CN111662658A - Environment-friendly adhesive for carton printing and preparation method thereof - Google Patents
Environment-friendly adhesive for carton printing and preparation method thereof Download PDFInfo
- Publication number
- CN111662658A CN111662658A CN202010659645.1A CN202010659645A CN111662658A CN 111662658 A CN111662658 A CN 111662658A CN 202010659645 A CN202010659645 A CN 202010659645A CN 111662658 A CN111662658 A CN 111662658A
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- carton printing
- friendly adhesive
- adhesive
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- 239000000853 adhesive Substances 0.000 title claims abstract description 33
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920002472 Starch Polymers 0.000 claims abstract description 18
- 229920003180 amino resin Polymers 0.000 claims abstract description 18
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 18
- 239000000440 bentonite Substances 0.000 claims abstract description 18
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 18
- 125000002091 cationic group Chemical group 0.000 claims abstract description 18
- 229920000642 polymer Polymers 0.000 claims abstract description 18
- 235000019698 starch Nutrition 0.000 claims abstract description 18
- 239000008107 starch Substances 0.000 claims abstract description 18
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 13
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 13
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 13
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 claims abstract description 13
- 229920002545 silicone oil Polymers 0.000 claims abstract description 13
- 229940103272 aluminum potassium sulfate Drugs 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 18
- 238000000227 grinding Methods 0.000 claims description 15
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- NJYZCEFQAIUHSD-UHFFFAOYSA-N acetoguanamine Chemical compound CC1=NC(N)=NC(N)=N1 NJYZCEFQAIUHSD-UHFFFAOYSA-N 0.000 claims description 5
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000007859 condensation product Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 5
- VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 230000002940 repellent Effects 0.000 claims description 4
- 239000005871 repellent Substances 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 230000005674 electromagnetic induction Effects 0.000 abstract description 3
- 238000007712 rapid solidification Methods 0.000 abstract 1
- 239000011087 paperboard Substances 0.000 description 8
- 239000000123 paper Substances 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 3
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to the technical field of adhesives, in particular to an environment-friendly adhesive for carton printing, which comprises the following raw materials in parts by weight: 50-65 parts of polyethylene glycol, 20-30 parts of aluminum potassium sulfate, 15-20 parts of emulsified silicone oil, 5-10 parts of amino resin, 10-15 parts of cationic non-starch polymer, 150 parts of 30% polyvinyl acetate emulsion, 200 parts of water, 5-15 parts of a waterproof agent, 10-20 parts of a tackifier and 20-26 parts of aluminum oxide-loaded bentonite. The invention can be rapidly melted when being heated at lower temperature, keeps smaller viscosity change in a wider temperature range, has higher melt strength and rapid solidification when being separated from a fixing roller, can be widely used for various carton printing, can fully meet the requirements of electromagnetic induction heating equipment for high speed, low temperature fixing and the like which are improved in recent years, has market prospect and is suitable for popularization.
Description
Technical Field
The invention relates to the technical field of adhesives, in particular to an environment-friendly adhesive for carton printing and a preparation method thereof.
Background
The paperboard is also called paperboard. The thick paper sheet is made up by using various paper pulps and making them be mutually interwoven. Paperboard is generally distinguished from paper by basis weight and caliper, and paper having a basis weight of greater than 250g/m2 and a caliper of greater than 0.5mm is generally referred to as paperboard (alternatively: paper having a caliper of greater than 0.1mm is generally referred to as paperboard; paper having a basis weight of less than 250g/m2 is generally referred to as paper, and paperboard having a basis weight of 250g/m2 or greater is referred to as paperboard). Before leaving a factory, a paperboard is usually printed, in order to be considered as environmental protection, water-based ink is used, but the water-based ink has a problem that the binding force between the ink and the paper is poor, decoloring is easy to generate, and a printing adhesive needs to be added, but the existing printing adhesive has poor environmental protection performance and poor low-temperature fixing property, so an environment-friendly carton printing adhesive and a preparation method thereof are provided for solving the problem.
Disclosure of Invention
The invention aims to solve the defects of poor environmental protection performance and poor low-temperature fixing performance of the existing printing adhesive in the prior art, and provides an environment-friendly adhesive for carton printing and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
an environment-friendly adhesive for carton printing is designed, and comprises the following raw materials in parts by weight: 50-65 parts of polyethylene glycol, 20-30 parts of aluminum potassium sulfate, 15-20 parts of emulsified silicone oil, 5-10 parts of amino resin, 10-15 parts of cationic non-starch polymer, 150 parts of 30% polyvinyl acetate emulsion, 200 parts of water, 5-15 parts of a waterproof agent, 10-20 parts of a tackifier and 20-26 parts of aluminum oxide-loaded bentonite.
