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CN111011385A - Nematicidal composition - Google Patents

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Publication number
CN111011385A
CN111011385A CN201911054258.9A CN201911054258A CN111011385A CN 111011385 A CN111011385 A CN 111011385A CN 201911054258 A CN201911054258 A CN 201911054258A CN 111011385 A CN111011385 A CN 111011385A
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Prior art keywords
ethylicin
composition
composition according
nematicidal
fluensulfone
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Chinese (zh)
Inventor
唐兴敏
柴方堃
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Hebei Veyong Bio Chemical Co ltd
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Hebei Veyong Bio Chemical Co ltd
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Priority to CN201911054258.9A priority Critical patent/CN111011385A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/781,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof
    • A01N41/08Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a nematicidal composition, which belongs to the technical field of pesticides, and comprises active ingredients of fluensulfone and ethylicin, wherein the mass ratio of the fluensulfone to the ethylicin is 40: 1-1: 40, the active ingredients also comprise rapeseed sterol lactone, and the weight ratio of the rapeseed sterol lactone is not more than 2%. Meanwhile, by compounding and synergism, the pesticide dosage is reduced, the pesticide application frequency is reduced, the pesticide is safer for crops, and the pesticide has the characteristics of safety to environment and human and low toxicity.

Description

Nematicidal composition
Technical Field
The invention relates to a nematicidal composition, and belongs to the technical field of pesticides.
Background
Plant parasitic nematodes mainly include: meloidogyne, reniform nematoda, heterodera, pratylenchus, restylenchus, longneedle nematoda, sword-leaved nematoda, burseoma, strongyloides. Nematodes not only directly harm host plants and affect the absorption of plants to nutrients and moisture, but also spread bacteria and viruses. Chemical control plays an important role in the control process of nematodes, and various nematicides exist in the market of China at present, but most nematicides belong to high toxicity, and have the problems of high toxicity, serious environmental pollution, insignificant control effect, easy generation of drug resistance of nematodes and the like.
Fluensulfone, common english name: fluensulfone, discovered in the last 90 th century, acquired a registered non-fumigant nematicide in the united states in 2014, which had a control effect on a variety of plant nematodes. The fluensulfone is a fluoroolefin thioether compound, has control effect on various plant parasitic nematodes, can cause the nematodes to paralyze and stop feeding in a short time, and finally irreversibly kills the nematodes. The fluensulfone can also reduce the hatching of nematode eggs, the survival rate of larvae and the number of eggs. And the fluensulfone has low toxicity, such as low toxicity to beneficial and non-target organisms, and is a green substitute for a plurality of carbamate and organophosphorus nematicides and the like.
Ethylicin, the chemical name of which is ethyl thiosulfonate and the English common name of which is ethylicin, is a plant source bionic pesticide and is an ethyl homolog of edible garlic extract allicin.
Brassicasterol lactones, a growth-promoting plant hormone, belong to the class of sterol polyhydroxy derivatives. Similar to animal steroid hormones, the polypeptide has specific receptors, can regulate the expression of specific genes, plays an important role in plant cell division, embryo formation and development, and can improve the tolerance and yield of plants such as wheat, cereals, soybeans, spinach, citrus and the like to environmental stress, but reports for the technical field of pesticides are few.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a nematicidal composition, which can increase the control effect of plant pests caused by root-knot nematodes and the like, obviously reduce the dosage of pesticides, reduce the frequency of pesticide application and is safer to environment, crops, animals and human beings.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows:
a nematicidal composition comprises the effective components of fluensulfone and ethylicin.
The technical scheme of the invention is further improved as follows: the effective component in the composition also comprises brassinosteroid lactone.
The technical scheme of the invention is further improved as follows: the mass ratio of the effective components of the fluensulfone and ethylicin in the composition is 40: 1-1: 40.
The technical scheme of the invention is further improved as follows: the mass ratio of the effective components of the fluensulfone and ethylicin in the composition is 15: 1-1: 15.
The technical scheme of the invention is further improved as follows: the weight ratio of the rapeseed sterol lactone is not more than 2%.
The technical scheme of the invention is further improved as follows: the total mass percentage of the active ingredients in the composition is 0.5-85%.
The technical scheme of the invention is further improved as follows: the formulation of the composition is any one of suspending agent, aqueous emulsion, microemulsion, missible oil, wettable powder, water dispersible granule and granule.
