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CN111334705A - High-strength pearlite antifriction cast iron and preparation method and application thereof - Google Patents

High-strength pearlite antifriction cast iron and preparation method and application thereof Download PDF

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Publication number
CN111334705A
CN111334705A CN202010265183.5A CN202010265183A CN111334705A CN 111334705 A CN111334705 A CN 111334705A CN 202010265183 A CN202010265183 A CN 202010265183A CN 111334705 A CN111334705 A CN 111334705A
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China
Prior art keywords
cast iron
strength
cylinder sleeve
temperature
blank
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Pending
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CN202010265183.5A
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Chinese (zh)
Inventor
侯起飞
秦小才
邹悟会
王勇
徐超
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ZYNP Corp
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ZYNP Corp
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Priority to CN202010265183.5A priority Critical patent/CN111334705A/en
Publication of CN111334705A publication Critical patent/CN111334705A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D13/00Centrifugal casting; Casting by using centrifugal force
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/30Stress-relieving
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium
    • C22C37/08Cast-iron alloys containing chromium with nickel
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Child & Adolescent Psychology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)

Abstract

The invention provides alloy cast iron, which comprises the following components: 2.6-3.2% of C; 0.02-0.1% S; 1.5-2.6% of Si; 0.2-0.5% of P; 0.5 to 1.0% of Mn; 0.0-0.4% Cr; 0.1-0.8% of Cu; 0.1-0.7% of Mo; 0.1-0.7% Ni; 0.05-0.4% of Nb; the balance being Fe. The cylinder sleeve blank is obtained through centrifugal casting, the tensile strength of the cylinder sleeve blank is stable and reaches more than 400MPa, the hardness of the cylinder sleeve blank can reach 270-330 HBW, the mechanical property of the cylinder sleeve blank is equivalent to that of alloy bainite gray cast iron, but the cylinder sleeve blank is simple in production process, low in cost, good in wear resistance and high in use value and economic value. The invention also provides a preparation method and application of the high-strength pearlite antifriction cast iron.