Preferably, the feed consists of the following raw materials in parts by weight: 55 parts of polyethylene glycol, 25 parts of aluminum potassium sulfate, 18 parts of emulsified silicone oil, 7 parts of amino resin, 13 parts of cationic non-starch polymer, 125 parts of 30% polyvinyl acetate emulsion, 250 parts of water, 13 parts of a waterproof agent, 8 parts of a tackifier and 16 parts of aluminum oxide-loaded bentonite.
Preferably, the amino resin is a condensation product of an aldehyde and a compound selected from urea, melamine, benzoguanamine, glycoluril, acetoguanamine, biuret, or a mixture thereof.
Preferably, the water repellent agent is a CP-88 water repellent agent.
Preferably, the particle size of the alumina-loaded bentonite is 300-350 meshes.
Preferably, the particle size of the cationic non-starch polymer is 500-650 meshes.
A preparation method of an environment-friendly adhesive for carton printing comprises the following steps:
s1, stirring and mixing the cationic non-starch polymer, the aluminum oxide-loaded bentonite and the potassium aluminum sulfate, adjusting the pH value to 7.6-10.5, putting into a grinder for grinding, adjusting the grinding pitch to 13-14 mu m, and carrying out superfine grinding for 35-40min to prepare a mixture A.
S2, adding water into a dissolving machine, continuously stirring and heating to 65 ℃, slowly adding the mixture A, polyethylene glycol, emulsified silicone oil and amino resin into the continuously stirring dissolving machine according to the weight part ratio, continuously stirring for 10-25min, and cooling to 26-30 ℃ to obtain a carrier B;
s3, keeping the carrier B at the temperature of 26-30 ℃ and standing for 15-25min, starting a dissolving machine, slowly adding 30% polyvinyl acetate emulsion in sequence according to the weight part ratio, stirring for 5-10min, and finally adding a waterproof agent and a tackifier to obtain the adhesive.
The invention provides an environment-friendly adhesive for carton printing and a preparation method thereof, and the adhesive has the beneficial effects that: the invention has excellent low-temperature fixation, high-temperature offset resistance and good storage property, can be quickly melted when heated at a lower temperature, keeps smaller viscosity change in a wider temperature range, has higher melt strength and quick solidification when being separated from a fixation roller, can be widely used for various carton printing, can fully meet the requirements of electromagnetic induction heating equipment for high speed, low-temperature fixation and the like which are improved in recent years, has market prospect and is suitable for popularization.
Detailed Description
The invention is further illustrated by the following examples.
Example 1
An environment-friendly adhesive for carton printing comprises the following raw materials in parts by weight: 55 parts of polyethylene glycol, 25 parts of aluminum potassium sulfate, 18 parts of emulsified silicone oil, 7 parts of amino resin, 13 parts of cationic non-starch polymer, 125 parts of 30% polyvinyl acetate emulsion, 250 parts of water, 13 parts of a waterproof agent, 8 parts of a tackifier and 16 parts of aluminum oxide-loaded bentonite, wherein the amino resin is a condensation product of aldehyde and a compound selected from urea, melamine, benzoguanamine, glycoluril, acetoguanamine, biuret or a mixture thereof, the waterproof agent is a CP-88 waterproof agent, the particle size of the aluminum oxide-loaded bentonite is 320 meshes, and the particle size of the cationic non-starch polymer is 550 meshes.
A preparation method of an environment-friendly adhesive for carton printing comprises the following steps:
s1, stirring and mixing the cationic non-starch polymer, the aluminum oxide-loaded bentonite and the potassium aluminum sulfate, adjusting the pH value to 8.6, putting the mixture into a grinder for grinding, adjusting the grinding pitch to 14 mu m, and carrying out superfine grinding for 40min to prepare a mixture A.
S2, adding water into a dissolving machine, continuously stirring and heating to 65 ℃, slowly adding the mixture A, polyethylene glycol, emulsified silicone oil and amino resin into the continuously stirring dissolving machine according to the weight part ratio, continuously stirring for 15min, and cooling to 28 ℃ to obtain a carrier B;
s3, keeping the temperature of the carrier B at 28 ℃ and standing for 20min, starting a dissolving machine, slowly adding 30% polyvinyl acetate emulsion in sequence according to the weight ratio, stirring for 8min, and finally adding a waterproof agent and a tackifier to obtain the adhesive.
