CN110858673A - New energy automobile storage battery recycling device and recycling method thereof - Google Patents
New energy automobile storage battery recycling device and recycling method thereof Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 44
- 238000004064 recycling Methods 0.000 title claims abstract description 28
- 238000003860 storage Methods 0.000 title claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 31
- 229910052751 metal Inorganic materials 0.000 claims abstract description 31
- 239000007788 liquid Substances 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 11
- 238000011084 recovery Methods 0.000 claims abstract description 11
- 229920003023 plastic Polymers 0.000 claims description 58
- 238000005406 washing Methods 0.000 claims description 48
- 239000002253 acid Substances 0.000 claims description 34
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 26
- 239000002245 particle Substances 0.000 claims description 25
- 239000003792 electrolyte Substances 0.000 claims description 15
- 239000007769 metal material Substances 0.000 claims description 13
- 238000006386 neutralization reaction Methods 0.000 claims description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 238000005469 granulation Methods 0.000 claims description 9
- 230000003179 granulation Effects 0.000 claims description 9
- 239000002699 waste material Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 claims description 6
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims description 6
- 239000012779 reinforcing material Substances 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 4
- 239000006148 magnetic separator Substances 0.000 claims description 4
- 229920000426 Microplastic Polymers 0.000 claims description 3
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- 239000002516 radical scavenger Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- 230000032258 transport Effects 0.000 claims 1
- 239000010926 waste battery Substances 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- 239000003570 air Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000009933 burial Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
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- Manufacturing & Machinery (AREA)
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Abstract
本发明公开了一种新能源汽车蓄电池回收处理装置及其回收方法,包括料仓,所述料仓的顶部设置有抓斗吊车,所述料仓顶部的右侧设置有链板运输机,所述链板运输机的底部安装有锤式破碎机,所述锤式破碎机左侧的底部设置有电池液储罐,所述锤式破碎机右侧的底部安装有金属破碎机,金属破碎机的出料口设置有第一皮带运输机。本发明考虑了废旧蓄电池回收过程中的综合回收,并完善了回收过程中的环境保护,对环境友好,过程中产生的空气、水体、和固体污染都降低到最小程度,废旧蓄电池的物料利用率高,处理费用比较低,从经济的角度考虑比较划算,由于工艺过程在低温下完成,能源消耗比较低,对设备要求也比较低,整体投资小。
The invention discloses a new energy vehicle battery recovery and processing device and a recovery method thereof, comprising a silo, a grab crane is arranged on the top of the silo, a chain plate conveyor is arranged on the right side of the top of the silo, and the A hammer crusher is installed at the bottom of the chain plate conveyor, a battery liquid storage tank is arranged at the bottom of the left side of the hammer crusher, a metal crusher is installed at the bottom of the right side of the hammer crusher, and the outlet of the metal crusher is installed. The material port is provided with a first belt conveyor. The invention considers the comprehensive recovery in the recycling process of the waste battery, improves the environmental protection in the recycling process, is friendly to the environment, reduces the air, water and solid pollution generated in the process to a minimum, and the material utilization rate of the waste battery is reduced to a minimum. It is more cost-effective from an economic point of view. Since the process is completed at low temperature, the energy consumption is relatively low, the equipment requirements are relatively low, and the overall investment is small.
Description
技术领域technical field
本发明涉及电池回收技术领域,尤其涉及一种新能源汽车蓄电池回收处理装置及其回收方法。The invention relates to the technical field of battery recycling, in particular to a new energy vehicle battery recycling and processing device and a recycling method thereof.
背景技术Background technique
能源汽车是指采用非常规的车用燃料作为动力来源(或使用常规的车用燃料、采用新型车载动力装置),综合车辆的动力控制和驱动方面的先进技术,形成的技术原理先进、具有新技术、新结构的汽车,现有新能源汽车大都采用蓄电池作为动力来源。Energy vehicles refer to the use of unconventional vehicle fuels as the power source (or the use of conventional vehicle fuels and the use of new vehicle-mounted power units), and the integration of advanced technologies in vehicle power control and drive. Most of the existing new energy vehicles use batteries as the power source for vehicles with technology and new structure.
