CN110171145A - The production method and production equipment of thermoplastic composite core material - Google Patents
The production method and production equipment of thermoplastic composite core material Download PDFInfo
- Publication number
- CN110171145A CN110171145A CN201910390534.2A CN201910390534A CN110171145A CN 110171145 A CN110171145 A CN 110171145A CN 201910390534 A CN201910390534 A CN 201910390534A CN 110171145 A CN110171145 A CN 110171145A
- Authority
- CN
- China
- Prior art keywords
- core material
- along
- material unit
- outbound course
- thermoplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/20—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
本发明公开了一种热塑性复合芯材的生产方法和生产设备,生产方法包括:模内热复合成型具有结构层和功能层的平整片材并沿流水线输出方向持续输出;将平整片材分割加工成沿宽边输出方向等宽且沿流水线输出方向呈带状的多个芯材单元片,其中至少部分的芯材单元片的片材表面上加工有沿流水线输出方向重复呈现的非闭合的几何体;将多个芯材单元片沿宽边输出方向层叠拼接成单元拼接体。生产设备包括热复合挤出模具、几何体成型组件、切割组件、导向定位组件和热熔连接组件等。本发明提供了一种热塑性复合芯材的生产方法和生产设备,能够低成本、连续地生产出兼备结构强度高和功能多样化的双层结构热塑性复合芯材。
The invention discloses a production method and production equipment of a thermoplastic composite core material. The production method comprises: forming a flat sheet with a structural layer and a functional layer by thermal compounding in a mold and continuously outputting along the output direction of the assembly line; dividing and processing the flat sheet into A plurality of core material unit pieces with the same width along the broadside output direction and in the shape of a belt along the pipeline output direction, wherein at least part of the core material unit pieces are processed with non-closed geometry repeatedly presented along the pipeline output direction on the sheet surface; A plurality of core material unit sheets are stacked and spliced along the broadside output direction to form a unit splicing body. The production equipment includes thermal composite extrusion dies, geometry forming components, cutting components, guiding positioning components and hot melt connection components, etc. The invention provides a production method and production equipment of a thermoplastic composite core material, which can continuously produce a double-layer thermoplastic composite core material with high structural strength and diversified functions at low cost.
Description
技术领域technical field
本发明涉及材料成型技术领域,具体地,涉及一种热塑性复合芯材的生产方法和生产设备。The invention relates to the technical field of material forming, in particular to a production method and production equipment of a thermoplastic composite core material.
背景技术Background technique
蜂窝芯板不仅具有低密度、高强度的优点,还具备减震、隔音、隔热等许多优异的性能,因此被广泛应用在船舶、交通运输、航空航天等领域。其中,热塑性蜂窝芯材更具有极高的比强度、废料可回收再生利用、热成型性能好等优势,相比传统的金属材料和非可再生的热固性材料更具有竞争力。Honeycomb core panels not only have the advantages of low density and high strength, but also have many excellent properties such as shock absorption, sound insulation, and heat insulation, so they are widely used in ships, transportation, aerospace and other fields. Among them, thermoplastic honeycomb core materials have the advantages of extremely high specific strength, recyclable waste materials, and good thermoforming performance. Compared with traditional metal materials and non-renewable thermosetting materials, they are more competitive.
市面上的热塑性蜂窝芯材主要通过吹塑或吸塑的工艺生产成型,受限于加工压力和热塑性材料的塑性性能等,吸塑或者吹塑均不宜用来加工形状复杂或壁厚较大的产品,由此限制了热塑性蜂窝芯材的最大壁厚。此外,热塑性芯材由于壁厚较薄、容易产生破壁,不利于添加结构填料或者功能填料,导致热塑性芯材的功能多样化受限,无法满足实际应用中的多样化需求。Thermoplastic honeycomb core materials on the market are mainly produced by blow molding or blister technology, which is limited by processing pressure and plastic properties of thermoplastic materials. Blister molding or blow molding are not suitable for processing complex shapes or large wall thicknesses. products, thereby limiting the maximum wall thickness of the thermoplastic honeycomb core. In addition, due to the thin wall thickness of thermoplastic core materials, it is easy to cause wall breakage, which is not conducive to adding structural fillers or functional fillers, resulting in limited functional diversification of thermoplastic core materials, which cannot meet the diverse needs of practical applications.
另外,随着实际应用需求的不断升级,由单一结构材料制备的热塑性蜂窝芯材已不能满足各种复杂的应用场景。在实际应用场景中,热塑性蜂窝芯材除了需要达到轻质重载的要求,往往还需要针对不同的使用环境来适应性地增加一些使用功能,如阻燃性能、隔音性能、防腐性能等。现有的蜂窝形芯材通常通过在蜂窝壁的基体材料中分散性地添加功能填料的方式来产生新的功能,但功能材料受限于可添加的比例以及分散性的分布特点,其产生的功能效果也大大受限,导致现有的热塑性芯材在功能需求多样化方面存在瓶颈。In addition, with the continuous upgrading of practical application requirements, thermoplastic honeycomb core materials made of a single structural material can no longer meet various complex application scenarios. In practical application scenarios, in addition to meeting the requirements of light weight and heavy load, thermoplastic honeycomb core materials often need to be adaptively added to different use environments, such as flame retardant performance, sound insulation performance, anti-corrosion performance, etc. Existing honeycomb core materials usually create new functions by adding functional fillers dispersedly into the matrix material of the honeycomb wall, but the functional materials are limited by the proportion that can be added and the distribution characteristics of the dispersion. Functional effects are also greatly limited, resulting in bottlenecks in the diversification of functional requirements for existing thermoplastic core materials.
发明内容Contents of the invention
针对现有技术的上述缺陷或不足,本发明提供了一种热塑性复合芯材的生产方法和生产设备,能够低成本、连续地生产出兼备结构强度高和功能多样化的双层结构热塑性复合芯材。Aiming at the above-mentioned defects or deficiencies of the prior art, the present invention provides a production method and production equipment for thermoplastic composite core materials, which can continuously produce a double-layer thermoplastic composite core with high structural strength and diversified functions at low cost material.
为实现上述目的,本发明提供了一种热塑性复合芯材的生产方法,包括:To achieve the above object, the invention provides a production method of thermoplastic composite core material, comprising:
模内热复合成型具有结构层和功能层的平整的片材并沿流水线输出方向持续输出;In-mold thermal composite molding of flat sheets with structural layers and functional layers and continuous output along the output direction of the assembly line;
将所述片材分割加工成沿宽边输出方向等宽且沿所述流水线输出方向呈带状的多个芯材单元片,其中至少部分的所述芯材单元片的片材表面上加工有沿所述流水线输出方向重复呈现的非闭合的几何体;The sheet is divided and processed into a plurality of core material units with the same width along the output direction of the broadside and in the shape of a belt along the output direction of the assembly line, wherein at least part of the sheet surface of the core material unit is processed with non-closed geometry repeatedly rendered along the pipeline output direction;
将多个所述芯材单元片沿所述宽边输出方向层叠拼接成单元拼接体,所述单元拼接体包括沿所述流水线输出方向依次分布并通过所述几何体拼接形成的多个轴孔结构。stacking and splicing a plurality of core material unit pieces along the broadside output direction into a unit splicing body, and the unit splicing body includes a plurality of axial hole structures distributed sequentially along the pipeline output direction and formed by splicing the geometric bodies .
进一步地,在所述片材中,所述功能层与用于承受载荷的所述结构层可具有相容性。Further, in the sheet material, the functional layer may have compatibility with the structural layer for bearing load.
