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CN1295119A - Lubricant grease for electric contact - Google Patents

Lubricant grease for electric contact Download PDF

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Publication number
CN1295119A
CN1295119A CN 99122231 CN99122231A CN1295119A CN 1295119 A CN1295119 A CN 1295119A CN 99122231 CN99122231 CN 99122231 CN 99122231 A CN99122231 A CN 99122231A CN 1295119 A CN1295119 A CN 1295119A
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CN
China
Prior art keywords
lubricating grease
heavy
described lubricating
agent
weight
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Granted
Application number
CN 99122231
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Chinese (zh)
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CN1100130C (en
Inventor
刘中其
赵莉
王志成
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Sinopec Research Institute of Petroleum Processing
China Petrochemical Corp
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Sinopec Research Institute of Petroleum Processing
China Petrochemical Corp
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Application filed by Sinopec Research Institute of Petroleum Processing , China Petrochemical Corp filed Critical Sinopec Research Institute of Petroleum Processing
Priority to CN99122231A priority Critical patent/CN1100130C/en
Publication of CN1295119A publication Critical patent/CN1295119A/en
Application granted granted Critical
Publication of CN1100130C publication Critical patent/CN1100130C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

本发明提供的润滑脂含有如下组分:以基础油重量为基准,5~20重%的脂肪酸锂皂稠化剂,0.1~2.0重%的胺类抗氧剂,0.05~2重%的唑类防锈剂,0.01~0.08重%的脂肪酸铬钙盐导电剂,余量为酯类基础油。本发明提供的润滑脂可有效地控制润滑脂的电阻率稳定在电触点脂规格所要求的108~1010Ω·cm之间,不仅改善了电触点的接触状况,而且有耐电弧的作用,延长了电触点的使用寿命。该润滑脂适用温度范围-50~120℃,可用于旋转开关和滑移开关。The lubricating grease provided by the invention contains the following components: based on the weight of the base oil, 5-20% by weight of fatty acid lithium soap thickener, 0.1-2.0% by weight of amine antioxidant, and 0.05-2% by weight of azole Anti-rust agent, 0.01-0.08% by weight of fatty acid chromium calcium salt conductive agent, and the balance of ester base oil. The lubricating grease provided by the invention can effectively control the resistivity of the lubricating grease to be stable between 10 8 and 10 10 Ω·cm required by the specifications of the electrical contact grease, which not only improves the contact condition of the electrical contacts, but also has arc resistance. The role of extending the service life of electrical contacts. The lubricating grease is suitable for the temperature range of -50 ~ 120 ℃, and can be used for rotary switches and slide switches.

