CN1286910A - Re-compounded pretilachlor-pyrozosulfuron-ethyl preparation - Google Patents
Re-compounded pretilachlor-pyrozosulfuron-ethyl preparation Download PDFInfo
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- CN1286910A CN1286910A CN 99116847 CN99116847A CN1286910A CN 1286910 A CN1286910 A CN 1286910A CN 99116847 CN99116847 CN 99116847 CN 99116847 A CN99116847 A CN 99116847A CN 1286910 A CN1286910 A CN 1286910A
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- pyrazosulfuron
- clay
- sodium
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- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 239000004927 clay Substances 0.000 claims abstract description 29
- 239000003381 stabilizer Substances 0.000 claims abstract description 26
- VXMNDQDDWDDKOQ-UHFFFAOYSA-N Pyrazosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=CC=2C(O)=O)C)=N1 VXMNDQDDWDDKOQ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 13
- 235000009566 rice Nutrition 0.000 claims abstract description 13
- 239000000853 adhesive Substances 0.000 claims abstract description 12
- 230000001070 adhesive effect Effects 0.000 claims abstract description 12
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000010452 phosphate Substances 0.000 claims abstract description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 5
- 240000007594 Oryza sativa Species 0.000 claims abstract 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical group [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 24
- 150000001412 amines Chemical class 0.000 claims description 21
- 239000012752 auxiliary agent Substances 0.000 claims description 21
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 239000001175 calcium sulphate Substances 0.000 claims description 10
- 235000011132 calcium sulphate Nutrition 0.000 claims description 10
- 239000008187 granular material Substances 0.000 claims description 10
- 238000009736 wetting Methods 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 8
- 229910052791 calcium Inorganic materials 0.000 claims description 8
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical group [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 8
- 241001290610 Abildgaardia Species 0.000 claims description 7
- 241000209504 Poaceae Species 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 6
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 5
- 244000215068 Acacia senegal Species 0.000 claims description 4
- 229920000084 Gum arabic Polymers 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 239000000205 acacia gum Substances 0.000 claims description 4
- 235000010489 acacia gum Nutrition 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 4
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical group [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 4
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 4
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 4
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 4
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 4
- 239000011118 polyvinyl acetate Substances 0.000 claims description 4
- 229940005657 pyrophosphoric acid Drugs 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 4
- YLPGTOIOYRQOHV-UHFFFAOYSA-N Pretilachlor Chemical compound CCCOCCN(C(=O)CCl)C1=C(CC)C=CC=C1CC YLPGTOIOYRQOHV-UHFFFAOYSA-N 0.000 claims description 3
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 239000004009 herbicide Substances 0.000 abstract description 14
- 230000002363 herbicidal effect Effects 0.000 abstract description 8
- 238000001228 spectrum Methods 0.000 abstract description 5
- 230000000295 complement effect Effects 0.000 abstract description 2
- 241000234646 Cyperaceae Species 0.000 abstract 1
- 229920005552 sodium lignosulfonate Polymers 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 38
- 241000196324 Embryophyta Species 0.000 description 20
- 241000209094 Oryza Species 0.000 description 10
- 244000025254 Cannabis sativa Species 0.000 description 7
- 241000192043 Echinochloa Species 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229920005551 calcium lignosulfonate Polymers 0.000 description 5
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical group [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 5
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 3
- WTLNOANVTIKPEE-UHFFFAOYSA-N 2-acetyloxypropanoic acid Chemical compound OC(=O)C(C)OC(C)=O WTLNOANVTIKPEE-UHFFFAOYSA-N 0.000 description 2
- 244000150195 Cyperus longus Species 0.000 description 2
- 235000018109 Cyperus longus Nutrition 0.000 description 2
