CN111863962B - A new type of AlGaN-based multi-channel field effect transistor - Google Patents
A new type of AlGaN-based multi-channel field effect transistor Download PDFInfo
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- H10D30/473—High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having confinement of carriers by multiple heterojunctions, e.g. quantum well HEMT
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Abstract
Description
技术领域Technical Field
本发明涉及半导体器件技术领域,具体涉及一种新型AlGaN基多沟道场效应晶体管。The invention relates to the technical field of semiconductor devices, and in particular to a novel AlGaN-based multi-channel field effect transistor.
背景技术Background Art
基于铝镓氮(AlGaN)合金的场效应晶体管(FET)通常可通过两种方式掺杂,即杂质掺杂和极化诱导掺杂。AlGaN材料的杂质掺杂一般采用硅(Si)元素作为施主杂质,通过电离产生电子;极化诱导掺杂则利用III族氮化物特有的极化特性实现,利用极化电荷诱导体区电子形成导电沟道。Field effect transistors (FETs) based on aluminum gallium nitride (AlGaN) alloys can usually be doped in two ways, namely impurity doping and polarization induced doping. Impurity doping of AlGaN materials generally uses silicon (Si) as a donor impurity to generate electrons through ionization; polarization induced doping is achieved by using the unique polarization characteristics of group III nitrides, using polarized charges to induce body region electrons to form a conductive channel.
现有的掺杂技术及器件结构存在的问题有:1、在高铝组分的AlGaN材料中,杂质掺杂效率显著降低,载流子浓度受限。且载流子会受到较大的杂质散射,迁移率明显下降;2、在高频、高压条件下,AlGaN/GaN异质结界面处的二维电子气(2DEG)浓度过高,抑制电子迁移率和饱和速率,即载流子浓度和迁移率存在折中问题。电子迁移率和饱和速率的下降会造成晶体管的跨导大幅下降,造成非线性传输特性、信号失真等问题;3、对于2中所述问题,其中一种解决方案为采用组分渐变的AlGaN沟道层,通过极化诱导掺杂形成的三维电子气或三维空穴气提高晶体管高频线性度。但三维电子气或三维空穴气面密度较小,源、漏通路串联电阻较大,且沟道中合金散射较严重,载流子迁移率受限,限制了器件的电流密度;4、现有较常用的HEMT器件大多基于金属极性AlGaN/GaN异质结结构,这种器件存在表面Al组分较高、2DEG导电沟道距器件表面距离较远的问题,造成接触电阻和串联电阻较大,抑制器件的电流密度和功率密度;5、通常AlGaN基场效应晶体管中的导电沟道下方无特殊的结构设计,普遍存在载流子限制能力差、器件漏电大的现象,不利于器件的关态击穿特性和开态大偏压下电流饱和。The existing problems of doping technology and device structure are as follows: 1. In AlGaN materials with high aluminum components, the impurity doping efficiency is significantly reduced and the carrier concentration is limited. In addition, the carriers will be subject to greater impurity scattering, and the mobility will be significantly reduced; 2. Under high frequency and high voltage conditions, the concentration of two-dimensional electron gas (2DEG) at the interface of AlGaN/GaN heterojunction is too high, which suppresses electron mobility and saturation rate, that is, there is a compromise between carrier concentration and mobility. The decrease in electron mobility and saturation rate will cause a significant decrease in the transconductance of the transistor, resulting in nonlinear transmission characteristics, signal distortion and other problems; 3. For the problem described in 2, one solution is to use an AlGaN channel layer with a gradient composition, and improve the high-frequency linearity of the transistor through a three-dimensional electron gas or a three-dimensional hole gas formed by polarization-induced doping. However, the surface density of the three-dimensional electron gas or three-dimensional hole gas is small, the series resistance of the source and drain paths is large, and the alloy scattering in the channel is serious, the carrier mobility is limited, and the current density of the device is limited; 4. Most of the commonly used HEMT devices are based on the metal polarity AlGaN/GaN heterojunction structure. This type of device has the problem of high surface Al component and the 2DEG conductive channel is far away from the device surface, resulting in large contact resistance and series resistance, which inhibits the current density and power density of the device; 5. Usually, there is no special structural design under the conductive channel in AlGaN-based field effect transistors, and there is a common phenomenon of poor carrier confinement ability and large device leakage, which is not conducive to the off-state breakdown characteristics of the device and current saturation under large on-state bias.
发明内容Summary of the invention
(一)要解决的技术问题1. Technical issues to be resolved
上述5点现有掺杂技术及器件结构存在的问题。The above five problems exist in existing doping technology and device structure.
(二)技术方案(II) Technical solution
为了解决上述问题,本发明提供了一种新型AlGaN基多沟道场效应晶体管,所述晶体管包括:衬底1;依次设置在所述衬底1上的AlN缓冲层2和背势垒层3;设置于所述背势垒层3上的多量子阱结构4,所述多量子阱结构4为N层铝组分渐变的AlGaN沟道层401和设置在每两层铝组分渐变的AlGaN沟道层401之间的AlN量子垒层402,N≥2;设置于所述多量子阱结构上的GaN帽层5;从GaN帽层5两端分别向多量子阱结构4延伸预设深度的源电极6和漏电极7,以及;设置于GaN帽层5上,且在源电极6和漏电极7之间的栅极8。In order to solve the above problems, the present invention provides a novel AlGaN-based multi-channel field effect transistor, the transistor comprising: a substrate 1; an AlN buffer layer 2 and a back barrier layer 3 sequentially arranged on the substrate 1; a multi-quantum well structure 4 arranged on the back barrier layer 3, the multi-quantum well structure 4 being N layers of AlGaN channel layers 401 with a gradient aluminum component and an AlN quantum barrier layer 402 arranged between every two layers of AlGaN channel layers 401 with a gradient aluminum component, N≥2; a GaN cap layer 5 arranged on the multi-quantum well structure; a source electrode 6 and a drain electrode 7 extending from both ends of the GaN cap layer 5 to a preset depth toward the multi-quantum well structure 4, and; a gate 8 arranged on the GaN cap layer 5 and between the source electrode 6 and the drain electrode 7.
可选地,所述AlGaN铝组分渐变掺杂层401中铝组分在k1到k2之间沿所述铝组分渐变的AlGaN沟道层401生长方向渐变,其中0≤k1<1,0≤k2<1,k1和k2之间关系不做具体要求,即铝组分可以递增渐变,也可以递减渐变。Optionally, the aluminum component in the AlGaN aluminum component gradient doping layer 401 gradiently varies between k1 and k2 along the growth direction of the AlGaN channel layer 401 with the aluminum component gradient, wherein 0≤k1<1, 0≤k2<1, and there is no specific requirement for the relationship between k1 and k2, that is, the aluminum component can gradiently vary in an increasing manner or in a decreasing manner.
可选地,每层所述铝组分渐变的AlGaN沟道层401中铝组分渐变的起始值均相同,结束值均相同。Optionally, the starting value and the ending value of the aluminum composition gradient in each AlGaN channel layer 401 with the aluminum composition gradient are the same.
可选地,每层所述铝组分渐变的AlGaN沟道层401中铝组分渐变的起始值均不相同,结束值均不相同。Optionally, the starting value and the ending value of the aluminum composition gradient in each AlGaN channel layer 401 with the aluminum composition gradient are different.
