CN111435645B - Semiconductor structures and methods of forming them - Google Patents
Semiconductor structures and methods of forming them Download PDFInfo
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Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/62—Fin field-effect transistors [FinFET]
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/021—Manufacture or treatment of FETs having insulated gates [IGFET]
- H10D30/024—Manufacture or treatment of FETs having insulated gates [IGFET] of fin field-effect transistors [FinFET]
- H10D30/0241—Manufacture or treatment of FETs having insulated gates [IGFET] of fin field-effect transistors [FinFET] doping of vertical sidewalls, e.g. using tilted or multi-angled implants
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/13—Semiconductor regions connected to electrodes carrying current to be rectified, amplified or switched, e.g. source or drain regions
- H10D62/149—Source or drain regions of field-effect devices
- H10D62/151—Source or drain regions of field-effect devices of IGFETs
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- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
Description
技术领域Technical field
本发明实施例涉及半导体制造领域,尤其涉及一种半导体结构及其形成方法。Embodiments of the present invention relate to the field of semiconductor manufacturing, and in particular, to a semiconductor structure and a forming method thereof.
背景技术Background technique
随着半导体工艺技术的逐步发展,半导体工艺节点遵循摩尔定律的发展趋势不断减小。为了适应工艺节点的减小,MOSFET场效应管的沟道长度也相应不断缩短。然而随着器件沟道长度的缩短,器件源极与漏极间的距离也随之缩短,因此栅极对沟道的控制能力变差,栅极电压夹断(pinch off)沟道的难度也越来越大,使得亚阈值漏电(subthresholdleakage)现象,即所谓的短沟道效应(short-channel effects,SCE)更容易发生。With the gradual development of semiconductor process technology, the development trend of semiconductor process nodes following Moore's Law continues to decrease. In order to adapt to the reduction of process nodes, the channel length of MOSFET field effect transistors has also been shortened accordingly. However, as the channel length of the device shortens, the distance between the source and drain of the device also shortens. Therefore, the gate's ability to control the channel becomes worse, and it becomes more difficult for the gate voltage to pinch off the channel. is getting larger and larger, making it easier for the subthreshold leakage phenomenon, the so-called short-channel effects (SCE), to occur.
因此,为了更好的适应器件尺寸按比例缩小的要求,半导体工艺逐渐开始从平面MOSFET向具有更高功效的三维立体式的器件过渡,如鳍式场效应晶体管(FinFET)。FinFET中,栅极至少可以从两侧对超薄体(鳍部)进行控制,与平面MOSFET相比,栅极对沟道的控制能力更强,能够很好的抑制短沟道效应;且FinFET相对于其他器件,与现有集成电路制造具有更好的兼容性。Therefore, in order to better adapt to the requirements of device size scaling down, semiconductor technology has gradually begun to transition from planar MOSFETs to three-dimensional devices with higher efficiency, such as fin field effect transistors (FinFETs). In FinFET, the gate can at least control the ultra-thin body (fin) from both sides. Compared with planar MOSFET, the gate has stronger control over the channel and can well suppress the short channel effect; and FinFET Compared with other devices, it has better compatibility with existing integrated circuit manufacturing.
发明内容Contents of the invention
本发明实施例解决的问题是提供一种半导体结构及其形成方法,提升半导体结构的电学性能。The problem solved by embodiments of the present invention is to provide a semiconductor structure and a method for forming the same to improve the electrical performance of the semiconductor structure.
为解决上述问题,本发明实施例提供一种半导体结构的形成方法,包括:形成基底,所述基底包括衬底、凸出于所述衬底的鳍部以及横跨所述鳍部的栅极结构,所述栅极结构覆盖所述鳍部的部分顶部和部分侧壁;在所述栅极结构露出的鳍部侧面形成侧壁层;去除部分厚度的所述鳍部,形成由侧壁层和剩余鳍部围成的开口;在所述开口内形成底部源漏掺杂层;沿垂直于所述衬底表面的方向,去除部分高度的所述侧壁层;形成顶部源漏掺杂层,覆盖剩余所述侧壁层露出的底部源漏掺杂层顶部和侧壁,所述顶部源漏掺杂层和底部源漏掺杂层构成源漏掺杂层,所述顶部源漏掺杂层与所述底部源漏掺杂层中的掺杂离子类型相同,且所述顶部源漏掺杂层中离子的掺杂浓度大于底部源漏掺杂层中离子的掺杂浓度。In order to solve the above problems, embodiments of the present invention provide a method for forming a semiconductor structure, including: forming a substrate, the substrate includes a substrate, a fin protruding from the substrate, and a gate across the fin. structure, the gate structure covers part of the top and part of the sidewall of the fin; a sidewall layer is formed on the side of the fin exposed by the gate structure; part of the thickness of the fin is removed to form a sidewall layer and an opening surrounded by the remaining fins; forming a bottom source-drain doped layer in the opening; removing part of the height of the sidewall layer in a direction perpendicular to the substrate surface; forming a top source-drain doped layer , covering the top and side walls of the bottom source-drain doped layer exposed by the remaining sidewall layer, the top source-drain doped layer and the bottom source-drain doped layer constitute a source-drain doped layer, the top source-drain doped layer The type of doping ions in the layer is the same as that in the bottom source-drain doping layer, and the doping concentration of ions in the top source-drain doping layer is greater than the doping concentration of ions in the bottom source-drain doping layer.
相应的,本发明实施例还提供一种半导体结构,包括:衬底;鳍部,凸出于所述衬底;栅极结构,横跨所述鳍部且覆盖所述鳍部的部分顶部和部分侧壁;源漏掺杂层,位于所述栅极结构两侧的鳍部内,所述源漏掺杂层包括底部源漏掺杂层和覆盖所述底部源漏掺杂层顶部和部分侧壁的顶部源漏掺杂层,所述顶部源漏掺杂层和底部源漏掺杂层中的掺杂离子类型相同,且所述顶部源漏掺杂层中的离子掺杂浓度大于底部源漏掺杂层的离子掺杂浓度。Correspondingly, embodiments of the present invention also provide a semiconductor structure, including: a substrate; a fin protruding from the substrate; a gate structure spanning the fin and covering part of the top of the fin; Part of the sidewall; a source-drain doped layer located in the fins on both sides of the gate structure. The source-drain doped layer includes a bottom source-drain doped layer and covers the top and part of the side of the bottom source-drain doped layer. The top source-drain doping layer of the wall, the doping ion type in the top source-drain doping layer and the bottom source-drain doping layer is the same, and the ion doping concentration in the top source-drain doping layer is greater than that of the bottom source-drain doping layer. The ion doping concentration of the drain doped layer.
与现有技术相比,本发明实施例的技术方案具有以下优点:Compared with the existing technology, the technical solutions of the embodiments of the present invention have the following advantages:
本发明实施例中的源漏掺杂层包括底部源漏掺杂层以及覆盖其顶部和部分侧壁的顶部源漏掺杂层,顶部源漏掺杂层中离子的掺杂浓度大于底部源漏掺杂层中离子的掺杂浓度,为了使源漏掺杂层的总体掺杂浓度能够满足电性需求,与仅形成所述底部源漏掺杂层且使底部源漏掺杂层中的离子掺杂浓度较高的方案相比,本发明实施例可适当降低底部源漏掺杂层中的离子掺杂浓度,这有利于降低所述底部源漏掺杂层中掺杂离子向沟道区扩散的概率,从而有利于改善短沟道效应。The source-drain doped layer in the embodiment of the present invention includes a bottom source-drain doped layer and a top source-drain doped layer covering its top and part of the sidewalls. The doping concentration of ions in the top source-drain doped layer is greater than that of the bottom source-drain doped layer. The doping concentration of ions in the doped layer, in order to make the overall doping concentration of the source-drain doped layer meet the electrical requirements, is different from only forming the bottom source-drain doped layer and making the ions in the bottom source-drain doped layer Compared with solutions with higher doping concentrations, embodiments of the present invention can appropriately reduce the ion doping concentration in the bottom source-drain doped layer, which is beneficial to reducing the flow of doped ions in the bottom source-drain doped layer into the channel region. The probability of diffusion is beneficial to improve the short channel effect.
而且,反型层通常形成在靠近鳍部顶部的区域内以形成导电沟道,栅极结构对鳍部底部的控制能力较弱,鳍部底部内形成反型层的概率较低,鳍部底部产生漏电流、短沟道效应等问题的概率较高,与所述底部源漏掺杂层的全部侧壁均被顶部源漏掺杂层覆盖的方案相比,本实施例中,所述底部源漏掺杂层的底部未被顶部源漏掺杂层覆盖,有利于使所述形成方法改善短沟道效应的效果更为显著;此外,与仅形成所述底部源漏掺杂层的方案相比,本发明实施例通过顶部源漏掺杂层,增大了源漏掺杂层的表面积,从而增大了后续与源漏掺杂层电连接的接触孔插塞和源漏掺杂层的接触面积,且所述顶部源漏掺杂层的浓度较大,因此有利于降低所述接触孔插塞和所述源漏掺杂层的接触电阻,提升了半导体结构的电学性能。Moreover, the inversion layer is usually formed in an area close to the top of the fin to form a conductive channel. The gate structure has weak control over the bottom of the fin, and the probability of forming an inversion layer in the bottom of the fin is low. The probability of problems such as leakage current and short channel effect is relatively high. Compared with the solution in which all sidewalls of the bottom source-drain doped layer are covered by the top source-drain doped layer, in this embodiment, the bottom The bottom of the source-drain doped layer is not covered by the top source-drain doped layer, which is beneficial to the formation method improving the short channel effect more significantly; in addition, compared with the solution of only forming the bottom source-drain doped layer In comparison, the embodiment of the present invention increases the surface area of the source-drain doped layer through the top source-drain doped layer, thereby increasing the size of the contact hole plug and the source-drain doped layer that are subsequently electrically connected to the source-drain doped layer. The contact area is large, and the concentration of the top source-drain doped layer is relatively large, which is beneficial to reducing the contact resistance of the contact hole plug and the source-drain doped layer, and improving the electrical performance of the semiconductor structure.
附图说明Description of drawings
图1至图7是一种半导体结构的形成方法中各步骤对应的结构示意图;Figures 1 to 7 are structural schematic diagrams corresponding to each step in a method for forming a semiconductor structure;
图8至图20是本发明半导体结构的形成方法一实施例中各步骤对应的结构示意图。8 to 20 are structural schematic diagrams corresponding to each step in a method for forming a semiconductor structure according to an embodiment of the present invention.
具体实施方式Detailed ways
目前所形成的器件仍有性能不佳的问题。现结合一种半导体结构的形成方法分析器件性能不佳的原因。Devices currently formed still suffer from poor performance. Now, the reasons for poor device performance are analyzed based on a method of forming a semiconductor structure.
参考图1至图7,示出了一种半导体结构的形成方法中各步骤对应的结构示意图。Referring to FIGS. 1 to 7 , a schematic structural diagram corresponding to each step in a method for forming a semiconductor structure is shown.