The technical scheme of the invention is further improved as follows: the composition can be applied in any one of spraying, root irrigation, root soaking, seed soaking, throwing, broadcasting, furrow application and hole application.
The technical scheme of the invention is further improved as follows: the administration mode of the composition dosage form is any one of root irrigation, root soaking, seed soaking, furrow application and hole application.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows:
the nematicidal composition is applied to control plant nematodes.
Due to the adoption of the technical scheme, the invention has the technical progress that:
the invention has very obvious effect of preventing and controlling the nematodes, and is particularly suitable for preventing and controlling the nematodes of vegetable crops, grain crops, medicinal plants, lawns, fruit trees, flowers and the like. Such as species of Heterodera, Heterodera globifolia, pratylenchus, Paratylenchus, Ostertagia, Sclerodera, Paratylenchus, Heterodera, Globodera, Meloidogyne, Globodera, Bursaphelodera, and Bursaphelenchus.
The compound nematicide is mainly formed by compounding fluensulfone and ethylicin according to a certain proportion and adding a certain amount of brassinosteroid, can obviously increase the control effect of plant pests caused by root-knot nematodes and the like compared with a single agent, and has obvious synergistic effect; the action mechanisms of the effective components in the nematicidal composition are different, so that the single selection pressure on the nematodes is reduced, and the generation of nematode resistance is overcome and the generation speed of the nematode resistance is delayed; by compounding and synergism, the dosage of pesticide is reduced, the frequency of pesticide application is reduced, and the pesticide is safer for environment, crops, animals and human beings; the rapeseed sterol lactone added in the composition can stimulate the growth of crops, plays a role in strengthening seedlings and improves the tolerance capability.
The invention can be prepared into various dosage forms suitable for agricultural production according to the known method, is suitable for various application modes, and has wide application range and convenient application.
Detailed Description
The present invention will be described in further detail with reference to the following examples:
first, an embodiment
Example 141% Fluthiacetone and ethylicin wettable powder
Figure BDA0002256134520000031
According to the formula requirements, the raw pesticide, various auxiliary agents, fillers and the like are fully mixed and crushed by a jet mill until the fineness reaches a standard value, and then the product of the composition wettable powder is obtained.
Example 230% Fluthiacetone and ethylicin wettable powders
Figure BDA0002256134520000032
Figure BDA0002256134520000041
According to the formula requirements, the raw pesticide, various auxiliary agents, fillers and the like are fully mixed and crushed by a jet mill until the fineness reaches a standard value, and then the product of the composition wettable powder is obtained.
Example 316% Fluthiacetone and ethylicin granules
Figure BDA0002256134520000042
Mixing the above raw materials with powdery carrier, wetting agent, and adhesive at a certain proportion, pulverizing with coarse pulverizer, adding a certain amount of water, kneading, granulating in granulator, and drying to obtain granular product
Example 440% Fluthiacetone and ethylicin granules
Figure BDA0002256134520000043
Mixing the above raw materials with powdery carrier, wetting agent, and adhesive at a certain proportion, pulverizing with coarse pulverizer, adding a certain amount of water, kneading, granulating in granulator, and drying to obtain granular product
Example 541% Fluthiamethoxam sulfone and ethylicin suspension
Figure BDA0002256134520000044
Figure BDA0002256134520000051
Dissolving ethylicin into a uniform oil phase, uniformly mixing with the fluensulfone, the wetting dispersant, the thickening agent, the carrier, water and other components according to the proportion of the formula, and grinding and/or shearing at high speed to obtain the suspending agent.
Example 645% Fluthiacetone and ethylicin emulsifiable concentrate
Figure BDA0002256134520000052
According to the formula requirement, respectively adding solvent, original medicine and emulsifier, and uniformly mixing to obtain transparent emulsifiable solution.
Example 716% Thiofloxacin sulfone with ethylicin microemulsion
Figure BDA0002256134520000053
Adding active ingredients, a solvent, a cosolvent and an emulsifier together to dissolve into a uniform oil phase; adding water soluble substance into water, dissolving to obtain uniform water phase, and mixing oil phase and water phase under stirring to obtain microemulsion.
Example 80.5% Fluthiacetone and ethylicin soluble concentrate
Figure BDA0002256134520000054
Figure BDA0002256134520000061
According to the formula requirements, respectively adding solvent, original medicine and emulsifier, and uniformly mixing to obtain transparent soluble liquid.
