CN1295119A - Lubricant grease for electric contact - Google Patents
Lubricant grease for electric contact Download PDFInfo
- Publication number
- CN1295119A CN1295119A CN 99122231 CN99122231A CN1295119A CN 1295119 A CN1295119 A CN 1295119A CN 99122231 CN99122231 CN 99122231 CN 99122231 A CN99122231 A CN 99122231A CN 1295119 A CN1295119 A CN 1295119A
- Authority
- CN
- China
- Prior art keywords
- lubricating grease
- heavy
- described lubricating
- agent
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004519 grease Substances 0.000 title claims abstract description 36
- 239000000314 lubricant Substances 0.000 title description 2
- 230000001050 lubricating effect Effects 0.000 claims abstract description 34
- 239000002199 base oil Substances 0.000 claims abstract description 11
- 239000006258 conductive agent Substances 0.000 claims abstract description 10
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 6
- RQLWXPCFUSHLNV-UHFFFAOYSA-N [Cr].[Ca] Chemical compound [Cr].[Ca] RQLWXPCFUSHLNV-UHFFFAOYSA-N 0.000 claims abstract description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000001412 amines Chemical class 0.000 claims abstract description 5
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 5
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 4
- 150000002148 esters Chemical class 0.000 claims abstract description 4
- 239000000344 soap Substances 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 150000004867 thiadiazoles Chemical class 0.000 claims description 8
- 150000003852 triazoles Chemical class 0.000 claims description 8
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 7
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 7
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 7
- 150000002632 lipids Chemical class 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 6
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 claims description 6
- WJUMWVJBOZKPPU-UHFFFAOYSA-N 2,3-bis(6-methylheptyl)-N-phenylaniline Chemical compound C(CCCCC(C)C)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCC(C)C WJUMWVJBOZKPPU-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 3
- IHLDEDLAZNFOJB-UHFFFAOYSA-N 6-octoxy-6-oxohexanoic acid Chemical compound CCCCCCCCOC(=O)CCCCC(O)=O IHLDEDLAZNFOJB-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-BKFZFHPZSA-N lithium-12 Chemical compound [12Li] WHXSMMKQMYFTQS-BKFZFHPZSA-N 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000013556 antirust agent Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010891 electric arc Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 125000003473 lipid group Chemical group 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
本发明提供的润滑脂含有如下组分:以基础油重量为基准,5~20重%的脂肪酸锂皂稠化剂,0.1~2.0重%的胺类抗氧剂,0.05~2重%的唑类防锈剂,0.01~0.08重%的脂肪酸铬钙盐导电剂,余量为酯类基础油。本发明提供的润滑脂可有效地控制润滑脂的电阻率稳定在电触点脂规格所要求的108~1010Ω·cm之间,不仅改善了电触点的接触状况,而且有耐电弧的作用,延长了电触点的使用寿命。该润滑脂适用温度范围-50~120℃,可用于旋转开关和滑移开关。The lubricating grease provided by the invention contains the following components: based on the weight of the base oil, 5-20% by weight of fatty acid lithium soap thickener, 0.1-2.0% by weight of amine antioxidant, and 0.05-2% by weight of azole Anti-rust agent, 0.01-0.08% by weight of fatty acid chromium calcium salt conductive agent, and the balance of ester base oil. The lubricating grease provided by the invention can effectively control the resistivity of the lubricating grease to be stable between 10 8 and 10 10 Ω·cm required by the specifications of the electrical contact grease, which not only improves the contact condition of the electrical contacts, but also has arc resistance. The role of extending the service life of electrical contacts. The lubricating grease is suitable for the temperature range of -50 ~ 120 ℃, and can be used for rotary switches and slide switches.