Description

High-strength pearlite antifriction cast iron and preparation method and application thereof
Technical Field
The invention relates to the technical field of cast iron, in particular to high-strength pearlite antifriction cast iron and a preparation method and application thereof.
Background
The cylinder sleeve is a cylindrical workpiece and is positioned in a cylinder body hole of the machine body, the upper part of the cylinder sleeve is tightly pressed and fixed by a cylinder cover, the piston does reciprocating motion in an inner hole of the piston, and cooling water is arranged outside the piston; it, cylinder cover and piston together form the working space of cylinder. The cylinder liner is one of key parts of an engine and requires high mechanical performance. For example, at present, the high-strength cylinder liner mostly adopts an alloyed as-cast bainite gray cast iron cylinder liner, and the chemical composition of the cylinder liner is as follows by weight percent: carbon: 2.7-3.1%; silicon: 1.3-2.2%; manganese: 0.4-8%; phosphorus is less than or equal to 0.1 percent; sulfur is less than or equal to 0.1 percent; copper: 0.3-1.0%; molybdenum: 1.0-1.5%; nickel: 1.0-1.5%; the balance being Fe; the strength of the bainite material can reach more than 400MPa, but the bainite material uses more precious alloys and has higher cost, and the wear resistance and the corrosion resistance can not meet the requirements of more than six machine types in China.
Disclosure of Invention
In view of the above, the present invention aims to provide a high-strength pearlite antifriction cast iron, a preparation method and an application thereof, and the pearlite cast iron provided by the present invention has the advantages of high strength, high wear resistance, corrosion resistance, low friction coefficient and low manufacturing cost.
The invention provides high-strength pearlite antifriction cast iron which comprises the following components:
2.6-3.2 wt% of C;
0.02 to 0.1 wt% S;
1.5-2.6 wt% of Si;
0.2 to 0.5 wt% of P;
0.5 to 1.0 wt% Mn;
0.0 to 0.4 wt% of Cr;
0.1 to 0.8 wt% of Cu;
0.1 to 0.7 wt% of Mo;
0.1 to 0.7 wt% of Ni;
0.05 to 0.4 wt% of Nb;
the balance being Fe.
In the present invention, the high-strength pearlitic antifriction cast iron preferably has the following composition:
2.8-3.0 wt% of C;
0.04 to 0.0.6 wt% S;
1.8-2.2 wt% of Si;
0.25 to 0.5 wt% of P;
0.6-0.8 wt% Mn;
0.15 to 0.25 wt% of Cr;
0.3 to 0.6 wt% of Cu;
0.3 to 0.5 wt% of Mo;
0.3 to 0.5 wt% of Ni;
0.15 to 0.25 wt% of Nb;
the balance being Fe.
In the invention, the mass content of C is preferably 2.8-3.0%; the mass content of S is preferably 0.04-0.06%; the mass content of the Si is preferably 1.8-2.2%; the mass content of P is preferably 0.25-0.5%, and more preferably 0.3-0.4%; the mass content of Mn is preferably 0.6-0.8%; the mass content of Cr is preferably 0.15-0.25%; the mass content of Cu is preferably 0.3-0.6%, and more preferably 0.4-0.5%; the mass content of Mo is preferably 0.3-0.5%, and more preferably 0.4%; the mass content of the Ni is preferably 0.3-0.5%, and more preferably 0.4%; the mass content of Nb is preferably 0.15 to 0.25%, more preferably 0.2%.
The addition of the alloy elements such as molybdenum, nickel, niobium and the like can obtain the optimal pearlite structure, refine graphite and strengthen a matrix. The invention obtains the best cast iron performance mainly by matching and combining various elements, such as a proper amount of P element content, and is mainly used for forming the intermittent reticular phosphorus eutectic crystal to improve the wear resistance and the antifriction property of the cylinder sleeve, and the content is too low, the wear resistance and the antifriction effect are deteriorated and too high, and the cast iron brittleness is increased; adding a proper amount of manganese and chromium to adjust the macroscopic hardness of the cast iron; the addition of Mo, Ni and Nb can raise the strength, elastic modulus and fatigue strength of cast iron, and Nb has strong solid solution strengthening and dispersion strengthening action on the cast iron matrix, and the Nb (C, N) phase formed by Nb element has very high microhardness, so that the wear resistance of cast iron can be further raised.
The invention provides a preparation method of high-strength pearlite antifriction cast iron in the technical scheme, which comprises the following steps:
inoculating the alloy raw material after smelting to obtain molten iron;
carrying out centrifugal casting on the molten iron to obtain a blank;
and cooling, rough machining, stress relief annealing and finish machining are carried out on the blank to obtain the high-strength pearlite antifriction cast iron cylinder sleeve.
The alloy raw materials are not particularly limited, and those skilled in the art can adopt simple substances or alloys containing relevant alloy elements according to the required cast iron components.
In the invention, the smelting temperature is preferably 1500-1540 ℃, more preferably 1510-1530 ℃ and most preferably 1520 ℃.
The inoculation is not particularly limited in the present invention and may be carried out by a cast iron inoculation method well known to those skilled in the art, and the inoculant used in the inoculation is preferably a silicon-barium inoculant which is commercially available.
In the invention, the components of the molten iron are consistent with the components of the high-strength pearlite antifriction cast iron in the technical scheme, and the components are as follows: 2.6-3.2 wt% of C; 0.02 to 0.1 wt% S; 1.5-2.6 wt% of Si; 0.2 to 0.5 wt% of P; 0.5 to 1.0 wt% Mn; 0.0 to 0.4 wt% of Cr; 0.1 to 0.7 wt% of Mo; 0.1 to 0.7 wt% of Ni; 0.05-0.4% of Nb; the balance being Fe.
In the invention, the centrifugal casting temperature is preferably 1400-1440 ℃, more preferably 1410-1430 ℃, and most preferably 1420 ℃. In the invention, the rotation speed of centrifugal casting is preferably 1350-1400 r/min, and more preferably 1360-1370 r/min. In the invention, the centrifugal casting mold-releasing temperature is preferably 800-900 ℃, more preferably 820-880 ℃, and most preferably 840-860 ℃.
In the invention, the cooling is preferably carried out by air cooling after the compressed air is treated to the temperature of 550-650 ℃, more preferably 580-620 ℃, and most preferably 600 ℃. In the present invention, the cooling rate during the cooling process is preferably > 70 ℃/min.
The method of rough machining is not particularly limited in the present invention, and the cylinder liner having a desired shape may be obtained by rough machining methods well known to those skilled in the art.
In the invention, the temperature of the stress relief annealing is preferably 530-570 ℃, more preferably 540-560 ℃, and most preferably 550 ℃; the time of the stress relief annealing is preferably 2-3 hours.
The method for finishing is not particularly limited in the present invention, and the cylinder liner with the required dimensional accuracy can be obtained by adopting a finishing method well known to those skilled in the art.
The cast iron provided by the invention is easy to produce, qualified castings can be produced only by adopting the most common casting process, the casting process is far lower than the casting difficulty of as-cast bainite gray cast iron, and although the cast iron contains a small amount of precious metals, the content of the cast iron is much lower than that of the bainite gray cast iron, so the material cost is also greatly reduced.
The invention provides a cylinder liner, which is made of the high-strength pearlite antifriction cast iron in the technical scheme, and the preparation method of the cylinder liner is consistent with that of the high-strength pearlite antifriction cast iron in the technical scheme, and is not repeated herein.
The tensile strength of the cast iron provided by the invention reaches more than 450MPa, the cast iron is far higher than the highest mark HT350 (tensile strength is not lower than 350MPa) of gray cast iron, and the fatigue strength even reaches more than 200 MPa.
Compared with the prior art, the strength of the cast iron is greatly improved by optimally designing alloy components and a casting process, the cost is relatively low, the process is simple, the hardness is 270-330 HB, the tensile strength is greater than 400MPa, the cast iron matrix is fine flake pearlite, the structure is stable, and the stability of the size, namely form and position tolerance, of the cylinder sleeve is easily ensured; because the matrix structure has the mesh-shaped distribution of the phosphorus eutectic crystal and the microhardness of the Nb (C, N) phase can reach 2500-3000 HV, the wear resistance of the cylinder sleeve is greatly improved. The cast iron of the invention has relatively low alloy content, so the comprehensive cost is far lower than that of high-alloy bainite alloy cast iron.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other examples, which may be modified or appreciated by those of ordinary skill in the art based on the examples given herein, are intended to be within the scope of the present invention.
Example 1
Inoculating alloy elements after smelting to obtain molten iron, wherein the smelting temperature is controlled to be 1500-1520 ℃; the inoculant adopted during inoculation is a silicon-barium inoculant for Ningxia casting peak.
And centrifugally casting the obtained molten iron into a blank, controlling the casting temperature to be 1400-1420 ℃, controlling the centrifugal rotating speed to be 1360r/min in the casting process, and discharging at 850 ℃.
And cooling the obtained blank to 600 ℃ by compressed air, and then cooling by air, wherein the cooling speed in the cooling period is more than 70 ℃/min.
And (3) after rough machining, preserving the heat of the cooled blank at 550 ℃ for 3 hours, and finishing to obtain a finished cylinder sleeve product.
Detecting the components of the cylinder sleeve by adopting a photoelectric direct-reading spectrometer according to GB/T24234-2009 'cast iron multi-element determination spark discharge atomic emission spectrometry', wherein the detection result is that the cylinder sleeve comprises the following components:
c: 2.85 wt%, Si: 2.01 wt%, P: 0.28 wt%, S: 0.05 wt%, Mn: 0.65 wt%, Cr: 0.15 wt%, Cu: 0.45 wt%, Ni: 0.35 wt%, Mo: 0.4 wt%, Nb: 0.19 wt%, the balance being Fe.
The cylinder liner prepared in example 1 is subjected to mechanical property detection according to GB/T231.1-2018 part 1 of Brinell hardness test of metal material: the standard test of the test method comprises the following test results: HBW: 285; adopting a universal material testing machine WDW-300, and according to GB/T228.1-2010 part 1 of metal material tensile test: the standard test of the room temperature test method indicates that the tensile strength is as follows: 456 MPa; according to the standard detection of GB/T22315-2008 ' test method for elastic modulus and Poisson's ratio of metal material ', the detection result is that the elastic modulus of the cylinder sleeve prepared in the embodiment 1 of the invention is as follows: 146 GPa.
Example 2
Inoculating the alloy raw material after smelting to obtain molten iron; controlling the smelting temperature to be 1520-1540 ℃; the inoculant is silicon-barium inoculant of Ningxia casting peak.
Centrifugally casting the obtained molten iron into a blank, wherein the casting temperature is controlled to be 1420-1440 ℃, and the centrifugal rotating speed is 1360 r/min; and (4) demolding at 850 ℃.
Cooling the obtained blank to 580 ℃ by compressed air, and then cooling by air, wherein the cooling speed is more than 70 ℃/min during cooling.
And (4) roughly processing the cooled blank, preserving the heat at 550 ℃ for 3 hours, and finely processing the blank into a finished cylinder sleeve product.
According to the method of the embodiment 1, the components of the cylinder sleeve prepared in the embodiment 2 of the invention are detected, and the detection result is as follows:
c: 2.72 wt%, Si: 2.11 wt%, P: 0.32 wt%, S: 0.05 wt%, Mn: 0.71 wt%, Cr: 0.11 wt%, Cu: 0.35 wt%, Ni: 0.30 wt%, Mo: 0.37 wt%, Nb: 0.15 wt%, the balance being Fe.
According to the detection method of the embodiment 1, the mechanical property of the cylinder sleeve prepared in the embodiment 2 of the invention is detected, and the detection result is as follows: HBW: 310, tensile strength: 462MPa, modulus of elasticity: 151 GPa.
Example 3
Inoculating the alloy raw material after smelting to obtain molten iron; controlling the smelting temperature to be 1490-1510 ℃; the inoculant is silicon-barium inoculant of Ningxia casting peak.
Centrifugally casting the obtained molten iron into a blank, wherein the casting temperature is controlled to be 1400-1420 ℃, and the centrifugal rotating speed is 1360 r/min; and (4) demolding at 850 ℃.
Cooling the obtained blank to 610 ℃ by compressed air, and then cooling by air, wherein the cooling speed is more than 70 ℃/min during cooling.
And (4) roughly processing the cooled blank, preserving the heat at 550 ℃ for 3 hours, and finely processing the blank into a finished cylinder sleeve product.
According to the method of the embodiment 1, the components of the cylinder sleeve prepared in the embodiment 3 of the invention are detected, and the detection result is as follows:
c: 2.98 wt%, Si: 1.81 wt%, P: 0.3 wt%, S: 0.045 wt%, Mn: 0.53 wt%, Cr: 0.19 wt%, Cu: 0.35 wt%, Ni: 0.30 wt%, Mo: 0.3 wt%, Nb: 0.23 wt%, the balance being Fe.
According to the method of the embodiment 1, the mechanical property of the cylinder sleeve prepared in the embodiment 3 of the invention is detected, and the detection result is as follows: HBW279, tensile strength: 442MPa, modulus of elasticity: 144 GPa.
From the above examples, the invention provides a high strength pearlitic antifriction cast iron comprising the following components: 2.6-3.2% of C; 0.02-0.1% S; 1.5-2.6% of Si; 0.2-0.5% of P; 0.5 to 1.0% of Mn; 0.0-0.4% Cr; 0.1-0.8% of Cu; 0.1-0.7% of Mo; 0.1-0.7% Ni; 0.05-0.4% of Nb; the balance being Fe. The cylinder sleeve blank is obtained through centrifugal casting, the tensile strength of the cylinder sleeve blank is stable and reaches more than 400MPa, the hardness of the cylinder sleeve blank can reach 270-330 HBW, the mechanical property of the cylinder sleeve blank is equivalent to that of alloy bainite gray cast iron, but the cylinder sleeve blank is simple in production process, low in cost, good in wear resistance and high in use value and economic value.
While only the preferred embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention.

Claims (10)

1. A high-strength pearlite antifriction cast iron comprises the following components:
2.6-3.2 wt% of C;
0.02 to 0.1 wt% S;
1.5-2.6 wt% of Si;
0.2 to 0.5 wt% of P;
0.5 to 1.0 wt% Mn;
0.0 to 0.4 wt% of Cr;
0.1 to 0.8 wt% of Cu;
0.1 to 0.7 wt% of Mo;
0.1 to 0.7 wt% of Ni;
0.05 to 0.4 wt% of Nb;
the balance being Fe.
2. The high strength pearlitic friction reducing cast iron according to claim 1 having the composition:
2.8-3.0 wt% of C;
0.04 to 0.0.6 wt% S;
1.8-2.2 wt% of Si;
0.25 to 0.5 wt% of P;
0.6-0.8 wt% Mn;
0.15 to 0.25 wt% of Cr;
0.3 to 0.6 wt% of Cu;
0.3 to 0.5 wt% of Mo;
0.3 to 0.5 wt% of Ni;
0.15 to 0.25 wt% of Nb;
the balance being Fe.
3. A method for preparing the high strength pearlitic wear reduced cast iron of claim 1 comprising:
inoculating the alloy raw material after smelting to obtain molten iron;
carrying out centrifugal casting on the molten iron to obtain a blank;
and cooling, rough machining, stress relief annealing and finish machining are carried out on the blank to obtain the high-strength pearlite antifriction cast iron.
4. The method of claim 3, wherein the temperature of the smelting is 1500-1540 ℃.
5. The method of claim 3, wherein the temperature of the centrifugal casting is 1400-1440 ℃.
6. The method according to claim 3, wherein the rotational speed of the centrifugal casting is 1350-1400 r/min.
7. The method according to claim 3, wherein the centrifugal casting has a casting temperature of 800-900 ℃.
8. The method according to claim 1, wherein the temperature of the cooling is 550 to 650 ℃.
9. The method of claim 1, wherein the stress relief annealing temperature is 530-570 ℃; and the heat preservation time of the stress relief annealing is 2-3 hours.
10. A cylinder liner, the material of the cylinder liner is the high-strength pearlite antifriction cast iron of claim 1.
CN202010265183.5A 2020-04-07 2020-04-07 High-strength pearlite antifriction cast iron and preparation method and application thereof Pending CN111334705A (en)

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CN202010265183.5A CN111334705A (en) 2020-04-07 2020-04-07 High-strength pearlite antifriction cast iron and preparation method and application thereof

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Application Number Priority Date Filing Date Title
CN202010265183.5A CN111334705A (en) 2020-04-07 2020-04-07 High-strength pearlite antifriction cast iron and preparation method and application thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690867A (en) * 2020-07-08 2020-09-22 中原内配集团股份有限公司 Alloy cast iron and preparation method thereof
CN115491579A (en) * 2022-09-28 2022-12-20 江苏力源金河铸造有限公司 High-precision hydraulic electromagnetic valve casting and casting process design thereof
CN115725891A (en) * 2021-08-31 2023-03-03 通用汽车环球科技运作有限责任公司 High modulus, high strength and low alloy gray cast iron for cylinder liners and automotive applications
CN116179933A (en) * 2023-02-21 2023-05-30 安庆帝伯格茨缸套有限公司 A kind of high-strength pearlitic diesel engine cylinder liner material and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11286738A (en) * 1998-04-06 1999-10-19 Kubota Corp High-speed cast iron with graphite and iron phosphide
CN1653202A (en) * 2002-05-13 2005-08-10 斯堪尼亚有限公司 Gray cast iron alloy and cast internal combustion engine component
CN101798653A (en) * 2010-04-16 2010-08-11 上海贵煌特种钢有限公司 Rare earth high silicon-nickel-chrome alloy cast iron and smelting method thereof
CN104073710A (en) * 2014-06-24 2014-10-01 丹寨县真山机电有限公司 Antifriction cast iron for air conditioner compressors and preparation method thereof
CN106523171A (en) * 2016-11-02 2017-03-22 中原内配集团股份有限公司 New energy cylinder sleeve and production method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11286738A (en) * 1998-04-06 1999-10-19 Kubota Corp High-speed cast iron with graphite and iron phosphide
CN1653202A (en) * 2002-05-13 2005-08-10 斯堪尼亚有限公司 Gray cast iron alloy and cast internal combustion engine component
CN101798653A (en) * 2010-04-16 2010-08-11 上海贵煌特种钢有限公司 Rare earth high silicon-nickel-chrome alloy cast iron and smelting method thereof
CN104073710A (en) * 2014-06-24 2014-10-01 丹寨县真山机电有限公司 Antifriction cast iron for air conditioner compressors and preparation method thereof
CN106523171A (en) * 2016-11-02 2017-03-22 中原内配集团股份有限公司 New energy cylinder sleeve and production method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690867A (en) * 2020-07-08 2020-09-22 中原内配集团股份有限公司 Alloy cast iron and preparation method thereof
CN111690867B (en) * 2020-07-08 2021-12-07 中原内配集团股份有限公司 Alloy cast iron and preparation method thereof
CN115725891A (en) * 2021-08-31 2023-03-03 通用汽车环球科技运作有限责任公司 High modulus, high strength and low alloy gray cast iron for cylinder liners and automotive applications
CN115725891B (en) * 2021-08-31 2023-11-21 通用汽车环球科技运作有限责任公司 High modulus, high strength and low alloy gray cast iron for cylinder liner and automotive applications
CN115491579A (en) * 2022-09-28 2022-12-20 江苏力源金河铸造有限公司 High-precision hydraulic electromagnetic valve casting and casting process design thereof
CN116179933A (en) * 2023-02-21 2023-05-30 安庆帝伯格茨缸套有限公司 A kind of high-strength pearlitic diesel engine cylinder liner material and preparation method thereof

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