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CN112284836A - Plasma tail gas sampling pretreatment system - Google Patents

Plasma tail gas sampling pretreatment system Download PDF

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Publication number
CN112284836A
CN112284836A CN202011124558.2A CN202011124558A CN112284836A CN 112284836 A CN112284836 A CN 112284836A CN 202011124558 A CN202011124558 A CN 202011124558A CN 112284836 A CN112284836 A CN 112284836A
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CN
China
Prior art keywords
sampling
pipe
pretreatment system
cooling water
filter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011124558.2A
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Chinese (zh)
Inventor
吴冬琴
李要建
杨帆
曹德标
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Tianying Plasma Technology Co Ltd
Jiangsu Tianying Environmental Protection Energy Equipment Co Ltd
Original Assignee
Jiangsu Tianying Plasma Technology Co Ltd
Jiangsu Tianying Environmental Protection Energy Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Jiangsu Tianying Plasma Technology Co Ltd, Jiangsu Tianying Environmental Protection Energy Equipment Co Ltd filed Critical Jiangsu Tianying Plasma Technology Co Ltd
Priority to CN202011124558.2A priority Critical patent/CN112284836A/en
Publication of CN112284836A publication Critical patent/CN112284836A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/2202Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling
    • G01N1/2205Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling with filters
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/2247Sampling from a flowing stream of gas
    • G01N1/2258Sampling from a flowing stream of gas in a stack or chimney
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/2247Sampling from a flowing stream of gas
    • G01N1/2258Sampling from a flowing stream of gas in a stack or chimney
    • G01N2001/2261Sampling from a flowing stream of gas in a stack or chimney preventing condensation (heating lines)

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The invention discloses a plasma tail gas sampling pretreatment system which comprises a sampling probe, a connecting pipeline, a smoke dust filter, a sampling pipe, a quantitative dilution device and a ball valve, wherein the sampling probe is provided with a water cooling device, the outlet end of the sampling probe is connected with one end of the connecting pipeline, the other end of the connecting pipeline is connected with the air inlet of the smoke dust filter, the air outlet of the smoke dust filter is connected with one end of the sampling pipe, the quantitative dilution device is sequentially arranged on the sampling pipe, and the ball valve is arranged on the sampling pipe. The system can be normally used in a plasma melting furnace and a high-temperature flue, the temperature of a cooling water outlet is kept at about 120 ℃, so that sulfur dioxide and hydrogen chloride gas are not condensed, and meanwhile, the system can be normally used under the working conditions of high dust and high concentration, so that the situation that smoke dust blocks a sampling pipeline in the sampling process is avoided, and the purpose of continuous sampling is achieved.

