CN1103184C - Bactericide composition containing nitrile-bacteria-azole and its preparation method - Google Patents
Bactericide composition containing nitrile-bacteria-azole and its preparation method Download PDFInfo
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- CN1103184C CN1103184C CN00100576A CN00100576A CN1103184C CN 1103184 C CN1103184 C CN 1103184C CN 00100576 A CN00100576 A CN 00100576A CN 00100576 A CN00100576 A CN 00100576A CN 1103184 C CN1103184 C CN 1103184C
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- nitrile bacterium
- bacterium azoles
- bactericide
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- azoles
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- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 21
- 239000003899 bactericide agent Substances 0.000 title abstract description 16
- 238000002360 preparation method Methods 0.000 title description 7
- 241000894006 Bacteria Species 0.000 claims description 45
- 150000003851 azoles Chemical class 0.000 claims description 45
- 150000002825 nitriles Chemical class 0.000 claims description 44
- 239000000843 powder Substances 0.000 claims description 20
- 238000009736 wetting Methods 0.000 claims description 13
- 239000005802 Mancozeb Substances 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 239000005864 Sulphur Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 230000003641 microbiacidal effect Effects 0.000 claims description 6
- 229940124561 microbicide Drugs 0.000 claims description 6
- 239000002855 microbicide agent Substances 0.000 claims description 6
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- 239000013638 trimer Substances 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- ZMUQGGLSCIDPLS-UHFFFAOYSA-N Saponin 5 Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(O)C6OC7OC(CO)C(O)C(O)C7OC8OC(C)C(O)C(O)C8O)C(C)(C)C5CCC34C)C2C1)C(=O)O ZMUQGGLSCIDPLS-UHFFFAOYSA-N 0.000 claims 1
- 208000031888 Mycoses Diseases 0.000 abstract description 6
- 239000000575 pesticide Substances 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 4
- HZJKXKUJVSEEFU-UHFFFAOYSA-N 2-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)hexanenitrile Chemical compound C=1C=C(Cl)C=CC=1C(CCCC)(C#N)CN1C=NC=N1 HZJKXKUJVSEEFU-UHFFFAOYSA-N 0.000 abstract description 3
- 239000005811 Myclobutanil Substances 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract description 2
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 244000052616 bacterial pathogen Species 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 11
- 239000004563 wettable powder Substances 0.000 description 7
- 241000221785 Erysiphales Species 0.000 description 4
- 239000005843 Thiram Substances 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- JLHMVTORNNQCRM-UHFFFAOYSA-N ethylphosphine Chemical compound CCP JLHMVTORNNQCRM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 4
- 229960002447 thiram Drugs 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 241000220324 Pyrus Species 0.000 description 3
- 206010039509 Scab Diseases 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 235000021017 pears Nutrition 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 241000395107 Cladosporium cucumerinum Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000001934 delay Effects 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 239000005807 Metalaxyl Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 239000005842 Thiophanate-methyl Substances 0.000 description 1
- 241000510929 Uncinula Species 0.000 description 1
- 241000228452 Venturia inaequalis Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000005870 Ziram Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000011717 all-trans-retinol Substances 0.000 description 1
- 235000019169 all-trans-retinol Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- GAMFEMAXLMWCRG-UHFFFAOYSA-N bis(dimethylcarbamothioylsulfanyl)arsanyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)S[As](SC(=S)N(C)C)SC(=S)N(C)C GAMFEMAXLMWCRG-UHFFFAOYSA-N 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000017858 demethylation Effects 0.000 description 1
- 238000010520 demethylation reaction Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- WHDGWKAJBYRJJL-UHFFFAOYSA-K ferbam Chemical compound [Fe+3].CN(C)C([S-])=S.CN(C)C([S-])=S.CN(C)C([S-])=S WHDGWKAJBYRJJL-UHFFFAOYSA-K 0.000 description 1
- 239000004503 fine granule Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 1
- 229920000940 maneb Polymers 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 1
- 230000007170 pathology Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 239000000344 soap Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to pesticide and a processing field thereof. The present invention provides a binary compounding composition of a kind of myclobutanil and other kinds of bactericide. The use of the mixing bactericide can obviously delay the generation of the drug resistance of pathogenic bacteria to the myclobutanil, and the present invention can be widely used for the prevention and the cure of fungal diseases on crops.
Description
The present invention relates to agricultural chemicals and manufacture field thereof, specifically the present invention relates to contain the bactericidal composition and the manufacture method thereof of nitrile bacterium azoles.