结合参考图1至图3,分别示出了半导体结构的立体图、图1中aa1方向的剖视图以及图1中bb1方向的剖视图。形成基底,所述基底包括衬底1、凸出于所述衬底1上分立的鳍部2以及横跨所述鳍部2的栅极结构3,所述栅极结构3覆盖所述鳍部2的部分顶部和部分侧壁。With reference to FIGS. 1 to 3 , a perspective view of the semiconductor structure, a cross-sectional view in the aa1 direction in FIG. 1 and a cross-sectional view in the bb1 direction in FIG. 1 are respectively shown. Forming a substrate, the substrate includes a substrate 1, a discrete fin 2 protruding from the substrate 1, and a gate structure 3 across the fin 2, the gate structure 3 covering the fin 2 part of the top and part of the side wall.
参考图4,在所述栅极结构3露出的鳍部2侧面形成侧壁层4。Referring to FIG. 4 , a sidewall layer 4 is formed on the side of the fin 2 exposed by the gate structure 3 .
参考图5,去除栅极结构3两侧部分厚度的所述鳍部2,形成由侧壁层4和剩余鳍部2围成的开口5。Referring to FIG. 5 , the thickness of the fin portion 2 on both sides of the gate structure 3 is removed, forming an opening 5 surrounded by the sidewall layer 4 and the remaining fin portion 2 .
参考图6,在所述开口5内形成源漏掺杂层6。Referring to FIG. 6 , a source-drain doping layer 6 is formed in the opening 5 .
参考图7,去除所述侧壁层4;去除所述侧壁层4后,形成与所述源漏掺杂层6电连接的接触孔插塞7,所述接触孔插塞7覆盖所述源漏掺杂层6的顶部和侧壁。Referring to Figure 7, the sidewall layer 4 is removed; after the sidewall layer 4 is removed, a contact hole plug 7 electrically connected to the source and drain doped layer 6 is formed, and the contact hole plug 7 covers the The top and sidewalls of the source and drain doped layer 6.
在半导体领域中,为减小源漏掺杂层6与接触孔插塞7的接触电阻、以及提高半导体结构的载流子迁移率等电学性能,源漏掺杂层6的离子掺杂浓度通常较高,源漏掺杂层6中的掺杂离子向沟道区发生横向扩散的概率较大,因此容易恶化短沟道效应,从而导致所形成的半导体结构的电学性能不佳。In the semiconductor field, in order to reduce the contact resistance between the source-drain doped layer 6 and the contact hole plug 7 and improve the carrier mobility and other electrical properties of the semiconductor structure, the ion doping concentration of the source-drain doped layer 6 is usually If the value is higher, the doping ions in the source-drain doping layer 6 have a greater probability of lateral diffusion to the channel region, so the short channel effect is easily worsened, resulting in poor electrical performance of the formed semiconductor structure.
为了解决所述技术问题,本发明实施例中的源漏掺杂层包括底部源漏掺杂层以及覆盖其顶部和部分侧壁的顶部源漏掺杂层,顶部源漏掺杂层中离子的掺杂浓度大于底部源漏掺杂层中离子的掺杂浓度,为了使源漏掺杂层的总体掺杂浓度能够满足电性需求,与仅形成所述底部源漏掺杂层且使底部源漏掺杂层中的离子掺杂浓度较高的方案相比,本发明实施例可适当降低底部源漏掺杂层中的离子掺杂浓度,这有利于降低所述底部源漏掺杂层中掺杂离子向沟道区扩散的概率,从而有利于改善短沟道效应。In order to solve the technical problem described above, the source-drain doped layer in the embodiment of the present invention includes a bottom source-drain doped layer and a top source-drain doped layer covering its top and part of the sidewalls. The ions in the top source-drain doped layer The doping concentration is greater than the doping concentration of ions in the bottom source-drain doped layer. In order to make the overall doping concentration of the source-drain doped layer meet the electrical requirements, it is better to only form the bottom source-drain doped layer and make the bottom source Compared with the solution in which the ion doping concentration in the drain doping layer is relatively high, the embodiments of the present invention can appropriately reduce the ion doping concentration in the bottom source and drain doping layer, which is beneficial to reducing the ion doping concentration in the bottom source and drain doping layer. The probability of doping ions diffusing into the channel region is beneficial to improving the short channel effect.
而且,反型层通常形成在靠近鳍部顶部的区域内以形成导电沟道,栅极结构对鳍部底部的控制能力较弱,鳍部底部内形成反型层的概率较低,鳍部底部产生漏电流、短沟道效应等问题的概率较高,与所述底部源漏掺杂层的全部侧壁均被顶部源漏掺杂层覆盖的方案相比,本实施例中,所述底部源漏掺杂层的底部未被顶部源漏掺杂层覆盖,有利于使所述形成方法改善短沟道效应的效果更为显著。Moreover, the inversion layer is usually formed in an area close to the top of the fin to form a conductive channel. The gate structure has weak control over the bottom of the fin, and the probability of forming an inversion layer in the bottom of the fin is low. The probability of problems such as leakage current and short channel effect is relatively high. Compared with the solution in which all sidewalls of the bottom source-drain doped layer are covered by the top source-drain doped layer, in this embodiment, the bottom The bottom of the source-drain doped layer is not covered by the top source-drain doped layer, which is beneficial to making the formation method more effective in improving the short channel effect.
此外,与仅形成所述底部源漏掺杂层的方案相比,本发明实施例通过顶部源漏掺杂层,增大了源漏掺杂层的表面积,从而增大了后续与源漏掺杂层电连接的接触孔插塞和源漏掺杂层的接触面积,且所述顶部源漏掺杂层的浓度较大,因此有利于降低所述接触孔插塞和所述源漏掺杂层的接触电阻,提升了半导体结构的电学性能。In addition, compared with the solution of only forming the bottom source-drain doped layer, the embodiment of the present invention increases the surface area of the source-drain doped layer through the top source-drain doped layer, thereby increasing the subsequent connection with the source-drain doped layer. The contact area of the contact hole plug and the source-drain doping layer that is electrically connected to the impurity layer, and the concentration of the top source-drain doping layer is relatively large, which is beneficial to reducing the contact hole plug and the source-drain doping layer. The contact resistance of the layers improves the electrical performance of the semiconductor structure.
为使本发明实施例的上述目的、特征和优点能够更为明显易懂,下面结合附图对本发明的具体实施例做详细的说明。In order to make the above objects, features and advantages of the embodiments of the present invention more obvious and understandable, specific embodiments of the present invention will be described in detail below with reference to the accompanying drawings.
图8至图20是本发明半导体结构的形成方法一实施例中各步骤对应的结构示意图。8 to 20 are structural schematic diagrams corresponding to each step in a method for forming a semiconductor structure according to an embodiment of the present invention.
结合参考图8至图10,分别示出了半导体结构的立体图、图8中AA1方向的剖视图以及图8中BB1方向的剖视图。形成基底,所述基底包括衬底100、凸出于所述衬底100上分立的鳍部110以及横跨所述鳍部110的栅极结构114,所述栅极结构114覆盖所述鳍部110的部分顶部和部分侧壁。With reference to FIGS. 8 to 10 , a perspective view of the semiconductor structure, a cross-sectional view along the AA1 direction in FIG. 8 , and a cross-sectional view along the BB1 direction in FIG. 8 are respectively shown. Forming a substrate, the substrate includes a substrate 100, separate fins 110 protruding from the substrate 100, and a gate structure 114 spanning the fins 110, the gate structure 114 covering the fins Part of the top and part of the side wall of 110.
所述衬底100用于为后续形成半导体结构提供工艺平台。The substrate 100 is used to provide a process platform for subsequent formation of semiconductor structures.
本实施例中,所述衬底100为硅衬底。在其他实施例中,所述衬底的材料还可以为锗、锗化硅、碳化硅、砷化镓或镓化铟等其他材料,所述衬底还可以为绝缘体上的硅衬底或者绝缘体上的锗衬底等其他类型的衬底。In this embodiment, the substrate 100 is a silicon substrate. In other embodiments, the material of the substrate can also be other materials such as germanium, silicon germanium, silicon carbide, gallium arsenide or indium gallium. The substrate can also be a silicon substrate on an insulator or an insulator. on germanium substrates and other types of substrates.
所述鳍部110用于后续提供鳍式场效应晶体管的导电沟道。The fin portion 110 is used to subsequently provide a conductive channel for the fin field effect transistor.
本实施例中,所述鳍部110与所述衬底100由对同一半导体层进行刻蚀所得到。在其他实施例中,所述鳍部也可以是外延生长于所述衬底上的半导体层,从而达到精确控制所述鳍部高度的目的。In this embodiment, the fin portion 110 and the substrate 100 are obtained by etching the same semiconductor layer. In other embodiments, the fin portion may also be a semiconductor layer grown epitaxially on the substrate, thereby achieving the purpose of accurately controlling the height of the fin portion.
因此,本实施例中,所述鳍部110的材料与所述衬底100的材料相同,所述鳍部110的材料为硅。其他实施例中,所述鳍部的材料还可以是锗、锗化硅、碳化硅、砷化镓或镓化铟。Therefore, in this embodiment, the material of the fin portion 110 is the same as the material of the substrate 100 , and the material of the fin portion 110 is silicon. In other embodiments, the material of the fins may also be germanium, silicon germanium, silicon carbide, gallium arsenide or indium gallium.
需要说明的是,基底还包括隔离层111,位于鳍部110露出的衬底100上且覆盖鳍部110的部分侧壁。隔离层111用于对相邻器件之间起到电隔离作用。It should be noted that the substrate also includes an isolation layer 111 , which is located on the substrate 100 where the fins 110 are exposed and covers part of the sidewalls of the fins 110 . The isolation layer 111 is used to electrically isolate adjacent devices.
本实施例中,隔离层111的材料为氧化硅。在其他实施例中,隔离层的材料还可以为氮化硅、氮氧化硅、碳氧化硅、碳氮化硅或碳氮氧化硅等绝缘材料。In this embodiment, the material of the isolation layer 111 is silicon oxide. In other embodiments, the material of the isolation layer may also be an insulating material such as silicon nitride, silicon oxynitride, silicon oxycarbide, silicon carbonitride, or silicon oxycarboxynitride.
本实施例中,所述栅极结构114包括栅氧化层112(如图10所示)以及位于所述栅氧化层112上的栅极层113(如图10所示)。In this embodiment, the gate structure 114 includes a gate oxide layer 112 (shown in FIG. 10 ) and a gate layer 113 (shown in FIG. 10 ) located on the gate oxide layer 112 .
所述栅氧化层112的材料为氧化硅或氮氧化硅,所述栅极层113的材料为多晶硅、氧化硅、氮化硅、氮氧化硅、碳化硅、碳氮化硅、碳氮氧化硅或非晶碳。本实施例中,栅氧化层112的材料为氧化硅,栅极层113的材料为多晶硅。The gate oxide layer 112 is made of silicon oxide or silicon oxynitride, and the gate layer 113 is made of polysilicon, silicon oxide, silicon nitride, silicon oxynitride, silicon carbide, silicon carbonitride, or silicon nitride oxycarbon. or amorphous carbon. In this embodiment, the material of the gate oxide layer 112 is silicon oxide, and the material of the gate layer 113 is polysilicon.
在其他实施例中,所述栅极结构还可以为金属栅极结构。In other embodiments, the gate structure may also be a metal gate structure.