Description

Plasma tail gas sampling pretreatment system
Technical Field
The invention relates to a tail gas sampling pretreatment system, in particular to a plasma tail gas sampling pretreatment system, and belongs to the field of tail gas sampling.
Background
A large amount of fly ash can be generated in the incineration process of household garbage and solid hazardous waste, wherein the main components are chloride, and pollutants such as dioxin, heavy metal and the like with high concentration are contained, the toxicity of the pollutants has certain threat to the environment, and the pollutants belong to hazardous waste. At present, the traditional methods for treating the fly ash comprise solidification/stabilization, chemical treatment, acid extraction technology, landfill method and the like, and the plasma high-temperature melting treatment technology can thoroughly destroy organic pollutants such as dioxin, furan and the like in the fly ash and change heavy metals in the fly ash into molten slag for effective utilization. The concentrations of heavy metals, CO, HCl, SO2 and the like in tail gas generated in the fly ash melting process are high. The concentration condition of the tail gas needs to be monitored in real time, the process is subjected to pre-control, the concentration condition of the tail gas treatment process is fed back in time, and the operation cost is reduced. The sampling monitoring device on the market at present has lower range and can not be suitable for severe working conditions, such as high temperature, high dust and high concentration tail gas.
In the operation process of the traditional tail gas treatment process, the tail gas treatment condition is monitored through the concentration of tail gas emission, the concentration of the tail gas changes in real time, and only the tail end emission concentration is used for judging that the treatment agent in the middle process is excessively wasted and the treatment does not reach the standard, so that the feedback delay is caused. The tail gas monitoring is carried out in the plasma furnace or the high-temperature flue, the concentration condition of the tail gas can be fed back in time, the addition amount of the medicament in the tail gas treatment process is guided, and the condition of excessive medicament or delayed feedback is avoided.
Disclosure of Invention
The invention aims to provide a plasma tail gas sampling pretreatment system, which realizes tail gas monitoring in a plasma furnace or a high-temperature flue.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows:
a plasma tail gas sampling pretreatment system is characterized in that: contain sampling probe, connecting line, smoke and dust filter, sampling tube, quantitative diluting device and ball valve, sampling probe is provided with water cooling plant and sampling probe's exit end is connected with connecting line's one end, and connecting line's the other end is connected with smoke and dust filter's air inlet, and smoke and dust filter's gas outlet is connected with the one end of sampling tube, and quantitative diluting device sets gradually on the sampling tube, and the ball valve setting is on the sampling tube.
Furthermore, the sampling probe comprises a water cooling device and a connector, the water cooling device comprises an inner pipe, a middle pipe and an outer pipe, the middle pipe is sleeved outside the inner pipe, the middle pipe and the inner pipe are coaxially arranged, one end part of the middle pipe and one end part of the inner pipe are mutually sealed and connected, an internal cooling water flow passage is formed between the inner wall of the middle pipe and the outer wall of the inner pipe, the outer pipe is sleeved outside the middle pipe, the outer pipe and the middle pipe are coaxially arranged, one end part of the outer pipe and the other end part of the inner pipe are mutually sealed and connected, an external cooling water flow passage is formed between the inner wall of the outer pipe and the outer wall of the middle pipe, a gap is reserved between the other end part of the middle pipe and the connection part of the outer pipe and the inner pipe to enable the internal cooling water flow passage, the outer side of one end of the middle pipe is provided with a cooling water outlet which is communicated with an internal cooling water flow channel, and one end of the connector is fixedly connected with the connecting part of the inner pipe and one end of the middle pipe and is communicated with the inner pipe.
Further, a temperature sensor is arranged on the side surface of the cooling water outlet and used for monitoring the temperature of the cooling water at the position of the cooling water outlet in real time.
Furthermore, the smoke filter comprises a filter cylinder, a cover plate and a filter medium, wherein the cover plate is fixed at the upper end of the filter cylinder, an air inlet is formed in the upper side of the cover plate, an air outlet is formed in the lower end of the filter cylinder, and the filter medium is arranged in the accommodating cavity of the filter cylinder.
Further, an air outlet at the lower end of the filter cylinder is fixedly connected with one end of the sampling tube through a pipeline connector.
Furthermore, a box door capable of being opened and closed is arranged on the side surface of the filter cylinder body.
Further, the filter medium is made of quartz wool.
Further, the air inlet contains intake pipe and panel, and the intake pipe is fixed in the middle of the panel, and open around the panel have with the screw that the filter cylinder body apron matches, the panel passes through the bolt locking to be fixed on the apron.
Further, the quantitative dilution device comprises a dilution gas pipeline, a manual ball valve and a rotor flow meter, one end of the dilution gas pipeline is fixed on the side face of the sampling tube and communicated with the sampling tube, and the manual ball valve and the rotor flow meter are respectively arranged on the dilution gas pipeline.
Further, a thermometer is arranged on the side surface of the sampling tube.
Compared with the prior art, the invention has the following advantages and effects:
1. the system can be normally used in a plasma melting furnace and a high-temperature flue, the temperature of a cooling water outlet is kept at about 120 ℃, so that sulfur dioxide and hydrogen chloride gas are not condensed, and the system can be normally used under the working conditions of high dust and high concentration, so that the smoke dust is prevented from blocking a sampling pipeline in the sampling process, and the aim of continuous sampling is fulfilled;
2. the invention adopts three layers of water cooling sleeves and an external smoke filter, and can simultaneously solve the problems of high-temperature melting and burning of the sampling tube, high dust blockage and incapability of ensuring the condensation of hydrogen chloride and sulfur dioxide;
