[go: up one dir, main page]

CN111867396B - Salty and/or spicy taste enhancer - Google Patents

Salty and/or spicy taste enhancer Download PDF

Info

Publication number
CN111867396B
CN111867396B CN201980019198.9A CN201980019198A CN111867396B CN 111867396 B CN111867396 B CN 111867396B CN 201980019198 A CN201980019198 A CN 201980019198A CN 111867396 B CN111867396 B CN 111867396B
Authority
CN
China
Prior art keywords
weight
ppm
acid
salt
spices
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201980019198.9A
Other languages
Chinese (zh)
Other versions
CN111867396A (en
Inventor
北田亮
菅野京子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Original Assignee
Ajinomoto Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc filed Critical Ajinomoto Co Inc
Publication of CN111867396A publication Critical patent/CN111867396A/en
Application granted granted Critical
Publication of CN111867396B publication Critical patent/CN111867396B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/40Table salts; Dietetic salt substitutes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L23/00Soups; Sauces; Preparation or treatment thereof

Landscapes

  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Seasonings (AREA)
  • Seeds, Soups, And Other Foods (AREA)

Abstract

The purpose of the present invention is to provide a novel salty taste and/or spicy taste enhancer, a salty taste and/or spicy taste enhancing method, etc. that can effectively enhance salty taste and/or spicy taste. The present invention relates to a salty taste and/or spicy taste enhancer containing a branched saturated aliphatic monocarboxylic acid or a salt thereof.

Description

咸味和/或辛香感增强剂Salty and/or spicy flavor enhancers

技术领域Technical Field

本发明涉及咸味和/或辛香感增强剂。另外,本发明涉及利用该咸味和/或辛香感增强剂等的食品的制造方法。进一步地,本发明涉及利用该咸味和/或辛香感增强剂等的咸味和/或辛香感的增强方法。The present invention relates to a salty and/or spicy enhancer. In addition, the present invention relates to a method for producing a food using the salty and/or spicy enhancer. Further, the present invention relates to a method for enhancing the salty and/or spicy sensation using the salty and/or spicy enhancer.

背景技术Background Art

食盐出于赋予咸味等各种用途而被应用于食品中,而食盐的过量摄取会提高引起高血压或心脏疾病等的风险,另外,由于近年来的健康意识,减少食盐的摄取量正在受到重视。食盐的摄取量可以通过在制造食品时减少食盐的使用量(减盐)等来降低,然而,这样的经减盐的食品存在因咸味不足而导致满足感降低的问题。因此,正在寻求开发不增加食盐的摄取量地增强食品咸味的技术。Salt is used in food for various purposes such as imparting saltiness, and excessive intake of salt increases the risk of causing high blood pressure or heart disease, etc. In addition, due to health awareness in recent years, reducing the intake of salt is receiving attention. The intake of salt can be reduced by reducing the amount of salt used (salt reduction) when manufacturing food, but such salt-reduced food has the problem of reduced satisfaction due to insufficient saltiness. Therefore, a technology for enhancing the saltiness of food without increasing the intake of salt is being sought.

另一方面,以往,据报告4-甲基戊酸(也被称为异己酸、4-甲基缬草酸等)可以被用作具有可可或巧克力的香味、茶风味、或者酸奶或奶酪样香味的香料组合物(专利文献1~3)。然而,专利文献1~3中均未记载4-甲基戊酸具有咸味增强效果、辛香感增强效果。On the other hand, it has been reported that 4-methylvaleric acid (also known as isocaproic acid, 4-methylvaleric acid, etc.) can be used as a flavor composition having a cocoa or chocolate flavor, a tea flavor, or a yogurt or cheese-like flavor (Patent Documents 1 to 3). However, Patent Documents 1 to 3 do not describe that 4-methylvaleric acid has a salty taste enhancement effect or a spicy flavor enhancement effect.

[现有技术文献][Prior art literature]

[专利文献][Patent Document]

专利文献1:JP特开2006-121958号公报Patent Document 1: Japanese Patent Application Publication No. 2006-121958

专利文献2:JP特开2005-143467号公报Patent Document 2: Japanese Patent Application Publication No. 2005-143467

专利文献3:JP特开2006-124490号公报Patent Document 3: Japanese Patent Application Publication No. 2006-124490

发明内容Summary of the invention

[发明所要解决的问题][Problems to be solved by the invention]

本发明的目的在于提供可以有效地增强咸味、辛香感的新型咸味和/或辛香感增强剂、咸味和/或辛香感增强方法等。The object of the present invention is to provide a novel salty and/or spicy enhancer, a salty and/or spicy enhancer method, etc., which can effectively enhance the salty and spicy taste.

[解决问题的手段][Methods of solving the problem]

本发明人为了解决上述问题进行各种研究后新发现了,分支饱和脂肪族一元羧酸具有咸味增强作用。The present inventors have made various studies to solve the above problems and have newly found that branched saturated aliphatic monocarboxylic acids have a salty taste enhancing effect.

另外,本发明人进一步进行研究后发现,除了分支饱和脂肪族一元羧酸外,通过并用3-甲硫基丙醛(methional)、丁酸、葫芦巴内酯(sotolon),可以更有效地增强咸味。In addition, the present inventors have conducted further studies and found that the salty taste can be more effectively enhanced by using 3-methylthiopropionaldehyde (methional), butyric acid, and sotolon in addition to the branched saturated aliphatic monocarboxylic acid.

另外,本发明人还新发现了,分支饱和脂肪族一元羧酸具有辛香感增强作用。In addition, the present inventors have newly discovered that branched saturated aliphatic monocarboxylic acids have a spicy aroma enhancing effect.

另外,本发明人还发现了,除了分支饱和脂肪族一元羧酸外,通过并用3-甲硫基丙醛、丁酸、葫芦巴内酯,可以更有效地增强辛香感。The present inventors have also found that the spicy aroma can be more effectively enhanced by using 3-methylmercaptopropionaldehyde, butyric acid, and trigonelline lactone in addition to the branched saturated aliphatic monocarboxylic acid.

本发明人基于这些发现进一步反复研究,从而完成了本发明。The present inventors have further conducted studies based on these findings and have completed the present invention.

即,本发明如下所述。That is, the present invention is as follows.

[1]一种咸味和/或辛香感增强剂,其含有(A)碳原子数为4~18的分支饱和脂肪族一元羧酸或其盐。[1] A salty and/or spicy flavor enhancer comprising (A) a branched saturated aliphatic monocarboxylic acid having 4 to 18 carbon atoms or a salt thereof.

[2]根据[1]所述的咸味和/或辛香感增强剂,其中,(A)为通式(I)表示的化合物或其盐:[2] The salty and/or spicy flavor enhancer according to [1], wherein (A) is a compound represented by the general formula (I) or a salt thereof:

[化1][Chemistry 1]

〔式中,R表示被至少1个C1~4烷基取代的C1~12直链亚烷基〕。[wherein R represents a C 1-12 straight-chain alkylene group substituted with at least one C 1-4 alkyl group].

[3]根据[1]或[2]所述的咸味和/或辛香感增强剂,其中,(A)为选自异丁酸、异缬草酸、2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸以及4-甲基壬酸中的至少一种化合物或其盐。[3] The salty and/or spicy flavor enhancer according to [1] or [2], wherein (A) is at least one compound selected from isobutyric acid, isovaleric acid, 2-methylvaleric acid, 3-methylvaleric acid, 4-methylvaleric acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, 4-methyloctanoic acid and 4-methylnonanoic acid, or a salt thereof.

[4]根据[1]~[3]中任一项所述的咸味和/或辛香感增强剂,其中,(A)为4-甲基戊酸或其盐。[4] The salty and/or spicy taste enhancer according to any one of [1] to [3], wherein (A) is 4-methylvaleric acid or a salt thereof.

[5]根据[1]~[4]中任一项所述的咸味和/或辛香感增强剂,其中,所述咸味和/或辛香感增强剂还含有选自(B)3-甲硫基丙醛、(C)丁酸或其盐以及(D)葫芦巴内酯中的至少一种。[5] The salty and/or spicy enhancer according to any one of [1] to [4], wherein the salty and/or spicy enhancer further contains at least one selected from (B) 3-methylthiopropionaldehyde, (C) butyric acid or a salt thereof, and (D) fenugreek lactone.

[6]根据[5]所述的咸味和/或辛香感增强剂,其中,所述咸味和/或辛香感增强剂中的(A)的含量a1和(B)的含量b1的重量比为a1:b1=1:0.01~50。[6] The salty and/or spicy enhancer according to [5], wherein the weight ratio of the content a1 of (A) to the content b1 of (B) in the salty and/or spicy enhancer is a1 : b1 =1:0.01-50.

[7]根据[5]或[6]所述的咸味和/或辛香感增强剂,其中,所述咸味和/或辛香感增强剂中的(A)的含量a1和(C)的含量c1的重量比为a1:c1=1:0.1~500。[7] The salty and/or spicy enhancer according to [5] or [6], wherein the weight ratio of the content a1 of (A) to the content c1 of (C) in the salty and/or spicy enhancer is a1 : c1 =1:0.1-500.

[8]根据[5]~[7]中任一项所述的咸味和/或辛香感增强剂,其中,所述咸味和/或辛香感增强剂中的(A)的含量a1和(D)的含量d1的重量比为a1:d1=1:0.01~50。[8] The salty and/or spicy enhancer according to any one of [5] to [7], wherein the weight ratio of the content a1 of (A) to the content d1 of (D) in the salty and/or spicy enhancer is a1 : d1 =1:0.01-50.

[9]根据[5]~[8]中任一项所述的咸味和/或辛香感增强剂,其中,所述咸味和/或辛香感增强剂含有(B)、(C)和(D)。[9] The salty and/or spicy flavor enhancer according to any one of [5] to [8], wherein the salty and/or spicy flavor enhancer contains (B), (C) and (D).

[10]根据[1]~[9]中任一项所述的咸味和/或辛香感增强剂,其中,所述咸味和/或辛香感增强剂还增强选自畜肉风味和奶酪风味中的至少一种。[10] The salty and/or spicy flavor enhancer according to any one of [1] to [9], wherein the salty and/or spicy flavor enhancer further enhances at least one selected from the group consisting of meat flavor and cheese flavor.

[11]根据[1]~[10]中任一项所述的咸味和/或辛香感增强剂,其中,所述咸味和/或辛香感增强剂为咸味增强剂。[11] The salty and/or spicy flavor enhancer according to any one of [1] to [10], wherein the salty and/or spicy flavor enhancer is a salty flavor enhancer.

[11-2]根据[1]~[10]中任一项所述的咸味和/或辛香感增强剂,其中,所述咸味和/或辛香感增强剂为辛香感增强剂。[11-2] The salty and/or spicy enhancer according to any one of [1] to [10], wherein the salty and/or spicy enhancer is a spicy enhancer.

[11-3]根据[1]~[10]中任一项所述的咸味和/或辛香感增强剂,其中,所述咸味和/或辛香感增强剂为咸味和辛香感增强剂。[11-3] The salty and/or spicy enhancer according to any one of [1] to [10], wherein the salty and/or spicy enhancer is a salty and spicy enhancer.

[12]一种含有食盐和/或辛香料的食品,其含有[1]~[11]中任一项所述的咸味和/或辛香感增强剂。[12] A food containing salt and/or spices, which contains the salty and/or spicy flavor enhancer according to any one of [1] to [11].

[13]根据[12]所述的含有食盐和/或辛香料的食品,其中,所述咸味和/或辛香感增强剂中的(A)的含量为0.01重量%以上、100重量%以下。[13] The food containing salt and/or spice according to [12], wherein the content of (A) in the salty and/or spicy enhancer is 0.01% by weight or more and 100% by weight or less.

[14]根据[12]或[13]所述的含有食盐和/或辛香料的食品,其中,所述咸味和/或辛香感增强剂含有(B),所述咸味和/或辛香感增强剂中的(B)的含量为0.01重量%以上、99.9重量%以下。[14] The food containing salt and/or spices according to [12] or [13], wherein the salty taste and/or spicy aroma enhancer contains (B), and the content of (B) in the salty taste and/or spicy aroma enhancer is greater than 0.01% by weight and less than 99.9% by weight.

[15]根据[12]~[14]中任一项所述的含有食盐和/或辛香料的食品,其中,所述咸味和/或辛香感增强剂含有(C),所述咸味和/或辛香感增强剂中的(C)的含量为0.01重量%以上、99.9重量%以下。[15] The food containing salt and/or spices according to any one of [12] to [14], wherein the salty taste and/or spicy aroma enhancer contains (C), and the content of (C) in the salty taste and/or spicy aroma enhancer is greater than 0.01% by weight and less than 99.9% by weight.

[16]根据[12]~[15]中任一项所述的含有食盐和/或辛香料的食品,其中,所述咸味和/或辛香感增强剂含有(D),所述咸味和/或辛香感增强剂中的(D)的含量为0.01重量%以上、99.9重量%以下。[16] The food containing salt and/or spices according to any one of [12] to [15], wherein the salty taste and/or spicy aroma enhancer contains (D), and the content of (D) in the salty taste and/or spicy aroma enhancer is greater than 0.01% by weight and less than 99.9% by weight.

[17]一种含有食盐和/或辛香料的食品的制造方法,其包括:添加(A)碳原子数为4~18的分支饱和脂肪族一元羧酸或其盐。[17] A method for producing a food containing salt and/or spices, comprising: adding (A) a branched saturated aliphatic monocarboxylic acid having 4 to 18 carbon atoms or a salt thereof.

[18]根据[17]所述的制造方法,其中,(A)为通式(I)表示的化合物或其盐:[18] The production method according to [17], wherein (A) is a compound represented by the general formula (I) or a salt thereof:

[化2][Chemistry 2]

〔式中,R表示被至少1个C1~4烷基取代的C1~12直链亚烷基〕。[wherein R represents a C 1-12 straight-chain alkylene group substituted with at least one C 1-4 alkyl group].

[19]根据[17]或[18]所述的制造方法,其中,(A)为选自异丁酸、异缬草酸、2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸以及4-甲基壬酸中的至少一种化合物或其盐。[19] The production method according to [17] or [18], wherein (A) is at least one compound or a salt thereof selected from isobutyric acid, isovaleric acid, 2-methylvaleric acid, 3-methylvaleric acid, 4-methylvaleric acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, 4-methyloctanoic acid and 4-methylnonanoic acid.

[20]根据[17]~[19]中任一项所述的制造方法,其中,(A)为4-甲基戊酸或其盐。[20] The production method according to any one of [17] to [19], wherein (A) is 4-methylvaleric acid or a salt thereof.

[21]根据[17]~[20]中任一项所述的制造方法,其中,(A)的添加量为0.00005重量ppm以上、15重量ppm以下。[21] The production method according to any one of [17] to [20], wherein the amount of (A) added is 0.00005 wt ppm or more and 15 wt ppm or less.

[22]根据[17]~[21]中任一项所述的制造方法,其中,所述制造方法还包括:添加选自(B)3-甲硫基丙醛、(C)丁酸或其盐以及(D)葫芦巴内酯中的至少一种。[22] The production method according to any one of [17] to [21], wherein the production method further comprises: adding at least one selected from (B) 3-methylthiopropionaldehyde, (C) butyric acid or a salt thereof, and (D) fenugreek lactone.

[23]根据[22]所述的制造方法,其中,(A)的添加量a2和(B)的添加量b2的重量比为a2:b2=1:0.01~50。[23] The production method according to [22], wherein the weight ratio of the addition amount a2 of (A) to the addition amount b2 of (B) is a2 : b2 =1:0.01-50.

[24]根据[22]或[23]所述的制造方法,其中,(A)的添加量a2和(C)的添加量c2的重量比为a2:c2=1:0.1~500。[24] The production method according to [22] or [23], wherein the weight ratio of the addition amount a2 of (A) to the addition amount c2 of (C) is a2 : c2 =1:0.1-500.

[25]根据[22]~[24]中任一项所述的制造方法,其中,(A)的添加量a2和(D)的添加量d2的重量比为a2:d2=1:0.01~50。[25] The production method according to any one of [22] to [24], wherein the weight ratio of the addition amount a2 of (A) to the addition amount d2 of (D) is a2 : d2 =1:0.01-50.

[26]根据[22]~[25]中任一项所述的制造方法,其中,(B)的添加量为0.001重量ppm以上、10重量ppm以下。[26] The production method according to any one of [22] to [25], wherein the amount of (B) added is 0.001 ppm by weight or more and 10 ppm by weight or less.

[27]根据[22]~[26]中任一项所述的制造方法,其中,(C)的添加量为0.01重量ppm以上、100重量ppm以下。[27] The production method according to any one of [22] to [26], wherein the amount of (C) added is 0.01 ppm by weight or more and 100 ppm by weight or less.

[28]根据[22]~[27]中任一项所述的制造方法,其中,(D)的添加量为0.0001重量ppm以上、50重量ppm以下。[28] The production method according to any one of [22] to [27], wherein the amount of (D) added is 0.0001 ppm by weight or more and 50 ppm by weight or less.

[29]根据[22]~[28]中任一项所述的制造方法,其中,在所述含有食盐和/或辛香料的食品中添加(B)、(C)和(D)。[29] The production method according to any one of [22] to [28], wherein (B), (C) and (D) are added to the food containing salt and/or spices.

[30]根据[17]~[29]中任一项所述的制造方法,其中,所述含有食盐和/或辛香料的食品为咸味和/或辛香感得到增强的食品。[30] The production method according to any one of [17] to [29], wherein the food containing salt and/or spices is a food with enhanced salty and/or spicy taste.

[31]根据[30]所述的制造方法,其中,所述含有食盐和/或辛香料的食品为选自畜肉风味和奶酪风味中的至少一种也得到增强的食品。[31] The production method according to [30], wherein the food containing salt and/or spices is a food in which at least one of meat flavor and cheese flavor is also enhanced.

[32]根据[17]~[31]中任一项所述的制造方法,其中,所述制造方法为含有食盐的食品的制造方法。[32] The production method according to any one of [17] to [31], wherein the production method is a method for producing a food containing salt.

[32-2]根据[17]~[31]中任一项所述的制造方法,其中,所述制造方法为含有辛香料的食品的制造方法。[32-2] The production method according to any one of [17] to [31], wherein the production method is a method for producing a food containing spice.

[32-3]根据[17]~[31]中任一项所述的制造方法,其中,所述制造方法为含有食盐和辛香料的食品的制造方法。[32-3] The production method according to any one of [17] to [31], wherein the production method is a method for producing a food containing salt and spices.

[33]一种含有食盐的食品的咸味增强方法,其包括:添加(A)碳原子数为4~18的分支饱和脂肪族一元羧酸或其盐。[33] A method for enhancing the salty taste of food containing salt, comprising: adding (A) a branched saturated aliphatic monocarboxylic acid having 4 to 18 carbon atoms or a salt thereof.

[34]一种含有辛香料的食品的辛香感增强方法,其包括:添加(A)碳原子数为4~18的分支饱和脂肪族一元羧酸或其盐。[34] A method for enhancing the spiciness of food containing spices, comprising: adding (A) a branched saturated aliphatic monocarboxylic acid having 4 to 18 carbon atoms or a salt thereof.

[34-2]一种含有食盐和辛香料的食品的咸味和辛香感增强方法,其包括:添加(A)碳原子数为4~18的分支饱和脂肪族一元羧酸或其盐。[34-2] A method for enhancing the saltiness and spiciness of food containing salt and spices, comprising: adding (A) a branched saturated aliphatic monocarboxylic acid having 4 to 18 carbon atoms or a salt thereof.

[35]根据[33]或[34]所述的增强方法,其中,(A)为通式(I)表示的化合物或其盐:[35] The enhancement method according to [33] or [34], wherein (A) is a compound represented by the general formula (I) or a salt thereof:

[化3][Chemistry 3]

〔式中,R表示被至少1个C1~4烷基取代的C1~12直链亚烷基〕。[wherein R represents a C 1-12 straight-chain alkylene group substituted with at least one C 1-4 alkyl group].

[36]根据[33]~[35]中任一项所述的增强方法,其中,(A)为选自异丁酸、异缬草酸、2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸以及4-甲基壬酸中的至少一种化合物或其盐。[36] The enhancement method according to any one of [33] to [35], wherein (A) is at least one compound or a salt thereof selected from isobutyric acid, isovaleric acid, 2-methylvaleric acid, 3-methylvaleric acid, 4-methylvaleric acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, 4-methyloctanoic acid and 4-methylnonanoic acid.

[37]根据[33]~[36]中任一项所述的增强方法,其中,(A)为4-甲基戊酸或其盐。[37] The enhancement method according to any one of [33] to [36], wherein (A) is 4-methylvaleric acid or a salt thereof.

[38]根据[33]~[37]中任一项所述的增强方法,其中,(A)的添加量为0.00005重量ppm以上、15重量ppm以下。[38] The reinforcement method according to any one of [33] to [37], wherein the amount of (A) added is 0.00005 ppm by weight or more and 15 ppm by weight or less.