Crop is subjected to the dip-dye of various diseases, particularly fungal disease easily in growth and development process, it is of a great variety, endanger the most serious, as wheat rust, the scab of apple, pears etc., the outburst of these diseases has in recent years caused destructive strike to the production of these crops.For a long time, the control of crop pest is mainly relied on and chemical control, i.e. the application of bactericide, but the long-term use of bactericide have caused the pesticide resistance of germ to bactericide, and the preventive effect of bactericide is descended.For overcoming the pesticide resistance of germ, adopt new bactericide kind and the mixed agent between bactericide to prevent and treat crop pest more.
Nitrile bacterium azoles is a kind of azoles fungicide that China develops recently, and it has low toxicity, characteristics such as efficient, and its mechanism of action is to suppress the sterol demethylation of germ spore, inhale therapeutic action in the tool, fungicidal spectrum is wide, to wheat powdery mildew, smut, and apple scab, powdery mildew, anthracnose; Uncinula bacterium on the crops such as grape all has good preventive effect.Because its preventive effect is good, in recent years, nitrile bacterium azoles particularly when apple scab was sent out greatly in 1998,1999, has played good effect to the harm of controlling and prevent and treat this germ in China's wide popularization and application.But nitrile bacterium azoles faces the drug-fast problem of germ equally, how to delay germ to its drug-fast generation, prolongs its service life, just becomes the problem that study.
The objective of the invention is at the problems referred to above, proposed a kind of method that delays germ to the drug-fast generation of nitrile bacterium azoles, be about to nitrile bacterium azoles and other fungicide compoundings and form new composition pesticide.
Below narrate main contents of the present invention:
A kind of microbicide compositions that contains nitrile bacterium azoles, said composition are by nitrile bacterium azoles and the formulated binary built bactericide of other any bactericide.
Other any bactericide of the present invention can be tmtd, ziram, ferbam, maneb, zineb, mancozeb, ethyl phosphine aluminium, asomate, thiophanate-methyl, tpn, enemy can pine, known any in the bactericide any one of can be used as of carbendazim, the mould spirit of evil, procymidone, metalaxyl, sulphur and other.
A kind of bactericidal composition that contains nitrile bacterium azoles is characterized in that containing the nitrile bacterium azoles of 1-10% and other bactericide of 5-50%.
A kind of bactericidal composition that contains nitrile bacterium azoles, the method that the ordinary person knows in its available this area is made the Multiple Pesticides formulation, as wetting powder, fine granule, missible oil, suspension emulsion etc.Below be that example is illustrated with the wetting powder that contains nitrile bacterium azoles:
A kind of wetting powder that contains nitrile bacterium azoles is characterized in that each components contents of this wetting powder is (percentage by weight):
Nitrile bacterium azoles: 1-10%
Other bactericide: 5-50%
Filler: 40-75%
Auxiliary agent: 5-15%
Filler of the present invention can be that white carbon, bentonite, talcum powder, diatomite, precipitated calcium carbonate etc. well known to a person skilled in the art material.
Auxiliary agent of the present invention can be wetting agent such as lignin sulfonic acid salt, soap class, alkyl sulfonates, laruyl alcohol; Suspending agent such as sodium phosphate trimer, draw back a kind of in powder, sodium silicate, carboxymethyl cellulose, xanthans, the polyaryl phenol polyethenoxy pyrophosphoric acid or several composition arbitrarily.
A kind of manufacture method that contains nitrile bacterium azoles wetting powder, this method is at first bulk myclobutanil, other bactericide original drugs, filler and insecticides adjuvant fully to be mixed in mixer, method with comminution by gas stream or ultramicro grinding is crushed to 95% mistake, 325 mesh sieves with this mixture again, and crushed material is this microbicide compositions.
The preparation and the processing method of other formulation of the present invention are not enumerated one by one at this, and those skilled in the art should be able to make other formulation by the composition content of effective scope that the present invention provides.
The present invention compares than prior art has following typical advantages:
1, delays germ to the drug-fast generation of nitrile bacterium azoles.
2, bactericidal composition of the present invention is by composite control spectrum and the control efficiency of having enlarged.Really.
3, synergistic effect is remarkable.
Be described in detail the present invention by the following examples:
One: 20% nitrile bacterium of embodiment azoles thiram wettable powder
Take by weighing the former powder 2kg of nitrile bacterium azoles (pure), tmtd 18kg (pure), sodium lignin sulfonate 5kg, precipitated calcium carbonate 75kg is crushed to 95% with comminution by gas stream after mixing and crosses 325 mesh sieves, promptly obtains 20% nitrile bacterium azoles thiram wettable powder.Inhale treatment and protection double action in said preparation has, can be widely used in the control of the fungal disease on the various crops, 1000 times of liquid of said preparation show very high preventive effect to the scab on apple, pears, the cucumber.
