CN110511828A - Intelligent cleaning robot cleaning agent and preparation method thereof - Google Patents
Intelligent cleaning robot cleaning agent and preparation method thereof Download PDFInfo
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- CN110511828A CN110511828A CN201910839497.9A CN201910839497A CN110511828A CN 110511828 A CN110511828 A CN 110511828A CN 201910839497 A CN201910839497 A CN 201910839497A CN 110511828 A CN110511828 A CN 110511828A
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- photoinitiator
- cleaning
- cleaning robot
- agent
- surfactant
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- 238000004140 cleaning Methods 0.000 title claims abstract description 72
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000004094 surface-active agent Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002518 antifoaming agent Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 5
- 239000012952 cationic photoinitiator Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 10
- 150000007524 organic acids Chemical class 0.000 abstract description 8
- 238000002474 experimental method Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000011521 glass Substances 0.000 description 6
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical group CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- CSTYVZIYKPZTEE-UHFFFAOYSA-N C=1C=CC=CC=1[Ti]C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1[Ti]C1=CC=CC=C1 CSTYVZIYKPZTEE-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000013401 experimental design Methods 0.000 description 3
- 238000003682 fluorination reaction Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 125000005520 diaryliodonium group Chemical group 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- 235000015511 Liquidambar orientalis Nutrition 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000004870 Styrax Substances 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000003211 polymerization photoinitiator Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to intelligent cleaning robot cleaning agents and preparation method thereof, and cleaning agent is made of surfactant and water, by it is characterized in that, containing photoinitiator.Organic acid is free of in the application, the application can still play the effect of organic acid when in use；The present invention can reduction light reflection, object is imaged in the vision system of cleaning robot apparent, the present invention is applied to the bright and clean article of clean the surface, can improve the cleaning efficiency, and clean cleaner.
Description
Technical field
The present invention relates to intelligent cleaning robot cleaning agents and preparation method thereof.
Background technique
Cleaning robot is very high in American-European Korea Spro's popularization degree, and China was also applying in recent years, in particular for the family of building
The cleaning of outer glass.Since building is higher, there is very big risk using artificial cleaning, especially encounter in the process of cleaning
Strong wind, then may to cleaning personnel personal safety constitute a threat to, therefore at present using cleaning robot to outdoors building into
Row cleaning becomes the first choice of each large enterprises.
Scavenger surface information is fed back to vision positioning system, vision positioning system root in cleaning by cleaning robot
Cleaning operation is carried out according to the information of feedback, cleaning agent currently on the market is mostly the product of organic acid and surfactant compound,
This products application has the following problems the 1) presence due to organic acid in intelligent robot, topples in use, may be to skin
It damages；Equipment may be caused to corrode when use；2) existing cannot make the vision positioning system of cleaning robot obtain standard
True information has seriously affected the cleaning efficiency of cleaning robot.
Since intelligent cleaning robot belongs to Newly Sprouted Things in China, there is no compatibilities therewith for existing market, to people
Body and equipment are corrosion-free, and can be improved the cleaning agent of cleaning efficiency.
Summary of the invention
The present invention provides intelligent cleaning robot cleaning agent and preparation method thereof, solves technical problem 1) without organic
Acid will not cause to corrode to human body and equipment；2) cleaning robot human visual system is made to obtain accurate information；3) cleaning matter is improved
Amount and efficiency.
In order to solve the above-mentioned technical problem, the invention adopts the following technical scheme:
Intelligent cleaning robot cleaning agent, is made of surfactant and water, contains photoinitiator.
Preferably, the photoinitiator be free radical polymerization photoinitiator, it is Cationic photoinitiator, visible light-initiated
Two kinds of one of agent, water-soluble photoinitiator and macromolecular photoinitiator or arbitrary proportion.
Preferably, the photoinitiator is the composition of visible light initiator and Cationic photoinitiator.
Preferably, also contain defoaming agent.
Surfactant, water and photoinitiator are added to container by the preparation method of intelligent cleaning robot cleaning agent
In, it stirs evenly, defoaming agent is added to get intelligent cleaning robot cleaning agent；
Surfactant, water, photoinitiator and defoaming agent mass ratio be 3~98.8:1~96:0.1~7:0~2.