可选地,在所有的所述铝组分渐变的AlGaN沟道层401中,N>3时,至少有两层所述铝组分渐变的AlGaN沟道层401中铝组分渐变的起始值均相同,结束值均相同。Optionally, in all the AlGaN channel layers 401 with a gradient aluminum composition, when N>3, at least two of the AlGaN channel layers 401 with a gradient aluminum composition have the same starting value and the same ending value of the gradient aluminum composition.
可选地,所述多量子阱结构中所述铝组分渐变的AlGaN沟道层401还可以为BxAlyGa1-x-yN铝组分渐变沟道层或InzAlfGa1-z-fN铝组分渐变沟道层。Optionally, the AlGaN channel layer 401 with a graded aluminum composition in the multiple quantum well structure may also be a BxAlyGa1 -xyN graded aluminum composition channel layer or an InzAlfGa1 -zfN graded aluminum composition channel layer.
可选地,所述BxAlyGa1-x-yN铝组分渐变层或InzAlfGa1-z-fN铝组分渐变层中铝组分在k1到k2之间沿所述BxAlyGa1-x-yN铝组分渐变层或InzAlfGa1-z-fN铝组分渐变层生长方向渐变,其中0≤k1<1,0≤k2<1,k1和k2之间关系不做具体要求,即铝组分可以递增渐变,也可以递减渐变。Optionally, the aluminum component in the BxAlyGa1 -xyN aluminum component gradient layer or the InzAlfGa1 -zfN aluminum component gradient layer gradually changes between k1 and k2 along the growth direction of the BxAlyGa1 -xyN aluminum component gradient layer or the InzAlfGa1 -zfN aluminum component gradient layer, where 0≤k1< 1 , 0≤k2<1, and there is no specific requirement for the relationship between k1 and k2, that is , the aluminum component can gradually change in an increasing manner or in a decreasing manner.
可选地,所述背势垒层3为AlmGa1-mN、BxAlyGa1-x-yN或InzAlfGa1-z-fN中的一种,所述背势垒层3的禁带宽度大于所述多量子阱结构4中第一层铝组分渐变的AlGaN沟道层401的渐变起始点所对应的AlGaN合金的禁带宽度。例如,第一层(401)中铝组分从0.1渐变到0.2,渐变起始点为Al0.1Ga0.9N,则背势垒的禁带宽度大于Al0.1Ga0.9N所对应的禁带宽度。Optionally, the back barrier layer 3 is one of Al m Ga 1-m N, B x Al y Ga 1-xy N or In z Al f Ga 1-zf N, and the bandgap width of the back barrier layer 3 is greater than the bandgap width of the AlGaN alloy corresponding to the gradient starting point of the first layer of the AlGaN channel layer 401 with a gradient aluminum component in the multi-quantum well structure 4. For example, the aluminum component in the first layer (401) changes gradually from 0.1 to 0.2, and the gradient starting point is Al 0.1 Ga 0.9 N, then the bandgap width of the back barrier is greater than the bandgap width corresponding to Al 0.1 Ga 0.9 N.
可选地,所述衬底1厚度为0.1~10μm;所述背势垒层3厚度为0.1~5μm,所述GaN帽层5厚度为1~5nm;所述AlGaN铝组分渐变掺杂层401厚度为1~100nm,AlN量子垒层(402)厚度为1~10nm。Optionally, the substrate 1 has a thickness of 0.1-10 μm; the back barrier layer 3 has a thickness of 0.1-5 μm, the GaN cap layer 5 has a thickness of 1-5 nm; the AlGaN aluminum component graded doping layer 401 has a thickness of 1-100 nm, and the AlN quantum barrier layer (402) has a thickness of 1-10 nm.
可选地,所述源电极6和漏电极7采用Ti/Al/Ni/Au欧姆接触金属堆叠层,所述栅极8采用Ni/Au金属堆叠层。Optionally, the source electrode 6 and the drain electrode 7 are made of a Ti/Al/Ni/Au ohmic contact metal stack layer, and the gate 8 is made of a Ni/Au metal stack layer.
(三)有益效果(III) Beneficial effects
本发明至少具有以下有益效果:The present invention has at least the following beneficial effects:
本发明实施例利用III族氮化物的极化特性,通过调控铝组分渐变的AlGaN沟道层401中铝组分的渐变梯度,实现了无需杂质掺杂源的三维电子气或三维空穴气导电沟道。通过调控沟道中的三维载流子的掺杂曲线,可有效地调控晶体管在高频条件下的线性度,有利于减小高频电子线路中的信号失真和增益衰减;此外,铝组分渐变的AlGaN沟道层与AlN量子垒形成的异质结界面处同时存在极化诱导掺杂形成的高面密度二维电子气或二维空穴气,有利于提高器件的输出功率密度。同时结合AlGaN/AlN多量子阱的特殊能带结构,实现了更有效的载流子限制作用,有效减小器件漏电,可以实现器件更好的关态击穿特性和开态大偏压下的电流饱和。AlN量子垒作为插入层可减小沟道处的合金散射,进一步提高载流子迁移率。因此多量子阱结构的晶体管利用极化效应同时实现了三维电子/空穴气和二维电子/空穴气导电沟道,结合了良好的输出功率密度和良好的高频线性度;本发明所述的晶体管可基于金属极性或氮极性的III族氮化物,其中,基于氮极性AlGaN材料的N型场效应晶体管由于器件表面铝组分含量更低,有利于形成低接触电阻的欧姆接触,提高器件的电流密度。The embodiment of the present invention utilizes the polarization characteristics of group III nitrides, and realizes a three-dimensional electron gas or three-dimensional hole gas conductive channel without an impurity doping source by regulating the gradient of the aluminum component in the AlGaN channel layer 401 with a gradient aluminum component. By regulating the doping curve of the three-dimensional carriers in the channel, the linearity of the transistor under high-frequency conditions can be effectively regulated, which is beneficial to reducing signal distortion and gain attenuation in high-frequency electronic circuits; in addition, at the heterojunction interface formed by the AlGaN channel layer with a gradient aluminum component and the AlN quantum barrier, there is a high-surface-density two-dimensional electron gas or two-dimensional hole gas formed by polarization-induced doping, which is beneficial to improving the output power density of the device. At the same time, combined with the special energy band structure of the AlGaN/AlN multiple quantum well, a more effective carrier confinement effect is achieved, the device leakage is effectively reduced, and better off-state breakdown characteristics and current saturation under a large bias voltage in the on-state can be achieved. The AlN quantum barrier as an insertion layer can reduce alloy scattering at the channel and further improve the carrier mobility. Therefore, the transistor with a multi-quantum well structure utilizes the polarization effect to simultaneously realize three-dimensional electron/hole gas and two-dimensional electron/hole gas conductive channels, combining good output power density and good high-frequency linearity; the transistor described in the present invention can be based on metal polarity or nitrogen polarity Group III nitrides, among which the N-type field effect transistor based on nitrogen polarity AlGaN material is conducive to forming an ohmic contact with low contact resistance due to the lower aluminum component content on the device surface, thereby improving the current density of the device.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是本发明实施例提供的新型AlGaN基多沟道场效应晶体管的结构示意图;FIG1 is a schematic structural diagram of a novel AlGaN-based multi-channel field effect transistor provided by an embodiment of the present invention;
图2是本发明实施例提供的新型AlGaN基多沟道场效应晶体管中多量子阱结构原理示意图;FIG2 is a schematic diagram of the principle of a multi-quantum well structure in a novel AlGaN-based multi-channel field effect transistor provided by an embodiment of the present invention;
图3A是本发明一个实施例提供的金属极性N型场效应晶体管中铝组分渐变的AlGaN沟道层示意图;其中,铝组分为递增渐变;FIG3A is a schematic diagram of an AlGaN channel layer with a gradient aluminum composition in a metal polarity N-type field effect transistor provided by an embodiment of the present invention; wherein the aluminum composition is incrementally gradient;