本实施例中,所述栅氧化层112还覆盖所述栅极层113露出的鳍部110表面。需要说明的是,为方便示意和描述,本实施例中,图8仅示意出了栅极结构114中的栅极层113。In this embodiment, the gate oxide layer 112 also covers the surface of the fin 110 exposed by the gate layer 113 . It should be noted that, for convenience of illustration and description, in this embodiment, FIG. 8 only illustrates the gate layer 113 in the gate structure 114 .
本实施例中,所述栅极结构114顶部还形成有衬垫氧化层(pad oxide)115(如图10所示)以及位于衬垫氧化层115上的栅极掩膜层116(如图10所示)。In this embodiment, a pad oxide layer (pad oxide) 115 (as shown in FIG. 10 ) and a gate mask layer 116 (as shown in FIG. 10 ) located on the pad oxide layer 115 are also formed on the top of the gate structure 114 . shown).
所述栅极掩膜层116用于作为形成栅极层113的刻蚀掩膜,还能够在后续制程中保护栅极层113顶部。本实施例中,栅极掩膜层116的材料为氮化硅。The gate mask layer 116 is used as an etching mask to form the gate layer 113 and can also protect the top of the gate layer 113 in subsequent processes. In this embodiment, the material of the gate mask layer 116 is silicon nitride.
所述衬垫氧化层115用于在形成栅极掩膜层116、以及以所述栅极掩膜层116为掩膜形成栅极层113时起到应力缓冲的作用,提高所述栅极掩膜层116和栅极层113之间的粘附性,避免栅极掩膜层116与栅极层113直接接触产生位错的问题。本实施例中,所述衬垫氧化层115的材料为氧化硅。The pad oxide layer 115 is used to play a stress buffering role when forming the gate mask layer 116 and using the gate mask layer 116 as a mask to form the gate layer 113, thereby improving the gate mask layer. The adhesion between the film layer 116 and the gate layer 113 avoids the problem of dislocation caused by direct contact between the gate mask layer 116 and the gate layer 113 . In this embodiment, the material of the pad oxide layer 115 is silicon oxide.
继续参考图10,本实施例中,所述形成方法还包括:形成所述基底后,在所述栅极层113、衬垫氧化层115和栅极掩膜层116的侧壁上形成第一侧墙118。Continuing to refer to FIG. 10 , in this embodiment, the forming method further includes: after forming the substrate, forming a first layer on the sidewalls of the gate layer 113 , the pad oxide layer 115 and the gate mask layer 116 . Side walls 118.
所述第一侧墙118用于在后续工艺制程中对栅极层113的侧壁起到保护作用。所述形成方法还可以包括低掺杂漏离子注入工艺,所述第一侧墙作为偏移侧墙(OffsetSpacer),还用于定义低掺杂漏离子注入工艺的注入区域。The first spacers 118 are used to protect the sidewalls of the gate layer 113 in subsequent processes. The formation method may further include a low-doping drain ion implantation process, and the first spacer serves as an offset spacer and is also used to define an implantation region of the low-doping drain ion implantation process.
本实施例中,所述第一侧墙118的材料为氮化硅。在其他实施例中,所述第一侧墙的材料还能够为氧化硅、氮氧化硅、碳化硅、碳氧化硅或碳氮氧化硅。In this embodiment, the first spacer 118 is made of silicon nitride. In other embodiments, the material of the first side wall can also be silicon oxide, silicon oxynitride, silicon carbide, silicon oxycarbide or silicon oxynitride.
结合参考图11,形成所述第一侧墙118后,所述形成方法还包括:去除第一侧墙118露出鳍部110表面上的栅氧化层112。通过去除位于第一侧墙118露出鳍部110表面上的栅氧化层112,有利于简化后续形成侧壁层、刻蚀所述鳍部110以及侧壁层的工艺流程。Referring to FIG. 11 , after forming the first spacers 118 , the forming method further includes: removing the first spacers 118 to expose the gate oxide layer 112 on the surface of the fin 110 . By removing the gate oxide layer 112 on the surface of the first sidewall 118 exposing the fin 110 , it is beneficial to simplify the subsequent process of forming the sidewall layer and etching the fin 110 and the sidewall layer.
在其他实施例中,根据实际工艺需求,也可以保留位于所述第一侧墙露出鳍部表面上的栅氧化层。In other embodiments, according to actual process requirements, the gate oxide layer located on the exposed fin surface of the first spacer may also be retained.
参考图12至图15,在所述栅极结构114露出的鳍部110侧面形成侧壁层125(如图15所示)。Referring to FIGS. 12 to 15 , a sidewall layer 125 is formed on the side of the fin 110 exposed by the gate structure 114 (as shown in FIG. 15 ).
所述侧壁层125用于定义后续底部源漏掺杂层沿垂直于鳍部110延伸方向的形成区域。本实施例中,所述侧壁层125的材料为氮化硅。在其他实施例中,所述侧壁层的材料还可以为碳氮化硅、碳氮化硅硼或碳氮氧化硅。The sidewall layer 125 is used to define a subsequent formation region of the bottom source and drain doped layer along a direction perpendicular to the extending direction of the fin 110 . In this embodiment, the material of the sidewall layer 125 is silicon nitride. In other embodiments, the material of the sidewall layer may also be silicon carbonitride, boron silicon nitride, or silicon oxynitride.
具体地,形成所述侧壁层125的步骤包括:Specifically, the step of forming the sidewall layer 125 includes:
结合参考图12至图13,图12是基于图11的剖面图,图13是图12沿垂直于鳍部延伸方向的剖面图,在所述第一侧墙118露出的鳍部110表面以及隔离层111上形成侧壁材料层120。Referring to FIGS. 12 to 13 , FIG. 12 is a cross-sectional view based on FIG. 11 , and FIG. 13 is a cross-sectional view of FIG. 12 along the direction perpendicular to the extension of the fins. The surface of the fins 110 exposed on the first side wall 118 and the isolation A layer 120 of sidewall material is formed on layer 111 .
所述侧壁材料层120用于后续形成侧壁层。本实施例中,采用原子层沉积(AtomicLayer Deposition,ALD)工艺形成侧壁材料层120。The sidewall material layer 120 is used to subsequently form a sidewall layer. In this embodiment, the sidewall material layer 120 is formed using an atomic layer deposition (ALD) process.
原子层沉积工艺具有较好的保形覆盖能力,因此,结合参考图12,本实施例中,所述侧壁材料层120还形成于所述栅极掩膜层116和第一侧墙118顶部、以及第一侧墙118的侧壁上,而且,原子层沉积工艺的沉积均匀性较好,有利于提高侧壁材料层120的厚度均一性,相应提高了后续侧壁层的厚度均一性。The atomic layer deposition process has good conformal coverage capability. Therefore, with reference to FIG. 12 , in this embodiment, the sidewall material layer 120 is also formed on top of the gate mask layer 116 and the first sidewall 118 , and on the sidewalls of the first sidewalls 118. Moreover, the deposition uniformity of the atomic layer deposition process is good, which is beneficial to improving the thickness uniformity of the sidewall material layer 120, and correspondingly improves the thickness uniformity of subsequent sidewall layers.
结合参考图14至图15,去除鳍部110顶部的侧壁材料层120,形成所述侧壁层125。With reference to FIGS. 14 and 15 , the sidewall material layer 120 on the top of the fin 110 is removed to form the sidewall layer 125 .
需要说明的是,本实施例中,去除鳍部110顶部的侧壁材料层120的步骤中,还去除了栅极掩膜层116和第一侧墙118顶部的侧壁材料层120,保留位于第一侧墙118侧壁上的侧壁材料层120作为第二侧墙119。It should be noted that in this embodiment, in the step of removing the sidewall material layer 120 on top of the fin 110, the gate mask layer 116 and the sidewall material layer 120 on top of the first sidewall 118 are also removed, leaving only The sidewall material layer 120 on the sidewall of the first sidewall 118 serves as the second sidewall 119.
所述第二侧墙119用于在后续工艺制程中保护所述栅极层113的侧壁,所述第二侧墙119还用于定义后续源漏掺杂层沿鳍部110延伸方向的形成区域。The second spacers 119 are used to protect the sidewalls of the gate layer 113 in subsequent processes. The second spacers 119 are also used to define the formation of subsequent source and drain doped layers along the extension direction of the fins 110 area.
通过在形成侧壁层125的步骤中形成第二侧墙119,有利于简化工艺流程。By forming the second sidewall 119 in the step of forming the sidewall layer 125, it is beneficial to simplify the process flow.
因此,本实施例中,所述第二侧墙119与侧壁层125的材料相同,所述第二侧墙119的材料为氮化硅。在其他实施例中,所述第二侧墙的材料还可以与所述侧壁层的材料不同,所述第二侧墙的材料还能够为氧化硅、氮氧化硅、碳化硅、碳氧化硅或碳氮氧化硅。Therefore, in this embodiment, the second spacer 119 and the sidewall layer 125 are made of the same material, and the material of the second spacer 119 is silicon nitride. In other embodiments, the material of the second sidewall can also be different from the material of the sidewall layer. The material of the second sidewall can also be silicon oxide, silicon oxynitride, silicon carbide, or silicon oxycarbide. Or silicon oxynitride.
本实施例中,采用干法刻蚀工艺,去除所述鳍部110顶部的侧壁材料层120。In this embodiment, a dry etching process is used to remove the sidewall material layer 120 on the top of the fin 110 .
还需要说明的是,本实施例中,在去除所述鳍部110顶部、以及栅极掩膜层116和第一侧墙118顶部的侧壁材料层120的步骤中,还一并去除了位于隔离层111上的侧壁材料层120。It should also be noted that in this embodiment, during the step of removing the sidewall material layer 120 on top of the fin portion 110 and the gate mask layer 116 and the first sidewall 118 , the sidewall material layer 120 located on the top of the gate mask layer 116 and the first sidewall 118 is also removed. Sidewall material layer 120 on isolation layer 111 .
在其他实施例中,还可以保留位于隔离层上的侧壁材料层,位于隔离层上的侧壁材料层还能够对鳍部侧面的侧壁层起到支撑作用,从而有利于降低后续刻蚀鳍部、以及侧壁层的步骤中,侧壁层发生倾斜、脱落的概率。具体地,可以在位于隔离层上的侧壁材料层上形成保护层,以保护层为掩膜,去除鳍部顶部、栅极掩膜层和第一侧墙顶部的侧壁材料层,位于隔离层上的侧壁材料层在保护层的保护下被保留。In other embodiments, the sidewall material layer located on the isolation layer can also be retained. The sidewall material layer located on the isolation layer can also support the sidewall layer on the side of the fin, thereby helping to reduce subsequent etching. During the steps of fins and sidewall layers, the probability that the sidewall layer will tilt or fall off. Specifically, a protective layer can be formed on the sidewall material layer located on the isolation layer. Using the protective layer as a mask, remove the sidewall material layer on top of the fin, the gate mask layer and the top of the first sidewall, and remove the sidewall material layer on the isolation layer. The layer of sidewall material on the layer is retained under the protection of the protective layer.
参考图16,去除部分厚度的所述鳍部110,形成由侧壁层125和剩余鳍部110围成的开口200。Referring to FIG. 16 , part of the thickness of the fin 110 is removed, forming an opening 200 surrounded by the sidewall layer 125 and the remaining fin 110 .
