CN1288667A - Diethofencarb-carbendazim composite germicide - Google Patents
Diethofencarb-carbendazim composite germicide Download PDFInfo
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- CN1288667A CN1288667A CN 99119605 CN99119605A CN1288667A CN 1288667 A CN1288667 A CN 1288667A CN 99119605 CN99119605 CN 99119605 CN 99119605 A CN99119605 A CN 99119605A CN 1288667 A CN1288667 A CN 1288667A
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- China
- Prior art keywords
- carbendazim
- mould prestige
- mould
- grams
- germicide
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- 239000006013 carbendazim Substances 0.000 title claims abstract description 22
- 239000002131 composite material Substances 0.000 title claims description 17
- 230000002070 germicidal effect Effects 0.000 title claims description 16
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims abstract description 21
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 235000013311 vegetables Nutrition 0.000 claims abstract description 9
- 201000010099 disease Diseases 0.000 claims abstract description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 239000000575 pesticide Substances 0.000 claims description 10
- 239000003905 agrochemical Substances 0.000 claims description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 8
- 238000009472 formulation Methods 0.000 claims description 8
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims description 8
- 239000005867 Iprodione Substances 0.000 claims description 7
- CFZLNRGUBAVQNO-UHFFFAOYSA-N N-(3,5-Dichlorophenyl)succinimide Chemical compound ClC1=CC(Cl)=CC(N2C(CCC2=O)=O)=C1 CFZLNRGUBAVQNO-UHFFFAOYSA-N 0.000 claims description 7
- JHXVRRJXCDAINK-UHFFFAOYSA-N NC(=O)N.N#CC#N Chemical compound NC(=O)N.N#CC#N JHXVRRJXCDAINK-UHFFFAOYSA-N 0.000 claims description 7
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 230000000844 anti-bacterial effect Effects 0.000 claims description 6
- 238000009313 farming Methods 0.000 claims description 6
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- -1 sawmilling Substances 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 5
- 210000000481 breast Anatomy 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 claims description 5
- 239000000375 suspending agent Substances 0.000 claims description 5
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 4
- FSCWZHGZWWDELK-UHFFFAOYSA-N 3-(3,5-dichlorophenyl)-5-ethenyl-5-methyl-2,4-oxazolidinedione Chemical compound O=C1C(C)(C=C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 FSCWZHGZWWDELK-UHFFFAOYSA-N 0.000 claims description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 4
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 claims description 4
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 3
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 244000037666 field crops Species 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- 241000894006 Bacteria Species 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- 239000000020 Nitrocellulose Substances 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims description 2
- 229960000892 attapulgite Drugs 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 150000003851 azoles Chemical class 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- 229940092782 bentonite Drugs 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000446 fuel Substances 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- 229920001220 nitrocellulos Polymers 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- 235000010333 potassium nitrate Nutrition 0.000 claims description 2
- 239000004323 potassium nitrate Substances 0.000 claims description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 2
- 239000010902 straw Substances 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 claims description 2
- 240000000249 Morus alba Species 0.000 claims 1
- 235000008708 Morus alba Nutrition 0.000 claims 1
- 244000269722 Thea sinensis Species 0.000 claims 1
- 239000002671 adjuvant Substances 0.000 claims 1
- 235000013616 tea Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 235000013399 edible fruits Nutrition 0.000 abstract description 3
- 230000000855 fungicidal effect Effects 0.000 abstract description 3
- 239000000779 smoke Substances 0.000 abstract description 2
- 239000000725 suspension Substances 0.000 abstract description 2
- 239000005759 Diethofencarb Substances 0.000 abstract 1
- LNJNFVJKDJYTEU-UHFFFAOYSA-N diethofencarb Chemical compound CCOC1=CC=C(NC(=O)OC(C)C)C=C1OCC LNJNFVJKDJYTEU-UHFFFAOYSA-N 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 abstract 1
- 239000004546 suspension concentrate Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 9
- 238000003672 processing method Methods 0.000 description 6
- 241000221785 Erysiphales Species 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 241000233679 Peronosporaceae Species 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000008234 soft water Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 244000241257 Cucumis melo Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- 239000005747 Chlorothalonil Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- 229940125810 compound 20 Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- JAXFJECJQZDFJS-XHEPKHHKSA-N gtpl8555 Chemical compound OC(=O)C[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@@H]1C(=O)N[C@H](B1O[C@@]2(C)[C@H]3C[C@H](C3(C)C)C[C@H]2O1)CCC1=CC=C(F)C=C1 JAXFJECJQZDFJS-XHEPKHHKSA-N 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The high-efficiency, broad-spectrum, safe and low-pollution compounded fungicide with specific effect for preventing and curing several diseases of crops, forest, fruit tree and vegetables is formed from diethofencarb and carbendazim, and can be made into smoke preparation, suspension preparation, suspension concentrate, wates emulsion and microemulsin, etc..