铅酸蓄电池的污染需要引起我们的重视,铅酸蓄电池由于其性价比高、功率特性好、自放电小、高低温性能优越、运行安全可靠、回收技术成熟以及铅的再利用率高等优点,长期以来一直是世界上产量最大的电池产品,其产值及销售额至今仍占全球电池的一半,占二次电池的70%。今天,中国已经发展成为全球铅酸蓄电池的生产基地,铅的消耗量已经超过美国成为全球铅用量的第一大国。目前对环境危害比较严重的是废旧蓄电池的回收、拆解及冶炼过程。具有一定经济规模的大型再生铅企业,在环保上做了很大的投入,有的甚至实现了在线监测。而小的冶炼厂则设施过于简陋,甚至不设任何的环保设施。尤其是一些小作坊的手工拆解和冶炼,不仅对环境造成严重危害,而且也对从业人员的健康构成危害,且资源的综合利用率低。The pollution of lead-acid batteries needs our attention. Due to its high cost performance, good power characteristics, low self-discharge, superior high and low temperature performance, safe and reliable operation, mature recycling technology and high lead reuse rate, lead-acid batteries have been used for a long time. It has always been the largest battery product in the world, and its output value and sales still account for half of the global battery and 70% of the secondary battery. Today, China has developed into a global lead-acid battery production base, and the consumption of lead has surpassed the United States to become the world's largest lead consumption country. At present, the most serious harm to the environment is the recycling, dismantling and smelting process of used batteries. Large-scale secondary lead enterprises with a certain economic scale have made a lot of investment in environmental protection, and some have even realized online monitoring. The small smelters are too rudimentary and do not even have any environmental protection facilities. In particular, the manual dismantling and smelting of some small workshops not only causes serious harm to the environment, but also harms the health of employees, and the comprehensive utilization rate of resources is low.
现有铅蓄电池处理大多采用固化深埋、存放于废矿井。废电池一般都运往专门的有毒、有害垃圾填埋场,因为其中尚有不少可作原料的有用物质,但这种做法不仅花费太大而且还造成浪费。为此,我们提出一种新能源汽车蓄电池回收处理装置及其回收方法。Most of the existing lead-acid battery treatment adopts solidification and deep burial, and is stored in waste mines. Waste batteries are generally transported to special toxic and hazardous landfills, because there are still many useful substances that can be used as raw materials, but this approach is not only expensive but also wasteful. To this end, we propose a new energy vehicle battery recycling device and its recycling method.
发明内容SUMMARY OF THE INVENTION
基于背景技术存在的技术问题,本发明提出了一种新能源汽车蓄电池回收处理装置及其回收方法,具有回收报废铅酸蓄电池,并再生成为铅酸蓄电池生产原料的特点,解决了现有蓄电池处理方法不仅花费太大,而且还造成浪费的问题。Based on the technical problems existing in the background technology, the present invention proposes a new energy vehicle battery recycling and processing device and a recycling method thereof, which have the characteristics of recycling scrap lead-acid batteries and regenerating them into lead-acid battery production raw materials, which solves the problem of the existing battery disposal. The method is not only too expensive, but also creates the problem of waste.
