mentioned component was closed cream 45 minutes in closing the cream machine, leave standstill 2 hours again after, be applied on the negative electrode grid.
After above positive and negative electrode grid curing drying, be 1.08g/cm at proportion
3Sulfuric acid solution in change into, can assemble after 18-20 hour.Injecting proportion at last is 1.29g/cm
3H
2SO
4Solution.
It is as follows to get the result after tested:
| Japan JISC8707-92 standard | ????1# | ????2# | |
| 0.1CA discharge capacity % (three circulations) | ????≥95 | ????108 | ????112 |
| 1CA discharge time minute | ????≥27 | ????38 | ????41 |
| 3CA discharge time minute | ????≥4 | ????7.8 | ????8 |
| 10CA discharges second appearance time | ?????- | ????280 | ????278 |
| -18 ℃ of 3CA discharge times minute | ????≥2 | ????5.3 | ????5.4 |
| -18 ℃ of 5CA seconds discharge time | ?????- | ????330 | ????328 |
| -18 ℃ of 10CA seconds discharge time | ?????- | ????130 | ????138 |
| Airtight efficient % | ????≥90 | ????99.2 | ????98.9 |
| The performance of the overcharging 0.1CA 96 hours discharge capacities of charging | ????≥95 | ????108 | ????110 |
| 28 days shelf characteric % | ????≥75 | ????78 | ????76 |
| Life-span is inferior | ????≥200 | ????338 | ????420 |
Anode plate grid of the present invention is made of the NEW Pb calcium alloy, overcome lead-calcium alloy commonly used and occurred the shortcoming that the early stage capacity of battery descends easily, and add PTFE in the positive active material and improved the anti-softening performance of decoherencing of active material, thereby is improved the useful life of positive plate.In addition, this positive plate and Pb, Ca, Sn, the negative electrode grid of Al alloy, combinations such as negative electrode active material make combination property of the present invention all above Japanese Industrial Standards, high-rate discharge ability particularly, the ultralow temperature starting performance is more outstanding.
Claims (10)
1 one kinds of fully sealed maintenance-free lead-acid battery for motorcycle comprise housing, pole, and plate railings of anode and cathode, surface reactive material and electrolyte the invention is characterized in:
The alloying component of said anode plate grid (weight) is: 0.05-0.12%Ca, 0.2-0.8%Sn, 0.01-0.05%Al, 0.02-0.1%Cu, 0.02-0.2%Bi, 0.02-0.08%Ce, surplus Pb;
Said anodal surface reactive material, adding proportion by the Pb powder is 1.25g/cm
3H
2SO
4Solution, and 0.5-0.8%PTFE, 0.1-0.3% opposite sex graphite, 0.05-0.1%Na
2SO
4, the 0.01-0.03% acrylic staple fibre is made;
The alloying component of said negative electrode grid (weight) is: 0.08-0.12%Ca, 0.1-0.8%Sn, 0.02-0.3%Al, surplus Pb;
Said negative terminal surface active material, adding proportion by the Pb powder is 1.25g/cm
3H
2SO
4Solution, and 0.1-0.5%BaSO
4, the 0.05-0.5% marasperse BS, the 0.05-0.5% alpha-or beta-naphthoic acid, 0.01-0.08% Laplace Irving W makes;
Said electrolyte adopts concentration to be: 1.285-1.30g/cm
3H
2SO
4Solution.
2 according to the described storage battery of claim 1, it is characterized in that: the alloying component of anode plate grid (weight) is: 0.05-0.08%Ca, 0.2-0.4%Sn, 0.01-0.03%Al, 0.02-0.04%Cu, 0.15-0.2%Bi, 0.02-0.04%Ce, surplus Pb.
3 according to the described storage battery of claim 1, it is characterized in that: the alloying component of anode plate grid (weight) is: 0.08-0.10%Ca, 0.4-0.6%Sn, 0.020.04%Al, 0.04-0.08%Cu, 0.9-0.15%Bi, 0.04-0.06%Ce, surplus Pb.
4 according to the described storage battery of claim 1, it is characterized in that: the alloying component of anode plate grid (weight) is: 0.10-0.12%Ca, 0.6-0.8%Sn, 0.040.05%Al, 0.08-0.10%Cu, 0.02-0.09%Bi, 0.06-0.08%Ce, surplus Pb.
5 according to claim 1 or 2,3,4 described storage batterys, it is characterized in that the alloying component (weight) of said negative electrode grid is: 0.08-0.10%Ca, 0.5-0.8%Sn, 0.02-0.1%Al, surplus Pb.
6 according to claim 1 or 2,3,4 described storage batterys, it is characterized in that the alloying component (weight) of said negative electrode grid is: 0.10-0.12%Ca, 0.1-0.5%Sn, 0.01-0.3%Al, surplus Pb.