[39]根据[33]~[38]中任一项所述的增强方法,其中,所述增强方法还包括:添加选自(B)3-甲硫基丙醛、(C)丁酸或其盐以及(D)葫芦巴内酯中的至少一种。[39] The enhancement method according to any one of [33] to [38], wherein the enhancement method further comprises: adding at least one selected from (B) 3-methylthiopropionaldehyde, (C) butyric acid or a salt thereof, and (D) fenugreek lactone.

[40]根据[39]所述的增强方法,其中,(A)的添加量a3和(B)的添加量b3的重量比为a3:b3=1:0.01~50。[40] The reinforcing method according to [39], wherein the weight ratio of the addition amount a3 of (A) to the addition amount b3 of (B) is a3 : b3 =1:0.01-50.

[41]根据[39]或[40]所述的增强方法,其中,(A)的添加量a3和(C)的添加量c3的重量比为a3:c3=1:0.1~500。[41] The reinforcing method according to [39] or [40], wherein the weight ratio of the addition amount a3 of (A) to the addition amount c3 of (C) is a3 : c3 =1:0.1-500.

[42]根据[39]~[41]中任一项所述的增强方法,其中,(A)的添加量a3和(D)的添加量d3的重量比为a3:d3=1:0.01~50。[42] The reinforcing method according to any one of [39] to [41], wherein the weight ratio of the addition amount a3 of (A) to the addition amount d3 of (D) is a3 : d3 =1:0.01-50.

[43]根据[39]~[42]中任一项所述的增强方法,其中,(B)的添加量为0.001重量ppm以上、10重量ppm以下。[43] The reinforcement method according to any one of [39] to [42], wherein the amount of (B) added is 0.001 ppm by weight or more and 10 ppm by weight or less.

[44]根据[39]~[43]中任一项所述的增强方法,其中,(C)的添加量为0.01重量ppm以上、100重量ppm以下。[44] The reinforcement method according to any one of [39] to [43], wherein the amount of (C) added is 0.01 ppm by weight or more and 100 ppm by weight or less.

[45]根据[39]~[44]中任一项所述的增强方法,其中,(D)的添加量为0.0001重量ppm以上、50重量ppm以下。[45] The reinforcement method according to any one of [39] to [44], wherein the amount of (D) added is 0.0001 ppm by weight or more and 50 ppm by weight or less.

[46]根据[39]~[45]中任一项所述的增强方法,其中,在所述含有食盐和/或辛香料的食品中,添加(B)、(C)和(D)。[46] The enhancement method according to any one of [39] to [45], wherein (B), (C) and (D) are added to the food containing salt and/or spices.

[47]根据[33]~[46]中任一项所述的增强方法,其中,所述增强方法还增强选自畜肉风味和奶酪风味中的至少一种。[47] The enhancement method according to any one of [33] to [46], wherein the enhancement method further enhances at least one selected from the group consisting of livestock flavor and cheese flavor.

[发明效果][Effects of the invention]

根据本发明,可以提供可以有效地增强咸味、辛香感的新型咸味和/或辛香感增强剂。此外,本发明的咸味和/或辛香感增强剂不仅可以增强咸味、辛香感,而且可以增强畜肉风味、奶酪风味。According to the present invention, a novel salty taste and/or spicy flavor enhancer that can effectively enhance salty taste and spicy flavor can be provided. In addition, the salty taste and/or spicy flavor enhancer of the present invention can not only enhance salty taste and spicy flavor, but also enhance the flavor of livestock meat and cheese.

此外,根据本发明,可以制造咸味得到有效增强的含有食盐的食品。本发明的制造方法可以制造不仅咸味得到增强而且畜肉风味、奶酪风味得到增强的含有食盐的食品。此外,根据本发明,还可以制造辛香感得到有效增强的含有辛香料的食品。进一步地,根据本发明,可以制造咸味和辛香感得到增强的含有食盐和辛香料的食品。In addition, according to the present invention, a food containing salt whose saltiness is effectively enhanced can be manufactured. The manufacturing method of the present invention can manufacture a food containing salt whose saltiness is not only enhanced but also whose meat flavor and cheese flavor are enhanced. In addition, according to the present invention, a food containing spices whose spiciness is effectively enhanced can be manufactured. Further, according to the present invention, a food containing salt and spices whose saltiness and spiciness are enhanced can be manufactured.

此外,根据本发明,可以有效地增强含有食盐的食品的咸味。本发明的增强方法不仅可以增强咸味,而且可以增强畜肉风味、奶酪风味。此外,根据本发明,可以有效地增强含有辛香料的食品的辛香感。进一步地,根据本发明,可以有效地增强含有食盐和辛香料的食品的咸味和辛香感。In addition, according to the present invention, the saltiness of foods containing salt can be effectively enhanced. The enhancement method of the present invention can not only enhance the saltiness, but also enhance the flavor of livestock and cheese. In addition, according to the present invention, the spiciness of foods containing spices can be effectively enhanced. Further, according to the present invention, the saltiness and spiciness of foods containing salt and spices can be effectively enhanced.

此外,无论含有食盐的食品、含有辛香料的食品、含有食盐和辛香料的食品的种类,本发明都可以通用地增强各种各样的食品中的咸味、辛香感。Furthermore, the present invention can universally enhance the salty and spicy taste in a variety of foods, regardless of the types of foods containing salt, foods containing spices, or foods containing salt and spices.

具体实施方式DETAILED DESCRIPTION

(本发明的咸味和/或辛香感增强剂)(Salty and/or spicy flavor enhancer of the present invention)

本发明的咸味和/或辛香感增强剂(本说明书中,有时有称为“本发明的剂”的情况)的主要特征在于:其含有(A)分支饱和脂肪族一元羧酸或其盐(本说明书中,有时有简称为“(A)”的情况)作为有效成分。The salty and/or spicy enhancer of the present invention (sometimes referred to as "the agent of the present invention" in this specification) is mainly characterized in that it contains (A) a branched saturated aliphatic monocarboxylic acid or a salt thereof (sometimes referred to as "(A)" in this specification) as an active ingredient.

[(A)分支饱和脂肪族一元羧酸或其盐][(A) Branched saturated aliphatic monocarboxylic acid or its salt]

本发明中使用的“分支饱和脂肪族一元羧酸”是指,碳链仅由单键构成且碳链上具有至少一个分支的脂肪族一元羧酸。分支饱和脂肪族一元羧酸的碳原子数优选为4~18,更优选为4~14,进一步优选为6~12,特别优选为6~10。The "branched saturated aliphatic monocarboxylic acid" used in the present invention refers to an aliphatic monocarboxylic acid whose carbon chain consists only of single bonds and has at least one branch on the carbon chain. The number of carbon atoms in the branched saturated aliphatic monocarboxylic acid is preferably 4 to 18, more preferably 4 to 14, further preferably 6 to 12, and particularly preferably 6 to 10.

本发明中使用的分支饱和脂肪族一元羧酸优选为下述通式(I)表示的化合物(以下,有时有称为化合物(I)的情况)The branched saturated aliphatic monocarboxylic acid used in the present invention is preferably a compound represented by the following general formula (I) (hereinafter, sometimes referred to as compound (I)):

通式(I):General formula (I):

[化4][Chemistry 4]

〔式中,R表示被至少1个C1~4烷基取代的C1~12直链亚烷基〕[wherein R represents a C 1-12 straight-chain alkylene group substituted with at least one C 1-4 alkyl group]

R中的“C1~12直链亚烷基”是指,碳原子数为1~12的直链状亚烷基,具体地为亚甲基、亚乙基、亚丙基、亚丁基、亚戊基、亚己基、亚庚基、亚辛基、亚壬基、亚癸基、亚十一烷基、亚十二烷基。其中,优选C1-10直链亚烷基,更优选C1-8直链亚烷基,特别优选C3-8直链亚烷基。The "C 1-12 straight chain alkylene" in R refers to a straight chain alkylene group having 1 to 12 carbon atoms, specifically methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, nonylene, decylene, undecylene, and dodecylene. Among them, C 1-10 straight chain alkylene is preferred, C 1-8 straight chain alkylene is more preferred, and C 3-8 straight chain alkylene is particularly preferred.

R中的C1~12直链亚烷基优选被至少1个C1~4烷基取代(即,C1~12直链亚烷基中的至少1个氢原子被C1~4烷基取代),更优选被1~4个C1~4烷基取代,进一步优选被1个或2个C1~4烷基取代,特别优选被1个C1~4烷基取代。The C 1-12 straight-chain alkylene group in R is preferably substituted by at least one C 1-4 alkyl group (i.e., at least one hydrogen atom in the C 1-12 straight-chain alkylene group is substituted by a C 1-4 alkyl group), more preferably substituted by 1 to 4 C 1-4 alkyl groups, further preferably substituted by 1 or 2 C 1-4 alkyl groups, and particularly preferably substituted by 1 C 1-4 alkyl group.

R中的“C1-4烷基”是指直链状或支链状的碳原子数为1~4的烷基,可列举例如甲基、乙基、丙基、丁基等。其中,优选甲基、乙基,更优选甲基。The "C 1-4 alkyl group" in R refers to a linear or branched alkyl group having 1 to 4 carbon atoms, and examples thereof include methyl, ethyl, propyl, butyl, etc. Among them, methyl and ethyl are preferred, and methyl is more preferred.

R优选为被至少1个甲基取代的C1~12直链亚烷基,更优选为被1个或2个甲基取代的C1~10直链亚烷基,进一步优选为被1个甲基取代的C1~8直链亚烷基,特别优选为被1个甲基取代的C3~8直链亚烷基。R is preferably a C 1-12 straight chain alkylene group substituted with at least one methyl group, more preferably a C 1-10 straight chain alkylene group substituted with one or two methyl groups, further preferably a C 1-8 straight chain alkylene group substituted with one methyl group, and particularly preferably a C 3-8 straight chain alkylene group substituted with one methyl group.

作为化合物(I)的具体示例,可列举异丁酸、异缬草酸、2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸、4-甲基壬酸等,优选为2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸、4-甲基壬酸,特别优选为4-甲基戊酸。Specific examples of compound (I) include isobutyric acid, isovaleric acid, 2-methylpentanoic acid, 3-methylpentanoic acid, 4-methylpentanoic acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, 4-methyloctanoic acid, and 4-methylnonanoic acid. Preferred are 2-methylpentanoic acid, 3-methylpentanoic acid, 4-methylpentanoic acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, 4-methyloctanoic acid, and 4-methylnonanoic acid. Particularly preferred is 4-methylpentanoic acid.

异丁酸(也被称为2-甲基丙酸)由下述式表示,其CAS登录号为79-31-2。Isobutyric acid (also known as 2-methylpropionic acid) is represented by the following formula and its CAS registration number is 79-31-2.

[化5][Chemistry 5]

异缬草酸(也被称为3-甲基丁酸)由下述式表示,其CAS登录号为503-74-2。Isovaleric acid (also known as 3-methylbutyric acid) is represented by the following formula and its CAS registration number is 503-74-2.

[化6][Chemistry 6]

2-甲基戊酸由下述式表示,其CAS登录号为97-61-0。2-Methylvaleric acid is represented by the following formula and its CAS registration number is 97-61-0.

[化7][Chemistry 7]

3-甲基戊酸由下述式表示,其CAS登录号为105-43-1。3-Methylvaleric acid is represented by the following formula and its CAS registration number is 105-43-1.

[化8][Chemistry 8]

4-甲基戊酸由下述式表示,其CAS登录号为646-07-1。4-Methylvaleric acid is represented by the following formula and its CAS registration number is 646-07-1.

[化9][Chemistry 9]

2-甲基己酸由下述式表示,其CAS登录号为4536-23-6。2-Methylhexanoic acid is represented by the following formula and its CAS registration number is 4536-23-6.

[化10][Chemistry 10]

5-甲基己酸由下述式表示,其CAS登录号为628-46-6。5-Methylhexanoic acid is represented by the following formula and its CAS registration number is 628-46-6.

[化11][Chemistry 11]

2-甲基庚酸由下述式表示,其CAS登录号为1188-02-9。2-Methylheptanoic acid is represented by the following formula and its CAS registration number is 1188-02-9.

[化12][Chemistry 12]

4-甲基辛酸由下述式表示,其CAS登录号为54947-74-9。4-Methyloctanoic acid is represented by the following formula, and its CAS registration number is 54947-74-9.

[化13][Chemistry 13]

4-甲基壬酸由下述式表示,其CAS登录号为45019-28-1。4-Methylnonanoic acid is represented by the following formula and its CAS registration number is 45019-28-1.

[化14][Chemistry 14]

从咸味增强效果的角度考虑,化合物(I)优选为异丁酸、异缬草酸、3-甲基戊酸、4-甲基戊酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸、4-甲基壬酸,更优选为3-甲基戊酸、4-甲基戊酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸、4-甲基壬酸。From the perspective of the salty taste enhancement effect, compound (I) is preferably isobutyric acid, isovaleric acid, 3-methylpentanoic acid, 4-methylpentanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, 4-methyloctanoic acid, 4-methylnonanoic acid, and more preferably 3-methylpentanoic acid, 4-methylpentanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, 4-methyloctanoic acid, 4-methylnonanoic acid.

从辛香感增强效果的角度考虑,化合物(I)优选为异丁酸、异缬草酸、3-甲基戊酸、4-甲基戊酸、5-甲基己酸、4-甲基辛酸、4-甲基壬酸,更优选为3-甲基戊酸、4-甲基戊酸、5-甲基己酸、4-甲基辛酸、4-甲基壬酸。From the perspective of the spicy aroma enhancement effect, compound (I) is preferably isobutyric acid, isovaleric acid, 3-methylvaleric acid, 4-methylvaleric acid, 5-methylhexanoic acid, 4-methyloctanoic acid, 4-methylnonanoic acid, and more preferably 3-methylvaleric acid, 4-methylvaleric acid, 5-methylhexanoic acid, 4-methyloctanoic acid, 4-methylnonanoic acid.

作为本发明中使用的分支饱和脂肪族一元羧酸的盐,只要其为可食用性的盐且不损害本发明的目的就没有特别限定,可列举例如与钠、钾等碱金属的盐;与钙、镁等碱土金属的盐;铵盐;铝盐;锌盐;与三乙胺、乙醇胺、吗啉、吡咯烷、哌啶、哌嗪、二环己胺等有机胺的盐;与精氨酸、赖氨酸等碱性氨基酸的盐。这些盐可为水合物(水合盐),作为这样的水合物,可列举例如1~6水合物等。这些盐可单独使用任一种,或者可组合使用2种以上。The salt of the branched saturated aliphatic monocarboxylic acid used in the present invention is not particularly limited as long as it is an edible salt and does not impair the purpose of the present invention, and examples thereof include salts with alkali metals such as sodium and potassium; salts with alkaline earth metals such as calcium and magnesium; ammonium salts; aluminum salts; zinc salts; salts with organic amines such as triethylamine, ethanolamine, morpholine, pyrrolidine, piperidine, piperazine, and dicyclohexylamine; and salts with basic amino acids such as arginine and lysine. These salts may be hydrates (hydrated salts), and examples of such hydrates include 1 to 6 hydrates. Any of these salts may be used alone, or two or more may be used in combination.

(A)的制造方法没有特别限定,可使用通过本身已知的方法或以此为准的方法制得者。(A)可使用市售品,由于简便而优选。The production method of (A) is not particularly limited, and those produced by a known method or a method equivalent thereto can be used. (A) can be a commercially available product, which is preferred because of its simplicity.

本发明中,(A)可单独使用1种,或者可组合使用2种以上。In the present invention, (A) may be used alone or in combination of two or more.

相对于本发明的剂,本发明的剂中的(A)的含量(本说明书中,有时有称为“a1”或“(A)的含量a1”的情况)优选为0.01重量%以上,更优选为0.1重量%以上,特别优选为1重量%以上。另外,相对于本发明的剂,该a1优选为100重量%以下,更优选为99.9重量%以下,进一步优选为99重量%以下,特别优选为90重量%以下。The content of (A) in the agent of the present invention (sometimes referred to as " a1 " or "content a1 of (A)" in this specification) is preferably 0.01% by weight or more, more preferably 0.1% by weight or more, and particularly preferably 1% by weight or more, relative to the agent of the present invention. In addition, a1 is preferably 100% by weight or less, more preferably 99.9% by weight or less, further preferably 99% by weight or less, and particularly preferably 90% by weight or less, relative to the agent of the present invention.

本说明书中,“(A)的含量”是指,例如,在本发明的剂仅含有1种(A)时,其是指该1种(A)的含量,在本发明的剂含有2种以上(A)时,其是指它们的合计含量。另外,在(A)含有盐时,该盐的重量被换算为游离形式的重量。In this specification, "content of (A)" means, for example, when the agent of the present invention contains only one (A), it means the content of the one (A), and when the agent of the present invention contains two or more (A), it means the total content of them. In addition, when (A) contains a salt, the weight of the salt is converted to the weight of the free form.

优选地,本发明的剂除了含有(A)之外,还含有选自(B)3-甲硫基丙醛(本说明书中,有时有简称为“(B)”的情况)、(C)丁酸或其盐(本说明书中,有时有简称为“(C)”的情况)以及(D)葫芦巴内酯(本说明书中,有时有简称为“(D)”的情况)中的至少一种。本发明的剂,通过除了含有(A)之外,还含有选自(B)、(C)和(D)中的至少一种,可以更有效地增强咸味、辛香感。Preferably, the agent of the present invention contains at least one selected from (B) 3-methylthiopropionaldehyde (sometimes referred to as "(B)" in this specification), (C) butyric acid or a salt thereof (sometimes referred to as "(C)" in this specification), and (D) fenugreek lactone (sometimes referred to as "(D)" in this specification) in addition to (A). The agent of the present invention can more effectively enhance the salty taste and spicy aroma by containing at least one selected from (B), (C) and (D) in addition to (A).

[(B)3-甲硫基丙醛][(B)3-Methylthiopropionaldehyde]

本发明中使用的3-甲硫基丙醛由下述式表示,其CAS登录号为3268-49-3。3-Methylthiopropionaldehyde used in the present invention is represented by the following formula, and its CAS registration number is 3268-49-3.

[化15][Chemistry 15]

[(C)丁酸或其盐][(C) butyric acid or its salt]

本发明中使用的丁酸由下述式表示,其CAS登录号为107-92-6。The butyric acid used in the present invention is represented by the following formula, and its CAS registration number is 107-92-6.

[化16][Chemistry 16]

作为本发明中使用的丁酸的盐,只要其为可食用性的盐且不损害本发明的目的就没有特别限定,可列举例如与钠、钾等碱金属的盐;与钙、镁等碱土金属的盐;铵盐;铝盐;锌盐;与三乙胺、乙醇胺、吗啉、吡咯烷、哌啶、哌嗪、二环己胺等有机胺的盐;与精氨酸、赖氨酸等碱性氨基酸的盐。这些盐可为水合物(水合盐),作为这样的水合物,可列举例如1~6水合物等。这些盐可单独使用任一种,或者可组合使用2种以上。The salt of butyric acid used in the present invention is not particularly limited as long as it is an edible salt and does not impair the purpose of the present invention, and examples thereof include salts with alkali metals such as sodium and potassium; salts with alkaline earth metals such as calcium and magnesium; ammonium salts; aluminum salts; zinc salts; salts with organic amines such as triethylamine, ethanolamine, morpholine, pyrrolidine, piperidine, piperazine, and dicyclohexylamine; and salts with basic amino acids such as arginine and lysine. These salts may be hydrates (hydrated salts), and examples of such hydrates include 1 to 6 hydrates. Any of these salts may be used alone, or two or more may be used in combination.

[(D)葫芦巴内酯][(D)Trigonelline]

本发明中使用的葫芦巴内酯由下述式表示,其CAS登录号为28664-35-9。The trigonelline lactone used in the present invention is represented by the following formula, and its CAS registration number is 28664-35-9.

[化17][Chemistry 17]

(B)、(C)、(D)的制造方法均没有特别限制,可使用通过本身已知的方法或以此为准的方法制得者。(B)、(C)、(D)可分别使用市售品,由于简便而优选。The production methods of (B), (C), and (D) are not particularly limited, and those produced by known methods or methods equivalent thereto can be used. Commercial products can be used for (B), (C), and (D), respectively, and are preferably used for simplicity.

本发明的剂含有(B)时,相对于本发明的剂,本发明的剂中的(B)的含量(本说明书中,有时有称为“b1”或“(B)的含量b1”的情况)优选为0.01重量%以上,更优选为0.1重量%以上,特别优选为1重量%以上。另外,相对于本发明的剂,该b1优选为99.9重量%以下,更优选为99重量%以下,特别优选为90重量%以下。When the agent of the present invention contains (B), the content of (B) in the agent of the present invention (sometimes referred to as "b 1 " or "content b 1 of (B)" in this specification) is preferably 0.01% by weight or more, more preferably 0.1% by weight or more, and particularly preferably 1% by weight or more, relative to the agent of the present invention. In addition, b 1 is preferably 99.9% by weight or less, more preferably 99% by weight or less, and particularly preferably 90% by weight or less, relative to the agent of the present invention.