本发明提供如下技术方案:The present invention provides the following technical solutions:
一种新能源汽车蓄电池回收处理装置,包括料仓,所述料仓的顶部设置有抓斗吊车,所述料仓顶部的右侧设置有链板运输机,所述链板运输机的底部安装有锤式破碎机,所述锤式破碎机左侧的底部设置有电池液储罐,所述锤式破碎机右侧的底部安装有金属破碎机,所述金属破碎机的出料口设置有第一皮带运输机,所述第一皮带运输机的顶部安装有强磁分离机,所述金属破碎机通过第一皮带运输机与水力分选槽连接;A new energy vehicle battery recovery and processing device includes a silo, a grab crane is arranged on the top of the silo, a chain plate conveyor is installed on the right side of the top of the silo, and a hammer is installed at the bottom of the chain plate conveyor The bottom of the left side of the hammer crusher is provided with a battery fluid storage tank, the bottom of the right side of the hammer crusher is provided with a metal crusher, and the discharge port of the metal crusher is provided with a first a belt conveyor, a strong magnetic separator is installed on the top of the first belt conveyor, and the metal crusher is connected to the hydraulic sorting tank through the first belt conveyor;
所述水力分选槽的底部设置有分选循环槽,所述分选循环槽的底部活动连接有分选底流槽,所述水力分选槽的顶部设置有塑料打捞机,所述塑料打捞机将物料输送至塑料酸性洗涤槽,所述塑料酸性洗涤槽的右侧连通有中和洗涤池,所述中和洗涤池的右侧设置有塑料烘干机,所述塑料烘干机的出料口设置有第二皮带运输机,所述水力分选槽的右侧通过分选捞料机与金属干燥机连接,所述金属干燥机的顶部连通有排气筒,所述金属干燥机的出料口设置有第三皮带运输机。The bottom of the hydraulic sorting tank is provided with a sorting circulation tank, the bottom of the sorting circulation tank is movably connected with a sorting bottom flow tank, and the top of the hydraulic sorting tank is provided with a plastic fishing machine, the plastic fishing machine The material is transported to the plastic acid washing tank, the right side of the plastic acid washing tank is connected with a neutralization washing tank, and the right side of the neutralization washing tank is provided with a plastic dryer, and the discharge of the plastic dryer is The port is provided with a second belt conveyor, the right side of the hydraulic sorting tank is connected with the metal dryer through the sorting and scavenger, the top of the metal dryer is connected with an exhaust cylinder, and the discharge of the metal dryer The mouth is provided with a third belt conveyor.
优选的,所述塑料酸性洗涤槽的底部设置有酸性循环池,所述中和洗涤池的底部设置有中和循环池。Preferably, an acid circulation tank is arranged at the bottom of the plastic acid washing tank, and a neutralization circulation tank is arranged at the bottom of the neutralization washing tank.
优选的,所述塑料烘干机通过第二皮带运输机连接有塑料料仓,所述金属干燥机通过第三皮带运输机连接有金属料仓。Preferably, the plastic dryer is connected with a plastic silo through a second belt conveyor, and the metal dryer is connected with a metal silo through a third belt conveyor.
一种新能源汽车蓄电池回收处理方法,包括如下步骤:A method for recycling and processing a battery of a new energy vehicle, comprising the following steps:
a、破碎:将蓄电池破碎成利于分选的碎片颗粒,通过采用二级破碎,在一级破碎中,主要对蓄电池进行结构破坏,使电解液分离出来,并使蓄电池破碎到便于二级破碎处理的粒级,二级破碎,使蓄电池破碎到能够分选的粒级;a. Crushing: The battery is crushed into debris particles that are conducive to sorting. By using secondary crushing, in the primary crushing, the structure of the battery is mainly destroyed, the electrolyte is separated, and the battery is crushed to facilitate the secondary crushing treatment. The particle size of the battery is divided into two grades, and the secondary crushing is performed to make the battery crushed to the particle size that can be sorted;