3. the tail gas treatment and regulation system is simple in structure, simple and convenient to operate and low in cost, and solves the problem of operation cost waste caused by slow feedback of the tail gas treatment and regulation process in the fly ash fusion operation process in the project operation process.
Drawings
FIG. 1 is a schematic diagram of a plasma tail gas sampling pretreatment system of the present invention.
FIG. 2 is a schematic view of a sampling probe of the present invention.
FIG. 3 is a schematic view of a soot filter of the present invention.
FIG. 4 is a schematic view of a quantitative dilution apparatus of the present invention.
Detailed Description
To elaborate on technical solutions adopted by the present invention to achieve predetermined technical objects, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention, it is obvious that the described embodiments are only partial embodiments of the present invention, not all embodiments, and technical means or technical features in the embodiments of the present invention may be replaced without creative efforts, and the present invention will be described in detail below with reference to the drawings and in conjunction with the embodiments.
As shown in figure 1, the plasma tail gas sampling pretreatment system comprises a sampling probe 1, a connecting pipeline 2, a soot filter 3, a sampling pipe 4, a quantitative dilution device 5 and a ball valve 6, wherein the sampling probe 1 is provided with a water cooling device, the outlet end of the sampling probe 1 is connected with one end of the connecting pipeline 2, the other end of the connecting pipeline 2 is connected with the air inlet of the soot filter 3, the air outlet of the soot filter 3 is connected with one end of the sampling pipe 4, the quantitative dilution device 5 is sequentially arranged on the sampling pipe 4, and the ball valve 6 is arranged on the sampling pipe 4. The water cooling device on the sampling probe cools the flue gas, and the problem of high temperature resistance of the sampling tube is effectively solved, and meanwhile, the service life of rear-end sampling equipment is ensured. The smoke dust filter prevents the smoke dust from being too much to cause the blockage of the sampling pipeline. The sampling is carried out in the furnace, and the filtering is carried out outside the furnace, so that the operation and maintenance process is more convenient and faster. 6 manual ball valves of stainless steel of ball valve for manual termination sampling process, threaded connection stainless steel sampling tube is passed through to the rear end, can match the sampling equipment of different brands and use, and through later stage reducing design, the sampling tube of different specifications can be connected simultaneously.
As shown in fig. 2, the sampling probe 1 includes a water cooling device and a connector, the water cooling device includes an inner tube 7, a middle tube 8 and an outer tube 9, the middle tube 8 is sleeved outside the inner tube 7 and the middle tube 8 and the inner tube 7 are coaxially arranged, one end of the middle tube 8 and one end of the inner tube 7 are hermetically connected, an internal cooling water channel 10 is formed between the inner wall of the middle tube 8 and the outer wall of the inner tube 7, the outer tube 9 is sleeved outside the middle tube 8 and the outer tube 9 and the middle tube 8 are coaxially arranged, one end of the outer tube 9 and the other end of the inner tube 7 are hermetically connected, an external cooling water channel 11 is formed between the inner wall of the outer tube 9 and the outer wall of the middle tube 8, and a gap is left between the other end of the middle tube 8 and the connecting portion between the outer tube 9 and the inner tube 7, so that the internal cooling water channel 10 and the external cooling water channel 11 are 11, a cooling water outlet 13 is arranged at the outer side of one end of the middle pipe 8, the cooling water outlet 13 is communicated with the internal cooling water flow channel 10, one end of the connector is fixedly connected with the connecting part of the inner pipe 7 and one end of the middle pipe 8, and the connector is communicated with the inner pipe 7. The side of the cooling water outlet 13 is provided with a temperature sensor 14 for monitoring the temperature of the cooling water at the position of the cooling water outlet in real time.
As shown in fig. 3, the soot filter includes a filter cylinder 15, a cover plate 16 and a filter medium 17, the cover plate 16 is fixed on the upper end of the filter cylinder 15, the upper side of the cover plate 16 is provided with an air inlet, the lower end of the filter cylinder 15 is provided with an air outlet, and the filter medium 17 is arranged in the cavity of the filter cylinder 15. The air outlet at the lower end of the filter cylinder 15 is fixedly connected with one end of the sampling tube 4 through a pipeline connector 18. The side of the filter cylinder 15 is provided with a door 19 which can be opened and closed. The filter medium 17 is made of quartz wool. The air inlet contains intake pipe 20 and panel 21, and intake pipe 20 is fixed in the middle of panel 21, and panel 21 is opened all around has the screw that matches with filter cylinder body apron 16, and panel 21 passes through bolt locking to be fixed on apron 16. And (3) checking the air tightness of the sectional inspection device before sampling the tail gas every time and replacing quartz wool in the smoke dust filter.
As shown in fig. 4, the quantitative dilution device comprises a dilution gas pipeline 22, a manual ball valve 23 and a rotameter 24, one end of the dilution gas pipeline 22 is fixed on the side surface of the sampling tube 4 and communicated with the sampling tube 4, the manual ball valve 23 and the rotameter 24 are respectively arranged on the dilution gas pipeline 22, the flow is adjusted through the manual ball valve 23, the manual ball valve is opened to introduce dilution gas, and the introduction time is accumulated to achieve the purpose of quantitatively and previously diluting flue gas. If the tail gas concentration exceeds the measuring range in the sampling detection process, the rotor flow meter is adjusted, the manual ball valve 23 is opened, and the diluent gas is quantitatively introduced. The side surface of the sampling tube 4 is provided with a thermometer 25, the thermometer is arranged at the tail gas outlet at the rear end of the soot filter, and the tail gas sampling temperature is controlled by adjusting the water flow rate of the water cooling device. And (3) observing the temperature in the thermometer in the sampling process, regulating the flow speed of circulating water to be small if the temperature is lower than 120 ℃, and keeping the outlet temperature of cooling water to be about 120 ℃ so that sulfur dioxide and hydrogen chloride gas are not condensed.
Although the present invention has been described with reference to a preferred embodiment, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (10)

