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CN1117046C - Quantity-contorllable multifunctional gas fertilizer of solid CO2 and its preparing process - Google Patents

Quantity-contorllable multifunctional gas fertilizer of solid CO2 and its preparing process Download PDF

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Publication number
CN1117046C
CN1117046C CN 00110944 CN00110944A CN1117046C CN 1117046 C CN1117046 C CN 1117046C CN 00110944 CN00110944 CN 00110944 CN 00110944 A CN00110944 A CN 00110944A CN 1117046 C CN1117046 C CN 1117046C
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CN
China
Prior art keywords
parts
solid
gas fertilizer
fertilizer
calcium oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 00110944
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Chinese (zh)
Other versions
CN1266830A (en
Inventor
刘兆辉
聂燕
江丽华
张玉兰
王月明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Soil and Fertilizer Institute of Shandong Academy of Agricultural Sciences
Original Assignee
Soil and Fertilizer Institute of Shandong Academy of Agricultural Sciences
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Soil and Fertilizer Institute of Shandong Academy of Agricultural Sciences filed Critical Soil and Fertilizer Institute of Shandong Academy of Agricultural Sciences
Priority to CN 00110944 priority Critical patent/CN1117046C/en
Publication of CN1266830A publication Critical patent/CN1266830A/en
Application granted granted Critical
Publication of CN1117046C publication Critical patent/CN1117046C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D7/00Fertilisers producing carbon dioxide

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The present invention relates to a solid fertilizer generating carbon dioxide and a preparation method thereof. The solid fertilizer comprises 30 to 60 portions of light calcium carbonate or magnesium carbonate, 0 to 15 portions of elemental sulfur, 5 to 35 portions of monoammonium phosphate, 0 to 15 portions of potassium chloride or/and potassium sulfate, 1 to 50 portions of ammonium sulfate or ammonium sulfonate, 0 to 10 portions of calcium oxide carrier and 0 to 10 portions of binding agent. The present invention has the advantages of simple preparation, easy and safe transportation and use and one fertilizer with multiple functions, the solid fertilizer provides carbon dioxide, simultaneously, the gas generating residues are potassium and a middle quantity of element fertilizers, the solid fertilizer is suitable for the requirements of different growth periods of crops, and the gas quantity of the required carbon dioxide can be controlled.