本发明的剂含有(C)时,相对于本发明的剂,本发明的剂中的(C)的含量(本说明书中,有时有称为“c1”或“(C)的含量c1”的情况)优选为0.01重量%以上,更优选为0.1重量%以上,特别优选为1重量%以上。另外,相对于本发明的剂,该c1优选为99.9重量%以下,更优选为99重量%以下,特别优选为90重量%以下。When the agent of the present invention contains (C), the content of (C) in the agent of the present invention (sometimes referred to as "c 1 " or "content c 1 of (C)" in this specification) is preferably 0.01% by weight or more, more preferably 0.1% by weight or more, and particularly preferably 1% by weight or more, relative to the agent of the present invention. Furthermore, c 1 is preferably 99.9% by weight or less, more preferably 99% by weight or less, and particularly preferably 90% by weight or less, relative to the agent of the present invention.

本说明书中,“(C)的含量”是指,例如,在本发明的剂仅含有1种(C)时,其是指该1种(C)的含量,在本发明的剂含有2种以上(C)时,其是指它们的合计含量。另外,在(C)含有盐时,该盐的重量被换算为游离形式的重量。In this specification, "the content of (C)" means, for example, when the agent of the present invention contains only one (C), it means the content of the one (C), and when the agent of the present invention contains two or more (C), it means their total content. In addition, when (C) contains a salt, the weight of the salt is converted to the weight of the free form.

本发明的剂含有(D)时,相对于本发明的剂,本发明的剂中的(D)的含量(本说明书中,有时有称为“d1”或“(D)的含量d1”的情况)优选为0.01重量%以上,更优选为0.1重量%以上,特别优选为1重量%以上。另外,相对于本发明的剂,该d1优选为99.9重量%以下,更优选为99重量%以下,特别优选为90重量%以下。When the agent of the present invention contains (D), the content of (D) in the agent of the present invention (sometimes referred to as "d 1 " or "content d 1 of (D)" in this specification) is preferably 0.01% by weight or more, more preferably 0.1% by weight or more, and particularly preferably 1% by weight or more, relative to the agent of the present invention. In addition, d 1 is preferably 99.9% by weight or less, more preferably 99% by weight or less, and particularly preferably 90% by weight or less, relative to the agent of the present invention.

本发明的剂含有(B)时,从可以有效地增强咸味的角度考虑,本发明的剂中的(A)的含量a1和(B)的含量b1的重量比(a1:b1)优选为1:0.01~50,更优选为1:0.1~10,特别优选为1:0.5~5。When the agent of the present invention contains (B), the weight ratio ( a1 : b1 ) of the content a1 of (A) to the content b1 of (B) in the agent of the present invention is preferably 1:0.01-50, more preferably 1:0.1-10, and particularly preferably 1:0.5-5, from the viewpoint of effectively enhancing the salty taste.

本发明的剂含有(C)时,从可以有效地增强咸味的角度考虑,本发明的剂中的(A)的含量a1和(C)的含量c1的重量比(a1:c1)优选为1:0.1~500,更优选为1:1~100,特别优选为1:5~50。When the agent of the present invention contains (C), the weight ratio ( a1 : c1 ) of the content a1 of (A) to the content c1 of (C) in the agent of the present invention is preferably 1:0.1-500, more preferably 1:1-100, and particularly preferably 1:5-50, from the viewpoint of effectively enhancing the salty taste.

本发明的剂含有(D)时,从可以有效地增强咸味的角度考虑,本发明的剂中的(A)的含量a1和(D)的含量d1的重量比(a1:d1)优选为1:0.01~50,更优选为1:0.1~10,特别优选为1:0.5~5。When the agent of the present invention contains (D), the weight ratio ( a1 : d1 ) of the content a1 of (A) to the content d1 of (D) in the agent of the present invention is preferably 1:0.01-50, more preferably 1:0.1-10, and particularly preferably 1:0.5-5, from the viewpoint of effectively enhancing the salty taste.

本发明的剂,优选地,除了含有(A)之外,还含有选自(B)、(C)和(D)中的至少两种,更优选地,除了含有(A)之外,还含有(B)、(C)和(D)的全部。The agent of the present invention preferably contains at least two selected from (B), (C) and (D) in addition to (A), and more preferably contains all of (B), (C) and (D) in addition to (A).

本发明的剂的形态没有特别限制,可列举例如固体状(包括粉末状、颗粒状等)、液体状(包括浆状等)、凝胶状、糊状等。The form of the agent of the present invention is not particularly limited, and examples thereof include solid (including powder, granular, etc.), liquid (including slurry, etc.), gel, and paste.

本发明的剂可仅由(A)组成,或者可由(A)与选自(B)、(C)和(D)中的至少一种组成,除了这些之外,还可以含有香料领域中常用的基剂(base)。The agent of the present invention may consist of (A) alone, or may consist of (A) and at least one selected from (B), (C) and (D), and may contain a base commonly used in the perfume field in addition to these.

作为本发明的剂的形态为液体状时的基剂,可列举例如水、乙醇、丙三醇、丙二醇、各种动植物油类等。When the agent of the present invention is in a liquid form, examples of the base include water, ethanol, glycerol, propylene glycol, and various animal and plant oils.

作为本发明的剂的形态为固体状时的基剂,可列举例如淀粉、糊精、环糊精、蔗糖或葡萄糖等各种糖类;蛋白质;肽;食盐;固体脂肪;二氧化硅,以及它们的混合物,还有酵母菌体或各种粉末提取物类等。When the agent of the present invention is in a solid form, examples of the base include various sugars such as starch, dextrin, cyclodextrin, sucrose or glucose; proteins; peptides; salts; solid fats; silicon dioxide, and mixtures thereof, as well as yeast cells or various powdered extracts.

只要不损害本发明的目的,本发明的剂除了可含有(A)~(D)之外,还可含有例如赋形剂、pH调节剂、抗氧化剂、增稠稳定剂、甜味剂(例如,砂糖类等)、酸味剂、香辛料、着色剂等。Unless the purpose of the present invention is impaired, the agent of the present invention may contain, in addition to (A) to (D), for example, excipients, pH adjusters, antioxidants, thickening stabilizers, sweeteners (for example, sugars), acidulants, spices, colorants, etc.

本发明的剂的制造可通过香料领域中惯用的方法进行。本发明的剂可单独或组合实施例如浓缩处理、干燥处理、脱色处理等。The preparation of the agent of the present invention can be carried out by a method commonly used in the field of perfumes. The agent of the present invention can be subjected to, for example, concentration treatment, drying treatment, decolorization treatment, etc., alone or in combination.

本发明的剂适宜用于增强含有食盐的食品的咸味。本发明中,“含有食盐的食品”是指必须含有食盐的食品,此处含有食盐的食品等中所述的“食品”是指广泛地包含可以经口摄取的食品的概念,也包含饮料或调味料等。本发明中的“含有食盐的食品”中也包含食盐本身。另外,本发明中的“咸味和/或辛香感增强剂”为包含咸味和/或辛香感增强用组合物的概念。含有食盐的食品可含有辛香料。The agent of the present invention is suitable for enhancing the saltiness of foods containing salt. In the present invention, "foods containing salt" refer to foods that must contain salt. The "food" mentioned in the foods containing salt, etc. here refers to a concept that widely includes foods that can be taken orally, and also includes beverages or seasonings. The "foods containing salt" in the present invention also include salt itself. In addition, the "salty and/or spicy enhancer" in the present invention is a concept that includes a composition for enhancing salty and/or spicy. Foods containing salt may contain spices.

本发明中,咸味的“增强”是指,好像提高盐分浓度一样地,强烈感觉到咸味。咸味的有无、程度可以通过基于专业评价员的感官评价(例如,如后述实施例所示的感官评价等)来评价。In the present invention, "enhancement" of saltiness means that the saltiness is strongly felt as if the salt concentration is increased. The presence and degree of saltiness can be evaluated by sensory evaluation by professional evaluators (for example, sensory evaluation as described in the Examples below).

可以添加本发明的剂的含有食盐的食品只要含有食盐且可以经口摄取就没有特别限定,优选为期望咸味得到增强的含有食盐的食品,可列举例如,玉米汤、法式清汤(consommésoup(例如,鸡肉、猪肉、牛肉等)、法式浓汤(potage)、蛋汤、裙带菜汤、鱼翅汤、中华风汤、咖喱风味汤、拉面汤、日式清汤、味增汤等汤(包括干燥汤料);火腿、香肠、饺子、烧麦、汉堡牛肉饼、干炸食品、炸猪排等食用肉加工食品;日式鱼糕(Kamaboko)、竹轮鱼糕等水产加工食品;黄油等乳制品;炒饭等米饭加工食品;天然调味料、风味调味料、菜谱式调味料(menu seasoing)、蛋黄酱、沙拉调味汁(dressing)、沙司(sauce)(例如,多明格拉斯酱(demi-glace sauce)、中浓度辣酱油、白酱汁、奶酪酱、卡尔博纳拉酱(carbonara sauce)等)等调味料;面类、奶汁烤菜(gratin)、油炸丸子(Korokke)、腌渍物等其它加工食品;冷冻食品(上述食品(例如,饺子、烧麦、炒饭、汉堡牛肉饼、干炸食品、奶汁烤菜、炸猪排、油炸丸子等)的冷冻品等)等。The salt-containing food to which the agent of the present invention can be added is not particularly limited as long as it contains salt and can be orally ingested, and is preferably a salt-containing food in which the salty taste is expected to be enhanced, and examples thereof include soups (including dry soup bases) such as corn soup, consommé soup (e.g., chicken, pork, beef, etc.), potage, egg soup, kelp soup, shark fin soup, Chinese-style soup, curry-flavored soup, ramen soup, Japanese consommé soup, and miso soup; processed meat foods such as ham, sausage, dumplings, siomai, hamburger steaks, karaage, and pork cutlets; processed fishery foods such as kamaboko and chikuwa kamaboko; dairy products such as butter; processed rice foods such as fried rice; natural seasonings, flavor seasonings, menu seasonings, mayonnaise, salad dressings, sauces (e.g., demi-glace sauce), medium-concentration spicy soy sauce, white sauce, cheese sauce, carbonara sauce, etc.; other processed foods such as noodles, gratins, korokke, pickles, etc.; frozen foods (frozen products of the above foods (for example, dumplings, steamed buns, fried rice, hamburger patties, karaage, gratins, deep-fried pork cutlets, korokke, etc.)), etc.

本说明书中,“天然调味料”是指,以天然物质为原料、通过提取、分解、加热、发酵等方法制造的调味料,作为其具体例,可列举鸡肉提取物、牛肉提取物、猪肉提取物、羊肉提取物等各种畜肉提取物类;鸡骨架提取物、牛骨提取物、猪骨提取物等各种骨架提取物类;鲣鱼提取物、鲭鱼提取物、黄花鱼提取物、扇贝提取物、蟹提取物、虾提取物、鱼干提取物、干贝提取物等各种海产品提取物类;鲣鱼干提取物、鲭鱼干提取物、大马哈鱼干(宗田節)提取物等各种鱼干提取物类;洋葱提取物、白菜提取物、芹菜提取物等各种蔬菜提取物类;海带提取物等各种海藻提取物类;大蒜提取物、辣椒提取物、胡椒提取物、可可提取物等各种香辛料提取物类;酵母提取物类;各种蛋白水解物;酱油、鱼酱、虾酱、味噌等各种发酵调味料等或其混合物、加工品(例如,日式面条汤底(Mentsuyu)、橙醋酱油等酱油加工品等)等。“风味调味料”是指,用于赋予食品以风味原料的香气、风味、味道的调味料,例如可以通过在天然调味料中添加砂糖类、食盐等来制造。作为风味调味料的具体例,可列举鸡肉风味调味料、牛肉风味调味料、猪风味调味料等各种畜肉风味调味料;鲣鱼风味调味料、鱼干风味调味料、干贝风味调味料、甲壳类风味调味料等各种海产品风味调味料;各种香辛蔬菜风味调味料;海带风味调味料等。“菜谱式调味料”是指,适合于特定的菜谱(中华菜谱等)的烹饪的调味料,作为其具体例,可列举中华复合调味料、复合调味料、通用膏糊调味料、火锅调味料、什锦饭调味料、炒饭调味料、混合香辛料等。In this specification, "natural seasoning" refers to seasonings made from natural substances by extraction, decomposition, heating, fermentation and the like. Specific examples thereof include various animal meat extracts such as chicken extract, beef extract, pork extract, and mutton extract; various skeleton extracts such as chicken skeleton extract, cattle bone extract, and pig bone extract; various marine extracts such as bonito extract, mackerel extract, yellow croaker extract, scallop extract, crab extract, shrimp extract, dried fish extract, and dried scallop extract; dried bonito extract, mackerel extract, yellow croaker extract, scallop extract, crab extract, shrimp extract, dried fish extract, and dried scallop extract; dried bonito extract, mackerel extract, yellow croaker extract, scallop extract, and dried fish ... yellow croaker extract, scallop extract, and dried fish extract; dried bonito extract, mackerel extract, yellow croaker extract, yellow croaker extract, scallop extract, and dried fish extract; dried bonito extract, mackerel extract, yellow croaker extract, yellow croaker extract, scallop extract, and dried fish extract; dried bonito extract, mackerel extract, yellow croaker extract, yellow croaker extract, scallop extract, and dried fish extract; dried bonito extract, mackerel extract, yellow croaker extract, yellow croaker extract, yellow croaker extract, scallop extract, and dried fish extract; dried Various dried fish extracts such as dried fish extract and dried salmon (Souda Setsu) extract; various vegetable extracts such as onion extract, cabbage extract, celery extract; various seaweed extracts such as kelp extract; various spice extracts such as garlic extract, chili extract, pepper extract, cocoa extract; yeast extracts; various protein hydrolysates; various fermented seasonings such as soy sauce, fish sauce, shrimp paste, miso, etc., or mixtures thereof, processed products (e.g., Japanese noodle soup base (Mentsuyu), soy sauce processed products such as orange vinegar soy sauce, etc.), etc. "Flavor seasoning" refers to a seasoning used to give food the aroma, flavor, and taste of a flavor raw material, and can be produced by, for example, adding sugar, salt, etc. to natural seasonings. Specific examples of flavor seasonings include chicken flavor seasonings, beef flavor seasonings, pork flavor seasonings, and other livestock flavor seasonings; bonito flavor seasonings, dried fish flavor seasonings, scallop flavor seasonings, crustacean flavor seasonings, and other seafood flavor seasonings; various spice vegetable flavor seasonings; kelp flavor seasonings, and the like. "Recipe seasonings" refer to seasonings suitable for cooking a specific recipe (such as a Chinese recipe), and specific examples thereof include Chinese compound seasonings, compound seasonings, general paste seasonings, hot pot seasonings, mixed rice seasonings, fried rice seasonings, and mixed spices.

可以添加本发明的剂的含有食盐的食品可以以适合于进食的方式提供(贩卖、流通),或者可以以需要规定的处理或烹饪以变成适合于进食的方式的方式提供。例如,可以添加本发明的剂的含有食盐的食品可作为为了变成适合于进食的方式而需要用水等进行稀释的浓缩物等提供(贩卖、流通)。The food containing salt to which the agent of the present invention can be added can be provided (sold, circulated) in a form suitable for eating, or can be provided in a form that requires a predetermined treatment or cooking to become a form suitable for eating. For example, the food containing salt to which the agent of the present invention can be added can be provided (sold, circulated) as a concentrate that needs to be diluted with water or the like in order to become a form suitable for eating.

可以添加本发明的剂的含有食盐的食品例如可作为保健功能食品、特定保健用食品、营养功能食品、膳食补充剂、营养补充食品、健康补充食品、医疗用食品、医疗食品等提供。Foods containing salt to which the agent of the present invention can be added can be provided as, for example, health functional foods, foods for specific health purposes, nutritional functional foods, dietary supplements, nutritional supplement foods, health supplement foods, medical foods, and medical foods.

可以添加本发明的剂的含有食盐的食品中的食盐含量(盐分浓度)没有特别限制,相对于含有食盐的食品的进食时的总重量,该含量通常为0.01重量%以上,从可以有效地增强咸味的角度考虑,优选为0.3重量%以上,更优选为0.5重量%以上,特别优选为1.5重量%以上。另外,该含量的上限没有特别限定,可为100重量%,考虑到实际食品中的盐分浓度时,相对于含有食盐的食品的进食时的总重量,该含量优选为20重量%以下,更优选为15重量%以下。The salt content (salt concentration) in the food containing salt to which the agent of the present invention can be added is not particularly limited. The content is usually 0.01% by weight or more relative to the total weight of the food containing salt when eaten. From the perspective of effectively enhancing the salty taste, it is preferably 0.3% by weight or more, more preferably 0.5% by weight or more, and particularly preferably 1.5% by weight or more. In addition, the upper limit of the content is not particularly limited and can be 100% by weight. Considering the salt concentration in the actual food, the content is preferably 20% by weight or less, more preferably 15% by weight or less relative to the total weight of the food containing salt when eaten.

将本发明的剂添加到含有食盐的食品中的方法和条件没有特别限定,可以根据本发明的剂的形态或含有食盐的食品的种类等适当设定。将本发明的剂添加到含有食盐的食品中的时期没有特别限定,可在任意时刻添加,可列举例如食品制造过程中、食品完成后(例如,即将进食食品之前、进食食品过程中等)等。可将本发明的剂添加到制造含有食盐的食品之前的食品原料中。The method and conditions for adding the agent of the present invention to the food containing salt are not particularly limited, and can be appropriately set according to the form of the agent of the present invention or the type of food containing salt. The period for adding the agent of the present invention to the food containing salt is not particularly limited, and can be added at any time, for example, during the food manufacturing process, after the food is completed (for example, just before eating the food, during eating the food, etc.), etc. The agent of the present invention can be added to the food raw materials before manufacturing the food containing salt.

从可以有效增强咸味的角度考虑,优选将本发明的剂添加到含有食盐的食品中,使得相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(A)的量在特定范围。具体地,相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(A)的量优选为0.00005重量ppm以上,更优选为0.0005重量ppm以上,特别优选为0.003重量ppm以上。另外,相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(A)的量优选为15重量ppm以下,更优选为5重量ppm以下,特别优选为0.5重量ppm以下。From the perspective of effectively enhancing the salty taste, it is preferred that the agent of the present invention is added to the food containing salt so that the amount of (A) added to the food containing salt is within a specific range relative to the total weight of the food containing salt when eaten. Specifically, the amount of (A) added to the food containing salt is preferably 0.00005 ppm by weight or more, more preferably 0.0005 ppm by weight or more, and particularly preferably 0.003 ppm by weight or more, relative to the total weight of the food containing salt when eaten. In addition, the amount of (A) added to the food containing salt is preferably 15 ppm by weight or less, more preferably 5 ppm by weight or less, and particularly preferably 0.5 ppm by weight or less, relative to the total weight of the food containing salt when eaten.

本发明的剂含有(B)时,从可以有效增强咸味的角度考虑,优选将本发明的剂添加到含有食盐的食品中,使得相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(B)的量在特定范围。具体地,相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(B)的量优选为0.0008重量ppm以上,更优选为0.001重量ppm以上,进一步优选为0.003重量ppm以上,更进一步优选为0.005重量ppm以上,特别优选为0.008重量ppm以上。另外,相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(B)的量优选为10重量ppm以下,更优选为1重量ppm以下,进一步优选为0.5重量ppm以下,更进一步优选为0.3重量ppm以下,特别优选为0.1重量ppm以下,最优选为0.03重量ppm以下。When the agent of the present invention contains (B), from the perspective of effectively enhancing the salty taste, it is preferred that the agent of the present invention is added to the food containing salt so that the amount of (B) added to the food containing salt is within a specific range relative to the total weight of the food containing salt when eaten. Specifically, the amount of (B) added to the food containing salt is preferably 0.0008 ppm by weight or more, more preferably 0.001 ppm by weight or more, further preferably 0.003 ppm by weight or more, further preferably 0.005 ppm by weight or more, and particularly preferably 0.008 ppm by weight or more, relative to the total weight of the food containing salt when eaten. In addition, the amount of (B) added to the food containing salt is preferably 10 ppm by weight or less, more preferably 1 ppm by weight or less, further preferably 0.5 ppm by weight or less, further preferably 0.3 ppm by weight or less, particularly preferably 0.1 ppm by weight or less, and most preferably 0.03 ppm by weight or less, relative to the total weight of the food containing salt when eaten.