所述开口200用于为后续形成底部源漏掺杂层提供空间位置。The opening 200 is used to provide a spatial location for the subsequent formation of the bottom source and drain doped layer.
具体地,形成所述开口200的步骤包括:采用干法刻蚀工艺,去除部分厚度的所述鳍部110,形成由侧壁层125和剩余鳍部110围成的开口200。干法刻蚀工艺具有较好的刻蚀剖面控制性,有利于使开口200的形貌满足工艺需求。Specifically, the step of forming the opening 200 includes: using a dry etching process to remove part of the thickness of the fin portion 110 to form the opening 200 surrounded by the sidewall layer 125 and the remaining fin portion 110 . The dry etching process has better etching profile controllability, which is conducive to making the shape of the opening 200 meet process requirements.
参考图17,在所述开口200(如图16所示)内形成底部源漏掺杂层131。Referring to FIG. 17 , a bottom source-drain doping layer 131 is formed within the opening 200 (shown in FIG. 16 ).
所述底部源漏掺杂层131用于为后续形成源漏掺杂层,底部源漏掺杂层131还用于为后续形成顶部源漏掺杂层提供工艺平台。The bottom source-drain doping layer 131 is used for subsequent formation of the source-drain doping layer, and the bottom source-drain doping layer 131 is also used to provide a process platform for the subsequent formation of the top source-drain doping layer.
后续制程还包括,去除部分高度的所述侧壁层125;在剩余所述侧壁层125露出的底部源漏掺杂层131顶部和侧壁形成顶部源漏掺杂层,所述顶部源漏掺杂层和底部源漏掺杂层131构成源漏掺杂层。为了使所述源漏掺杂层的总体掺杂浓度满足电性需求,与仅形成所述底部源漏掺杂层且使底部源漏掺杂层中的离子掺杂浓度较高的方案相比,本实施例中可适当降低底部源漏掺杂层131中的离子掺杂浓度,这有利于降低底部源漏掺杂层131中掺杂离子向沟道区扩散的概率,从而有利于改善短沟道效应。The subsequent process also includes removing part of the height of the sidewall layer 125; forming a top source-drain doped layer on the top and side walls of the bottom source-drain doped layer 131 exposed by the remaining sidewall layer 125, and the top source-drain doped layer is The doped layer and the bottom source-drain doped layer 131 constitute a source-drain doped layer. In order to make the overall doping concentration of the source-drain doped layer meet the electrical requirements, compared with the solution of only forming the bottom source-drain doped layer and making the ion doping concentration in the bottom source-drain doped layer higher , in this embodiment, the ion doping concentration in the bottom source-drain doped layer 131 can be appropriately reduced, which is beneficial to reducing the probability of doped ions in the bottom source-drain doped layer 131 diffusing to the channel region, thereby helping to improve short-term operation. channeling effect.
因此,本实施例中,所述底部源漏掺杂层131中的离子掺杂浓度不宜过低,也不宜过高。如果底部源漏掺杂层131中离子掺杂浓度过低,容易使后续源漏掺杂层的总体掺杂浓度难以满足电性需求;如果底部源漏掺杂层131中的离子掺杂浓度过高,底部源漏掺杂层131中掺杂离子向沟道区扩散的概率较大,不利于改善半导体结构的短沟道效应。为此,本实施例中,本实施例中,所述半导体结构用于形成NMOS晶体管,底部源漏掺杂层131中掺杂有N型离子,N型离子的掺杂浓度为3.0E20原子每立方厘米至8.0E21原子每立方厘米。在其他实施例中,所述半导体结构用于形成PMOS晶体管时,底部源漏掺杂层中掺杂有P型离子,P型离子的掺杂浓度为1.0E20原子每立方厘米至4.0E20原子每立方厘米。Therefore, in this embodiment, the ion doping concentration in the bottom source-drain doping layer 131 should not be too low or too high. If the ion doping concentration in the bottom source-drain doping layer 131 is too low, the overall doping concentration of the subsequent source-drain doping layer may be difficult to meet the electrical requirements; if the ion doping concentration in the bottom source-drain doping layer 131 is too high High, the probability of doping ions in the bottom source-drain doping layer 131 to diffuse to the channel region is high, which is not conducive to improving the short channel effect of the semiconductor structure. To this end, in this embodiment, the semiconductor structure is used to form an NMOS transistor, and the bottom source and drain doping layer 131 is doped with N-type ions, and the doping concentration of the N-type ions is 3.0E20 atoms per cubic centimeter to 8.0E21 atoms per cubic centimeter. In other embodiments, when the semiconductor structure is used to form a PMOS transistor, the bottom source-drain doping layer is doped with P-type ions, and the doping concentration of P-type ions ranges from 1.0E20 atoms per cubic centimeter to 4.0E20 atoms per cubic centimeter. cubic centimeters.
具体地,本实施例中,采用原位自掺杂工艺形成所述底部源漏掺杂层131,即采用外延工艺,在所述开口200内形成外延层(图未示),且在形成所述外延层的过程中原位自掺杂离子形成所述底部源漏掺杂层131。原位自掺杂工艺为半导体领域中常用的形成源漏掺杂层的工艺,工艺兼容性较高。Specifically, in this embodiment, an in-situ self-doping process is used to form the bottom source and drain doped layer 131, that is, an epitaxial process is used to form an epitaxial layer (not shown) in the opening 200, and after forming the During the process of the epitaxial layer, the bottom source and drain doped layer 131 is formed by in-situ self-doping ions. The in-situ self-doping process is a commonly used process in the semiconductor field to form source and drain doped layers, and has high process compatibility.
因此,本实施例中,所述半导体结构用于形成NMOS晶体管,底部源漏掺杂层131包括掺杂有N型离子的外延层,外延层的材料可以为Si或SiC,从而为NMOS晶体管的沟道区提供拉应力作用,有利于提高NMOS晶体管的载流子迁移率,其中,N型离子为P离子、As离子或Sb离子。在其他实施例中,所述半导体结构用于形成PMOS晶体管时,底部源漏掺杂层包括掺杂有P型离子的外延层,外延层的材料可以为Si或SiGe,从而为PMOS晶体管的沟道区提供压应力作用,有利于提高PMOS晶体管的载流子迁移率,其中,P型离子为B离子、Ga离子或In离子。Therefore, in this embodiment, the semiconductor structure is used to form an NMOS transistor. The bottom source-drain doped layer 131 includes an epitaxial layer doped with N-type ions. The material of the epitaxial layer can be Si or SiC, thereby forming the NMOS transistor. The channel region provides tensile stress, which is beneficial to improving the carrier mobility of the NMOS transistor. Among them, the N-type ions are P ions, As ions or Sb ions. In other embodiments, when the semiconductor structure is used to form a PMOS transistor, the bottom source-drain doping layer includes an epitaxial layer doped with P-type ions. The material of the epitaxial layer can be Si or SiGe, thereby forming a channel for the PMOS transistor. The channel region provides compressive stress, which is beneficial to improving the carrier mobility of the PMOS transistor, in which the P-type ions are B ions, Ga ions or In ions.
参考图18,沿垂直于所述衬底100表面的方向,去除部分高度的侧壁层125。Referring to FIG. 18 , part of the height of the sidewall layer 125 is removed in a direction perpendicular to the surface of the substrate 100 .
通过去除部分高度的所述侧壁层125,从而露出所述底部源漏掺杂层131的部分侧壁,为后续在剩余所述侧壁层125露出的底部源漏掺杂层131顶部和侧壁形成顶部源漏掺杂层提供工艺基础。By removing part of the height of the sidewall layer 125 , part of the sidewall of the bottom source-drain doped layer 131 is exposed, and the top and sides of the bottom source-drain doped layer 131 are subsequently exposed on the remaining sidewall layer 125 . The walls form the top source and drain doped layers to provide the basis for the process.
而且,反型层通常形成在靠近鳍部110顶部的区域内以形成导电沟道,栅极结构114对鳍部110底部的控制能力较弱,鳍部110底部内形成反型层的概率较低,鳍部110底部产生漏电流、短沟道效应等问题的概率较高,与全部去除所述侧壁层的方案相比,本实施例中仅去除部分高度的所述侧壁层125,保留位于底部源漏掺杂层131底部侧壁上的部分侧壁层125,使所述底部源漏掺杂层131的底部未被顶部源漏掺杂层覆盖,有利于使所述形成方法用于改善短沟道效应的效果更为显著。Moreover, the inversion layer is usually formed in an area close to the top of the fin 110 to form a conductive channel. The gate structure 114 has weak control over the bottom of the fin 110 and the probability of forming an inversion layer in the bottom of the fin 110 is low. , the probability of problems such as leakage current and short channel effect at the bottom of the fin 110 is relatively high. Compared with the solution of completely removing the sidewall layer, in this embodiment, only a part of the height of the sidewall layer 125 is removed, leaving The partial sidewall layer 125 located on the bottom sidewall of the bottom source-drain doped layer 131 prevents the bottom of the bottom source-drain doped layer 131 from being covered by the top source-drain doped layer, which is beneficial to the formation method. The effect of improving the short channel effect is more significant.
因此,本实施例中,去除部分高度的所述侧壁层125后,剩余侧壁层125的高度不宜过小,也不宜过大。如果剩余侧壁层125的高度过小,则后续顶部源漏掺杂层过于靠近鳍部110底部,顶部源漏掺杂层中的掺杂离子向鳍部110底部内扩散的概率较高,不利于改善短沟道效应;如果剩余侧壁层125的高度过大,则所述顶部源漏掺杂层的体积和表面积相应过小,容易使后续源漏掺杂层的总体掺杂浓度难以满足电性需求,例如,顶部源漏掺杂层与后续接触孔插塞的接触面积过小,容易使源漏掺杂层与接触孔插塞的接触电阻过大,而且,顶部源漏掺杂层的体积过小还容易导致源漏掺杂层中的应力过小,不利于提高半导体结构的载流子迁移率。为此,本实施例中,去除部分高度的所述侧壁层125后,剩余侧壁层125的高度为15nm至25nm。Therefore, in this embodiment, after removing part of the height of the sidewall layer 125 , the height of the remaining sidewall layer 125 should not be too small, nor should it be too large. If the height of the remaining sidewall layer 125 is too small, the subsequent top source-drain doped layer will be too close to the bottom of the fin 110, and the doped ions in the top source-drain doped layer will have a higher probability of diffusing into the bottom of the fin 110, and will not It is beneficial to improve the short channel effect; if the height of the remaining sidewall layer 125 is too large, the volume and surface area of the top source-drain doped layer will be too small, which will easily make it difficult to meet the overall doping concentration of the subsequent source-drain doped layer. Electrical requirements, for example, the contact area between the top source-drain doped layer and subsequent contact hole plugs is too small, which can easily cause the contact resistance between the source-drain doped layer and the contact hole plug to be too large, and the top source-drain doped layer Too small a volume can easily lead to too little stress in the source and drain doped layers, which is not conducive to improving the carrier mobility of the semiconductor structure. For this reason, in this embodiment, after part of the height of the sidewall layer 125 is removed, the height of the remaining sidewall layer 125 is 15 nm to 25 nm.