- 241000234642 Festuca Species 0.000 description 2
- 150000005693 branched-chain amino acids Chemical class 0.000 description 2
- 230000034994 death Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 2
- 235000019838 diammonium phosphate Nutrition 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 description 2
- 235000019800 disodium phosphate Nutrition 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 2
- 235000019799 monosodium phosphate Nutrition 0.000 description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000285790 Cyperus iria Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- AGPKZVBTJJNPAG-WHFBIAKZSA-N L-isoleucine Chemical compound CC[C@H](C)[C@H](N)C(O)=O AGPKZVBTJJNPAG-WHFBIAKZSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- 240000007038 Lindernia dubia Species 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 241000091577 Mexicana Species 0.000 description 1
- 240000000178 Monochoria vaginalis Species 0.000 description 1
- 241000756999 Potamogetonaceae Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 230000010261 cell growth Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 229960000310 isoleucine Drugs 0.000 description 1
- AGPKZVBTJJNPAG-UHFFFAOYSA-N isoleucine Natural products CCC(C)C(N)C(O)=O AGPKZVBTJJNPAG-UHFFFAOYSA-N 0.000 description 1
- 229960003646 lysine Drugs 0.000 description 1
- 230000017074 necrotic cell death Effects 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- 229940099402 potassium metaphosphate Drugs 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000003161 proteinsynthetic effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The re-compounded preparation as herbicide for rice field contains preftilachlor 10-50 wt% and pyrazosulfuron 0.2-10 wt% as effective components as well as agricultural acceptable adhesive, such as polyvinyl alcohol, 1.0-2.0 wt%; stabilizer, such as sulfate and phosphate, 0.5-1.0 wt%; assistant, such as sodium lignosulfonate, 5-15 wt% besides carrier, such as kaolin, clay, pot clay, etc. It is compounded in granulated preparation or wettable powder. It has synergetic and complementary herbicide spectrum and can prevent and kill graminaceous, latifolious and sedge family weeds.
Description
The present invention relates to a kind of composition pesticide, relate in particular to a kind of third careless amine of killing weeds in rice field and complex preparation of pyrazosulfuron of being used for.
The third careless amine (pretilachlor) is the selectivity preemergence herbicide that Switzerland Novartis Co.,Ltd (NOVARTIS) develops.
The chemical structural formula of the third careless amine is:
The third careless amine mainly absorbs by plant hypocotyl, mesocotyl and coleoptile, directly disturbs weeds body internal protein synthetic, and photosynthetic and respiration are had remote-effects, causes weeds death.And paddy rice has stronger capacity of decomposition to the third careless amine, thereby has certain selectivity.The third careless amine can effectively be prevented and kill off the annual gramineae grass and the part broad leaved weed in rice field, as barnyard grass grass, Monochoria vaginalis, Herba Ammanniae Bacciferae etc., but to the sedge weed weak effect.
Pyrazosulfuron (pyrazosulfuron) is to inhale the conduction weed killer herbicide in a kind of efficient selective.
The chemical constitution of pyrazosulfuron is:
Pyrazosulfuron is mainly the weeds root and blade absorbs, and transfer to each one of weeds, by suppressing the activity of acetolactate synthestase, make the branched-chain amino acid biosynthesis block, the biosynthesis of hindered aminoacid, lysine, isoleucine, stop the division and the growth of cell, cause the weed growth function to be obstructed, make the weeds necrosis.It kills the grass spectrum and is applicable to the broad leaved weed of preventing and kill off the rice field, as Duck tongue grass, pondweed, mexicana, Procumbent Falsepimpernel etc., reaches sedge weed such as fescue, difformed galingale herb, Herba Cyperi Glomerati, cyperus iria etc.But to preventing and kill off the active low of barnyard grass in paddy field, application can not be prevented and kill off grass family in the rice field, broad-leaved section and sedge weed fully separately.
The purpose of this invention is to provide a kind of grass spectrum of killing and have complementary advantages, can prevent and kill off the third careless amine of grass family in the rice field, broad-leaved section and sedge weed and the complex preparation of pyrazosulfuron fully.
