CN111058289A - A kind of method for enhancing the hygroscopicity of sodium periodate oxidized cotton fabric - Google Patents
A kind of method for enhancing the hygroscopicity of sodium periodate oxidized cotton fabric Download PDFInfo
- Publication number
- CN111058289A CN111058289A CN202010051205.8A CN202010051205A CN111058289A CN 111058289 A CN111058289 A CN 111058289A CN 202010051205 A CN202010051205 A CN 202010051205A CN 111058289 A CN111058289 A CN 111058289A
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- China
- Prior art keywords
- cotton fabric
- solution
- pectinase
- sodium periodate
- cellulase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229920000742 Cotton Polymers 0.000 title claims abstract description 61
- 239000004744 fabric Substances 0.000 title claims abstract description 56
- JQWHASGSAFIOCM-UHFFFAOYSA-M sodium periodate Chemical compound [Na+].[O-]I(=O)(=O)=O JQWHASGSAFIOCM-UHFFFAOYSA-M 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 12
- 230000002708 enhancing effect Effects 0.000 title claims abstract description 5
- 108010059820 Polygalacturonase Proteins 0.000 claims abstract description 24
- 108010093305 exopolygalacturonase Proteins 0.000 claims abstract description 24
- 108010059892 Cellulase Proteins 0.000 claims abstract description 23
- 229940106157 cellulase Drugs 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 238000011282 treatment Methods 0.000 abstract description 19
- 230000003647 oxidation Effects 0.000 abstract description 7
- 238000007254 oxidation reaction Methods 0.000 abstract description 7
- 239000004753 textile Substances 0.000 abstract description 7
- 238000004043 dyeing Methods 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000000835 fiber Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 125000003172 aldehyde group Chemical group 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 108010093096 Immobilized Enzymes Proteins 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000009739 binding Methods 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229940079919 digestives enzyme preparation Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/30—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with oxides of halogens, oxyacids of halogens or their salts, e.g. with perchlorates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
本发明涉及一种增强高碘酸钠氧化棉织物吸湿性的方法，属于纺织印染技术领域。本发明采用以下工艺：（1）在水中加入质量比为2:1的纤维素酶和果胶酶，充分搅拌溶解；（2）在上述溶液中浸入高碘酸钠处理的棉织物，控制浴比为20:1，棉织物与纤维素酶、果胶酶的质量比为100:1:0.5，然后将溶液升温至50℃处理1‑3h；（3）将棉织物从溶液中取出，脱水晾干。本发明利用纤维素酶、果胶酶协同使用对高碘酸钠氧化处理后的棉织物进行改性，可有效改善因为氧化而造成的吸湿性下降的问题。The invention relates to a method for enhancing the hygroscopicity of sodium periodate oxidized cotton fabric, and belongs to the technical field of textile printing and dyeing. The present invention adopts the following process: (1) adding cellulase and pectinase in water with a mass ratio of 2:1, fully stirring and dissolving; (2) immersing the cotton fabric treated with sodium periodate in the above solution, and controlling the bath The ratio is 20:1, the mass ratio of cotton fabric to cellulase and pectinase is 100:1:0.5, and then the solution is heated to 50 °C for 1-3h; (3) The cotton fabric is taken out of the solution and dehydrated Let dry. The invention utilizes the synergistic use of cellulase and pectinase to modify the cotton fabric after the oxidation treatment of sodium periodate, and can effectively improve the problem of the decrease in hygroscopicity caused by the oxidation.
Description
Technical Field
The invention relates to a method for enhancing the moisture absorption of sodium periodate-cotton oxide fabric, belonging to the technical field of textile printing and dyeing.
Background
The cotton fiber is a polysaccharide substance whose basic constituent substance is cellulose, and has the characteristics of moisture absorption, heat preservation, heat resistance, alkali resistance, sanitation and the like. Generally, cotton fibers have a strong absorption capacity for gaseous moisture, i.e., have a good moisture absorption. The hygroscopicity of the fibers depends mainly on the chemical structure of the fibers, i.e. the polarity and number of hydrophilic groups on the macromolecular chains of the fibers. Normally, cotton fibers absorb moisture from the surrounding atmosphere, making them soft and not stiff. If the humidity of the cotton cloth is increased and the ambient temperature is higher, the moisture content in the fiber can be evaporated and dispersed, so that the fabric keeps a water balance state and people feel comfortable.
After the cotton fabric absorbs moisture, the electrostatic property, the mechanical property, the friction property, the optical property and the like of the cotton fabric are changed, the relationship with the dyeing, finishing effect and the like of the textile is close, and the size stability of the textile is also influenced. Therefore, the moisture absorption of the fiber is an important characteristic of the fiber for clothing, and is very important in the production process. The moisture absorption of cotton fabrics is often expressed in terms of moisture regain and moisture content. The moisture regain is the percentage of the mass of water in the textile fibres relative to the mass of the absolutely dry fibres, and the moisture content is the percentage of the mass of water contained in the textile fibres relative to the mass of the fibres not dried.
