CN111936612A - Reactor and apparatus for anaerobic digestion - Google Patents
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Abstract
Description
技术领域technical field
本发明总体上涉及伴随有沼气回收的有机基质的厌氧生物降解的系统和方法。特别地,本发明涉及用于有机基质的干式厌氧消化的连续搅拌的水平反应器、以及包含所述反应器(或多个反应器)的设备设施。The present invention generally relates to systems and methods for anaerobic biodegradation of organic substrates with biogas recovery. In particular, the present invention relates to continuously stirred horizontal reactors for dry anaerobic digestion of organic substrates, and plant facilities comprising said reactor (or reactors).
背景技术Background technique
厌氧消化(AD)是由产甲烷菌分解有机物的复杂过程,在包括农业和工业废弃物处理在内的各种生物炼制技术中已经被减少使用。在所有情况下,厌氧消化还伴随着沼气的产生,沼气被进一步升级以生产出生物燃料。Anaerobic digestion (AD), the complex process of decomposing organic matter by methanogens, has been reduced in use in various biorefinery technologies including agricultural and industrial waste treatment. In all cases, anaerobic digestion is also accompanied by the production of biogas, which is further upgraded to produce biofuels.
通常将两种类型的厌氧消化过程区分开来以便管理具有不同干物质(DM)含量的固态废弃物,这两种类型的厌氧消化过程分别被称为“湿式”(DM为5wt%至15wt%)和“干式”(DM为30wt%至55wt%)。与平均容量为2m3至4000m3的湿式消化器相比,具有平均容量为950m3至1000m3、可升级到约2000m3的干式消化器通常更紧凑。通常而言,任何厌氧消化器均可用于湿式过程和干式过程;然而,在实践中,装备被设计成满足由进料材料的选择和/或可用性、预期输出、可用场所等强加的特定要求。当用于废弃物处理时,干式消化的其他优点涉及承受相对不纯净的废弃物,即含有大量不可生物降解的物质;因此,在消化前对原料进行预处理和调整的费用可以降到最低。Two types of anaerobic digestion processes are generally distinguished in order to manage solid waste with different dry matter (DM) contents, and these two types of anaerobic digestion processes are referred to as "wet" (DM from 5 wt% to 15wt%) and "dry" (30wt% to 55wt% DM). Dry digesters with an average capacity of 950m 3 to 1000m 3 , upgradable to about 2000m 3 are generally more compact than wet digesters with an average capacity of 2m 3 to 4000m 3 . Generally speaking, any anaerobic digester can be used for both wet and dry processes; however, in practice, equipment is designed to meet specific requirements imposed by selection and/or availability of feed materials, expected output, available sites, etc. Require. Other advantages of dry digestion, when used for waste treatment, relate to the tolerance of relatively impure waste, i.e. containing substantial amounts of non-biodegradable material; therefore, the cost of pre-processing and conditioning the feedstock prior to digestion can be minimized .
常规的AD设备包括预处理设施、一个或多个消化器反应器以及若干后处理设施,后处理设施包括固体分离器和用于经消化的材料的卫生罐,以及使经消化的材料的一部分作为接种物返回到反应空间中的再循环器具。常见的反应器构型包括具有在大多数情况下为一个或多个壁结合式混合器的固定的穹顶形罐。以连续流通式基础操作的干式AD反应器通常被称为塞流式反应器,并且干式AD反应器被实施为具有入口和出口的水平延伸的窄罐,在该窄罐中,进料在沿着该罐的长度行进时被不断地分解。一些塞流式解决方案补充有呈带叶片的杆的形式的混合器或混合螺杆。Conventional AD equipment includes a pretreatment facility, one or more digester reactors, and several post-processing facilities, including a solids separator and sanitary tanks for digested material, and a portion of the digested material as a The inoculum is returned to the recirculation apparatus in the reaction space. Common reactor configurations include stationary dome-shaped tanks with, in most cases, one or more wall-bound mixers. Dry AD reactors operating on a continuous flow-through basis are often referred to as plug flow reactors, and are implemented as a horizontally extending narrow tank with an inlet and an outlet in which the feed is fed. It is continuously decomposed as it travels along the length of the tank. Some plug flow solutions are supplemented with mixers or mixing screws in the form of bladed rods.
干式厌氧消化——也被称为干发酵——由于以下原因而获得更多的优势。首先,废弃物部分的处理变得更具挑战性。一些废弃物管理措施禁止填埋有机废弃物;因此,由于存在大量杂质比如石头、沙子和泥土,意在用于回收的废弃物部分变得更干燥且更难以粉碎。有机废弃物的焚化是流行的解决方案,但它提供了较低的能量产量,并导致严重的烟道气体排放。另一方面,虽然干物质在一定程度上可以通过湿式厌氧消化方法来处理,但湿式厌氧消化方法不允许原料中存在大量杂质。Dry anaerobic digestion - also known as dry fermentation - has additional advantages for the following reasons. First, the disposal of the waste portion becomes more challenging. Some waste management measures prohibit landfilling of organic waste; therefore, the portion of waste intended for recycling becomes drier and more difficult to shred due to the presence of large amounts of impurities such as stones, sand and dirt. Incineration of organic waste is a popular solution, but it offers lower energy yields and leads to severe flue gas emissions. On the other hand, while dry matter can be handled to some extent by wet anaerobic digestion methods, wet anaerobic digestion methods do not allow the presence of large amounts of impurities in the feedstock.
然而,以连续流基础操作的干式厌氧消化器解决方案受到若干常见缺点的影响。在大多数情况下,从农业和市政来源获得的可生物降解的废弃物含有基本量的不易消化的固体,例如石头、沙子、玻璃和各种塑料,这在消化器中导致漂浮层和大量的沉积物。为了处理沉重的沉积物,美国专利No.8241869(Büchner等人)公开了一种以塞流式基础操作的干式厌氧发酵桶,该发酵桶以长形管状容器的形式提供,该容器具有构造成将沉积物朝向排放端部推动的交叠的搅拌叶片以及用于将固态沉积物从反应器经由额外的出口移除的抽吸插接部。但是,该解决方案无法解决轻质杂质的分离问题;因此将需要提供过滤站来处理富含塑料的废弃物流。However, dry anaerobic digester solutions operating on a continuous flow basis suffer from several common disadvantages. In most cases, biodegradable wastes obtained from agricultural and municipal sources contain substantial amounts of non-digestible solids such as stones, sand, glass and various plastics, which result in slicks and large amounts of plastic in the digester sediment. To handle heavy sediments, US Patent No. 8,241,869 (Büchner et al.) discloses a dry anaerobic fermenter operating on a plug-flow basis, provided in the form of an elongated tubular vessel having Overlapping stirring blades configured to push sediment towards the discharge end and a suction spigot for removing solid sediment from the reactor via an additional outlet. However, this solution does not address the separation of light impurities; therefore a filter station will be required to handle the plastic-rich waste stream.
另外,上述难以消化的基质(沙子、石头等)引起摩擦,因此,装备需要坚固的进料系统。In addition, the aforementioned indigestible substrates (sand, stones, etc.) cause friction, so the equipment requires a robust feeding system.
另外的挑战涉及在不损害其资本投资方面的经济可行性的前提下提高AD设备的容量。常规的解决方案包括:增加每个设备的反应罐的数量,这由于有限的面积而并非总是可能的;以及/或者提供传动装置,传动装置对材料的搅拌以及材料行进通过极长的反应器进行支撑。因此,根据美国专利no.7659108(Schmid)的示例性解决方案涉及用于检测及补偿水平厌氧发酵罐内——特别是长度超过50米的水平厌氧发酵罐内——的搅拌机杆下垂的器具。An additional challenge involves increasing the capacity of AD equipment without compromising its economic viability in terms of capital investment. Conventional solutions include: increasing the number of reaction tanks per device, which is not always possible due to limited area; and/or providing transmissions that agitate and travel the material through extremely long reactors support. Thus, an exemplary solution according to US patent no. 7659108 (Schmid) relates to detection and compensation of drooping of agitator bars in horizontal anaerobic fermenters, especially in horizontal anaerobic fermenters longer than 50 meters appliance.
此外,根据国家和欧盟对可生物降解原料的厌氧消化过程的标准和法规中规定的现有要求,包括第539/2006号《芬兰化肥产品法》和第24/11号《芬兰化肥产品法令》,以及针对非人类食用的动物副产品和派生产品实施的第1069/2009号法规(EC)的第142/2011号委员会法规(EU),AD过程产生的分解产物必须先经过净化,然后以肥料、堆肥或土壤改良剂的形式重新引入到生态系统中。在常规厌氧消化器设备中,这种净化在通常位于消化器反应器下游的单独设施中进行。In addition, according to existing requirements set out in national and EU standards and regulations for anaerobic digestion processes of biodegradable feedstocks, including Finnish Fertilizer Products Act No. 539/2006 and Finnish Fertilizer Products Act No. 24/11 , and Commission Regulation (EU) No. 142/2011 of Regulation (EC) No. 1069/2009 on animal by-products and derived products not intended for human consumption, that the decomposition products from the AD process must first be purified and then treated with fertilizers. , compost or soil amendments are reintroduced into the ecosystem. In conventional anaerobic digester plants, this purification is carried out in a separate facility, usually downstream of the digester reactor.