可选地,沿流水线输出方向持续输出的所述片材中,所述结构层的片层厚度不小于0.1mm。Optionally, among the sheets continuously output along the output direction of the assembly line, the sheet thickness of the structural layer is not less than 0.1 mm.
可选地,所述轴孔结构包括拼接轴孔和围绕所述拼接轴孔的周向封闭的轴孔周壁,任意形状的所述拼接轴孔的外接圆的直径不小于1mm;和/或,任意形状的所述拼接轴孔的孔轴长与该拼接轴孔的外接圆的直径之比不大于200。Optionally, the shaft hole structure includes a spliced shaft hole and a circumferentially closed shaft hole wall surrounding the spliced shaft hole, and the diameter of the circumscribed circle of the spliced shaft hole of any shape is not less than 1 mm; and/or, The ratio of the axial length of the spliced shaft hole of any shape to the diameter of the circumscribed circle of the spliced shaft hole is not greater than 200.
进一步地,将多个所述芯材单元片沿所述宽边输出方向层叠拼接成单元拼接体可包括:Further, stacking and splicing a plurality of core material unit sheets along the broadside output direction into a unit splicing body may include:
将分割加工后的各个所述芯材单元片分别翻转预设角度,使得翻转后的所述芯材单元片长度方向(L)保持沿所述流水线输出方向,芯材单元片宽度方向(W)与所述片材的宽边输出方向之间形成夹角(a);Each of the divided and processed core material units is turned over at a preset angle, so that the length direction (L) of the turned over core material unit remains along the output direction of the assembly line, and the core material unit width direction (W) forming an angle (a) with the broadside output direction of the sheet;
沿所述宽边输出方向将翻转后的各个所述芯材单元片收拢并层叠拼接成单元拼接体。Each of the turned core material unit pieces is gathered and laminated and spliced into a unit splicing body along the broadside output direction.
此外,各个所述芯材单元片的旋转轴线(PP’)可沿所述流水线输出方向。In addition, the rotation axis (PP') of each of the core material unit pieces may be along the output direction of the pipeline.
可选地,将分割加工后的各个所述芯材单元片分别翻转预设角度包括:使任意相邻的两个所述芯材单元片的翻转方向相反;Optionally, turning each of the divided and processed core material unit pieces at preset angles includes: making the turning directions of any two adjacent core material unit pieces opposite;
其中,在沿所述宽边输出方向依次排布的第一芯材单元片、第二芯材单元片和第三芯材单元片中,所述第二芯材单元片的所述结构层与一侧的所述第一芯材单元片的所述结构层沿所述宽边输出方向对齐,所述第二芯材单元片的所述功能层与另一侧的所述第三芯材单元片的所述功能层沿所述宽边输出方向对齐。Wherein, in the first core material unit piece, the second core material unit piece and the third core material unit piece arranged in sequence along the broadside output direction, the structural layer of the second core material unit piece is The structural layer of the first core material unit sheet on one side is aligned along the broadside output direction, the functional layer of the second core material unit sheet is aligned with the third core material unit on the other side The functional layers of the sheet are aligned along the broadside output direction.
可选地,将分割加工后的各个所述芯材单元片分别翻转预设角度包括:使任意相邻的两个所述芯材单元片的翻转方向相同;Optionally, turning each of the divided and processed core material unit pieces at preset angles includes: making the turning directions of any two adjacent core material unit pieces the same;
其中,在沿所述宽边输出方向依次排布的第一芯材单元片、第二芯材单元片和第三芯材单元片中,所述第二芯材单元片的所述结构层与一侧的所述第一芯材单元片的所述功能层沿所述宽边输出方向对齐,所述第二芯材单元片的所述功能层与另一侧的所述第三芯材单元片的所述结构层沿所述宽边输出方向对齐。Wherein, in the first core material unit piece, the second core material unit piece and the third core material unit piece arranged in sequence along the broadside output direction, the structural layer of the second core material unit piece is The functional layer of the first core material unit sheet on one side is aligned along the broadside output direction, the functional layer of the second core material unit sheet is aligned with the third core material unit on the other side The structural layers of the sheet are aligned along the broadside output direction.
进一步地,将多个所述芯材单元片沿所述宽边输出方向层叠拼接成单元拼接体还包括:Further, stacking and splicing a plurality of core material unit sheets along the broadside output direction into a unit splicing body further includes:
在层叠拼接之前,沿所述流水线输出方向移动调整所述芯材单元片,使得任意相邻的两个所述芯材单元片中,一者的几何形状高点与另一者的几何形状低点沿所述宽边输出方向对齐。Before lamination and splicing, move and adjust the core material unit piece along the output direction of the assembly line, so that in any two adjacent core material unit pieces, one has a high geometric shape and the other has a low geometric shape Points are aligned along the broadside output direction.
可选地,将多个所述芯材单元片沿所述宽边输出方向层叠拼接成单元拼接体包括:Optionally, stacking and splicing a plurality of core material unit sheets along the broadside output direction into a unit splicing body includes:
在各个所述芯材单元片的接触表面涂覆胶接层,并通过所述胶接层连接相邻的所述芯材单元片;或者Coating an adhesive layer on the contact surface of each of the core material units, and connecting adjacent core material units through the adhesive layer; or
使任意相邻的所述芯材单元片之间的所述结构层或所述功能层之间以熔融粘接方式相连。The structural layers or the functional layers between any adjacent core material unit sheets are connected by fusion bonding.
可选地,所述结构层的材质包括热塑性聚合物、填料填充的热塑性聚合物、纤维增强的热塑性树脂基复合材料、塑性形变纸张和/或钢塑复合物。Optionally, the material of the structural layer includes thermoplastic polymers, filled thermoplastic polymers, fiber-reinforced thermoplastic resin-based composite materials, plastically deformable paper and/or steel-plastic composites.
进一步地,所述热塑性聚合物可为聚丙烯、聚乙烯、聚酰胺、热塑性聚酯、聚氯乙烯、聚苯乙烯、聚碳酸酯、聚苯醚、热塑性弹性体、多元共聚热塑性塑料、聚甲基丙烯酸甲酯、聚苯硫醚、聚醚醚酮和聚酰亚胺中的一种或其中多种的共混物;Further, the thermoplastic polymer can be polypropylene, polyethylene, polyamide, thermoplastic polyester, polyvinyl chloride, polystyrene, polycarbonate, polyphenylene ether, thermoplastic elastomer, multi-component copolymerized thermoplastic, polymethyl One of methyl acrylate, polyphenylene sulfide, polyether ether ketone and polyimide or a blend of multiple thereof;
或者,填料填充的所述热塑性聚合物中的填料可为蜡、滑石粉、炭黑、白炭黑、高岭土、碳酸钙、硬脂酸、硬脂酸钙、晶须、二氧化钛、氧化铁、颜料、阻燃剂和抗氧剂中的一种或其中多种的组合物;Alternatively, the filler in the thermoplastic polymer filled with filler can be wax, talc, carbon black, silica, kaolin, calcium carbonate, stearic acid, calcium stearate, whiskers, titanium dioxide, iron oxide, pigment One or more combinations of flame retardants and antioxidants;
或者,纤维增强的所述热塑性树脂基复合材料中的纤维可为有机纤维、无机纤维、金属纤维、高分子纤维、植物纤维中的一种或多种;Alternatively, the fibers in the fiber-reinforced thermoplastic resin-based composite material can be one or more of organic fibers, inorganic fibers, metal fibers, polymer fibers, and plant fibers;
或者,纤维增强的所述热塑性树脂基复合材料中的纤维可为玻璃纤维、碳纤维、玄武岩纤维、钢丝纤维、聚丙烯纤维、聚酯纤维、超高分子量聚乙烯纤维、聚酰亚胺纤维和麻纤维中的一种或者其中多种的组合物。Alternatively, the fibers in the fiber-reinforced thermoplastic resin-based composite material may be glass fibers, carbon fibers, basalt fibers, steel fibers, polypropylene fibers, polyester fibers, ultra-high molecular weight polyethylene fibers, polyimide fibers, and hemp fibers. One or a combination of multiple fibers.