Description

A kind of lubricating grease that is used for electrical contact
The invention belongs to lubricant, specifically a kind of lubricating grease that is used for the electrical contact maintenance and uses.
Electrical contact often prolongs in time and produces corrosion and oxidation in secular use, influences the quality and the work-ing life of electrical contact.Electrical contact lubricating grease has the antioxygen preservative activity, can ensure that the electrical contact contact is good.
The patent documentation of relevant electrical contact has US5242611, US5282986 etc.Consisting of of the disclosed lubricating grease of US5242611 wherein: 52.1~52.4% refinery coke, 47.2~47.64% lithium saponify, 0.004~0.7% transmission fluid.
Consisting of of the disclosed lubricating grease of US5282986, (1) synthetic hydrocarbon oil; (2) 0.2~3.0% the inorganics that is selected from zinc oxide, ferric oxide etc.; (3) 3~20% 12-hydroxy lithium stearate; (4) 0.1~5.0% phenol types or amine type oxidation inhibitor.
Above-mentioned document is not controlled the resistivity of lubricating grease, and the electrical property of electrical contact fat is extremely important.
The object of the present invention is to provide a kind of have suitable resistivity and favorable protection ability, can satisfy the lubricating grease of electrical contact service requirements.
Lubricating grease provided by the invention has following composition, with base oil weight is benchmark, the lipid acid lithium soap viscosifying agent of 5~20 heavy %, 0.1 the amine antioxidants of~2.0 heavy %, 0.05 the azole rust-preventive agent of~2.0 heavy %, 0.01 the lipid acid chromium calcium salt conductive agent of~0.1 heavy %, surplus is an ester class base oil.
Described base oil is the ester class oil with good low-temperature performance, can be dioctyl sebacate, Octyl adipate, dioctyl phthalate (DOP), or above-mentioned any two kinds mixture.Preferred dioctyl sebacate.
Described viscosifying agent is the lipid acid lithium soap, as the 12-hydroxy lithium stearate, and lithium stearate, the mixture of lithium stearate and 12-hydroxy lithium stearate, preferred 12-hydroxy lithium stearate.The viscosifying agent consumption is 5~20 heavy % of base oil, preferred 7~15 heavy %.
Described oxidation inhibitor is amine antioxidants, and is right as pentanoic, to di-iso-octyldiphenylamine, and αNai An etc., preferably right, to di-iso-octyldiphenylamine.The oxidation inhibitor consumption is 0.1~2.0 heavy %, preferred 0.3~0.6 heavy %.
Described rust-preventive agent is selected from one of 124 Triazole, thiadiazoles and their derivative, or the mixture of the two, the mixture of the arbitrary proportion of preferred 124 Triazole and thiadiazoles, more preferably the two mixture of 2~10: 1.The content of rust-preventive agent can be 0.05~2 heavy %, preferred 0.1~1 heavy %.
Described conductive agent is a lipid acid chromium calcium salt, and this conductive agent has good molecular polarity, is a kind of static inhibitor commonly used in the oil fuel.The present invention finds that it can also reduce lubricating grease resistivity, makes electrical contact not by corrosion and oxidation, ensures that the electrical contact contact is good, and has certain conductive effect, can tolerate electric arc to a certain degree.Described conductive agent consumption can be 0.01~0.1 heavy %, preferred 0.02~0.06 heavy %.
Can also optionally add tackifier in the lubricating grease provided by the invention, described tackifier are ethylene-propylene copolymer, and molecular weight is 30000~100000, and weaker concn is generally 5~12 heavy %, in the multipolymer consumption is 0.05~0.3 heavy %, preferred 0.08~0.2 heavy %.
Lubricating grease provided by the invention is to make the preparation of fat method routinely.Promptly earlier viscosifying agent and part base oil are mixed, be warmed up to 210 ℃, stop heating, add the surplus base oil.Add various additives in the temperature-fall period, stirring gets final product.
Lubricating grease provided by the invention, owing to added a kind of conductive agent, the resistivity of sight-feed lubricator fat is stabilized in electrical contact fat specification desired 10 effectively 8~10 10Between the Ω cm, not only improve the contact condition of electrical contact, and the effect of anti-electric arc has been arranged, prolonged the work-ing life of electrical contact.This lubricating grease Applicable temperature scope-50~120 ℃ can be used for turn switch and slippage switch.
The invention will be further described below by example.
Example 1
227g dioctyl sebacate and 36g12-hydroxy lithium stearate are mixed in cup, heating while stirring, temperature reaches 210 ℃, stop heating, add the 113g dioctyl sebacate, be cooled to 120 ℃, it is right to add, and to di-iso-octyldiphenylamine 1.2g, concentration is the ethylene-propylene copolymer 6g of 8.5 heavy %, 124 Triazole 2g, thiadiazoles derivative 0.4g, lipid acid chromium calcium salt (T1501, Yanshan Mountain refinery product) 0.1g, stir well the back and grind three times, obtain the lubricating grease sample.Physicochemical property sees Table 1.
Example 2
227g dioctyl sebacate and 48g lithium stearate are mixed in cup, heating while stirring, temperature reaches 210 ℃, stops heating, add the 113g dioctyl sebacate, be cooled to 120 ℃, add pentanoic 2g, 124 Triazole 2g, thiadiazoles derivative 0.4g, lipid acid chromium calcium salt 0.1g stirs well the back and grinds three times, obtains the lubricating grease sample.Physicochemical property sees Table 1.
Example 3
227g dioctyl phthalate (DOP) and 22.4g12-hydroxy lithium stearate and 5.6g lithium stearate are mixed in cup, heating while stirring, temperature reaches 210 ℃, stop heating, add 113g and face dioctyl phthalate, be cooled to 120 ℃, add alpha-naphthylamine 2g, concentration is the ethylene-propylene copolymer 4g of 8.5 heavy %, 124 Triazole 1.5g, thiadiazoles derivative 0.2g, conductive agent 0.16g, stir well the back and grind three times, obtain the lubricating grease sample.Physicochemical property sees Table 1.
Example 4
Operation does not just add thiadiazoles derivative with example 2, and physicochemical property sees Table 1.
Example 5
Operation does not just add 124 Triazole with example 2, and physicochemical property sees Table 1.
Comparative Examples
Operation does not just add conductive agent with example 1, and physicochemical property sees Table 1.Table 1
Lubricating grease Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Examples Test method
Cone penetration, 0.1mm ?278 ?266 ?289 ?268 ?272 ?285 ?GB/T269
Dropping point, ℃, ?192 ?188 ?189 ?185 ?190 ?190 ?GB/T4929
Stencil oil-dividing, and % (100 ℃, 24h) ?0.12 ?0.21 ?0.15 ?0.24 ?0.26 ?0.17 ?SH/T0324
Corrosion (T 2Copper, 100 ℃, 24h) Qualified Qualified Qualified Qualified Qualified Qualified GB/T7326
Chemical stability, and Mpa (99 ℃, 100h) 0.005 ????/ ????/ ????/ ????/ ?0.007 ?SH/T0325
Resistivity, Ω cm * 10 8 ????48 ????56 ????8.9 ????77 ????69 ????260 ?GB/T7539
As can be seen from Table 1, lubricating grease provided by the invention has suitable resistivity and favorable protection.

