CN1136336C - Chemical removing technology for composite coating of aircraft engine steel blade before low temperature aluminizing - Google Patents
Chemical removing technology for composite coating of aircraft engine steel blade before low temperature aluminizing Download PDFInfo
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- CN1136336C CN1136336C CNB991146131A CN99114613A CN1136336C CN 1136336 C CN1136336 C CN 1136336C CN B991146131 A CNB991146131 A CN B991146131A CN 99114613 A CN99114613 A CN 99114613A CN 1136336 C CN1136336 C CN 1136336C
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- Prior art keywords
- blade
- solution
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- water
- low temperature
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 13
- 239000010959 steel Substances 0.000 title claims abstract description 13
- 238000000576 coating method Methods 0.000 title claims description 29
- 239000011248 coating agent Substances 0.000 title claims description 28
- 238000005269 aluminizing Methods 0.000 title claims description 14
- 239000000126 substance Substances 0.000 title abstract description 8
- 238000005516 engineering process Methods 0.000 title description 3
- 239000002131 composite material Substances 0.000 title description 2
- 238000000034 method Methods 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 20
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 18
- 239000012528 membrane Substances 0.000 claims description 17
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 14
- 229910001220 stainless steel Inorganic materials 0.000 claims description 14
- 239000010935 stainless steel Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 11
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 10
- 239000003637 basic solution Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000008399 tap water Substances 0.000 claims description 9
- 235000020679 tap water Nutrition 0.000 claims description 9
- 235000010344 sodium nitrate Nutrition 0.000 claims description 8
- 239000004317 sodium nitrate Substances 0.000 claims description 8
- 229940001516 sodium nitrate Drugs 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- 235000010333 potassium nitrate Nutrition 0.000 claims description 7
- 239000004323 potassium nitrate Substances 0.000 claims description 7
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 5
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 5
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims description 5
- 229940039790 sodium oxalate Drugs 0.000 claims description 5
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 5
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 5
- 229940038773 trisodium citrate Drugs 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 2
- 238000000861 blow drying Methods 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- 238000011010 flushing procedure Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 238000002161 passivation Methods 0.000 abstract description 3
- 229910052909 inorganic silicate Inorganic materials 0.000 abstract description 2
- 231100000989 no adverse effect Toxicity 0.000 abstract description 2
- -1 sodium (potassium) hydroxide sodium (potassium) nitrate Chemical compound 0.000 abstract 2
- 229920006254 polymer film Polymers 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910000926 A-3 tool steel Inorganic materials 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910015372 FeAl Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000005480 shot peening Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
Landscapes
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
The present invention proposes a scheme for removing a low-temperature aluminized layer of an engine steel blade by a chemical method. A removal solution prepared from sodium (potassium) hydroxide sodium (potassium) nitrate, potassium permanganate and organic acid salt is used in the scheme. The solution can rapidly remove the aluminized layer, cause the passivation of the aluminized layer and a basal body of a basal body division point, rapidly break a-Si-O-Si-bond in a polymer film layer of inorganic silicate and damage or dissolve the film layer. The process is characterized in that a blade only needs to be immersed in the solution for several minutes, cleanly washed in clear water and dried or blow-dried. The scheme has the advantages of labor saving, time saving and no adverse effect on base materials.
Description
Technical field:
The present invention relates to a kind of chemistry and remove the production method of steel blade of aircraft engine low temperature aluminizing compound coating.
Background technology:
Engine steel blade compound coating is to add the modified Portland ceramic topcoats by the low temperature aluminizing layer to constitute.The chemical ingredients of low temperature aluminizing layer mainly is Fe
2Al
5And FeAl
3Detection shows that the thickness of aluminized coating is about 12 μ m.In matrix 11 μ m depths, Al concentration reaches 6% generally speaking, and is high more near surfaces A l concentration more, upper layer is up to 68%, and 16-20 μ m depths begins to be the composition of base material own under matrix, and therefore, whole aluminized coating is to be rich in Al, Cr the Fe base from chemical ingredients.