本实施例中,采用干法刻蚀工艺,去除部分厚度的侧壁层125。采用干法刻蚀工艺有利于控制横向刻蚀和纵向刻蚀的比例,从而提高刻蚀工艺的各向异性,有利于使侧壁层125的刻蚀量满足工艺需求,而且,还有利于降低在去除部分厚度的侧壁层125过程中,对其他膜层结构如底部源漏掺杂层131的影响。In this embodiment, a dry etching process is used to remove part of the thickness of the sidewall layer 125 . The use of dry etching process is conducive to controlling the ratio of lateral etching and longitudinal etching, thereby improving the anisotropy of the etching process, which is conducive to making the etching amount of the sidewall layer 125 meet process requirements, and is also conducive to reducing the In the process of removing part of the thickness of the sidewall layer 125, other film layer structures such as the bottom source and drain doped layer 131 are affected.
需要说明的是,所述干法刻蚀工艺的偏置电压不宜过小,也不宜过大。如果所述底部偏置电压过小,容易降低所述干法刻蚀工艺的各向异性,导致所述干法刻蚀工艺也横向刻蚀所述侧壁层125;如果所述偏置电压过大,容易对所述侧壁层125造成过刻蚀,从而导致剩余所述侧壁层125的高度过小。为此,本实施例中,所述干法刻蚀工艺的偏置电压为80V至250V。It should be noted that the bias voltage of the dry etching process should not be too small or too large. If the bottom bias voltage is too small, it is easy to reduce the anisotropy of the dry etching process, causing the dry etching process to also laterally etch the sidewall layer 125; if the bias voltage is too high, If it is large, it is easy to cause over-etching of the sidewall layer 125, resulting in the height of the remaining sidewall layer 125 being too small. For this reason, in this embodiment, the bias voltage of the dry etching process is 80V to 250V.
相应地,所述干法刻蚀工艺的刻蚀功率也不宜过小或过大。本实施例中,所述干法刻蚀工艺的刻蚀功率为100W至400W。Correspondingly, the etching power of the dry etching process should not be too small or too large. In this embodiment, the etching power of the dry etching process is 100W to 400W.
还需要说明的是,所述干法刻蚀工艺的刻蚀时间不宜过短,也不宜过长。如果所述刻蚀时间过短,容易使所述侧壁层125的刻蚀量难以满足工艺需求;如果所述刻蚀时间过长,容易对所述侧壁层125造成过刻蚀,而且容易降低生产产能。为此,本实施例中,所述干法刻蚀工艺的刻蚀时间为10S至200S。It should also be noted that the etching time of the dry etching process should not be too short or too long. If the etching time is too short, the etching amount of the sidewall layer 125 may be difficult to meet process requirements; if the etching time is too long, the sidewall layer 125 may be easily over-etched, and the etching amount of the sidewall layer 125 may be easily over-etched. Reduce production capacity. For this reason, in this embodiment, the etching time of the dry etching process is 10S to 200S.
此外,所述干法刻蚀工艺的工艺压强不宜过低,也不宜过高。如果所述工艺压强过低,容易降低刻蚀速率,相应降低了生产制造效率;如果所述工艺压强过高,容易降低工艺稳定性,而且容易降低干法刻蚀工艺的刻蚀均匀性,此外,工艺压强过高还容易导致生产成本的增加。为此,本实施例中,所述干法刻蚀工艺的工艺压强为10mtorr至200mtorr。In addition, the process pressure of the dry etching process should not be too low or too high. If the process pressure is too low, it is easy to reduce the etching rate, and accordingly the manufacturing efficiency is reduced; if the process pressure is too high, it is easy to reduce the process stability, and it is easy to reduce the etching uniformity of the dry etching process. In addition, , too high process pressure can easily lead to an increase in production costs. For this reason, in this embodiment, the process pressure of the dry etching process is 10 mtorr to 200 mtorr.
参考图19,形成顶部源漏掺杂层132,覆盖剩余所述侧壁层125露出的底部源漏掺杂层131顶部和侧壁,所述顶部源漏掺杂层132和底部源漏掺杂层131构成源漏掺杂层130,所述顶部源漏掺杂层132与所述底部源漏掺杂层131中的掺杂离子类型相同,且所述顶部源漏掺杂层132中离子的掺杂浓度大于底部源漏掺杂层131中离子的掺杂浓度。Referring to Figure 19, a top source-drain doped layer 132 is formed to cover the top and side walls of the bottom source-drain doped layer 131 exposed by the remaining sidewall layer 125. The top source-drain doped layer 132 and the bottom source-drain doped layer 132 are Layer 131 constitutes a source-drain doped layer 130, the top source-drain doped layer 132 has the same type of doping ions as the bottom source-drain doped layer 131, and the ions in the top source-drain doped layer 132 have the same type. The doping concentration is greater than the doping concentration of ions in the bottom source-drain doping layer 131 .
通过使所述顶部源漏掺杂层132中离子掺杂浓度较大,从而有利于使源漏掺杂层130的总体掺杂浓度能够满足电性需求。而且,通过使底部源漏掺杂层131中的掺杂浓度较小,且顶部源漏掺杂层132仅覆盖侧壁层125露出的底部源漏掺杂层131侧壁,顶部源漏掺杂层132中掺杂离子向鳍部110底部内扩散的概率较低,有利于使所述形成方法改善鳍部110底部漏电流、短沟道效应的效果更为显著。By making the ion doping concentration in the top source-drain doping layer 132 larger, it is beneficial to make the overall doping concentration of the source-drain doping layer 130 meet electrical requirements. Moreover, by making the doping concentration in the bottom source-drain doped layer 131 smaller, and the top source-drain doped layer 132 only covering the sidewalls of the bottom source-drain doped layer 131 exposed by the sidewall layer 125, the top source-drain doped layer 131 is The probability that the doped ions in the layer 132 will diffuse into the bottom of the fin portion 110 is low, which is conducive to making the formation method more effective in improving the leakage current and short channel effect at the bottom of the fin portion 110 .
此外,与仅形成底部源漏掺杂层的方案相比,本实施例通过所述顶部源漏掺杂层132,增大了源漏掺杂层130的表面积,从而增大了后续与源漏掺杂层130电连接的接触孔插塞和源漏掺杂层130的接触面积,且所述顶部源漏掺杂层132的浓度较大,因此有利于降低所述接触孔插塞和所述源漏掺杂层130的接触电阻,提升了半导体结构的电学性能。In addition, compared with the solution of only forming the bottom source-drain doped layer, this embodiment increases the surface area of the source-drain doped layer 130 through the top source-drain doped layer 132, thereby increasing the subsequent connection with the source-drain doped layer. The contact area of the contact hole plug and the source-drain doped layer 130 that the doped layer 130 is electrically connected to, and the concentration of the top source-drain doped layer 132 is relatively large, which is beneficial to reducing the contact hole plug and the The contact resistance of the source-drain doped layer 130 improves the electrical performance of the semiconductor structure.
具体地,形成顶部源漏掺杂层132的步骤包括:在剩余所述侧壁层125露出的底部源漏掺杂层131表面进行外延生长,形成外延层(图未示);在所述外延层内掺杂离子,形成顶部源漏掺杂层132。Specifically, the step of forming the top source-drain doped layer 132 includes: performing epitaxial growth on the surface of the bottom source-drain doped layer 131 where the remaining sidewall layer 125 is exposed, to form an epitaxial layer (not shown); Ions are doped into the layer to form a top source-drain doped layer 132.
通过在形成外延层后,进行离子掺杂,有利于精确控制所述顶部源漏掺杂层132中的离子掺杂浓度。By performing ion doping after forming the epitaxial layer, it is beneficial to accurately control the ion doping concentration in the top source-drain doping layer 132 .
本实施例中,采用固态源扩散工艺在所述外延层内掺杂离子。固态源扩散工艺对外延层产生的损伤较小,而且有利于在外延层表面形成较高的掺杂浓度,有利于进一步降低后续接触孔插塞和源漏掺杂层130的接触电阻。In this embodiment, a solid-state source diffusion process is used to dope ions in the epitaxial layer. The solid-state source diffusion process causes less damage to the epitaxial layer, and is conducive to forming a higher doping concentration on the surface of the epitaxial layer, which is conducive to further reducing the contact resistance of subsequent contact hole plugs and the source-drain doped layer 130 .
在其他实施例中,形成所述顶部源漏掺杂层的步骤还可以包括:在剩余所述侧壁层露出的底部源漏掺杂层表面进行外延生长,形成外延层,且在形成所述外延层的过程中原位自掺杂离子形成所述顶部源漏掺杂层In other embodiments, the step of forming the top source and drain doped layer may further include: performing epitaxial growth on the surface of the bottom source and drain doped layer where the remaining sidewall layer is exposed, forming an epitaxial layer, and forming the During the epitaxial layer process, in-situ self-doping ions form the top source and drain doped layer.
因此,本实施例中,所述半导体结构用于形成NMOS晶体管,顶部源漏掺杂层132也包括掺杂有N型离子的外延层,外延层的材料可以为Si或SiC,从而为NMOS晶体管的沟道区提供拉应力作用,有利于提高NMOS晶体管的载流子迁移率,其中,所述N型离子为P离子、As离子或Sb离子。在其他实施例中,所述半导体结构用于形成PMOS晶体管时,顶部源漏掺杂层包括掺杂有P型离子的外延层,外延层的材料可以为Si或SiGe,外延层为PMOS晶体管的沟道区提供压应力作用,从而有利于提高PMOS晶体管的载流子迁移率,其中,所述P型离子为B离子、Ga离子或In离子。Therefore, in this embodiment, the semiconductor structure is used to form an NMOS transistor. The top source-drain doped layer 132 also includes an epitaxial layer doped with N-type ions. The material of the epitaxial layer can be Si or SiC, thereby forming an NMOS transistor. The channel region provides tensile stress, which is beneficial to improving the carrier mobility of the NMOS transistor, wherein the N-type ions are P ions, As ions or Sb ions. In other embodiments, when the semiconductor structure is used to form a PMOS transistor, the top source-drain doping layer includes an epitaxial layer doped with P-type ions. The material of the epitaxial layer can be Si or SiGe. The epitaxial layer is of the PMOS transistor. The channel region provides compressive stress, which is beneficial to improving the carrier mobility of the PMOS transistor, wherein the P-type ions are B ions, Ga ions or In ions.