Description
The present invention relates to the mould prestige carbendazim composite germicide of a kind of Compositional type bactericide agricultural chemicals-second.
For many years, China owing to often reuse a certain agricultural chemicals at areal, causes this agricultural chemicals that multiple germ has been produced pesticide resistance in the process of using the pesticide control disease, causes drug effect significantly to descend, the disease wildness of stretching.
In the process preparation of bactericide agricultural chemicals, most kinds are wetting powder, are missible oil secondly.The processing formulation is single and backward, and drug effect is not played well during use; The benzene kind solvent that the consumption of modified milk oil require is a large amount of, this has not only consumed a large amount of industrial chemicals, simultaneously not only dangerous but also can pollute to environment in pesticide processing and use, some countries propose, and forbidding benzene class is done the motion of solvent in formulations of pesticide processing.
The object of the present invention is to provide a kind of efficient, wide spectrum, safety and oligosaprobic disinfectant use in agriculture.
The present invention is achieved in that the mould prestige carbendazim composite germicide of second, and the weight ratio of its active ingredient is 1: 0.1～10, and the proportioning of active ingredient (m/m) is 1～50% in the preparation; Process preparation all adopts pesticides new formulation, as: fumicants, suspending agent, suspended emulsion, aqueous emulsion, microemulsion; Carbendazim in the mould prestige carbendazim composite germicide of second can substitute with one of following agricultural chemicals: white urea cyanogen, tpn, triazolone, nitrile bacterium azoles, dislike mould spirit; The mould prestige of second in the mould prestige carbendazim composite germicide of second can substitute with one of following: dimethachlon, vinclozolin, iprodione, procymidone, probenazole.In the alternative composition pesticide of the mould prestige carbendazim of second sterilization combination, do not relate to dimethachlon and tpn, procymidone and the claim of tpn two compositions in this patent.
Difference according to the mould prestige carbendazim composite germicide processing of second formulation, the component of processing fumicants (except that pesticide active ingredient) heat supply agent is fuel (wood powder, sawmilling, straw powder, charcoal, starch, sucrose, thiocarbamide, an ammonium thiocyanate), oxidant (potassium chlorate, potassium nitrate, ammonium nitrate, nitrocellulose), cooling blast reducer (ammonium chloride, potter's clay); Processing suspending agent, suspension missible oil, aqueous emulsion, the used auxiliary agent of microemulsion are one of following or their combination: M-9, NNO, MF, LS, T, BX, LS-Na, DBS-Na, farming breast 300
#, 500
#, 600
#, 700
#, 1600
#, 1656H, 1656L, CMC, PVA, soluble starch, n-octyl alcohol, n-butanol, isoamyl alcohol, isopropyl alcohol, ethanol, methyl alcohol, ethylene glycol, glycerine, cyclohexanone, butanone, acetone, chloroform, dodecanol-1, tetradecanol-1, octadecanol-1, nonadecanol-1, eicosanol-1, toluene, white carbon, precipitated calcium carbonate, attapulgite, bentonite, diatomite.