Example 2
An environment-friendly adhesive for carton printing comprises the following raw materials in parts by weight: 50 parts of polyethylene glycol, 20 parts of aluminum potassium sulfate, 15 parts of emulsified silicone oil, 5 parts of amino resin, 10 parts of cationic non-starch polymer, 120 parts of 30% polyvinyl acetate emulsion, 200 parts of water, 5 parts of a waterproof agent, 10 parts of a tackifier and 20 parts of aluminum oxide-loaded bentonite, wherein the amino resin is a condensation product of aldehyde and a compound selected from urea, melamine, benzoguanamine, glycoluril, acetoguanamine, biuret or a mixture thereof, the waterproof agent is a CP-88 waterproof agent, the particle size of the aluminum oxide-loaded bentonite is 300 meshes, and the particle size of the cationic non-starch polymer is 500 meshes.
A preparation method of an environment-friendly adhesive for carton printing comprises the following steps:
s1, stirring and mixing the cationic non-starch polymer, the aluminum oxide-loaded bentonite and the potassium aluminum sulfate, adjusting the pH value to 7.6, putting the mixture into a grinder for grinding, adjusting the grinding pitch to 13 mu m, and carrying out superfine grinding for 35min to prepare a mixture A.
S2, adding water into a dissolving machine, continuously stirring and heating to 65 ℃, slowly adding the mixture A, polyethylene glycol, emulsified silicone oil and amino resin into the continuously stirring dissolving machine according to the weight part ratio, continuously stirring for 10min, and cooling to 26 ℃ to obtain a carrier B;
s3, keeping the temperature of the carrier B at 26 ℃ and standing for 15min, starting a dissolving machine, slowly adding 30% polyvinyl acetate emulsion in sequence according to the weight ratio, stirring for 5min, and finally adding a waterproof agent and a tackifier to obtain the adhesive.
Example 3
An environment-friendly adhesive for carton printing comprises the following raw materials in parts by weight: 65 parts of polyethylene glycol, 30 parts of aluminum potassium sulfate, 20 parts of emulsified silicone oil, 10 parts of amino resin, 15 parts of cationic non-starch polymer, 150 parts of 30% polyvinyl acetate emulsion, 250 parts of water, 15 parts of a waterproof agent, 20 parts of a tackifier and 26 parts of aluminum oxide-loaded bentonite, wherein the amino resin is a condensation product of aldehyde and a compound selected from urea, melamine, benzoguanamine, glycoluril, acetoguanamine, biuret or a mixture thereof, the waterproof agent is a CP-88 waterproof agent, the particle size of the aluminum oxide-loaded bentonite is 350 meshes, and the particle size of the cationic non-starch polymer is 650 meshes.
A preparation method of an environment-friendly adhesive for carton printing comprises the following steps:
s1, stirring and mixing the cationic non-starch polymer, the aluminum oxide-loaded bentonite and the potassium aluminum sulfate, adjusting the pH value to 10.5, putting the mixture into a grinder for grinding, adjusting the grinding pitch to 14 mu m, and carrying out superfine grinding for 40min to prepare a mixture A.
S2, adding water into a dissolving machine, continuously stirring and heating to 65 ℃, slowly adding the mixture A, polyethylene glycol, emulsified silicone oil and amino resin into the continuously stirring dissolving machine according to the weight part ratio, continuously stirring for 25min, and cooling to 30 ℃ to obtain a carrier B;
s3, keeping the carrier B at the temperature of 26-30 ℃ and standing for 25min, starting a dissolving machine, slowly adding 30% polyvinyl acetate emulsion in sequence according to the weight ratio, stirring for 10min, and finally adding a waterproof agent and a tackifier to obtain the adhesive.
The invention has excellent low-temperature fixation, high-temperature offset resistance and good storage property, can be quickly melted when heated at a lower temperature, keeps smaller viscosity change in a wider temperature range, has higher melt strength and quick solidification when being separated from a fixation roller, can be widely used for various carton printing, can fully meet the requirements of electromagnetic induction heating equipment for high speed, low-temperature fixation and the like which are improved in recent years, has market prospect and is suitable for popularization.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (7)
1. The environment-friendly adhesive for carton printing is characterized by comprising the following raw materials in parts by weight: 50-65 parts of polyethylene glycol, 20-30 parts of aluminum potassium sulfate, 15-20 parts of emulsified silicone oil, 5-10 parts of amino resin, 10-15 parts of cationic non-starch polymer, 150 parts of 30% polyvinyl acetate emulsion, 200 parts of water, 5-15 parts of a waterproof agent, 10-20 parts of a tackifier and 20-26 parts of aluminum oxide-loaded bentonite.