Example 985% Fluthiamethoxam sulfone and ethylicin dispersible granules
Figure BDA0002256134520000062
The active ingredients, the dispersing agent, the wetting agent, the disintegrating agent and the filler are uniformly mixed according to the proportion of the formula, and are crushed into wettable powder by airflow, and a certain amount of water is added for mixing and extrusion molding. And drying and screening to obtain the water dispersible granule.
Second, comparative example
Comparative example 141% fluthiacet sulfone and ethylicin wettable powder
Figure BDA0002256134520000063
According to the formula requirements, the raw pesticide, various auxiliary agents, fillers and the like are fully mixed and crushed by a jet mill until the fineness reaches a standard value, and then the product of the composition wettable powder is obtained.
Comparative example 230% fluthiacet sulfone and ethylicin wettable powder
Figure BDA0002256134520000064
Figure BDA0002256134520000071
According to the formula requirements, the raw pesticide, various auxiliary agents, fillers and the like are fully mixed and crushed by a jet mill until the fineness reaches a standard value, and then the product of the composition wettable powder is obtained.
Comparative example 316% Fluthiacetone and ethylicin granules
Figure BDA0002256134520000072
Mixing the above raw materials with powdery carrier, wetting agent, and adhesive at a certain proportion, pulverizing with coarse pulverizer, adding a certain amount of water, kneading, granulating in granulator, and drying to obtain granular product
Comparative example 440% Fluthiacetone and ethylicin granules
Figure BDA0002256134520000073
Mixing the above raw materials with powdery carrier, wetting agent, and adhesive at a certain proportion, pulverizing with coarse pulverizer, adding a certain amount of water, kneading, granulating in granulator, and drying to obtain granular product
Comparative example 541% Fluthiamethoxam sulfone and ethylicin suspension
Figure BDA0002256134520000074
Figure BDA0002256134520000081
Dissolving ethylicin into a uniform oil phase, uniformly mixing with the fluensulfone, the wetting dispersant, the thickening agent, the carrier, water and other components according to the proportion of the formula, and grinding and/or shearing at high speed to obtain the suspending agent.
Comparative example 645% Fluthiacetone and ethylicin emulsifiable concentrate
Figure BDA0002256134520000082
According to the formula requirement, respectively adding solvent, original medicine and emulsifier, and uniformly mixing to obtain transparent emulsifiable solution.
Comparative example 716% Fluthiacetone and ethylicin microemulsion
Figure BDA0002256134520000083
Adding active ingredients, a solvent, a cosolvent and an emulsifier together to dissolve into a uniform oil phase; adding water soluble substance into water, dissolving to obtain uniform water phase, and mixing oil phase and water phase under stirring to obtain microemulsion.
Comparative example 80.5% Fluthiacetone and ethylicin soluble liquid formulation
Figure BDA0002256134520000091
According to the formula requirements, respectively adding solvent, original medicine and emulsifier, and uniformly mixing to obtain transparent soluble liquid.
Comparative example 985% Fluthiamethoxam sulfone and ethylicin dispersible granule
Figure BDA0002256134520000092
The active ingredients, the dispersing agent, the wetting agent, the disintegrating agent and the filler are uniformly mixed according to the proportion of the formula, and are crushed into wettable powder by airflow, and a certain amount of water is added for mixing and extrusion molding. And drying and screening to obtain the water dispersible granule.
Comparative example 1060% Fluthiamethoxam sulfone dispersible granules
Figure BDA0002256134520000093
Figure BDA0002256134520000101
The active ingredients, the dispersing agent, the wetting agent, the disintegrating agent and the filler are uniformly mixed according to the proportion of the formula, and are crushed into wettable powder by airflow, and a certain amount of water is added for mixing and extrusion molding. And drying and screening to obtain the water dispersible granule.
Comparative example 1160% ethylicin dispersible granule
Figure BDA0002256134520000102
The active ingredients, the dispersing agent, the wetting agent, the disintegrating agent and the filler are uniformly mixed according to the proportion of the formula, and are crushed into wettable powder by airflow, and a certain amount of water is added for mixing and extrusion molding. And drying and screening to obtain the water dispersible granule.
Third, field drug effect test example
1. Control effect on tomato root-knot nematode
The test is carried out in a vegetable greenhouse of Baoding city in Hebei province in 11 months in 2018, a root irrigation method is adopted, 100ml of tomatoes are irrigated into each tomato, the selected tomatoes basically grow consistently and are in a vegetative growth period, nematodes are heavier in the past year, and the damage condition of the tomato roots is checked at 30 days and 60 days after the application of the tomato roots. As can be seen from the data in Table 2, the synergistic effect of various formulations is obvious after the fluensulfone and ethylicin are compounded; the control effect of each compound medicament on the nematodes 30 days and 60 days after the application is also obviously better than that of a single medicament.