图3B是本发明图3A提供的金属极性N型场效应晶体管的能带图;FIG3B is an energy band diagram of the metal polarity N-type field effect transistor provided in FIG3A of the present invention;
图3C是本发明图3A提供的金属极性N型场效应晶体管的电子浓度分布图;FIG3C is a diagram showing the electron concentration distribution of the metal polarity N-type field effect transistor provided in FIG3A of the present invention;
图4A是本发明另一个实施例提供的金属极性P型场效应晶体管中铝组分渐变的AlGaN沟道层示意图;其中,铝组分为递减渐变;FIG4A is a schematic diagram of an AlGaN channel layer with a gradient aluminum component in a metal polarity P-type field effect transistor provided by another embodiment of the present invention; wherein the aluminum component is a decreasing gradient;
图4B是本发明图4A提供的金属极性P型场效应晶体管的能带图;FIG4B is an energy band diagram of the metal polarity P-type field effect transistor provided in FIG4A of the present invention;
图4C是本发明图4A提供的金属极性P型场效应晶体管的电子浓度分布图;FIG4C is a diagram showing the electron concentration distribution of the metal polarity P-type field effect transistor provided in FIG4A of the present invention;
图5A是本发明又一个实施例提供的金属极性N型场效应晶体管中铝组分渐变的AlGaN沟道层示意图;其中,铝组分为递增渐变;FIG5A is a schematic diagram of an AlGaN channel layer with a gradient aluminum component in a metal polarity N-type field effect transistor provided by another embodiment of the present invention; wherein the aluminum component is gradually increased;
图5B是本发明图5A提供的金属极性N型场效应晶体管的能带图;FIG5B is an energy band diagram of the metal polarity N-type field effect transistor provided in FIG5A of the present invention;
图5C是本发明图5A提供的金属极性N型场效应晶体管的电子浓度分布图;FIG5C is a diagram showing the electron concentration distribution of the metal polarity N-type field effect transistor provided in FIG5A of the present invention;
图6是本发明实施例提供的多量子阱结构的制备方法流程图。FIG. 6 is a flow chart of a method for preparing a multi-quantum well structure provided in an embodiment of the present invention.
具体实施方式DETAILED DESCRIPTION
以下,将参照附图来描述本发明的实施例。但是应该理解,这些描述只是示例性的,而并非要限制本发明的范围。在下面的详细描述中,为便于解释,阐述了许多具体的细节以提供对本发明实施例的全面理解。然而,明显地,一个或多个实施例在没有这些具体细节的情况下也可以被实施。此外,在以下说明中,省略了对公知结构和技术的描述,以避免不必要地混淆本发明的概念。Below, embodiments of the present invention will be described with reference to the accompanying drawings. However, it should be understood that these descriptions are exemplary only and are not intended to limit the scope of the present invention. In the following detailed description, for ease of explanation, many specific details are set forth to provide a comprehensive understanding of embodiments of the present invention. However, it is apparent that one or more embodiments may also be implemented without these specific details. In addition, in the following description, descriptions of known structures and technologies are omitted to avoid unnecessary confusion of concepts of the present invention.
在此使用的术语仅仅是为了描述具体实施例,而并非意在限制本发明。在此使用的术语“包括”、“包含”等表明了所述特征、步骤、操作和/或部件的存在,但是并不排除存在或添加一个或多个其他特征、步骤、操作或部件。The terms used herein are only for describing specific embodiments and are not intended to limit the present invention. The terms "comprise", "include", etc. used herein indicate the existence of the features, steps, operations and/or components, but do not exclude the existence or addition of one or more other features, steps, operations or components.
本发明实施例提供了一种新型AlGaN基多沟道场效应晶体管,参见图1,所述晶体管包括:衬底1;依次设置在所述衬底1上的AlN缓冲层2和背势垒层3;设置于所述背势垒层3上的多量子阱结构4,所述多量子阱结构4为N层铝组分渐变的AlGaN沟道层401和设置在每两层铝组分渐变的AlGaN沟道层401之间的AlN量子垒层402,N≥2;设置于所述多量子阱结构4上的GaN帽层5;从GaN帽层5两端分别向多量子阱结构4延伸预设深度的源电极6和漏电极7,以及;设置于GaN帽层5上,且在源电极6和漏电极7之间的栅极8。An embodiment of the present invention provides a novel AlGaN-based multi-channel field effect transistor, referring to FIG1 , wherein the transistor comprises: a substrate 1; an AlN buffer layer 2 and a back barrier layer 3 sequentially arranged on the substrate 1; a multi-quantum well structure 4 arranged on the back barrier layer 3, wherein the multi-quantum well structure 4 is an N-layer AlGaN channel layer 401 with a gradient aluminum component and an AlN quantum barrier layer 402 arranged between every two layers of the AlGaN channel layer 401 with a gradient aluminum component, N≥2; a GaN cap layer 5 arranged on the multi-quantum well structure 4; a source electrode 6 and a drain electrode 7 extending from both ends of the GaN cap layer 5 to a preset depth toward the multi-quantum well structure 4, and; a gate 8 arranged on the GaN cap layer 5 and between the source electrode 6 and the drain electrode 7.
首先,需要说明的是,金属极性及氮极性的III族氮化物:III族氮化物由金属元素(Al、Ga、In)和氮(N)元素组成,在室温下以纤锌矿结构稳定存在。以GaN为例,Ga原子和N原子以四面体形式结合,同时形成沿c轴交替排列的Ga原子层和N原子层。Ga-N双原子层的排列不同决定了GaN材料的不同极性:若Ga(金属)原子层在上,则材料为Ga极性(金属极性);若N(氮)原子层在上,则材料为N(氮)极性。本发明提供的新型AlGaN基多沟道场效应晶体管可以为基于金属极性AlGaN材料的场效应晶体管,也可以为基于氮极性AlGaN材料的场效应晶体管。通过调节铝组分渐变的AlGaN沟道层中铝组分渐变梯度,通过极化诱导掺杂,无需引入掺杂杂质就可以形成高浓度的三维电子气或三维空穴气导电沟道。其中基于氮极性的N型场效应晶体管在器件处具有更低的铝组分,有利于形成低接触电阻的源漏欧姆接触,提高器件的电流密度和功率密度。First of all, it should be noted that metal polarity and nitrogen polarity III-nitrides: Group III nitrides are composed of metal elements (Al, Ga, In) and nitrogen (N) elements, and exist stably in a wurtzite structure at room temperature. Taking GaN as an example, Ga atoms and N atoms are combined in a tetrahedral form, and at the same time form Ga atomic layers and N atomic layers arranged alternately along the c-axis. The different arrangements of the Ga-N double atomic layers determine the different polarities of the GaN material: if the Ga (metal) atomic layer is on top, the material is Ga polarity (metal polarity); if the N (nitrogen) atomic layer is on top, the material is N (nitrogen) polarity. The new AlGaN-based multi-channel field effect transistor provided by the present invention can be a field effect transistor based on metal polarity AlGaN material, or it can be a field effect transistor based on nitrogen polarity AlGaN material. By adjusting the aluminum component gradient in the AlGaN channel layer with a gradient aluminum component, through polarization-induced doping, a high-concentration three-dimensional electron gas or three-dimensional hole gas conductive channel can be formed without introducing doping impurities. Among them, the nitrogen-polarity-based N-type field effect transistor has a lower aluminum component in the device, which is conducive to forming a source-drain ohmic contact with low contact resistance, thereby improving the current density and power density of the device.
