CN1288970A - Molten iron treating agent and its application - Google Patents
Molten iron treating agent and its application Download PDFInfo
- Publication number
- CN1288970A CN1288970A CN 00124768 CN00124768A CN1288970A CN 1288970 A CN1288970 A CN 1288970A CN 00124768 CN00124768 CN 00124768 CN 00124768 A CN00124768 A CN 00124768A CN 1288970 A CN1288970 A CN 1288970A
- Authority
- CN
- China
- Prior art keywords
- powder
- iron
- agent
- molten iron
- granularity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 title claims description 47
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 18
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011777 magnesium Substances 0.000 claims abstract description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 9
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 9
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 8
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 235000003599 food sweetener Nutrition 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 239000003765 sweetening agent Substances 0.000 claims description 12
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims description 10
- 238000006477 desulfuration reaction Methods 0.000 claims description 7
- 230000023556 desulfurization Effects 0.000 claims description 7
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 229910052702 rhenium Inorganic materials 0.000 claims description 4
- 230000003009 desulfurizing effect Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 abstract description 7
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 abstract description 3
- 229910000640 Fe alloy Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 13
- 229910001018 Cast iron Inorganic materials 0.000 description 10
- 229910001141 Ductile iron Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- MHKWSJBPFXBFMX-UHFFFAOYSA-N iron magnesium Chemical compound [Mg].[Fe] MHKWSJBPFXBFMX-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 230000002650 habitual effect Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- NPURPEXKKDAKIH-UHFFFAOYSA-N iodoimino(oxo)methane Chemical compound IN=C=O NPURPEXKKDAKIH-UHFFFAOYSA-N 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000005058 metal casting Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Landscapes
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Abstract
The present invention provides a melted iron spheroidizing medium, containing (wt%) 5-12% of Mg, 5-60% of Si, 0.5-8% of Re, Na2CO3 less than 40% and the rest is Fe. Said invented spheroidizing mediam is made up by uniformly mixing magnesium powder, silicon-iron powder, rare earth silicon iron alloy powder, sodium carbonate powder and iron powder. Besides, said invention also provides a melted iron desulfurizer containing (wt%) 4-15% of Mg, 30-45% of Na2CO3 and the rest is Fe. Said desulfurizer is made up by uniformly mixing the magnesium powder, sodium carbonate powder and iron powder or iron dust according to the above-mentioned mixing ratio.
Description
The invention relates to the casting of metal, more particularly, the present invention is the hot metal treating agent that uses in the cast iron manufacturing processed, particularly nodulizing agent and sweetening agent.
The production history of cast iron existing 2500 at least.Early stage Cast Iron Production has played pushing effect to society and expanding economy, and be exactly an important sign iron period of Chinese society.In the Industrial Revolution for the first time of Europe, cast iron has also played due effect as structural timber.
At the twentieth century of technology develop rapidly, have a lot of new metals and non-metallic material to come out, but cast iron is still one of important engineering material, cast iron still occupies an important position in economy.This is because the manufacturing technology of cast iron has obtained important breakthrough.
On April 12 nineteen forty-three, the K.D.Millis of U.S. International nickel Co. Ltd. Inco. Ltd. (INCO) at first succeeds in developing modern spheroidal graphite cast iron, and begins to be used for industrial production in 1948.Because use nodulizing agent to handle cast iron or attached with alloying and corresponding thermal treatment, the intensity of spheroidal graphite cast iron reaches 40-160Kg/mm
2, further enlarged the range of application of cast iron.Since magnesium iron came out, the founder author of a lot of countries had carried out extensive studies to nodulizing agent and spheriodization process thereof, and existing at present a lot of effective nodulizing agents and nodulizing process are used for producing.
At present, spheroidal graphite cast iron production adopts more widely that method is to pour the Bao Neifa spheriodization process thereof, and this is because this method is simple, the less investment, easy to operate of equipment comparatively speaking.But its technology stability is poor, and especially along with the raising of molten iron temperature, the reaction boiling is more violent, and the consumption of nodulizing agent also increases thereupon, and the specific absorption of magnesium reduces.For example, under 1530-1570 ℃ the molten iron temperature condition of coming out of the stove, the molten iron chemical ingredients is identical, use the rare earth magnesium ferrosilicon alloy nodulizing agent of fusion process to carry out spheroidizing, the add-on of nodulizing agent is increased to 2.1-2.3% by the 1.1-1.2% below 1480 ℃, along with the increase of nodulizing agent add-on, the reduction of molten iron temperature also increases thereupon.In addition, pour in the Bao Neifa spheroidizing at the habitual magnesium alloy of founding, employed spheroidizing agent melts in advance by certain chemical ingredients requirement, and in the process of founding, the scaling loss of magnesium and rare earth element is inevitable.In order to guarantee its chemical ingredients, especially magnesium needs to add the percentage amounts about 1.2% more.However, the content of magnesia in the finished product still can't eliminate.The production process of founding electric furnace has strengthened the production cost of nodulizing agent.