Modified Portland salt ceramic topcoats then is on the aluminized coating surface, be coated with equably or the silicate of about 2～6 μ m of spray one bed thickness, and form-Si-O-Si-key inorganic polymer rete through dehydration, as the important mechanical barrier in compound coating surface, closely be attached to aluminized coating and provide the abrasion resistance energy it.
But,, do not see that but bibliographical information crosses chemical removal method to a kind of like this compound coating.Some production unit adopts mechanical polishing or abrasive paper for metallograph manual grinding, and the unit that also has adopts the mechanical means of blast, shot-peening and so on.But it is big that such method exists labour intensity, and efficient is low, the uppity drawback of matrix size, and the utmost point does not fit into batch process, the batch process when particularly the band coating part is reprocessed.Therefore, the part of whole complete method when the removal of research low temperature aluminizing compound coating is not only the production process floating coat and is reprocessed, and be to solve the requisite important procedure that blade at first will run in overhauling.
Summary of the invention:
Task of the present invention is that development is a kind of in the chemical process of effectively removing low temperature aluminizing compound coating on the blade under the prerequisite of not damaging the steel blade of aircraft engine matrix.
Method of the present invention has been finished above-mentioned design objective preferably, it is characterized in that it being to cause the body material passivation with a kind of, and can remove the method for the chemical cleaning solution removal blade surface compound coating of low temperature aluminizing compound coating more up hill and dale.The chemical cleaning solution that uses in method is a kind of alkaline cleaning fluid, and its compound method is as follows:
One, preparation basic solution
Prescription is as follows by heavy part:
Sodium hydroxide or potassium hydroxide 30～200
SODIUMNITRATE or saltpetre 20～100
Potassium permanganate 10～60
Sodium oxalate or Trisodium Citrate 1～20
Water 620～939
Two, the compound method of this basic solution is:
In molten device, add 500 parts of tap water earlier, add sodium oxalate or Trisodium Citrate by formulation selection again, add SODIUMNITRATE or saltpetre while hot after stirring, dissolve evenly, treat to add potassium permanganate after solution is cooled to room temperature, stir, adding water to gross weight is 1000 parts, promptly obtains required basic solution after mixing;
Three, clean the working method of removing compound coating:
But in a steam heating or electrically heated, and the enough solution of preparation in the steel tank of band exhausting system, cleaning solution is heated to 80～100 ℃, pack into the stainless steel basket and to be with the blade of aluminized coating, and hang in the solution of heating, kept 5～10 minutes, the stainless steel basket is hung out, directly immerse in the tap water and wash down, and then with the hot water injection who is not less than 60 ℃.
This solution has not only reached can remove aluminized coating fast, causes the matrix passivation at aluminized coating and matrix dividing point, also can be apace under the effect of oxygenant with in the inorganic silicate macromolecule membranous layer-the Si-O-Si-key interrupts, destroys or the dissolving rete.Here it is, and this chemical method is removed the compound mechanism of removing layer.This chemical process is removed the advantage of compound coating method, and being only needs blade dipping several minutes in the solution of regulation, and water is rinsed well, dried and get final product again, and is time saving and energy saving, and base material is had no adverse effect.
Remove more thoroughly in order to make the aluminized coating on the blade, the present invention also is included in after the basic solution membrane removal processing, further remove the membrane method that removes that residues in the blade surface reactant with a kind of membrane removal liquid, just in the vanes aqueous slkali soaking, after chemically composited coating breaks away from from the blade matrix, wash the reactant that blade surface produces with membrane removal liquid again, it is characterized in that:
One, the membrane removal liquid formula is as follows by weight:
Sodium hydroxide or potassium hydroxide 10～60
SODIUMNITRATE or saltpetre 5～30
Tripoly phosphate sodium STPP 10～20
Water 890～975
Two, the method for preparation membrane removal liquid is as follows:
Earlier in a certain amount of water, add tripoly phosphate sodium STPP, add other two kinds of pharmaceutical chemicalss after the dissolving more respectively by the prescription share, no matter successively, add water to again after being dissolved in water evenly 1000 parts standby.