本发明的剂含有(C)时,从可以有效增强咸味的角度考虑,优选将本发明的剂添加到含有食盐的食品中,使得相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(C)的量在特定范围。具体地,相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(C)的量优选为0.008重量ppm以上,更优选为0.01重量ppm以上,进一步优选为0.05重量ppm以上,特别优选为0.08重量ppm以上。另外,相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(C)的量优选为100重量ppm以下,更优选为10重量ppm以下,进一步优选为5重量ppm以下,更进一步优选为3重量ppm以下,特别优选为1重量ppm以下,最优选为0.3重量ppm以下。When the agent of the present invention contains (C), from the perspective of effectively enhancing the salty taste, it is preferred that the agent of the present invention is added to the food containing salt so that the amount of (C) added to the food containing salt is within a specific range relative to the total weight of the food containing salt when eaten. Specifically, the amount of (C) added to the food containing salt is preferably 0.008 ppm by weight or more, more preferably 0.01 ppm by weight or more, further preferably 0.05 ppm by weight or more, and particularly preferably 0.08 ppm by weight or more, relative to the total weight of the food containing salt when eaten. In addition, the amount of (C) added to the food containing salt is preferably 100 ppm by weight or less, more preferably 10 ppm by weight or less, further preferably 5 ppm by weight or less, further preferably 3 ppm by weight or less, particularly preferably 1 ppm by weight or less, and most preferably 0.3 ppm by weight or less.

本发明的剂含有(D)时,从可以有效增强咸味的角度考虑,优选将本发明的剂添加到含有食盐的食品中,使得相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(D)的量在特定范围。具体地,相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(D)的量优选为0.0001重量ppm以上,更优选为0.0005重量ppm以上,进一步优选为0.0008重量ppm以上,更进一步优选为0.001重量ppm以上,特别优选为0.003重量ppm以上。另外,相对于含有食盐的食品的进食时的总重量,添加到含有食盐的食品中的(D)的量优选为50重量ppm以下,更优选为5重量ppm以下,进一步优选为1重量ppm以下,更进一步优选为0.1重量ppm以下,特别优选为0.03重量ppm以下。When the agent of the present invention contains (D), from the perspective of effectively enhancing the salty taste, it is preferred that the agent of the present invention is added to the food containing salt so that the amount of (D) added to the food containing salt is within a specific range relative to the total weight of the food containing salt when eaten. Specifically, the amount of (D) added to the food containing salt is preferably 0.0001 ppm by weight or more, more preferably 0.0005 ppm by weight or more, further preferably 0.0008 ppm by weight or more, further preferably 0.001 ppm by weight or more, and particularly preferably 0.003 ppm by weight or more, relative to the total weight of the food containing salt when eaten. In addition, the amount of (D) added to the food containing salt is preferably 50 ppm by weight or less, more preferably 5 ppm by weight or less, further preferably 1 ppm by weight or less, further preferably 0.1 ppm by weight or less, and particularly preferably 0.03 ppm by weight or less.

通过本发明的剂,也可以增强选自畜肉风味和奶酪风味中的至少一种,本发明的剂可为选自畜肉风味增强剂和奶酪风味增强剂中的至少一种。The agent of the present invention can also enhance at least one selected from the group consisting of meat flavor and cheese flavor. The agent of the present invention can be at least one selected from the group consisting of meat flavor enhancers and cheese flavor enhancers.

本发明中,“畜肉风味”是指,由畜肉(例如,牛肉、猪肉、鸡肉等)或畜肉提取物(例如,牛肉提取物、猪肉提取物、鸡肉提取物等)等来自畜肉的食材感觉到的特有风味,另外,畜肉风味的“增强”是指,好像增加来自畜肉的食材的量一样地,强烈感觉到畜肉风味。畜肉风味的有无或程度可以通过基于专业评价员的感官评价进行评价。In the present invention, "meat flavor" refers to a unique flavor felt from meat (e.g., beef, pork, chicken, etc.) or meat extracts (e.g., beef extracts, pork extracts, chicken extracts, etc.) derived from meat, and "enhancement" of meat flavor means that the meat flavor is strongly felt as if the amount of meat-derived food is increased. The presence or degree of meat flavor can be evaluated by sensory evaluation by professional evaluators.

本发明中,奶酪风味的“增强”是指,好像增加奶酪的量一样地,强烈感觉到奶酪风味。奶酪风味的有无或程度可以通过基于专业评价员的感官评价来进行评价。In the present invention, "enhancement" of cheese flavor means that the cheese flavor is strongly felt as if the amount of cheese is increased. The presence or degree of cheese flavor can be evaluated by sensory evaluation by professional evaluators.

本发明的剂也适宜用于增强含有辛香料的食品的辛香感。本发明中,“含有辛香料的食品”是指必须含有辛香料的食品,该辛香料只要其一般可用于赋予食品的风味、赋予食品的辛辣味等就没有特别限制,可列举例如肉豆蔻(nutmeg)、肉豆蔻衣(mace)、大蒜、月桂、百里香、胡椒(例如,黑胡椒、白胡椒等)、罗勒、姜、姜黄、小茴香、葛缕子(caraway)、辣椒(chili pepper)、肉桂、甘牛至、迷迭香、孜然芹、芹菜、芫荽、洋葱等。只要不损害本发明的目的,这些辛香料可根据食品的种类、烹饪方法等,通过本身已知的方法或以此为准的方法,实施加工处理、烹饪。本发明中的“含有辛香料的食品”中也包含辛香料本身。含有辛香料的食品可含有食盐。The agent of the present invention is also suitable for enhancing the spicy and fragrant sense of food containing spices. In the present invention, "food containing spices" refers to food that must contain spices. The spices are generally used to impart flavor to food, impart spicy taste to food, etc. There is no particular restriction, such as nutmeg, mace, garlic, laurel, thyme, pepper (for example, black pepper, white pepper, etc.), basil, ginger, turmeric, cumin, caraway, chili pepper, cinnamon, sweet oregano, rosemary, cumin, celery, coriander, onion, etc. As long as the purpose of the present invention is not impaired, these spices can be processed and cooked according to the type of food, cooking method, etc., by methods known per se or as a standard. Spices themselves are also included in the "food containing spices" in the present invention. Food containing spices can contain salt.

本发明中,辛香感的“增强”是指,好像增加辛香料含量一样地,强烈感觉到辛香料特有的风味、辛辣味。辛香感的有无或程度可以通过基于专业评价员的感官评价(例如,后述实施例所示的感官评价等)来进行评价。In the present invention, "enhancement" of spiciness means that the flavor and spiciness unique to spiciness are strongly felt as if the spiciness content is increased. The presence or degree of spiciness can be evaluated by sensory evaluation based on professional evaluators (for example, sensory evaluation shown in the examples described below).

可以添加本发明的剂的含有辛香料的食品只要含有辛香料且可以经口摄取就没有特别限制,优选为期望辛香感得到增强的含有辛香料的食品,可列举例如与作为可以添加本发明的剂的含有食盐的食品而列举的示例相同的示例。The spice-containing food to which the agent of the present invention can be added is not particularly limited as long as it contains spice and can be orally ingested, but is preferably a spice-containing food in which the spiciness is expected to be enhanced, and examples thereof include the same examples as those listed as the salt-containing food to which the agent of the present invention can be added.

可以添加本发明的剂的含有辛香料的食品可以以与可以添加本发明的剂的含有食盐的食品同样的方式提供。The spice-containing food to which the agent of the present invention can be added can be provided in the same manner as the salt-containing food to which the agent of the present invention can be added.

可以添加本发明的剂的含有辛香料的食品中的辛香料的含量(辛香料含量)只要为可以感觉到辛香感的量就没有特别限定,相对于含有辛香料的食品的进食时的总重量,该含量通常为0.001重量%以上,从可以有效增强辛香感的角度考虑,优选为0.005重量%以上,更优选为0.008重量%以上,特别优选为0.01重量%以上。另外,该含量的上限没有特别限定,可为100重量%,考虑到实际食品中的辛香料含量的话,相对于含有辛香料的食品的进食时的总重量,该含量优选为5重量%以下,更优选为1重量%以下。The content of spices in the spice-containing food to which the agent of the present invention can be added (spice content) is not particularly limited as long as it is an amount that can feel the spiciness. The content is usually 0.001% by weight or more relative to the total weight of the spice-containing food when eaten. From the perspective of effectively enhancing the spiciness, it is preferably 0.005% by weight or more, more preferably 0.008% by weight or more, and particularly preferably 0.01% by weight or more. In addition, the upper limit of the content is not particularly limited and can be 100% by weight. Considering the spice content in the actual food, the content is preferably 5% by weight or less, more preferably 1% by weight or less relative to the total weight of the spice-containing food when eaten.

将本发明的剂添加到含有辛香料的食品中的方法和条件没有特别限定,可以与添加到含有食盐的食品中的方法和条件一样地设定。The method and conditions for adding the agent of the present invention to foods containing spice are not particularly limited, and can be set in the same manner as the method and conditions for adding the agent to foods containing salt.

从可以有效增强辛香感的角度考虑,优选将本发明的剂添加到含有辛香料的食品中,使得相对于含有辛香料的食品的进食时的总重量,添加到含有辛香料的食品中的(A)的量在特定范围。具体地,添加到含有辛香料的食品中的(A)的量与上述的添加到含有食盐的食品中的(A)的量相同,优选的范围也相同。From the perspective of effectively enhancing the spicy flavor, it is preferred that the agent of the present invention is added to the food containing spices so that the amount of (A) added to the food containing spices is within a specific range relative to the total weight of the food containing spices when consumed. Specifically, the amount of (A) added to the food containing spices is the same as the amount of (A) added to the food containing salt described above, and the preferred range is also the same.

本发明的剂含有(B)、(C)、(D)时,从可以有效增强辛香感的角度考虑,优选将本发明的剂添加到含有辛香料的食品中,使得相对于含有辛香料的食品的进食时的总重量,添加到含有辛香料的食品中的(B)、(C)、(D)的量分别在特定范围。具体地,添加到含有辛香料的食品中的(B)、(C)、(D)的量分别与上述的添加到含有食盐的食品中的(B)、(C)、(D)的量相同,优选的范围也相同。When the agent of the present invention contains (B), (C), and (D), from the perspective of effectively enhancing the spicy aroma, it is preferred that the agent of the present invention is added to the food containing spices so that the amounts of (B), (C), and (D) added to the food containing spices are within specific ranges relative to the total weight of the food containing spices when consumed. Specifically, the amounts of (B), (C), and (D) added to the food containing spices are the same as the amounts of (B), (C), and (D) added to the food containing salt, and the preferred ranges are also the same.

本发明的剂也适合用于增强含有食盐和辛香料的食品的咸味和辛香感。本发明中,“含有食盐和辛香料的食品”是指,必须含有食盐和辛香料两者的食品。The agent of the present invention is also suitable for enhancing the salty taste and spicy aroma of foods containing salt and spices. In the present invention, "foods containing salt and spices" refer to foods that necessarily contain both salt and spices.

可以添加本发明的剂的含有食盐和辛香料的食品只要含有食盐和辛香料且可以经口摄取就没有特别限定,优选为期望咸味和辛香感得到增强的含有食盐和辛香料的食品,可列举例如与作为可以添加本发明的剂的含有食盐的食品而列举的示例相同的示例。The food containing salt and spice to which the agent of the present invention can be added is not particularly limited as long as it contains salt and spice and can be orally ingested, but is preferably a food containing salt and spice in which the saltiness and spiciness are expected to be enhanced, and examples thereof include the same examples as those cited as the food containing salt to which the agent of the present invention can be added.

可以添加本发明的剂的含有食盐和辛香料的食品可以以与可以添加本发明的剂的含有食盐的食品相同的方式提供。The food containing common salt and spices to which the agent of the present invention can be added can be provided in the same manner as the food containing common salt to which the agent of the present invention can be added.

可以添加本发明的剂的含有食盐和辛香料的食品的盐分浓度、辛香料含量均无特别限定,分别与上述的可以添加本发明的剂的含有食盐的食品的盐分浓度、可以添加本发明的剂的含有辛香料的食品的辛香料含量相同,优选的范围也相同。The salt concentration and spice content of the food containing salt and spice to which the agent of the present invention can be added are not particularly limited, and are the same as the salt concentration of the food containing salt to which the agent of the present invention can be added and the spice content of the food containing spice to which the agent of the present invention can be added, and the preferred ranges are also the same.

将本发明的剂添加到含有食盐和辛香料的食品中的方法和条件没有特别限定,可以与添加到含有食盐的食品中的方法和条件一样地设定。The method and conditions for adding the agent of the present invention to foods containing salt and spices are not particularly limited, and can be set in the same manner as the method and conditions for adding the agent to foods containing salt.

从可以有效增强咸味和辛香感的角度考虑,优选将本发明的剂添加到含有食盐和辛香料的食品中,使得相对于含有食盐和辛香料的食品的进食时的总重量,添加到含有食盐和辛香料的食品中的(A)的量在特定范围。具体地,添加到含有食盐和辛香料的食品中的(A)的量与上述的添加到含有食盐的食品中的(A)的量相同,优选的范围也相同。From the perspective of effectively enhancing the salty and spicy taste, it is preferred that the agent of the present invention is added to a food containing salt and spices so that the amount of (A) added to the food containing salt and spices is within a specific range relative to the total weight of the food containing salt and spices when consumed. Specifically, the amount of (A) added to the food containing salt and spices is the same as the amount of (A) added to the food containing salt, and the preferred range is also the same.

本发明的剂含有(B)、(C)、(D)时,从可以有效增强咸味和辛香感的角度考虑,优选将本发明的剂添加到含有食盐和辛香料的食品中,使得相对于含有食盐和辛香料的食品的进食时的总重量,添加到含有食盐和辛香料的食品中的(B)、(C)、(D)的量分别在特定范围。具体地,添加到含有食盐和辛香料的食品中的(B)、(C)、(D)的量分别与上述的添加到含有食盐的食品中的(B)、(C)、(D)的量相同,优选的范围也相同。When the agent of the present invention contains (B), (C), and (D), from the perspective of effectively enhancing the salty taste and spicy aroma, it is preferred that the agent of the present invention is added to a food containing salt and spices so that the amounts of (B), (C), and (D) added to the food containing salt and spices are respectively within a specific range relative to the total weight of the food containing salt and spices when consumed. Specifically, the amounts of (B), (C), and (D) added to the food containing salt and spices are respectively the same as the amounts of (B), (C), and (D) added to the above-mentioned food containing salt, and the preferred ranges are also the same.

根据本发明,还可以提供含有本发明的剂的含有食盐的食品、含有本发明的剂的含有辛香料的食品、以及含有本发明的剂的含有食盐和辛香料的食品(本说明书中,有时有将这些食品统称为“本发明的食品”的情况)。本说明书中,有时有将含有食盐的食品、含有辛香料的食品以及含有食盐和辛香料的食品统称为“含有食盐和/或辛香料的食品”的情况。According to the present invention, it is also possible to provide a food containing salt containing the agent of the present invention, a food containing spices containing the agent of the present invention, and a food containing salt and spices containing the agent of the present invention (in this specification, these foods are sometimes collectively referred to as "foods of the present invention"). In this specification, foods containing salt, foods containing spices, and foods containing salt and spices are sometimes collectively referred to as "foods containing salt and/or spices".

对本发明的食品中的本发明的剂的含量进行适当调整,使得相对于含有食盐和/或辛香料的食品的进食时的总重量,添加到含有食盐和/或辛香料的食品中的(A)、(B)、(C)、(D)的量分别在上述范围内即可,没有特别限定。The content of the agent of the present invention in the food of the present invention may be appropriately adjusted so that the amounts of (A), (B), (C), and (D) added to the food containing salt and/or spices are within the above ranges relative to the total weight of the food containing salt and/or spices when consumed, and are not particularly limited.

本发明的食品的种类没有特别限定,优选为期望咸味、辛香感得到增强的食品的种类,可列举例如与作为可以添加本发明的剂的食品而列举的示例相同的示例。The type of the food of the present invention is not particularly limited, but is preferably a type of food in which saltiness or spiciness is desired to be enhanced, and examples thereof include the same examples as those exemplified as the food to which the agent of the present invention can be added.

(本发明的制造方法)(Manufacturing method of the present invention)

本发明还提供包括添加(A)分支饱和脂肪族一元羧酸或其盐的含有食盐的食品的制造方法、包括添加(A)分支饱和脂肪族一元羧酸或其盐的含有辛香料的食品的制造方法、以及包括添加(A)分支饱和脂肪族一元羧酸或其盐的含有食盐和辛香料的食品的制造方法(本说明书中,有时有将这些制造方法统称为“本发明的制造方法”的情况)。The present invention also provides a method for producing a food containing salt by adding (A) a branched saturated aliphatic monocarboxylic acid or a salt thereof, a method for producing a food containing spice by adding (A) a branched saturated aliphatic monocarboxylic acid or a salt thereof, and a method for producing a food containing salt and spice by adding (A) a branched saturated aliphatic monocarboxylic acid or a salt thereof (in this specification, these production methods may be collectively referred to as the "production method of the present invention").

本发明的制造方法中使用的(A)与本发明的剂中包含的(A)相同,优选方式也相同。(A) used in the production method of the present invention is the same as (A) contained in the agent of the present invention, and preferred embodiments are also the same.

本发明的制造方法中,从可以有效增强咸味、辛香感的角度考虑,相对于含有食盐和/或辛香料的食品的进食时的总重量,(A)的添加量(本说明书中,有时有称为“a2”或“(A)的添加量a2”的情况)优选为0.00005重量ppm以上,更优选为0.0005重量ppm以上,特别优选为0.003重量ppm以上。另外,从可以有效增强咸味、辛香感的角度考虑,相对于含有食盐和/或辛香料的食品的进食时的总重量,a2优选为15重量ppm以下,更优选为5重量ppm以下,特别优选为0.5重量ppm以下。In the production method of the present invention, from the viewpoint of effectively enhancing the salty taste and spicy aroma, the amount of (A) added (sometimes referred to as "a 2 " or "amount of (A) added a 2 " in this specification) is preferably 0.00005 ppm by weight or more, more preferably 0.0005 ppm by weight or more, and particularly preferably 0.003 ppm by weight or more, relative to the total weight of the food containing salt and/or spice when consumed, from the viewpoint of effectively enhancing the salty taste and spicy aroma. In addition, from the viewpoint of effectively enhancing the salty taste and spicy aroma, a 2 is preferably 15 ppm by weight or less, more preferably 5 ppm by weight or less, and particularly preferably 0.5 ppm by weight or less, relative to the total weight of the food containing salt and/or spice when consumed.

本说明书中,“(A)的添加量”,例如,在本发明的制造方法中仅添加1种(A)时,其是指该1种的量,在本发明的制造方法中添加2种以上(A)时,其是指它们的合计量。另外,在(A)含有盐时,该盐的重量被换算为游离形式的重量。In this specification, the "addition amount of (A)" refers to the amount of, for example, only one (A) when added in the production method of the present invention, and refers to the total amount of these when two or more (A) are added in the production method of the present invention. In addition, when (A) contains a salt, the weight of the salt is converted to the weight of the free form.

优选地,本发明的制造方法除了包括添加(A)之外,还包括添加选自(B)3-甲硫基丙醛、(C)丁酸或其盐以及(D)葫芦巴内酯中的至少一种。Preferably, the production method of the present invention comprises, in addition to adding (A), further comprising adding at least one selected from (B) 3-methylthiopropionaldehyde, (C) butyric acid or a salt thereof, and (D) trigonelline lactone.

可以在本发明的制造方法中使用的(B)、(C)、(D)分别与可以包含在本发明的剂中的(B)、(C)、(D)相同,优选方式也相同。(B), (C), and (D) that can be used in the production method of the present invention are the same as (B), (C), and (D) that can be contained in the agent of the present invention, respectively, and preferred embodiments are also the same.

本发明的制造方法包括添加(B)时,从可以有效增强咸味、辛香感的角度考虑,相对于含有食盐和/或辛香料的食品的进食时的总重量,(B)的添加量(本说明书中,有时有称为“b2”或“(B)的添加量b2”的情况)优选为0.0008重量ppm以上,更优选为0.001重量ppm以上,进一步优选为0.003重量ppm以上,更进一步优选为0.005重量ppm以上,特别优选为0.008重量ppm以上。另外,从可以有效增强咸味、辛香感的角度考虑,相对于含有食盐和/或辛香料的食品的进食时的总重量,b2优选为10重量ppm以下,更优选为1重量ppm以下,进一步优选为0.5重量ppm以下,更进一步优选为0.3重量ppm以下,特别优选为0.1重量ppm以下,最优选为0.03重量ppm以下。When the production method of the present invention includes adding (B), from the viewpoint of effectively enhancing the salty taste and spicy aroma, the amount of (B) added (sometimes referred to as "b 2 " or "the amount of (B) added b 2 " in this specification) is preferably 0.0008 ppm by weight or more, more preferably 0.001 ppm by weight or more, further preferably 0.003 ppm by weight or more, further preferably 0.005 ppm by weight or more, and particularly preferably 0.008 ppm by weight or more, relative to the total weight of the food containing salt and/or spice when consumed, from the viewpoint of effectively enhancing the salty taste and spicy aroma. In addition, from the viewpoint of effectively enhancing the salty taste and spicy aroma, b 2 is preferably 10 ppm by weight or less, more preferably 1 ppm by weight or less, further preferably 0.5 ppm by weight or less, further preferably 0.3 ppm by weight or less, particularly preferably 0.1 ppm by weight or less, and most preferably 0.03 ppm by weight or less, relative to the total weight of the food containing salt and/or spice when consumed.