可选地,所述功能层为阻燃层、抗紫外层、颜色层、阻热或传热层、透磁或阻磁层、防腐层、或隔音层中的一种或者多种功能组合层。Optionally, the functional layer is one or more functional combination layers in a flame retardant layer, an anti-ultraviolet layer, a color layer, a heat-resistant or heat-transfer layer, a magnetically permeable or magnetically resistant layer, an anti-corrosion layer, or a sound-insulating layer .
进一步地,所述功能层的材质可包括阻燃填料填充聚合物、抗紫外填料填充聚合物、颜料填料填充聚合物、阻热或传热填料填充聚合物、透磁或阻磁填料填充聚合物、防腐填料填充聚合物、隔音填料填充聚合物中的一种或者多种组合物。Further, the material of the functional layer may include a flame-retardant filler-filled polymer, an anti-ultraviolet filler-filled polymer, a pigment-filled polymer, a heat-resistant or heat-transfer filler-filled polymer, a magnetically permeable or magnetic-resistant filler-filled polymer One or more combinations of anti-corrosion filler-filled polymers and sound-insulating filler-filled polymers.
更进一步地,所述生产方法还可包括:Further, the production method may also include:
使得在拼接成型的所述单元拼接体中,当所述片材的片材表面的垂直方向为承受压缩载荷方向时,所述单元拼接体的材料体积利用率不低于60%,优选的,材料体积利用率不低于80%;In the unit splicing formed by splicing, when the vertical direction of the sheet surface of the sheet is the direction to bear the compressive load, the material volume utilization rate of the unit splicing body is not lower than 60%, preferably, The material volume utilization rate is not less than 80%;
和/或,在所述单元拼接体的平行于所述片材的片材表面的芯材横截面上,平面空隙率不低于40%,进一步的,所述平面空隙率不低于60%。And/or, on the cross-section of the core material of the unit assembly parallel to the sheet surface of the sheet, the planar void ratio is not lower than 40%, further, the planar void ratio is not lower than 60% .
根据本发明的另一方面,提供了一种热塑性组合芯材的生产设备,包括:According to another aspect of the present invention, a kind of production equipment of thermoplastic composite core material is provided, comprising:
热塑材料成型设备,用于在模内热复合成型具有结构层和功能层的平整的片材并沿流水线输出方向持续输出;Thermoplastic material molding equipment, used for thermal composite molding in the mold of flat sheets with structural layers and functional layers and continuous output along the output direction of the assembly line;
芯材单元片加工成型组件,用于将所述片材分割加工成沿宽边输出方向等宽且沿所述流水线输出方向呈带状的多个芯材单元片,其中至少部分的所述芯材单元片的片材表面上加工有沿所述流水线输出方向重复呈现的非闭合的几何体;The core material unit piece processing and forming component is used to divide and process the sheet into a plurality of core material unit pieces with the same width along the output direction of the broadside and a belt shape along the output direction of the assembly line, wherein at least part of the core material The sheet surface of the material unit sheet is processed with non-closed geometric bodies that are repeatedly presented along the output direction of the assembly line;
单元拼接体拼接组件,用于将多个所述芯材单元片沿所述宽边输出方向层叠拼接成单元拼接体,所述单元拼接体包括沿所述流水线输出方向依次分布并通过所述几何体拼接形成的多个轴孔结构。The unit splicing body splicing assembly is used to stack and splice a plurality of the core material unit sheets along the broadside output direction into a unit splicing body, and the unit splicing body includes sequentially distributed along the pipeline output direction and passes through the geometric body Multiple shaft hole structures formed by splicing.
可选地,所述热塑材料成型设备包括上下布置的第一挤出模具和第二挤出模具以及位于所述第一挤出模具和所述第二挤出模具的成型挤出口的热复合成型段。Optionally, the thermoplastic material molding equipment includes a first extrusion die and a second extrusion die arranged up and down, and a heat compounding device located at the molding extrusion port of the first extrusion die and the second extrusion die. Forming section.
进一步地,所述单元拼接体拼接组件包括:Further, the splicing assembly of the unit splicing body includes:
导向定位组件,用于将分割加工后的各个所述芯材单元片分别翻转预设角度,使得翻转后的所述芯材单元片长度方向保持沿所述流水线输出方向,所述芯材单元片宽度方向与所述片材的宽边输出方向之间形成夹角;The guiding and positioning component is used to flip each of the divided and processed core material units at a preset angle, so that the length direction of the turned core material unit remains along the output direction of the assembly line, and the core material unit An included angle is formed between the width direction and the broadside output direction of the sheet;
聚拢组件,用于沿所述宽边输出方向收拢各个所述芯材单元片;Gathering components, used to gather each of the core material unit pieces along the output direction of the broadside;
熔融粘接组件,用于加热各个所述芯材单元片以熔融粘接成单元拼接体。The fusion bonding component is used for heating each of the core material unit pieces to melt and bond them into a unit splicing body.
根据本发明的另一方面,还提供了一种热塑性组合芯材的生产设备,包括:According to another aspect of the present invention, a kind of production equipment of thermoplastic composite core material is also provided, comprising:
热塑材料成型设备,用于在模内热复合成型具有结构层和功能层的平整的片材并沿流水线输出方向持续输出;Thermoplastic material molding equipment, used for thermal composite molding in the mold of flat sheets with structural layers and functional layers and continuous output along the output direction of the assembly line;
芯材单元片加工成型组件,用于将所述片材分割加工成沿宽边输出方向等宽且沿所述流水线输出方向呈带状的多个芯材单元片,其中至少部分的所述芯材单元片的片材表面上加工有沿所述流水线输出方向重复呈现的非闭合的几何体;The core material unit piece processing and forming component is used to divide and process the sheet into a plurality of core material unit pieces with the same width along the output direction of the broadside and a belt shape along the output direction of the assembly line, wherein at least part of the core material The sheet surface of the material unit sheet is processed with non-closed geometric bodies that are repeatedly presented along the output direction of the assembly line;
胶枪,用于在各个所述芯材单元片的接触表面涂覆胶接层;单元拼接体拼接组件,用于将多个所述芯材单元片沿所述宽边输出方向层叠拼接成单元拼接体,所述单元拼接体包括沿所述流水线输出方向依次分布并通过所述几何体拼接形成的多个轴孔结构。A glue gun, used for coating an adhesive layer on the contact surface of each of the core material unit pieces; a unit splicing assembly, used for stacking and splicing a plurality of the core material unit pieces along the output direction of the broadside into a unit A splicing body, the unit splicing body includes a plurality of axial hole structures distributed sequentially along the output direction of the pipeline and formed by splicing the geometric bodies.