Advantage of the present invention and good effect: 1, in disinfectant use in agriculture, bactericide agricultural chemicals with two kinds of different types of structure, different sterilization mechanism and different fungicidal spectrums carries out the composite effect that can reach raising to control resistant strain germ selectively, enlarge fungicidal spectrum, and can synergy and delay the drug-fast development of germ, the mould prestige carbendazim composite germicide of second of the present invention has promptly reached above-mentioned purpose.2, in the processing formulation of the mould prestige carbendazim composite germicide of second, only relate to pesticides new formulation, as fumicants, suspending agent, suspended emulsion, aqueous emulsion and microemulsion.These pesticides new formulations in use can have been given play to drug effect better than pulvis, wetting powder, thereby can reduce the consumption of agricultural chemicals, fall end control cost.Make solvent and also alleviated the pollution of agricultural chemicals owing to use no or little the benzene class, favorable economic benefit and environmental benefit are arranged environment.
The mould prestige carbendazim of embodiment 1:25% second fumicants
Get former medicine 5 grams of the mould prestige of second, carbendazim active compound 20 grams, sawmilling 16 grams, ammonium nitrate 34 grams, ammonium chloride 22.5 grams, ammonium thiocyanate 2.5 grams.
Processing method: above-mentioned raw materials is mixed, mix through pulverizing (40 order), packing is the powdery fumicants.Inserting in fumicants during use ignites to twist with the fingers lights, gray mold, early blight, powdery mildew, downy mildew on the control protection ground vegetables.Every mu with fumicants 200～300 gram, and effect reaches more than 90%.
Embodiment 2:20% probenazole chlorothalonil smoke
Get former medicine 2 grams of probenazole, former medicine 18 grams of tpn, wood powder 16 grams, potassium chlorate 18 grams, potter's clay 30 grams, ammonium chloride 16 grams.
Processing method: potassium chlorate pulverized separately and by 80 mesh sieves, the pulverizing (80 order) that mixes of all the other raw materials, the potassium chlorate after will pulverizing again mixes, add suitable quantity of water after, mixing, moulding, oven dry smoked sheet.Light gray mold, downy mildew, powdery mildew, early blight, late blight on the control protection ground vegetables during use with fire.Every mu with fumicants 200～300 gram, and effect reaches more than 90%.
Embodiment 3:40% vinclozolin frost urea cyanogen suspending agent
Get vinclozolin 25 grams, white urea cyanogen 15 grams, 1656H 2 grams, M-95 gram, white carbon 3 grams, CMC2 gram, ethylene glycol 5 grams, water 43 grams.
Processing method: above-mentioned raw materials is mixed, and through ball milling (200 order), sand milling becomes 3～5 microns of average grain diameters.Gray mildew, early blight, late blight, downy mildew on control protection ground and the land for growing field crops vegetables.Every mu of usefulness 50～100 is restrained agent, and effect reaches more than 90%.
Embodiment 4:25% iprodione triazolone suspended emulsion
Get former medicine 15 grams of iprodione, former medicine 10 grams of triazolone, 1656H 5 grams, M-95 gram, white carbon 3 grams, CMC 2 grams, cyclohexanone 10 grams, ethylene glycol 3 grams, water 37 grams.
Processing method: the former medicine of triazolone, 1656H, cyclohexanone are mixed, mix with other raw material after the stirring and dissolving again, through ball milling (200 order), sand milling is made 3～5 microns of average grain diameters.Control vegetables, melon, beans gray mold, powdery mildew, early blight, rust.Every mu with preparation 100～150 gram, and effect reaches more than 90%.
Embodiment 5:15% dimethachlon triazolone aqueous emulsion
Get former medicine 5 grams of dimethachlon, former medicine 10 grams of triazolone, toluene 30 grams, 1656H 5 grams, n-butanol 2 grams, ethylene glycol 2 grams, CMC 1 gram, soft water 45 grams.
Processing method: dimethachlon triazolone, toluene, 1656H, n-butanol are put into pot, make oil phase behind the stirring and evenly mixing, ethylene glycol, CMC and soft water are put into the pot stirring and evenly mixing make water.Under high-speed stirred, oil phase is added aqueous phase, finely disseminated aqueous emulsion.Prevent and treat powdery mildew of wheat and barley, rust, vegetables, melon and fruit class gray mold, powdery mildew.Every mu with preparation 100～200 gram, and effect reaches more than 90%.