通常,装载到干式AD反应器的原料中的DM含量明显高于湿式过程中的DM含量。DM含量越高导致热传导率越低;因此,干式反应器必须有更强大的加热系统。湿式过程具有较高的能量消耗,并且为回收过程带来高成本。我们在此指出,尽管在干式发酵反应器中较高的DM含量不是必不可少的,但如果旨在用于干式处理的反应器装载有适合在(廉价)湿式AD设备中处理的原料材料,则干式发酵的益处将会丧失。Typically, the DM content in the feedstock loaded into the dry AD reactor is significantly higher than that in the wet process. Higher DM content results in lower thermal conductivity; therefore, the dry reactor must have a more powerful heating system. Wet processes have high energy consumption and bring high costs to the recycling process. We point out here that although higher DM content in dry fermentation reactors is not essential, if the reactors intended for dry processing are loaded with feedstocks suitable for processing in (cheap) wet AD plants material, the benefits of dry fermentation will be lost.
AD反应器的设置通常与(生物)气体的生产相关联。为了使所述气体生产最大化,需要在所有类型的消化过程中进行有效混合。由于原料的较高的固体含量,这依然是干式AD(发酵)反应器的一个挑战。The setup of an AD reactor is usually associated with the production of (bio)gas. To maximize the gas production, efficient mixing is required in all types of digestion processes. This remains a challenge for dry AD (fermentation) reactors due to the higher solids content of the feedstock.
在这方面,考虑到应对将AD技术作为固态废弃物管理系统的部分来应用的挑战,仍然需要对与适用于沼气生产的、水平且连续搅拌的反应器中的厌氧消化有关的技术进行修订,并且特别地,该技术与污染物的不理想去除、流出路径的堵塞、消化器中材料的无效混合和/或低沼气产量有关。In this regard, considering the challenges of applying AD technology as part of a solid waste management system, there is still a need to revise the technology related to anaerobic digestion in horizontal and continuously stirred reactors suitable for biogas production , and in particular, the technology is associated with suboptimal removal of pollutants, blockage of outflow paths, ineffective mixing of materials in the digester, and/or low biogas production.
发明内容SUMMARY OF THE INVENTION
本发明的目的是解决或至少减轻由相关技术的限制和缺点引起的每个问题。该目的通过用于可生物降解的有机基质的厌氧消化的反应器布置结构的各种实施方式及其相关用途来实现。因此,在本发明的一个方面,根据独立权利要求1中的所限定的内容,提供了一种用于可生物降解的有机基质的厌氧消化的反应器布置结构。It is an object of the present invention to solve or at least alleviate each of the problems caused by limitations and disadvantages of the related art. This object is achieved by various embodiments of reactor arrangements for the anaerobic digestion of biodegradable organic substrates and their associated uses. Accordingly, in one aspect of the present invention, according to what is defined in
在一个优选实施方式中,反应器包括:水平延伸的至少一个反应器罐,罐具有位于进入端部处的流入端口以及位于与进入端部相反的排放端部处的至少一个流出端口;纵向延伸的至少两个搅拌器,搅拌器并排布置在罐的内部;以及温度调整系统,温度调整系统配置成对反应器罐中的温度进行调节并且包括多个内部管,所述内部管构造成沿纵向方向横穿通过罐的侧向壁和/或基部并使温度调整流体沿着所述多个内部管输送。In a preferred embodiment, the reactor comprises: at least one reactor tank extending horizontally, the tank having an inflow port at the inlet end and at least one outflow port at the discharge end opposite the inlet end; longitudinally extending of at least two stirrers arranged side by side inside the tank; and a temperature regulation system configured to regulate the temperature in the reactor tank and including a plurality of inner tubes configured to longitudinally The direction traverses through the lateral walls and/or base of the tank and transports the temperature regulating fluid along the plurality of internal tubes.
在实施方式中,反应器布置结构构造成使可生物降解的有机基质沿着反应器罐的长度朝向排放端部输送,以使得:经消化的有机基质通过主流出端口从罐排放、以及难以消化的残留物通过至少一个辅助流出端口排放。In an embodiment, the reactor arrangement is configured such that the biodegradable organic substrate is transported along the length of the reactor tank towards the discharge end such that: the digested organic substrate is discharged from the tank through the main outlet port and is indigestible The residue is discharged through at least one auxiliary outflow port.
在实施方式中,沿纵向方向限定罐的内部的侧向壁是倾斜的,从而在侧向壁与底部之间的相交部处沿着罐的整个长度形成有一个或多个倾斜元件。在实施方式中,每个所述侧向壁包括大致平坦的一个或多个面板,所述一个或多个面板具有设置为单独模块的倾斜元件。In an embodiment, the lateral walls defining the interior of the can in the longitudinal direction are inclined such that one or more inclined elements are formed along the entire length of the can at the intersection between the lateral walls and the bottom. In an embodiment, each of said lateral walls comprises one or more panels that are substantially flat, said one or more panels having inclined elements arranged as separate modules.
在一些实施方式中,每个搅拌器包括驱动杆,驱动杆具有安装至驱动杆的若干叶片。在实施方式中,在搅拌器的驱动杆内部布置有下述内部管:该内部管构造成使温度调整流体沿着内部管输送。In some embodiments, each agitator includes a drive rod having several blades mounted to the drive rod. In an embodiment, an inner tube is arranged inside the drive rod of the agitator, the inner tube being configured to transport the temperature regulating fluid along the inner tube.
在一些实施方式中,布置在罐的侧向壁中的管内的温度状况以及布置在罐的基部中的管内的温度状况是能够独立调节的。In some embodiments, the temperature conditions in the tubes arranged in the lateral walls of the tank and the temperature conditions in the tubes arranged in the base of the tank are independently adjustable.
在实施方式中,反应器布置结构还包括具有至少一个进料供给器件的预处理设施,进料供给器件构造成将进入至少一个反应器罐的有机基质的温度调节成与所述罐中所保持的温度相符。In an embodiment, the reactor arrangement further comprises a pretreatment facility having at least one feed supply device configured to regulate the temperature of the organic substrate entering the at least one reactor tank to be consistent with that maintained in the tank temperature matches.
在一些实施方式中,反应器还包括用于对经消化的基质进行热净化的卫生系统。在实施方式中,所述卫生系统设置在布置于至少一个罐的下游的后处理设施中。In some embodiments, the reactor also includes a sanitation system for thermal purification of the digested substrate. In an embodiment, the sanitation system is provided in an aftertreatment facility arranged downstream of the at least one tank.
在替代实施方式中,卫生系统包括至少一个被封包的导管,导管构造成沿纵向方向横穿通过罐的侧向壁和/或基部并接纳通过主流出端口排放的经消化的基质。In an alternative embodiment, the sanitary system includes at least one enveloped conduit configured to traverse through the lateral wall and/or base of the tank in a longitudinal direction and to receive digested substrate discharged through the main outlet port.
在实施方式中,反应器布置结构还包括热回收和循环系统,热回收和循环系统配置成将在厌氧消化期间在至少一个罐中产生的热进行回收并将由此回收的热引导至预处理设施。In an embodiment, the reactor arrangement further comprises a heat recovery and circulation system configured to recover heat generated in the at least one tank during the anaerobic digestion and direct the recovered heat to the pretreatment facility.
在一些实施方式中,所述热回收和循环系统还配置成将所回收的热引导至温度调整系统以及可选地引导至卫生系统。In some embodiments, the heat recovery and circulation system is further configured to direct the recovered heat to a temperature regulation system and optionally to a sanitary system.
在实施方式中,热回收和循环系统包括至少一个热交换器单元,热交换器单元用于介导至少一个罐与预处理设施之间的热传递。In an embodiment, the heat recovery and circulation system includes at least one heat exchanger unit for mediating heat transfer between the at least one tank and the pretreatment facility.
在一些实施方式中,反应器布置结构包括挨着彼此布置的若干罐。In some embodiments, the reactor arrangement includes several tanks arranged next to each other.
在另一方面,根据独立权利要求16所限定的内容,提供了一种反应器布置结构用于有机废弃物的厌氧消化的用途。In another aspect, according to what is defined in
在又一方面,根据独立权利要求17所限定的内容,提供了一种反应器布置结构用于沼气生产的用途。In a further aspect, according to what is defined in
本发明的实用性来自于根据本发明的每个具体实施方式的各种原因。首先,本发明提供了紧凑的反应器解决方案,与相同类型的常规AD反应器相比,该反应器的长度减少了至少两倍,其中,通过提供至少两个并排设置的反应子区来补偿减小的长度。搅拌器单元之间没有分隔壁允许有效地混合经消化的基质。通过减小反应器的长度,避免了在搅动搅拌器和/或驱动发动机方面施加过多的负载,从而增加了反应器的稳定性和可靠性,提高了混合效率,降低了能量需求,并允许节省大量的维修和维护成本。The utility of the invention arises from various reasons in accordance with each embodiment of the invention. First, the present invention provides a compact reactor solution, the length of which is reduced by at least two times compared to conventional AD reactors of the same type, wherein this is compensated by the provision of at least two reactor sub-zones arranged side by side reduced length. The absence of dividing walls between the agitator units allows for efficient mixing of the digested matrix. By reducing the length of the reactor, excessive loads on the agitator and/or drive motor are avoided, thereby increasing the stability and reliability of the reactor, improving mixing efficiency, reducing energy requirements, and allowing Save a lot of repair and maintenance costs.