本发明的生产方法可通过例如热复合挤出模具等持续输出双层塑性材料,可适应性地将不同的功能材料与结构材料热复合成型为蜂窝形芯材,由此生产出来的双层结构热塑性复合芯材不仅保持了原有结构材料的轻质重载的优点,还能通过与功能性材料结合获得单一组成材料所不能达到的综合性能,如阻燃性能、屏蔽性能、吸音性能等。并且,本生产方法生产连续性较好,一体化生产出蜂窝体,生产效率高。此外,本发明的生产设备均由多个相对简单的装置组成,大大降低生产成本、并可实现连续大规模生产。The production method of the present invention can continuously output double-layer plastic materials through thermal composite extrusion dies, etc., and can adaptively thermally composite different functional materials and structural materials into honeycomb core materials, thereby producing a double-layer structure Thermoplastic composite core materials not only maintain the advantages of light weight and heavy load of the original structural materials, but also obtain comprehensive properties that cannot be achieved by a single component material by combining with functional materials, such as flame retardancy, shielding performance, and sound absorption performance. Moreover, the production method has good production continuity, and the honeycomb body is produced in an integrated manner, and the production efficiency is high. In addition, the production equipment of the present invention is composed of a plurality of relatively simple devices, which greatly reduces the production cost and can realize continuous large-scale production.
本发明的其它特征和优点将在随后的具体实施方式部分予以详细说明。Other features and advantages of the present invention will be described in detail in the detailed description that follows.
附图说明Description of drawings
附图是用来提供对本发明的进一步理解,并且构成说明书的一部分,与下面的具体实施方式一起用于解释本发明,但并不构成对本发明的限制。在附图中:The accompanying drawings are used to provide a further understanding of the present invention, and constitute a part of the description, together with the following specific embodiments, are used to explain the present invention, but do not constitute a limitation to the present invention. In the attached picture:
图1为根据本发明的具体实施例中,热塑性复合芯材的生产方法的流程示意图;Fig. 1 is according to the specific embodiment of the present invention, the schematic flow sheet of the production method of thermoplastic composite core material;
图2为根据发明的一种具体实施例的热塑材料成型设备;Fig. 2 is a thermoplastic material molding device according to a specific embodiment of the invention;
图3为应用于图1的生产方法中的生产设备的一种具体实施例的结构示意图;Fig. 3 is a schematic structural view of a specific embodiment of the production equipment used in the production method of Fig. 1;
图4为构成本发明的单元拼接体的一种具体实施例的最小组成单元的芯材单元片的主视图;Fig. 4 is the front view of the core material unit sheet of the smallest constituent unit constituting a specific embodiment of the unit assembly of the present invention;
图5为图4的局部放大示意图;Fig. 5 is a partially enlarged schematic diagram of Fig. 4;
图6展示了根据本发明的一种具体实施例的热塑性复合芯材的立体结构;Fig. 6 shows the three-dimensional structure of the thermoplastic composite core material according to a specific embodiment of the present invention;
图7为图6的主视图;Fig. 7 is the front view of Fig. 6;
图8展示了图4所示的芯材单元片的一种层叠拼接的方式,其中任意相邻的两个芯材单元片的翻转方向相同;Fig. 8 shows a kind of lamination splicing mode of the core material unit piece shown in Fig. 4, wherein the turning direction of any adjacent two core material unit pieces is the same;
图9为图8的局部放大示意图;Fig. 9 is a partially enlarged schematic diagram of Fig. 8;
图10展示了图4所示的芯材单元片的另一种层叠拼接的方式,其中任意相邻的两个芯材单元片的翻转方向相反;Fig. 10 shows another way of lamination and splicing of the core material unit pieces shown in Fig. 4, wherein the turning directions of any two adjacent core material unit pieces are opposite;
图11为图10的局部放大示意图;Fig. 11 is a partially enlarged schematic diagram of Fig. 10;
图12为展示了一种根据本发明的热塑性复合芯材的结构的主视图,其中的拼接轴孔有多种形状,相邻的芯材单元片的结构形状不同。Fig. 12 is a front view showing the structure of a thermoplastic composite core material according to the present invention, wherein the spliced shaft holes have various shapes, and the structural shapes of adjacent core material unit pieces are different.
附图标记说明:Explanation of reference signs:
100 单元拼接体 101 拼接轴孔100 unit splice body 101 splice shaft hole
102 几何形状高点 103 几何形状低点102 Geometry Highs 103 Geometry Lows
104 几何体 105 几何体第一内孔104 Geometry 105 Geometry 1st inner hole
106 几何体第二内孔 1 热塑材料成型设备106 geometry second inner hole 1 thermoplastic material molding equipment
1a 第一挤出模具 1b 第二挤出模具1a First Extrusion Die 1b Second Extrusion Die
1c 热复合成型段 2 几何体成型组件1c Thermal composite forming section 2 Geometry forming component
4 切割组件 5 导向定位组件4 Cutting component 5 Guide positioning component
7 聚拢组件 8 热熔连接组件7 Gathering Components 8 Fusion Joining Components
10 平整片材10 flat sheets
20 片材单元带 30 芯材单元片20 sheet unit with 30 core unit
31 平整芯材单元片 32 几何芯材单元片31 Flat core element 32 Geometric core element
A 结构层 B 功能层A Structural layer B Functional layer
D1 第一方向 D2 第二方向D1 first direction D2 second direction
D3 第三方向 Z 流水线平台垂直方向D3 The third direction Z Vertical direction of assembly line platform
X 流水线输出方向 Y 宽边输出方向X Pipeline output direction Y Broadside output direction
a 夹角 OO' 几何内孔中心线a Included angle OO' Centerline of geometric inner hole
W 芯材单元片宽度方向 L 芯材单元片长度方向W Core element width direction L Core element length direction
具体实施方式Detailed ways
以下结合附图对本发明实施例的具体实施方式进行详细说明。应当理解的是,此处所描述的具体实施方式仅用于说明和解释本发明实施例,并不用于限制本发明实施例。The specific implementation manners of the embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings. It should be understood that the specific implementation manners described here are only used to illustrate and explain the embodiments of the present invention, and are not intended to limit the embodiments of the present invention.
需要说明的是,在不冲突的情况下,本发明中的实施例及实施例中的特征可以相互组合。It should be noted that, in the case of no conflict, the embodiments of the present invention and the features in the embodiments can be combined with each other.
在本发明实施例中,在未作相反说明的情况下,使用的方位词如“上、下、顶、底”通常是针对附图所示的方向而言的或者是针对竖直、垂直或重力方向上而言的各部件相互位置关系描述用词。In the embodiments of the present invention, unless stated to the contrary, the used orientation words such as "up, down, top, bottom" usually refer to the directions shown in the drawings or refer to vertical, vertical or The term used to describe the mutual positional relationship of each component in terms of the direction of gravity.
下面将参考附图并结合示例性实施例来详细说明本发明。The present invention will be described in detail below in conjunction with exemplary embodiments with reference to the accompanying drawings.
本发明的示例性实施例中提供了一种热塑性复合芯材及其生产方法和生产设备。如图4~图12所示,本发明的热塑性复合芯材为蜂窝形芯材,即为图6中所示单元拼接体100,该单元拼接体100由多个沿第一方向D1延伸且沿第二方向D2层叠拼接的芯材单元片30组成。其中,芯材单元片30的成型板材为包括结构层A和功能层B的双层片材结构,该结构层A为用于形成承受载荷的结构材料,而功能层B则为用于提供各种功能的功能材料。Exemplary embodiments of the present invention provide a thermoplastic composite core material and a production method and production equipment thereof. As shown in Figures 4 to 12, the thermoplastic composite core material of the present invention is a honeycomb core material, that is, the unit splicing body 100 shown in Figure 6, the unit splicing body 100 is composed of a plurality of The core material unit sheets 30 are stacked and spliced in the second direction D2. Wherein, the molded plate of the core unit sheet 30 is a double-layer sheet structure comprising a structural layer A and a functional layer B, the structural layer A is used to form a load-bearing structural material, and the functional layer B is used to provide various functional materials.