Description

Quantity-contorllable multifunctional gas fertilizer of solid CO 2 and preparation method thereof
The present invention relates to a kind of solid state gas fertilizer, be specifically related to a kind of fertilizer that produces carbonic acid gas and preparation method thereof.
Carbonic acid gas is the necessary basic substance of plant photosynthesis; concentration of carbon dioxide does not satisfy the needs of vegetables normal growth far away in the protection ground; gas concentration lwevel is low to moderate 50ppm sometimes in the canopy; in the big time of photosynthetic rate; the morning 9 is up at 5 o'clock in afternoon; gas concentration lwevel is too low, can not satisfy photosynthetic requirement.Enrich carbonic acid gas vegetable crop is obviously increased, studies show that, when carbonic acid gas is increased to about 1000ppm, vegetable crop can increase by 30~100%, has very high product and throws ratio.Enriching carbonic acid gas not only can increase output and can improve the quality of vegetables, improves the visual appearance and the interior quality of product; Enrich the resistance that carbonic acid gas can improve vegetables, increase its ability pest-resistant, disease-resistant and anti-other adverse circumstance; Enrich carbonic acid gas and can make the vegetables precocity, in advance listing.
At present, using the normal method that adopts of carbonic acid gas mainly contains:
1. venting method
Venting method has two kinds: natural ventilation and enhancing ventilation.Natural ventilation is to stay ventage with protecting, and air is entered automatically, flows mutually with air, strengthens ventilation and adopts gas blower or ventilation to fan, and strengthens ventilation intensity, and effect is better than natural ventilation.
2. steel cylinder and dry ice method
The steel cylinder that fills Liquid carbon dioxide is placed in the canopy, and carbonic acid gas is slowly emitted.Using dry ice (solidified carbon dioxide) in the canopy, also is the effective ways that increase carbonic acid gas.The effect of these two kinds of methods is fine, but cost is higher, uses also inconvenient.
3. combustion method
Combustion method is divided two big classes: method for releasing and indirect method for releasing directly burn.Directly the high-grade kerosene of burning, paraffin etc. can provide carbonic acid gas, and indirect method is canopy exterior point honeycomb briquette stove such as patent CN1209425A, puts into canopy behind the treated elimination obnoxious flavour of gas, the cumbersome inconvenient operation of this method.
4. bicarbonate of ammonia and dilute sulphuric acid reaction method
Dilute sulphuric acid is put into acid-resistant container add excessive bicarbonate of ammonia, great amount of carbon dioxide is emitted in reaction, as patent CN2143228A, CN2109071A.These method raw material sources are convenient, and venting is direct, but inconvenient operation, vitriol oil transportation inconvenience has certain danger.
5. solid gas fertilizer law
Different materials is made solid particulate to be applied in the soil or can to emit carbon dioxide in the container, as patent CN1115748A, CN1125707A, in patent, adopted the common granulation of solid acid and carbon compound, preparation particle CO 2 gas fertilizer, but its manufacturing cost is high or use inconvenience, does not reach a fertile multiple-effect or same fertilizer efficiency different administration method different dosage form.
The object of the present invention is to provide a kind of easy to use, a fertile multi-purpose gas fertilizer of solid CO 2.
Another object of the present invention provides a kind of gas fertilizer of solid CO 2 preparation method simple to operation.
The objective of the invention is to be achieved through the following technical solutions.
Gas fertilizer of solid CO 2 of the present invention is composed as follows, be weight part, down with: 5~35 parts of Repone K of 0~15 part of monoammonium phosphate of 30~60 parts of elemental sulfurs of light calcium carbonate or magnesiumcarbonate or/and 0~15 part of ammonium sulfate of vitriolate of tartar or/and 0~10 part of above-mentioned binding agent of 0~10 part of binding agent of 1~50 part of calcium oxide of thionamic acid is selected from colorless and odorless mineral oil, animal grease or Vegetable oil lipoprotein.Above-mentioned Vegetable oil lipoprotein is selected from peanut, soybean, rapeseed oil, Oleum Gossypii semen, tea oil.Above-mentioned mineral oil is good with alkane machine oil.The component of above-mentioned phosgene gaseous fertilizer is preferably as follows technical scheme: 1. light calcium carbonate or magnesiumcarbonate are 40~50 parts
8~10 parts of elemental sulfurs
20~25 parts of monoammonium phosphates
4~6 parts in Repone K
2~6 parts of vitriolate of tartar
2~5 parts in ammonium sulfate
2~5 parts in calcium oxide
Use before 2~5 parts of these preferred versions of binding agent are applicable to the arable land, belong to base and execute type fertilizer.2. light calcium carbonate or magnesiumcarbonate are 40~50 parts
4~6 parts of elemental sulfurs
20~33 parts of monoammonium phosphates
4~6 parts of vitriolate of tartar
5~20 parts of thionamic acids
2~5 parts in calcium oxide
2~5 parts of these preferred versions of binding agent are applicable to when crop is topdressed to be used, and belongs to impose type fertilizer.3. light calcium carbonate or magnesiumcarbonate are 40~50 parts
24~26 parts of monoammonium phosphates
24~28 parts of thionamic acids
2~5 parts in calcium oxide