由此,本发明实施例中在衬底1上外延AlN缓冲层2可以保证后续外延的晶体质量;在AlN缓冲层2上外延生长一本征掺杂的背势垒层,可以用于抑制大电压下沟道中电子向背势垒漂移引起的漏电。多量子阱结构4中铝组分渐变的AlGaN沟道层401作为量子阱,AlN量子垒层402作为量子垒,使得该器件存在多个AlGaN/AlN异质结结构。参见图2,III族氮化物材料具有自发极化和压电极化,本发明实施例中AlN和GaN的晶格常数分别为和通过计算各异质结界面处的剩余极化电荷可知,(1)在基于金属极性AlGaN材料的器件中,当AlN量子垒外延生长在铝组分渐变的AlGaN沟道层上时,二者界面处存在极化正电荷;当铝组分渐变的AlGaN沟道层外延在AlN量子垒上时,二者界面处产生极化负电荷。(2)在基于氮极性AlGaN材料的器件中,当AlN量子垒外延生长在铝组分渐变的AlGaN沟道层上时,界面处存在极化负电荷;当铝组分渐变的AlGaN沟道层外延在AlN量子垒上时,界面处产生极化正电荷。上述异质结界面产生的极化电荷会引起能带的弯曲并实现极化诱导掺杂形成导电沟道。Therefore, in the embodiment of the present invention, epitaxially growing the AlN buffer layer 2 on the substrate 1 can ensure the crystal quality of the subsequent epitaxy; epitaxially growing an intrinsically doped back barrier layer on the AlN buffer layer 2 can be used to suppress leakage caused by electrons drifting toward the back barrier in the channel under high voltage. In the multi-quantum well structure 4, the AlGaN channel layer 401 with a gradient aluminum component serves as a quantum well, and the AlN quantum barrier layer 402 serves as a quantum barrier, so that the device has multiple AlGaN/AlN heterojunction structures. Referring to FIG. 2 , the III-group nitride material has spontaneous polarization and piezoelectric polarization. In the embodiment of the present invention, the lattice constants of AlN and GaN are respectively and By calculating the residual polarization charge at each heterojunction interface, it can be known that: (1) in a device based on metal polar AlGaN material, when the AlN quantum barrier is epitaxially grown on the AlGaN channel layer with a gradient aluminum composition, there is a polarization positive charge at the interface between the two; when the AlGaN channel layer with a gradient aluminum composition is epitaxially grown on the AlN quantum barrier, a polarization negative charge is generated at the interface between the two. (2) in a device based on nitrogen polar AlGaN material, when the AlN quantum barrier is epitaxially grown on the AlGaN channel layer with a gradient aluminum composition, there is a polarization negative charge at the interface; when the AlGaN channel layer with a gradient aluminum composition is epitaxially grown on the AlN quantum barrier, a polarization positive charge is generated at the interface. The polarization charge generated at the above heterojunction interface will cause the bending of the energy band and realize polarization-induced doping to form a conductive channel.
同时铝组分渐变的AlGaN沟道层可以等效为无数个微小的突变异质结,其中每一个异质结都存在极化电场。参见图3,在金属极性的铝组分渐变的AlGaN沟道中,极化电荷在三维方向扩展,能够在整个渐变层中形成较高浓度的固定极化正电荷,并最终利用极化诱导效应形成三维电子气进行导电。同理,通过调节晶体管的极性(金属极性、氮极性)及渐变梯度(递增、递增),可以实现四种三维载流子掺杂:金属极性三维电子气掺杂;金属极性三维空穴气掺杂;氮极性三维电子气掺杂;氮极性三维空穴气掺杂。At the same time, the AlGaN channel layer with a gradient aluminum component can be equivalent to countless tiny mutant heterojunctions, each of which has a polarization electric field. Referring to Figure 3, in the AlGaN channel with a gradient aluminum component of metal polarity, the polarization charge expands in the three-dimensional direction, which can form a high concentration of fixed polarization positive charge in the entire gradient layer, and finally use the polarization induced effect to form a three-dimensional electron gas for conduction. Similarly, by adjusting the polarity (metal polarity, nitrogen polarity) and gradient (increasing, increasing) of the transistor, four types of three-dimensional carrier doping can be achieved: metal polarity three-dimensional electron gas doping; metal polarity three-dimensional hole gas doping; nitrogen polarity three-dimensional electron gas doping; nitrogen polarity three-dimensional hole gas doping.
可以得出,本发明实施例利用III族氮化物的极化特性,实现了异质结处的二维电子或空穴气以及铝组分渐变的AlGaN沟道内三维电子气或三维空穴气的结合。三维电子/空穴气的浓度仅由铝组分渐变梯度决定,这种掺杂曲线有利于器件实现恒定的跨导,从器件设计角度实现了高频下的线性传输特性,有利于减小信号传输中的增益衰减和信号失真;异质结界面处的二维电子/空穴气具有更高的载流子密度和迁移率,有利于器件的输出电流和功率密度;且AlN量子垒可以有效减小合金散射,提高了载流子迁移率;同时结合AlGaN/AlN多量子阱的特殊能带结构,实现了更有效的载流子限制作用,能有效减小器件漏电,可以实现器件更好的关态击穿特性和开态大偏压下的电流饱和。It can be concluded that the embodiment of the present invention utilizes the polarization characteristics of group III nitrides to realize the combination of two-dimensional electrons or hole gases at the heterojunction and three-dimensional electron gases or three-dimensional hole gases in the AlGaN channel with a gradual aluminum component change. The concentration of the three-dimensional electron/hole gas is determined only by the gradual gradient of the aluminum component. This doping curve is conducive to the device to achieve constant transconductance, and from the perspective of device design, it realizes linear transmission characteristics at high frequencies, which is conducive to reducing gain attenuation and signal distortion in signal transmission; the two-dimensional electron/hole gas at the heterojunction interface has a higher carrier density and mobility, which is conducive to the output current and power density of the device; and the AlN quantum barrier can effectively reduce alloy scattering and improve carrier mobility; at the same time, combined with the special band structure of AlGaN/AlN multiple quantum wells, a more effective carrier confinement effect is achieved, which can effectively reduce device leakage, and can achieve better off-state breakdown characteristics of the device and current saturation under large on-state bias.
其中,需要说明的是,上文所述III族氮化物的极化效应(即III族氮化物的极化特性):纤锌矿结构的III族氮化物在c轴方向上正负电荷的中心不重合而产生宏观极化作用,称为自发极化(Spontaneous polarization);同时材料内部的压力也能引起III族氮化物材料内部正负电荷中心的分离,该效应称为压电极化(Piezoelectric polarization),极化效应对III族氮化物材料和器件性能有着重要的影响。Among them, it should be noted that the polarization effect of the III-nitrides mentioned above (i.e., the polarization characteristics of the III-nitrides) is as follows: the centers of positive and negative charges in the c-axis direction of the wurtzite-structured III-nitrides do not coincide, resulting in a macroscopic polarization effect, which is called spontaneous polarization; at the same time, the pressure inside the material can also cause the separation of the positive and negative charge centers inside the III-nitride material, and this effect is called piezoelectric polarization. The polarization effect has an important influence on the performance of the III-nitride materials and devices.