In order to expand the application range of cellulose substances such as cotton and the like, periodate is often used in industry to carry out selective oxidation treatment on the cellulose substances, and the prepared product has the characteristics of good biocompatibility, degradability, environmental friendliness and the like, and can also be applied to the fields of fluorescence, energy storage, chelation, immobilized enzyme and the like, so that the research on the periodate is a hotspot in recent years. However, after periodate oxidation, glucose residual groups in the cotton fiber macromolecules are broken, and hydroxyl groups at the 2 and 3 positions are converted into aldehyde groups, so that the hygroscopicity of the cotton fiber macromolecules is remarkably reduced, and the comfort, the colorability and the like are adversely affected.
Disclosure of Invention
The method utilizes the synergistic use of the cellulase and the pectinase to modify the cotton fabric subjected to the sodium periodate oxidation treatment, and effectively solves the problem of reduced hygroscopicity caused by oxidation.
The invention adopts the following process:
(1) adding cellulase and pectinase in a mass ratio of 2:1 into water, and fully stirring for dissolving;
(2) soaking the cotton fabric treated by the sodium periodate in the solution, controlling the bath ratio to be 20:1, and the mass ratio of the cotton fabric to the cellulase and the pectinase to be 100:1:0.5, and then heating the solution to 50 ℃ for treatment for 1-3 h;
(3) taking the cotton fabric out of the solution, dewatering and airing.
Firstly, adding cellulase and pectinase with the mass ratio of 2:1 into water, and fully stirring and dissolving. Cellulase and pectinase are commercially available enzyme preparations for textile use. The cotton fabric treated with sodium periodate was put into the above solution. Sodium periodate is oxidized to selectively oxidize the macromolecules of the cotton fibers, and partial 2-and 3-site hydroxyl groups are converted into aldehyde groups, so that the moisture absorption is obviously reduced. Controlling the bath ratio to be 20:1, controlling the mass ratio of the cotton fabric to the added cellulase and pectinase to be 100:1:0.5, and then heating the solution to 50 ℃ for treatment for 1-3 h. In the process, the cellulase and the pectinase generate structure extension and association, and are transferred to and attached to the surface of the oxidized cotton fabric and generate binding reaction with the oxidized cotton fabric, so that the spatial structure, amino acid distribution, interaction and the like of the cellulase and the pectinase are further promoted to be adjusted, the polarity, the affinity and the hydrophobicity and the charge distribution characteristic of the surface of the fabric are synergistically changed, and finally, the hygroscopicity of the surface of the oxidized cotton fabric is improved. And finally, taking the cotton fabric out of the solution, dehydrating and airing.
Detailed Description
The invention is further illustrated by the following comparative examples and examples.
Example 1
Cotton fabric oxidized with sodium periodate (less oxidized) was treated as follows:
(1) adding cellulase and pectinase in a mass ratio of 2:1 into water, and fully stirring for dissolving;
(2) adding a cotton fabric into the solution, controlling the bath ratio to be 20:1, and the mass ratio of the cotton fabric to the cellulase and the pectinase to be 100:1:0.5, and then heating the solution to 50 ℃ for treatment for 1 h;
(3) taking the cotton fabric out of the solution, dewatering and airing.
Comparative example 1
The same cotton fabric as in example 1 was subjected to the following treatments:
(1) adding the same cellulase as in example 1 into water, and fully stirring for dissolving;
(2) adding a cotton fabric into the solution, controlling the bath ratio to be 20:1 and the mass ratio of the cotton fabric to the cellulase to be 100:1, and then heating the solution to 50 ℃ for treatment for 1 h;
(3) taking the cotton fabric out of the solution, dewatering and airing.
Comparative example 2
The same cotton fabric as in example 1 was subjected to the following treatments:
(1) adding the same pectinase as the one in the example 1 into water, and fully stirring for dissolving;
(2) adding a cotton fabric into the solution, controlling the bath ratio to be 20:1 and the mass ratio of the cotton fabric to the pectinase to be 100:0.5, and then heating the solution to 50 ℃ for treatment for 1 h;
(3) taking the cotton fabric out of the solution, dewatering and airing.
Tests show that after the treatment of the example 1, the comparative example 1 and the comparative example 2, the hygroscopicity of the sodium periodate oxidized cotton fabric is respectively improved by 79%, 15% and 9%, which shows that the hygroscopicity of the sodium periodate oxidized cotton fabric can be effectively and synergistically improved by using the method of combined treatment of cellulase and pectinase.