Description
| Lubricating grease | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Comparative Examples | Test method |
| Cone penetration, 0.1mm | ?278 | ?266 | ?289 | ?268 | ?272 | ?285 | ?GB/T269 |
| Dropping point, ℃, | ?192 | ?188 | ?189 | ?185 | ?190 | ?190 | ?GB/T4929 |
| Stencil oil-dividing, and % (100 ℃, 24h) | ?0.12 | ?0.21 | ?0.15 | ?0.24 | ?0.26 | ?0.17 | ?SH/T0324 |
| Corrosion (T 2Copper, 100 ℃, 24h) | Qualified | Qualified | Qualified | Qualified | Qualified | Qualified | GB/T7326 |
| Chemical stability, and Mpa (99 ℃, 100h) | 0.005 | ????/ | ????/ | ????/ | ????/ | ?0.007 | ?SH/T0325 |
| Resistivity, Ω cm * 10 8 | ????48 | ????56 | ????8.9 | ????77 | ????69 | ????260 | ?GB/T7539 |
Claims (11)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99122231A CN1100130C (en) | 1999-11-04 | 1999-11-04 | A grease for electrical contacts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99122231A CN1100130C (en) | 1999-11-04 | 1999-11-04 | A grease for electrical contacts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1295119A true CN1295119A (en) | 2001-05-16 |
| CN1100130C CN1100130C (en) | 2003-01-29 |
Family
ID=5282378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99122231A Expired - Lifetime CN1100130C (en) | 1999-11-04 | 1999-11-04 | A grease for electrical contacts |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1100130C (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332007C (en) * | 2005-06-29 | 2007-08-15 | 吉林正基科技开发有限责任公司 | Conducting polymer high-temperature lubricating grease and its preparing method |
| CN101240214B (en) * | 2008-03-12 | 2010-07-21 | 益田润石(北京)化工有限公司 | Electric contact point lubricating protective agent |
| CN102517136A (en) * | 2011-12-22 | 2012-06-27 | 深圳市优宝惠新材料科技有限公司 | Electrical contact lubricant composition suitable for high voltage and heavy current |
| CN102604715A (en) * | 2012-02-09 | 2012-07-25 | 中山大学 | Composite lithium based lubricating grease composition and its preparation method |
| CN102618359A (en) * | 2012-02-13 | 2012-08-01 | 中山大学 | Silicon-based lubricating grease composition for electrical contact, and preparation method thereof |
| CN103146466A (en) * | 2013-03-17 | 2013-06-12 | 中山大学惠州研究院 | Composite lithium-based lubricating grease composition and preparation method thereof |
| CN105296116A (en) * | 2015-11-23 | 2016-02-03 | 广西大学 | Environment-friendly castor-oil plant based conductive grease composition |
| CN105482872A (en) * | 2015-07-17 | 2016-04-13 | 路伯润滑油(苏州)有限公司 | Grease for rotary plugs and preparation method thereof |
| CN105602678A (en) * | 2015-11-23 | 2016-05-25 | 广西大学 | Castor oil-based grease composition for electric contact |
| CN105733788A (en) * | 2016-04-26 | 2016-07-06 | 苏州思创源博电子科技有限公司 | Preparation method of environment-friendly electric contact lubricating oil |
| CN108774567A (en) * | 2018-03-30 | 2018-11-09 | 深圳市合诚润滑材料有限公司 | A kind of vehicle switch contact lubricating grease and preparation method thereof |
| CN113491039A (en) * | 2019-06-05 | 2021-10-08 | 埃尔尼国际股份有限公司 | Electrical contact elements for high operating voltages |
| CN114921281A (en) * | 2022-05-02 | 2022-08-19 | 杭州富阳金容润滑油脂有限公司 | Novel lubricating grease and production process thereof |
| CN116286143A (en) * | 2023-03-22 | 2023-06-23 | 中国科学院兰州化学物理研究所 | Lubricating additive, conductive grease and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5242611A (en) * | 1991-01-14 | 1993-09-07 | Griffaw Norman E | Electrical contact protective lubricant |