现有的热塑性蜂窝芯材通常通过在蜂窝壁的基体材料中分散性地添加功能填料的方式来增加热塑性蜂窝芯材的新功能,如阻燃、防热、屏蔽、吸声等功能。但是此种方式受限于功能填料的可添加最大比例以及实际分布状况,性能往往分散性大且难以精确控制材料的结构和性能,功能填料产生的功能效果也大大受限,导致现有的热塑性蜂窝芯材在进一步提高复合功能方面存在瓶颈。The existing thermoplastic honeycomb core materials usually increase the new functions of thermoplastic honeycomb core materials by adding functional fillers dispersedly in the matrix material of the honeycomb wall, such as flame retardancy, heat protection, shielding, sound absorption and other functions. However, this method is limited by the maximum proportion of functional fillers that can be added and the actual distribution. The performance is often highly dispersed and it is difficult to accurately control the structure and properties of the material. The functional effects of functional fillers are also greatly limited, resulting in the existing thermoplastic The honeycomb core material has a bottleneck in further improving the composite function.
此外,市面上的热塑性蜂窝形芯材主要有两种,一种是圆管式蜂窝芯材,即通过挤出壁厚较厚的圆管后将其吹塑形成壁厚较小的圆管,并将多根圆管堆成坨后放入烤箱进行加热,圆管加热后相互粘结形成圆管式蜂窝形芯材。此圆管式蜂窝芯材的生产简单但不连续、生产效率低。还有一种是在片材表面吸塑形成半蜂窝形结构,然后将成型后的片材折叠成蜂窝体结构,该折叠式蜂窝芯材生产连续但控制复杂,且物料浪费较多。再者,无论是圆管式蜂窝芯材还是折叠式蜂窝芯材,都需要通过吹塑或者吸塑的生产工艺成型,吹塑或吸塑均受限于加工压力和热塑性材料的塑性性能等,使得热塑性蜂窝芯材的最大壁厚受限且容易产生破壁,不利于添加结构填料或者功能填料,导致热塑性芯材的应用场合受限,无法满足实际应用中的多样化的需求。In addition, there are mainly two types of thermoplastic honeycomb core materials on the market, one is the round tube honeycomb core material, that is, a round tube with a thicker wall thickness is extruded and then blown into a round tube with a smaller wall thickness. A plurality of round tubes are piled up and put into an oven for heating, and the round tubes are bonded to each other after heating to form a round tube honeycomb core material. The production of the round tube type honeycomb core material is simple but discontinuous and the production efficiency is low. Another method is to form a semi-honeycomb structure by absorbing plastic on the surface of the sheet, and then fold the formed sheet into a honeycomb structure. The production of the folded honeycomb core material is continuous but the control is complicated, and there is more material waste. Furthermore, whether it is a circular tubular honeycomb core material or a folded honeycomb core material, it needs to be formed by blow molding or blister production process, which is limited by processing pressure and plastic properties of thermoplastic materials. The maximum wall thickness of the thermoplastic honeycomb core material is limited and the wall is prone to breakage, which is not conducive to the addition of structural fillers or functional fillers, resulting in limited application of thermoplastic core materials and unable to meet the diverse needs in practical applications.
相较于现有的热塑性蜂窝芯材,本发明的热塑性复合芯材除了保持了原有结构材料的轻质重载的优点以外,本发明的热塑性复合芯材的蜂窝壁为结构层复合功能层的双层片材热复合结构,可适应性地将不同的功能材料与结构材料热复合以获得单一结构材料所不能达到的综合性能。由于功能层与结构层是独立分层设置,不存在混合比例以及分散性的限制,能够更加精确地控制材料的结构以及性能。再者,本发明的热塑性复合芯材的功能层连续分布,所能达到的功能效果显著。此外,本发明的热塑性复合芯材采用的功能层和结构层相容性好,两者之间能产生物理或化学的相容性,如浸润性、反应性和互溶性等,两者的结合强度高,满足了实际应用中的多样化的需求。Compared with the existing thermoplastic honeycomb core material, the thermoplastic composite core material of the present invention maintains the advantages of light weight and heavy load of the original structural material, and the honeycomb wall of the thermoplastic composite core material of the present invention is a structural layer composite functional layer The double-layer sheet thermal composite structure can adaptively thermally composite different functional materials and structural materials to obtain comprehensive properties that cannot be achieved by a single structural material. Since the functional layer and the structural layer are independently layered, there is no restriction on the mixing ratio and dispersion, and the structure and performance of the material can be controlled more precisely. Furthermore, the functional layers of the thermoplastic composite core material of the present invention are distributed continuously, and the functional effects that can be achieved are remarkable. In addition, the functional layer and the structural layer used in the thermoplastic composite core material of the present invention have good compatibility, and physical or chemical compatibility can be produced between the two, such as wettability, reactivity, and mutual solubility. The strength is high, which meets the diverse needs in practical applications.
进一步地,参见图1,本发明的热塑性复合芯材的生产方法可实现连续流水作业、生产效率高、大大降低生产成本、实现节约型生产,且无需采用吸塑或吹塑的生产工艺,无壁厚方面的限制,可生产出较大壁厚的的热塑性复合芯材,同时可添加各种增强填料或者功能填料,不会产生破壁,大大拓展了本发明的热塑性复合芯材的应用场合。Further, referring to Fig. 1, the production method of thermoplastic composite core material of the present invention can realize continuous flow operation, high production efficiency, greatly reduce production cost, realize economical production, and do not need to adopt the production process of blister or blow molding, without Due to the limitation of wall thickness, thermoplastic composite core materials with larger wall thickness can be produced, and various reinforcing fillers or functional fillers can be added at the same time, without breaking the wall, which greatly expands the application occasions of the thermoplastic composite core material of the present invention .
更进一步地,参见图2、图3,针对本发明的热塑性复合芯材的生产方法,相应地,本发明还提供了一种热塑性复合芯材的生产设备,该生产设备均由多个相对简单的装置组成,大大降低生产成本、并可实现连续大规模生产。Further, referring to Fig. 2 and Fig. 3, for the production method of thermoplastic composite core material of the present invention, correspondingly, the present invention also provides a kind of production equipment of thermoplastic composite core material, and the production equipment is composed of a plurality of relatively simple The composition of the device greatly reduces the production cost and realizes continuous mass production.
以下将述及本发明的热塑性复合芯材及其生产方法和生产设备。The thermoplastic composite core material of the present invention and its production method and production equipment will be described below.
其中,为了便于说明和理解本发明的热塑性复合芯材及其生产方法和生产设备,定义平整片材10从热塑材料成型设备1沿流水线持续输出的方向为流水线输出方向X,即平整片材10的长度方向;定义平整片材10的宽度方向为平整片材10的宽边输出方向Y;定义垂直于流水线平台的方向为垂直方向Z。参见图3,坐标系原点均设置在热塑材料成型设备1的上游,并通过流水线输出方向X、宽边输出方向Y和流水线平台垂直方向Z共同限定出了每一组生产设备的绝对坐标系。定义芯材单元片宽度方向为单元拼接体100的第三方向D3;定义芯材单元片长度方向L为单元拼接体100的第一方向D1;定义单元拼接体100的厚度方向为单元拼接体的第二方向D2。Among them, in order to facilitate the description and understanding of the thermoplastic composite core material and its production method and production equipment of the present invention, the direction in which the flat sheet 10 is continuously output from the thermoplastic material molding equipment 1 along the assembly line is defined as the output direction X of the assembly line, that is, the flat sheet The length direction of 10; the width direction of the flat sheet 10 is defined as the broadside output direction Y of the flat sheet 10; the direction perpendicular to the assembly line platform is defined as the vertical direction Z. Referring to Figure 3, the origin of the coordinate system is set at the upstream of the thermoplastic material molding equipment 1, and the absolute coordinate system of each group of production equipment is jointly defined by the output direction X of the assembly line, the output direction Y of the wide side and the vertical direction Z of the assembly line platform . Define the core material unit sheet width direction as the third direction D3 of the unit splicing body 100; define the core material unit sheet length direction L as the first direction D1 of the unit splicing body 100; define the thickness direction of the unit splicing body 100 as the unit splicing body The second direction D2.