需要说明的是,所述顶部源漏掺杂层132中的离子掺杂浓度不宜过低,也不宜过高。如果顶部源漏掺杂层132中的离子掺杂浓度过低,容易使源漏掺杂层130的总体掺杂浓度难以满足电性需求,例如,半导体结构的载流子迁移率过低、接触孔插塞与所述源漏掺杂层130的接触电阻过大等;如果顶部源漏掺杂层132中的离子掺杂浓度过高,则顶部源漏掺杂层132中的掺杂离子向沟道区扩散的概率较大,不利于改善半导体结构的短沟道效应。为此,本实施例中,所述半导体结构用于形成NMOS晶体管,所述顶部源漏掺杂层132中掺杂有N型离子,所述N型离子的掺杂浓度为5.0E20原子每立方厘米至1.0E22原子每立方厘米。在其他实施例中,所述半导体结构用于形成PMOS晶体管时,所述顶部源漏掺杂层中掺杂有P型离子,所述P型离子的掺杂浓度为1.2E20原子每立方厘米至8.0E21原子每立方厘米。It should be noted that the ion doping concentration in the top source-drain doped layer 132 should not be too low, nor should it be too high. If the ion doping concentration in the top source-drain doped layer 132 is too low, it is easy to make it difficult for the overall doping concentration of the source-drain doped layer 130 to meet the electrical requirements. For example, the carrier mobility of the semiconductor structure is too low, the contact The contact resistance between the hole plug and the source-drain doped layer 130 is too large; if the ion doping concentration in the top source-drain doped layer 132 is too high, the doped ions in the top source-drain doped layer 132 will move toward The probability of diffusion in the channel region is high, which is not conducive to improving the short channel effect of the semiconductor structure. To this end, in this embodiment, the semiconductor structure is used to form an NMOS transistor, and the top source-drain doping layer 132 is doped with N-type ions. The doping concentration of the N-type ions is 5.0E20 atoms per cubic cm to 1.0E22 atoms per cubic centimeter. In other embodiments, when the semiconductor structure is used to form a PMOS transistor, the top source-drain doping layer is doped with P-type ions, and the doping concentration of the P-type ions is 1.2E20 atoms per cubic centimeter to 8.0E21 atoms per cubic centimeter.
还需要说明的是,所述顶部源漏掺杂层132的体积不宜过小,也不宜过大。如果顶部源漏掺杂层132的体积过小,则源漏掺杂层130中的应力过小,半导体结构的载流子迁移率较低;如果顶部源漏掺杂层132的体积过大,容易导致源漏掺杂层130上的寄生电容过大。为此,本实施例中,位于底部源漏掺杂层131顶部的顶部源漏掺杂层132厚度为3nm至10nm,位于底部源漏掺杂层131侧壁上的顶部源漏掺杂层132厚度为2nm至6nm,从而使顶部源漏掺杂层132的体积满足工艺需求。It should also be noted that the volume of the top source-drain doped layer 132 should not be too small, nor should it be too large. If the volume of the top source-drain doped layer 132 is too small, the stress in the source-drain doped layer 130 is too small, and the carrier mobility of the semiconductor structure is low; if the volume of the top source-drain doped layer 132 is too large, It is easy to cause the parasitic capacitance on the source-drain doped layer 130 to be too large. For this reason, in this embodiment, the thickness of the top source-drain doped layer 132 located on the top of the bottom source-drain doped layer 131 is 3 nm to 10 nm, and the top source-drain doped layer 132 located on the sidewall of the bottom source-drain doped layer 131 has a thickness of 3 nm to 10 nm. The thickness is 2 nm to 6 nm, so that the volume of the top source and drain doped layer 132 meets the process requirements.
具体地,本实施例中,所述顶部源漏掺杂层132的侧壁与剩余所述侧壁层125的侧壁相齐平,有利于精确控制所述顶部源漏掺杂层132在底部源漏掺杂层131侧壁上的厚度,降低工艺难度。其中,所述顶部源漏掺杂层132的侧壁指的是顶部源漏掺杂层132不与底部源漏掺杂层131相接触的侧壁。Specifically, in this embodiment, the sidewalls of the top source-drain doped layer 132 are flush with the sidewalls of the remaining sidewall layers 125, which is conducive to precise control of the top source-drain doped layer 132 at the bottom. The thickness on the sidewalls of the source and drain doped layer 131 reduces process difficulty. The sidewalls of the top source-drain doped layer 132 refer to the sidewalls of the top source-drain doped layer 132 that are not in contact with the bottom source-drain doped layer 131 .
结合参考图20,本实施例中,形成所述顶部源漏掺杂层132之后,还包括:去除侧壁层125;去除侧壁层125后,形成与所述源漏掺杂层130电连接的接触孔插塞135,所述接触孔插塞135覆盖源漏掺杂层130的顶部与侧壁。Referring to FIG. 20 , in this embodiment, after forming the top source-drain doped layer 132 , it also includes: removing the sidewall layer 125 ; after removing the sidewall layer 125 , forming an electrical connection with the source-drain doped layer 130 The contact hole plug 135 covers the top and side walls of the source and drain doped layer 130 .
本实施例中,所述源漏掺杂层130包括底部源漏掺杂层131以及覆盖其顶部和部分侧壁的顶部源漏掺杂层132,源漏掺杂层130的表面积较大,因此接触孔插塞135与源漏掺杂层130的接触面积也较大,两者之间的接触电阻较小,而且,顶部源漏掺杂层132的离子掺杂浓度较大,能够进一步减小源漏掺杂层130与接触孔插塞135的接触电阻,优化了半导体结构的电学性能。In this embodiment, the source-drain doped layer 130 includes a bottom source-drain doped layer 131 and a top source-drain doped layer 132 covering its top and part of the sidewalls. The surface area of the source-drain doped layer 130 is large, so The contact area between the contact hole plug 135 and the source-drain doped layer 130 is also large, and the contact resistance between the two is small. Moreover, the ion doping concentration of the top source-drain doped layer 132 is large, which can further reduce The contact resistance between the source-drain doped layer 130 and the contact hole plug 135 optimizes the electrical performance of the semiconductor structure.
通过去除所述侧壁层125,从而为形成所述接触孔插塞135提供工艺平台。By removing the sidewall layer 125 , a process platform is provided for forming the contact hole plug 135 .
所述接触孔插塞135用于源漏掺杂层130与后端金属层、以及外部电路的电连接。本实施例中,所述接触孔插塞135的材料为W,可以采用化学气相沉积、溅射或电镀的方式形成。在其他实施例中,所述接触孔插塞的材料还可以是Al、Cu、Ag、Au或Co等金属材料。The contact hole plug 135 is used for electrical connection between the source and drain doped layer 130, the back-end metal layer, and external circuits. In this embodiment, the contact hole plug 135 is made of W and can be formed by chemical vapor deposition, sputtering or electroplating. In other embodiments, the material of the contact hole plug may also be a metal material such as Al, Cu, Ag, Au or Co.
具体地,形成所述接触孔插塞135的步骤包括:在所述栅极结构114露出的衬底100上形成层间介质层137;在层间介质层137内形成接触孔(图未示),所述接触孔露出源漏掺杂层130的顶部和侧壁;在接触孔内填充导电材料,形成接触孔插塞135。Specifically, the steps of forming the contact hole plug 135 include: forming an interlayer dielectric layer 137 on the substrate 100 where the gate structure 114 is exposed; forming a contact hole (not shown) in the interlayer dielectric layer 137 , the contact hole exposes the top and sidewalls of the source-drain doped layer 130; the contact hole is filled with conductive material to form a contact hole plug 135.
需要说明的是,本实施例中,所述接触孔插塞135和所述源漏掺杂层130之间还形成有硅化物层136,从而有利于进一步降低所述接触孔插塞135和所述源漏掺杂层130之间的接触电阻。It should be noted that in this embodiment, a silicide layer 136 is also formed between the contact hole plug 135 and the source and drain doped layer 130, which is beneficial to further reducing the contact hole plug 135 and the source and drain doped layer 130. The contact resistance between the source and drain doped layers 130.
相应的,本发明还提供一种半导体结构。参考图20,示出了本发明半导体结构一实施例的结构示意图。Correspondingly, the present invention also provides a semiconductor structure. Referring to FIG. 20 , a schematic structural diagram of an embodiment of the semiconductor structure of the present invention is shown.
所述半导体结构包括:衬底100;鳍部110,凸出于所述衬底100;栅极结构114(如图14所示),横跨所述鳍部110且覆盖所述鳍部110的部分顶部和部分侧壁;源漏掺杂层130,位于所述栅极结构114两侧的鳍部110内,所述源漏掺杂层130包括底部源漏掺杂层131和覆盖所述底部源漏掺杂层131顶部和部分侧壁的顶部源漏掺杂层132,所述顶部源漏掺杂层132和底部源漏掺杂层131中的掺杂离子类型相同,且所述顶部源漏掺杂层132中的离子掺杂浓度大于底部源漏掺杂层131的离子掺杂浓度。The semiconductor structure includes: a substrate 100; a fin portion 110 protruding from the substrate 100; a gate structure 114 (as shown in FIG. 14) spanning the fin portion 110 and covering the fin portion 110. Part of the top and part of the sidewall; the source-drain doped layer 130 is located in the fins 110 on both sides of the gate structure 114. The source-drain doped layer 130 includes a bottom source-drain doped layer 131 and covers the bottom. The top source-drain doped layer 132 on the top of the source-drain doped layer 131 and part of the sidewalls, the doping ion types in the top source-drain doped layer 132 and the bottom source-drain doped layer 131 are the same, and the top source-drain doped layer 132 The ion doping concentration in the drain doped layer 132 is greater than the ion doping concentration of the bottom source and drain doped layer 131 .
本实施例中源漏掺杂层130包括底部源漏掺杂层131以及覆盖其顶部和部分侧壁的顶部源漏掺杂层132,顶部源漏掺杂层132中离子的掺杂浓度大于底部源漏掺杂层131中离子的掺杂浓度,为了使源漏掺杂层130的总体掺杂浓度能够满足电性需求,与仅形成所述底部源漏掺杂层且使底部源漏掺杂层中的离子掺杂浓度较高的方案相比,本实施例可适当降低底部源漏掺杂层131中的离子掺杂浓度,这有利于降低所述底部源漏掺杂层131中掺杂离子向沟道区扩散的概率,从而有利于改善短沟道效应。In this embodiment, the source-drain doped layer 130 includes a bottom source-drain doped layer 131 and a top source-drain doped layer 132 covering its top and part of the sidewalls. The doping concentration of ions in the top source-drain doped layer 132 is greater than that of the bottom one. The doping concentration of ions in the source-drain doped layer 131, in order to make the overall doping concentration of the source-drain doped layer 130 meet the electrical requirements, is different from only forming the bottom source-drain doped layer and doping the bottom source-drain layer. Compared with the solution with a higher ion doping concentration in the layer, this embodiment can appropriately reduce the ion doping concentration in the bottom source-drain doping layer 131, which is beneficial to reducing the doping in the bottom source-drain doping layer 131. The probability of ions diffusing to the channel region is beneficial to improving the short channel effect.
而且,反型层通常形成在靠近鳍部110顶部的区域内以形成导电沟道,栅极结构114对鳍部110底部的控制能力较弱,鳍部110底部内形成反型层的概率较低,鳍部110底部产生漏电流、短沟道效应等问题的概率较高,与所述底部源漏掺杂层的全部侧壁均被顶部源漏掺杂层覆盖的方案相比,本实施例中,所述底部源漏掺杂层131的底部未被顶部源漏掺杂层132覆盖,有利于进一步改善短沟道效应,降低鳍部110底部内产生漏电流问题的概率。Moreover, the inversion layer is usually formed in an area close to the top of the fin 110 to form a conductive channel. The gate structure 114 has weak control over the bottom of the fin 110 and the probability of forming an inversion layer in the bottom of the fin 110 is low. , the probability of problems such as leakage current and short channel effect at the bottom of the fin 110 is relatively high. Compared with the solution in which all sidewalls of the bottom source-drain doped layer are covered by the top source-drain doped layer, this embodiment , the bottom of the bottom source-drain doped layer 131 is not covered by the top source-drain doped layer 132 , which is beneficial to further improving the short channel effect and reducing the probability of leakage current problems in the bottom of the fin 110 .