另外,上文所述的N层铝组分渐变的AlGaN沟道层401和设置在每两层铝组分渐变的AlGaN沟道层401之间的AlN量子垒层402,N≥2;,是指:在背势垒层3上设置第一层铝组分渐变的AlGaN沟道层401,在该第一层铝组分渐变的AlGaN沟道层401上外延第一层AlN量子垒层402,然后在该第一层AlN量子垒层402上外延第二层铝组分渐变的AlGaN沟道层401,在该第二层铝组分渐变的AlGaN沟道层401上外延第二层AlN量子垒层402,然后以此类推,继续在第二层AlN量子垒层402上依次外延第三层铝组分渐变的AlGaN沟道层401、第三层AlN量子垒层402,……,第N层铝组分渐变的AlGaN沟道层401。然后在这第N层铝组分渐变的AlGaN沟道层401上即可设置GaN帽层5。In addition, the N layers of AlGaN channel layers 401 with a gradient aluminum composition and the AlN quantum barrier layers 402 arranged between every two layers of AlGaN channel layers 401 with a gradient aluminum composition, N≥2, mentioned above, refer to: a first layer of AlGaN channel layer 401 with a gradient aluminum composition is arranged on the back barrier layer 3, a first layer of AlN quantum barrier layer 402 is epitaxially grown on the first layer of AlGaN channel layer 401 with a gradient aluminum composition, and then a second layer of AlGaN channel layer 401 with a gradient aluminum composition is epitaxially grown on the first layer of AlN quantum barrier layer 402, and a second layer of AlN quantum barrier layer 402 is epitaxially grown on the second layer of AlGaN channel layer 401 with a gradient aluminum composition, and then by analogy, a third layer of AlGaN channel layer 401 with a gradient aluminum composition, a third layer of AlN quantum barrier layer 402, ..., an Nth layer of AlGaN channel layer 401 with a gradient aluminum composition is epitaxially grown on the second layer of AlN quantum barrier layer 402. Then, a GaN cap layer 5 can be disposed on the Nth AlGaN channel layer 401 with a graded aluminum composition.
在本发明实施例一种可行的方式中,所述铝组分渐变的AlGaN沟道层401中铝组分在k1到k2之间沿所述铝组分渐变的AlGaN沟道层401生长方向渐变,其中0≤k1<1,0≤k2<1。该渐变具体是指:在分子式AlxGa1-xN中x的值可以逐渐渐变。例如AlGaN薄膜中Al组分x由k1=0.1到k2=0.3线性递增、x由k1=0.6到k2=0.2线性递减等。该x的值从0到1之中的任何一个数字,比如,还可以是由Al0.001Ga0.999N渐变到Al0.231Ga0.769N等等。需要说明的是,通常情况下,铝组分渐变的AlGaN导电层401的生长方向为从下至上的方向。In a feasible manner of the embodiment of the present invention, the aluminum component in the AlGaN channel layer 401 with a gradient aluminum component gradually changes between k1 and k2 along the growth direction of the AlGaN channel layer 401 with a gradient aluminum component, wherein 0≤k1<1, 0≤k2<1. The gradient specifically means that the value of x in the molecular formula AlxGa1 -xN can gradually change. For example, the Al component x in the AlGaN film increases linearly from k1=0.1 to k2=0.3, and x decreases linearly from k1=0.6 to k2=0.2, etc. The value of x is any number from 0 to 1, for example, it can also be a gradient from Al 0.001 Ga 0.999 N to Al 0.231 Ga 0.769 N, etc. It should be noted that, under normal circumstances, the growth direction of the AlGaN conductive layer 401 with a gradient aluminum component is from bottom to top.
需要说明的是,对于基于金属极性和氮极性AlGaN材料的场效应晶体管,其铝组分渐变的AlGaN沟道层401分别可以有如下生长及对应的掺杂方案:It should be noted that, for field effect transistors based on metal polarity and nitrogen polarity AlGaN materials, the AlGaN channel layer 401 with a gradient aluminum composition can have the following growth and corresponding doping schemes:
(1)金属极性:(1) Metal polarity:
铝组分渐变的AlGaN沟道层401中铝组分沿所述铝组分渐变的AlGaN沟道层401生长方向逐渐增大,形成三维电子气沟道,所述晶体管为N型。例如:首先外延渐变层1,Al组分由a1渐变到a2,即Ala1Ga1-a1N-Ala2Ga1-a2N(a1<a2<1);在渐变层1上外延第一个AlN量子垒;随后外延渐变层2,Al组分由b1渐变到b2,即Alb1Ga1-b1N-Alb2Ga1-b2N(b1<b2<1);在外延层上外延第二个AlN量子垒;以此类推,一直到最后外延渐变层n(n≥2),Al组分由n1渐变到n2,即Aln1Ga1-n1N-Aln2Ga1-n2N(n1<n2<1);在渐变层n上外延GaN帽层,用于提高器件表面的有效势垒高度。The aluminum component in the AlGaN channel layer 401 with a gradient aluminum component gradually increases along the growth direction of the AlGaN channel layer 401 with a gradient aluminum component, forming a three-dimensional electron gas channel, and the transistor is of N-type. For example: first, epitaxially grow graded layer 1, and the Al component gradually changes from a1 to a2 , that is, Al a1 Ga 1-a1 N-Al a2 Ga 1-a2 N ( a1 < a2 <1); epitaxially grow the first AlN quantum barrier on graded layer 1; then, epitaxially grow graded layer 2, and the Al component gradually changes from b1 to b2 , that is, Al b1 Ga 1-b1 N-Al b2 Ga 1-b2 N ( b1 < b2 <1); epitaxially grow the second AlN quantum barrier on the epitaxial layer; and so on, until the last epitaxial graded layer n (n≥2) is grown, and the Al component gradually changes from n1 to n2 , that is, Al n1 Ga 1-n1 N-Al n2 Ga 1-n2 N ( n1 < n2 <1); epitaxially grow a GaN cap layer on graded layer n to increase the effective barrier height on the device surface.
组分渐变的AlGaN沟道层401中铝组分沿所述铝组分渐变的AlGaN沟道层401生长方向逐渐减小,形成三维空穴气沟道,所述晶体管为P型。例如:首先外延渐变层1,Al组分由a1渐变到a2,即Ala1Ga1-a1N-Ala2Ga1-a2N(1>a1>a2);在渐变层1上外延第一个AlN量子垒;随后外延渐变层2,Al组分由b1渐变到b2,即Alb1Ga1-b1N-Alb2Ga1-b2N(1>b1>b2);在外延层上外延第二个AlN量子垒;以此类推,一直到最后外延渐变层n(n≥2),Al组分由n1渐变到n2,即Aln1Ga1-n1N-Aln2Ga1-n2N(1>n1>n2);在渐变层n上外延GaN帽层,用于提高器件表面的有效势垒高度。The aluminum component in the AlGaN channel layer 401 with a gradient composition gradually decreases along the growth direction of the AlGaN channel layer 401 with a gradient composition, forming a three-dimensional hole gas channel, and the transistor is of P type. For example: first, epitaxially grow graded layer 1, and the Al component gradually changes from a1 to a2 , that is, Al a1 Ga 1-a1 N-Al a2 Ga 1-a2 N (1> a1 > a2 ); epitaxially grow the first AlN quantum barrier on graded layer 1; then, epitaxially grow graded layer 2, and the Al component gradually changes from b1 to b2 , that is, Al b1 Ga 1-b1 N-Al b2 Ga 1-b2 N (1> b1 > b2 ); epitaxially grow the second AlN quantum barrier on the epitaxial layer; and so on, until the last epitaxial graded layer n (n≥2) is grown, and the Al component gradually changes from n1 to n2 , that is, Al n1 Ga 1-n1 N-Al n2 Ga 1-n2 N (1> n1 > n2 ); epitaxially grow a GaN cap layer on graded layer n to increase the effective barrier height on the device surface.