2. The environment-friendly adhesive for carton printing according to claim 1, which is prepared from the following raw materials in parts by weight: 55 parts of polyethylene glycol, 25 parts of aluminum potassium sulfate, 18 parts of emulsified silicone oil, 7 parts of amino resin, 13 parts of cationic non-starch polymer, 125 parts of 30% polyvinyl acetate emulsion, 250 parts of water, 13 parts of a waterproof agent, 8 parts of a tackifier and 16 parts of aluminum oxide-loaded bentonite.
3. The environment-friendly adhesive for carton printing according to claims 1 to 2, wherein the amino resin is a condensation product of an aldehyde and a compound selected from urea, melamine, benzoguanamine, glycoluril, acetoguanamine, biuret, or a mixture thereof.
4. The environment-friendly adhesive for carton printing according to claims 1-2, wherein the water repellent agent is a CP-88 water repellent agent.
5. The adhesive for printing on the environment-friendly carton as claimed in claims 1-2, wherein the particle size of the alumina-loaded bentonite is 300-350 mesh.
6. The environment-friendly adhesive for carton printing according to claims 1-2, wherein the particle size of the cationic non-starch polymer is 500-650 mesh.
7. The method for preparing the environment-friendly adhesive for carton printing according to claims 1 to 6, comprising the following steps:
s1, stirring and mixing the cationic non-starch polymer, the aluminum oxide-loaded bentonite and the potassium aluminum sulfate, adjusting the pH value to 7.6-10.5, putting into a grinder for grinding, adjusting the grinding pitch to 13-14 mu m, and carrying out superfine grinding for 35-40min to prepare a mixture A;
s2, adding water into a dissolving machine, continuously stirring and heating to 65 ℃, slowly adding the mixture A, polyethylene glycol, emulsified silicone oil and amino resin into the continuously stirring dissolving machine according to the weight part ratio, continuously stirring for 10-25min, and cooling to 26-30 ℃ to obtain a carrier B;
s3, keeping the carrier B at the temperature of 26-30 ℃ and standing for 15-25min, starting a dissolving machine, slowly adding 30% polyvinyl acetate emulsion in sequence according to the weight part ratio, stirring for 5-10min, and finally adding a waterproof agent and a tackifier to obtain the adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010659645.1A CN111662658A (en) | 2020-07-10 | 2020-07-10 | Environment-friendly adhesive for carton printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010659645.1A CN111662658A (en) | 2020-07-10 | 2020-07-10 | Environment-friendly adhesive for carton printing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111662658A true CN111662658A (en) | 2020-09-15 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202010659645.1A Pending CN111662658A (en) | 2020-07-10 | 2020-07-10 | Environment-friendly adhesive for carton printing and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6673862B1 (en) * | 1999-12-10 | 2004-01-06 | Air Products Polymers, L.P. | Vinyl acetate ethylene emulsions stabilized with poly(ethylene/poly (vinyl alcohol) blend |
| CN106753065A (en) * | 2016-12-30 | 2017-05-31 | 河南中包科技有限公司 | A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production |
| CN105579642B (en) * | 2013-09-06 | 2017-08-11 | 国际纸业公司 | Paperboard with improved bending stiffness and method of making the same |
| CN108795322A (en) * | 2018-07-03 | 2018-11-13 | 东莞市瑞兴纸制品有限公司 | A kind of adhesive and preparation method for corrugated board |
| CN109355035A (en) * | 2018-11-20 | 2019-02-19 | 邳州市定邦物流有限公司 | A kind of preparation method of carton adhesive |
-
2020
- 2020-07-10 CN CN202010659645.1A patent/CN111662658A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6673862B1 (en) * | 1999-12-10 | 2004-01-06 | Air Products Polymers, L.P. | Vinyl acetate ethylene emulsions stabilized with poly(ethylene/poly (vinyl alcohol) blend |
| CN105579642B (en) * | 2013-09-06 | 2017-08-11 | 国际纸业公司 | Paperboard with improved bending stiffness and method of making the same |
| CN106753065A (en) * | 2016-12-30 | 2017-05-31 | 河南中包科技有限公司 | A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production |
| CN108795322A (en) * | 2018-07-03 | 2018-11-13 | 东莞市瑞兴纸制品有限公司 | A kind of adhesive and preparation method for corrugated board |
| CN109355035A (en) * | 2018-11-20 | 2019-02-19 | 邳州市定邦物流有限公司 | A kind of preparation method of carton adhesive |
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Application publication date: 20200915 |
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