7 according to claim 1 or 3 described storage batterys, and it is characterized in that: the alloying component of anode plate grid (weight) is: 0.1%Ca, 0.4%Sn, 0.03%Al, 0.08%Cu, 0.1%Bi, 0.06%Ce, surplus Pb.
8 according to claim 1 or 4 described storage batterys, and it is characterized in that: the alloying component of anode plate grid (weight) is: 0.1%Ca, 0.6%Sn, 0.05%Al, 0.08%Cu, 0.04%Bi, 0.07%Ce, surplus Pb.
9 according to claim 1 or 5 described storage batterys, it is characterized in that the alloying component (weight) of said negative electrode grid is: 0.08%Ca, 0.6%Sn, 0.85%Al, surplus Pb.
10 according to claim 1 or 6 described storage batterys, it is characterized in that the alloying component (weight) of said negative electrode grid is: 0.1%Ca, 0.1%Sn, 0.12%Al, surplus Pb.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97119841A CN1221990A (en) | 1997-12-31 | 1997-12-31 | Fully sealed maintenance-free lead-acid battery for motorcycle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97119841A CN1221990A (en) | 1997-12-31 | 1997-12-31 | Fully sealed maintenance-free lead-acid battery for motorcycle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1221990A true CN1221990A (en) | 1999-07-07 |
Family
ID=5175607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97119841A Pending CN1221990A (en) | 1997-12-31 | 1997-12-31 | Fully sealed maintenance-free lead-acid battery for motorcycle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1221990A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100361342C (en) * | 2005-12-19 | 2008-01-09 | 山西通用集团股份有限公司 | Electrolyte for lead 2-calcium accumulator |
| CN101540415A (en) * | 2008-01-16 | 2009-09-23 | 天津市豪升新能源技术研究所 | High energy sealed lead acid storage battery for 12-TKM-160 light tank |
| CN101807723A (en) * | 2010-03-24 | 2010-08-18 | 衡阳瑞达电源有限公司 | Lead-acid battery and manufacturing method thereof |
| CN102034983A (en) * | 2010-11-12 | 2011-04-27 | 肇庆理士电源技术有限公司 | Alloy material for positive grid of storage battery and preparation method thereof |
| CN102306799A (en) * | 2010-03-24 | 2012-01-04 | 衡阳瑞达电源有限公司 | Deep cycle-resistant lead-acid storage battery plate and manufacturing method |
| CN101557009B (en) * | 2008-01-11 | 2013-07-03 | 天津市豪升新能源技术研究所 | High-energy sealed lead-acid battery for 12-TKMA-150 type tank |
| CN103943866A (en) * | 2014-04-21 | 2014-07-23 | 衡阳瑞达电源有限公司 | Alloy grid for storage battery |
-
1997
- 1997-12-31 CN CN97119841A patent/CN1221990A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100361342C (en) * | 2005-12-19 | 2008-01-09 | 山西通用集团股份有限公司 | Electrolyte for lead 2-calcium accumulator |
| CN101557009B (en) * | 2008-01-11 | 2013-07-03 | 天津市豪升新能源技术研究所 | High-energy sealed lead-acid battery for 12-TKMA-150 type tank |
| CN101540415A (en) * | 2008-01-16 | 2009-09-23 | 天津市豪升新能源技术研究所 | High energy sealed lead acid storage battery for 12-TKM-160 light tank |
| CN101807723A (en) * | 2010-03-24 | 2010-08-18 | 衡阳瑞达电源有限公司 | Lead-acid battery and manufacturing method thereof |
| CN102306799A (en) * | 2010-03-24 | 2012-01-04 | 衡阳瑞达电源有限公司 | Deep cycle-resistant lead-acid storage battery plate and manufacturing method |
| CN102306799B (en) * | 2010-03-24 | 2014-12-10 | 衡阳瑞达电源有限公司 | Deep cycle-resistant lead-acid storage battery plate and manufacturing method |
| CN101807723B (en) * | 2010-03-24 | 2015-04-08 | 衡阳瑞达电源有限公司 | Lead-acid battery and manufacturing method thereof |
| CN102034983A (en) * | 2010-11-12 | 2011-04-27 | 肇庆理士电源技术有限公司 | Alloy material for positive grid of storage battery and preparation method thereof |
| CN102034983B (en) * | 2010-11-12 | 2013-10-16 | 肇庆理士电源技术有限公司 | Preparation method of alloy material for positive grid of storage battery |
| CN103943866A (en) * | 2014-04-21 | 2014-07-23 | 衡阳瑞达电源有限公司 | Alloy grid for storage battery |
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