Three, membrane removal working method:
At a constant voltage is 12V, and anodic current is the 3-6A/ decimetre
2Condition under blade is connected on the anode, negative electrode adopts stainless steel plate, the stainless steel plate area is 1: 1 with the ratio of blade area, solution is heated to 40～60 ℃, blade is immersed in the solution, soak and take out blade after 1～3 minute, rinse well in being not less than 60 ℃ hot water, compressed air blow drying gets final product.
The present invention adopts the alkaline solution that contains strong oxidizing property that aluminising composite cementation coating on the blade is removed, and has guaranteed that blade matrix size and intensity are all unaffected, for the reliability, advance, the operability that guarantee repeatedly aluminizing method have been made significant contribution.
Embodiment:
Enumerate embodiment below:
Example 1:
In stainless steel vessel, add the 500kg tap water, add the 5kg sodium oxalate again, 40kg sodium hydroxide, stirring, add while hot after the dissolving evenly SODIUMNITRATE 20kg treats that solution is cooled to and adds 20kg potassium permanganate after the room temperature and stir, adding water to gross weight is 1000kg, promptly gets needed 1000kg basic solution after mixing.
This solution is injected in the A3 steel tank, be heated to 80 ℃, pack into the stainless steel basket and overhaul blade, and be immersed in the solution of heating and flooded 6 minutes, hang out, immerse in the tap water and wash, and then with the hot water injection who is not less than 60 ℃, and dry up with pressurized air.
Example 2:
One, in being arranged, the A3 steel tank of electric heating tube and exhausting system prepares basic cleaning solution.In channel-section steel, inject the 500kg tap water earlier, add the 20kg Trisodium Citrate again, treat that its dissolving back adds potassium hydroxide 180kg, add saltpetre 100kg while hot after stirring, dissolving, stir, add 40kg potassium permanganate after being chilled to room temperature, add water 160kg, promptly make the 1000kg alkaline cleaning fluid after the dissolving evenly.Standby.
Two, preparation anode membrane removal liquid in can heating stainless steel tank.Inject the 500kg tap water earlier, add tripoly phosphate sodium STPP 20kg, add potassium hydroxide 50kg and SODIUMNITRATE 20kg after the dissolving again, add water 410kg and fully stir, promptly make 1000kg anode membrane removal liquid after the dissolving.
Three, remove the compound coating operation.With the blade stainless steel basket of packing into, and hang in that submergence hung out after 8 minutes in the thermokalite scavenging solution that is heated to 100 ℃, directly immerse in the tap water and clean, and then with 60 ℃ hot water injection, and enter down the road and remove membrane process.
Four, anode removes membrane operations.At constant voltage is 12V, and d.c. anode current is 5A/dm
2Condition under, blade is connected on the anode, the anode stainless steel plate, blade is 1: 1 with the ratio of anode stainless steel plate area.Blade and stainless steel plate are immersed in immersion taking-up after 3 minutes in the anode membrane removal liquid that is heated to 50 ℃, and rinse well in 65 ℃ hot water, pressurized air dries up, and has promptly finished the thorough removing technology to the low temperature aluminizing compound coating.
Claims (4)
1, steel blade of aircraft engine low temperature aluminizing compound coating chemistry removal method, it is characterized in that to heat and being with the enough basic cleaning solution of the interior preparation of steel tank of exhausting system, solution is heated to 80～100 ℃, pack into the stainless steel basket and to be with the blade of aluminized coating, and immerse flood in the solution be heated to said temperature 5～10 minutes, hang out, immerse in the tap water and wash, use the hot water injection who is not less than 60 ℃ after the flushing again, and dry up with pressurized air
The prescription of use therein basic solution is as follows by weight:
Sodium hydroxide or potassium hydroxide 30～200
SODIUMNITRATE or saltpetre 20～100
Potassium permanganate 10～60
Sodium oxalate or Trisodium Citrate 1～20
Water 620～939.