b、除铁:部分蓄电池有铁件作为加强材料,利用强力磁力机进行除铁作业,该过程在碎料运输过程中完成;b. Iron removal: Some batteries have iron parts as reinforcing materials, and a powerful magnetic machine is used for iron removal, which is completed during the transportation of scraps;
c、水力分选:利用塑料与金属材料的不同密度,在液体搅拌机中完成,塑料通过分选机而分离除去,同时电池中的过氧化铅、硫酸铅等物质也通过液体的洗涤而存留在液体中被除去,金属材料颗粒由带式传送机捞出,进入到碱洗工序脱除酸;c. Hydraulic sorting: using the different densities of plastic and metal materials, it is completed in a liquid mixer. The plastic is separated and removed by the sorting machine. At the same time, lead peroxide, lead sulfate and other substances in the battery are also washed by the liquid. It is removed from the liquid, and the metal material particles are pulled out by the belt conveyor and entered into the alkaline washing process to remove the acid;
d、塑料干燥制粒:分离出来的塑料颗粒,进入到洗涤池进行三级碱性洗涤,以除去酸,然后进入烘干机进行烘干,再进入挤压机造粒,得到粒料产品出售;d. Plastic drying and granulation: the separated plastic granules enter the washing tank for three-stage alkaline washing to remove acid, then enter the dryer for drying, and then enter the extruder for granulation to obtain granulated products for sale. ;
e、铅泥回收:主要是在破碎过程中与电解液一起进入到废液罐的铅泥、分选过程中洗涤的铅泥和塑料洗涤产生的铅泥,分别通过三条过滤机组分离。e. Recovery of lead mud: The lead mud that enters the waste liquid tank together with the electrolyte during the crushing process, the lead mud washed in the sorting process and the lead mud produced by plastic washing are separated by three filter units respectively.
优选的,所述回收过程中对酸液进行回收,从破碎过程中产出的电解液是比较纯净的稀硫酸,经过过滤净化后,浓缩再循环使用。Preferably, the acid solution is recovered in the recovery process, and the electrolyte solution produced from the crushing process is relatively pure dilute sulfuric acid, which is concentrated and recycled after being filtered and purified.
本发明提供了一种新能源汽车蓄电池回收处理装置及其回收方法,考虑了废旧蓄电池回收过程中的综合回收,并完善了回收过程中的环境保护,对环境友好,过程中产生的空气、水体、和固体污染都降低到最小程度,废旧蓄电池的物料利用率高,处理费用比较低,从经济的角度考虑比较划算,由于工艺过程在低温下完成,能源消耗比较低,对设备要求也比较低,整体投资小。The invention provides a new energy vehicle battery recycling and processing device and a recycling method, which considers the comprehensive recovery in the recycling process of the waste battery, improves the environmental protection in the recycling process, is environmentally friendly, and generates air and water in the process. , and solid pollution are reduced to a minimum, the material utilization rate of waste batteries is high, and the treatment cost is relatively low, which is more cost-effective from an economic point of view. Because the process is completed at low temperature, the energy consumption is relatively low, and the equipment requirements are relatively low. , the overall investment is small.
附图说明Description of drawings
图1为本发明结构示意图;Fig. 1 is the structural representation of the present invention;
图2为本发明工艺流程图;Fig. 2 is the process flow diagram of the present invention;
图3为本发明塑料处理工艺图。Fig. 3 is a plastic processing process diagram of the present invention.