Invention has following advantageous effects:
1. part ultraviolet light and visible light can be absorbed by addition photoinitiator in the application, when preventing cleaning robot from cleaning,
Since visible reflectance interferes, the collimation error of cleaning robot vision positioning system, the information that cleaning robot obtains are caused
Inaccuracy, and then influence cleaning efficiency and cleaning effect.
2. cationic initiator is added in the application, so as to omit the addition of organic acid, without influencing using effect.
When not in use, it is stored in light protected environment or in light resistant container, there is no the generations of organic acid at this time therefore can't be right
Human body and equipment cause to corrode；Outdoors in use, being not used when being stored in container, the not presence of light, does not just have yet at this time
Super strong proton acid, and when cleaning solution sprays irradiation of the cationic initiator in light at this time in use, cleaning solution is exposed under sunlight
Under decompose reaction, the final super strong proton acid that generates also is bronsted acid, the effect of organic acid in cleaning agent can be played,
Therefore cleaning effect is substantially unaffected.
3. since cleaning agent contains surfactant and water, when in use, a large amount of bubbles can be generated, and bubble
In the presence of the wetting for being unfavorable for cleaned material, and due to the presence of air in bubble, one layer of sky can be formed on the surface of cleaned material
Air bound is exhausted, causes the surface of cleaned material to image in the vision system of cleaning robot unintelligible, and then affects cleaning effect
Rate can significantly reduce the presence of bubble, reduce the isolation of air, the surface of cleaning materials is made to exist after defoaming agent is added in the application
It is clear to image in the vision system of cleaning robot, improves cleaning efficiency.
Detailed description of the invention
Fig. 1 is the transmission electron microscope photo using embodiment 3.
Fig. 2 is the transmission electron microscope photo using embodiment 4.
Fig. 3 is the transmission electron microscope photo using comparison 1.
Specific embodiment
The present invention is further illustrated below with reference to specific example.
Embodiment 1
Intelligent cleaning robot cleaning agent, is made of surfactant and water, contains photoinitiator.
The surfactant is composition of the AEO-9 and op-10 according to mass ratio 5:1；The photoinitiator is fluorination
Diphenyl titanium is luxuriant (Irgacure 784).
Surfactant, water and photoinitiator are added to container by the preparation method of intelligent cleaning robot cleaning agent
In, it stirs evenly to get intelligent cleaning robot cleaning agent；
The mass ratio of surfactant, water and photoinitiator is 7:92.5:0.5.
Embodiment 2
Intelligent cleaning robot cleaning agent, is made of surfactant and water, contains photoinitiator.
The surfactant is composition of the AEO-9 and op-10 according to mass ratio 5:1；The photoinitiator is two virtues
Base salt compounded of iodine.
Surfactant, water and photoinitiator are added to container by the preparation method of intelligent cleaning robot cleaning agent
In, it stirs evenly to get intelligent cleaning robot cleaning agent；
The mass ratio of surfactant, water and photoinitiator is 7:92.5:0.5.
Embodiment 3
Intelligent cleaning robot cleaning agent, is made of surfactant and water, contains photoinitiator.
The surfactant is composition of the AEO-9 and op-10 according to mass ratio 5:1；The photoinitiator is fluorination
Diphenyl titanium luxuriant (Irgacure 784) and diaryl iodonium salt according to mass ratio 1:1 composition.
Surfactant, water and photoinitiator are added to container by the preparation method of intelligent cleaning robot cleaning agent
In, it stirs evenly to get intelligent cleaning robot cleaning agent；
The mass ratio of surfactant, water and photoinitiator is 7:92.5:0.5.
Embodiment 4
Intelligent cleaning robot cleaning agent, is made of surfactant and water, contains photoinitiator；Also contain defoaming agent.
The surfactant is composition of the AEO-9 and op-10 according to mass ratio 5:1；The photoinitiator is fluorination
Diphenyl titanium luxuriant (Irgacure 784) and diaryl iodonium salt according to mass ratio 1:1 composition.
Surfactant, water and photoinitiator are added to container by the preparation method of intelligent cleaning robot cleaning agent
In, it stirs evenly, defoaming agent is added to get intelligent cleaning robot cleaning agent；The defoaming agent buying is in Beijing Xing Meiya
Chemical Co., Ltd.；Model SA362.