此外,与仅形成底部源漏掺杂层的方案相比,本实施例通过所述顶部源漏掺杂层132,增大了源漏掺杂层130的表面积,从而增大了后续与源漏掺杂层130电连接的接触孔插塞和源漏掺杂层130的接触面积,且所述顶部源漏掺杂层132的浓度较大,因此有利于降低接触孔插塞和所述源漏掺杂层130的接触电阻,提升了半导体结构的电学性能。In addition, compared with the solution of only forming the bottom source-drain doped layer, this embodiment increases the surface area of the source-drain doped layer 130 through the top source-drain doped layer 132, thereby increasing the subsequent connection with the source-drain doped layer. The contact area of the contact hole plug and the source-drain doped layer 130 that is electrically connected to the doped layer 130, and the concentration of the top source-drain doped layer 132 is relatively large, which is beneficial to reducing the contact hole plug and the source-drain doped layer 130. The contact resistance of the doped layer 130 improves the electrical performance of the semiconductor structure.
所述衬底100用于为半导体结构的形成提供工艺平台。The substrate 100 is used to provide a process platform for the formation of semiconductor structures.
本实施例中,所述衬底100为硅衬底。在其他实施例中,所述衬底的材料还可以为锗、锗化硅、碳化硅、砷化镓或镓化铟等其他材料,所述衬底还可以为绝缘体上的硅衬底或者绝缘体上的锗衬底等其他类型的衬底。In this embodiment, the substrate 100 is a silicon substrate. In other embodiments, the material of the substrate can also be other materials such as germanium, silicon germanium, silicon carbide, gallium arsenide or indium gallium. The substrate can also be a silicon substrate on an insulator or an insulator. on germanium substrates and other types of substrates.
所述鳍部110用于提供鳍式场效应晶体管的导电沟道。The fin portion 110 is used to provide a conductive channel of the fin field effect transistor.
本实施例中,所述鳍部110与所述衬底100由对同一半导体层进行刻蚀所得到。在其他实施例中,所述鳍部也可以是外延生长于所述衬底上的半导体层,从而达到精确控制所述鳍部高度的目的。In this embodiment, the fin portion 110 and the substrate 100 are obtained by etching the same semiconductor layer. In other embodiments, the fin portion may also be a semiconductor layer grown epitaxially on the substrate, thereby achieving the purpose of accurately controlling the height of the fin portion.
因此,本实施例中,所述鳍部110的材料与所述衬底100的材料相同,所述鳍部110的材料为硅。其他实施例中,所述鳍部的材料还可以是锗、锗化硅、碳化硅、砷化镓或镓化铟。Therefore, in this embodiment, the material of the fin portion 110 is the same as the material of the substrate 100 , and the material of the fin portion 110 is silicon. In other embodiments, the material of the fins may also be germanium, silicon germanium, silicon carbide, gallium arsenide or indium gallium.
需要说明的是,所述半导体结构还包括:隔离层111,位于所述鳍部110露出的衬底100上且覆盖所述鳍部110的部分侧壁。所述隔离层111用于对相邻器件之间起到电隔离作用。It should be noted that the semiconductor structure further includes an isolation layer 111 located on the substrate 100 where the fin 110 is exposed and covering part of the sidewall of the fin 110 . The isolation layer 111 is used to electrically isolate adjacent devices.
本实施例中,隔离层111的材料为氧化硅。在其他实施例中,隔离层的材料还可以为氮化硅、氮氧化硅、碳氧化硅、碳氮化硅或碳氮氧化硅等绝缘材料。In this embodiment, the material of the isolation layer 111 is silicon oxide. In other embodiments, the material of the isolation layer may also be an insulating material such as silicon nitride, silicon oxynitride, silicon oxycarbide, silicon carbonitride, or silicon oxycarboxynitride.
所述栅极结构114包括栅氧化层112(如图14所示)以及位于所述栅氧化层112上的栅极层113(如图14所示)。The gate structure 114 includes a gate oxide layer 112 (shown in FIG. 14 ) and a gate layer 113 (shown in FIG. 14 ) located on the gate oxide layer 112 .
栅氧化层112的材料为氧化硅或氮氧化硅,栅极层113的材料为多晶硅、氧化硅、氮化硅、氮氧化硅、碳化硅、碳氮化硅、碳氮氧化硅或非晶碳。本实施例中,栅氧化层112的材料为氧化硅,栅极层113的材料为多晶硅。The material of the gate oxide layer 112 is silicon oxide or silicon oxynitride, and the material of the gate layer 113 is polysilicon, silicon oxide, silicon nitride, silicon oxynitride, silicon carbide, silicon carbonitride, silicon oxynitride or amorphous carbon. . In this embodiment, the material of the gate oxide layer 112 is silicon oxide, and the material of the gate layer 113 is polysilicon.
在其他实施例中,所述栅极结构还可以为金属栅极结构。In other embodiments, the gate structure may also be a metal gate structure.
本实施例中,所述栅氧化层112仅位于所述栅极层113底部。在其他实施例中,所述栅氧化层还可以覆盖所述栅极层露出的鳍部表面。In this embodiment, the gate oxide layer 112 is only located at the bottom of the gate layer 113 . In other embodiments, the gate oxide layer may also cover the exposed fin surface of the gate layer.
本实施例中,所述栅极结构114顶部还形成有衬垫氧化层115(如图14所示)、以及位于所述衬垫氧化层115上的栅极掩膜层116(如图14所示)。In this embodiment, a pad oxide layer 115 (as shown in FIG. 14 ) and a gate mask layer 116 (as shown in FIG. 14 ) located on the pad oxide layer 115 are also formed on the top of the gate structure 114 . Show).
所述栅极掩膜层116用于作为形成所述栅极层113的刻蚀掩膜,所述栅极掩膜层116还用于在半导体结构的形成过程中保护所述栅极层113顶部。本实施例中,所述栅极掩膜层116的材料为氮化硅。The gate mask layer 116 is used as an etching mask to form the gate layer 113. The gate mask layer 116 is also used to protect the top of the gate layer 113 during the formation process of the semiconductor structure. . In this embodiment, the gate mask layer 116 is made of silicon nitride.
所述衬垫氧化层115用于在形成栅极掩膜层116、以及以所述栅极掩膜层116为掩膜形成栅极层113时起到应力缓冲的作用,提高所述栅极掩膜层116和栅极层113之间的粘附性,避免栅极掩膜层116与栅极层113直接接触产生位错的问题。本实施例中,所述衬垫氧化层115的材料为氧化硅。The pad oxide layer 115 is used to play a stress buffering role when forming the gate mask layer 116 and using the gate mask layer 116 as a mask to form the gate layer 113, thereby improving the gate mask layer. The adhesion between the film layer 116 and the gate layer 113 avoids the problem of dislocation caused by direct contact between the gate mask layer 116 and the gate layer 113 . In this embodiment, the material of the pad oxide layer 115 is silicon oxide.
如图14所示,所述半导体结构还包括:第一侧墙118,位于所述栅极层113、衬垫氧化层115和栅极掩膜层116的侧壁上;第二侧墙119,位于所述第一侧墙118的侧壁上。As shown in Figure 14, the semiconductor structure also includes: a first spacer 118 located on the sidewalls of the gate layer 113, the pad oxide layer 115 and the gate mask layer 116; a second spacer 119, Located on the side wall of the first side wall 118 .
所述第一侧墙118用于在半导体结构的形成过程中对栅极层113的侧壁起到保护作用。本实施例中,第一侧墙118的材料为氮化硅。在其他实施例中,第一侧墙的材料还能够为氧化硅、氮氧化硅、碳化硅、碳氧化硅或碳氮氧化硅。The first spacers 118 are used to protect the sidewalls of the gate layer 113 during the formation process of the semiconductor structure. In this embodiment, the material of the first spacer 118 is silicon nitride. In other embodiments, the material of the first sidewall can also be silicon oxide, silicon oxynitride, silicon carbide, silicon oxycarbide or silicon oxynitride.
所述第二侧墙119也用于在半导体结构的形成过程中保护栅极层113的侧壁,第二侧墙119还用于定义源漏掺杂层130沿鳍部110延伸方向的形成区域。The second spacers 119 are also used to protect the sidewalls of the gate layer 113 during the formation of the semiconductor structure. The second spacers 119 are also used to define the formation area of the source and drain doped layers 130 along the extension direction of the fins 110 .
本实施例中,所述第二侧墙119与所述侧壁层125的材料相同,所述第二侧墙119的材料为氮化硅。在其他实施例中,所述第二侧墙的材料还能够为氧化硅、氮氧化硅、碳化硅、碳氧化硅或碳氮氧化硅。In this embodiment, the second spacer 119 and the sidewall layer 125 are made of the same material, and the second spacer 119 is made of silicon nitride. In other embodiments, the material of the second side wall can also be silicon oxide, silicon oxynitride, silicon carbide, silicon oxycarbon or silicon oxynitride.
本实施例中,所述半导体结构用于形成NMOS晶体管,底部源漏掺杂层131和顶部源漏掺杂层132均包括掺杂有N型离子的外延层,外延层的材料可以为Si或SiC,从而为NMOS晶体管的沟道区提供拉应力作用,有利于提高NMOS晶体管的载流子迁移率,其中,N型离子为P离子、As离子或Sb离子。在其他实施例中,所述半导体结构用于形成PMOS晶体管时,底部源漏掺杂层和顶部源漏掺杂层包括掺杂有P型离子的外延层,外延层的材料可以为Si或SiGe,从而为PMOS晶体管的沟道区提供压应力作用,从而有利于提高PMOS晶体管的载流子迁移率,其中,P型离子为B离子、Ga离子或In离子。In this embodiment, the semiconductor structure is used to form an NMOS transistor. The bottom source-drain doped layer 131 and the top source-drain doped layer 132 both include an epitaxial layer doped with N-type ions. The material of the epitaxial layer can be Si or SiC, thereby providing tensile stress to the channel region of the NMOS transistor, which is beneficial to improving the carrier mobility of the NMOS transistor. Among them, the N-type ions are P ions, As ions or Sb ions. In other embodiments, when the semiconductor structure is used to form a PMOS transistor, the bottom source-drain doping layer and the top source-drain doping layer include an epitaxial layer doped with P-type ions, and the material of the epitaxial layer can be Si or SiGe. , thereby providing compressive stress to the channel region of the PMOS transistor, which is beneficial to improving the carrier mobility of the PMOS transistor, where the P-type ions are B ions, Ga ions or In ions.