此外,反应器内提供的对流出物/残留物进行高效分类和收回的系统允许处理“脏”原料,“脏”原料包括被各种沉积物和/或轻质杂质比方说例如为塑料包装和包裹物严重污染的有机基质。高效的沉积物收回系统进一步防止了在反应罐底部上形成固体层,并为其中的持续流动力学创造了先决条件。In addition, the system provided within the reactor for efficient sorting and recovery of effluent/residues allows the processing of "dirty" feedstocks including deposits and/or light impurities such as plastic packaging and The wrappings are heavily contaminated with organic substrates. An efficient sediment recovery system further prevents the formation of a solid layer on the bottom of the reaction tank and creates the prerequisites for continuous flow dynamics therein.
由于其预制备的构造模式,因此所公开的反应器解决方案可以在现场容易且迅速地组装。另外,就预制备的构造块体而言,用于所述反应器的预制备的构造块体设计成适于通过常规的机动交通工具或平台来运输,包括在标准桥梁(例如高速公路桥梁)下运输以及经由公路隧道进行运输;因此,无需特殊运输。Due to its pre-fabricated construction mode, the disclosed reactor solution can be easily and quickly assembled on site. Additionally, with regard to pre-fabricated building blocks, the pre-fabricated building blocks for the reactor are designed to be suitable for transport by conventional motor vehicles or platforms, including on standard bridges (eg highway bridges) under transport and via road tunnels; therefore, no special transport is required.
在此公开的反应器解决方案还允许对原料进行预热,使得当基质材料进入反应空间时,基质材料的温度接近微生物活性所需的温度。The reactor solutions disclosed herein also allow for preheating of the feedstock such that when the matrix material enters the reaction space, the temperature of the matrix material is close to that required for microbial activity.
此外,反应器采用了集成的热回收和循环(再循环)概念,因此,在反应罐内进行AD处理期间获得的热被回收以用于朝向所述反应空间的上游和下游的各种设施进行进一步储存和/或再循环。另外,如此回收的热可以进一步用于调节反应器罐内的温度,以获得最有利于存在于所述罐内的细菌种群的状态。结果,在北欧气候的冬季期间,本反应器在嗜热条件下(42℃至97℃、优选地为42℃至66℃、在某些情况下在43℃至55℃)完全能够以具有成本效益的方式运行。Furthermore, the reactor employs an integrated heat recovery and circulation (recycle) concept, so that the heat obtained during AD processing in the reaction tank is recovered for various facilities upstream and downstream towards the reaction space. Further storage and/or recycling. In addition, the heat thus recovered can be further used to adjust the temperature within the reactor tank to obtain conditions most favorable to the bacterial population present in the tank. As a result, the present reactor is fully capable of cost-effective operation under thermophilic conditions (42°C to 97°C, preferably 42°C to 66°C, and in some
在反应器罐的壁和/或基部的内部结合的卫生处理系统的提供增加了整体解决方案的紧凑性,并且自然地消除了建造单独的净化设施的需要。类似地,用于在反应器罐的壁和/或基部的内部使温度调整流体循环的中空管的集成系统进一步允许对该系统内的反应状态进行微调,从而为存在于罐中的微生物的生物降解创造了最有利的环境。通过调节反应器内部的温度,可以调整嗜温和嗜热细菌的种群,从而相应地改变沼气的产量。The provision of a sanitation system integrated inside the walls and/or base of the reactor tank increases the compactness of the overall solution and naturally eliminates the need to build a separate purification facility. Similarly, an integrated system of hollow tubes for circulating temperature-regulating fluid inside the walls and/or base of the reactor tank further allows fine-tuning of the reaction conditions within the system for the Biodegradation creates the most favorable environment. By adjusting the temperature inside the reactor, the population of mesophilic and thermophilic bacteria can be adjusted, thereby changing the biogas production accordingly.
总的来说,在此公开的反应器以具有成本效益的方式满足了在厌氧条件下高效消化(有机)废弃物部分所必需的要求,即:在整个反应器设施(包括进料器)中保持恒定的温度状况;在反应器罐的整个长度上进行均匀且有效地混合;并均匀地供给原料材料。Overall, the reactors disclosed herein meet the requirements necessary for efficient digestion of (organic) waste fractions under anaerobic conditions in a cost-effective manner, ie: in the entire reactor facility (including feeders) constant temperature conditions are maintained in the reactor; uniform and efficient mixing is performed over the entire length of the reactor tank; and feedstock materials are uniformly supplied.
表述“有机基质”在本公开中是指源自于生物的基质物料;而术语“可生物降解”是指自然分解和/或由于微生物的生物活性而分解的(有机)基质。术语“厌氧”在本公开中是指在没有氧气的情况下进行的生物降解过程。The expression "organic substrate" in the present disclosure refers to a substrate material of biological origin; whereas the term "biodegradable" refers to an (organic) substrate that decomposes naturally and/or as a result of the biological activity of microorganisms. The term "anaerobic" in this disclosure refers to a biodegradation process that takes place in the absence of oxygen.
在本文件的上下文中使用表述“若干”来表示从一(1)开始的任何正整数。表述“多个”在此是指从两(2)开始的任何正整数,例如至两个、三个或四个。The expression "number" is used in the context of this document to refer to any positive integer starting from one (1). The expression "plurality" here refers to any positive integer starting from two (2), eg to two, three or four.
通过考虑详细描述和附图,本发明的不同实施方式将变得明显。Various embodiments of the present invention will become apparent upon consideration of the detailed description and drawings.
附图说明Description of drawings
图1A、图1C和图1D示意性地示出了根据实施方式的厌氧消化的反应器布置结构100。图1B是根据实施方式的反应器布置结构100的立体图。图1E示出了根据实施方式的用于反应器布置结构100的顶部组件。1A, 1C and 1D schematically illustrate a
图2A、图2B和图3示出了反应器布置结构100的示例性构型。2A, 2B, and 3 illustrate exemplary configurations of
图4A至图4D示意性地示出了用于反应器100的各种构型的反应器罐101的横截面视图。4A-4D schematically illustrate cross-sectional views of
图5A是反应器布置结构100的呈示例性构型的纵向横切视图。图5B是根据实施方式的从顶部观察的厌氧消化布置结构100的平面图。5A is a longitudinal cross-sectional view of
图6示出了根据实施方式的从侧面观察的反应器罐101。Figure 6 shows the
图7示意性地示出了反应器布置结构100内的加热和温度调整系统。FIG. 7 schematically shows the heating and temperature regulation system within the
具体实施方式Detailed ways
本文中参照附图公开了本发明的详细的实施方式。在所有附图中,相同的附图标记用于指示相同的构件。以下引用被用于下述构件:Detailed embodiments of the present invention are disclosed herein with reference to the accompanying drawings. The same reference numerals are used to refer to the same components throughout the drawings. The following references are used for the following components:
100-厌氧消化的反应器布置结构,100-reactor arrangement for anaerobic digestion,
101-反应器罐,101 - Reactor Tank,
201-可选地具有机械部分的后处理设施,201 - Aftertreatment facility optionally with mechanical parts,
202-沉积物排放器件,202 - Sediment discharge device,
203-经消化的基质的排放器件,203 - Discharge device for digested matrix,
301-具有(可选的)盖311的进料罐,301 - feed tank with (optional)
302-第一进料供给器件,302 - first feed supply device,
401-预处理设施,401 - Pretreatment Facility,
402-第二进料供给器件(温度可调节),402 - Second Feed Supply Device (Temperature Adjustable),
501A-用于反应器支撑结构(多个反应器支撑结构)的顶部,501A - for the top of a reactor support structure (reactor support structures),
10、10A、10B-反应器罐的内部,10, 10A, 10B - the inside of the reactor tank,
11、11A、11B-侧向(壁)轮廓部,11, 11A, 11B - Lateral (Wall) Profiles,
12、12A-基部元件和相应的基部元件的延伸部,12, 12A - base element and extension of the corresponding base element,