Two: 40% nitrile bacterium of embodiment azoles ethyl phosphine aluminium wetting powder
Take by weighing the former powder 6kg of nitrile bacterium azoles (pure), ethyl phosphine aluminium 34kg (pure), sodium lignin sulfonate 6kg, yellow first glue 4kg, bentonite 50kg fully mixes after be crushed to 95% and crosses 325 mesh sieves, promptly gets 40% nitrile bacterium azoles ethyl phosphine aluminium wetting powder.2000 times of dilutions of said preparation can be prevented and treated apple mildew, anthracnose; Tomato blight; Multiple diseases such as wheat powdery mildew.
Three: 50% nitrile bacterium of embodiment azoles mancozeb wettable powder
Take by weighing the former powder 5kg of nitrile bacterium azoles (pure), mancozeb 45kg (pure) saponin 5kg, carboxymethyl cellulose 1kg, dodecyl sodium sulfate 4kg, diatomite 40kg is after fully mixing, be crushed to 95% through airslide disintegrating mill and cross 325 mesh sieves, promptly get 50% nitrile bacterium azoles mancozeb wettable powder.Said preparation has protection and treatment double action to the crop fungal disease.Can be widely used in the various fungal diseases on the various crops.
Four: 50% nitrile bacterium of embodiment azoles sulphur wetting powder
Take by weighing the former powder 8kg of nitrile bacterium azoles (pure), sulphur 42kg, sodium lignin sulfonate 4kg, sodium phosphate trimer 2kg draws back powder 4kg, and white carbon 40kg after fully mixing, pulverizes through micronizer, promptly gets 50% nitrile bacterium azoles sulphur wetting powder.1500 times of dilutions of said preparation can be used for the control of pears, apple, scab of cucumber, powdery mildew.Also can be used for the control of the fungal disease on other crops.EXPERIMENTAL EXAMPLE: the mensuration of several microbicide compositions co-toxicity coefficients of the present invention: Xibei Univ. of Agricultural ﹠ Forest Science ﹠ Technology's plant protection is the plant pathology laboratory; to 20% nitrile bacterium azoles thiram wettable powder of the present invention; 50% nitrile bacterium azoles mancozeb wettable powder; 50% nitrile bacterium azoles sulphur wetting powder has been done Toxicity Determination, and the method for Toxicity Determination is a growth rate method.Test data adopts the probit value analytical method to return, and obtains dense EC in regression equation and the inhibition
50, obtain the co-toxicity coefficient CTC value of each mixture again with Sun-Johnson toxicity index method, CTC＞120 are synergy.Result of the test sees Table 1,2,3.
Table 1 20% nitrile bacterium azoles thiram wettable powder is to the co-toxicity of scab of cucumber
Handle virulence regression equation EC
50(mg/ml) co-toxicity coefficient
Tmtd Y=4.19+0.913X 0.00242
Nitrile bacterium azoles Y=5.784+0.492X 2.03*10
-1
Mixture Y=5.154+0.570X 7.63*10
-1151.52
Table 2 50% nitrile bacterium azoles mancozeb is to the co-toxicity of apple anthracnose
Handle virulence regression equation EC
50(mg/l) co-toxicity coefficient is handled
Nitrile bacterium azoles Y=6.357+0.045X 0.2177
Mancozeb Y=5.293+1.848X 0.6940
Mixture Y=6.275+1.691X 0.1761 323.35
Table 3 50% nitrile bacterium azoles sulphur is to the co-toxicity of apple anthracnose
Handle virulence regression equation EC
50(mg/l) co-toxicity coefficient is handled
Nitrile bacterium azoles Y=6.357+0.045X 0.2177
Sulphur Y=4.939+1.144X 1.128
Mixture Y=5.739+1.795X 0.3875 205.5
Claims (3)
1, a kind of microbicide compositions that contains nitrile bacterium azoles is characterized in that said composition wetting powder percentage by weight is:
Nitrile bacterium azoles: 2%
Tmtd 18%
Precipitated calcium carbonate 75%
Sodium lignin sulfonate 5%
2, a kind of microbicide compositions that contains nitrile bacterium azoles is characterized in that said composition wetting powder percentage by weight is:
Nitrile bacterium azoles: 5%
Mancozeb 45%
Saponin 5%
Carboxymethyl cellulose 1%
Dodecyl sodium sulfate 4%
Diatomite 40%