图中:1料仓、2抓斗吊车、3链板运输机、4锤式破碎机、5电池液储罐、6金属破碎机、7第一皮带运输机、8强磁分离机、9水力分选槽、10分选循环槽、11分选底流槽、12塑料打捞机、13塑料酸性洗涤槽、14中和洗涤池、15塑料烘干机、16第二皮带运输机、17分选捞料机、18金属干燥机、19排气筒、20第三皮带运输机、21酸性循环池、22中和循环池、23塑料料仓、24金属料仓。In the picture: 1 silo, 2 grab crane, 3 chain plate conveyor, 4 hammer crusher, 5 battery liquid storage tank, 6 metal crusher, 7 first belt conveyor, 8 strong magnetic separator, 9 hydraulic separation Tank, 10 sorting circulation tank, 11 sorting bottom flow tank, 12 plastic salvage machine, 13 plastic acid washing tank, 14 neutralizing washing tank, 15 plastic dryer, 16 second belt conveyor, 17 sorting fisher, 18 metal dryers, 19 exhaust tanks, 20 third belt conveyors, 21 acid circulation pools, 22 neutralization circulation pools, 23 plastic silos, 24 metal silos.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
请参阅图1-3,本发明提供一种技术方案:Please refer to Figures 1-3, the present invention provides a technical solution:
一种新能源汽车蓄电池回收处理装置,包括料仓1,料仓1的顶部设置有抓斗吊车2,抓斗吊车2的起重量为5t,料仓1顶部的右侧设置有链板运输机3,链板运输机3的底部安装有锤式破碎机4,锤式破碎机4为一级破碎,锤式破碎机4左侧的底部设置有电池液储罐5,一级破碎后,电池液进入到电池液储罐5,锤式破碎机4右侧的底部安装有金属破碎机6,金属破碎机6进行二级破碎,金属破碎机6为带刀盘金属破碎机,对电池碎片进一步破碎到分离粒度,金属破碎机6的出料口设置有第一皮带运输机7,将碎料运输到水力分选池,第一皮带运输机7的顶部安装有强磁分离机8,将皮带上的物料中铁物料分离,金属破碎机6通过第一皮带运输机7与水力分选槽9连接,水力分选槽9将塑料从分选池中捞出,进入洗涤槽;A new energy vehicle battery recycling and processing device, comprising a silo 1, a grab crane 2 is arranged on the top of the silo 1, the lifting capacity of the grab crane 2 is 5t, and a chain plate conveyor 3 is arranged on the right side of the top of the silo 1 , a hammer crusher 4 is installed at the bottom of the chain plate conveyor 3, the hammer crusher 4 is a primary crusher, and the bottom of the left side of the hammer crusher 4 is provided with a battery fluid storage tank 5. After primary crushing, the battery fluid enters To the battery liquid storage tank 5, a metal crusher 6 is installed at the bottom of the right side of the hammer crusher 4, and the metal crusher 6 performs secondary crushing. To separate the particle size, the discharge port of the metal crusher 6 is provided with a first belt conveyor 7 to transport the scraps to the hydraulic separation tank, and a strong magnetic separator 8 is installed on the top of the first belt conveyor 7 to separate the iron in the material on the belt. Material separation, the metal crusher 6 is connected to the hydraulic sorting tank 9 through the first belt conveyor 7, and the hydraulic sorting tank 9 pulls the plastic out of the sorting tank and enters the washing tank;
水力分选槽9的底部设置有分选循环槽10,分选循环槽10的底部活动连接有分选底流槽11,水力分选槽9的顶部设置有塑料打捞机12,塑料打捞机12将物料输送至塑料酸性洗涤槽13,塑料酸性洗涤槽13的右侧连通有中和洗涤池14,中和洗涤池14的右侧设置有塑料烘干机15,塑料烘干机15的出料口设置有第二皮带运输机16,水力分选槽9的右侧通过分选捞料机17与金属干燥机18连接,金属干燥机18将铅金属物料进行热风干燥,金属干燥机18的顶部连通有排气筒19,金属干燥机18的出料口设置有第三皮带运输机20,塑料酸性洗涤槽13的底部设置有酸性循环池21,中和洗涤池14的底部设置有中和循环池22,塑料烘干机15通过第二皮带运输机16连接有塑料料仓23,金属干燥机18通过第三皮带运输机20连接有金属料仓24。The bottom of the hydraulic sorting tank 9 is provided with a sorting circulation tank 10, the bottom of the sorting circulation tank 10 is movably connected with a sorting bottom flow tank 11, and the top of the hydraulic sorting tank 9 is provided with a plastic fishing machine 12, and the plastic fishing machine 12 will The material is transported to the plastic acid washing tank 13, the right side of the plastic acid washing tank 13 is connected with the neutralization washing tank 14, the right side of the neutralization washing tank 14 is provided with a plastic dryer 15, and the discharge port of the plastic dryer 15 A second belt conveyor 16 is provided, and the right side of the hydraulic sorting tank 9 is connected to a metal dryer 18 through a sorting and scavenger 17. The metal dryer 18 dries the lead metal material with hot air, and the top of the metal dryer 18 is connected with a The exhaust cylinder 19, the discharge port of the metal dryer 18 is provided with a third belt conveyor 20, the bottom of the plastic acid washing tank 13 is provided with an acid circulation tank 21, and the bottom of the neutralization washing tank 14 is provided with a neutralization circulation tank 22, The plastic dryer 15 is connected with a plastic silo 23 through a second belt conveyor 16 , and the metal dryer 18 is connected with a metal silo 24 through a third belt conveyor 20 .