Claims (11)

1. lubricating grease that is used for electrical contact, contain following component: with base oil weight is benchmark, the lipid acid lithium soap viscosifying agent of 5~20 heavy %, 0.1 the amine antioxidants of~2.0 heavy %, 0.1 the azole rust-preventive agent of~1.0 heavy %, 0.01 the lipid acid chromium calcium salt conductive agent of~0.1 heavy %, surplus is an ester class base oil.
2. according to the described lubricating grease of claim 1, wherein base oil is selected from dioctyl sebacate, Octyl adipate, dioctyl phthalate (DOP), or above-mentioned any two kinds mixture.
3. according to the described lubricating grease of claim 1, wherein viscosifying agent is selected from the 12-hydroxy lithium stearate, the mixture of lithium stearate or lithium stearate and 12-hydroxy lithium stearate.
4. according to claim 1 or 3 described lubricating grease, wherein the viscosifying agent consumption is 7~15 heavy %.
5. according to the described lubricating grease of claim 1, wherein oxidation inhibitor is selected from pentanoic, and is right, to di-iso-octyldiphenylamine or αNai An.
6. according to claim 1 or 5 described lubricating grease, wherein the oxidation inhibitor consumption is 0.3~0.6 heavy %.
7. according to the described lubricating grease of claim 1, wherein rust-preventive agent is selected from one of 124 Triazole, thiadiazoles and their derivative, or the mixture of the two.
8. according to claim 1 or 7 described lubricating grease, wherein rust-preventive agent is the mixture of 124 Triazole and thiadiazoles 2~10: 1.
9. according to claim 1 or 7 described lubricating grease, wherein the content of rust-preventive agent is 0.1~1.0 heavy %.
10. according to the described lubricating grease of claim 1, wherein the consumption of conductive agent is 0.02~0.06 heavy %.
11. according to the described lubricating grease of claim 1, also contain tackifier in the lubricating grease provided by the invention, described tackifier are the ethylene-propylene copolymer of molecular weight 30000~100000, consumption is 0.05~0.3 heavy %.
CN99122231A 1999-11-04 1999-11-04 A grease for electrical contacts Expired - Lifetime CN1100130C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN99122231A CN1100130C (en) 1999-11-04 1999-11-04 A grease for electrical contacts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN99122231A CN1100130C (en) 1999-11-04 1999-11-04 A grease for electrical contacts

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CN1295119A true CN1295119A (en) 2001-05-16
CN1100130C CN1100130C (en) 2003-01-29