本发明的制造方法包括添加(C)时,从可以有效增强咸味、辛香感的角度考虑,相对于含有食盐和/或辛香料的食品的进食时的总重量,(C)的添加量(本说明书中,有时有称为“c2”或“(C)的添加量c2”的情况)优选为0.008重量ppm以上,更优选为0.01重量ppm以上,进一步优选为0.05重量ppm以上,特别优选为0.08重量ppm以上。另外,从可以有效增强咸味、辛香感的角度考虑,相对于含有食盐和/或辛香料的食品的进食时的总重量,c2优选为100重量ppm以下,更优选为10重量ppm以下,进一步优选为5重量ppm以下,更进一步优选为3重量ppm以下,特别优选为1重量ppm以下,最优选为0.3重量ppm以下。When the production method of the present invention includes adding (C), from the viewpoint of effectively enhancing the salty taste and spicy aroma, the amount of (C) added (sometimes referred to as "c 2 " or "the amount of (C) added c 2 " in this specification) is preferably 0.008 ppm by weight or more, more preferably 0.01 ppm by weight or more, further preferably 0.05 ppm by weight or more, and particularly preferably 0.08 ppm by weight or more, relative to the total weight of the food containing salt and/or spice when consumed, from the viewpoint of effectively enhancing the salty taste and spicy aroma. Furthermore, from the viewpoint of effectively enhancing the salty taste and spicy aroma, c 2 is preferably 100 ppm by weight or less, more preferably 10 ppm by weight or less, further preferably 5 ppm by weight or less, further preferably 3 ppm by weight or less, particularly preferably 1 ppm by weight or less, and most preferably 0.3 ppm by weight or less, relative to the total weight of the food containing salt and/or spice when consumed.

本说明书中,“(C)的添加量”,例如,在本发明的制造方法中仅添加1种(C)时,其是指该1种的量,在本发明的制造方法中添加2种以上(C)时,其是指它们的合计量。另外,在(C)含有盐时,该盐的重量被换算为游离形式的重量。In this specification, the "addition amount of (C)" refers to the amount of, for example, only one (C) when added in the production method of the present invention, and refers to the total amount of these when two or more (C) are added in the production method of the present invention. In addition, when (C) contains a salt, the weight of the salt is converted to the weight of the free form.

本发明的制造方法包括添加(D)时,从可以有效增强咸味、辛香感的角度考虑,相对于含有食盐和/或辛香料的食品的进食时的总重量,(D)的添加量(本说明书中,有时有称为“d2”或“(D)的添加量d2”的情况)优选为0.0001重量ppm以上,更优选为0.0005重量ppm以上,进一步优选为0.0008重量ppm以上,更进一步优选为0.001重量ppm以上,特别优选为0.003重量ppm以上。另外,从可以有效增强咸味、辛香感的角度考虑,相对于含有食盐和/或辛香料的食品的进食时的总重量,d2优选为50重量ppm以下,更优选为5重量ppm以下,进一步优选为1重量ppm以下,更进一步优选为0.1重量ppm以下,特别优选为0.03重量ppm以下。When the production method of the present invention includes adding (D), from the viewpoint of effectively enhancing the salty taste and spicy aroma, the amount of (D) added (sometimes referred to as "d 2 " or "the amount of (D) added d 2 " in this specification) is preferably 0.0001 ppm by weight or more, more preferably 0.0005 ppm by weight or more, further preferably 0.0008 ppm by weight or more, still further preferably 0.001 ppm by weight or more, and particularly preferably 0.003 ppm by weight or more, relative to the total weight of the food containing salt and/or spice when consumed, from the viewpoint of effectively enhancing the salty taste and spicy aroma. Furthermore, from the viewpoint of effectively enhancing the salty taste and spicy aroma, d 2 is preferably 50 ppm by weight or less, more preferably 5 ppm by weight or less, further preferably 1 ppm by weight or less, further preferably 0.1 ppm by weight or less, and particularly preferably 0.03 ppm by weight or less, relative to the total weight of the food containing salt and/or spice when consumed.

本发明的制造方法包括添加(B)时,从可以有效增强咸味、辛香感的角度考虑,(A)的添加量a2和(B)的添加量b2的重量比(a2:b2)优选为1:0.01~50,更优选为1:0.1~10,特别优选为1:0.5~5。When the production method of the present invention includes adding (B), from the perspective of effectively enhancing the salty and spicy taste, the weight ratio ( a2 : b2 ) of the addition amount a2 of (A) and the addition amount b2 of (B) is preferably 1:0.01-50, more preferably 1:0.1-10, and particularly preferably 1:0.5-5.

本发明的制造方法包括添加(C)时,从可以有效增强咸味、辛香感的角度考虑,(A)的添加量a2和(C)的添加量c2的重量比(a2:c2)优选为1:0.1~500,更优选为1:1~100,特别优选为1:5~50。When the production method of the present invention includes adding (C), from the perspective of effectively enhancing the salty and spicy taste, the weight ratio of the addition amount a2 of (A) to the addition amount c2 of (C) ( a2 : c2 ) is preferably 1:0.1-500, more preferably 1:1-100, and particularly preferably 1:5-50.

本发明的制造方法包括添加(D)时,从可以有效增强咸味、辛香感的角度考虑,(A)的添加量a2和(D)的添加量d2的重量比(a2:d2)优选为1:0.01~50,更优选为1:0.1~10,特别优选为1:0.5~5。When the production method of the present invention includes adding (D), from the perspective of effectively enhancing the salty and spicy taste, the weight ratio ( a2 : d2 ) of the addition amount a2 of (A) to the addition amount d2 of (D) is preferably 1:0.01-50, more preferably 1:0.1-10, and particularly preferably 1:0.5-5.

本发明的制造方法,优选地,除了包括添加(A)之外,还包括添加选自(B)、(C)和(D)中的至少两种,更优选地,除了包括添加(A)之外,还包括添加(B)、(C)和(D)全部。The manufacturing method of the present invention preferably includes, in addition to adding (A), adding at least two selected from (B), (C) and (D), and more preferably, includes, in addition to adding (A), adding all of (B), (C) and (D).

本发明的制造方法除了包括添加(A)之外还包括添加选自(B)、(C)和(D)中的至少一种时,可分别添加(A)与选自(B)、(C)和(D)中的至少一种,或者,可在添加前预先将它们混合,添加所获得的混合物。或者,它们的添加可使用本发明的剂进行。在分别添加(A)与选自(B)、(C)和(D)中的至少一种时,添加的顺序和间隔没有特别限定,例如,在添加(A)和(B)时,可按照(A)、(B)的顺序或者其相反顺序添加,或者,可同时添加(A)和(B)。When the manufacturing method of the present invention further comprises adding at least one selected from (B), (C) and (D) in addition to adding (A), (A) and at least one selected from (B), (C) and (D) may be added separately, or they may be mixed in advance before adding and the obtained mixture may be added. Alternatively, their addition may be carried out using the agent of the present invention. When (A) and at least one selected from (B), (C) and (D) are added separately, the order and interval of addition are not particularly limited. For example, when (A) and (B) are added, they may be added in the order of (A), (B) or in the reverse order thereof, or (A) and (B) may be added simultaneously.

本发明的制造方法除了上述的(A)~(D)的添加之外,还可根据制造食品的种类等适当包括在食品制造中惯用的处理工序、烹饪工序。The production method of the present invention may appropriately include a processing step and a cooking step commonly used in food production, in addition to the addition of (A) to (D) described above, depending on the type of food to be produced.

通过本发明的制造方法获得的含有食盐和/或辛香料的食品的种类没有特别限定,优选为期望咸味、辛香感得到增强的含有食盐和/或辛香料的食品的种类,可列举例如与作为可以添加本发明的剂的含有食盐的食品而列举的示例相同的示例。The type of food containing salt and/or spice obtained by the production method of the present invention is not particularly limited, but is preferably a type of food containing salt and/or spice in which the saltiness and spiciness are expected to be enhanced, and examples thereof include the same examples as those cited as the food containing salt to which the agent of the present invention can be added.

根据本发明的制造方法,可以制造咸味得到增强的含有食盐的食品、辛香感得到增强的含有辛香料的食品、咸味和辛香感得到增强的含有食盐和辛香料的食品。另外,根据本发明的制造方法,可以制造选自畜肉风味和奶酪风味中的至少一种也得到增强的含有食盐的食品。According to the manufacturing method of the present invention, a salt-containing food with enhanced saltiness, a spice-containing food with enhanced spiciness, and a salt-and-spice-containing food with enhanced saltiness and spiciness can be manufactured. In addition, according to the manufacturing method of the present invention, a salt-containing food with enhanced at least one of meat flavor and cheese flavor can be manufactured.

(本发明的增强方法)(Enhancement method of the present invention)

本发明还提供包括添加(A)分支饱和脂肪族一元羧酸或其盐的、含有食盐的食品的咸味增强方法;包括添加(A)分支饱和脂肪族一元羧酸或其盐的、含有辛香料的食品的辛香感增强方法;以及包括添加(A)分支饱和脂肪族一元羧酸或其盐的、含有食盐和辛香料的食品的咸味和辛香感增强方法(本说明书中,有时有将这些增强方法统称为“本发明的增强方法”的情况)。The present invention also provides a method for enhancing the salty taste of a food containing salt by adding (A) a branched saturated aliphatic monocarboxylic acid or a salt thereof; a method for enhancing the spiciness of a food containing spices by adding (A) a branched saturated aliphatic monocarboxylic acid or a salt thereof; and a method for enhancing the salty taste and spiciness of a food containing salt and spices by adding (A) a branched saturated aliphatic monocarboxylic acid or a salt thereof (in this specification, these enhancing methods are sometimes collectively referred to as the "enhancing method of the present invention").

本发明的增强方法中使用的(A)与本发明的剂中包含的(A)相同,优选方式也相同。(A) used in the enhancement method of the present invention is the same as (A) contained in the agent of the present invention, and preferred aspects are also the same.

本发明的增强方法中,(A)的添加量(本说明书中,有时有称为“a3”或“(A)的添加量a3”的情况)可与本发明的制造方法中的(A)的添加量a2一样地设定,优选的范围也相同。In the reinforcing method of the present invention, the amount of (A) added (sometimes referred to as "a 3 " or "amount of (A) added a 3 " in this specification) can be set similarly to the amount of (A) added a 2 in the production method of the present invention, and the preferred range is also the same.

优选地,本发明的增强方法除了包括添加(A)之外,还包括添加选自(B)3-甲硫基丙醛、(C)丁酸或其盐以及(D)葫芦巴内酯中的至少一种。Preferably, the enhancement method of the present invention comprises, in addition to adding (A), further comprising adding at least one selected from (B) 3-methylthiopropionaldehyde, (C) butyric acid or a salt thereof, and (D) trigonelline lactone.

可以在本发明的增强方法中使用的(B)、(C)、(D)分别与可以包含在本发明的剂中的(B)、(C)、(D)相同,优选方式也相同。(B), (C), and (D) that can be used in the enhancement method of the present invention are the same as (B), (C), and (D) that can be contained in the agent of the present invention, respectively, and preferred embodiments are also the same.

本发明的增强方法包括添加(B)时,(B)的添加量(本说明书中,有时有称为“b3”或“(B)的添加量b3”的情况)可与本发明的制造方法中的(B)的添加量b2一样地设定,优选的范围也相同。When the reinforcing method of the present invention includes adding (B), the amount of (B) added (sometimes referred to as " b3 " or "amount b3 of (B) added" in this specification) can be set similarly to the amount b2 of (B) added in the production method of the present invention, and the preferred range is also the same.

本发明的增强方法包括添加(C)时,(C)的添加量(本说明书中,有时有称为“c3”或“(C)的添加量c3”的情况)可与本发明的制造方法中的(C)的添加量c2一样地设定,优选的范围也相同。When the reinforcing method of the present invention includes adding (C), the amount of (C) added (sometimes referred to as "c 3 " or "the amount of (C) added c 3 " in this specification) can be set similarly to the amount of (C) added c 2 in the production method of the present invention, and the preferred range is also the same.

本发明的增强方法包括添加(D)时,(D)的添加量(本说明书中,有时有称为“d3”或“(D)的添加量d3”的情况)可与本发明的制造方法中的(D)的添加量d2一样地设定,优选的范围也相同。When the reinforcing method of the present invention includes adding (D), the amount of (D) added (sometimes referred to as "d 3 " or "the amount of (D) added d 3 " in this specification) can be set similarly to the amount of (D) added d 2 in the production method of the present invention, and the preferred range is also the same.

本发明的增强方法包括添加(B)时,(A)的添加量a3和(B)的添加量b3的重量比(a3:b3)可与本发明的制造方法中的(A)的添加量a2和(B)的添加量b2的重量比(a2:b2)一样地设定,优选的范围也相同。When the reinforcing method of the present invention includes adding (B), the weight ratio ( a3 : b3 ) of the addition amount a3 of (A) to the addition amount b3 of (B) can be set similarly to the weight ratio ( a2 : b2 ) of the addition amount a2 of (A) to the addition amount b2 of (B) in the production method of the present invention, and the preferred range is also the same.

本发明的增强方法包括添加(C)时,(A)的添加量a3和(C)的添加量c3的重量比(a3:c3)可与本发明的制造方法中的(A)的添加量a2和(C)的添加量c2的重量比(a2:c2)一样地设定,优选的范围也相同。When the reinforcing method of the present invention includes adding (C), the weight ratio ( a3 : c3 ) of the addition amount a3 of (A) to the addition amount c3 of (C) can be set similarly to the weight ratio ( a2 : c2 ) of the addition amount a2 of (A) to the addition amount c2 of (C) in the production method of the present invention, and the preferred range is also the same.

本发明的增强方法包括添加(D)时,(A)的添加量a3和(D)的添加量d3的重量比(a3:d3)可与本发明的制造方法中的(A)的添加量a2和(D)的添加量d2的重量比(a2:d2)一样地设定,优选的范围也相同。When the reinforcing method of the present invention includes adding (D), the weight ratio ( a3 : d3 ) of the addition amount a3 of (A) to the addition amount d3 of (D) can be set similarly to the weight ratio ( a2 : d2 ) of the addition amount a2 of (A) to the addition amount d2 of (D) in the production method of the present invention, and the preferred range is also the same.

除非另有说明,否则本发明的增强方法可与本发明的制造方法一样地实施,优选的方式也相同。Unless otherwise specified, the reinforcing method of the present invention can be implemented in the same manner as the manufacturing method of the present invention, and the preferred embodiments are also the same.

本发明的增强方法中,添加(A)或者添加(A)与选自(B)、(C)和(D)中的至少一种(以下,有时有将它们统称为“(A)等”的情况)的方法和条件没有特别限定,可以根据添加它们的含有食盐和/或辛香料的食品的种类等适当设定。将(A)等添加到含有食盐和/或辛香料的食品中的时间点没有特别限定,可在任意时刻添加,可列举例如含有食盐和/或辛香料的食品的制造中以及含有食盐和/或辛香料的食品的完成后(例如,即将进食含有食盐和/或辛香料的食品之前、含有食盐和/或辛香料的食品的进食中等)等。可在制造含有食盐和/或辛香料的食品之前的食品原料中,添加(A)等。In the enhancement method of the present invention, the method and conditions for adding (A) or adding (A) and at least one selected from (B), (C) and (D) (hereinafter, they may be collectively referred to as "(A) etc.") are not particularly limited and can be appropriately set according to the type of food containing salt and/or spices to which they are added. The time point for adding (A) etc. to the food containing salt and/or spices is not particularly limited and can be added at any time, for example, during the production of the food containing salt and/or spices and after the completion of the food containing salt and/or spices (for example, before the food containing salt and/or spices is eaten, during the consumption of the food containing salt and/or spices, etc.). (A) etc. can be added to the food raw materials before the food containing salt and/or spices is produced.

根据本发明的增强方法,可以增强含有食盐的食品的咸味、可以增强含有辛香料的食品的辛香感、可以增强含有食盐和辛香料的食品的咸味和辛香感。另外,根据本发明的增强方法,也可以增强选自畜肉风味和奶酪风味中的至少一种,本发明的增强方法可为选自畜肉风味增强方法和奶酪风味增强方法中的至少一种。According to the enhancement method of the present invention, the saltiness of foods containing salt can be enhanced, the spiciness of foods containing spices can be enhanced, and the saltiness and spiciness of foods containing salt and spices can be enhanced. In addition, according to the enhancement method of the present invention, at least one selected from the flavor of livestock and cheese can be enhanced. The enhancement method of the present invention can be at least one selected from the method for enhancing the flavor of livestock and cheese.

通过本发明的增强方法从而咸味、辛香感可以得到增强的含有食盐和/或辛香料的食品的种类没有特别限定,优选为期望咸味、辛香感得到增强者,可列举例如与作为可以添加本发明的剂的含有食盐的食品而列举的示例相同的示例。The types of foods containing salt and/or spices to which the salty taste and spicy aroma can be enhanced by the enhancement method of the present invention are not particularly limited, but preferably foods to which the salty taste and spicy aroma are desired to be enhanced, and examples thereof include the same examples as those listed as foods containing salt to which the agent of the present invention can be added.

以下实施例中更具体地说明本发明,但本发明完全不局限于这些例子。另外,本说明书中,记载为“%”、“ppm”时,除非另有特别说明,否则是指“重量%”、“重量ppm”。The present invention is described in more detail in the following examples, but the present invention is not limited to these examples. In addition, in this specification, "%" or "ppm" means "% by weight" or "ppm by weight" unless otherwise specified.

以下各试验例中使用的试剂除非另有特别说明,否则均为市售品(Sigma-Aldrich公司制造)。Unless otherwise specified, all reagents used in the following test examples are commercially available products (manufactured by Sigma-Aldrich).

[实施例][Example]

(试验例1:日式面条汤底)(Test Example 1: Japanese noodle soup base)

<对照组的调制><Preparation of control group>

用水将市售的浓缩型日式面条汤底(YAMAKI株式会社制造,“Mentsuyu”)进行稀释,使得其相对于稀释后的日式面条汤底的总重量为33重量%,调制日式面条汤底,作为对照组(对照组的盐分浓度:2.3%)。A commercially available concentrated Japanese noodle soup base ("Mentsuyu" manufactured by YAMAKI Co., Ltd.) was diluted with water to 33% by weight relative to the total weight of the diluted Japanese noodle soup base to prepare a Japanese noodle soup base as a control group (salt concentration of the control group: 2.3%).

<评价样品的调制><Preparation of evaluation samples>

如下表1所示地,向对照组中,相对于评价样品总量添加0.001~10重量ppm的4-甲基戊酸,调制评价样品。As shown in Table 1 below, 0.001 to 10 ppm by weight of 4-methylvaleric acid was added to the control group based on the total amount of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,实施感官评价。Sensory evaluation was performed on the saltiness intensity of the evaluation samples.

通过2名专家评价员,将评价样品与对照组进行比较,基于下述基准评价,从而进行感官评价。The sensory evaluation was performed by two expert panelists by comparing the evaluation samples with the control group and evaluating based on the following criteria.

[评价基准][Evaluation criteria]

×:无咸味增强效果×: No salty taste enhancement effect

△:稍微有咸味增强效果△: Slightly enhances the salty taste

○:有咸味增强效果○: Has a salty taste enhancement effect

◎:相当有咸味增强效果◎: Significantly enhances the salty taste

结果示于下表1。The results are shown in Table 1 below.

[表1][Table 1]

评价体系:日式面条汤底Evaluation system: Japanese noodle soup base

(试验例2:鸡骨架汤)(Test Example 2: Chicken Skeleton Soup)

<对照组的调制><Preparation of control group>

用热水溶解市售的鸡骨架汤调味料(味之素株式会社制造,“MarudorigaraSoup”),使得其相对于鸡骨架汤的总重量为1.67重量%,调制鸡骨架汤,作为对照组(对照组的盐分浓度:0.8%)。A commercially available chicken broth seasoning (Marudorigara Soup, manufactured by Ajinomoto Co., Ltd.) was dissolved in hot water to a concentration of 1.67% by weight relative to the total weight of the chicken broth to prepare chicken broth as a control group (salt concentration of the control group: 0.8%).