一种新能源汽车蓄电池回收处理方法,包括如下步骤:A method for recycling and processing a battery of a new energy vehicle, comprising the following steps:
a、破碎:将蓄电池破碎成利于分选的碎片颗粒,通过采用二级破碎,在一级破碎中,主要对蓄电池进行结构破坏,使电解液分离出来,并使蓄电池破碎到便于二级破碎处理的粒级,二级破碎,使蓄电池破碎到能够分选的粒级;a. Crushing: The battery is crushed into debris particles that are conducive to sorting. By using secondary crushing, in the primary crushing, the structure of the battery is mainly destroyed, the electrolyte is separated, and the battery is crushed to facilitate the secondary crushing treatment. The particle size of the battery is divided into two grades, and the secondary crushing is performed to make the battery crushed to the particle size that can be sorted;
b、除铁:部分蓄电池有铁件作为加强材料,利用强力磁力机进行除铁作业,该过程在碎料运输过程中完成;b. Iron removal: Some batteries have iron parts as reinforcing materials, and a powerful magnetic machine is used for iron removal, which is completed during the transportation of scraps;
c、水力分选:利用塑料与金属材料的不同密度,在液体搅拌机中完成,塑料通过分选机而分离除去,同时电池中的过氧化铅、硫酸铅等物质也通过液体的洗涤而存留在液体中被除去,金属材料颗粒由带式传送机捞出,进入到碱洗工序脱除酸;c. Hydraulic sorting: using the different densities of plastic and metal materials, it is completed in a liquid mixer. The plastic is separated and removed by the sorting machine. At the same time, lead peroxide, lead sulfate and other substances in the battery are also washed by the liquid. It is removed from the liquid, and the metal material particles are pulled out by the belt conveyor and entered into the alkaline washing process to remove the acid;
d、塑料干燥制粒:分离出来的塑料颗粒,进入到洗涤池进行三级碱性洗涤,以除去酸,然后进入烘干机进行烘干,再进入挤压机造粒,得到粒料产品出售;d. Plastic drying and granulation: the separated plastic granules enter the washing tank for three-stage alkaline washing to remove acid, then enter the dryer for drying, and then enter the extruder for granulation to obtain granulated products for sale. ;
e、铅泥回收:主要是在破碎过程中与电解液一起进入到废液罐的铅泥、分选过程中洗涤的铅泥和塑料洗涤产生的铅泥,分别通过三条过滤机组分离。e. Recovery of lead mud: The lead mud that enters the waste liquid tank together with the electrolyte during the crushing process, the lead mud washed in the sorting process and the lead mud produced by plastic washing are separated by three filter units respectively.