参见图1,本发明的热塑性复合芯材的生产方法可包括步骤:Referring to Fig. 1, the production method of thermoplastic composite core material of the present invention may comprise steps:
S11、模内热复合成型具有结构层A和功能层B的平整片材10并沿流水线输出方向X持续输出;S11. The flat sheet 10 having the structural layer A and the functional layer B is formed by in-mold thermocompositing, and is continuously output along the output direction X of the assembly line;
S12、将平整片材10分割加工成沿宽边输出方向Y等宽且沿流水线输出方向X呈带状的多个芯材单元片30,其中至少部分的芯材单元片30的片材表面上加工有沿流水线输出方向X重复呈现的非闭合的几何体104;S12. Divide and process the flat sheet 10 into a plurality of core material unit pieces 30 having the same width along the broadside output direction Y and belt-shaped along the pipeline output direction X, wherein at least part of the core material unit pieces 30 are on the sheet surface Process open geometry 104 with repeated representations along the pipeline output direction X;
S13、将多个芯材单元片30沿宽边输出方向Y层叠拼接成单元拼接体100,单元拼接体100包括沿流水线输出方向X依次分布并通过几何体104拼接形成的多个轴孔结构。S13. Stack and splice a plurality of core material unit pieces 30 along the broadside output direction Y to form a unit splicing body 100 . The unit splicing body 100 includes a plurality of axial hole structures distributed sequentially along the pipeline output direction X and spliced by geometric bodies 104 .
其中,在S11中,平整片材10的输出方式可采用挤出、流延、压延或辊压加工等。平整片材10均为具有结构层A和功能层B的双层片材热复合结构,结构层A和功能层B的材料具有相容性,可直接在生产流水线上热复合成型,即沿流水线输出方向X同步输出的结构材料和功能材料在模具内可不通过粘结剂直接热复合成型,由此双层片材热复合结构可连续沿流水线输出方向X直接成型输出,生产工艺简单连续。并且,功能层B可适应性地根据所需的功能选择不同的功能材料与结构层A的结构材料进行热复合,可选地,功能材料可为阻燃材料、隔音材料、防腐材料等其他符合本发明的功能材料。Wherein, in S11, the output method of the flat sheet 10 may be extrusion, casting, calendering or rolling processing. The flat sheet 10 is a double-layer sheet thermal composite structure with a structural layer A and a functional layer B. The materials of the structural layer A and the functional layer B are compatible, and can be thermally composited directly on the production line, that is, along the line The structural materials and functional materials that are output synchronously in the output direction X can be directly thermally compounded in the mold without binders, so that the double-layer sheet thermal composite structure can be directly formed and output along the output direction X of the assembly line, and the production process is simple and continuous. Moreover, the functional layer B can adaptively select different functional materials according to the required functions for thermal compounding with the structural material of the structural layer A. Optionally, the functional materials can be flame-retardant materials, sound-insulating materials, anti-corrosion materials, etc. Functional material of the present invention.
并且,由于在本发明的第一生产方法中无吸塑或者吹塑工艺,故热塑性复合材料无壁厚方面限制,即沿流水线输出方向X持续输出的平整片材10中,结构层A的片层厚度可不小于0.1mm,由此形成的蜂窝形芯体的结构强度高。Moreover, since there is no blister or blow molding process in the first production method of the present invention, the thermoplastic composite material has no wall thickness limitation, that is, in the flat sheet 10 that is continuously output along the output direction X of the assembly line, the sheet of the structural layer A The thickness of the layer can be not less than 0.1 mm, and the structural strength of the honeycomb core formed thereby is high.
需要说明的是,平整片材10可采用直接挤出的成型方式,由于平整片材10沿宽边输出方向Y的输出宽边尺寸有限,故可沿宽边输出方向Y多组输出平整片材10,由此增加沿宽边输出方向Y同步输出的几何芯材单元片32或平整芯材单元片31的数量,由此可较大程度地拓展单元拼接体100的生产尺寸。It should be noted that the flat sheet 10 can be formed by direct extrusion. Since the output width of the flat sheet 10 along the width output direction Y is limited, multiple groups of flat sheets can be output along the width output direction Y. 10, thereby increasing the number of geometric core material unit pieces 32 or flattened core material unit pieces 31 synchronously output along the broadside output direction Y, thereby expanding the production size of the unit assembly 100 to a large extent.
进一步地,根据加工片材形状和分割片材的先后顺序,S12可包括子步骤:Further, according to the shape of the processed sheet and the sequence of dividing the sheet, S12 may include sub-steps:
S121、将平整片材10分割加工成沿宽边输出方向Y等宽且沿流水线输出方向X呈带状的多个片材单元带20;S121. Divide and process the flat sheet 10 into a plurality of sheet unit belts 20 having the same width along the output direction Y of the broadside and in the shape of a belt along the output direction X of the assembly line;
S122、将至少部分的片材单元带20的片材表面上加工有沿流水线输出方向X重复呈现的非闭合的几何体104,从而形成沿流水线输出方向X呈带状的多个芯材单元片30。S122, processing at least part of the sheet surface of the sheet unit belt 20 with non-closed geometrical bodies 104 that appear repeatedly along the pipeline output direction X, thereby forming a plurality of core material unit pieces 30 that are strip-shaped along the pipeline output direction X .
或者,S12可包括子步骤:Alternatively, S12 may include substeps:
S121’、将平整片材10的片材表面上加工有沿流水线输出方向X重复呈现的非闭合的几何体104;S121', processing the sheet surface of the flat sheet 10 with non-closed geometry 104 repeatedly presented along the pipeline output direction X;
S122’、将表面已加工完成的平整片材10分割加工成沿宽边输出方向Y等宽且沿流水线输出方向X呈带状的多个芯材单元片30。S122', dividing and processing the flat sheet 10 whose surface has been processed into a plurality of core material unit pieces 30 having the same width along the output direction Y of the broadside and in the shape of belts along the output direction X of the assembly line.
本领域技术人员能够理解的是,平整片材10可通过调整用于加工出几何体104的模具的形状来加工出平整单元片材31或者几何芯材单元片32,几何体104的加工方式可采用辊压、板压或者链式模具挤压等。用于加工出几何体104的模具至少部分外周部形成有呈凸起状并沿平整片材10的宽边输出方向Y延伸的棱边压接部,以在平整片材10或片材单元带20的片材表面上加工出垂直于片材表面的几何凸起部,在几何凸起部上形成有在片材表面呈非闭合状的并沿宽边输出方向Y轴向贯通的几何体第一内孔105,即形成几何体104。如图3所示,加工出的芯材单元片30上加工出有几何内孔中心线OO’平行于宽边输出方向的几何体104。Those skilled in the art can understand that the flat sheet 10 can be processed into a flat unit sheet 31 or a geometric core unit sheet 32 by adjusting the shape of the mold used to process the geometric body 104, and the geometric body 104 can be processed by rollers. Press, plate press or chain die extrusion, etc. At least part of the outer periphery of the mold used to process the geometric body 104 is formed with an edge crimping portion that is convex and extends along the broadside output direction Y of the flat sheet 10, so that the flat sheet 10 or the sheet unit belt 20 A geometric protruding portion perpendicular to the surface of the sheet is processed on the surface of the sheet material, and a geometric first interior that is not closed on the surface of the sheet material and penetrates the Y axis along the broadside output direction is formed on the geometric protruding portion. Hole 105 , ie forms geometry 104 . As shown in FIG. 3 , the processed core material unit piece 30 is processed with a geometric body 104 whose geometric inner hole centerline OO' is parallel to the broadside output direction.