13-外部绝缘部/衬垫,13 - External Insulation/Gasket,
14-外部基础元件,14 - External base element,
15、501-分别位于反应罐上方的覆盖件和顶部,15, 501 - Cover and top respectively above the reaction tank,
16、17-进入端部和相应的排放端部,16, 17 - entry end and corresponding discharge end,
18-流入端口,18 - Incoming port,
19、20、21-流出端口,19, 20, 21 - outgoing ports,
22-搅拌器22 - agitator
23-传动杆/轴,23 - Transmission rod/shaft,
24、24A、24B-混合叶片及混合叶片的部件,24, 24A, 24B - mixing blades and parts of mixing blades,
25-分离装置,25 - Separation device,
26-用于容置驱动杆的凹陷部,26 - The recess for housing the drive rod,
27-驱动杆支撑元件,27 - Drive rod support element,
30-卫生系统,30 - Health System,
31、32、33-根据实施方式的用于卫生系统的流导管、套和抽取开孔,31, 32, 33 - Flow conduits, sheaths and extraction apertures for sanitary systems according to embodiments,
40-温度调整系统,40-Temperature adjustment system,
41、42-反应器罐的壁和基部内部的管(多个管),41, 42 - the walls of the reactor tank and the tube(s) inside the base,
43-驱动杆内部的管(多个管),43 - Tube(s) inside the drive rod,
44-热回收和循环系统,44 - Heat Recovery and Circulation Systems,
50-热交换器单元,50 - Heat Exchanger Unit,
51-中央热分配和控制单元,51 - Central heat distribution and control unit,
图1A至图1C以下面的100示意性地示出了根据本发明的方面的厌氧消化反应器布置结构——下文中为反应器——100的各种实施方式的概念。布置结构100有利地包括至少一个反应器罐或池101、预处理设施401和后处理设施201。预处理设施有利地包括各种进料机302、402、用于储存原料材料、化学物质、缓冲剂等的若干储存容器301以及各种机械解决方案。后处理设施201有利地包括排放器具202、热回收及热净化解决方案、以及可选的机械解决方案。1A-1C schematically illustrate at 100 below the concept of various embodiments of an anaerobic digestion reactor arrangement - hereinafter reactor - 100 in accordance with aspects of the present invention. The
图1B示出了构造为厌氧(生物)消化设备的示例性布置结构100,该布置结构包括两个反应器罐101(见顶部501),反应器罐101具有常见的预处理设施401和带有排放器具的常见的后处理设施201。构造成用于对原料材料进行预处理以及将原料材料供给到罐(多个罐)101中的各种器件(例如301、302、402)可以定位在单独的“处理”厅(图1B,左侧的建造物,图5B)中、以及/或者定位于布置在罐(多个罐)的上游的预处理部分中。由附图标记301、302、401和可选的402指示的元件是特定于设备的(取决于设备的大小、基质、气候条件等),并且可以在各实施方式中变化。优选地,构造成用于有机原料的热处理的进料供给器件402于在此描述的和/或基于本公开的技术人员所理解的每个实施方式中基本上不改变地设置。FIG. 1B shows an
反应器布置结构100有利地包括:温度调整系统,温度调整系统配置成调节反应器罐(或多个反应器罐)中的温度;以及热回收和循环系统,热回收和循环系统配置成使在厌氧消化期间在罐(多个罐)中产生的热回收并将由此回收的热引导至预处理设施401并且可选地引导至温度调整系统。下面将进一步详细描述所提及的系统。The
因此,反应器布置结构100包括水平延长的罐101,罐101构成反应室(反应空间)。因此,在一些优选实施方式中,反应器罐101具有作为表示长×宽×高的以下尺寸:21m×12m×6m至7m。Thus, the
反应器罐101由水平延伸的四边形容器限定,该容器具有用于接纳有机原料的进入端部16和用于提取经消化的浆料(消化物)的排放端部17。为了清楚的目的,在本公开中,术语“消化物”和“经消化的基质”是指除沼气以外的任何大致为固态的厌氧消化的副产物。从预处理设施401中的进料罐(或多个进料罐)301供给的原料通过设置在进入端部16处的进料入口端口18(流入端口)接纳到反应器罐101中。The
在优选实施方式中,反应器罐101在反应器罐101的底部处是矩形的。在这种情况下,罐的宽度在进入端部和排放端部处是相同的。In a preferred embodiment, the
在一些其他实施方式中,反应器罐101可以构造为四边形本体,该四边形本体在排放端部17处的宽度大于在进入端部16(未示出)处的宽度。在四边形本体的基部处,这种构型形成了上下倒置的等腰梯形(其中,等腰梯形的更窄的基部位于进入端部16处)。In some other embodiments, the
反应器罐101在反应器罐101的内部10内容置有至少两个并排定位的且沿纵向方向延伸穿过反应器罐的整个长度的搅拌器或混合器22,反应器罐的整个长度在本公开中被限定为从进入端部16至排放端部17的距离。The
如上所述,搅拌器轴不应过长。另一方面,AD反应器罐的容量必须至少为800m3;否则会危及反应器状态的稳定性。通过提供具有双混合轴(即,两个挨着彼此定位的轴)的罐来满足这两个要求。As mentioned above, the agitator shaft should not be too long. On the other hand, the AD reactor tank must have a capacity of at least 800 m 3 ; otherwise the stability of the reactor state is compromised. Both requirements are met by providing a tank with dual mixing shafts (ie two shafts positioned next to each other).
搅拌器可以严格平行地布置(在“矩形”罐101的情况下),或者,搅拌器在每个方向上偏离纵向对称轴线优选地不大于45度(在“梯形”反应器罐101的情况下)。The agitators may be arranged strictly parallel (in the case of the "rectangular" tank 101 ), or the agitators are preferably not more than 45 degrees off the longitudinal axis of symmetry in each direction (in the case of the "trapezoidal" reactor tank 101 ) ).
每个搅拌器22包括驱动杆23,该驱动杆23构造为具有若干混合叶片24的轴。轴有利地设置为管状本体,该管状本体的壁厚在介于30mm至70mm的范围内、优选地在介于50mm至70mm的范围内、还优选地在介于约60mm至65mm的范围内。在一些实施方式中,混合叶片24构造为分别配装至驱动杆的叶片桨叶(轮叶),以遵循大致放射状模式(图2A、图2B)或大致螺旋形模式(未示出)。在一些替代实施方式(未示出)中,每个混合叶片可以构造为开放式叶轮,该开放式叶轮包括附接至中心毂的一系列轮叶,该中心毂配装至驱动杆23。搅拌器还可以构造为螺旋带状叶轮(未示出)。Each
图1C示出了包括混合叶片24的反应器的示例性构型,该混合叶片构造为由单独的部件24A、24B制成的桨叶。每个桨叶的最内部部件24A(虚线框)设置为一对管状元件,该管状元件可以穿行通过轴23并例如通过焊接来固定,由此对桨叶造成的机械应力的量是最小的,并且整个轴结构被给予了扭转刚度。最内部部件24A可以紧固至已经位于制造设施处的轴(多个轴)23。最外部部件24B与最内部部件24A的附接可以例如经由接合联接来实现,然后进行焊接。FIG. 1C shows an exemplary configuration of a reactor including mixing
为了便于运输约20m长的轴(多个轴),可以在组装反应器布置结构100的位置处将最外部部件24B紧固至最内部部件24A。从图1C可以看出,在轴(多个轴)23上安装有其他相同的混合叶片24,使得每个后续叶片相对于前一个叶片旋转45度。这些位置是固定的。举例来说,图1C上用罗马数字(ii)和(iv)表示的混合叶片24的最外端指向四个基本方向,即、相应地为北(N)-南(S)和东(E)-西(W);而由数字(i)和(iii)指示的叶片指向四个中间方向,即、相应地为西南-东北和西北-东南。在上面的示例中,使用了指南针方向。To facilitate transport of the shaft(s) about 20 m long, the
在反应器罐101依循梯形形状的情况下,成系列的叶片24的直径优选地构造成朝向排放端部17的方向逐渐增大。Where the
杆23优选地是发动机驱动的。可以在设置于后处理设施201和/或预处理设施401中的机械部分内设置至少一个马达发动机,该马达发动机优选地为电动马达(未示出)。在一些情况下,至少一个附加的驱动机构可以安装在罐101的与罐101的进入“前”端部16相邻的外部,以与设置在机械部分内的反应器的“后部”上的主马达发动机配对。通过在反应器罐的两个端部处提供至少两个马达,可以避免搅拌器的过载。机械部分还可以包括附加的机构,例如各种控制器、放大器等。
还优选的是,齿轮箱和马达头布置在预处理设施401内的区域。通过这种布置结构,可以更换用于搅拌器的密封结构,甚至在反应罐(多个反应罐)填充有基质材料时也可以进行更换。It is also preferred that the gearbox and motor head are arranged in an area within the
为了提供反应器罐101内的反应基质的最有效的搅拌,搅拌器22设定成沿相反的方向旋转(如图2A、图2B上的箭头所示);因此反应基质被大致从罐101的中央朝向罐的侧部引导然后返回至中央。优选的旋转模式还如图4A(箭头绘出方向)所示,其中位于反应器罐101右侧的搅拌器(从进入端部16观察)设定成顺时针旋转,相应地,左侧的搅拌器设定成逆时针旋转。在其他构型中,搅拌器22可以设定成朝向彼此旋转(右侧-逆时针;左侧-顺时针);或替代性地,搅拌器22可以设定成沿相同的方向旋转。In order to provide the most efficient agitation of the reaction substrate within the
叶片24在驱动杆23上呈放射状和螺旋形/盘旋形模式的布置优选地使得位于进入端部16处的各个叶片24之间的间隔大于位于排放端部17处的间隔。每单位距离的叶片密度沿着驱动杆23的增大允许反应基质的有效处理、即反应基质的混合,反应基质的密度又在反应基质沿着罐101的长度从进入端部16朝向排放端部17行进时减小,这是因为有机基质由于厌氧消化而溶解在反应器内。The arrangement of the
反应器100优选地构造为用于有机基质的连续搅拌的厌氧消化处理的水平塞流式反应器(PFR)。在本公开中,术语“厌氧消化”是指微生物在广泛温度范围内在缺氧条件下降解有机物并伴随产生沼气的过程。基于所述温度范围,通常可以确定两个子过程:在10℃至48℃的范围内、优选地在30℃至42℃的范围内进行的嗜温消化、以及在42℃至97℃的范围内、优选地在42℃至66℃的范围内、和一些情况下在43℃至55℃的范围内的嗜热消化。因此,在上文指示的范围内稳定且为活性的微生物是指嗜温微生物和嗜热微生物。
实际上,根据Brock Biology of Microorganisms(布罗克微生物生物学)(第12版,Madigan,Martinko,Dunlap和Clark),嗜热微生物细分成:在42℃至66℃的范围内、最佳地在60℃处为活性的嗜热菌、例如嗜热脂肪地芽孢杆菌(Geobacillusstearothermophilus);在67℃至97℃的温度范围内、最佳地在88℃处为活性的超嗜热菌1(hyperthermophiles1)、例如塞勒热球菌(Thercococcus celer);以及在高于100℃的温度处为活性的超嗜热菌2、例如延胡索叶菌(Pyrolobus fumarii)。为了本发明的目的,嗜热温度范围被限定为42℃至97℃。In fact, according to Brock Biology of Microorganisms (12th ed., Madigan, Martinko, Dunlap, and Clark), thermophilic microorganisms are subdivided into: Thermophilic bacteria such as Geobacillus stearothermophilus active at 60°C; hyperthermophiles 1 active at temperatures ranging from 67°C to 97°C, optimally at 88°C ), such as Thermococcus celer (Thercococcus celer); and hyperthermophilic bacteria 2, such as Pyrolobus fumarii, which are active at temperatures above 100°C. For the purposes of the present invention, the thermophilic temperature range is defined as 42°C to 97°C.