Example 2
Cotton fabric oxidized with sodium periodate (higher degree of oxidation) was treated as follows:
(1) adding cellulase and pectinase in a mass ratio of 2:1 into water, and fully stirring for dissolving;
(2) adding a cotton fabric into the solution, controlling the bath ratio to be 20:1, and the mass ratio of the cotton fabric to the cellulase and the pectinase to be 100:1:0.5, and then heating the solution to 50 ℃ for treatment for 3 hours;
(3) taking the cotton fabric out of the solution, dewatering and airing.
Comparative example 3
The same cotton fabric as in example 2 was subjected to the following treatments:
(1) adding the same cellulase as in example 2 into water, and fully stirring for dissolving;
(2) adding a cotton fabric into the solution, controlling the bath ratio to be 20:1 and the mass ratio of the cotton fabric to the cellulase to be 100:1, and then heating the solution to 50 ℃ for treatment for 3 hours;
(3) taking the cotton fabric out of the solution, dewatering and airing.
Comparative example 4
The same cotton fabric as in example 2 was subjected to the following treatments:
(1) adding the same pectinase as the pectinase in the embodiment 2 into water, and fully stirring for dissolving;
(2) adding a cotton fabric into the solution, controlling the bath ratio to be 20:1 and the mass ratio of the cotton fabric to the pectinase to be 100:0.5, and then heating the solution to 50 ℃ for treatment for 3 hours;
(3) taking the cotton fabric out of the solution, dewatering and airing.
Tests show that after the treatment of the example 2, the comparative example 3 and the comparative example 4, the hygroscopicity of the sodium periodate oxidized cotton fabric is respectively increased by 88%, 27% and 11%, which shows that the hygroscopicity of the sodium periodate oxidized cotton fabric can be effectively and synergistically improved by using the method of combined treatment of cellulase and pectinase.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010051205.8A CN111058289A (en) | 2020-01-17 | 2020-01-17 | A kind of method for enhancing the hygroscopicity of sodium periodate oxidized cotton fabric |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010051205.8A CN111058289A (en) | 2020-01-17 | 2020-01-17 | A kind of method for enhancing the hygroscopicity of sodium periodate oxidized cotton fabric |
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|---|---|
| CN111058289A true CN111058289A (en) | 2020-04-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202010051205.8A Pending CN111058289A (en) | 2020-01-17 | 2020-01-17 | A kind of method for enhancing the hygroscopicity of sodium periodate oxidized cotton fabric |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1212727A (en) * | 1996-03-06 | 1999-03-31 | 加利福尼亚大学董事会 | Enzyme treatment to enhance wettability and absorbency of textiles |
| CN1489377A (en) * | 2003-08-13 | 2004-04-14 | ������������ҽ��ϵͳ�ɷ�����˾ | Series lens image system of electric-controlled fixing diaphragm for x-ray machine |
| CN1793484A (en) * | 2005-12-29 | 2006-06-28 | 苏州大学 | Process for preparing modified cotton fibre |
| CN102851990A (en) * | 2012-09-26 | 2013-01-02 | 江苏波波熊纺织品有限公司 | Machine-woven colored-cotton fabric arranging technology |
| CN107724091A (en) * | 2017-09-20 | 2018-02-23 | 莆田学院 | The biological complex enzyme and its pretreatment scouring process of a kind of pretreatment scouring process for bafta dyeing and finishing |
| CN108893972A (en) * | 2018-06-22 | 2018-11-27 | 苏州市天翱特种织绣有限公司 | A kind of method of modifying of cotton fiber fabric |
| WO2019222978A1 (en) * | 2018-05-24 | 2019-11-28 | 盐城市宏贵针织有限公司 | Knitted undergarment fabric and processing process therefor |
-
2020
- 2020-01-17 CN CN202010051205.8A patent/CN111058289A/en active Pending
Patent Citations (7)
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| CN1212727A (en) * | 1996-03-06 | 1999-03-31 | 加利福尼亚大学董事会 | Enzyme treatment to enhance wettability and absorbency of textiles |
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| CN1793484A (en) * | 2005-12-29 | 2006-06-28 | 苏州大学 | Process for preparing modified cotton fibre |
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| CN107724091A (en) * | 2017-09-20 | 2018-02-23 | 莆田学院 | The biological complex enzyme and its pretreatment scouring process of a kind of pretreatment scouring process for bafta dyeing and finishing |
| WO2019222978A1 (en) * | 2018-05-24 | 2019-11-28 | 盐城市宏贵针织有限公司 | Knitted undergarment fabric and processing process therefor |
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Non-Patent Citations (4)
| Title |
|---|
| TANJA NIKOLIĆ等: "SORPTION PROPERTIES OF PERIODATE OXIDIZED COTTON", 《CHEM.IND. CHEM. ENG. Q.》 * |
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Application publication date: 20200424 |