Embodiment 6:10% iprodione frost urea cyanogen microemulsion
Get former medicine 7 grams of iprodione, white urea cyanogen 3 grams, acetone 35 grams, farming breast 1600
#15 grams, farming breast 500
#5 grams, soft water 35 grams.
Processing method: iprodione frost urea cyanogen and acetone are dropped in the container, and stirring and dissolving is made oil phase; With farming breast 500
#, 1600
#Drop in another container stirring and dissolving with soft water and make water; Under the strong agitation of even matter blender, oil phase is added aqueous phase, obtain the yellow transparent microemulsion.Gray mold, early blight, stalk break, downy mildew on control protection ground and land for growing field crops vegetables, cotton, fruit tree, grape, the flowers and other crops.Every mu with preparation 150～250 gram, and effect reaches more than 90%.
Claims (7)
1, the mould prestige carbendazim composite germicide of second is characterized in that the weight ratio of active ingredient is 1: 0.1～10, and the proportioning of active ingredient (m/m) is 1～50% in the preparation, and all the other are heat supply agent (fumicants is used) or auxiliary agent.
2, the mould prestige carbendazim composite germicide of second according to claim 1 is characterized in that its processing formulation can be fumicants, suspending agent, suspended emulsion, aqueous emulsion and microemulsion.
3, according to claim 1 and the mould prestige carbendazim composite germicide of 2 described second, it is characterized in that the carbendazim in the bactericidal composition can substitute with one of following agricultural chemicals: white urea cyanogen, tpn, triazolone, nitrile bacterium azoles, dislike mould spirit.
4,, it is characterized in that the mould prestige of second in the bactericidal composition can substitute with one of following agricultural chemicals: dimethachlon, vinclozolin, iprodione, procymidone, probenazole according to claim 1 and the mould prestige carbendazim composite germicide of 2 described second.According to claim 3 and the how mould clever bactericidal composition of the mould prestige of 4 described second, it is characterized in that in their alternative composition pesticide, dimethachlon and tpn, procymidone and tpn two compositions be not in this patent claimed range.
5, according to the mould prestige carbendazim composite germicide of the described second of claim 1～4, it is characterized in that used heat supply agent is following composition: fuel (wood powder, sawmilling, straw powder, charcoal, starch, sucrose, thiocarbamide, ammonium thiocyanate), oxidant (potassium chlorate, potassium nitrate, ammonium nitrate, nitrocellulose), cooling antismoke agent (ammonium chloride, potter's clay).
6,, it is characterized in that adjuvant used one of following or their combination that is: M-9, NNO, MF, LS, T, BX, LS-Na, DBS-Na, farming breast 300 according to the mould prestige carbendazim composite germicide of the described second of claim 1～4
#, 500
#, 600
#, 700
#, 1600
#, 1656H, 1656L, CMC, PVA, soluble starch, n-octyl alcohol, n-butanol, isoamyl alcohol, isopropyl alcohol, ethanol, methyl alcohol, ethylene glycol, glycerine, cyclohexanone, butanone, acetone, chloroform, dodecanol-1, tetradecanol-1, octadecanol-1, nonadecanol-1, eicosanol-1, toluene, white carbon, precipitated calcium carbonate, attapulgite, bentonite, diatomite.