嗜温微生物的示例性代表是具有最佳温度为约39℃的大肠杆菌。An exemplary representative of mesophilic microorganisms is E. coli with an optimum temperature of about 39°C.
嗜温微生物表明了沼气生产的效率和产量的提高;然而,嗜热微生物同样对温度、pH水平、氧化还原电位的变化、以及对诸如重金属、抗生素和洗涤剂等抑制因子的存在更为敏感。就将上述参数调节到合适的值而言,本文提供的反应器100可以构造成与嗜温微生物、嗜热微生物或与同时存在于反应器罐中的两种类型的微生物一起操作。在有机基质材料行进通过反应器100时,有机基质材料由于微生物的活性而逐渐溶解。Mesophilic microorganisms demonstrated increased efficiency and yield in biogas production; however, thermophilic microorganisms were also more sensitive to changes in temperature, pH levels, redox potential, and to the presence of inhibitors such as heavy metals, antibiotics, and detergents. The
因此,在细菌介导的厌氧消化过程中,可生物降解的有机基质被分解以产生沼气和大致为固态的残留物,该残留物通常被称为消化物。所述消化物包括纤维材料(纤维素和木质素)、死亡的细菌细胞以及含有固体和产甲烷液体的泥渣状部分。这些副产物可以进一步用作肥料、堆肥、如纤维板等低级建筑材料、和/或用作乙醇生产的原料。Thus, during bacterial-mediated anaerobic digestion, the biodegradable organic substrate is decomposed to produce biogas and a roughly solid residue, commonly referred to as digestate. The digestate includes fibrous material (cellulose and lignin), dead bacterial cells, and a sludge-like fraction containing solids and methanogenic liquids. These by-products can be further used as fertilizers, compost, low-grade building materials such as fiberboard, and/or as feedstocks for ethanol production.
用于反应器100的进料输入主要由植物或动物来源的有机废弃物表示,有机废弃物例如为田间(植物)生物质和副产物(蔗渣、麸皮、稻草)、厨房和餐饮(生物)废弃物、家庭和/或城市废弃物、食品工业、林业、农业(耕种、动物和家禽饲养)的副产物、以及污水浆料和废水泥渣。Feed input for
显然,就纯度而言,上述原料相差很大。就此,田间生物质和农作物副产物例如基本上没有难以消化的或不易消化的杂质,或者田间生物质和农作物副产物包含呈砾石或沙子形式的难以消化的或不易消化的杂质的可忽略不计的量。另一方面,家庭或农业生物废弃物通常包含由难以消化的塑料和/或金属表示的大量的污染物以及各种不易消化的有机副产物,有机副产物比方说例如为木头和/或木材加工的工业副产物。Obviously, the above-mentioned raw materials vary widely in terms of purity. In this regard, field biomass and crop by-products, for example, are substantially free of indigestible or non-digestible impurities, or field biomass and crop by-products contain negligible amounts of indigestible or non-digestible impurities in the form of gravel or sand quantity. On the other hand, household or agricultural bio-waste usually contains a large amount of pollutants represented by indigestible plastics and/or metals and various indigestible organic by-products such as wood and/or wood processing for example of industrial by-products.
为了有效地处理存在于行进通过反应器罐101的反应基质中的这些难以消化的部分、特别是从进入端部16沿着反应器罐的长度朝向排放端部17行进通过反应器罐101中的反应基质中的这些难以消化的部分,反应器布置结构100还包括下述器具:该器具用于将经消化的基质从难以消化的残留物分类及分离并且从彼此独立的罐101提取含有消化物的部分和含有残留物的部分。In order to efficiently treat these indigestible fractions present in the reaction matrix traveling through the
进一步参照图3,图3示出了反应器布置结构100内的反应器罐101(未示出后处理设施201)。因此,反应器罐101包括位于进入端部16处的原料接纳流入端口18和位于与进入端部16相反的排放端部17处的至少一个流出端口。在一些构型中,反应器包括位于排放端部17处的若干流出端口19、20、21。从进料罐(未示出)经由预处理设施401供给的包含原料(F)的可生物降解的有机基质通过所述流入端口18进入反应器罐101。如上所提及的,原料(F)包括悬浮在原料中的各种固态的、难以消化的污染物。With further reference to Figure 3, Figure 3 shows the
在原料(F)沿着反应器罐101的长度行进、同时通过至少两个搅拌器22连续搅拌的情况下,包含在原料中的可生物降解的有机基质材料借助于嗜温微生物和/或嗜热微生物经历了厌氧消化的过程。同时,沉重的、无浮力的难以消化的沉积物例如石头、砾石、沙子、玻璃、金属颗粒等由于其自身重量而被向下拖拽而沉落在罐101的底部处,而轻质的、有浮力的难以消化的残留物比方说例如为塑料则漂浮于有机基质材料的表面并驻留在那里。在具有入口和出口的常规的消化器中,在排空反应器(多个反应器)时必须手动去除这种难以消化的污染物,以避免堵塞排放路径和/或避免在反应器罐的底部上形成沉积物层。沉积物层的形成引起基部水平的升高,从而改变了搅拌时产生的流动动力学。With the feedstock (F) traveling along the length of the
反应器布置结构100可以构造成允许在消化过程期间从反应空间101连续有效地去除难以消化的污染物。因此,如图3上用大写字母D表示的经消化的基质(消化物)可以从反应器罐101经由主流出端口19排放,而无浮力的难以消化的残留物R1(沉积物)可以经由第一辅助流出端口20排放。由此获得的经消化的基质D没有固态的、难以消化的物质,或者包含无意义或可忽略的量的难以消化的杂质。无论如何,经消化的基质D不需要进一步净化和/或精制。The
反应器100还可以包括第二辅助流出端口21,该第二辅助流出端口21构造成接纳轻质的、有浮力的难以消化的残留物R2(漂浮物质),比如各种不可回收的塑料(塑料包装、泡沫塑料等)。相应地,在一些情况下,所述辅助流出端口20和21可以直接布置在主流出端口的下方或上方(见图3,端口21)。替代性地,所述辅助端口20、21中的任一者(见图3,端口20)可以在与主端口19的位置相关的水平平面内侧向移位。在一些其他情况下,至少一个辅助流出端口20、21可以布置在与主流出端口19相同的水平处。The
反应器布置结构100还可以包括若干器件,所述多个器件构造成:在有机基质材料沿着反应器罐101的长度朝向流出端口19、20和/或21行进时对悬浮在经过厌氧消化的有机基质材料中的固态的、难以消化的物质的分离和分类进行介导。The
在接下来的构型中,反应器布置结构100包括沉积物排放器件202(图1A、图2A、图2B),沉积物排放器件构造成将无浮力的难以消化的残留物R1从罐101的底部经由第一辅助流出端口20输送至反应空间外部。器件202布置在排放端部17处,可选地,器件202位于后处理设施201内,并且器件202构造为至少一个输送器,该输送器比如为设计成收集聚积在罐101的底部上且朝向排放端部17缓慢行进(由于搅拌器介导的搅拌)的例如为砾石和沙子等固态沉积物的螺杆式输送器。因此,在图2A和图2B上所示的实施方式中,101、器件202包括:输送螺杆,该输送螺杆设置在罐101内并且布置在大致水平的平面内;以及第二输送螺杆202,第二输送螺杆202布置在上升管内,从而在将沉积的残留物R1从反应器100取出之前,使沉积的残留物R1向上输送。从反应器100取出后,收集固态的无浮力的沉积物以用于回收。替代构型包括单个升高或非升高输送器,比方说例如螺杆式输送器。不管怎样,可以利用任何其他合适的实现形式。在图5A上还示出了在反应器布置结构100内设置的器件202。In the next configuration, the
在一些构型中,反应器100还包括附加的残留物排放器件(未示出),该附加的残留物排放器件构造成将存在于沿着反应器罐101的长度行进的有机基质材料的表面上的有浮力的难以消化的残留物R2经由第二辅助流出端口21输送至反应空间外部。该附加的残留物排放器件的可能构型包括输送器,该输送器构造成将轻质的塑料残留物R2在水平平面内传送和/或向下传送以进行进一步收集和回收。In some configurations, the
图2B示出了下述示例性构型:在该示例性构型中,反应器100还包括位于反应器罐101内的若干分离装置25,分离装置25用于促进悬浮在有机基质中的难以消化的(有浮力的/漂浮的以及无浮力的/沉积的两者)物质的分离。分离装置25可以构造为具有固定至罐101的底部的下端部的竖向棒,所述棒设定成执行振动或振荡运动。所述棒优选地是马达驱动的。分离装置25优选地定位成与罐101的排放端部17相邻,以促进经消化的(生物降解的)有机产物与难以消化的固体分离,并且相应地促进经消化的产物D以及残留物R1和/或R2朝向适合的流出端口19、20和/或21分类。FIG. 2B shows an exemplary configuration in which the
在一些构型中,反应器罐101包括用于排放(未分离的)消化物D的若干可选地相同的流出端口19、20、21。在这种情况下,难以消化的残留物的分离发生在其他地方。所有流出端口可以位于同一水平或不同水平处。应注意的是,每个罐可以提供三个以上的流出端口。In some configurations, the