<评价样品的调制><Preparation of evaluation samples>

如下表2所示地,向对照组中,相对于评价样品的总重量,添加0.0001~10重量ppm的4-甲基戊酸,调制评价样品。As shown in Table 2 below, 0.0001 to 10 ppm by weight of 4-methylvaleric acid was added to the control group based on the total weight of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,与试验例1一样地实施感官评价。Sensory evaluation was performed in the same manner as in Test Example 1 regarding the saltiness intensity of the evaluation samples.

结果示于下表2。The results are shown in Table 2 below.

[表2][Table 2]

评价体系:鸡骨架汤Evaluation system: Chicken skeleton soup

(试验例3:味增汤)(Test Example 3: Miso Soup)

<对照组的调制><Preparation of control group>

用热水溶解市售的鲣鱼风味调味料(味之素株式会社制造,“Hondashi(注册商标)”),使得其相对于味增汤的总重量为0.67重量%,用热水溶解市售的味噌(MARUSAN-AI株式会社制造,“Junsei Koji Miso”),使得其相对于味噌汤的总重量为6重量%,调制味增汤,作为对照组(对照组的盐分浓度:0.97%)。Commercially available bonito flavor seasoning (manufactured by Ajinomoto Co., Ltd., "Hondashi (registered trademark)") was dissolved in hot water to a concentration of 0.67% by weight relative to the total weight of the miso soup, and commercially available miso (manufactured by MARUSAN-AI Co., Ltd., "Junsei Koji Miso") was dissolved in hot water to a concentration of 6% by weight relative to the total weight of the miso soup, and miso soup was prepared as a control group (salt concentration of the control group: 0.97%).

<评价样品的调制><Preparation of evaluation samples>

如下表3所示地,向对照组中,相对于评价样品的总重量,添加0.0001~10重量ppm的4-甲基戊酸,调制评价样品。As shown in Table 3 below, 0.0001 to 10 ppm by weight of 4-methylvaleric acid was added to the control group based on the total weight of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,与试验例1一样地实施感官评价。Sensory evaluation was performed in the same manner as in Test Example 1 regarding the saltiness intensity of the evaluation samples.

结果示于下表3。The results are shown in Table 3 below.

[表3][Table 3]

评价体系:味增汤Evaluation system: Miso soup

(试验例4:玉米汤)(Test Example 4: Corn Soup)

<对照组的调制><Preparation of control group>

用热水溶解市售的干燥玉米汤(味之素株式会社制造,“Knorr(注册商标)CupSoup Corn Cream”),使得其相对于玉米汤的总重量为11.7重量%,调制玉米汤,作为对照组(对照组的盐分浓度:0.67%)。Commercially available dry corn soup ("Knorr (registered trademark) Cup Soup Corn Cream" manufactured by Ajinomoto Co., Ltd.) was dissolved in hot water to a concentration of 11.7% by weight relative to the total weight of the corn soup to prepare corn soup, which was used as a control group (salt concentration of the control group: 0.67%).

<评价样品的调制><Preparation of evaluation samples>

如下表4所示地,向对照组中,相对于评价样品的总重量,添加0.0001~10重量ppm的4-甲基戊酸,调制评价样品。As shown in Table 4 below, 0.0001 to 10 ppm by weight of 4-methylvaleric acid was added to the control group based on the total weight of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,与试验例1一样地实施感官评价。Sensory evaluation was performed in the same manner as in Test Example 1 regarding the saltiness intensity of the evaluation samples.

结果示于下表4。The results are shown in Table 4 below.

[表4][Table 4]

评价体系:玉米汤Evaluation system: Corn soup

(试验例5:法式浓汤)(Test Example 5: French Soup)

<对照组的调制><Preparation of control group>

用热水溶解市售的干燥法式浓汤(味之素株式会社制造,“Knorr(注册商标)CupSoup Potage”),使得其相对于法式浓汤的总重量为11.3重量%,调制法式浓汤,作为对照组(对照组的盐分浓度:0.8%)。Commercially available dried bisque (“Knorr (registered trademark) Cup Soup Potage” manufactured by Ajinomoto Co., Ltd.) was dissolved in hot water to a concentration of 11.3% by weight relative to the total weight of the bisque, and bisque was prepared as a control group (salt concentration of the control group: 0.8%).

<评价样品的调制><Preparation of evaluation samples>

如下表5所示地,向对照组中,相对于评价样品的总重量,添加0.001~10重量ppm的4-甲基戊酸,调制评价样品。As shown in Table 5 below, 0.001 to 10 ppm by weight of 4-methylvaleric acid was added to the control group based on the total weight of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,与试验例1一样地实施感官评价。Sensory evaluation was performed in the same manner as in Test Example 1 regarding the saltiness intensity of the evaluation samples.

结果示于下表5。The results are shown in Table 5 below.

[表5][Table 5]

评价体系:法式浓汤Evaluation system: French soup

(试验例6:法式清汤)(Test Example 6: French Bouillabaisse)

<对照组的调制><Preparation of control group>

用热水溶解市售的干燥法式清汤(味之素株式会社制造,“味之素KK Consomme”),使得其相对于法式清汤的总重量为1.77重量%,调制法式清汤,作为对照组(对照组的盐分浓度:0.83%)。Commercially available dry consomme (Ajinomoto Co., Ltd., "Ajinomoto KK Consomme") was dissolved in hot water to a concentration of 1.77% by weight relative to the total weight of the consomme to prepare a consomme as a control group (salt concentration of the control group: 0.83%).

<评价样品的调制><Preparation of evaluation samples>

如下表6所示地,向对照组中,相对于评价样品的总重量,添加0.01~10重量ppm的4-甲基戊酸,调制评价样品。As shown in Table 6 below, 0.01 to 10 ppm by weight of 4-methylvaleric acid was added to the control group based on the total weight of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,与试验例1一样地实施感官评价。Sensory evaluation was performed in the same manner as in Test Example 1 regarding the saltiness intensity of the evaluation samples.

结果示于下表6。The results are shown in Table 6 below.

[表6][Table 6]

评价体系:法式清汤Evaluation system: French consommé

(试验例7:奶酪酱)(Test Example 7: Cheese Sauce)

<对照组><Control group>

直接使用市售的奶酪酱(Mizkan America公司制造,“RAGU(注册商标)DoubleCheddar cheese sauce”)作为对照组(对照组的盐分浓度:1.8%)。As a control group, commercially available cheese sauce ("RAGU (registered trademark) Double Cheddar cheese sauce" manufactured by Mizkan America) was used as it is (salt concentration of the control group: 1.8%).

<评价样品的调制><Preparation of evaluation samples>

如下表7所示地,向对照组中,相对于评价样品的总重量,添加0.0001~10重量ppm的4-甲基戊酸,调制评价样品。As shown in Table 7 below, 0.0001 to 10 ppm by weight of 4-methylvaleric acid was added to the control group based on the total weight of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,与试验例1一样地实施感官评价。Sensory evaluation was performed in the same manner as in Test Example 1 regarding the saltiness intensity of the evaluation samples.

结果示于下表7。The results are shown in Table 7 below.

[表7][Table 7]

评价体系:奶酪酱Rating system:Cheese sauce

根据表1~7所示的结果可明确,在添加有4-甲基戊酸的各种各样的含有食盐的食品中,与对照组相比,咸味增强,已经确认:4-甲基戊酸对于各种各样的含有食盐的食品具有咸味增强效果。The results shown in Tables 1 to 7 clearly show that the salty taste of various salt-containing foods to which 4-methylvaleric acid was added was enhanced compared to the control group, and it was confirmed that 4-methylvaleric acid has a salty taste enhancing effect on various salt-containing foods.

4-甲基戊酸的添加量多时,有时也存在根据食品而感觉到异味的情况。When the amount of 4-methylvaleric acid added is large, an unpleasant smell may be perceived in some foods.

(试验例8)(Test Example 8)

<对照组的调制><Preparation of control group>

向下表10所示的市售的食品中,添加食盐,使得其为下表11所示的盐分浓度,作为对照组。Salt was added to the commercially available foods shown in Table 10 below so as to have the salt concentrations shown in Table 11 below, and these were used as a control group.

<评价样品的调制><Preparation of evaluation samples>

各对照组中,向盐分浓度超过1%的对照组中,以表8所示的量,另外,向盐分浓度为1%以下的对照组中,以表9所示的量,分别添加4-甲基戊酸、3-甲硫基丙醛、丁酸和葫芦巴内酯,调制评价样品。In each control group, 4-methylvaleric acid, 3-methylthiopropionaldehyde, butyric acid and fenugreek lactone were added in the amounts shown in Table 8 to the control group having a salt concentration of more than 1%, and in the amounts shown in Table 9 to the control group having a salt concentration of less than 1%, respectively, to prepare evaluation samples.

对评价样品的咸味强度,实施感官评价。Sensory evaluation was performed on the saltiness intensity of the evaluation samples.

通过2名专业评价员,将评价样品与对照组相比较,基于下述基准评价,从而进行感官评价。The sensory evaluation was performed by two professional panelists by comparing the evaluation samples with the control group and evaluating based on the following criteria.

[评价基准][Evaluation criteria]

×:无咸味增强效果×: No salty taste enhancement effect

△:稍微有咸味增强效果△: Slightly enhances the salty taste

○:有咸味增强效果○: Has a salty taste enhancement effect

◎:相当有咸味增强效果◎: Significantly enhances the salty taste

结果示于下表11。The results are shown in Table 11 below.

[表8][Table 8]

[表9][Table 9]

根据表11所示的结果可明确,添加有4-甲基戊酸、3-甲硫基丙醛、丁酸和葫芦巴内酯的各含有食盐的食品中,确认有咸味增强效果。其中,盐分浓度超过1重量%的含有食盐的食品中,确认有更高的咸味增强效果。The results shown in Table 11 clearly show that the salty taste enhancing effect was observed in each of the salt-containing foods to which 4-methylvaleric acid, 3-methylthiopropionaldehyde, butyric acid, and fenugreek lactone were added. In particular, a higher salty taste enhancing effect was observed in the salt-containing foods having a salt concentration exceeding 1% by weight.

另外,添加有4-甲基戊酸、3-甲硫基丙醛、丁酸和葫芦巴内酯的各含有食盐的食品之中,在鸡骨架汤、减盐鸡骨架汤、牛肉风味调味料、鸡肉风味调味料、法式清汤、减盐法式清汤和多明格拉斯酱中,确认有畜肉风味增强效果,在奶酪酱中,确认有奶酪风味增强效果连同咸味增强效果。In addition, among the foods containing salt to which 4-methylvaleric acid, 3-methylthiopropionaldehyde, butyric acid and fenugreek lactone were added, the meat flavor enhancement effect was confirmed in chicken bone soup, reduced-salt chicken bone soup, beef flavor seasoning, chicken flavor seasoning, French consomme, reduced-salt French consomme and domingo sauce, and the cheese flavor enhancement effect and salty taste enhancement effect were confirmed in cheese sauce.

(试验例9)(Test Example 9)

<对照组的调制><Preparation of control group>

按照下述方法,分别针对日式面条汤底、法式清汤、鸡骨架汤、味噌汤和卡尔博纳拉酱,调制对照组。Prepare control groups for Japanese noodle soup base, French consomme, chicken bone soup, miso soup, and carbonara sauce as described below.

(日式面条汤底)(Japanese noodle soup base)

用水稀释市售的浓缩型日式面条汤底(YAMAKI株式会社制造,“Mentsuyu”),使得其相对于稀释后的日式面条汤底的总重量为33重量%,然后,添加4-甲基戊酸,使得其相对于对照组总量为0.005重量ppm,将所获得的日式面条汤底作为对照组(对照组的盐分浓度:2.3%)。A commercially available concentrated Japanese noodle soup base (manufactured by YAMAKI Co., Ltd., "Mentsuyu") was diluted with water to 33% by weight relative to the total weight of the diluted Japanese noodle soup base, and then 4-methylvaleric acid was added to 0.005 ppm by weight relative to the total amount of the control group. The obtained Japanese noodle soup base was used as a control group (salt concentration of the control group: 2.3%).

(法式清汤)(French Bouillabaisse)

用热水溶解市售的干燥法式清汤(味之素株式会社制造,“Ajinomoto KKConsomme”),使得其相对于法式清汤的总重量为1.77重量%,然后,添加4-甲基戊酸,使得其相对于对照组的总量为0.005重量ppm,将所获得的法式清汤作为对照组(对照组的盐分浓度:0.83%)。Commercially available dry consomme (manufactured by Ajinomoto Co., Ltd., "Ajinomoto KKConsomme") was dissolved in hot water to a concentration of 1.77 wt % relative to the total weight of the consomme. Then, 4-methylvaleric acid was added to a concentration of 0.005 wt ppm relative to the total amount of the control group, and the resulting consomme was used as a control group (salt concentration of the control group: 0.83%).

(鸡骨架汤)(Chicken Skeleton Soup)

用热水溶解市售的鸡骨架汤调味料(味之素株式会社制造,“MarudorigaraSoup”),使得其相对于鸡骨架汤的总重量为1.67重量%,然后,添加4-甲基戊酸,使得其相对于对照组总量为0.005重量ppm,将所获得的鸡骨架汤作为对照组(对照组的盐分浓度:0.8%)。Commercially available chicken skeleton soup seasoning (manufactured by Ajinomoto Co., Ltd., "Marudorigara Soup") was dissolved in hot water to a concentration of 1.67 wt % relative to the total weight of the chicken skeleton soup. Then, 4-methylvaleric acid was added to a concentration of 0.005 wt ppm relative to the total amount of the control group, and the obtained chicken skeleton soup was used as a control group (salt concentration of the control group: 0.8%).

(味噌汤)(Miso Soup)

用热水溶解市售的鲣鱼风味调味料(味之素株式会社制造,“Hondashi(注册商标)”),使得其相对于味噌汤的总重量为0.67重量%,用热水溶解市售的味噌(MARUSAN-AI株式会社制造,“Junsei Koji Miso”),使得其相对于味噌汤的总重量为6重量%,然后,添加4-甲基戊酸,使得其相对于对照组总量为0.005重量ppm,将所获得的味噌汤作为对照组(对照组的盐分浓度:0.97%)。Commercially available bonito flavor seasoning (manufactured by Ajinomoto Co., Ltd., "Hondashi (registered trademark)") was dissolved in hot water so as to account for 0.67% by weight relative to the total weight of the miso soup, and commercially available miso (manufactured by MARUSAN-AI Co., Ltd., "Junsei Koji Miso") was dissolved in hot water so as to account for 6% by weight relative to the total weight of the miso soup. Then, 4-methylvaleric acid was added so as to account for 0.005 ppm by weight relative to the total amount of the control group, and the obtained miso soup was used as a control group (salt concentration of the control group: 0.97%).

(卡尔博纳拉酱)(Carbonara sauce)

向市售的卡尔博纳拉酱(Seven&i Holdings株式会社制造,“Carbonara”)中,添加4-甲基戊酸,使得其相对于对照组总量为0.005重量ppm,将所获得的卡尔博纳拉酱作为对照组(对照组的盐分浓度:0.97%)。A control group was prepared by adding 0.005 ppm by weight of 4-methylvaleric acid to commercially available Carbonara sauce (Carbonara, manufactured by Seven & i Holdings Co., Ltd.) (salt concentration of the control group: 0.97%).

<评价样品的调制><Preparation of evaluation samples>

如下表12所示地,向各对照组中,相对于评价样品总量,添加0.001~0.05重量ppm的3-甲硫基丙醛,调制评价样品。As shown in Table 12 below, 0.001 to 0.05 ppm by weight of 3-methylthiopropionaldehyde was added to each control group based on the total amount of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,实施感官评价。Sensory evaluation was performed on the saltiness intensity of the evaluation samples.

通过2名专业评价员,将评价样品与各食品的对照组进行比较,基于下述基准评价,从而进行感官评价。The sensory evaluation was performed by two professional assessors by comparing the evaluation samples with a control group of each food and evaluating based on the following criteria.

[评价基准][Evaluation criteria]

◎:咸味相当强◎: Very strong salty taste

○:咸味强○: Strong salty taste

△:咸味略微强△: Slightly salty

×:咸味无变化或者弱×: No change or weak saltiness

结果示于下表12。The results are shown in Table 12 below.

[表12][Table 12]

根据表12所示的结果可明确,与相对于含有食盐的食品添加4-甲基戊酸,使得其为0.005重量ppm的情况相比较,通过相对于含有食盐的食品分别添加4-甲基戊酸和3-甲硫基丙醛,使得它们分别为0.005重量ppm以及0.001~0.05重量ppm,可以更有效地增强各含有食盐的食品的咸味。It is clear from the results shown in Table 12 that, compared with the case where 4-methylvaleric acid is added to foods containing salt in an amount of 0.005 ppm by weight, the saltiness of each food containing salt can be more effectively enhanced by adding 4-methylvaleric acid and 3-methylthiopropionaldehyde to foods containing salt in an amount of 0.005 ppm by weight and 0.001 to 0.05 ppm by weight, respectively.

(试验例10)(Test Example 10)

<对照组的调制><Preparation of control group>

按照以下方法,对于日式面条汤底、法式清汤和卡尔博纳拉酱,分别调制对照组。Prepare control groups for Japanese noodle soup base, French consomme, and Carbonara sauce as follows.

(日式面条汤底)(Japanese noodle soup base)

用水稀释市售的浓缩型日式面条汤底(YAMAKI株式会社制造,“Mentsuyu”),使得其相对于稀释后的日式面条汤底的总重量为33重量%,然后,分别添加4-甲基戊酸和3-甲硫基丙醛,使得它们相对于对照组总量分别为0.005重量ppm和0.01重量ppm,将所获得的日式面条汤底作为对照组(对照组的盐分浓度:2.3%)。A commercially available concentrated Japanese noodle soup base (manufactured by YAMAKI Co., Ltd., "Mentsuyu") was diluted with water to 33 wt % relative to the total weight of the diluted Japanese noodle soup base, and then 4-methylvaleric acid and 3-methylthiopropionaldehyde were added to each other so that their amounts were 0.005 wt ppm and 0.01 wt ppm, respectively, relative to the total amount of the control group. The obtained Japanese noodle soup base was used as a control group (salt concentration of the control group: 2.3%).

(法式清汤)(French Bouillabaisse)

用热水溶解市售的干燥法式清汤(味之素株式会社制造,“Ajinomoto KKConsomme”),使得其相对于法式清汤的总重量为1.77重量%,然后,分别添加4-甲基戊酸和3-甲硫基丙醛,使得它们相对于对照组总量分别为0.005重量ppm和0.01重量ppm,将所获得的法式清汤作为对照组(对照组的盐分浓度:0.83%)。Commercially available dry consomme (manufactured by Ajinomoto Co., Ltd., "Ajinomoto KKConsomme") was dissolved in hot water to a concentration of 1.77 wt % relative to the total weight of the consomme. Then, 4-methylvaleric acid and 3-methylmercaptopropionaldehyde were added to a concentration of 0.005 wt ppm and 0.01 wt ppm, respectively, relative to the total weight of the control group. The resulting consomme was used as a control group (salt concentration of the control group: 0.83%).

(卡尔博纳拉酱)(Carbonara sauce)

向市售的卡尔博纳拉酱(Seven&i Holdings株式会社制造,“Carbonara”)中,分别添加4-甲基戊酸和3-甲硫基丙醛,使得它们相对于对照组总量分别为0.005重量ppm和0.01重量ppm,将所获得的卡尔博纳拉酱作为对照组(对照组的盐分浓度:0.97%)。To commercially available Carbonara sauce (Carbonara, manufactured by Seven & i Holdings Co., Ltd.), 4-methylvaleric acid and 3-methylthiopropionaldehyde were added so that the amounts thereof were 0.005 ppm by weight and 0.01 ppm by weight, respectively, based on the total amount of the control group, and the obtained Carbonara sauce was used as a control group (salt concentration of the control group: 0.97%).

<评价样品的调制><Preparation of evaluation samples>

如下表13所示地,向各对照组中,相对于评价样品总量,添加0.01~0.5重量ppm的丁酸,调制评价样品。As shown in Table 13 below, to each control group, 0.01 to 0.5 ppm by weight of butyric acid was added based on the total amount of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,实施感官评价。Sensory evaluation was performed on the saltiness intensity of the evaluation samples.

通过2名专业评价员,将评价样品与各食品的对照组进行比较,基于下述基准评价,从而进行感官评价。The sensory evaluation was performed by two professional assessors by comparing the evaluation samples with a control group of each food and evaluating based on the following criteria.

[评价基准][Evaluation criteria]

◎:咸味相当强◎: Very strong salty taste

○:咸味强○: Strong salty taste

△:咸味略微强△: Slightly salty

×:咸味无变化或弱×: No change or weak saltiness

结果示于下表13。The results are shown in Table 13 below.