The present invention is achieved in that the complex preparation of a kind of third careless amine and pyrazosulfuron, be characterized in that effective ingredient is the third careless amine (pretilachlor) and pyrazosulfuron (pyrazosulfuron) in the complex preparation, the third careless amine content is 10%～50% (weight) in the preparation, pyrazosulfuron content is 0.2%～10% (weight), all the other are that agricultural goes up acceptable adhesive, stabilizing agent, auxiliary agent and carrier add to 100% (weight) and make granule or wetting powder, effective component content is 10.2%～60% (weight) in the granule, and effective component content is 10.2%～60% (weight) in the wetting powder.
Adhesive described in the present invention is polyvinyl alcohol, polyvinyl acetate, starch and gum Arabic, accounts for 1.0%～2.0% (weight) of preparation.
Stabilizing agent described in the present invention is sulphate and phosphate, the sulphate stabilizing agent is barium sulfate, calcium sulphate, phosphate stabilizer is dipotassium hydrogen phosphate, sodium, ammonium salt, the potassium or the sodium salt of potassium dihydrogen phosphate, sodium, ammonium salt, pyrophosphoric acid, tripolyphosphate, four polyphosphoric acids, metaphosphoric acid, single using or the mixing application accounts for 0.5%～1% (weight) of preparation.
Auxiliary agent described in the present invention is sodium lignin sulfonate or sulfoacid calcium, draws back powder, dodecyl sodium sulfonate calcium, accounts for 5%～15% (weight) of preparation.
Carrier described in the present invention is kaolin, diatomite, sand, clay, potter's clay, bentonite, adds to 100% (weight).
The complex preparation of the present invention's third careless amine and pyrazosulfuron is granule or wetting powder, is used to prevent and kill off transplanting rice field, or seedlings rice seedling Tanaka's grass family, broad-leaved section and sedge weed.
Granule can be used coating method, mediate manufactured, and carrier is kaolin, diatomite, sand, clay, potter's clay, bentonite etc., and adhesive is polyvinyl alcohol, polyvinyl acetate, starch, gum Arabic etc.
The pulvis carrier of wetting powder is kaolin, diatomite, sand, clay, potter's clay, bentonite etc.Auxiliary agent is sodium lignin sulfonate or calcium, draw back powder, dodecyl sodium sulfate etc.
The third careless amine and pyrazosulfuron mix and can cause that pyrazosulfuron slowly decomposes, and add barium sulfate or calcium sulphate and phosphatic mixture in the preparation as stabilizing agent, and effect is fine.
The present invention is mixed with complex preparation with the third careless amine and pyrazosulfuron, and the third careless amine is the selectivity preemergence herbicide, mainly absorbs by weeds young shoot coleoptile and immature secondary root, disturbs weeds body internal protein to synthesize and causes weeds death; Pyrazosulfuron is to inhale the conduction weed killer herbicide in the selectivity, is mainly weeds root and blade and absorbs, and transfer to each one of weeds, by suppressing the activity of acetolactate synthestase, makes the branched-chain amino acid biosynthesis block, and the division of cell and growth are destroyed.Because therefore the site of action difference of two kinds of weed killer herbicides in the weeds body improved and killed careless effect.It is with strong complementarity to kill the grass spectrum, and the careless spectrum of killing of broad is arranged, and can effectively prevent and kill off all weeds in the rice field, comprises grass family, broad-leaved section and sedge weed, has overcome pyrazosulfuron to preventing and kill off the active low defective of barnyard grass in paddy field, has solved most of weeds problem in rice field.
The third careless amine generally is considered as the weed killer herbicide of dry crop such as corn, soybean, peanut, cotton etc., in the present invention, the third careless amine is changed by the nonirrigated farmland executes the paddy field, a little less than weeds plant children in the paddy field, it is big that the absorptive tissue area becomes, and the paddy field environment helps the diffusion of weed killer herbicide and moves, and more helps bioactive performance, general 1/10～1/15 of the nonirrigated farmland effective dose that only needs can be prevented and treated weeds such as barnyard grass grass, difformed galingale herb, fescue in the paddy field.Reduce owing to kill barnyard grass agent consumption, drug cost is obviously reduced, overcome single defective that needs higher dosage with pyrazosulfuron control barnyard grass in paddy field.