进一步参照图4A至图4D,图4A至图4D以反应器罐101的横截面示出了反应器布置结构100的各种实施方式。就此,罐101在纵向方向上由侧向壁(侧壁)限定。为了在反应器罐101中实现反应基质更有效的混合并且避免沉积物聚积在于(侧向)壁轮廓部与底部之间的相交部处形成的拐角处,沿纵向方向限定所述反应器罐101的内部10的每个侧向壁是倾斜的(斜向的)。因此,在侧向壁与底部相接的拐角或相交部处沿着反应器罐101的整个长度有利地形成了由大写字母S表示的倾斜元件。Referring further to FIGS. 4A-4D , FIGS. 4A-4D illustrate various embodiments of the
图4A示出了下述示例性构型:在该示例性构型中,每个侧向壁由若干L形轮廓部11限定;由此倾斜元件S相应地结合到每个L形轮廓部中。倾斜元件S在图4A上由虚线显示。FIG. 4A shows an exemplary configuration in which each lateral wall is defined by several L-shaped
在图4A的构型中,形成侧向壁的L形轮廓部11有利地定位成彼此相对并且在底部处由一个或多个基部(中央)元件12接合,使得在反应器罐101的内部10内形成至少两个邻接的子部段10A、10B,其中每个子部段10A、10B构造成接纳搅拌器22(未示出;箭头所绘出的为旋转方向)。因此,基部元件(多个基部元件)12的设置是为了在子部段10A、10B之间形成升高的分隔部。所述分隔部的高度可以可选地通过在所述分隔部上安装延伸元件(多个延伸元件)12A而增大。在一些构型(未示出)中,中央基部元件(多个中央基部元件)12(如图4A所示)可以设置为大致平坦的面板(多个面板),该面板具有可选地安装于该面板的单独的分隔元件。In the configuration of FIG. 4A , the L-shaped
各个L形轮廓部11定位成彼此成对地相对,以符合镜像对称的原理。L形轮廓部11构造成使得在外部将反应器罐101限定为在罐的基部处是矩形的罐,而罐101的内表面是弯曲的,以在至少两个邻接的子部段10A、10B内相应地容置至少两个搅拌器22。The individual L-shaped
图4B至图4D示出了反应器布置结构100的优选构型。Figures 4B-4D show preferred configurations of the
因此,图4B示出了下述构型:在该构型中,每个侧向壁由大致平坦的竖向面板11A形成。对于每个侧向壁11A,倾斜元件(S)可以设置为单独的模块11B。Thus, Figure 4B shows a configuration in which each lateral wall is formed by a generally flat
在一些构型中,形成侧壁的侧向面板设置为约450mm厚,而形成头部端(前端和后端)壁16和17的面板相应地设置为约550mm厚。所提及的面板优选地通过铸造或模制比方说例如连续模制来制造。如图4C所示,在端面板16、17中的每一者中形成有多个(在此为两个)孔或凹陷部26以容置轴23。通过在罐101的每个端部16、17处设置支撑/加强腿部27来进一步给轴提供额外的支撑(图1C、图6)。腿部27可以设置为约600mm厚的混凝土板坯。In some configurations, the side panels forming the side walls are provided approximately 450 mm thick, while the panels forming the head end (front and rear)
在优选实施方式中,布置结构100包括至少两个挨着彼此放置的反应器罐101(图4D)。在这种情况下,两个相邻的反应器罐有利地共用侧向壁11,该侧向壁11可以设置为两个反应器罐之间的分隔壁(见图4D、图5B)。尽管如此,提供四个以上并排布置的反应器罐由于热膨胀而似乎不一定是可行的。在并排定位四个以上的罐的情况下,需要的是移动的密封件。In a preferred embodiment, the
倾斜表面可以是弯曲的(图4A)或平坦的(图4B)。倾斜(斜向)角(theta,θ)可以在约35度至约60度的范围内变化;优选地,倾斜角可被设为约45度。图4C和图4D示出了包括具有略微弯曲的倾斜表面的单独的倾斜元件11B的反应器构型。The sloped surface can be curved (FIG. 4A) or flat (FIG. 4B). The inclination (oblique) angle (theta, θ) may vary from about 35 degrees to about 60 degrees; preferably, the inclination angle may be set to about 45 degrees. Figures 4C and 4D show a reactor configuration comprising a separate
在图4B至图4D所示的构型中,基部元件12设置为大致平坦的面板(例如600mm厚);因此,至少两个搅拌器22接纳在未分离的内部10中。在另外的构型中(未示出),基部元件的设置可以以图4A所示的方式实现。因此,如图4B所示的反应器罐还可以包括单独的分隔元件(未示出),以将内部10分离成至少两个子部段。每个倾斜模块11B又设置为长形的块体或延伸通过罐101的整个长度的若干连续块体。In the configuration shown in FIGS. 4B to 4D , the
为了确保材料在反应器罐101内的有效混合,反应器罐101构造成具有大致平坦的底部,如图4B至图4D所示。To ensure efficient mixing of the materials within the
反应器100还有利地包括至少一层外部衬垫和/或绝缘部13(图4A、图4B)。反应器罐101还放置到基础元件14上并且通过挠性或刚性的覆盖件15(图1C、图1D、图4C,图4D)从顶部密封。
尽管沼气是进入反应空间的有机原料的细菌消化的最终产物,但大多数沼气是在消化过程中产生的,因此,反应器100有利地配备有用于储存沼气的可充气的覆盖件和/或顶部。挠性覆盖件15设置为可膨胀层或若干层,可膨胀层或若干层在膨胀时可以容置在固定的、刚性的穹顶状顶部结构501中(图1A至图1E)。在一些情况下,覆盖件15可以构造为刚性的固定结构(穹顶状的或平坦的),在这种情况下,反应器有利地配备有沼气提取系统(未示出)。Although biogas is the end product of bacterial digestion of organic feedstock entering the reaction space, most biogas is produced during the digestion process, therefore,
通常优选的是,用于反应器布置结构100的顶部结构构造为包括内膜层15和外膜层501的双膜结构。外层501通常被空气充气并且构造成保持外层的形状,甚至在反应器罐(多个反应器罐)101中没有沼气产生活动的情况下也能如此。外膜501可以构造成一次覆盖若干反应器罐101(每个反应器罐覆盖有内膜15),例如:一次覆盖一个反应器罐(图1B、图1C)或者一次覆盖数个反应器罐(图1D、图1E)。内膜15通常是由可充气的气密膜在于反应器罐内部产生沼气时形成的。双膜可以从一个或更多个罐移除以进行维修和保养。出于安全原因(在典型的厌氧罐中恢复富含空气/氧气的氛围)上述动作需要移除两种膜。当在单个罐中进行维修工作时,反应器布置结构中的其他罐仍然可以正常运行(尽管在一些构型中已移除了外膜501)。It is generally preferred that the top structure for
在一些构型中,以一角度设置结合或容置厌氧消化的反应器罐(多个反应器罐)的建造物或其他支撑结构的顶部501A(图1B、图1C)。在图1B和图1C所示的示例中,预处理侧401(进料侧)的壁约9m高,而后处理侧201(输出侧)的壁约6m高。在所述构型中,每个反应器罐101被双膜(层15和501)覆盖。如图1B、图1C所示的反应器设施特别适用于具有大体温和气候的地理位置,这消除了顶部之间雪和雨水聚积的风险。In some configurations, the top 501A of the building or other support structure incorporating or housing the anaerobic digestion reactor tank(s) is positioned at an angle (FIGS. 1B, 1C). In the example shown in Figures IB and 1C, the walls of the pretreatment side 401 (feed side) are about 9 m high, while the walls of the post treatment side 201 (output side) are about 6 m high. In the described configuration, each
图1D和图1E示出了下述反应器布置结构:在该反应器布置结构中,反应器罐101-1、101-2由常见的顶部(外膜501)覆盖。这种构型是在没有倾斜顶部结构的情况下实现的。图1D、图1E所示的反应器设施在北欧气候中是特别优选的,因为它允许避免雪和雨水聚积在顶部501上(雪从顶部501向下流动)。Figures 1D and 1E show a reactor arrangement in which the reactor tanks 101-1, 101-2 are covered by a common top (outer membrane 501). This configuration is achieved without a sloping top structure. The reactor arrangement shown in Figures 1D, 1E is particularly preferred in Nordic climates as it allows to avoid accumulation of snow and rain on the top 501 (from which the snow flows down).
侧向轮廓部11、11A和/或11B以及基部(中央)元件12可以实现为优选地由混凝土制成的预铸块体(预铸块体在运到施工现场之前形成并硬化)。典型的混凝土块体或板坯包括粉末状硅酸盐水泥、水、沙子和砾石。在一些情况下,所述混凝土块体中的沉重的沙子和砾石可以例如用轻质膨胀粘土或膨胀粘土集料代替。在一些情况下,可以使用预铸的煤渣块体,其中上述砾石和沙子被煤和/或煤渣代替。The lateral profiles 11, 11A and/or 11B and the base (central)
壁结构和基部结构优选地由混凝土制成并且在现场(在组装反应器的现场)模制。The wall structure and base structure are preferably made of concrete and moulded in situ (at the site where the reactor is assembled).