1. A plasma tail gas sampling pretreatment system is characterized in that: contain sampling probe, connecting line, smoke and dust filter, sampling tube, quantitative diluting device and ball valve, sampling probe is provided with water cooling plant and sampling probe's exit end is connected with connecting line's one end, and connecting line's the other end is connected with smoke and dust filter's air inlet, and smoke and dust filter's gas outlet is connected with the one end of sampling tube, and quantitative diluting device sets gradually on the sampling tube, and the ball valve setting is on the sampling tube.
2. A plasma exhaust sampling pretreatment system according to claim 1, characterized in that: the sampling probe comprises a water cooling device and a connector, the water cooling device comprises an inner pipe, a middle pipe and an outer pipe, the middle pipe is sleeved outside the inner pipe and is coaxially arranged with the inner pipe, one end part of the middle pipe and one end part of the inner pipe are mutually sealed and connected, an internal cooling water flow passage is formed between the inner wall of the middle pipe and the outer wall of the inner pipe, the outer pipe is sleeved outside the middle pipe and is coaxially arranged with the middle pipe, one end part of the outer pipe and the other end part of the inner pipe are mutually sealed and connected, an external cooling water flow passage is formed between the inner wall of the outer pipe and the outer wall of the middle pipe, a gap is reserved between the other end part of the middle pipe and the connection part of the outer pipe and the inner pipe to enable the internal cooling water flow passage to be communicated with the external cooling water flow passage, the other end of the outer pipe is sealed and fixed on, one end of the connector is fixedly connected with the connecting part of one end of the inner pipe and one end of the middle pipe, and the connector is communicated with the inner pipe.
3. A plasma exhaust sampling pretreatment system according to claim 2, wherein: and a temperature sensor is arranged on the side surface of the cooling water outlet and used for monitoring the temperature of the cooling water at the position of the cooling water outlet in real time.
4. A plasma exhaust sampling pretreatment system according to claim 1, characterized in that: the smoke filter comprises a filter cylinder, a cover plate and a filter medium, wherein the cover plate is fixed at the upper end of the filter cylinder, an air inlet is formed in the upper side of the cover plate, an air outlet is formed in the lower end of the filter cylinder, and the filter medium is arranged in a containing cavity of the filter cylinder.
5. A plasma exhaust sampling pretreatment system according to claim 4, characterized in that: and the air outlet at the lower end of the filter cylinder body is fixedly connected with one end of the sampling tube through a pipeline connector.
6. A plasma exhaust sampling pretreatment system according to claim 4, characterized in that: the side surface of the filter cylinder body is provided with a box door which can be opened and closed.
7. A plasma exhaust sampling pretreatment system according to claim 4, characterized in that: the filter medium is made of quartz wool.
8. A plasma exhaust sampling pretreatment system according to claim 4, characterized in that: the air inlet contains intake pipe and panel, and the intake pipe is fixed in the middle of the panel, and the panel is opened all around has the screw that matches with filter cylinder body apron, and the panel passes through the bolt locking to be fixed on the apron.
9. A plasma exhaust sampling pretreatment system according to claim 1, characterized in that: the quantitative dilution device comprises a dilution gas pipeline, a manual ball valve and a rotor flow meter, one end of the dilution gas pipeline is fixed on the side face of the sampling tube and communicated with the sampling tube, and the manual ball valve and the rotor flow meter are respectively arranged on the dilution gas pipeline.
10. A plasma exhaust sampling pretreatment system according to claim 1, characterized in that: the thermometer is arranged on the side surface of the sampling tube.
CN202011124558.2A 2020-10-20 2020-10-20 Plasma tail gas sampling pretreatment system Pending CN112284836A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011124558.2A CN112284836A (en) 2020-10-20 2020-10-20 Plasma tail gas sampling pretreatment system