[表13][Table 13]

根据表13所示的结果可明确,与相对于含有食盐的食品,分别添加4-甲基戊酸和3-甲硫基丙醛,使得它们分别为0.005重量ppm和0.01重量ppm的情况相比较,通过相对于含有食盐的食品,分别添加4-甲基戊酸、3-甲硫基丙醛和丁酸,使得它们分别为0.005重量ppm、0.01重量ppm和0.01~0.5重量ppm,可以更有效地增强各含有食盐的食品的咸味。It is clear from the results shown in Table 13 that the saltiness of each food containing salt can be more effectively enhanced by adding 4-methylvaleric acid, 3-methylmercaptopropionaldehyde and butyric acid to foods containing salt in amounts of 0.005 wt ppm, 0.01 wt ppm and 0.01 to 0.5 wt ppm, respectively, compared to the case where 4-methylvaleric acid and 3-methylmercaptopropionaldehyde are added to foods containing salt in amounts of 0.005 wt ppm and 0.01 wt ppm, respectively.

(试验例11)(Test Example 11)

<对照组的调制><Preparation of control group>

按照下述方法,对于日式面条汤底、法式清汤、鸡骨架汤、味噌汤和卡尔博纳拉酱,分别调制对照组。A control group was prepared for Japanese noodle soup, French consomme, chicken bone soup, miso soup, and carbonara sauce as described below.

(日式面条汤底)(Japanese noodle soup base)

用水稀释市售的浓缩型日式面条汤底(YAMAKI株式会社制造,“Mentsuyu”),使得其相对于稀释后的日式面条汤底的总重量为33重量%,然后,分别添加4-甲基戊酸、3-甲硫基丙醛和丁酸,使得它们相对于对照组总量分别为0.005重量ppm、0.01重量ppm和0.1重量ppm,将所获得的日式面条汤底作为对照组(对照组的盐分浓度:2.3%)。A commercially available concentrated Japanese noodle soup base (manufactured by YAMAKI Co., Ltd., "Mentsuyu") was diluted with water to 33 wt % relative to the total weight of the diluted Japanese noodle soup base, and then 4-methylvaleric acid, 3-methylthiopropionaldehyde and butyric acid were added respectively to make their amounts 0.005 wt ppm, 0.01 wt ppm and 0.1 wt ppm relative to the total amount of the control group, and the obtained Japanese noodle soup base was used as a control group (salt concentration of the control group: 2.3%).

(法式清汤)(French Bouillabaisse)

用热水溶解市售的干燥法式清汤(味之素株式会社制造,“Ajinomoto KKConsomme”),使得其相对于法式清汤的总重量为1.77重量%,然后,分别添加4-甲基戊酸、3-甲硫基丙醛和丁酸,使得它们相对于对照组总量分别为0.005重量ppm、0.01重量ppm和0.1重量ppm,将所获得的法式清汤作为对照组(对照组的盐分浓度:0.83%)。Commercially available dry consomme (manufactured by Ajinomoto Co., Ltd., "Ajinomoto KKConsomme") was dissolved in hot water to a concentration of 1.77 wt % relative to the total weight of the consomme. Then, 4-methylvaleric acid, 3-methylthiopropionaldehyde, and butyric acid were added to a concentration of 0.005 wt ppm, 0.01 wt ppm, and 0.1 wt ppm, respectively, relative to the total amount of the control group. The resulting consomme was used as a control group (salt concentration of the control group: 0.83%).

(鸡骨架汤)(Chicken Skeleton Soup)

用热水溶解市售的鸡骨架汤调味料(味之素株式会社制造,“MarudorigaraSoup”)使得其相对于鸡骨架汤的总重量为1.67重量%,然后,分别添加4-甲基戊酸、3-甲硫基丙醛和丁酸,使得它们相对于对照组总量分别为0.005重量ppm、0.01重量ppm和0.1重量ppm,将所获得的鸡骨架汤作为对照组(对照组的盐分浓度:0.8%)。Commercially available chicken skeleton soup seasoning (manufactured by Ajinomoto Co., Ltd., "Marudorigara Soup") was dissolved in hot water to a concentration of 1.67 wt % relative to the total weight of the chicken skeleton soup. Then, 4-methylvaleric acid, 3-methylthiopropionaldehyde and butyric acid were added to a concentration of 0.005 wt ppm, 0.01 wt ppm and 0.1 wt ppm, respectively, relative to the total amount of the control group. The obtained chicken skeleton soup was used as a control group (salt concentration of the control group: 0.8%).

(味噌汤)(Miso Soup)

用热水溶解市售的鲣鱼风味调味料(味之素株式会社制造,“Hondashi(注册商标)”),使得其相对于味噌汤的总重量为0.67重量%,用热水溶解市售的味增(MARUSAN-AI株式会社制造,“Junsei Koji Miso”),使得其相对于味噌汤的总重量为6重量%,然后,分别添加4-甲基戊酸、3-甲硫基丙醛和丁酸,使得它们相对于对照组总量分别为0.005重量ppm、0.01重量ppm和0.1重量ppm,将所获得的味噌汤作为对照组(对照组的盐分浓度:0.97%)。Commercially available bonito flavor seasoning (manufactured by Ajinomoto Co., Ltd., "Hondashi (registered trademark)") was dissolved in hot water to a concentration of 0.67% by weight relative to the total weight of the miso soup, and commercially available miso (manufactured by MARUSAN-AI Co., Ltd., "Junsei Koji Miso") was dissolved in hot water to a concentration of 6% by weight relative to the total weight of the miso soup. Then, 4-methylvaleric acid, 3-methylthiopropionaldehyde, and butyric acid were added to a concentration of 0.005 ppm by weight, 0.01 ppm by weight, and 0.1 ppm by weight, respectively, relative to the total amount of the control group. The resulting miso soup was used as a control group (salt concentration of the control group: 0.97%).

(卡尔博纳拉酱)(Carbonara sauce)

向市售的卡尔博纳拉酱(Seven&i Holdings株式会社制造,“Carbonara”)中,分别添加4-甲基戊酸、3-甲硫基丙醛和丁酸,使得它们相对于对照组总量分别为0.005重量ppm、0.01重量ppm和0.1重量ppm,将所获得的卡尔博纳拉酱作为对照组(对照组的盐分浓度:0.97%)。To commercially available Carbonara sauce (manufactured by Seven & i Holdings Co., Ltd., "Carbonara"), 4-methylvaleric acid, 3-methylthiopropionaldehyde, and butyric acid were added so that their amounts were 0.005 ppm by weight, 0.01 ppm by weight, and 0.1 ppm by weight, respectively, relative to the total amount of the control group, and the obtained Carbonara sauce was used as a control group (salt concentration of the control group: 0.97%).

<评价样品的调制><Preparation of evaluation samples>

如下表14所示地,向各对照组中,相对于评价样品总量,添加0.001~0.05重量ppm的葫芦巴内酯,调制评价样品。As shown in Table 14 below, 0.001 to 0.05 ppm by weight of fenugreek lactone was added to each control group based on the total amount of the evaluation sample to prepare the evaluation sample.

对评价样品的咸味强度,实施感官评价。Sensory evaluation was performed on the saltiness intensity of the evaluation samples.

通过2名专业评价员,将评价样品与各食品的对照组进行比较,基于下述基准评价,从而进行感官评价。The sensory evaluation was performed by two professional assessors by comparing the evaluation samples with a control group of each food and evaluating based on the following criteria.

[评价基准][Evaluation criteria]

◎:咸味相当强◎: Very strong salty taste

○:咸味强○: Strong salty taste

△:咸味略微强△: Slightly salty

×:咸味无变化或弱×: No change or weak saltiness

结果示于下表14。The results are shown in Table 14 below.

[表14][Table 14]

根据表14所示的结果可明确,与相对于含有食盐的食品,分别添加4-甲基戊酸、3-甲硫基丙醛和丁酸,使得它们分别为0.005重量ppm、0.01重量ppm和0.1重量ppm的情况相比较,通过相对于含有食盐的食品,分别添加4-甲基戊酸、3-甲硫基丙醛、丁酸和葫芦巴内酯,使得它们分别为0.005重量ppm、0.01重量ppm、0.1重量ppm和0.001~0.05重量ppm,可以更有效地增强各含有食盐的食品的咸味。It is clear from the results shown in Table 14 that the saltiness of each food containing salt can be more effectively enhanced by adding 4-methylvaleric acid, 3-methylmercaptopropionaldehyde, butyric acid and fenugreek lactone to foods containing salt in amounts of 0.005 wt ppm, 0.01 wt ppm, 0.1 wt ppm and 0.001 to 0.05 wt ppm, respectively, compared to the case where 4-methylvaleric acid, 3-methylmercaptopropionaldehyde and butyric acid are added to foods containing salt in amounts of 0.005 wt ppm, 0.01 wt ppm and 0.1 wt ppm, respectively.

(试验例12)(Test Example 12)

<对照组的调制><Preparation of control group>

(氯化钠水溶液)(Sodium chloride aqueous solution)

调制1%氯化钠水溶液,作为对照组。A 1% sodium chloride aqueous solution was prepared as a control group.

(拉面)(Hand-Pulled Noodle)

将市售的速食拉面(三洋食品株式会社制造,“Sapporo Ichiban Shoyu Aji”)的汤用粉末8g溶解在500mL的沸腾过的热水中,调制拉面汤,作为对照组。8 g of soup powder of commercially available instant ramen ("Sapporo Ichiban Shoyu Aji", manufactured by Sanyo Foods Co., Ltd.) was dissolved in 500 mL of boiling hot water to prepare ramen soup, which was used as a control group.

<评价样品的调制><Preparation of evaluation samples>

向对照组中,添加下表15所示的各成分,使得其相对于评价样品总量为0.01重量ppm,调制评价样品。To the control group, each component shown in the following Table 15 was added so as to be 0.01 ppm by weight based on the total amount of the evaluation sample, thereby preparing an evaluation sample.

对评价样品的咸味强度、辛香感强度,实施感官评价。Sensory evaluation was performed on the saltiness intensity and spicy intensity of the evaluation samples.

通过2名专业评价员,将氯化钠水溶液的评价样品与对照组进行比较,基于下述基准评价,从而进行咸味强度的感官评价。The sensory evaluation of the saltiness intensity was performed by two professional panelists by comparing the evaluation samples of the sodium chloride aqueous solution with the control group and evaluating based on the following criteria.

另外,通过2名专业评价员,将拉面的评价样品与对照组进行比较,基于下述基准评价,从而进行辛香感强度的感官评价。In addition, two professional panelists compared the evaluation samples of ramen noodles with the control group and evaluated them based on the following criteria to conduct a sensory evaluation of the intensity of spicy flavor.

[评价基准][Evaluation criteria]

◎:咸味强度或辛香感强度明显强于对照组◎: The saltiness or spicy intensity is significantly stronger than the control group

○:咸味强度或辛香感强度略微强于对照组○: The saltiness or spiciness is slightly stronger than the control group

△:咸味强度或辛香感强度与对照组相同△: The saltiness or spicy intensity is the same as the control group

×:咸味强度或辛香感强度弱于对照组×: The saltiness or spicy intensity is weaker than the control group

结果示于下表15。The results are shown in Table 15 below.

[表15][Table 15]

已经确认:与对照组相比较,添加有异丁酸、异缬草酸、2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸、4-甲基壬酸的含有食盐的食品、含有辛香料的食品中,咸味、辛香感增强,该成分对含有食盐的食品具有咸味增强效果,另外,对含有辛香料的食品具有辛香感增强效果。It has been confirmed that compared with the control group, the salty taste and spicy aroma of foods containing salt and foods containing spices to which isobutyric acid, isovaleric acid, 2-methylvaleric acid, 3-methylvaleric acid, 4-methylvaleric acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, 4-methyloctanoic acid, and 4-methylnonanoic acid are added are enhanced. This ingredient has a salty taste enhancing effect on foods containing salt, and also has a spicy aroma enhancing effect on foods containing spices.

(试验例13)(Test Example 13)

<阴性对照的调制><Preparation of negative control>

(日式面条汤底)(Japanese noodle soup base)

用水稀释(2倍稀释)市售的浓缩型日式面条汤底(YAMAKI株式会社制造,“Mentsuyu”),使得其相对于稀释后的日式面条汤底的总重量为50重量%,调制日式面条汤底,作为阴性对照(阴性对照的盐分浓度:3.5%)。A commercially available concentrated Japanese noodle soup base ("Mentsuyu" manufactured by YAMAKI Co., Ltd.) was diluted with water (2-fold dilution) to 50% by weight relative to the total weight of the diluted Japanese noodle soup base, and a Japanese noodle soup base was prepared as a negative control (salt concentration of negative control: 3.5%).

(奶酪酱)(Cheese Sauce)

直接将市售的奶酪酱(Mizkan America公司制造,“RAGU(注册商标)DoubleCheddar cheese sauce”)用作阴性对照(阴性对照的盐分浓度:1.8%)。A commercially available cheese sauce ("RAGU (registered trademark) Double Cheddar cheese sauce" manufactured by Mizkan America) was used as a negative control (salt concentration of the negative control: 1.8%).

<阳性对照的调制><Preparation of positive control>

(日式面条汤底)(Japanese noodle soup base)

用水稀释(2倍稀释)市售的浓缩型日式面条汤底(YAMAKI株式会社制造,“Mentsuyu”),使得其相对于稀释后的日式面条汤底的总重量为50重量%,然后,分别添加4-甲基戊酸、3-甲硫基丙醛、丁酸和葫芦巴内酯,使得它们相对于阳性对照总量分别为下表16所示的量,将所获得的日式面条汤底作为阳性对照(阳性对照的盐分浓度:3.5%)。A commercially available concentrated Japanese noodle soup base (manufactured by YAMAKI Co., Ltd., "Mentsuyu") was diluted with water (2-fold dilution) to 50% by weight relative to the total weight of the diluted Japanese noodle soup base, and then 4-methylvaleric acid, 3-methylthiopropionaldehyde, butyric acid and fenugreek lactone were added respectively so that their amounts relative to the total amount of the positive control were shown in the following Table 16, and the obtained Japanese noodle soup base was used as a positive control (salt concentration of the positive control: 3.5%).

(奶酪酱)(Cheese Sauce)

向市售的奶酪酱(Mizkan America公司制造,“RAGU(注册商标)Double Cheddarcheese sauce”)中,分别添加4-甲基戊酸、3-甲硫基丙醛、丁酸和葫芦巴内酯,使得它们相对于阳性对照总量分别为下表17所示的量,将所获得的奶酪酱作为阳性对照(阳性对照的盐分浓度:1.8%)。To a commercially available cheese sauce ("RAGU (registered trademark) Double Cheddarcheese sauce" manufactured by Mizkan America), 4-methylvaleric acid, 3-methylthiopropionaldehyde, butyric acid and fenugreek lactone were added respectively so that their amounts relative to the total amount of the positive control were as shown in the following Table 17, and the obtained cheese sauce was used as a positive control (salt concentration of the positive control: 1.8%).

[表16][Table 16]

[表17][Table 17]

<评价样品的调制><Preparation of evaluation samples>

除了使用下表18记载的各有机酸代替4-甲基戊酸之外,通过与阳性对照相同的步骤,分别对于日式面条汤底和奶酪酱,调制评价样品。Evaluation samples were prepared for Japanese noodle soup base and cheese sauce respectively by the same procedure as the positive control except that each organic acid described in Table 18 below was used instead of 4-methylvaleric acid.

对评价样品的咸味强度,实施感官评价。Sensory evaluation was performed on the saltiness intensity of the evaluation samples.

感官评价通过下述方法进行:2名专业评价员以非盲方式通过合议对各评价样品进行评分(以0.5分为增量),其中,将阴性对照设定为0分,将阳性对照设定为5分。The sensory evaluation was performed by the following method: 2 professional evaluators scored each evaluation sample by consensus in a non-blind manner (in increments of 0.5 points), wherein the negative control was set to 0 points and the positive control was set to 5 points.

结果示于下表18。The results are shown in Table 18 below.

[表18][Table 18]

已经确认:与4-甲基戊酸相同地,异丁酸、异缬草酸、5-甲基己酸、4-甲基辛酸、4-甲基壬酸通过与3-甲硫基丙醛、丁酸和葫芦巴内酯并用,可以更有效地增强含有食盐的食品的咸味。It has been confirmed that, similar to 4-methylvaleric acid, isobutyric acid, isovaleric acid, 5-methylhexanoic acid, 4-methyloctanoic acid, and 4-methylnonanoic acid can more effectively enhance the salty taste of foods containing salt by using them in combination with 3-methylmercaptopropionaldehyde, butyric acid, and trigonelline.

(试验例14)(Test Example 14)

<阴性对照的调制><Preparation of negative control>

(拉面)(Hand-Pulled Noodle)

将市售的速食拉面(三洋食品株式会社制造,“Sapporo Ichiban Shoyu Aji”)的汤用粉末8g溶解在500mL的沸腾过的热水中,调制拉面汤,作为阴性对照。As a negative control, 8 g of soup powder of commercially available instant ramen ("Sapporo Ichiban Shoyu Aji", manufactured by Sanyo Foods Co., Ltd.) was dissolved in 500 mL of boiling hot water to prepare ramen soup.

(朝鲜泡菜(kimchi)锅)(Kimchi Pot)

用6倍(重量)的热水稀释市售的锅物调味料(EBARA食品工业株式会社制造,“Kimchi Nabe no moto”),调制朝鲜泡菜锅汤,作为阴性对照。A commercially available hot pot seasoning ("Kimchi Nabe no moto" manufactured by EBARA Food Industry Co., Ltd.) was diluted with 6 times (by weight) of hot water to prepare kimchi hot pot soup as a negative control.

<阳性对照的调制><Preparation of positive control>

(拉面)(Hand-Pulled Noodle)

将市售的速食拉面(三洋食品株式会社制造,“Sapporo Ichiban Shoyu Aji”)的汤用粉末8g溶解在500mL的沸腾过的热水中,然后,分别添加4-甲基戊酸、3-甲硫基丙醛、丁酸和葫芦巴内酯,使得它们相对于阳性对照总量分别为上表16所示的量,将所获得的拉面汤作为阳性对照。8 g of soup powder of commercially available instant ramen (manufactured by Sanyo Foods Co., Ltd., "Sapporo Ichiban Shoyu Aji") was dissolved in 500 mL of boiling hot water, and then 4-methylvaleric acid, 3-methylthiopropionaldehyde, butyric acid and fenugreek lactone were added respectively so that their amounts relative to the total amount of the positive control were shown in Table 16 above, and the obtained ramen soup was used as a positive control.

(朝鲜泡菜锅)(Kimchi Pot)

用6倍(重量)的热水稀释市售的锅物调味料(EBARA食品工业株式会社制造,“Kimchi Nabe no moto”),然后,分别添加4-甲基戊酸、3-甲硫基丙醛、丁酸和葫芦巴内酯,使得它们相对于阳性对照总量分别为上表17所示的量,将所获得的朝鲜泡菜锅汤作为阳性对照。A commercially available hot pot seasoning ("Kimchi Nabe no moto" manufactured by EBARA Food Industries, Ltd.) was diluted with 6 times (by weight) hot water, and then 4-methylvaleric acid, 3-methylthiopropionaldehyde, butyric acid and fenugreek lactone were added respectively so that their amounts relative to the total amount of the positive control were respectively as shown in Table 17 above, and the obtained kimchi hot pot soup was used as a positive control.

<评价样品的调制><Preparation of evaluation samples>

除了使用下表19记载的各有机酸代替4-甲基戊酸之外,通过与阳性对照相同的步骤,分别对于拉面和朝鲜泡菜锅,调制评价样品。Evaluation samples were prepared for ramen and kimchi stew respectively by the same procedure as the positive control except that the organic acids listed in Table 19 below were used instead of 4-methylvaleric acid.

对各评价样品的辛香感强度,实施感官评价。Sensory evaluation was performed on the spicy aroma intensity of each evaluation sample.

感官评价通过下述方法进行:2名专业评价员以非盲方式通过合议对各评价样品进行评分(以0.5分为增量),其中,将阴性对照设定为0分,将阳性对照设定为5分。The sensory evaluation was performed by the following method: 2 professional evaluators scored each evaluation sample by consensus in a non-blind manner (in increments of 0.5 points), wherein the negative control was set to 0 points and the positive control was set to 5 points.

结果示于下表19。The results are shown in Table 19 below.

[表19][Table 19]

已经确认:与4-甲基戊酸相同地,异丁酸、异缬草酸、5-甲基己酸、4-甲基辛酸、4-甲基壬酸通过与3-甲硫基丙醛、丁酸和葫芦巴内酯并用,可以更有效地增强含有辛香料的食品的辛香感。It has been confirmed that, similar to 4-methylvaleric acid, isobutyric acid, isovaleric acid, 5-methylhexanoic acid, 4-methyloctanoic acid, and 4-methylnonanoic acid can more effectively enhance the spicy flavor of spice-containing foods by using them in combination with 3-methylmercaptopropionaldehyde, butyric acid, and fenugreek lactone.