The purpose of this invention is to provide a kind of hot metal treating agent that is used to pour Bao Neifa spheroidizing production spheroidal graphite cast iron, this hot metal treating agent production technique is simple, and steady quality is reliable, and is easy and simple to handle, and mechanical property and castability are good, and production cost is lower.
A first aspect of the present invention is a kind of molten iron nodulizing agent that is used to produce cast iron, it contain (weight %): 5-12%Mg, 5-60%Si, 0.5-8%Re,＜40%Na
2CO
3, surplus is Fe.
This nodulizing agent is to make by magnesium powder, ferrosilicon powder, rare earth ferrosilicon alloy powder, yellow soda ash powder and iron powder are mixed by said ratio.The granularity of magnesium powder is below 100 orders, and the granularity of ferrosilicon powder is＜1mm that the granularity of rare earth ferrosilicon alloy powder is＜1mm that the granularity of ferrosilicon powder is＜3mm.
Above-mentioned Re preferably is selected from a kind of or two kinds of rare earth elements in lanthanum (La) and the cerium (Ce).
The nodulizing agent of the invention described above can adopt the method that pours in the bag that molten iron is carried out spheroidizing, and the base iron temperature is controlled at 1380-1580 ℃ during processing, and the add-on of molten iron nodulizing agent is the 0.6-1.2% of processed molten iron gross weight.
A second aspect of the present invention is a kind of iron melt desulfurizing agent, it is characterized in that, contains (weight %): 4-15%Mg, 30-45%Na
2CO
3, surplus is Fe, this sweetening agent is magnesium powder, yellow soda ash powder and iron powder or iron filings to be mixed by said ratio make.
Sweetening agent of the present invention is magnesium powder, yellow soda ash powder and iron powder or iron filings to be mixed by said ratio make.The granularity of magnesium powder is below 100 orders, preferably below 200 orders.
When using sweetening agent of the present invention that molten iron is carried out the desulfurization processing, can adopt the method that pours in the bag to carry out, the add-on of hot metal treating agent is the 0.5-1.0% of processed molten iron gross weight, and processed base iron temperature is controlled at 1300-1550 ℃.
Below, be described more specifically the present invention by embodiment.
Embodiment 1
Adopt the mechanically mixing method to prepare the molten iron nodulizing agent, nodulizing agent contains (weight %): 8%Mg, 7%Re, 40%Si, and surplus is Fe.
Use above-mentioned nodulizing agent on disappearance mould production line, to carry out the molten iron Processing Test.Spheroidizing is to carry out under 1547 ℃ at molten iron temperature, actual treatment iron water amount 642Kg, and the hot metal treating agent add-on is 1.14% of a base iron weight, 35 seconds spheroidizing reacion time.Listed the result of the molten iron spectral analysis after spheroidizing in the table 1.Table 1 element term C Si Mn P S Ce Mg weight % 3.52 2.69 0.123 0.069 0.012 0.020 0.049
To diameter phi 6mm measure physical strength with the type test block, result, tensile strength are 481.0Mpa, unit elongation is 20.3%.Compare with the nodulizing agent of prior art, after handling with the nodulizing agent of this example, tensile strength and unit elongation have raising in various degree, and simultaneously, the consumption of nodulizing agent reduces 40-50%.
Embodiment 2
Adopt the mechanically mixing method to prepare the molten iron nodulizing agent, nodulizing agent contains (weight %): 6%Mg, 2%Re, 35%Si, 8%Na
2CO
3, surplus is Fe.
Use above-mentioned nodulizing agent to carry out the molten iron spheroidizing, actual treatment iron water amount 570Kg, molten iron nodulizing agent add-on is 1.12% of a base iron weight, 50 seconds spheroidizing reacion time.In addition operation is similarly to Example 1 carried out spheroidizing to molten iron.Listed spectroscopic analysis result in the table 2 through the molten iron after the spheroidizing
Table 2 ultimate analysis C Si Mn P S Ce Mg weight % 3.64 2.54 0.106 0.065 0.017 0.006 0.039
To diameter phi 6mm measure physical strength with the type test block, result, tensile strength are 523.10Mpa, unit elongation is 15.6%.
Embodiment 3
Adopt the mechanically mixing method to prepare iron melt desulfurizing agent.This sweetening agent contains (weight %): 6.5%Mg, 43.5%Na
2CO
3, surplus is Fe.
Use above-mentioned sweetening agent that the molten iron of cupola melting is carried out the desulfurization processing.With 1000Kg dam-type hot metal ladle, the base iron sulphur content is 0.043%, and it is 1000Kg that the molten iron gross weight is handled in desulfurization, the molten iron temperature of coming out of the stove is 1520 ℃, the sweetening agent add-on is 0.7% of a processed molten iron gross weight, and the desulphurization reaction time is 2 minutes and 15 seconds, and the desulphurization reaction process is consistent gently.Sulfur content of hot metal is 0.013% after desulfurization is handled, and desulfurization degree reaches 70%.