Preparation of the present invention is quite favourable to the agricultural environment ecological protection; used composition is generally low to the more conventional mixture of mammiferous toxicity; in aquatic environment; the actual concentrations of the third careless amine and pyrazosulfuron will hang down 10 times than them to test toxicity to fish index TLM value (48,96 hours at the appointed time, the concentration that has half to survive).
Preparation of the present invention is mixed with granule or wetting powder, and it is convenient to use, as long as evenly spread fertilizer over the fields.
Be embodiments of the invention below:
Each component ratio (weight %) among the present invention
Specifically being constructed as follows of the scheme 1～scheme 6 of granule:
Stabilizing agent in the scheme 1 is the mixture of barium sulfate and sodium hydrogen phosphate, and adhesive is a polyvinyl alcohol, and auxiliary agent is a sodium lignin sulfonate, and carrier is the mixture of diatomite and clay.
Stabilizing agent in the scheme 2 is the mixture of calcium sulphate and dipotassium hydrogen phosphate, and adhesive is a polyvinyl alcohol, and auxiliary agent is a calcium lignosulfonate, and carrier is the mixture of clay and potter's clay.
Stabilizing agent in the scheme 3 is the mixture of calcium sulphate and diammonium hydrogen phosphate, and adhesive is a polyvinyl alcohol, and auxiliary agent is for drawing back powder, and carrier is the mixture of bentonite and clay.
Stabilizing agent in the scheme 4 is the mixture of barium sulfate and potassium dihydrogen phosphate, and adhesive is a polyvinyl acetate, and auxiliary agent is a dodecyl sodium sulfonate calcium, and carrier is the mixture of kaolin and clay.
Stabilizing agent in the scheme 5 is the mixture of barium sulfate and sodium dihydrogen phosphate, and adhesive is a starch, and auxiliary agent is a calcium lignosulfonate, and carrier is the mixture of kaolin, sand and clay.
Stabilizing agent in the scheme 6 is the mixture of calcium sulphate and pyrophosphoric acid, and adhesive is a gum Arabic, and auxiliary agent is a sodium lignin sulfonate, and carrier is clay and bentonitic mixture.
Specifically being constructed as follows of the scheme 1～scheme 10 of wetting powder:
Stabilizing agent in the scheme 1 is the mixture of barium sulfate and sodium hydrogen phosphate, and auxiliary agent is a sodium lignin sulfonate, and carrier is the mixture of diatomite and clay.
Stabilizing agent in the scheme 2 is the mixture of calcium sulphate and dipotassium hydrogen phosphate, and auxiliary agent is a calcium lignosulfonate, and carrier is the mixture of clay and potter's clay.
Stabilizing agent in the scheme 3 is the mixture of calcium sulphate and diammonium hydrogen phosphate, and auxiliary agent is for drawing back powder, and carrier is the mixture of bentonite and clay.
Stabilizing agent in the scheme 4 is the mixture of barium sulfate and potassium dihydrogen phosphate, and auxiliary agent is a dodecyl sodium sulfonate calcium, and carrier is the mixture of kaolin and clay.
Stabilizing agent in the scheme 5 is the mixture of barium sulfate and sodium dihydrogen phosphate, and auxiliary agent is a calcium lignosulfonate, and carrier is the mixture of diatomite and potter's clay.
Stabilizing agent in the scheme 6 is the mixture of calcium sulphate and pyrophosphoric acid, and auxiliary agent is a sodium lignin sulfonate, and carrier is clay and bentonitic mixture.
Stabilizing agent in the scheme 7 is the mixture of barium sulfate and tripolyphosphate, and auxiliary agent is a sodium lignin sulfonate, and carrier is the mixture of diatomite, sand and clay.