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1332007C (en) * 2005-06-29 2007-08-15 吉林正基科技开发有限责任公司 Conducting polymer high-temperature lubricating grease and its preparing method
CN101240214B (en) * 2008-03-12 2010-07-21 益田润石(北京)化工有限公司 Electric contact point lubricating protective agent
CN102517136A (en) * 2011-12-22 2012-06-27 深圳市优宝惠新材料科技有限公司 Electrical contact lubricant composition suitable for high voltage and heavy current
CN102604715A (en) * 2012-02-09 2012-07-25 中山大学 Composite lithium based lubricating grease composition and its preparation method
CN102618359A (en) * 2012-02-13 2012-08-01 中山大学 Silicon-based lubricating grease composition for electrical contact, and preparation method thereof
CN103146466A (en) * 2013-03-17 2013-06-12 中山大学惠州研究院 Composite lithium-based lubricating grease composition and preparation method thereof
CN105296116A (en) * 2015-11-23 2016-02-03 广西大学 Environment-friendly castor-oil plant based conductive grease composition
CN105482872A (en) * 2015-07-17 2016-04-13 路伯润滑油(苏州)有限公司 Grease for rotary plugs and preparation method thereof
CN105602678A (en) * 2015-11-23 2016-05-25 广西大学 Castor oil-based grease composition for electric contact
CN105733788A (en) * 2016-04-26 2016-07-06 苏州思创源博电子科技有限公司 Preparation method of environment-friendly electric contact lubricating oil
CN108774567A (en) * 2018-03-30 2018-11-09 深圳市合诚润滑材料有限公司 A kind of vehicle switch contact lubricating grease and preparation method thereof
CN113491039A (en) * 2019-06-05 2021-10-08 埃尔尼国际股份有限公司 Electrical contact elements for high operating voltages
CN114921281A (en) * 2022-05-02 2022-08-19 杭州富阳金容润滑油脂有限公司 Novel lubricating grease and production process thereof
CN116286143A (en) * 2023-03-22 2023-06-23 中国科学院兰州化学物理研究所 Lubricating additive, conductive grease and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5242611A (en) * 1991-01-14 1993-09-07 Griffaw Norman E Electrical contact protective lubricant
JP2795767B2 (en) * 1991-12-27 1998-09-10 株式会社東海理化電機製作所 Grease for sliding contacts

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1332007C (en) * 2005-06-29 2007-08-15 吉林正基科技开发有限责任公司 Conducting polymer high-temperature lubricating grease and its preparing method
CN101240214B (en) * 2008-03-12 2010-07-21 益田润石(北京)化工有限公司 Electric contact point lubricating protective agent
CN102517136A (en) * 2011-12-22 2012-06-27 深圳市优宝惠新材料科技有限公司 Electrical contact lubricant composition suitable for high voltage and heavy current
CN102517136B (en) * 2011-12-22 2013-08-28 深圳市优宝惠新材料科技有限公司 Electrical contact lubricant composition suitable for high voltage and heavy current
CN102604715A (en) * 2012-02-09 2012-07-25 中山大学 Composite lithium based lubricating grease composition and its preparation method
CN102618359A (en) * 2012-02-13 2012-08-01 中山大学 Silicon-based lubricating grease composition for electrical contact, and preparation method thereof
CN103146466A (en) * 2013-03-17 2013-06-12 中山大学惠州研究院 Composite lithium-based lubricating grease composition and preparation method thereof
CN105482872A (en) * 2015-07-17 2016-04-13 路伯润滑油(苏州)有限公司 Grease for rotary plugs and preparation method thereof
CN105482872B (en) * 2015-07-17 2018-12-18 路伯润滑油(苏州)有限公司 Rotary connector lubricating grease and preparation method thereof
CN105296116A (en) * 2015-11-23 2016-02-03 广西大学 Environment-friendly castor-oil plant based conductive grease composition
CN105602678A (en) * 2015-11-23 2016-05-25 广西大学 Castor oil-based grease composition for electric contact
CN105733788A (en) * 2016-04-26 2016-07-06 苏州思创源博电子科技有限公司 Preparation method of environment-friendly electric contact lubricating oil
CN108774567A (en) * 2018-03-30 2018-11-09 深圳市合诚润滑材料有限公司 A kind of vehicle switch contact lubricating grease and preparation method thereof
CN113491039A (en) * 2019-06-05 2021-10-08 埃尔尼国际股份有限公司 Electrical contact elements for high operating voltages
CN114921281A (en) * 2022-05-02 2022-08-19 杭州富阳金容润滑油脂有限公司 Novel lubricating grease and production process thereof
CN116286143A (en) * 2023-03-22 2023-06-23 中国科学院兰州化学物理研究所 Lubricating additive, conductive grease and preparation method thereof
CN116286143B (en) * 2023-03-22 2025-06-06 中国科学院兰州化学物理研究所 Lubricating additive, conductive grease and preparation method thereof

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Applicant after: China Petrochemical Group Corp.

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