进一步地,S13可包括:Further, S13 may include:
将分割加工后的各个芯材单元片30分别翻转预设角度,使得翻转后的芯材单元片长度方向L保持沿流水线输出方向X,芯材单元片宽度方向W与平整片材10的宽边输出方向Y之间形成夹角a;沿宽边输出方向Y将翻转后的各个芯材单元片30收拢并层叠拼接成单元拼接体100。其中,为了便于在生产流水线上将各个芯材单元片30进行收拢层叠,各个芯材单元片30的旋转轴线PP’沿流水线输出方向X。翻转后的各个芯材单元片30的几何内孔中心线OO’可能会倾斜于流水线平台。可选地,如图3所示,夹角a为90°,翻转后的各个芯材单元片30的几何内孔中心线OO’垂直于流水线平台,即翻转后的各个芯材单元片30与平整片材10垂直。Each core material unit piece 30 after splitting and processing is respectively turned over a predetermined angle, so that the length direction L of the turned over core material unit piece remains along the line output direction X, and the width direction W of the core material unit piece is in line with the wide side of the flat sheet 10. An included angle a is formed between the output directions Y; along the broadside output direction Y, the turned core material unit pieces 30 are collected and laminated to form a unit splicing body 100 . Wherein, in order to facilitate stacking and stacking each core material unit piece 30 on the production line, the rotation axis PP' of each core material unit piece 30 is along the output direction X of the line. The centerline OO' of the geometric inner hole of each core material unit piece 30 after turning over may be inclined to the assembly line platform. Optionally, as shown in FIG. 3 , the included angle a is 90°, and the geometric inner hole centerline OO' of each core material unit piece 30 after turning over is perpendicular to the assembly line platform, that is, each core material unit piece 30 after turning over and The flat sheet 10 is vertical.
更进一步地,将分割加工后的各个芯材单元片30分别翻转预设角度可包括:Further, turning each of the divided and processed core material unit pieces 30 to preset angles may include:
使任意相邻的两个芯材单元片30的翻转方向相反;其中,在沿宽边输出方向Y依次排布的第一芯材单元片、第二芯材单元片和第三芯材单元片中,第二芯材单元片的结构层A与一侧的第一芯材单元片的结构层A沿宽边输出方向Y对齐,第二芯材单元片的功能层B与另一侧的第三芯材单元片的功能层B沿宽边输出方向Y对齐。如图10、图11所示,相邻的两个芯材单元片30的翻转方向相反并拼接在一起时,拼接位置的组合方式为A-A-B-B接触,即相邻两个芯材单元片的拼接位置的两侧均为功能层B或均为结构层A。The turning direction of any two adjacent core material unit pieces 30 is opposite; wherein, the first core material unit piece, the second core material unit piece and the third core material unit piece arranged in sequence along the broadside output direction Y Among them, the structural layer A of the second core material unit is aligned with the structural layer A of the first core material unit on one side along the output direction Y of the broadside, and the functional layer B of the second core material unit is aligned with the second core material unit on the other side. The functional layer B of the three-core unit sheet is aligned along the output direction Y of the broadside. As shown in Figure 10 and Figure 11, when two adjacent core material unit pieces 30 are turned in the opposite direction and spliced together, the combination of the splicing position is A-A-B-B contact, that is, the splicing position of two adjacent core material unit pieces Both sides are functional layer B or both are structural layer A.
或者,将分割加工后的各个芯材单元片30分别翻转预设角度还可包括:Alternatively, turning each of the core material unit pieces 30 after division and processing to preset angles may also include:
使任意相邻的两个芯材单元片30的翻转方向相同;其中,在沿宽边输出方向Y依次排布的第一芯材单元片、第二芯材单元片和第三芯材单元片中,第二芯材单元片的结构层A与一侧的第一芯材单元片的功能层B沿宽边输出方向Y对齐,第二芯材单元片的功能层B与另一侧的第三芯材单元片的结构层A沿宽边输出方向Y对齐。如图8、图9所示,相邻的两个芯材单元片30的翻转方向相同并拼接在一起时,拼接位置的组合方式为A-B-A-B接触,即相邻两个芯材单元片30的拼接位置的其中一侧为功能层B,另一侧为结构层A。Make the turning direction of any adjacent two core material unit pieces 30 the same; wherein, the first core material unit piece, the second core material unit piece and the third core material unit piece arranged in sequence along the broadside output direction Y Among them, the structural layer A of the second core material unit is aligned with the functional layer B of the first core material unit on one side along the broadside output direction Y, and the functional layer B of the second core material unit is aligned with the first core material unit on the other side. The structural layer A of the three-core unit sheet is aligned along the broadside output direction Y. As shown in Fig. 8 and Fig. 9, when two adjacent core material unit pieces 30 have the same turning direction and are spliced together, the combination mode of the splicing position is A-B-A-B contact, that is, the splicing of two adjacent core material unit pieces 30 On one side of the location is functional floor B and on the other side is structural floor A.
此外,将多个芯材单元片30沿宽边输出方向Y层叠拼接成单元拼接体100还可包括:In addition, stacking and splicing a plurality of core material unit sheets 30 along the broadside output direction Y to form a unit splicing body 100 may further include:
在层叠拼接之前,沿流水线输出方向X移动调整芯材单元片30,使得任意相邻的两个芯材单元片30中,一者的几何形状高点102与另一者的几何形状低点103沿宽边输出方向Y对齐。如图3、图6、图7所示,多个芯材单元片30沿宽边输出方向Y层叠拼接后的单元拼接体100,任意相邻的两个芯材单元片30的其中一者的几何形状高点102与另一者的几何形状低点103沿宽边输出方向Y对齐,由此形成沿流水线输出方向X依次间隔分布且沿垂直于流水平台的垂直方向Z轴向贯通的拼接轴孔101。Before lamination and splicing, move and adjust the core material unit piece 30 along the output direction X of the assembly line, so that in any two adjacent core material unit pieces 30, one has a geometrically high point 102 and the other has a geometrically low point 103 Alignment along broadside output direction Y. As shown in Fig. 3, Fig. 6, and Fig. 7, a plurality of core material unit pieces 30 are stacked and spliced along the broadside output direction Y to form a spliced unit 100, and one of any two adjacent core material unit pieces 30 The high point 102 of the geometric shape is aligned with the low point 103 of the other geometric shape along the output direction Y of the broadside, thereby forming a splicing axis that is distributed sequentially along the output direction X of the assembly line and runs through the vertical direction Z axially perpendicular to the flow platform Hole 101.