附加地或替代性地,前述轮廓部可以由金属制成。金属基构型包括由金属片材和可选的芯部构成的解决方案。在一些实施方式中,侧向壁11、11A是混凝土板坯,而倾斜模块11B是金属基块体。不排除完全的金属基构型。Additionally or alternatively, the aforementioned profile may be made of metal. Metal-based configurations include solutions consisting of sheet metal and an optional core. In some embodiments, the
在一些实施方式中(未示出),反应器罐101可以包括并排定位的若干基部(中央)元件12,以形成至少两个沿纵向方向平行延伸的分隔部,从而在罐101的内部10内形成至少三个邻接的子部段。这种构型允许在反应空间10的内部内容置至少三个平行布置的搅拌器22。In some embodiments (not shown), the
优选地,反应器布置结构100还包括用于对经消化的基质进行热净化的卫生系统30(图3、图4A、图4B、图5B)。卫生处理系统30配置成用于经由包含在经消化的基质中的微生物的抑制和/或灭活(因此,可逆或不可逆地丧失微生物活性)而对经消化的基质D进行后处理;从而消除或至少降低了流行病学风险。Preferably, the
因此,卫生系统30配置成将作为热能的流的热传递至经消化的基质;因此,微生物活性的衰减/消除是热诱导的。举例来说,在70℃的温度处进行了1小时的卫生处理;并且在100℃的温度处进行了20分钟的卫生处理;因此,通过形成所述卫生系统的器件的流动速率已经被相应地调节。Thus, the
在优选构型中,卫生系统30设置在布置于至少一个罐101的下游的后处理设施201中。所述卫生系统30可以与下述排放器件203结合:该排放器件203构造成从若干罐101收集经消化的基质D并将所述经消化的基质输送到反应器布置结构100外部(图5B)。在一些构型中,器件203可以构造为输送器,比方说例如是刮板式输送器,而卫生系统30可以围绕所述输送器构建以建立加热套。替代性地,排放器件203可以构造为用于将经消化的基质从若干罐101朝向出口输送的加热输送器或导管。In a preferred configuration, the
不管经消化的基质是否需要进行后处理、即卫生处理,构造为例如管道系统的器件(多个器件)203都可以经由例如若干热交换器单元50(图5B)来用于热回收。Whether or not the digested substrate needs to be post-treated, ie sanitized, the device(s) 203 configured as eg a piping system can be used for heat recovery via eg several heat exchanger units 50 (FIG. 5B).
在一些替代性构型中,卫生系统30可以结合到在反应器罐101的内部形成的倾斜元件S中(图3、图4A、图4B)。在这种情况下,卫生系统包括封包在套或护套32中的至少一个导管31。热经由所述套(多个套)32传递至导管(多个导管)31。一个或多个导管31构造成沿纵向方向横穿通过罐101的侧向壁和/或基部,并且接纳通过主流出端口19排放的经消化的基质。In some alternative configurations, the
导管(多个导管)31可以构造成横穿通过反应器罐101的由若干L形轮廓部11(图4A)限定的每个侧向壁。无论L型轮廓部是否由混凝土板坯形成,为了在L型轮廓部中容纳卫生系统30,每个所述板坯包括预制的贯通开孔,该贯通开孔在组装反应器罐时形成中空的管状的管或通道。替代性地,导管(多个导管)31可以构造成横穿通过倾斜模块11B(图4B)。附加地或替代性地,导管(多个导管)31可以结合到基部(中央)元件(多个基部(中央)元件)12中。The conduit(s) 31 may be configured to traverse each lateral wall through the
如图3、图4A、图4B所示的那样来实现的卫生系统30配置成接纳从反应器罐101通过主流出端口19排放的经消化的基质D,以介导所述基质D从排放端部17沿着至少一个导管31至进入端部16的行进,因此,存在于所述经消化的基质中的微生物被抑制和/或灭活,并通过布置在反应器罐101的进入端部处的至少一个开孔33来提取被后处理(卫生的)的基质D1。从反应器100的进入端部16取出的被后处理的经消化的基质D1被进一步输送到其他地方以进行储存或运输。
图3、图4A、图4B示出了以单个U形或Y形导管的形式设置的卫生系统30,该单个U形或Y形导管从主流出端口19(位于排放端部17处)穿过两个侧向壁、特别地穿过侧向壁的倾斜元件S朝向布置在进入端部16处的开孔33。替代性地,延伸穿过每个侧向壁11的导管可以设置为单独的元件。因此,当经消化的基质D沿着设置为沿纵向方向“穿透”侧向壁11的封包导管31的卫生系统30行进时,经消化的基质通过热后处理而被净化。Figures 3, 4A, 4B show a
设置在卫生系统30内的加热套或其他加热装置(图3、图5B)有利地包括与热产生设备连通的热传递器具。优选地,净化所需的热是从下面进一步描述的热回收和循环系统44(图5B)获得的。因此,加热可以经由液体循环来实现。附加地或替代性地,可以借助于外部热交换器或热泵来介导热传递。热交换器50的示例性位置在图3和图5B上示出。A heating jacket or other heating device (Figs. 3, 5B) provided within the
反应器布置结构100还包括温度调整系统40,该温度调整系统40配置成调节一个或多个罐101中的温度。系统40包括多个内部管41、42,所述内部管构造成沿纵向方向横穿通过罐的侧向壁11和/或基部12,并相应地使温度调整流体沿着内部管输送(图4A至图4C)。借助于温度调整系统40,将反应器罐101内的温度维持在适合于厌氧消化必不可少的细菌种群的正常作用的水平处。The
为了将温度调整装置40容置到反应器罐101中,形成侧向壁和/或基部元件(多个基部元件)12的元件11、11A可以设置为具有多个中空的管状管40的预成形的中空芯部的混凝土板坯。形成装置40的管的直径优选地小于形成导管31的管的直径。为了清楚的目的,附图标记41进一步指代布置在侧壁11中的管,而附图标记42指代布置在基部元件12中的管。管41和42设置在温度调整系统40内。In order to accommodate the
在一些实施方式中,管41、42还包括下述(例如,金属)管道:该管道封包在形成侧向壁11、11A和/或基部(中央)元件(多个基部(中央)元件)12或内部衬垫/涂层的混凝土板坯中,以减少混凝土板坯的磨损。涂层、比方说例如金属涂层优选地在组装块体11、11A、12之前被施加。In some embodiments, the tubes 41 , 42 further comprise (eg, metal) conduits that are enclosed in forming the
温度调整流体是二醇化合物,比方说例如是乙二醇或丙二醇。替代性地,温度调整液体可以是水。通过使加热流体循环通过管41、42,反应器罐101内的温度保持得足够高,以便进行嗜温消化(10℃至8℃、优选地为30℃至42℃)、或进行嗜热消化(42℃至97℃、优选地在42℃至66℃内,在某些情况下,在43℃至55℃内)。The temperature adjustment fluid is a glycol compound such as, for example, ethylene glycol or propylene glycol. Alternatively, the temperature adjustment liquid may be water. By circulating the heating fluid through the pipes 41, 42, the temperature within the
形成温度调整系统40的管41、42可以布置到大致为闭环的再循环路径中,其中温度调整流体在管41、42与在下文进一步描述的热回收和循环系统44、以及与可选地至少一个外部热源(未示出)之间再循环。为了创建再循环路径,在一些构型中,头部端的壁元件或头部端的L形轮廓部可以在其内设置有预成形的转弯部和/或管道弯头。The tubes 41, 42 forming the
参照图6,在若干构型中,在每个搅拌器的驱动杆23内部布置有内部管43,内部管43构造成使温度调整流体沿着内部管43输送。正如上文所述的,搅拌器轴(多个搅拌器轴)设置为内部为中空的管状本体。形成在每个所述搅拌器轴内部的管43用于使温度调整流体例如二醇或水沿着管输送并为在反应器罐101中搅拌的基质提供额外的加热。Referring to FIG. 6 , in several configurations, an
温度调整流体(例如,二醇)在排放侧部17处被给送到管43中。流体经由轴23朝向进入端部16的方向(图6中的由箭头标识)循环以及返回。该轴优选地至少在排放端部17处配备有旋转联接器,以允许在搅拌器轴22的旋转期间将温度调整流体引导到管43中。A temperature regulating fluid (eg, glycol) is fed into
在轴内部提供温度调整液体允许使微生物活性在反应器罐的整个长度上相等。Providing a temperature-adjusting liquid inside the shaft allows microbial activity to be equalized over the entire length of the reactor tank.
进一步优选地,经由若干局部温度控制单元(未示出)和/或经由中央热分配和控制单元51(图7)能够独立地调节布置在罐101的侧向壁中的管41内的以及布置在所述罐的基部中的管42内的温度状况。为反应器罐101的壁和底部中的每一者提供独立的温度控制允许将热能适当地分配到罐内最可能出现材料沉淀物和沉积物的位置,例如将热能分配在基质移动较慢或以其他方式被阻碍的位置上。Further preferably, via several local temperature control units (not shown) and/or via a central heat distribution and control unit 51 ( FIG. 7 ) the arrangement and arrangement within the tubes 41 arranged in the lateral walls of the
以类似的方式,搅拌器轴(多个搅拌器轴)内部的管(多个管)43内的温度状况可以独立于管41和/或42中的温度来控制。In a similar manner, the temperature conditions within the tube(s) 43 inside the stirrer shaft(s) can be controlled independently of the temperature in tubes 41 and/or 42 .