2, steel blade of aircraft engine low temperature aluminizing compound coating chemistry removal method as claimed in claim 1, it is characterized in that with thermokalite solution soaking blade, the collocation method of this basic solution is: add 500 parts of tap water earlier in container, add sodium oxalate or Trisodium Citrate by formulation selection again, stir, add SODIUMNITRATE or saltpetre while hot after the dissolving evenly, treat to add potassium permanganate after solution is cooled to room temperature, stir, add water to 1000 parts, promptly get required basic solution after mixing.
3, steel blade of aircraft engine low temperature aluminizing compound coating chemistry removal method as claimed in claim 1, it is characterized in that, after with above-mentioned basic solution decoating, further the reactant that will residue in blade surface with a kind of membrane removal liquid is thoroughly disposed, and this membrane removal liquid formula is as follows by weight:
Sodium hydroxide or potassium hydroxide 10～60
SODIUMNITRATE or saltpetre 5～30
Tripoly phosphate sodium STPP 10～20
Water 890～975.
4, steel blade of aircraft engine low temperature aluminizing compound coating chemistry removal method as claimed in claim 3 is characterized in that the compound method that adopts membrane removal liquid to clean is as follows:
In 500 parts water, add tripoly phosphate sodium STPP earlier, add other two kinds of pharmaceutical chemicalss after the dissolving more respectively,, add water to gross weight after the dissolving evenly and promptly get membrane removal liquid for 1000 parts no matter successively by the prescription share,
The membrane removal working method:
At a constant voltage is 12V, and anodic current is 3-6A/dm
2Condition under blade is connected on the anode, negative electrode adopts stainless steel plate, the stainless steel plate area is 1: 1 with the blade area ratio, solution is heated to 40～60 ℃, blade handled take out blade after 1～3 minute, rinse well in being not less than 60 ℃ hot water, compressed air blow drying gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991146131A CN1136336C (en) | 1999-01-12 | 1999-01-12 | Chemical removing technology for composite coating of aircraft engine steel blade before low temperature aluminizing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991146131A CN1136336C (en) | 1999-01-12 | 1999-01-12 | Chemical removing technology for composite coating of aircraft engine steel blade before low temperature aluminizing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1227280A CN1227280A (en) | 1999-09-01 |
| CN1136336C true CN1136336C (en) | 2004-01-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991146131A Expired - Fee Related CN1136336C (en) | 1999-01-12 | 1999-01-12 | Chemical removing technology for composite coating of aircraft engine steel blade before low temperature aluminizing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1136336C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10377968B2 (en) | 2017-06-12 | 2019-08-13 | General Electric Company | Cleaning compositions and methods for removing oxides from superalloy substrates |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8876978B2 (en) * | 2008-02-14 | 2014-11-04 | Mitsubishi Heavy Industries, Ltd. | Method for regenerating gas turbine blade and gas turbine blade regenerating apparatus |
| CN102431269B (en) * | 2011-09-29 | 2014-07-23 | 上海联净电子科技有限公司 | Technology and device for processing film-coated iron |
| CN102766867B (en) * | 2012-08-15 | 2014-08-27 | 中国南方航空工业(集团)有限公司 | Method for removing NiAl/AlSi coatings |
| CN110230064A (en) * | 2019-05-09 | 2019-09-13 | 航天精工股份有限公司 | A kind of solution and method stripping molybdenum disulfide coating and aluminized coating |
| CN116005165A (en) * | 2022-12-23 | 2023-04-25 | 中国航发北京航空材料研究院 | Method for removing powder embedded aluminized coating on surface of nickel-based superalloy |
-
1999
- 1999-01-12 CN CNB991146131A patent/CN1136336C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10377968B2 (en) | 2017-06-12 | 2019-08-13 | General Electric Company | Cleaning compositions and methods for removing oxides from superalloy substrates |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1227280A (en) | 1999-09-01 |
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