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Application Number Priority Date Filing Date Title
CN202011124558.2A CN112284836A (en) 2020-10-20 2020-10-20 Plasma tail gas sampling pretreatment system

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Publication Number Publication Date
CN112284836A true CN112284836A (en) 2021-01-29

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CN202011124558.2A Pending CN112284836A (en) 2020-10-20 2020-10-20 Plasma tail gas sampling pretreatment system

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102101016A (en) * 2009-11-18 2011-06-22 株式会社堀场制作所 Method for refining dilution air and dilution air refinery
CN202582956U (en) * 2012-04-13 2012-12-05 中国矿业大学 High-temperature and high-dust gas and ash content sampling device
CN104075913A (en) * 2014-07-17 2014-10-01 北京航空航天大学 Dilution sampling device for PM2.5 discharged by stationary pollution source
CN104458352A (en) * 2014-12-22 2015-03-25 天津水泥工业设计研究院有限公司 Large-flow sampling device for industrial flue gas particulate matters
CN105709622A (en) * 2016-01-29 2016-06-29 北京航空航天大学 Small ejector and particulate matter dilution acquisition system
CN109781474A (en) * 2018-12-26 2019-05-21 西安交通大学 A kind of sampling of high-temperature flue gas particle and measuring device and its application method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102101016A (en) * 2009-11-18 2011-06-22 株式会社堀场制作所 Method for refining dilution air and dilution air refinery
CN202582956U (en) * 2012-04-13 2012-12-05 中国矿业大学 High-temperature and high-dust gas and ash content sampling device
CN104075913A (en) * 2014-07-17 2014-10-01 北京航空航天大学 Dilution sampling device for PM2.5 discharged by stationary pollution source
CN104458352A (en) * 2014-12-22 2015-03-25 天津水泥工业设计研究院有限公司 Large-flow sampling device for industrial flue gas particulate matters
CN105709622A (en) * 2016-01-29 2016-06-29 北京航空航天大学 Small ejector and particulate matter dilution acquisition system
CN109781474A (en) * 2018-12-26 2019-05-21 西安交通大学 A kind of sampling of high-temperature flue gas particle and measuring device and its application method

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Application publication date: 20210129

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