Stabilizing agent in the scheme 8 is the mixture of calcium sulphate and four polyphosphoric acids, and auxiliary agent is a calcium lignosulfonate, and carrier is the mixture of diatomite and potter's clay.
Stabilizing agent in the scheme 9 is the mixture of barium sulfate and potassium metaphosphate, and auxiliary agent is for drawing back powder, and carrier is the mixture of clay and potter's clay.
Stabilizing agent in the scheme 10 is the mixture of barium sulfate and sodium metaphosphate, and auxiliary agent is a dodecyl sodium sulfonate calcium, and carrier is clay and bentonitic mixture.
The component of above-mentioned granule scheme 1～6 and the relevant mixture that reaches described in the wetting powder scheme 1～10 is formed by any proportioning.
The granule scheme 1～6 of above-mentioned embodiment and wetting powder scheme 1～10 listed prescription are not the restrictions to each component proportioning of the present invention, but content of the present invention is further described.
Claims (6)
1, the complex preparation of a kind of third careless amine and pyrazosulfuron, it is characterized in that the effective ingredient in the complex preparation is the third careless amine (pretilachlor) and pyrazosulfuron (pyrazosulfuron), the third careless amine content is 10%～50% (weight) in the preparation, pyrazosulfuron content is 0.2%～10% (weight), all the other are that agricultural goes up acceptable adhesive, stabilizing agent, auxiliary agent and carrier add to 100% (weight) and are mixed with granule or wetting powder, effective component content is 10.2%～60% (weight) in the granule, and effective component content is 10.2%～60% (weight) in the wetting powder.
2, complex preparation according to claim 1 is characterized in that described adhesive is polyvinyl alcohol, polyvinyl acetate, starch and gum Arabic, accounts for 1.0%～2.0% (weight) of preparation.
3, complex preparation according to claim 1, it is characterized in that described stabilizing agent is sulphate and phosphate, the sulphate stabilizing agent is barium sulfate, calcium sulphate, phosphate stabilizer is dipotassium hydrogen phosphate, sodium, ammonium salt, the potassium or the sodium salt of potassium dihydrogen phosphate, sodium, ammonium salt, pyrophosphoric acid, tripolyphosphate, four polyphosphoric acids, metaphosphoric acid, single using or the mixing application accounts for 0.5%～1% (weight) of preparation.
4, complex preparation according to claim 1 is characterized in that described auxiliary agent is a sodium lignin sulfonate, or sulfoacid calcium, draws back powder, dodecyl sodium sulfonate calcium, accounts for 5%～15% (weight) of preparation.
5, complex preparation according to claim 1 is characterized in that described carrier is kaolin, diatomite, sand, clay, potter's clay, bentonite, adds to 100% (weight).