7, the mould prestige carbendazim composite germicide of second of the present invention, be mainly used in control protection ground vegetables and land for growing field crops farming, woods, really, tea, mulberry, vegetables multiple diseases.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99119605 CN1288667A (en) | 1999-09-21 | 1999-09-21 | Diethofencarb-carbendazim composite germicide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99119605 CN1288667A (en) | 1999-09-21 | 1999-09-21 | Diethofencarb-carbendazim composite germicide |
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| Publication Number | Publication Date |
|---|---|
| CN1288667A true CN1288667A (en) | 2001-03-28 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 99119605 Pending CN1288667A (en) | 1999-09-21 | 1999-09-21 | Diethofencarb-carbendazim composite germicide |
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| CN (1) | CN1288667A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1941798A3 (en) * | 2004-12-17 | 2009-08-05 | Devgen NV | Nematicidal compositions |
| US7659277B2 (en) * | 2003-07-11 | 2010-02-09 | Proteologies, Ltd. | Ubiquitin ligase inhibitors and methods related thereto |
| CN101715779B (en) * | 2009-11-17 | 2013-05-08 | 金陵科技学院 | Bactericidal composite of myclobutanil and iprodione, preparation method and application thereof |
| CN103875665A (en) * | 2014-04-23 | 2014-06-25 | 郑留军 | Wood flour fog-free composite preparation for pest control of vegetables and flowers in greenhouse and application thereof |
| CN105580819A (en) * | 2014-11-17 | 2016-05-18 | 武汉凌科达科技有限公司 | Plant-based composite pesticide |
| CN105638681A (en) * | 2014-11-17 | 2016-06-08 | 武汉凌科达科技有限公司 | A preparing method of a plant-sourced composite pesticide |
| CN107047585A (en) * | 2017-06-12 | 2017-08-18 | 宋琦 | One kind is combined antifungal agricultural chemicals |
| CN108174729A (en) * | 2018-01-11 | 2018-06-19 | 和县农丰蔬菜种子专业合作社 | A kind of nuisanceless insect-prevention method of green house of vegetables |
| CN108207979A (en) * | 2016-12-13 | 2018-06-29 | 沈阳中化农药化工研发有限公司 | A kind of Fungicidal composition and its application |
| CN108552200A (en) * | 2018-04-17 | 2018-09-21 | 广东省生物工程研究所（广州甘蔗糖业研究所） | Have effects that prevent the bactericidal composition of smut and its application |
| CN108633384A (en) * | 2018-04-17 | 2018-10-12 | 广东省生物工程研究所（广州甘蔗糖业研究所） | The sterilization method of cane seedling |
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1999
- 1999-09-21 CN CN 99119605 patent/CN1288667A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7659277B2 (en) * | 2003-07-11 | 2010-02-09 | Proteologies, Ltd. | Ubiquitin ligase inhibitors and methods related thereto |
| EP1941798A3 (en) * | 2004-12-17 | 2009-08-05 | Devgen NV | Nematicidal compositions |
| CN101715779B (en) * | 2009-11-17 | 2013-05-08 | 金陵科技学院 | Bactericidal composite of myclobutanil and iprodione, preparation method and application thereof |
| CN103875665A (en) * | 2014-04-23 | 2014-06-25 | 郑留军 | Wood flour fog-free composite preparation for pest control of vegetables and flowers in greenhouse and application thereof |
| CN105580819A (en) * | 2014-11-17 | 2016-05-18 | 武汉凌科达科技有限公司 | Plant-based composite pesticide |
| CN105638681A (en) * | 2014-11-17 | 2016-06-08 | 武汉凌科达科技有限公司 | A preparing method of a plant-sourced composite pesticide |
| CN108207979A (en) * | 2016-12-13 | 2018-06-29 | 沈阳中化农药化工研发有限公司 | A kind of Fungicidal composition and its application |
| CN107047585A (en) * | 2017-06-12 | 2017-08-18 | 宋琦 | One kind is combined antifungal agricultural chemicals |
| CN108174729A (en) * | 2018-01-11 | 2018-06-19 | 和县农丰蔬菜种子专业合作社 | A kind of nuisanceless insect-prevention method of green house of vegetables |
| CN108552200A (en) * | 2018-04-17 | 2018-09-21 | 广东省生物工程研究所（广州甘蔗糖业研究所） | Have effects that prevent the bactericidal composition of smut and its application |
| CN108633384A (en) * | 2018-04-17 | 2018-10-12 | 广东省生物工程研究所（广州甘蔗糖业研究所） | The sterilization method of cane seedling |
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