2~5 parts of these preferred versions of binding agent belong to top application type fertilizer, are applicable to the plant growth busy season or the best fruiting period.4. light calcium carbonate or magnesiumcarbonate are 40~50 parts
5~7 parts of monoammonium phosphates
4~6 parts of vitriolate of tartar
40~50 parts of thionamic acids
0~2 part in calcium oxide
0~2 part of additive
This preferred version need add water when using, and amount of water is done calculation by required carbon dioxide releasing amount and got final product.Be applicable to the plant growth busy season or the best fruiting period.
Preparation method of the present invention comprises the steps:
1. each component is got in weighing according to the above ratio, mixes;
2. with pair roller type or the granulation of muller formula tablets press;
3. metering pack sealing.
The present invention prepares simply, transports easy to use, safe; The present invention is when providing carbonic acid gas, and the aerogenesis residuum is nitrogen phosphorus potassium and secondary nutrients, and one is fertile multi-functional; Product of the present invention is applicable to the needs in the vegetative period that crop is different, and required carbonic acid gas tolerance can be controlled.
Principle of the present invention is: crop at different growth phases to carbon dioxide demand difference to some extent, to nutrient demand difference to some extent.Adopt light calcium carbonate or magnesiumcarbonate when making CO 2 gas fertilizer, it produces carbon dioxide under sour environment, acidic substance are provided by monoammonium phosphate, ammonium sulfate, elemental sulfur or dithiocarbamic acid, be equipped with an amount of potassium simultaneously, produce carbonic acid gas release rate difference, the different multi-functional CO 2 gas fertilizer of crop nutrition content content by extruder grain.Use the slowest base of carbonic acid gas release rate and execute type before the arable land, it is in slow carbon dioxide gas of whole season of plant growth, and offers an amount of nitrogen phosphorus potassium of crop and middle trace element; Use imposes type in the plant growth busy season, and its carbonic acid gas release rate is medium, contains required reasonably combined nutrient of plant growth busy season in the fertilizer; Adopt top application type or container to add the water releasing type carbon dioxide gaseous fertilizer in the plant growth busy season or the best fruiting period, add gauge water and emit quantitative carbon dioxide, residuum is nitrogen phosphorus potassium and secondary nutrients behind the aerogenesis.
The invention will be further described below in conjunction with embodiment.
Embodiment 1. bases are executed type fertilizer
40 parts of light calcium carbonates
8 parts of elemental sulfurs
20 parts of monoammonium phosphates
4 parts in Repone K
2 parts of vitriolate of tartar
2 parts in ammonium sulfate
2 parts in calcium oxide
2 parts of Oleum Gossypii semen binding agents
The preparation method comprises the steps: that each component is got in weighing according to the above ratio, mixes; With pair roller type or the granulation of muller formula tablets press; Metering pack sealing.
Embodiment 2. bases are executed type fertilizer
50 parts of light calcium carbonates
10 parts of elemental sulfurs
25 parts of monoammonium phosphates
6 parts in Repone K
6 parts of vitriolate of tartar
5 parts in ammonium sulfate
4 parts in calcium oxide
4 parts of peanut oil binding agents.
Embodiment 3. bases are executed type fertilizer
45 parts in magnesiumcarbonate
9 parts of elemental sulfurs
23 parts of monoammonium phosphates
5 parts in Repone K
5 parts of vitriolate of tartar
4 parts in ammonium sulfate
3 parts in calcium oxide
3 parts of machine oil binding agents.
Embodiment 4. imposes type fertilizer
46 parts of light calcium carbonates
5 parts of elemental sulfurs
20 parts of monoammonium phosphates
5 parts of vitriolate of tartar
18 parts of thionamic acids
3 parts in calcium oxide
4 parts of machine oil binding agents.
Embodiment 5. imposes type fertilizer
40 parts in magnesiumcarbonate
4 parts of elemental sulfurs
22 parts of monoammonium phosphates
4 parts of vitriolate of tartar
13 parts of thionamic acids
3 parts in calcium oxide
3 parts of soybean oil binding agents.
Embodiment 6. imposes type fertilizer
50 parts of light calcium carbonates
6 parts of elemental sulfurs
32 parts of monoammonium phosphates
6 parts of vitriolate of tartar
10 parts of thionamic acids
3 parts in calcium oxide
5 parts of animal oil binding agents.
Embodiment 7. top application type fertilizer
47 parts of light calcium carbonates
25 parts of monoammonium phosphates
26 parts of thionamic acids
4 parts in calcium oxide
4 parts of machine oil binding agents.
Embodiment 8. top application type fertilizer
42 parts of light calcium carbonates
25 parts of monoammonium phosphates
24 parts of thionamic acids
2 parts of tea oil binding agents.
Embodiment 9. top application type fertilizer
50 parts of light calcium carbonates
26 parts of monoammonium phosphates
28 parts of thionamic acids
3 parts in calcium oxide
5 parts of rapeseed oil binding agents.
Embodiment 10. adds water releasing type
45 parts in magnesiumcarbonate
6 parts of monoammonium phosphates
5 parts of vitriolate of tartar
45 parts of thionamic acids.
Embodiment 11. adds water releasing type
40 parts of light calcium carbonates
5 parts of monoammonium phosphates
4 parts of vitriolate of tartar
40 parts of thionamic acids
1 part in calcium oxide
1 part of machine oil caking agent.
Embodiment 12. adds water releasing type
50 parts of light calcium carbonates
7 parts of monoammonium phosphates
6 parts of vitriolate of tartar
50 parts of thionamic acids.