| JP2795767B2 (en) * | 1991-12-27 | 1998-09-10 | 株式会社東海理化電機製作所 | Grease for sliding contacts |
-
1999
- 1999-11-04 CN CN99122231A patent/CN1100130C/en not_active Expired - Lifetime
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332007C (en) * | 2005-06-29 | 2007-08-15 | 吉林正基科技开发有限责任公司 | Conducting polymer high-temperature lubricating grease and its preparing method |
| CN101240214B (en) * | 2008-03-12 | 2010-07-21 | 益田润石(北京)化工有限公司 | Electric contact point lubricating protective agent |
| CN102517136A (en) * | 2011-12-22 | 2012-06-27 | 深圳市优宝惠新材料科技有限公司 | Electrical contact lubricant composition suitable for high voltage and heavy current |
| CN102517136B (en) * | 2011-12-22 | 2013-08-28 | 深圳市优宝惠新材料科技有限公司 | Electrical contact lubricant composition suitable for high voltage and heavy current |
| CN102604715A (en) * | 2012-02-09 | 2012-07-25 | 中山大学 | Composite lithium based lubricating grease composition and its preparation method |
| CN102618359A (en) * | 2012-02-13 | 2012-08-01 | 中山大学 | Silicon-based lubricating grease composition for electrical contact, and preparation method thereof |
| CN103146466A (en) * | 2013-03-17 | 2013-06-12 | 中山大学惠州研究院 | Composite lithium-based lubricating grease composition and preparation method thereof |
| CN105482872A (en) * | 2015-07-17 | 2016-04-13 | 路伯润滑油(苏州)有限公司 | Grease for rotary plugs and preparation method thereof |
| CN105482872B (en) * | 2015-07-17 | 2018-12-18 | 路伯润滑油(苏州)有限公司 | Rotary connector lubricating grease and preparation method thereof |
| CN105296116A (en) * | 2015-11-23 | 2016-02-03 | 广西大学 | Environment-friendly castor-oil plant based conductive grease composition |
| CN105602678A (en) * | 2015-11-23 | 2016-05-25 | 广西大学 | Castor oil-based grease composition for electric contact |
| CN105733788A (en) * | 2016-04-26 | 2016-07-06 | 苏州思创源博电子科技有限公司 | Preparation method of environment-friendly electric contact lubricating oil |
| CN108774567A (en) * | 2018-03-30 | 2018-11-09 | 深圳市合诚润滑材料有限公司 | A kind of vehicle switch contact lubricating grease and preparation method thereof |
| CN113491039A (en) * | 2019-06-05 | 2021-10-08 | 埃尔尼国际股份有限公司 | Electrical contact elements for high operating voltages |
| CN114921281A (en) * | 2022-05-02 | 2022-08-19 | 杭州富阳金容润滑油脂有限公司 | Novel lubricating grease and production process thereof |
| CN116286143A (en) * | 2023-03-22 | 2023-06-23 | 中国科学院兰州化学物理研究所 | Lubricating additive, conductive grease and preparation method thereof |
| CN116286143B (en) * | 2023-03-22 | 2025-06-06 | 中国科学院兰州化学物理研究所 | Lubricating additive, conductive grease and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1100130C (en) | 2003-01-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Applicant after: China Petrochemical Group Corp. Applicant after: Sinopec Research Institute of Petroleum Processing Applicant before: China Petrochemical Group Corp. Applicant before: Chinese petrochemical industry Research Institute of Petro-Chemical Engineering of group company |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: CHINA PETROCHEMICAL CORPORATION; CHINA PETROLEUM + CHEMICAL CORPORATION, PETROLEUM CHEMICAL ENGINEERING INSTITUTE TO: CHINA PETROCHEMICAL CORPORATION; CHINA PETROCHEMICAL GROUP PETROCHEMICAL SINCE INSTITUTE |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20030129 |
|
| CX01 | Expiry of patent term |