实施例一:Example 1:
首先将蓄电池破碎成利于分选的碎片颗粒,通过采用二级破碎,在一级破碎中,主要对蓄电池进行结构破坏,使电解液分离出来,并使蓄电池破碎到便于二级破碎处理的粒级,二级破碎,使蓄电池破碎到能够分选的粒级;部分蓄电池有铁件作为加强材料,利用强力磁力机进行除铁作业,该过程在碎料运输过程中完成;利用塑料与金属材料的不同密度,在液体搅拌机中完成,塑料通过分选机而分离除去,同时电池中的过氧化铅、硫酸铅等物质也通过液体的洗涤而存留在液体中被除去,金属材料颗粒由带式传送机捞出,进入到碱洗工序脱除酸;分离出来的塑料颗粒,进入到洗涤池进行三级碱性洗涤,以除去酸,然后进入烘干机进行烘干,再进入挤压机造粒,得到粒料产品出售;主要是在破碎过程中与电解液一起进入到废液罐的铅泥、分选过程中洗涤的铅泥和塑料洗涤产生的铅泥,分别通过三条过滤机组分离。First, the battery is crushed into debris particles that are convenient for sorting. By using secondary crushing, in the primary crushing, the structure of the battery is mainly destroyed, the electrolyte is separated, and the battery is crushed to a particle size that is convenient for secondary crushing. , secondary crushing, so that the battery is crushed to a grade that can be sorted; some batteries have iron parts as reinforcing materials, and a strong magnetic machine is used for iron removal, which is completed during the transportation of scrap materials; the use of plastic and metal materials Different densities are completed in a liquid mixer. The plastic is separated and removed by a sorting machine. At the same time, lead peroxide, lead sulfate and other substances in the battery are also removed in the liquid by washing the liquid, and the metal material particles are conveyed by the belt. It is taken out by the machine and enters the alkaline washing process to remove the acid; the separated plastic particles enter the washing tank for three-stage alkaline washing to remove the acid, and then enter the dryer for drying, and then enter the extruder for granulation , get the granular product for sale; mainly the lead mud that enters the waste liquid tank together with the electrolyte during the crushing process, the lead mud washed in the sorting process and the lead mud produced by plastic washing are separated by three filter units respectively.
实施例二:Embodiment 2:
首先将蓄电池破碎成利于分选的碎片颗粒,通过采用二级破碎,在一级破碎中,主要对蓄电池进行结构破坏,使电解液分离出来,并使蓄电池破碎到便于二级破碎处理的粒级,二级破碎,使蓄电池破碎到能够分选的粒级;部分蓄电池有铁件作为加强材料,利用强力磁力机进行除铁作业,该过程在碎料运输过程中完成;利用塑料与金属材料的不同密度,在液体搅拌机中完成,塑料通过分选机而分离除去,同时电池中的过氧化铅、硫酸铅等物质也通过液体的洗涤而存留在液体中被除去,金属材料颗粒由带式传送机捞出,进入到碱洗工序脱除酸;分离出来的塑料颗粒,进入到洗涤池进行三级碱性洗涤,以除去酸,然后进入烘干机进行烘干,再进入挤压机造粒,得到粒料产品出售;从破碎过程中产出的电解液是比较纯净的稀硫酸,经过过滤净化后,浓缩再循环使用;主要是在破碎过程中与电解液一起进入到废液罐的铅泥、分选过程中洗涤的铅泥和塑料洗涤产生的铅泥,分别通过三条过滤机组分离。First, the battery is crushed into debris particles that are convenient for sorting. By using secondary crushing, in the primary crushing, the structure of the battery is mainly destroyed, the electrolyte is separated, and the battery is crushed to a particle size that is convenient for secondary crushing. , secondary crushing, so that the battery is crushed to a grade that can be sorted; some batteries have iron parts as reinforcing materials, and a strong magnetic machine is used for iron removal, which is completed during the transportation of scrap materials; the use of plastic and metal materials Different densities are completed in a liquid mixer. The plastic is separated and removed by a sorting machine. At the same time, lead peroxide, lead sulfate and other substances in the battery are also removed in the liquid by washing the liquid, and the metal material particles are conveyed by the belt. It is taken out by the machine and enters the alkaline washing process to remove the acid; the separated plastic particles enter the washing tank for three-stage alkaline washing to remove the acid, and then enter the dryer for drying, and then enter the extruder for granulation , obtain pellet products for sale; the electrolyte produced from the crushing process is relatively pure dilute sulfuric acid, which is concentrated and recycled after being filtered and purified; it is mainly the lead that enters the waste liquid tank together with the electrolyte during the crushing process. The mud, the lead mud washed in the sorting process and the lead mud produced by plastic washing are separated by three filter units respectively.