The test-results of the foregoing description shows that hot metal treating agent of the present invention has solved problems such as magnesium absorption rate is low when pouring the Bao Neifa spheroidizing, reaction is violent, molten iron splashes.The molten iron cooling is little, is generally 50-60 ℃, can reduce nodulizing agent add-on about 40%, for production low-sulfur, low Re high-quality magnesium iron spare have been created condition.Hot metal treating agent manufacturing process of the present invention is simple, just can prepare by mechanically mixing, does not need melting.The silicon content of hot metal treating agent of the present invention can be adjusted arbitrarily, has relaxed the requirement to the base iron silicon content, is a kind of ideal hot metal treating agent.
Claims (8)
1. a nodulizing agent is characterized in that, contain (weight %): 5-12%Mg, 5-60%Si, 0.5-8%Re,＜40%Na
2CO
3, surplus is Fe, this nodulizing agent is magnesium powder, ferrosilicon powder, rare earth ferrosilicon alloy powder, yellow soda ash powder and iron powder to be mixed by said ratio make.
2. the described nodulizing agent of claim 1 is characterized in that, the granularity of magnesium powder is below 100 orders, and the granularity of ferrosilicon powder is＜1mm that the granularity of rare earth ferrosilicon alloy powder is＜1mm that the granularity of iron powder is＜3mm.
3. the described nodulizing agent of claim 1 is characterized in that, described Re is La and/or Ce.
4. the method for molten iron being carried out spheroidizing with each described hot metal treating agent among the claim 1-3, it is characterized in that, pour method in the employing bag and molten iron is carried out spheroidizing with this treatment agent, the base iron temperature is controlled at 1380-1580 ℃, and the add-on of molten iron nodulizing agent is the 0.6-1.2% of processed molten iron gross weight.
5. iron melt desulfurizing agent is characterized in that, this sweetening agent contains (weight %): 4-15%Mg, 30-45%Na
2CO
3, surplus is Fe, this sweetening agent is magnesium powder, yellow soda ash powder and iron powder or iron filings to be mixed by said ratio make.
6. the described sweetening agent of claim 5 is characterized in that, the granularity of magnesium powder is below 100 orders.
7. the described sweetening agent of claim 6 is characterized in that, the granularity of magnesium powder is below 200 orders.
8. use the described sweetening agent of claim 5 that molten iron is carried out the method that desulfurization is handled, it is characterized in that, adopt the method that pours in the bag to carry out desulfurization and handle, the add-on of hot metal treating agent is the 0.5-1.0% of processed molten iron gross weight, and processed base iron temperature is controlled at 1300-1550 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00124768 CN1112456C (en) | 2000-09-14 | 2000-09-14 | Molten iron treating agent and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00124768 CN1112456C (en) | 2000-09-14 | 2000-09-14 | Molten iron treating agent and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1288970A true CN1288970A (en) | 2001-03-28 |
| CN1112456C CN1112456C (en) | 2003-06-25 |
Family
ID=4590646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00124768 Expired - Fee Related CN1112456C (en) | 2000-09-14 | 2000-09-14 | Molten iron treating agent and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1112456C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100513586C (en) * | 2007-07-04 | 2009-07-15 | 芜湖新兴铸管有限责任公司 | Production process and device of nodular cast iron pipe |
| CN102492888A (en) * | 2011-12-23 | 2012-06-13 | 天津市万路科技有限公司 | Vermiculizer and application thereof |
| CN103239139A (en) * | 2013-05-06 | 2013-08-14 | 三穗宏立厨具有限公司 | Rare earth alloy iron pan and production method thereof |
| CN104099511A (en) * | 2014-07-30 | 2014-10-15 | 宁波通达精密铸造有限公司 | Preparation method of spheroidal graphite cast iron |
| CN114854926A (en) * | 2022-03-24 | 2022-08-05 | 江苏亚峰合金材料有限公司 | Environment-friendly nodulizer for low-silicon nodular cast iron |
-
2000
- 2000-09-14 CN CN 00124768 patent/CN1112456C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100513586C (en) * | 2007-07-04 | 2009-07-15 | 芜湖新兴铸管有限责任公司 | Production process and device of nodular cast iron pipe |
| CN102492888A (en) * | 2011-12-23 | 2012-06-13 | 天津市万路科技有限公司 | Vermiculizer and application thereof |
| CN102492888B (en) * | 2011-12-23 | 2013-12-25 | 天津市万路科技有限公司 | Vermiculizer and application thereof |
| CN103239139A (en) * | 2013-05-06 | 2013-08-14 | 三穗宏立厨具有限公司 | Rare earth alloy iron pan and production method thereof |
| CN104099511A (en) * | 2014-07-30 | 2014-10-15 | 宁波通达精密铸造有限公司 | Preparation method of spheroidal graphite cast iron |
| CN104099511B (en) * | 2014-07-30 | 2016-04-06 | 宁波通达精密铸造有限公司 | The preparation method of spheroidal graphite cast iron |
| CN114854926A (en) * | 2022-03-24 | 2022-08-05 | 江苏亚峰合金材料有限公司 | Environment-friendly nodulizer for low-silicon nodular cast iron |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1112456C (en) | 2003-06-25 |
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