Surfactant, water, photoinitiator and defoaming agent mass ratio be 7:92.4:0.5:0.1.
Embodiment 5
Intelligent cleaning robot cleaning agent, is made of surfactant and water, contains photoinitiator.
The photoinitiator is 2- hydroxy-2-methyl -1- phenylacetone.
The surfactant is peregal.
Surfactant, water and photoinitiator are added in container, stirred evenly to get intelligent cleaning robot with clearly
Lotion.
Embodiment 6
Intelligent cleaning robot cleaning agent, is made of surfactant and water, contains photoinitiator.
The surfactant be sodium sulfate of polyethenoxy ether of fatty alcohol, neopelex, AES and AEO-9 by
According to the composition of mass ratio 5:3:2:1；
The photoinitiator is 2- hydroxy-2-methyl -1- [4- (2- hydroxyl-oxethyl) phenyl] -1- acetone, the double first of styrax
Ether, bis- (pentafluorophenyl group) titanium cyclopentadienyls and 2,4 dihydroxyl benzophenone according to mass ratio 3:2:4:1 composition.
Also contain defoaming agent;The defoaming agent is dimethicone.
Surfactant, water and photoinitiator are added to container by the preparation method of intelligent cleaning robot cleaning agent
In, it stirs evenly, defoaming agent is added to get intelligent cleaning robot cleaning agent；
Surfactant, water, photoinitiator and defoaming agent mass ratio be 15:81:2:2.
Beneficial effects of the present invention are further illustrated below with reference to experimental data:
Experiment one
1, material to be tested is tested
1 materials and methods:
1.1 test sites: Yantai analysis center
1.2 experiment detections: wavelength is the reflectivity of the range of 200~850nm；
1.3 experimental subjects: in addition to photoinitiator is not added, other preparation methods and embodiment 1 are equal by embodiment 1 to 4 and comparison 1(
Unanimously)；
1.4 experimental facilities: USB4000 spectrometer；
1.5 experimental designs: by embodiment 1 to 4 and comparison 1(in addition to photoinitiator is not added, other preparation methods and embodiment 1
It is consistent) uniformly it is applied on glass plate, it measures.
This experiment other experiment conditions in addition to experiment process is different are consistent.
2 results and analysis
Respectively influence of the processing to glass-reflected rate of table 1
By embodiment 1 to 4 in table 1 and comparison 1 data compare as can be seen that the application by addition photoinitiator, can subtract
Few light
Reflection.
Experiment two
1 materials and methods:
1.1 test sites: Yantai analysis center；
1.2 experiment detections: same glass slide uses the microscope view of different disposal；
1.3 experimental subjects: embodiment 3, embodiment 4 and comparison 2(be not in addition to being added photoinitiator, other preparation methods and implementation
Example 3 is consistent)；
1.4 experimental designs: the one side of glass slide is uniformly smeared into embodiment 3, another side is not processed, and is placed in microscopically observation
Its
Imaging；Embodiment 4 is uniformly applied to embodiment 3 and smears position by embodiment of erasing 3, be placed under microscope square its at
Picture；Embodiment of erasing 4, by comparison 2(in addition to photoinitiator is not added, other preparation methods are consistent with embodiment 3) uniformly apply
It smears and smears position in embodiment 4, be placed in its imaging of microscopically observation.
This experiment other experiment conditions in addition to experiment process is different are consistent.
2 results and analysis
The comparison 1 that photoinitiator is not added it can be seen from experiment has apparent reflection, and smears almost seeing not for the application
To reflection, and the image of the application is smeared compared to comparison 1(in addition to photoinitiator is not added, other preparation methods and embodiment 3
Image unanimously) is apparent；The image that the embodiment 4 of photoinitiator and defoaming agent had wherein both been added is apparent.
Experiment three
1, material to be tested is tested
1 materials and methods:
1.1 test sites: Yantai City economic and technological development zone Wanke city.
1.2 experiment detections: cleaning robot puts the speed of glass on the skin and is carried out an acceptance inspection by property personnel for this experiment
Examination is divided into: being satisfied with, is satisfied in the main, is good, poor four grades.