TABLE 1 field control Effect of Fluthiacetone and ethylicin combination on tomato root-knot nematode
Figure BDA0002256134520000103
Figure BDA0002256134520000111
2. Prevention and treatment effect on soybean cyst nematode
The test is carried out on a farm in Shenyang city of Liaoning province in 2018, the root spraying method is adopted in the test, the selected soybeans in the test field are in the seedling stage, the plants grow basically consistently, the nematodes grow seriously in the past year, and the damage condition of the roots of the soybeans is checked at 30 days and 60 days after the application of the pesticide. As can be seen from the data in Table 3, the synergistic effect of various formulations is obvious after the fluensulfone and ethylicin are compounded; the control effect of each compound medicament on the soybean cyst nematodes 30 days and 60 days after the application is also obviously better than that of a single medicament.
TABLE 2 field control of soybean cyst nematodes by combination of fluensulfone and ethylicin
Figure BDA0002256134520000121
From the field control effect of the compound of the fluensulfone and the ethylicin on the tomato root-knot nematode and the soybean cyst nematode, the control effect of each compound medicament is obviously better than that of a single medicament, which indicates that the compound has a synergistic effect; and after the rape seed sterol lactone is added into the compound preparation of the fluensulfone and the ethylicin, the control effect is obviously improved, the synergistic effect is enhanced, the lasting period is prolonged, and the aims of reducing the dosage and the application frequency, delaying the generation of drug resistance of harmful nematodes and reducing the control cost can be achieved.
The present invention is not limited to the above preferred embodiments, and any modifications, equivalent substitutions and improvements made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. A nematicidal composition comprising: the effective components of the composition comprise fluensulfone and ethylicin.
2. A nematicidal composition according to claim 1, wherein: the effective component in the composition also comprises brassinosteroid lactone.
3. A nematicidal composition according to claim 1, wherein: the mass ratio of the effective components of the fluensulfone and ethylicin in the composition is 40: 1-1: 40.
4. A nematicidal composition according to claim 3, wherein: the mass ratio of the effective components of the fluensulfone and ethylicin in the composition is 15: 1-1: 15.
5. A nematicidal composition according to claim 2, wherein: the weight ratio of the rapeseed sterol lactone is not more than 2%.
6. A nematicidal composition according to any one of claims 1 to 5, wherein: the total mass percentage of the active ingredients in the composition is 0.5-85%.
7. A nematicidal composition according to claim 6, wherein: the formulation of the composition is any one of suspending agent, aqueous emulsion, microemulsion, missible oil, wettable powder, water dispersible granule and granule.
8. A nematicidal composition according to claim 7, wherein: the composition can be applied in any one of spraying, root irrigation, root soaking, seed soaking, throwing, broadcasting, furrow application and hole application.
9. A nematicidal composition according to claim 8, wherein: the administration mode of the composition dosage form is any one of root irrigation, root soaking, seed soaking, furrow application and hole application.
10. Use of a nematicidal composition according to any one of claims 1 to 5 and 7 to 8 to control plant nematodes.
CN201911054258.9A 2019-10-31 2019-10-31 Nematicidal composition Pending CN111011385A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112602721A (en) * 2020-12-15 2021-04-06 美丰农业科技(上海)有限公司 Agricultural composition for killing nematodes
WO2022099971A1 (en) * 2020-11-13 2022-05-19 海南大学 Method for controlling plant nematodes

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1359379A (en) * 1999-07-06 2002-07-17 日本拜耳农药株式会社 Nematicidal trifluorobutenes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1359379A (en) * 1999-07-06 2002-07-17 日本拜耳农药株式会社 Nematicidal trifluorobutenes

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
师迎春 等: "《菜园农药安全使用技术》", 31 August 2004, 中国农业出版社 *
毛丹 等: "《农作物科学用药手册》", 28 February 2018, 中原农民出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022099971A1 (en) * 2020-11-13 2022-05-19 海南大学 Method for controlling plant nematodes
CN112602721A (en) * 2020-12-15 2021-04-06 美丰农业科技(上海)有限公司 Agricultural composition for killing nematodes

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Application publication date: 20200417