(2)氮极性:AlGaN铝组分渐变掺杂层401中铝组分沿所述AlGaN铝组分渐变掺杂层401生长方向逐渐减小,形成三维电子气沟道,所述晶体管为N型。例如:首先外延渐变层1,Al组分沿生长方向由a1逐渐减小地渐变到a2,即AlalGa1-a1N-Ala2Ga1-a2N(a1>a2>1);在渐变层1上外延第一个AlN量子垒;随后外延渐变层2,Al组分沿生长方向由b1逐渐减小地渐变到b2,即Alb1Ga1-b1N-Alb2Ga1-b2N(b1>b2>1);在外延层上外延第二个AlN量子垒;以此类推,一直到最后外延渐变层n(n≥2),Al组分沿生长方向由n1逐渐减小地渐变到n2,即AlnlGa1-n1N-Aln2Ga1-n2N(n1>n2>1);在渐变层n上外延GaN帽层,用于提高器件表面的有效势垒高度。(2) Nitrogen polarity: the aluminum component in the AlGaN aluminum component graded doping layer 401 gradually decreases along the growth direction of the AlGaN aluminum component graded doping layer 401, forming a three-dimensional electron gas channel, and the transistor is N-type. For example: first, epitaxially grow graded layer 1, and the Al component gradually decreases from a1 to a2 along the growth direction, that is, AlalGa1 -a1N - Ala2Ga1 - a2N( a1 > a2 >1); epitaxially grow the first AlN quantum barrier on graded layer 1; then, epitaxially grow graded layer 2, and the Al component gradually decreases from b1 to b2 along the growth direction, that is, Alb1Ga1 -b1N - Alb2Ga1 -b2N ( b1 > b2 >1); epitaxially grow the second AlN quantum barrier on the epitaxial layer; and so on, until the last epitaxial graded layer n(n≥2), the Al component gradually decreases from n1 to n2 along the growth direction, that is, AlnlGa1 -n1N - Aln2Ga1 -n2N ( n1 > n2 >1); a GaN cap layer is epitaxially grown on the graded layer n to increase the effective barrier height on the device surface.
铝组分渐变的AlGaN沟道层401中铝组分沿所述铝组分渐变的AlGaN沟道层401生长方向逐渐增大,形成三维电子气沟道,所述晶体管为P型。例如:首先外延渐变层1,Al组分由a1渐变到a2,即Ala1Ga1-a1N-Ala2Ga1-a2N(a1<a2<1);在渐变层1上外延第一个AlN量子垒;随后外延渐变层2,Al组分由b1渐变到b2,即Alb1Ga1-b1N-Alb2Ga1-b2N(b1<b2<1);在外延层上外延第二个AlN量子垒;以此类推,一直到最后外延渐变层n(n≥2),Al组分由n1渐变到n2,即Aln1Ga1-n1N-Aln2Ga1-n2N(n1<n2<1);在渐变层n上外延GaN帽层,用于提高器件表面的有效势垒高度。The aluminum component in the AlGaN channel layer 401 with a gradient aluminum component gradually increases along the growth direction of the AlGaN channel layer 401 with a gradient aluminum component, forming a three-dimensional electron gas channel, and the transistor is of P type. For example: first, epitaxially grow graded layer 1, and the Al component gradually changes from a1 to a2 , that is, Al a1 Ga 1-a1 N-Al a2 Ga 1-a2 N ( a1 < a2 <1); epitaxially grow the first AlN quantum barrier on graded layer 1; then, epitaxially grow graded layer 2, and the Al component gradually changes from b1 to b2 , that is, Al b1 Ga 1-b1 N-Al b2 Ga 1-b2 N ( b1 < b2 <1); epitaxially grow the second AlN quantum barrier on the epitaxial layer; and so on, until the last epitaxial graded layer n (n≥2) is grown, and the Al component gradually changes from n1 to n2 , that is, Al n1 Ga 1-n1 N-Al n2 Ga 1-n2 N ( n1 < n2 <1); epitaxially grow a GaN cap layer on graded layer n to increase the effective barrier height on the device surface.
在本发明实施例一种可行的方式中,每层所述AlGaN铝组分渐变掺杂层401中铝组分渐变的起始值均相同,结束值均相同。例如,共有3层AlGaN铝组分渐变掺杂层,第一层AlGaN铝组分渐变掺杂层、第二层AlGaN铝组分渐变掺杂层和第三层AlGaN铝组分渐变掺杂层均为AlGaN薄膜中Al组分r由0.1到0.3线性递增或r由0.6到0.2线性递减。In a feasible manner of the embodiment of the present invention, the starting value of the aluminum component gradient in each layer of the AlGaN aluminum component gradient doping layer 401 is the same, and the ending value is the same. For example, there are 3 layers of AlGaN aluminum component gradient doping layers, and the first layer of AlGaN aluminum component gradient doping layer, the second layer of AlGaN aluminum component gradient doping layer, and the third layer of AlGaN aluminum component gradient doping layer are all AlGaN film Al component r linearly increases from 0.1 to 0.3 or r linearly decreases from 0.6 to 0.2.
在本发明实施例一种可行的方式中,每层所述铝组分渐变的AlGaN沟道层401中铝组分渐变的起始值均不相同,结束值均不相同。例如,共有3层AlGaN铝组分渐变掺杂层,第一层铝组分渐变的AlGaN沟道层中Al组分由a1渐变到a2,即Ala1Ga1-a1N渐变到Ala2Ga1-a2N(0≤a1<a2<1)、第二层铝组分渐变的AlGaN沟道层中Al组分由b1渐变到b2,即Alb1Ga1-b1N渐变到Alb2Ga1-b2N(0≤b1<b2<1);和第三层铝组分渐变的AlGaN沟道层中Al组分由n1渐变到n2,即Aln1Ga1-nlN-Aln2Ga1-n2N(0≤n1<n2<1)。此时,a1、b1和n1不相等,a2、b2和n2不相等。此处,以Al组分为线性递增为例进行说明,本领域技术人员可以理解的是,Al组分同样可以递减。In a feasible manner of the embodiment of the present invention, the starting value and the ending value of the aluminum composition gradient in each AlGaN channel layer 401 with the aluminum composition gradient are different. For example, there are three AlGaN aluminum composition gradient doping layers, the Al composition in the first AlGaN channel layer with aluminum composition gradient changes from a1 to a2 , that is, Al a1 Ga 1-a1 N changes gradually to Al a2 Ga 1-a2 N ( 0≤a1 < a2 <1), the Al composition in the second AlGaN channel layer with aluminum composition gradient changes gradually from b1 to b2 , that is, Al b1 Ga 1-b1 N changes gradually to Al b2 Ga 1-b2 N ( 0≤b1 < b2 <1); and the Al composition in the third AlGaN channel layer with aluminum composition gradient changes gradually from n1 to n2 , that is, Al n1 Ga 1-nl N-Al n2 Ga 1-n2 N ( 0≤n1 < n2 <1). At this time, a1 , b1 and n1 are not equal, and a2 , b2 and n2 are not equal. Here, the linear increase of Al component is taken as an example for explanation, and those skilled in the art can understand that the Al component can also decrease.