1.3 materials to be tested: embodiment 1 to 4 and comparison 1(be not in addition to being added photoinitiator, other preparation methods and embodiment
1 is uniform
It causes)；
1.4 experimental designs: being arbitrarily grouped the 5 side by side building of selection, respectively corresponds embodiment 1 to 4 and comparison 1(is removed
It is not added outside photoinitiator, other preparation methods are consistent with embodiment 1)；Selected story height is 30 layers.
Cleaning robot selected by this experiment is provided by Yantai Hai Telin automation Science and Technology Ltd.；
This experiment other experiment conditions in addition to experiment process is different are consistent；.
2 results and analysis
Cleaning robot puts the speed and customer satisfaction evaluation testing result of glass on the skin, is shown in Table 2
By experimental data in table 2 compare it can be seen from the application can significantly improve the cleaning efficiency of cleaning robot, and clean
Effect is good, can be with cleaning robot compatible use；And the comparison 1 for the photoinitiator and defoaming agent not being added, then cleaning speed is slow,
And cleaning effect is poor, with cleaning robot compatible use, effect is unsatisfactory.
Claims (5)
1. intelligent cleaning robot cleaning agent, is made of surfactant and water, by it is characterized in that, containing photoinitiator.
2. intelligence cleaning robot cleaning agent as described in claim 1, which is characterized in that the photoinitiator is radical polymerization
One in light combination initiator, Cationic photoinitiator, visible light initiator, water-soluble photoinitiator and macromolecular photoinitiator
Two kinds of kind or arbitrary proportion.
3. intelligence cleaning robot cleaning agent as described in claim 1, which is characterized in that the photoinitiator is that visible light draws
Send out the composition of agent and Cationic photoinitiator.
4. the intelligent cleaning robot cleaning agent as described in claims 1 to 3 any one, which is characterized in that also containing defoaming
Agent.
5. the preparation method of intelligent cleaning robot cleaning agent, which is characterized in that add surfactant, water and photoinitiator
Enter into container, stir evenly, defoaming agent is added to get intelligent cleaning robot cleaning agent；
Surfactant, water, photoinitiator and defoaming agent mass ratio be 3~98.8:1~96:0.1~7:0~2.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2019102702069 | 2019-04-04 | ||
| CN201910270206 | 2019-04-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110511828A true CN110511828A (en) | 2019-11-29 |
| CN110511828B CN110511828B (en) | 2021-06-15 |
Family
ID=68629949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910839497.9A Active CN110511828B (en) | 2019-04-04 | 2019-09-06 | Cleaning agent for intelligent cleaning robot and preparation method thereof |
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| CN (1) | CN110511828B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104342302A (en) * | 2014-10-26 | 2015-02-11 | 青岛克立克信息技术有限公司 | Long-acting and traceless cleaning agent |
| CN107446723A (en) * | 2017-09-29 | 2017-12-08 | 成都意町工业产品设计有限公司 | A kind of cleaning robot glass cleaner |
| CN107541358A (en) * | 2017-09-29 | 2018-01-05 | 成都意町工业产品设计有限公司 | A kind of cleaning robot cleaning agent with fast cleaning function |
| CN107686780A (en) * | 2017-09-29 | 2018-02-13 | 成都意町工业产品设计有限公司 | A kind of cleaning robot cleaning agent |
-
2019
- 2019-09-06 CN CN201910839497.9A patent/CN110511828B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104342302A (en) * | 2014-10-26 | 2015-02-11 | 青岛克立克信息技术有限公司 | Long-acting and traceless cleaning agent |
| CN107446723A (en) * | 2017-09-29 | 2017-12-08 | 成都意町工业产品设计有限公司 | A kind of cleaning robot glass cleaner |
| CN107541358A (en) * | 2017-09-29 | 2018-01-05 | 成都意町工业产品设计有限公司 | A kind of cleaning robot cleaning agent with fast cleaning function |
| CN107686780A (en) * | 2017-09-29 | 2018-02-13 | 成都意町工业产品设计有限公司 | A kind of cleaning robot cleaning agent |
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| Publication number | Publication date |
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| CN110511828B (en) | 2021-06-15 |
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