需要说明的是,本实施例中,所述底部源漏掺杂层131中的离子掺杂浓度不宜过低,也不宜过高。如果底部源漏掺杂层131中的离子掺杂浓度过低,容易使源漏掺杂层130的总体掺杂浓度难以满足电性需求;如果底部源漏掺杂层131中的离子掺杂浓度过高,底部源漏掺杂层131中掺杂离子向沟道区扩散的概率较大,不利于改善半导体结构的短沟道效应。为此,本实施例中,所述半导体结构用于形成NMOS晶体管,底部源漏掺杂层131中掺杂有N型离子,所述N型离子的掺杂浓度为3.0E20原子每立方厘米至8.0E21原子每立方厘米。在其他实施例中,所述半导体结构用于形成NMOS晶体管时,底部源漏掺杂层中掺杂有P型离子,所述P型离子的掺杂浓度为1.0E20原子每立方厘米至4.0E20原子每立方厘米。It should be noted that in this embodiment, the ion doping concentration in the bottom source-drain doped layer 131 should not be too low, nor should it be too high. If the ion doping concentration in the bottom source-drain doping layer 131 is too low, it is easy for the overall doping concentration of the source-drain doping layer 130 to meet the electrical requirements; if the ion doping concentration in the bottom source-drain doping layer 131 If it is too high, the probability of doping ions in the bottom source-drain doping layer 131 to diffuse to the channel region is high, which is not conducive to improving the short channel effect of the semiconductor structure. To this end, in this embodiment, the semiconductor structure is used to form an NMOS transistor, and the bottom source-drain doping layer 131 is doped with N-type ions. The doping concentration of the N-type ions is 3.0E20 atoms per cubic centimeter to 8.0E21 atoms per cubic centimeter. In other embodiments, when the semiconductor structure is used to form an NMOS transistor, the bottom source-drain doping layer is doped with P-type ions, and the doping concentration of the P-type ions is 1.0E20 atoms per cubic centimeter to 4.0E20 atoms per cubic centimeter.
还需要说明的是,所述顶部源漏掺杂层132中的离子掺杂浓度不宜过低,也不宜过高。如果顶部源漏掺杂层132中的离子掺杂浓度过低,源漏掺杂层130的总体掺杂浓度也难以满足电性需求,例如,半导体结构的载流子迁移率过低、接触孔插塞与所述源漏掺杂层130的接触电阻过大等;如果顶部源漏掺杂层132中的离子掺杂浓度过高,则顶部源漏掺杂层132中的掺杂离子向沟道区扩散的概率较大。为此,本实施例中,所述半导体结构用于形成NMOS晶体管,所述顶部源漏掺杂层132中掺杂有N型离子,所述N型离子的掺杂浓度为5.0E20原子每立方厘米至1.0E22原子每立方厘米。在其他实施例中,所述半导体结构用于形成PMOS晶体管时,所述顶部源漏掺杂层中掺杂有P型离子,所述P型离子的掺杂浓度为1.2E20原子每立方厘米至8.0E21原子每立方厘米。It should also be noted that the ion doping concentration in the top source-drain doped layer 132 should not be too low or too high. If the ion doping concentration in the top source-drain doped layer 132 is too low, the overall doping concentration of the source-drain doped layer 130 is difficult to meet the electrical requirements. For example, the carrier mobility of the semiconductor structure is too low, the contact hole The contact resistance between the plug and the source-drain doped layer 130 is too large, etc.; if the ion doping concentration in the top source-drain doped layer 132 is too high, the doped ions in the top source-drain doped layer 132 will flow into the trench. The probability of spreading in the road area is relatively high. To this end, in this embodiment, the semiconductor structure is used to form an NMOS transistor, and the top source-drain doping layer 132 is doped with N-type ions. The doping concentration of the N-type ions is 5.0E20 atoms per cubic cm to 1.0E22 atoms per cubic centimeter. In other embodiments, when the semiconductor structure is used to form a PMOS transistor, the top source-drain doping layer is doped with P-type ions, and the doping concentration of the P-type ions is 1.2E20 atoms per cubic centimeter to 8.0E21 atoms per cubic centimeter.
此外,所述顶部源漏掺杂层132的体积不宜过小,也不宜过大。如果所述顶部源漏掺杂层132的体积过小,则所述源漏掺杂层130中的应力过小,半导体结构的载流子迁移率较低;如果所述顶部源漏掺杂层132的体积过大,则容易导致所述源漏掺杂层130上的寄生电容过大。为此,本实施例中,位于所述底部源漏掺杂层131顶部的顶部源漏掺杂层132厚度为3nm至10nm,位于所述底部源漏掺杂层131侧壁上的顶部源漏掺杂层132厚度为2nm至6nm。In addition, the volume of the top source-drain doped layer 132 should not be too small or too large. If the volume of the top source-drain doped layer 132 is too small, the stress in the source-drain doped layer 130 is too small, and the carrier mobility of the semiconductor structure is low; if the top source-drain doped layer 132 If the volume of 132 is too large, the parasitic capacitance on the source-drain doped layer 130 may be too large. For this reason, in this embodiment, the thickness of the top source-drain doped layer 132 located on the top of the bottom source-drain doped layer 131 is 3 nm to 10 nm, and the top source-drain doped layer 132 located on the side wall of the bottom source-drain doped layer 131 has a thickness of 3 nm to 10 nm. The thickness of the doping layer 132 is 2nm to 6nm.
本实施例中,所述顶部源漏掺杂层132露出的底部源漏掺杂层131的高度不宜过小,也不宜过大。如果所述高度过小,则所述顶部源漏掺杂层132过于靠近鳍部110底部,顶部源漏掺杂层132中的掺杂离子向鳍部110底部内扩散的概率较高,不利于改善所述半导体结构的短沟道效应;如果所述高度过大,则所述顶部源漏掺杂层132的体积和表面积相应过小,容易使所述源漏掺杂层130的总体掺杂浓度难以满足电性需求,例如,顶部源漏掺杂层132与后续接触孔插塞的接触面积过小,从而使源漏掺杂层130与接触孔插塞的接触电阻过大,而且,所述顶部源漏掺杂层132的体积过小还容易导致源漏掺杂层130中的应力过小,不利于提高半导体结构的载流子迁移率。为此,本实施例中,所述顶部源漏掺杂层132露出的底部源漏掺杂层131的高度为15nm至25nm。In this embodiment, the height of the bottom source-drain doped layer 131 exposed by the top source-drain doped layer 132 should not be too small, nor should it be too large. If the height is too small, the top source-drain doped layer 132 is too close to the bottom of the fin 110 , and the doping ions in the top source-drain doped layer 132 have a higher probability of diffusing into the bottom of the fin 110 , which is not conducive to Improve the short channel effect of the semiconductor structure; if the height is too large, the volume and surface area of the top source-drain doped layer 132 will be too small, which will easily cause the overall doping of the source-drain doped layer 130 to The concentration is difficult to meet the electrical requirements. For example, the contact area between the top source-drain doped layer 132 and subsequent contact hole plugs is too small, so that the contact resistance between the source-drain doped layer 130 and the contact hole plugs is too large, and so If the volume of the top source-drain doped layer 132 is too small, it will easily cause the stress in the source-drain doped layer 130 to be too small, which is not conducive to improving the carrier mobility of the semiconductor structure. For this reason, in this embodiment, the height of the bottom source-drain doped layer 131 exposed by the top source-drain doped layer 132 is 15 nm to 25 nm.
如图20所示,本实施例中,所述半导体结构还包括:接触孔插塞135,与源漏掺杂层130电连接,接触孔插塞135覆盖源漏掺杂层130的顶部与侧壁。As shown in Figure 20, in this embodiment, the semiconductor structure further includes: a contact hole plug 135, which is electrically connected to the source and drain doped layer 130. The contact hole plug 135 covers the top and sides of the source and drain doped layer 130. wall.
本实施例中,所述源漏掺杂层130包括底部源漏掺杂层131、以及覆盖其顶部和部分侧壁的顶部源漏掺杂层132,源漏掺杂层130的表面积较大,因此接触孔插塞135与源漏掺杂层130的接触面积也较大,两者之间的接触电阻较小,而且,顶部源漏掺杂层132的离子掺杂浓度较大,能够进一步减小所述源漏掺杂层130与接触孔插塞135的接触电阻,优化了半导体结构的电学性能。In this embodiment, the source-drain doped layer 130 includes a bottom source-drain doped layer 131 and a top source-drain doped layer 132 covering its top and part of the sidewalls. The surface area of the source-drain doped layer 130 is relatively large. Therefore, the contact area between the contact hole plug 135 and the source-drain doped layer 130 is also larger, and the contact resistance between the two is smaller. Moreover, the ion doping concentration of the top source-drain doped layer 132 is larger, which can further reduce the The contact resistance between the source-drain doped layer 130 and the contact hole plug 135 is reduced, thereby optimizing the electrical performance of the semiconductor structure.
所述接触孔插塞135用于源漏掺杂层130与后端金属层、以及外部电路的电连接。本实施例中,所述接触孔插塞135的材料为W。在其他实施例中,所述接触孔插塞的材料还可以是Al、Cu、Ag、Au或Co等金属材料。The contact hole plug 135 is used for electrical connection between the source and drain doped layer 130, the back-end metal layer, and external circuits. In this embodiment, the material of the contact hole plug 135 is W. In other embodiments, the material of the contact hole plug may also be a metal material such as Al, Cu, Ag, Au or Co.
需要说明的是,本实施例中,所述半导体结构还包括:硅化物层136,位于所述接触孔插塞135和所述源漏掺杂层130之间。所述硅化物层136用于进一步降低所述接触孔插塞135和源漏掺杂层130之间的接触电阻。It should be noted that in this embodiment, the semiconductor structure further includes: a silicide layer 136 located between the contact hole plug 135 and the source and drain doping layer 130 . The silicide layer 136 is used to further reduce the contact resistance between the contact hole plug 135 and the source-drain doped layer 130 .
此外,所述半导体结构还包括:层间介质层137,位于所述栅极结构114露出的衬底100上。In addition, the semiconductor structure further includes: an interlayer dielectric layer 137 located on the substrate 100 where the gate structure 114 is exposed.
所述层间介质层137用于为接触孔插塞135的形成提供工艺平台,层间介质层137还用于隔离相邻器件,层间介质层137的材料为绝缘材料,例如氧化硅、氮化硅、氮氧化硅、碳氧化硅、碳氮化硅和碳氮氧化硅中的一种或多种。The interlayer dielectric layer 137 is used to provide a process platform for the formation of the contact hole plug 135. The interlayer dielectric layer 137 is also used to isolate adjacent devices. The material of the interlayer dielectric layer 137 is an insulating material, such as silicon oxide, nitrogen. One or more of silicon nitride, silicon oxynitride, silicon oxycarbide, silicon carbonitride and silicon oxynitride.
所述半导体结构可以采用前述实施例所述的形成方法所形成,也可以采用其他形成方法所形成。对本实施例所述半导体结构的具体描述,可参考前述实施例中的相应描述,本实施例在此不再赘述。The semiconductor structure may be formed using the forming method described in the previous embodiment, or may be formed using other forming methods. For the specific description of the semiconductor structure described in this embodiment, reference may be made to the corresponding description in the foregoing embodiments, which will not be described again in this embodiment.
虽然本发明披露如上,但本发明并非限定于此。任何本领域技术人员,在不脱离本发明的精神和范围内,均可作各种更动与修改,因此本发明的保护范围应当以权利要求所限定的范围为准。Although the present invention is disclosed as above, the present invention is not limited thereto. Any person skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention should be subject to the scope defined by the claims.
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