在本发明又一个可行的方式中,N>3时,在所有的所述铝组分渐变的AlGaN沟道层401中,至少有两层所述铝组分渐变的AlGaN沟道层401中铝组分渐变的起始值均相同,结束值均相同。即其中某几层的渐变的起始值可以相等,结束值可以相等,其余几层的则可以不同。In another feasible mode of the present invention, when N>3, among all the AlGaN channel layers 401 with aluminum component gradient, at least two layers of the AlGaN channel layers 401 with aluminum component gradient have the same starting value and the same ending value of the aluminum component gradient. That is, the starting value and the ending value of the gradient of some layers can be equal, and those of the remaining layers can be different.
另外,所述多量子阱结构4中所述铝组分渐变沟道层401还可以为BxAlyGa1-x-yN铝组分渐变沟道层或InzAlfGa1-z-fN铝组分渐变沟道层。所述BxAlyGa1-x-yN铝组分渐变掺杂层或InzAlfGa1-z-fN铝组分渐变掺杂层中铝组分在k1到k2之间沿所述BxAlyGa1-x-yN铝组分渐变沟道层或InzAlfGa1-z-fN铝组分渐变沟道层厚度渐变,其中0≤k1<1,0≤k2<1,k1和k2之间关系不做具体要求,即铝组分可以递增渐变,也可以递减渐变。In addition, the aluminum composition gradient channel layer 401 in the multi-quantum well structure 4 may also be a BxAlyGa1 -xyN aluminum composition gradient channel layer or an InzAlfGa1 -zfN aluminum composition gradient channel layer. The aluminum composition in the BxAlyGa1 -xyN aluminum composition gradient doping layer or the InzAlfGa1 - zfN aluminum composition gradient doping layer varies gradually between k1 and k2 along the thickness of the BxAlyGa1 - xyN aluminum composition gradient channel layer or the InzAlfGa1 -zfN aluminum composition gradient channel layer, wherein 0≤k1<1, 0≤k2<1, and there is no specific requirement for the relationship between k1 and k2, that is, the aluminum composition may vary gradually in increasing order or in decreasing order.
所述背势垒层3为AlmGa1-mN、BxAlyGa1-x-yN或InzAlfGa1-z-fN中的一种,其中0≤m<1,0≤x<1,0≤y<1,0≤z<1,0≤f<1。此处,为实现充分的载流子限制作用,防止高电压工作条件下漏电流增大和器件击穿,故需要保证背势垒层3的禁带宽度大于所述多量子阱结构4中第一层铝组分渐变沟道层401渐变起始点所对应的合金的禁带宽度。例如,第一层(401)中铝组分从0.1渐变到0.2,渐变起始点为Al0.1Ga0.9N,则背势垒的禁带宽度大于Al0.1Ga0.9N所对应的禁带宽度。The back barrier layer 3 is one of Al m Ga 1-m N, B x Al y Ga 1-xy N or In z Al f Ga 1-zf N, wherein 0≤m<1, 0≤x<1, 0≤y<1, 0≤z<1, 0≤f<1. Here, in order to achieve sufficient carrier confinement and prevent leakage current increase and device breakdown under high voltage working conditions, it is necessary to ensure that the bandgap width of the back barrier layer 3 is greater than the bandgap width of the alloy corresponding to the gradient starting point of the first aluminum component gradient channel layer 401 in the multi-quantum well structure 4. For example, the aluminum component in the first layer (401) gradually changes from 0.1 to 0.2, and the gradient starting point is Al 0.1 Ga 0.9 N, then the bandgap width of the back barrier is greater than the bandgap width corresponding to Al 0.1 Ga 0.9 N.
请参见图3A-3C,图4A-4C,图5A-5C,其分别提供了三种专利所述的包含多量子阱结构的场效应晶体管的能带图和载流子掺杂分布作为典型实例。Please refer to FIGS. 3A-3C , 4A-4C , and 5A-5C , which respectively provide energy band diagrams and carrier doping distributions of field effect transistors containing multi-quantum well structures described in three patents as typical examples.
图3A为一基于金属极性AlGaN材料的N型场效应晶体管,沟道中组分渐变的AlGaN沟道层401中铝组分沿生长方向线性增加,该晶体管中包含三个铝组分渐变的AlGaN沟道层401和两个AlN量子垒402。其能带图参见图3B,可以看到在两个铝组分渐变的AlGaN沟道层401和AlN量子垒402形成的异质结界面中形成了很窄的导电沟道;同时组分渐变的AlGaN沟道层1中形成了低于费米能级的平缓导带。该晶体管结构的电子掺杂分布参见图3C,在两个铝组分渐变的AlGaN沟道层401和AlN量子垒402形成的异质结界面中分别存在电子浓度为2.9×1019cm-3和4.3×1019cm-3的高密度二维电子气,同时在组分渐变的AlGaN沟道层1形成了密度约为1×1019cm-3的三维电子气导电沟道。FIG3A is an N-type field effect transistor based on metal polarity AlGaN material, in which the aluminum component in the AlGaN channel layer 401 with a gradient aluminum component in the channel increases linearly along the growth direction, and the transistor comprises three AlGaN channel layers 401 with a gradient aluminum component and two AlN quantum barriers 402. Its energy band diagram is shown in FIG3B , where it can be seen that a very narrow conductive channel is formed in the heterojunction interface formed by the two AlGaN channel layers 401 with a gradient aluminum component and the AlN quantum barriers 402; at the same time, a gentle conduction band below the Fermi level is formed in the AlGaN channel layer 1 with a gradient aluminum component. The electron doping distribution of the transistor structure is shown in Figure 3C. In the heterojunction interface formed by the two AlGaN channel layers 401 with gradient aluminum composition and the AlN quantum barrier 402, there are high-density two-dimensional electron gases with electron concentrations of 2.9×10 19 cm -3 and 4.3×10 19 cm -3 , respectively. At the same time, a three-dimensional electron gas conductive channel with a density of about 1×10 19 cm -3 is formed in the AlGaN channel layer 1 with gradient composition.
图4A为一基于金属极性AlGaN材料的P型场效应晶体管,沟道中组分渐变的AlGaN沟道层401中铝组分沿生长方向线性减小,该晶体管中包含三个铝组分渐变的AlGaN沟道层401和两个AlN量子垒402。其能带图参见图4B,可以看到在两个铝组分渐变的AlGaN沟道层401和AlN量子垒402形成的异质结界面中形成了很窄的导电沟道;同时组分渐变的AlGaN沟道层1中形成了高于费米能级的平缓价带。该晶体管结构的电子掺杂分布参见图4C,在两个铝组分渐变的AlGaN沟道层401和AlN量子垒402形成的异质结界面中分别存在空穴浓度为2.3×1019cm-3和5.6×1019cm-3的高密度二维空穴气,同时在组分渐变的AlGaN沟道层1形成了密度约为1×1019cm-3的三维空穴气导电沟道。FIG4A is a P-type field effect transistor based on metal polarity AlGaN material, in which the aluminum component in the AlGaN channel layer 401 with a gradient aluminum component in the channel decreases linearly along the growth direction, and the transistor comprises three AlGaN channel layers 401 with a gradient aluminum component and two AlN quantum barriers 402. Its energy band diagram is shown in FIG4B , where it can be seen that a very narrow conductive channel is formed in the heterojunction interface formed by the two AlGaN channel layers 401 with a gradient aluminum component and the AlN quantum barriers 402; at the same time, a flat valence band above the Fermi level is formed in the AlGaN channel layer 1 with a gradient aluminum component. The electron doping distribution of the transistor structure is shown in Figure 4C. In the heterojunction interface formed by the two AlGaN channel layers 401 with gradient aluminum composition and the AlN quantum barrier 402, there are high-density two-dimensional hole gases with hole concentrations of 2.3×10 19 cm -3 and 5.6×10 19 cm -3 , respectively. At the same time, a three-dimensional hole gas conductive channel with a density of about 1×10 19 cm -3 is formed in the AlGaN channel layer 1 with gradient composition.