6, according to claim 1,2,3,4 or 5 described complex preparations, it is characterized in that complex preparation is used to prevent and kill off transplanting rice field, or seedlings rice seedling Tanaka's grass family, broad-leaved section and sedge weed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99116847 CN1286910A (en) | 1999-09-08 | 1999-09-08 | Re-compounded pretilachlor-pyrozosulfuron-ethyl preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99116847 CN1286910A (en) | 1999-09-08 | 1999-09-08 | Re-compounded pretilachlor-pyrozosulfuron-ethyl preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1286910A true CN1286910A (en) | 2001-03-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99116847 Pending CN1286910A (en) | 1999-09-08 | 1999-09-08 | Re-compounded pretilachlor-pyrozosulfuron-ethyl preparation |
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| Country | Link |
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| CN (1) | CN1286910A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102077834A (en) * | 2010-12-20 | 2011-06-01 | 山东德浩化学有限公司 | Microcapsule suspension concentrate for preventing and removing rice paddy weed and preparation method thereof |
| WO2012042316A1 (en) * | 2010-09-27 | 2012-04-05 | United Phosphorus Limited | Granules |
| CN102524278A (en) * | 2011-12-13 | 2012-07-04 | 济南科赛基农化工有限公司 | Oxaziclomefone, pyrazosulfuron, pretilachlor ternary effervescent herbicide for paddy fields and preparation method thereof |
| CN102640759A (en) * | 2012-04-01 | 2012-08-22 | 广东中迅农科股份有限公司 | Weeding composition for rice direct-seeding field |
| CN103081937A (en) * | 2013-02-21 | 2013-05-08 | 中农立华生物科技股份有限公司 | Compound weeding composition of pretilachlor and pyrazosulfuron-ethyl and granules of composition |
| CN103190425A (en) * | 2013-03-28 | 2013-07-10 | 济南科赛基农化工有限公司 | Effervescent tablet herbicide and preparation method thereof |
| CN106659163A (en) * | 2014-07-30 | 2017-05-10 | 日产化学工业株式会社 | Solid agrochemical composition |
| CN106665628A (en) * | 2016-12-03 | 2017-05-17 | 江苏莱科化学有限公司 | Herbicide containing pyrazosulfuron-ethyl, pretilachlor and mefenacet and application of herbicide |
| CN108617678A (en) * | 2018-06-04 | 2018-10-09 | 山东耘歌生物科技有限公司 | A kind of effervescent formulation and preparation method thereof containing pyrazosulfuron, pretilachlor and three azole amides |
| US20230309557A1 (en) * | 2020-07-11 | 2023-10-05 | Upl Limited | A solid agrochemical composition and process of preparation thereof |
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1999
- 1999-09-08 CN CN 99116847 patent/CN1286910A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103153067B (en) * | 2010-09-27 | 2015-05-13 | Upl有限公司 | Granules |
| WO2012042316A1 (en) * | 2010-09-27 | 2012-04-05 | United Phosphorus Limited | Granules |
| CN103153067A (en) * | 2010-09-27 | 2013-06-12 | 联合磷业有限公司 | Granules |
| CN102077834A (en) * | 2010-12-20 | 2011-06-01 | 山东德浩化学有限公司 | Microcapsule suspension concentrate for preventing and removing rice paddy weed and preparation method thereof |
| CN102077834B (en) * | 2010-12-20 | 2014-04-30 | 山东德浩化学有限公司 | Microcapsule suspension concentrate for preventing and removing rice paddy weed and preparation method thereof |
| CN102524278A (en) * | 2011-12-13 | 2012-07-04 | 济南科赛基农化工有限公司 | Oxaziclomefone, pyrazosulfuron, pretilachlor ternary effervescent herbicide for paddy fields and preparation method thereof |
| CN102640759A (en) * | 2012-04-01 | 2012-08-22 | 广东中迅农科股份有限公司 | Weeding composition for rice direct-seeding field |
| CN103081937A (en) * | 2013-02-21 | 2013-05-08 | 中农立华生物科技股份有限公司 | Compound weeding composition of pretilachlor and pyrazosulfuron-ethyl and granules of composition |
| CN103190425A (en) * | 2013-03-28 | 2013-07-10 | 济南科赛基农化工有限公司 | Effervescent tablet herbicide and preparation method thereof |
| CN106659163A (en) * | 2014-07-30 | 2017-05-10 | 日产化学工业株式会社 | Solid agrochemical composition |
| CN106665628A (en) * | 2016-12-03 | 2017-05-17 | 江苏莱科化学有限公司 | Herbicide containing pyrazosulfuron-ethyl, pretilachlor and mefenacet and application of herbicide |
| CN108617678A (en) * | 2018-06-04 | 2018-10-09 | 山东耘歌生物科技有限公司 | A kind of effervescent formulation and preparation method thereof containing pyrazosulfuron, pretilachlor and three azole amides |
| US20230309557A1 (en) * | 2020-07-11 | 2023-10-05 | Upl Limited | A solid agrochemical composition and process of preparation thereof |
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