实施例三:Embodiment three:
首先将蓄电池破碎成利于分选的碎片颗粒,通过采用二级破碎,在一级破碎中,主要对蓄电池进行结构破坏,使电解液分离出来,并使蓄电池破碎到便于二级破碎处理的粒级,二级破碎,使蓄电池破碎到能够分选的粒级;部分蓄电池有铁件作为加强材料,利用强力磁力机进行除铁作业,该过程在碎料运输过程中完成;利用塑料与金属材料的不同密度,在液体搅拌机中完成,塑料通过分选机而分离除去,同时电池中的过氧化铅、硫酸铅等物质也通过液体的洗涤而存留在液体中被除去,金属材料颗粒由带式传送机捞出,进入到碱洗工序脱除酸;分离出来的塑料颗粒,进入到洗涤池进行三级碱性洗涤,以除去酸,然后进入烘干机进行烘干,再进入挤压机造粒,得到粒料产品出售;从破碎过程中产出的电解液是比较纯净的稀硫酸,经过过滤净化后,浓缩再循环使用;主要是在破碎过程中与电解液一起进入到废液罐的铅泥、分选过程中洗涤的铅泥和塑料洗涤产生的铅泥,分别通过三条过滤机组分离,最后对系统的循环水中的铅泥进行过滤分离,滤液返回到系统,铅泥外运,并浓缩稀硫酸,达到使用标准。First, the battery is crushed into debris particles that are convenient for sorting. By using secondary crushing, in the primary crushing, the structure of the battery is mainly destroyed, the electrolyte is separated, and the battery is crushed to a particle size that is convenient for secondary crushing. , secondary crushing, so that the battery is crushed to a grade that can be sorted; some batteries have iron parts as reinforcing materials, and a strong magnetic machine is used for iron removal, which is completed during the transportation of scrap materials; the use of plastic and metal materials Different densities are completed in a liquid mixer. The plastic is separated and removed by a sorting machine. At the same time, lead peroxide, lead sulfate and other substances in the battery are also removed in the liquid by washing the liquid, and the metal material particles are conveyed by the belt. It is taken out by the machine and enters the alkaline washing process to remove the acid; the separated plastic particles enter the washing tank for three-stage alkaline washing to remove the acid, and then enter the dryer for drying, and then enter the extruder for granulation , to obtain pellet products for sale; the electrolyte produced from the crushing process is relatively pure dilute sulfuric acid, which is concentrated and recycled after being filtered and purified; it is mainly the lead that enters the waste liquid tank together with the electrolyte during the crushing process. The mud, the lead mud washed in the sorting process and the lead mud produced by plastic washing are separated by three filter units respectively. Finally, the lead mud in the circulating water of the system is filtered and separated, the filtrate is returned to the system, and the lead mud is transported out and concentrated. Dilute sulfuric acid, up to the standard of use.
本发明中,考虑了废旧蓄电池回收过程中的综合回收,并完善了回收过程中的环境保护,对环境友好,过程中产生的空气、水体、和固体污染都降低到最小程度,废旧蓄电池的物料利用率高,处理费用比较低,从经济的角度考虑比较划算,由于工艺过程在低温下完成,能源消耗比较低,对设备要求也比较低,整体投资小。In the present invention, the comprehensive recovery in the recycling process of the waste battery is considered, and the environmental protection in the recycling process is improved, which is friendly to the environment, and the air, water, and solid pollution generated in the process are reduced to a minimum. The utilization rate is high, the processing cost is relatively low, and it is more cost-effective from an economic point of view. Since the process is completed at low temperature, the energy consumption is relatively low, the equipment requirements are relatively low, and the overall investment is small.
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above description is only a preferred embodiment of the present invention, but the protection scope of the present invention is not limited to this. The equivalent replacement or change of the inventive concept thereof shall be included within the protection scope of the present invention.
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