Claims (9)

1. a gas fertilizer of solid CO 2 is characterized in that, the each component weight part is as follows:
30~60 parts in light calcium carbonate or magnesiumcarbonate
0~15 part of elemental sulfur
5~35 parts of monoammonium phosphates
Repone K is or/and 0~15 part of vitriolate of tartar
Ammonium sulfate is or/and 1~50 part of thionamic acid
0~10 part in calcium oxide carrier
0~10 part of binding agent.
2. gas fertilizer of solid CO 2 according to claim 1 is characterized in that described binding agent is selected from colorless and odorless mineral oil, animal grease or Vegetable oil lipoprotein.
3. gas fertilizer of solid CO 2 as claimed in claim 1 or 2 is characterized in that described Vegetable oil lipoprotein is selected from peanut, soybean, rapeseed oil, Oleum Gossypii semen, tea oil.
4. gas fertilizer of solid CO 2 as claimed in claim 1 or 2 is characterized in that described mineral oil is alkane machine oil.
5. gas fertilizer of solid CO 2 as claimed in claim 1 or 2 is characterized in that described each component weight part is as follows:
40~50 parts in light calcium carbonate or magnesiumcarbonate
8~10 parts of elemental sulfurs
20~25 parts of monoammonium phosphates
4~6 parts in Repone K
2~6 parts of vitriolate of tartar
2~5 parts in ammonium sulfate
2~5 parts in calcium oxide
2~5 parts of binding agents.
6. gas fertilizer of solid CO 2 as claimed in claim 1 or 2 is characterized in that described each component weight part is as follows:
40~50 parts in light calcium carbonate or magnesiumcarbonate
4~6 parts of elemental sulfurs
20~33 parts of monoammonium phosphates
4~6 parts of vitriolate of tartar
5~20 parts of thionamic acids
2~5 parts in calcium oxide
2~5 parts of binding agents.
7. gas fertilizer of solid CO 2 as claimed in claim 1 or 2 is characterized in that described each component weight part is as follows:
40~50 parts of light calcium carbonates
24~26 parts of monoammonium phosphates
24~28 parts of thionamic acids
2~5 parts in calcium oxide
2~5 parts of binding agents.
8. gas fertilizer of solid CO 2 as claimed in claim 1 or 2 is characterized in that described each component weight part is as follows:
40~50 parts in light calcium carbonate or magnesiumcarbonate
5~7 parts of monoammonium phosphates
4~6 parts of vitriolate of tartar
40~50 parts of thionamic acids
0~2 part in calcium oxide
0~2 part of binding agent.
9. the preparation method of the described gas fertilizer of solid CO 2 of claim 1 comprises the steps:
(1) each component is got in weighing in proportion, mixes;
(2) with pair roller type or the granulation of muller formula tablets press;
(3) metering pack sealing.
CN 00110944 2000-03-14 2000-03-14 Quantity-contorllable multifunctional gas fertilizer of solid CO2 and its preparing process Expired - Fee Related CN1117046C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 00110944 CN1117046C (en) 2000-03-14 2000-03-14 Quantity-contorllable multifunctional gas fertilizer of solid CO2 and its preparing process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 00110944 CN1117046C (en) 2000-03-14 2000-03-14 Quantity-contorllable multifunctional gas fertilizer of solid CO2 and its preparing process

Publications (2)

Publication Number Publication Date
CN1266830A CN1266830A (en) 2000-09-20
CN1117046C true CN1117046C (en) 2003-08-06

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100412035C (en) * 2006-02-22 2008-08-20 王维超 Granular carbon dioxide and its preparation method

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2379270C2 (en) * 2005-12-16 2010-01-20 Александр Васильевич Вальков Method for production of complex fertiliser
BRPI1007177B1 (en) * 2009-01-29 2020-10-13 Shell Internationale Research Maatschappij B.V. process for manufacturing sulfur-containing fertilizer compositions, and sulfur-containing fertilizer composition
JP6584524B2 (en) * 2015-11-27 2019-10-02 三菱電機株式会社 Water heater
CN105503281B (en) * 2015-12-31 2019-06-11 张建民 A kind of carbon dioxide solid fertilizer and its preparation, application method
CN109251091A (en) * 2018-10-22 2019-01-22 北京蓉坤农业科技有限公司 A kind of auxotype granulated silica carbon generating agent and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100412035C (en) * 2006-02-22 2008-08-20 王维超 Granular carbon dioxide and its preparation method

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