温度调整系统40优选地设置成与包括至少一个热交换器50(图3、图7)的热回收和循环系统44连通。经由温度调整系统40和/或卫生系统30释放的过多的热能可以进一步供给至预处理设施401和/或被提取以进一步利用。The
在一些构型中,管41、42和43建立温度调整系统40,并在反应器罐内提供(内部)温度调整流体循环。反应器100还包括所谓的外部流体循环系统,该外部流体循环系统配置成使流体基本上在反应器罐外部循环(再循环),该外部流体循环系统还被称为用于热回收和循环(再循环)/再利用的系统44。In some configurations,
配置成用于使在厌氧消化期间产生的热高效回收和再利用的系统44形成了反应器100的核心特征之一(图5B、图7)。系统44优选地配置成将热从输出侧(设施201)传递至原料供给侧(设施401)。另外,所述热回收和循环(再循环)系统44优选地配置成与“内部”温度调整系统40连通,并且将由此回收的热引导至所述系统40并且可选地引导至卫生系统30。
图7示出了反应器100内的系统40、44的示例性构型。包括管41、42、43并且结合反应器罐101-1、101-2的温度调整系统40以虚线示出。热回收和循环(再循环)系统44设置为相互连接的导管或管道的网络,所述导管或管道构造成将在厌氧消化(17、201)期间获得的热朝向预处理设施401和预处理设施401中的各种器件301、302、401传递。如上所述,热传递经由液体循环来发生。FIG. 7 shows an exemplary configuration of the
我们在此注意到,系统40和44形成了用于热回收、循环和温度控制的集成总体。在本公开中,所述系统由不同的附图标记指示,以向读者提供反应器布置结构100的热回收功能的更好的理解。We note here that
系统40、44中的每一者有利地包括若干局部热交换单元50和比如恒温器(未示出)的温度控制单元,以检测及调整反应器布置结构100中的温度状况。Each of the
对系统40、44的集成控制经由中央热分配和控制单元51(图7)实现。优选的是,在热回收和循环系统44内设置有至少一个热交换器单元50,以介导罐(多个罐)101(消化物排放侧)与预处理设施401之间的热传递(图5B)。在图5B上,从输出端(设施201)至输入端(设施401)的热传递由箭头(T)示出。Integrated control of the
因此,系统44内的一个或多个热交换器单元50设置成用于将从至少一个反应器罐101中的厌氧消化过程获得的热能输送至预处理设施401。经由所述热交换器单元(多个热交换器单元)50,可以在后处理设施201/卫生系统30、温度调节装置40与前处理设施401之间(以指示的顺序)介导热传递。从设施401提取的热可以被储存、传递以供进一步使用和/或返回至输出侧(设施201)。Accordingly, one or more
在一些情况下,反应器100还包括用于将经消化的基质的一部分再引入到反应器罐101中的基质再循环器具(未示出)。在经消化的基质进入卫生系统30之前,使该部分(接种物)发生分离。优选的是,使经消化的基质的至少三分之一倒回到反应器100中,以在反应器罐中维持稳定的细菌种群。构造成用于将接种物输送返回到反应器罐中的一个或多个导管不经受热处理。In some cases, the
反应器100构造成用于有机基质的厌氧消化处理,其中干物质(固态物质)的含量占按重量计(wt%)的0至百分之80、优选地为0至45wt%。在大多数情况下,反应器罐101内部的有机基质的DM含量在10wt%至35wt%的范围内;然而,上述范围可以根据具体情况而变化。在一些实施方式中,原料中的干物质的优选含量占约35wt%。进入反应器罐101的有机基质保持处于固态,即干物质在上述30wt%至40wt%的范围内。在特殊情况下,在干物质的含量等于或超过50wt%的情况下,需要稀释反应基质。具有约35wt%的DM的有机基质在沿着反应器罐101的长度行进时进行溶解,由此经消化的产物D包含约25wt%的干物质。The
在本发明的一些方面中,提供了反应器100用于有机废弃物的厌氧消化的用途。In some aspects of the invention, the use of the
在另一方面,提供了反应器100用于沼气的生产的用途。如上所述,由微生物活性介导的厌氧消化过程导致产生沼气。沼气是主要为甲烷(50%至70%)和二氧化碳(30%至40%)以及微量氨(NH3)和硫化氢(H2S)的混合物。从反应器100获得的沼气有利地被引导用于进行进一步精炼,例如用于生产生物燃料。In another aspect, the use of the
图5A示出了厌氧消化反应器布置结构100的沿着(假想的)纵向对称轴线的横切部分,而图5B示出了从顶部观察的布置结构100的示例性布局。因此,反应器布置结构包括至少一个反应器罐101(在图5B上示出了三个罐101-1、101-2和101-3)、具有上文所讨论的热传递设备的后处理设施201、以及预处理设施401,预处理设施401包括有利地配备有盖311的至少一个进料罐301以及构造成沿罐101的方向输送原料的若干进料供应器件302、402。Figure 5A shows a transverse section of the anaerobic
进料罐(多个进料罐)301可以构造成接纳完全未加工(“原始”)原料或预粉碎原料。在适用的情况下,优选地在将原料装载到进料罐(多个进料罐)301中之前,在常规的粉碎机或碾碎机中进行预粉碎。期望的是,进入反应空间101的离散集料、比如原料块和/或固态残留物/无机物的大小不超过两个紧握拳头的大小(150mm至200mm)。无论要被反应器100处理的有机废弃物是否包含或被预期包含较大的集料和/或固态碎片(例如石头、砾石或牛骨),此类废弃物应以上述方式进行预粉碎。Feed tank(s) 301 may be configured to receive either fully raw ("raw") feedstock or pre-comminuted feedstock. Where applicable, pre-comminution is preferably performed in a conventional pulverizer or mill prior to loading the feedstock into the feed tank(s) 301 . Desirably, the size of discrete aggregates, such as feedstock clumps and/or solid residues/inorganics, entering the
另一方面,考虑到上文所述的实施方式,无论要被处理的原料是否是大致均匀的和/或是否不包含超大的集料,反应器100均可以装载包含必然量的难以消化的残留物——例如沙子、石头和各种塑料污染物——的不纯的基质。On the other hand, considering the above-described embodiments, whether the feedstock to be processed is substantially homogeneous and/or does not contain oversized aggregates, the
基本不纯的进料在进入反应器罐101之前在第一进料供给器件302和第二进料供给器件402中进行预处理。将原料输送到反应空间101中的第二器件402优选地以与上文讨论的排放器件203相同的方式构造为输送器,例如刮板输送器。优选地,所述器件402构造成将进入一个或多个反应器罐101的有机基质的温度调节成与所述罐中保持的温度相符。由进料供给器件402输送到反应器罐(多个反应器罐)101中的经温度调节的原料通过设置在进入端部16处的流入端口18接纳到反应空间中。The substantially impure feed is pretreated in the first feed supply means 302 and the second feed supply means 402 before entering the
在大多数情况下,进料供给器件402构造成通过加热而对有机原料进行热处理,因为与未处理的原料相比,反应器罐101内部维持的温度(尤其主要通过温度调整装置40维持的温度)通常更高。相应地,对反应器罐101内的温度进行调整的需要是由维持所存在的微生物的重要功能和活性的必须性引起的。在一些例外的情况下,设施401可以构造成使输入的原料冷却。In most cases, the
构造成将原料朝向储存(进料)罐301、朝向加热的输送器402输送的器件302优选地构造成螺杆输送器或活塞泵。The means 302 configured to convey the raw material towards the storage (feed)
对于本领域技术人员而言明显的是,随着技术的进步,本发明的基本思想旨在覆盖包括在本发明的精神和范围内的各种修改。因此,本发明及其实施方式不限于上述示例;相反,本发明及其实施方式通常可以在所附权利要求的范围内改变。It will be apparent to those skilled in the art that, as technology advances, the basic idea of the present invention is intended to cover various modifications included within the spirit and scope of the present invention. Therefore, the invention and its embodiments are not limited to the examples described above; rather, the invention and its embodiments may vary generally within the scope of the appended claims.
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| WO2022226572A1 (en) * | 2021-04-28 | 2022-11-03 | Concept Environmental Services Pty Ltd | Digestion tank |
| CN113388495A (en) * | 2021-05-27 | 2021-09-14 | 同济大学 | Vertical anaerobic digestion reactor for high-content inherent organic materials |
| CN217733090U (en) * | 2022-06-27 | 2022-11-04 | 河北诚至阳普新能源科技有限公司 | Combined anaerobic fermentation tank equipment |
| PL443887A1 (en) * | 2023-02-24 | 2024-08-26 | Przybylski Bogusz Rotag | Biogas plant cogeneration system |
| IT202300024048A1 (en) * | 2023-11-14 | 2025-05-14 | Ecomade Eng S R L | APPARATUS AND METHOD FOR THE PRE-TREATMENT OF AGRICULTURAL WASTE |
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| CN105624033A (en) * | 2016-03-17 | 2016-06-01 | 上海市政工程设计研究总院(集团)有限公司 | Organic refuse dry anaerobic digestion device |
Also Published As
| Publication number | Publication date |
|---|---|
| FI128217B (en) | 2019-12-31 |
| WO2019166620A1 (en) | 2019-09-06 |
| EP3759210A1 (en) | 2021-01-06 |
| FI20185197A1 (en) | 2019-09-02 |
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