[工业上的可利用性][Industrial Applicability]

根据本发明,可以提供能够有效增强咸味、辛香感的新型咸味和/或辛香感增强剂。另外,本发明的咸味和/或辛香感增强剂除了可以增强咸味、辛香感之外,还可以增强畜肉风味、奶酪风味。According to the present invention, a novel salty taste and/or spicy flavor enhancer that can effectively enhance salty taste and spicy flavor can be provided. In addition, the salty taste and/or spicy flavor enhancer of the present invention can enhance the flavor of livestock meat and cheese in addition to enhancing the salty taste and spicy flavor.

此外,根据本发明,可以制造咸味得到有效增强的含有食盐的食品。本发明的制造方法可以制造除咸味得到增强之外畜肉风味、奶酪风味也得到增强的含有食盐的食品。此外,根据本发明,也可以制造辛香感得到有效增强的含有辛香料的食品。进一步地,根据本发明,可以制造咸味和辛香感得到增强的含有食盐和辛香料的盐的食品。In addition, according to the present invention, a food containing salt whose saltiness is effectively enhanced can be manufactured. The manufacturing method of the present invention can manufacture a food containing salt whose saltiness is enhanced and whose meat flavor and cheese flavor are also enhanced. In addition, according to the present invention, a food containing spices whose spiciness is effectively enhanced can be manufactured. Further, according to the present invention, a food containing salt containing salt and spices whose saltiness and spiciness are enhanced can be manufactured.

另外,根据本发明,可以有效增强含有食盐的食品的咸味。本发明的增强方法除了可以增强咸味之外,还可以增强畜肉风味、奶酪风味。另外,根据本发明,可以有效地增强含有辛香料的食品的辛香感。进一步地,根据本发明,可以有效增强含有食盐和辛香料的食品的咸味和辛香感。In addition, according to the present invention, the saltiness of foods containing salt can be effectively enhanced. In addition to enhancing the saltiness, the enhancement method of the present invention can also enhance the flavor of livestock and cheese. In addition, according to the present invention, the spiciness of foods containing spices can be effectively enhanced. Further, according to the present invention, the saltiness and spiciness of foods containing salt and spices can be effectively enhanced.

另外,不论含有食盐的食品、含有辛香料的食品、含有食盐和辛香料的食品的种类,本发明都可以增强各种各样的食品的咸味、辛香感。In addition, the present invention can enhance the saltiness and spiciness of various foods, regardless of the types of foods containing salt, foods containing spices, or foods containing salt and spices.

本申请以在日本提交的专利申请特愿2018-046784(申请日:2018年3月14日)为基础,其内容全部包含在本说明书中。This application is based on patent application No. 2018-046784 (filing date: March 14, 2018) filed in Japan, the contents of which are all incorporated herein by reference.

Claims (23)

1.一种含有食盐和/或辛香料的食品,其特征在于,含有咸味和/或辛香感增强剂,所述咸味和/或辛香感增强剂含有(A)碳原子数为4~18的分支饱和脂肪族一元羧酸或其盐、(B)3-甲硫基丙醛、(C)丁酸或其盐,并且含有或不含有(D)葫芦巴内酯,1. A food containing salt and/or spices, characterized in that it contains a salty taste and/or spicy flavor enhancer, and the salty taste and/or spicy flavor enhancer contains (A) with a carbon number of Branched saturated aliphatic monocarboxylic acid of 4 to 18 or its salt, (B) 3-methylthiopropionaldehyde, (C) butyric acid or its salt, and containing or not containing (D) trigonelolactone, (A)为选自2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸以及4-甲基壬酸中的至少一种化合物或其盐,(A) is selected from the group consisting of 2-methylpentanoic acid, 3-methylpentanoic acid, 4-methylpentanoic acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, and 4-methylpentanoic acid. At least one compound of methyloctanoic acid and 4-methylnonanoic acid or a salt thereof, (A)的添加量为0.005重量ppm以上、15重量ppm以下,The addition amount of (A) is 0.005 ppm by weight or more and 15 ppm by weight or less, (B)的添加量为0.01重量ppm以上、10重量ppm以下,The addition amount of (B) is 0.01 ppm by weight or more and 10 ppm by weight or less, (C)的添加量为0.1重量ppm以上、10重量ppm以下,The addition amount of (C) is 0.1 ppm by weight or more and 10 ppm by weight or less, (D)的添加量为0.005重量ppm以上、50重量ppm以下。The addition amount of (D) is 0.005 ppm by weight or more and 50 ppm by weight or less. 2.根据权利要求1所述的含有食盐和/或辛香料的食品,其中,(A)为4-甲基戊酸或其盐。2. The food containing salt and/or spices according to claim 1, wherein (A) is 4-methylpentanoic acid or a salt thereof. 3.根据权利要求1所述的含有食盐和/或辛香料的食品,其中,所述含有食盐和/或辛香料的食品中的(A)的含量a1和(B)的含量b1的重量比为a1:b1=1:0.01~50。3. The food containing salt and/or spices according to claim 1, wherein the content of (A) in the food containing salt and/or spices is a 1 and the content b 1 of (B) The weight ratio is a 1 : b 1 =1:0.01~50. 4.根据权利要求1所述的含有食盐和/或辛香料的食品剂,其中,所述含有食盐和/或辛香料的食品中的(A)的含量a1和(C)的含量c1的重量比为a1:c1=1:0.1~500。4. The food preparation containing salt and/or spices according to claim 1, wherein the content of (A) in the food containing salt and/or spices is a 1 and the content c 1 of (C) The weight ratio is a 1 :c 1 =1:0.1~500. 5.根据权利要求1所述的含有食盐和/或辛香料的食品,其中,所述含有食盐和/或辛香料的食品中的(A)的含量a1和(D)的含量d1的重量比为a1:d1=1:0.01~50。5. The food containing salt and/or spices according to claim 1, wherein the content a1 of (A) and the content d1 of (D) in the food containing salt and/or spices are The weight ratio is a 1 : d 1 =1:0.01~50. 6.根据权利要求1所述的含有食盐和/或辛香料的食品,其中,所述含有食盐和/或辛香料的食品含有(B)、(C)和(D)。6. The food containing salt and/or spices according to claim 1, wherein the food containing salt and/or spices contains (B), (C) and (D). 7.根据权利要求1~6中任一项所述的含有食盐和/或辛香料的食品,其中,所述含有食盐和/或辛香料的食品还增强选自畜肉风味和奶酪风味中的至少一种。7. The food containing salt and/or spices according to any one of claims 1 to 6, wherein the food containing salt and/or spices further enhances at least one selected from the group consisting of meat flavor and cheese flavor. A sort of. 8.一种含有食盐和/或辛香料的食品的制造方法,其特征在于,包括:添加咸味和/或辛香感增强剂,所述咸味和/或辛香感增强剂含有(A)碳原子数为4~18的分支饱和脂肪族一元羧酸或其盐、(B)3-甲硫基丙醛、(C)丁酸或其盐,并且含有或不含有(D)葫芦巴内酯,8. A method for manufacturing food containing salt and/or spices, characterized by comprising: adding a salty and/or spicy flavor enhancer, the salty and/or spicy flavor enhancer containing (A ) Branched saturated aliphatic monocarboxylic acid with 4 to 18 carbon atoms or its salt, (B) 3-methylthiopropionaldehyde, (C) butyric acid or its salt, and containing or not containing (D) Fenugreek lactone, (A)为选自2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸以及4-甲基壬酸中的至少一种化合物或其盐,(A) is selected from the group consisting of 2-methylpentanoic acid, 3-methylpentanoic acid, 4-methylpentanoic acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, and 4-methylpentanoic acid. At least one compound of methyloctanoic acid and 4-methylnonanoic acid or a salt thereof, (A)的添加量为0.005重量ppm以上、15重量ppm以下,The addition amount of (A) is 0.005 ppm by weight or more and 15 ppm by weight or less, (B)的添加量为0.01重量ppm以上、10重量ppm以下,The addition amount of (B) is 0.01 ppm by weight or more and 10 ppm by weight or less, (C)的添加量为0.1重量ppm以上、10重量ppm以下,The addition amount of (C) is 0.1 ppm by weight or more and 10 ppm by weight or less, (D)的添加量为0.005重量ppm以上、50重量ppm以下。The addition amount of (D) is 0.005 ppm by weight or more and 50 ppm by weight or less. 9.根据权利要求8所述的制造方法,其中,(A)为4-甲基戊酸或其盐。9. The production method according to claim 8, wherein (A) is 4-methylpentanoic acid or a salt thereof. 10.根据权利要求8所述的制造方法,其中,(A)的添加量a2和(B)的添加量b2的重量比为a2:b2=1:0.01~50。10. The manufacturing method according to claim 8, wherein the weight ratio of the added amount a2 of (A) and the added amount b2 of (B) is a2 : b2 =1:0.01-50. 11.根据权利要求8所述的制造方法,其中,(A)的添加量a2和(C)的添加量c2的重量比为a2:c2=1:0.1~500。11. The manufacturing method according to claim 8, wherein the weight ratio of the added amount a2 of (A) and the added amount c2 of (C) is a2 : c2 =1:0.1-500. 12.根据权利要求8所述的制造方法,其中,(A)的添加量a2和(D)的添加量d2的重量比为a2:d2=1:0.01~50。12. The manufacturing method according to claim 8, wherein the weight ratio of the added amount a2 of (A) and the added amount d2 of (D) is a2 : d2 =1:0.01-50. 13.根据权利要求8所述的制造方法,其中,所述含有食盐和/或辛香料的食品为咸味和/或辛香感得到增强的食品。13. The manufacturing method according to claim 8, wherein the food containing salt and/or spices is a food with enhanced saltiness and/or spicy feeling. 14.根据权利要求13所述的制造方法,其中,所述含有食盐和/或辛香料的食品为选自畜肉风味和奶酪风味中的至少一种也得到增强的食品。The manufacturing method according to claim 13, wherein the food containing salt and/or spices is a food in which at least one selected from the group consisting of meat flavor and cheese flavor is also enhanced. 15.根据权利要求8~14中任一项所述的制造方法,其中,所述制造方法为含有食盐的食品的制造方法。The manufacturing method according to any one of claims 8 to 14, which is a manufacturing method of food containing salt. 16.一种含有食盐的食品的咸味增强方法,其特征在于,包括:添加(A)碳原子数为4~18的分支饱和脂肪族一元羧酸或其盐、(B)3-甲硫基丙醛、(C)丁酸或其盐,以及添加或不添加(D)葫芦巴内酯,16. A method for enhancing the saltiness of food containing salt, which includes: adding (A) a branched saturated aliphatic monocarboxylic acid with 4 to 18 carbon atoms or a salt thereof, (B) 3-methylsulfide propionaldehyde, (C) butyric acid or its salt, with or without the addition of (D) trigonelolactone, (A)为选自2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸以及4-甲基壬酸中的至少一种化合物或其盐,(A) is selected from the group consisting of 2-methylpentanoic acid, 3-methylpentanoic acid, 4-methylpentanoic acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, and 4-methylpentanoic acid. At least one compound of methyloctanoic acid and 4-methylnonanoic acid or a salt thereof, (A)的添加量为0.005重量ppm以上、15重量ppm以下,The addition amount of (A) is 0.005 ppm by weight or more and 15 ppm by weight or less, (B)的添加量为0.01重量ppm以上、10重量ppm以下,The addition amount of (B) is 0.01 ppm by weight or more and 10 ppm by weight or less, (C)的添加量为0.1重量ppm以上、10重量ppm以下,The addition amount of (C) is 0.1 ppm by weight or more and 10 ppm by weight or less, (D)的添加量为0.005重量ppm以上、50重量ppm以下。The addition amount of (D) is 0.005 ppm by weight or more and 50 ppm by weight or less. 17.一种含有辛香料的食品的辛香感增强方法,其特征在于,包括:添加(A)碳原子数为4~18的分支饱和脂肪族一元羧酸或其盐、(B)3-甲硫基丙醛、(C)丁酸或其盐,以及添加或不添加(D)葫芦巴内酯,17. A method for enhancing the spiciness of foods containing spices, which includes: adding (A) a branched saturated aliphatic monocarboxylic acid with 4 to 18 carbon atoms or a salt thereof, (B) 3- Methylthiopropionaldehyde, (C) butyric acid or its salt, with or without the addition of (D) trigonelolactone, (A)为选自2-甲基戊酸、3-甲基戊酸、4-甲基戊酸、2-甲基己酸、5-甲基己酸、2-甲基庚酸、4-甲基辛酸以及4-甲基壬酸中的至少一种化合物或其盐,(A) is selected from the group consisting of 2-methylpentanoic acid, 3-methylpentanoic acid, 4-methylpentanoic acid, 2-methylhexanoic acid, 5-methylhexanoic acid, 2-methylheptanoic acid, and 4-methylpentanoic acid. At least one compound of methyloctanoic acid and 4-methylnonanoic acid or a salt thereof, (A)的添加量为0.005重量ppm以上、15重量ppm以下,The addition amount of (A) is 0.005 ppm by weight or more and 15 ppm by weight or less, (B)的添加量为0.01重量ppm以上、10重量ppm以下,The addition amount of (B) is 0.01 ppm by weight or more and 10 ppm by weight or less, (C)的添加量为0.1重量ppm以上、10重量ppm以下,The addition amount of (C) is 0.1 ppm by weight or more and 10 ppm by weight or less, (D)的添加量为0.005重量ppm以上、50重量ppm以下。The addition amount of (D) is 0.005 ppm by weight or more and 50 ppm by weight or less. 18.根据权利要求16或17所述的增强方法,其中,(A)为4-甲基戊酸或其盐。18. The enhancement method according to claim 16 or 17, wherein (A) is 4-methylpentanoic acid or a salt thereof. 19.根据权利要求16或17所述的增强方法,其中,(A)的添加量a3和(B)的添加量b3的重量比为a3:b3=1:0.01~50。19. The reinforcement method according to claim 16 or 17, wherein the weight ratio of the added amount a3 of (A) and the added amount b3 of (B) is a3 : b3 =1:0.01-50. 20.根据权利要求16或17所述的增强方法,其中,(A)的添加量a3和(C)的添加量c3的重量比为a3:c3=1:0.1~500。20. The reinforcement method according to claim 16 or 17, wherein the weight ratio of the added amount a3 of (A) and the added amount c3 of (C) is a3 : c3 =1:0.1-500. 21.根据权利要求16或17所述的增强方法,其中,(A)的添加量a3和(D)的添加量d3的重量比为a3:d3=1:0.01~50。21. The reinforcement method according to claim 16 or 17, wherein the weight ratio of the added amount a3 of (A) and the added amount d3 of (D) is a3 : d3 =1:0.01-50. 22.根据权利要求16或17所述的增强方法,其中,在所述含有食盐的食品或所述含有辛香料的食品中添加(B)、(C)和(D)。22. The enhancement method according to claim 16 or 17, wherein (B), (C) and (D) are added to the salt-containing food or the spice-containing food. 23.根据权利要求16或17所述的增强方法,其中,所述增强方法还增强选自畜肉风味和奶酪风味中的至少一种。23. The enhancement method according to claim 16 or 17, wherein the enhancement method further enhances at least one selected from the group consisting of meat flavor and cheese flavor.
CN201980019198.9A 2018-03-14 2019-03-13 Salty and/or spicy taste enhancer Active CN111867396B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2018046784 2018-03-14
JP2018-046784 2018-03-14
PCT/JP2019/010210 WO2019177003A1 (en) 2018-03-14 2019-03-13 Salty taste- and/or spicy taste-enhancing agent

Publications (2)

Publication Number Publication Date
CN111867396A CN111867396A (en) 2020-10-30
CN111867396B true CN111867396B (en) 2024-01-19

Family

ID=67907202

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980019198.9A Active CN111867396B (en) 2018-03-14 2019-03-13 Salty and/or spicy taste enhancer

Country Status (3)

Country Link
JP (1) JP7306374B2 (en)
CN (1) CN111867396B (en)
WO (1) WO2019177003A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230345982A1 (en) * 2020-08-19 2023-11-02 Kikkoman Corporation Seasoning From Malted Rice Used as Raw Material
WO2023276675A1 (en) * 2021-06-28 2023-01-05 株式会社J-オイルミルズ Spice flavor enhancer and method for enhancing spice flavor of foodstuff
JPWO2023112761A1 (en) * 2021-12-13 2023-06-22
WO2023190557A1 (en) * 2022-03-28 2023-10-05 味の素株式会社 Salty taste enhancer
EP4492988A1 (en) * 2022-05-16 2025-01-22 Firmenich Incorporated Saturated fatty acids and their use to modify taste
EP4613108A1 (en) * 2022-11-04 2025-09-10 Ajinomoto Co., Inc. Sweetness and/or flavor enhancer
CN118902045A (en) * 2024-08-09 2024-11-08 上海应用技术大学 Salt-reducing and salt-increasing mixture
JP7727817B1 (en) * 2024-11-27 2025-08-21 株式会社ニッスイ Taste-improving composition, taste-improving seasoning, and method for improving the taste of food and drink

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05184326A (en) * 1992-01-09 1993-07-27 T Hasegawa Co Ltd Method for enhancing salty taste of drink or food containing salt
US5695802A (en) * 1994-06-16 1997-12-09 Firmenich Sa Flavoring composition and process
JP2003079336A (en) * 2001-09-10 2003-03-18 Ajinomoto Co Inc Flavor raw material matter and beverage and food containing the same
JP2010166886A (en) * 2009-01-26 2010-08-05 Tablemark Co Ltd Method for improving aroma of food product
JP2012223147A (en) * 2011-04-21 2012-11-15 Ogawa & Co Ltd Salty taste enhancer
WO2013172049A1 (en) * 2012-05-17 2013-11-21 国立大学法人九州大学 Taste enhancing agent
JP2017158543A (en) * 2016-03-04 2017-09-14 味の素株式会社 Saltiness enhancing composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0811372A2 (en) * 2007-06-07 2014-09-30 Unilever Nv "READY-TO-EAT FOOD USE, METHOD AND COMPOSITION"
JP5678281B2 (en) * 2012-07-19 2015-02-25 キッコーマン株式会社 Liquid seasoning with enhanced umami taste of glutamic acid

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05184326A (en) * 1992-01-09 1993-07-27 T Hasegawa Co Ltd Method for enhancing salty taste of drink or food containing salt
US5695802A (en) * 1994-06-16 1997-12-09 Firmenich Sa Flavoring composition and process
JP2003079336A (en) * 2001-09-10 2003-03-18 Ajinomoto Co Inc Flavor raw material matter and beverage and food containing the same
JP2010166886A (en) * 2009-01-26 2010-08-05 Tablemark Co Ltd Method for improving aroma of food product
JP2012223147A (en) * 2011-04-21 2012-11-15 Ogawa & Co Ltd Salty taste enhancer
WO2013172049A1 (en) * 2012-05-17 2013-11-21 国立大学法人九州大学 Taste enhancing agent
JP2017158543A (en) * 2016-03-04 2017-09-14 味の素株式会社 Saltiness enhancing composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
贾益群等.4-甲基戊酸.《食品添加剂及药剂辅料质谱与红外光谱鉴定》.吉林大学出版社,2007, *

Also Published As

Publication number Publication date
CN111867396A (en) 2020-10-30
JP7306374B2 (en) 2023-07-11
WO2019177003A1 (en) 2019-09-19
JPWO2019177003A1 (en) 2021-02-25

Similar Documents

Publication Publication Date Title
CN111867396B (en) Salty and/or spicy taste enhancer
JP5954176B2 (en) Aroma / flavoring composition
JP6414051B2 (en) Flavor-imparting composition, food and drink with a stewed dish-like flavor, and a method for producing the same
JP7031120B2 (en) Composition for imparting richness
WO2016175323A1 (en) Flavoring composition
JP6907607B2 (en) Fleshy aroma enhancer
TWI576049B (en) A composition for producing aroma and / or flavor, a food and a food product, and a method for producing the same
JP7729044B2 (en) Methods for suppressing off-flavors in foods
JP2002142715A (en) Soy sauce or soy saucelike fermented seasoning having improved taste flavor and food using the same
JP7363481B2 (en) flavor composition
JP2013078284A (en) Salty taste enhancement method by salty taste enhancer and salt reducing method for salt-containing food and drink
WO2022085750A1 (en) Method for enhancing saltiness of food
WO2023190557A1 (en) Salty taste enhancer
JP2019170188A (en) Salty taste enhancing composition
JP5867661B1 (en) Fragrance composition
JP6429643B2 (en) Umami enhancer containing methional and lower fatty acid ester
WO2017170196A1 (en) Cooked sensation imparting agent
JP4338907B2 (en) Fish soy using deep ocean water and its manufacturing method
WO2024158013A1 (en) Salty taste/umami enhancer
WO2025070565A1 (en) Method for improving eating quality of food
JP2023135861A (en) Salty taste enhancement composition
JP2011125315A (en) Body taste enhancer
JP6051148B2 (en) Low salt seasoning
JP2017184732A (en) Composition having body taste-imparting function
JP2019041726A (en) Bitterness and/or harsh taste inhibitor

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant