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CN111303765A - Impact-resistant high-weather-resistance water-based industrial coating and preparation method thereof - Google Patents

Impact-resistant high-weather-resistance water-based industrial coating and preparation method thereof Download PDF

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Publication number
CN111303765A
CN111303765A CN202010302017.8A CN202010302017A CN111303765A CN 111303765 A CN111303765 A CN 111303765A CN 202010302017 A CN202010302017 A CN 202010302017A CN 111303765 A CN111303765 A CN 111303765A
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Prior art keywords
parts
impact
resistant
weather
agent
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CN202010302017.8A
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Chinese (zh)
Inventor
陈建
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Hubei Junjie Chemical Product Marketing Planning Co Ltd
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Hubei Junjie Chemical Product Marketing Planning Co Ltd
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Priority to CN202010302017.8A priority Critical patent/CN111303765A/en
Publication of CN111303765A publication Critical patent/CN111303765A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an impact-resistant high-weather-resistance water-based industrial coating and a preparation method thereof, belonging to the technical field of industrial coatings, wherein 2-10 parts of graphene aerogel is adopted; 20-30 parts of an organic silicon emulsion; 1-10 parts of copper iron blackening agent selenium dioxide; 9-15 parts of elastic acrylic emulsion; 7-15 parts of vermiculite; 5-20 parts of deionized water; 1-5 parts of lithium magnesium silicate; 2-5 parts of perlite; 2.1-6.5 parts of auxiliary agent, the impact resistance of the industrial coating is improved, the service life of the ship body is longer, the coating does not need to be supplemented all the time, the weather-resistant water performance is improved, the ship body is not easy to corrode, and the impact resistance of the coating is further improved during production through the process flow of the invention.

Description

Impact-resistant high-weather-resistance water-based industrial coating and preparation method thereof
Technical Field
The invention relates to an industrial coating, in particular to an impact-resistant high-weather-resistance water-based industrial coating, and also relates to a preparation method of the industrial coating, in particular to a preparation method of the impact-resistant high-weather-resistance water-based industrial coating, belonging to the technical field of industrial coatings.
Background
In general, the coating can be divided into two major parts: architectural coatings and industrial coatings, by general definition, include traffic coatings, other coatings, and the like, under which automotive coatings, marine coatings, and the like may be subdivided, architectural coatings dividing wall interior and exterior coatings, wall interior coatings including interior wall coatings, floor coatings, furniture coatings, and the like.
With the global environmental issues becoming more prominent, the coating industry, a member of the chemical industry, is faced with environmental protection issues, and "environmental protection, energy conservation and health" are the inevitable development directions of coating products, and industrial coatings are given more important environmental responsibility due to their important positions in the coating industry and their permeability to the living field.
From the current development situation, the energy-saving, environment-friendly and low-pollution water-based paint is generally considered to replace solvent-based paint finally, and in addition, high-solid paint, powder paint, solvent-free paint and radiation curing paint also belong to environment-friendly paint, and the environment-friendly paint is the inevitable direction of future development of the paint industry, although the development of the current environment-friendly paint technology is still about to be broken through, but a plurality of coating enterprises, especially international coating enterprises, are greatly investing in the research on environment-friendly coating technology, so as to be capable of preempting in the future environment-friendly coating field, according to the relevant data, the environment-friendly industrial coating accounts for about 20 percent of the world industrial coating at present, and the proportion is estimated to rise to 30 percent by 2010, in developed areas in Europe, the proportion reaches 30% at present, and the environment-friendly industrial coating has wide market prospect.
In addition, in the field of application of industrial coatings, both general industrial coatings (related to household appliances, furniture and the like) which concern people's daily life and protective coatings of production equipment, railway roads, bridges, ships, airplanes and the like in factories are required to have higher weather resistance so as to prolong the service life of related industrial products, that is, the weather resistance of industrial coatings is more and more emphasized, and the improvement of the weather resistance of industrial coatings, particularly heavy anticorrosive coatings, will become an important development direction of industrial coatings in the future.
From the level of the industrial coating market, the future market of the industrial coating is concentrated towards the middle-high end market (wherein the high end market also comprises the coating market of a new industrial field), whether the requirement of the middle-high end market can be met or not, the real strength of a coating enterprise can be checked, in addition, the technical added value of the coating product in the middle-high end field is high, 35274and the like which are commonly found by a plurality of coating enterprises are achieved, and compared with the situation that the industrial coating enterprises in China generally use the theory of Farad cloud in the low end market, the theory that the technology is inferior can not be established in the competition of the industrial coating market in the future without changing the technology.
Despite the situation of the current coating market in China, the great potential of the market can be deeply recognized, domestic coating enterprises are difficult to build trees, the method is relatively disadvantaged in competition with the international paint big head, meanwhile, the competition among the coating enterprises in China is quite chaotic, leadership enterprises lack directional strength, and if Chinese paint enterprises obtain larger living space in future market competition, the Chinese paint enterprises need to integrate production modes mainly comprising small and medium-sized paint enterprises to ensure the investment of capital and technology, firstly optimize the competitive power of the Chinese paint enterprises, then possibly obtain the opportunity of competing with the international big head on the same table, the environmental protection is required to be mastered in the aspect of products, the technical content of the products is improved, the eyes are focused on the middle-high-end market and the market in the emerging industrial field, the traditional concept of winning the quantity is changed, and the way of winning the quality is taken.
The industrial coating in the prior art often falls off after impact when used on a ship body, a ship body and the like, sometimes falls off after being simply and lightly wiped, is very insecure and not resistant to impact, and is easy to corrode and low in weather resistance when the industrial coating used on the ship body is soaked in water for a long time.
Disclosure of Invention
The invention mainly aims to provide an impact-resistant high-weather-resistance water-based industrial coating and a preparation method thereof, wherein 2-10 parts of graphene aerogel is adopted; 20-30 parts of an organic silicon emulsion; 1-10 parts of copper iron blackening agent selenium dioxide; 9-15 parts of elastic acrylic emulsion; 7-15 parts of vermiculite; 5-20 parts of deionized water; 1-5 parts of lithium magnesium silicate; 2-5 parts of perlite; 2.1-6.5 parts of auxiliary agent, the impact resistance of the industrial coating is improved, the service life of the ship body is longer, the coating does not need to be supplemented all the time, the weather-resistant water performance is improved, the ship body is not easy to corrode, and the impact resistance of the coating is further improved during production through the process flow of the invention.
The purpose of the invention can be achieved by adopting the following technical scheme: an impact-resistant high-weather-resistance water-based industrial coating comprises the following components in parts by weight: 2-10 parts of graphene aerogel; 20-30 parts of an organic silicon emulsion; 1-10 parts of copper iron blackening agent selenium dioxide; 9-15 parts of elastic acrylic emulsion; 7-15 parts of vermiculite; 5-20 parts of deionized water; 1-5 parts of lithium magnesium silicate; 2-5 parts of perlite; 2.1-6.5 parts of auxiliary agent.
Preferably, the auxiliary agent comprises the following components in parts by weight: 0.1-0.3 part of multifunctional auxiliary agent; 0.3-0.6 part of dispersant; 0.1-0.3 part of defoaming agent; 0.5-2 parts of an antifreezing agent; 0.3-0.5 part of coupling agent; 0.8-2.8 parts of film-forming assistant.
Preferably, 2 parts of graphene aerogel; 20 parts of an organic silicon emulsion; 1 part of copper iron blackening agent selenium dioxide; 9 parts of elastic acrylic emulsion; 7 parts of vermiculite; 5 parts of deionized water; 1 part of lithium magnesium silicate; 2 parts of perlite; 2.1 parts of auxiliary agent.
Preferably, 6 parts of graphene aerogel; 25 parts of organic silicon emulsion; 6 parts of copper iron blackening agent selenium dioxide; 12 parts of elastic acrylic emulsion; 11 parts of vermiculite; 13 parts of deionized water; 3 parts of lithium magnesium silicate; 3.5 parts of perlite; 4 parts of auxiliary agent.
Preferably, 10 parts of graphene aerogel; 30 parts of an organic silicon emulsion; 10 parts of copper iron blackening agent selenium dioxide; 15 parts of elastic acrylic emulsion; 15 parts of vermiculite; 20 parts of deionized water; 5 parts of lithium magnesium silicate; 5 parts of perlite; 6.5 parts of auxiliary agent.
A preparation method of an impact-resistant high-weather-resistance water-based industrial coating comprises the following steps:
step 1: weighing 2-10 parts of graphene aerogel, 20-30 parts of organic silicon emulsion, 1-10 parts of copper iron blackening agent selenium dioxide, 9-15 parts of elastic acrylic emulsion, 7-15 parts of vermiculite, 5-20 parts of deionized water, 1-5 parts of lithium magnesium silicate, 2-5 parts of perlite and 2.1-6.5 parts of auxiliary agent according to parts by weight;
step 2: firstly putting graphene aerogel, organic silicon emulsion, elastic acrylic emulsion, vermiculite, deionized water and perlite into a mixing and stirring kettle;
and step 3: heating the mixing and stirring kettle to 60-80 ℃, driving the mixing and stirring kettle to stir at the rotating speed of 300-;
and 4, step 4: further adding copper-iron blackening agent selenium dioxide, magnesium lithium silicate and auxiliary agent into the mixing and stirring kettle, heating to 100-;
and 5: after stirring, putting the mixture into a heat exchange cooler for cooling;
step 6: cooling and then putting into a grinder for grinding;
and 7: and (5) discharging and packaging after grinding uniformly for spraying construction.
The invention has the beneficial technical effects that: 2-10 parts of graphene aerogel is adopted; 20-30 parts of an organic silicon emulsion; 1-10 parts of copper iron blackening agent selenium dioxide; 9-15 parts of elastic acrylic emulsion; 7-15 parts of vermiculite; 5-20 parts of deionized water; 1-5 parts of lithium magnesium silicate; 2-5 parts of perlite; 2.1-6.5 parts of auxiliary agent, the impact resistance of the industrial coating is improved, the service life of the ship body is longer, the coating does not need to be supplemented all the time, the weather-resistant water performance is improved, the ship body is not easy to corrode, and the impact resistance of the coating is further improved during production through the process flow of the invention.
Detailed Description
In order to make the technical solutions of the present invention more clear and definite for those skilled in the art, the present invention is further described in detail with reference to the following examples, but the embodiments of the present invention are not limited thereto.
Example one
An impact-resistant high-weather-resistance water-based industrial coating comprises the following components in parts by weight: 2-10 parts of graphene aerogel; 20-30 parts of an organic silicon emulsion; 1-10 parts of copper iron blackening agent selenium dioxide; 9-15 parts of elastic acrylic emulsion; 7-15 parts of vermiculite; 5-20 parts of deionized water; 1-5 parts of lithium magnesium silicate; 2-5 parts of perlite; 2.1-6.5 parts of auxiliary agent.
In this embodiment, the auxiliary agent comprises, in parts by weight: 0.1-0.3 part of multifunctional auxiliary agent; 0.3-0.6 part of dispersant; 0.1-0.3 part of defoaming agent; 0.5-2 parts of an antifreezing agent; 0.3-0.5 part of coupling agent; 0.8-2.8 parts of film-forming assistant.
Example two
In the embodiment, 2 parts of graphene aerogel; 20 parts of an organic silicon emulsion; 1 part of copper iron blackening agent selenium dioxide; 9 parts of elastic acrylic emulsion; 7 parts of vermiculite; 5 parts of deionized water; 1 part of lithium magnesium silicate; 2 parts of perlite; 2.1 parts of auxiliary agent.
EXAMPLE III
In the embodiment, 6 parts of graphene aerogel; 25 parts of organic silicon emulsion; 6 parts of copper iron blackening agent selenium dioxide; 12 parts of elastic acrylic emulsion; 11 parts of vermiculite; 13 parts of deionized water; 3 parts of lithium magnesium silicate; 3.5 parts of perlite; 4 parts of auxiliary agent.
Example four
In the embodiment, 10 parts of graphene aerogel; 30 parts of an organic silicon emulsion; 10 parts of copper iron blackening agent selenium dioxide; 15 parts of elastic acrylic emulsion; 15 parts of vermiculite; 20 parts of deionized water; 5 parts of lithium magnesium silicate; 5 parts of perlite; 6.5 parts of auxiliary agent.
EXAMPLE five
A preparation method of an impact-resistant high-weather-resistance water-based industrial coating comprises the following steps:
step 1: weighing 2-10 parts of graphene aerogel, 20-30 parts of organic silicon emulsion, 1-10 parts of copper iron blackening agent selenium dioxide, 9-15 parts of elastic acrylic emulsion, 7-15 parts of vermiculite, 5-20 parts of deionized water, 1-5 parts of lithium magnesium silicate, 2-5 parts of perlite and 2.1-6.5 parts of auxiliary agent according to parts by weight;
step 2: firstly putting graphene aerogel, organic silicon emulsion, elastic acrylic emulsion, vermiculite, deionized water and perlite into a mixing and stirring kettle;
and step 3: heating the mixing and stirring kettle to 60-80 ℃, driving the mixing and stirring kettle to stir at the rotating speed of 300-;
and 4, step 4: further adding copper-iron blackening agent selenium dioxide, magnesium lithium silicate and auxiliary agent into the mixing and stirring kettle, heating to 100-;
and 5: after stirring, putting the mixture into a heat exchange cooler for cooling;
step 6: cooling and then putting into a grinder for grinding;
and 7: and (5) discharging and packaging after grinding uniformly for spraying construction.
The above description is only for the purpose of illustrating the present invention and is not intended to limit the scope of the present invention, and any person skilled in the art can substitute or change the technical solution of the present invention and its conception within the scope of the present invention.

Claims (6)

1. The impact-resistant high-weather-resistance water-based industrial coating is characterized by comprising the following components in parts by weight:
2-10 parts of graphene aerogel;
20-30 parts of an organic silicon emulsion;
1-10 parts of copper iron blackening agent selenium dioxide;
9-15 parts of elastic acrylic emulsion;
7-15 parts of vermiculite;
5-20 parts of deionized water;
1-5 parts of lithium magnesium silicate;
2-5 parts of perlite;
2.1-6.5 parts of auxiliary agent.
2. The impact-resistant weather-resistant aqueous industrial coating as claimed in claim 1, wherein the auxiliary agent comprises the following components in parts by weight:
0.1-0.3 part of multifunctional auxiliary agent;
0.3-0.6 part of dispersant;
0.1-0.3 part of defoaming agent;
0.5-2 parts of an antifreezing agent;
0.3-0.5 part of coupling agent;
0.8-2.8 parts of film-forming assistant.
3. The impact-resistant weather-resistant aqueous industrial coating according to claim 1,
2 parts of graphene aerogel;
20 parts of an organic silicon emulsion;
1 part of copper iron blackening agent selenium dioxide;
9 parts of elastic acrylic emulsion;
7 parts of vermiculite;
5 parts of deionized water;
1 part of lithium magnesium silicate;
2 parts of perlite;
2.1 parts of auxiliary agent.
4. The impact-resistant weather-resistant aqueous industrial coating according to claim 1,
6 parts of graphene aerogel;
25 parts of organic silicon emulsion;
6 parts of copper iron blackening agent selenium dioxide;
12 parts of elastic acrylic emulsion;
11 parts of vermiculite;
13 parts of deionized water;
3 parts of lithium magnesium silicate;
3.5 parts of perlite;
4 parts of auxiliary agent.
5. The impact-resistant weather-resistant aqueous industrial coating according to claim 1,
10 parts of graphene aerogel;
30 parts of an organic silicon emulsion;
10 parts of copper iron blackening agent selenium dioxide;
15 parts of elastic acrylic emulsion;
15 parts of vermiculite;
20 parts of deionized water;
5 parts of lithium magnesium silicate;
5 parts of perlite;
6.5 parts of auxiliary agent.
6. The preparation method of the impact-resistant high-weather-resistant water-based industrial coating according to any one of claims 1 to 5, characterized by comprising the following steps:
step 1: weighing 2-10 parts of graphene aerogel, 20-30 parts of organic silicon emulsion, 1-10 parts of copper iron blackening agent selenium dioxide, 9-15 parts of elastic acrylic emulsion, 7-15 parts of vermiculite, 5-20 parts of deionized water, 1-5 parts of lithium magnesium silicate, 2-5 parts of perlite and 2.1-6.5 parts of auxiliary agent according to parts by weight;
step 2: firstly putting graphene aerogel, organic silicon emulsion, elastic acrylic emulsion, vermiculite, deionized water and perlite into a mixing and stirring kettle;
and step 3: heating the mixing and stirring kettle to 60-80 ℃, driving the mixing and stirring kettle to stir at the rotating speed of 300-;
and 4, step 4: further adding copper-iron blackening agent selenium dioxide, magnesium lithium silicate and auxiliary agent into the mixing and stirring kettle, heating to 100-;
and 5: after stirring, putting the mixture into a heat exchange cooler for cooling;
step 6: cooling and then putting into a grinder for grinding;
and 7: and (5) discharging and packaging after grinding uniformly for spraying construction.
CN202010302017.8A 2020-04-16 2020-04-16 Impact-resistant high-weather-resistance water-based industrial coating and preparation method thereof Withdrawn CN111303765A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010302017.8A CN111303765A (en) 2020-04-16 2020-04-16 Impact-resistant high-weather-resistance water-based industrial coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010302017.8A CN111303765A (en) 2020-04-16 2020-04-16 Impact-resistant high-weather-resistance water-based industrial coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN111303765A true CN111303765A (en) 2020-06-19

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Country Status (1)

Country Link
CN (1) CN111303765A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008137262A2 (en) * 2007-05-01 2008-11-13 Dow Corning Corporation Reinforced silicone resin film
CN102585698A (en) * 2012-03-21 2012-07-18 北京国泰瑞华精藻硅特种材料有限公司 Water-based industrial heat-proof coating
CN105368196A (en) * 2015-12-15 2016-03-02 天津一橙泽恒环保科技发展有限公司 Environment-friendly sound deadening coating
CN105400312A (en) * 2015-12-15 2016-03-16 天津一橙泽恒环保科技发展有限公司 Environment-friendly industrial coating
CN110016245A (en) * 2019-05-13 2019-07-16 平顶山学院 A thermal shock-resistant industrial coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008137262A2 (en) * 2007-05-01 2008-11-13 Dow Corning Corporation Reinforced silicone resin film
CN102585698A (en) * 2012-03-21 2012-07-18 北京国泰瑞华精藻硅特种材料有限公司 Water-based industrial heat-proof coating
CN105368196A (en) * 2015-12-15 2016-03-02 天津一橙泽恒环保科技发展有限公司 Environment-friendly sound deadening coating
CN105400312A (en) * 2015-12-15 2016-03-16 天津一橙泽恒环保科技发展有限公司 Environment-friendly industrial coating
CN110016245A (en) * 2019-05-13 2019-07-16 平顶山学院 A thermal shock-resistant industrial coating

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