图5A为一基于金属极性AlGaN材料的N型场效应晶体管,沟道中组分渐变的AlGaN沟道层401中铝组分沿生长方向线性减小,该晶体管中包含两个铝组分渐变的AlGaN沟道层401和一个AlN量子垒402。其能带图参见图5B,可以看到在铝组分渐变的AlGaN沟道层401和AlN量子垒402形成的异质结界面中形成了很窄的导电沟道;同时组分渐变的AlGaN沟道层1和2中均形成了低于费米能级的平缓导带。该晶体管结构的电子掺杂分布参见图5C,在铝组分渐变的AlGaN沟道层和AlN量子垒402形成的异质结界面中存在电子浓度为4×1019cm-3的高密度二维电子气,同时在组分渐变的AlGaN沟道层1形成了密度约为1×1019cm-3的三维空穴气导电沟道,在组分渐变的AlGaN沟道层2形成了密度约为4×1019cm-3的电子掺杂。其中组分渐变的AlGaN沟道层2形成的电子掺杂形状类似于杂质掺杂中的δ掺杂技术,是一种改善晶体管高频线性度的可行方案。FIG5A is an N-type field effect transistor based on metal polarity AlGaN material, in which the aluminum component in the AlGaN channel layer 401 with a gradient aluminum component in the channel decreases linearly along the growth direction, and the transistor includes two AlGaN channel layers 401 with a gradient aluminum component and an AlN quantum barrier 402. Its energy band diagram is shown in FIG5B , where it can be seen that a very narrow conductive channel is formed in the heterojunction interface formed by the AlGaN channel layer 401 with a gradient aluminum component and the AlN quantum barrier 402; at the same time, a gentle conduction band below the Fermi level is formed in both the AlGaN channel layers 1 and 2 with a gradient aluminum component. The electron doping distribution of the transistor structure is shown in FIG5C . In the heterojunction interface formed by the AlGaN channel layer with a gradient aluminum composition and the AlN quantum barrier 402, there is a high-density two-dimensional electron gas with an electron concentration of 4×10 19 cm -3 . At the same time, a three-dimensional hole gas conductive channel with a density of about 1×10 19 cm -3 is formed in the AlGaN channel layer 1 with a gradient composition, and an electron doping with a density of about 4×10 19 cm -3 is formed in the AlGaN channel layer 2 with a gradient composition. The electron doping shape formed by the AlGaN channel layer 2 with a gradient composition is similar to the delta doping technology in impurity doping, which is a feasible solution to improve the high-frequency linearity of the transistor.
所述衬底1为蓝宝石衬底,所述衬底1厚度为0.1~10μm,优选为2μm;所述背势垒层3厚度为0.1~5μm,优选为3μm。所述GaN帽层5厚度为1~5nm;所述铝组分渐变沟道层401厚度为1~100nm,AlN量子垒层402厚度为1~10nm。The substrate 1 is a sapphire substrate, and the thickness of the substrate 1 is 0.1-10 μm, preferably 2 μm; the thickness of the back barrier layer 3 is 0.1-5 μm, preferably 3 μm; the thickness of the GaN cap layer 5 is 1-5 nm; the thickness of the aluminum composition gradient channel layer 401 is 1-100 nm, and the thickness of the AlN quantum barrier layer 402 is 1-10 nm.
所述源电极6和漏电极7采用Ti/Al/Ni/Au欧姆接触金属堆叠层,所述栅极8采用Ni/Au金属堆叠层。其中,在制备源极和漏极之前,可对电极图案区域进行刻蚀,刻蚀深度具体在本发明实例中不做具体限制。栅极,源极和漏极的电极长度与宽度尺寸,以及三个电极之间的距离在本发明实例中均不做具体限制。The source electrode 6 and the drain electrode 7 are made of Ti/Al/Ni/Au ohmic contact metal stacking layers, and the gate 8 is made of Ni/Au metal stacking layers. Before preparing the source and drain electrodes, the electrode pattern area can be etched, and the etching depth is not specifically limited in the examples of the present invention. The length and width dimensions of the gate, source and drain electrodes, as well as the distances between the three electrodes are not specifically limited in the examples of the present invention.
另外,上文中所述从GaN帽层5两端分别向多量子阱结构4延伸预设深度的源电极6和漏电极7。其中本发明实施例对该预设深度不做具体限制,其可以为延伸至部分多量子阱结构4,例如延伸至第2层铝组分渐变沟道层401,也可以为延伸至全部的多量子阱结构4。In addition, the source electrode 6 and the drain electrode 7 described above extend from both ends of the GaN cap layer 5 to the multi-quantum well structure 4 at a preset depth. The embodiment of the present invention does not impose any specific limitation on the preset depth, which may extend to part of the multi-quantum well structure 4, for example, to the second aluminum composition gradient channel layer 401, or to the entire multi-quantum well structure 4.
请参见图3,本发明实施例中场效应晶体管的制备方法可以为:步骤S1,在蓝宝石衬底上生长AlN缓冲层,步骤S2,在AlN缓冲层上外延生长背势垒层,步骤S3,在所述背势垒层上N次交替生长铝组分渐变沟道层401和AlN量子垒层402,得到多量子阱结构,步骤S4,在所述多量子阱结构上外延生长GaN帽层,步骤S5,在通过步骤S1-S4得到的产品上制备源电极、漏电极和栅极8。Please refer to Figure 3. The preparation method of the field effect transistor in the embodiment of the present invention can be: step S1, growing an AlN buffer layer on a sapphire substrate, step S2, epitaxially growing a back barrier layer on the AlN buffer layer, step S3, alternately growing an aluminum component gradient channel layer 401 and an AlN quantum barrier layer 402 on the back barrier layer N times to obtain a multi-quantum well structure, step S4, epitaxially growing a GaN cap layer on the multi-quantum well structure, and step S5, preparing a source electrode, a drain electrode and a gate 8 on the product obtained by steps S1-S4.
以上所述的具体实施例,对本发明的目的、技术方案和有益效果进行了进一步详细说明,所应理解的是,以上所述仅为本发明的具体实施例而已,并不用于限制本发明,凡在本发明的精神和原则之内,所做的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The specific embodiments described above further illustrate the objectives, technical solutions and beneficial effects of the present invention in detail. It should be understood that the above description is only a specific embodiment of the present invention and is not intended to limit the present invention. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention should be included in the protection scope of the present invention.
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| CN106252403A (en) * | 2016-08-29 | 2016-12-21 | 中国科学院半导体研究所 | A kind of HEMT epitaxial structure and preparation method |
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