3, a kind of microbicide compositions that contains nitrile bacterium azoles is characterized in that said composition wetting powder percentage by weight is:
Nitrile bacterium azoles 8%
Sulphur 42%
Sodium lignin sulfonate 4%
Sodium phosphate trimer 2%
Draw back powder 4%
White carbon 40%
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00100576A CN1103184C (en) | 2000-01-26 | 2000-01-26 | Bactericide composition containing nitrile-bacteria-azole and its preparation method |
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|---|---|---|---|
| CN00100576A CN1103184C (en) | 2000-01-26 | 2000-01-26 | Bactericide composition containing nitrile-bacteria-azole and its preparation method |
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| Publication Number | Publication Date |
|---|---|
| CN1260116A CN1260116A (en) | 2000-07-19 |
| CN1103184C true CN1103184C (en) | 2003-03-19 |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100348104C (en) * | 2003-09-10 | 2007-11-14 | 西安克胜新依达农药有限公司 | Water dispersive myclobutanil particle and formula |
| DE102004049761A1 (en) * | 2004-10-12 | 2006-04-13 | Bayer Cropscience Ag | Fungicidal drug combinations |
| CN100367853C (en) * | 2006-06-22 | 2008-02-13 | 深圳诺普信农化股份有限公司 | Bactericidal composition containing kresoxim-methyl and myclobutanil |
| CN101507433A (en) * | 2008-11-10 | 2009-08-19 | 江苏省农业科学院 | Compound bactericide capable of preventing and controlling grape downy mildew |
| CN103053582B (en) * | 2009-12-23 | 2014-07-23 | 中国中化股份有限公司 | Antifungal composition containing pyraoxystrobin |
| EP2524600A1 (en) * | 2011-05-17 | 2012-11-21 | Bayer CropScience AG | Active compound combinations comprising phosphorous acid or a derivative thereof and Tebuconazole or Myclobutanil |
| CN102511491A (en) * | 2011-12-20 | 2012-06-27 | 利尔化学股份有限公司 | Sterilization composition and application thereof |
| CN104430422A (en) * | 2013-12-27 | 2015-03-25 | 辽宁省农业科学院 | Compound bactericide containing myclobutanil and carbendazim for preventing and treating principle diseases of vegetables |
| WO2024130462A1 (en) * | 2022-12-18 | 2024-06-27 | 张子勇 | Mancozeb nanosuspension containing metalaxyl-m, and preparation method therefor |
| CN116849226B (en) * | 2023-07-06 | 2025-05-27 | 一帆生物科技(上海)有限公司 | A bactericidal composition containing cymoxanil and myclobutanil and its application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099552A (en) * | 1993-06-02 | 1995-03-08 | 拜尔公司 | Fungicidal compositions |
| US5506251A (en) * | 1994-11-16 | 1996-04-09 | Rohm And Haas Company | Synergisic insecticidal compositions |
| WO1997037535A2 (en) * | 1996-04-11 | 1997-10-16 | Novartis Ag | Pesticidal compositions of cyprodinil and myclobutanil or ipridione |
| CN1217875A (en) * | 1997-11-21 | 1999-06-02 | 化学工业部沈阳化工研究院 | Smoke agents and tablets containing benamide bactericidal agents and compostions |
| CN1237335A (en) * | 1999-06-07 | 1999-12-08 | 青岛东生药业有限公司 | Compound myclobutanil fungicide |
-
2000
- 2000-01-26 CN CN00100576A patent/CN1103184C/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099552A (en) * | 1993-06-02 | 1995-03-08 | 拜尔公司 | Fungicidal compositions |
| US5506251A (en) * | 1994-11-16 | 1996-04-09 | Rohm And Haas Company | Synergisic insecticidal compositions |
| US5571829A (en) * | 1994-11-16 | 1996-11-05 | Rohm And Haas Company | Synergistic insecticidal compositions |
| WO1997037535A2 (en) * | 1996-04-11 | 1997-10-16 | Novartis Ag | Pesticidal compositions of cyprodinil and myclobutanil or ipridione |
| CN1217875A (en) * | 1997-11-21 | 1999-06-02 | 化学工业部沈阳化工研究院 | Smoke agents and tablets containing benamide bactericidal agents and compostions |
| CN1237335A (en) * | 1999-06-07 | 1999-12-08 | 青岛东生药业有限公司 | Compound myclobutanil fungicide |
Non-Patent Citations (1)
| Title |
|---|
| 安徽化工1999年第3期 1999-03-01 陈祥付等,丰乐西瓜种衣剂防治苗期病虫害试验初报 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1260116A (en) | 2000-07-19 |
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