其中,需要说明的是,当任意相邻的两个芯材单元片30形状相同且翻转方向相反时,可无需沿流水线输出方向X调整移动芯材单元片30的位置即可使得任意相邻的两个芯材单元片30中的一者的几何形状高点102与另一者的几何形状低点103沿宽边输出方向Y对齐。Wherein, it should be noted that, when any adjacent two core material unit pieces 30 have the same shape and the flipping direction is opposite, it is not necessary to adjust the position of the moving core material unit piece 30 along the output direction X of the assembly line so that any adjacent The geometrically high point 102 of one of the two core material dies 30 is aligned with the geometrically low point 103 of the other along the broadside output direction Y.
在一些具体实施方式中,将多个芯材单元片30沿宽边输出方向Y层叠拼接成单元拼接体100可包括:In some specific implementation manners, stacking and splicing a plurality of core material unit sheets 30 along the broadside output direction Y to form a unit splicing body 100 may include:
在各个芯材单元片30的接触表面涂覆胶接层,并通过胶接层连接相邻的芯材单元片30;或者使任意相邻的芯材单元片30之间的结构层A或功能层B之间以熔融粘接方式相连。The contact surface of each core material unit piece 30 is coated with an adhesive layer, and the adjacent core material unit pieces 30 are connected by the adhesive layer; or the structural layer A or functional layer between any adjacent core material unit pieces 30 The layers B are connected by fusion bonding.
具体地,在将平整片材10加工成芯材单元片30后,可在各个芯材单元片30的拼接接触表面涂覆胶体从而形成胶接层,以将收拢层叠后的芯材单元片30粘结成单元拼接体100。或者,可将收拢层叠后的芯材单元片30通过热熔拼接、超声拼接或红外拼接的熔融粘结方式粘结成单元拼接体100。Specifically, after the flat sheet 10 is processed into the core material unit piece 30, colloid can be coated on the splicing contact surface of each core material unit piece 30 so as to form an adhesive layer, so that the stacked core material unit piece 30 can be folded together. Bonded to form a unit assembly 100 . Alternatively, the gathered and stacked core material unit sheets 30 may be bonded into the unit splicing body 100 by means of fusion bonding such as hot-melt splicing, ultrasonic splicing or infrared splicing.
进一步地,本发明的第一生产方法还包括:Further, the first production method of the present invention also includes:
使得在拼接成型的单元拼接体100中,当平整片材10的片材表面的垂直方向为承受压缩载荷方向时,单元拼接体100的材料体积利用率不低于60%,优选的,材料体积利用率不低于80%;So that in the unit splicing body 100 formed by splicing, when the vertical direction of the sheet surface of the flat sheet 10 is the direction to bear the compressive load, the material volume utilization rate of the unit splicing body 100 is not less than 60%, preferably, the material volume The utilization rate is not less than 80%;
和/或,在单元拼接体100的平行于平整片材10的片材表面的芯材横截面上,平面空隙率不低于40%,进一步的,平面空隙率不低于60%。And/or, on the cross-section of the core material of the unit assembly 100 parallel to the sheet surface of the flat sheet 10, the planar void ratio is not lower than 40%, further, the planar void ratio is not lower than 60%.
对于上述的生产方法,本发明还提供了一种热塑性复合芯材的生产设备,包括:For above-mentioned production method, the present invention also provides a kind of production equipment of thermoplastic composite core material, comprising:
热塑材料成型设备1,用于在模内热复合成型具有结构层A和功能层B的平整片材10并沿流水线输出方向X持续输出;Thermoplastic material forming equipment 1, used for thermocombining forming a flat sheet 10 having a structural layer A and a functional layer B in a mold and continuously outputting along the output direction X of the pipeline;
芯材单元片加工成型组件,用于将平整片材10分割加工成沿宽边输出方向Y等宽且沿流水线输出方向X呈带状的多个芯材单元片30,其中至少部分的芯材单元片30的片材表面上加工有沿流水线输出方向X)复呈现的非闭合的几何体104;The core material unit piece processing and forming assembly is used to divide and process the flat sheet 10 into a plurality of core material unit pieces 30 with the same width along the broadside output direction Y and a strip shape along the pipeline output direction X, wherein at least part of the core material The sheet surface of the unit sheet 30 is processed with a non-closed geometric body 104 re-presented along the pipeline output direction X);
单元拼接体拼接组件,用于将多个芯材单元片30沿宽边输出方向Y层叠拼接成单元拼接体100,单元拼接体100包括沿流水线输出方向X依次分布并通过几何体104拼接形成的多个轴孔结构。The unit splicing body splicing assembly is used to stack and splice a plurality of core material unit pieces 30 along the wide-side output direction Y to form a unit splicing body 100. A shaft hole structure.
其中,如图2、图3所示,热塑材料成型设备1包括上下布置的第一挤出模具1a和第二挤出模具1b以及位于第一挤出模具1a和第二挤出模具1b的成型挤出口的热复合成型段1c。上下布置的第一挤出模具1a和第二挤出模具1b分别挤出具有相容性的功能材料片材和结构材料片材,两种材料通过热复合成型段1c进行模内热复合成型,以直接成型为结构层A复合功能层B的双层片材热复合结构的平整片材10,从而可以直接在流水线上持续输出生产。Wherein, as shown in Fig. 2 and Fig. 3, the thermoplastic material molding equipment 1 includes a first extrusion die 1a and a second extrusion die 1b arranged up and down and a The thermocomposite molding section 1c of the molding extrusion port. The first extrusion die 1a and the second extrusion die 1b arranged up and down respectively extrude a compatible functional material sheet and a structural material sheet, and the two materials are subjected to in-mold thermal composite molding through the thermal composite molding section 1c to The flat sheet 10 of the double-layer sheet thermal composite structure that is directly formed into the structural layer A and the functional layer B can be directly output on the assembly line for continuous production.
此外,芯材单元片加工成型组件可包括切割组件4和几何体成型组件2,切割组件4用于沿流水线输出方向X切割平整片材10或表面已成型加工有几何体104的平整片材10,几何体成型组件2用于在平整片材10或片材单元带20的片材表面加工成型出垂直于片材表面呈隆起状的几何凸起部,几何体104形成有在片材表面呈非闭合状且沿宽边输出方向Y轴向贯通的几何体第一内孔105。如图3所示,几何体成型组件2采用压辊组件对平整片材10或片材单元带20进行加工成型,本发明不限于此,也可采用板式模具或者链式模具等加工组件。并且根据裁切和几何成型加工的先后顺序的不同,切割组件4和几何体成型组件2在流水线上位置可调换。In addition, the core material unit sheet processing and forming assembly may include a cutting assembly 4 and a geometric body forming assembly 2, the cutting assembly 4 is used to cut the flat sheet 10 or the flat sheet 10 with a geometric body 104 on the surface along the output direction X of the pipeline, the geometric body The molding assembly 2 is used to process and form a geometric bulge perpendicular to the surface of the sheet on the sheet surface of the flat sheet 10 or the sheet unit belt 20, and the geometric body 104 is formed with an open shape on the surface of the sheet and A geometric first inner hole 105 penetrating axially along the broadside output direction Y. As shown in FIG. 3 , the geometry forming component 2 uses a pressure roller component to process and shape the flat sheet 10 or the sheet unit belt 20 . And according to the difference in the sequence of cutting and geometric forming, the positions of the cutting assembly 4 and the geometric forming assembly 2 on the assembly line can be exchanged.
进一步地,单元拼接体拼接组件包括:Further, the unit splicing body splicing assembly includes:
导向定位组件5,用于将分割加工后的各个芯材单元片30分别翻转预设角度,使得翻转后的芯材单元片长度方向L保持沿流水线输出方向X,芯材单元片宽度方向W与平整片材10的宽边输出方向Y之间形成夹角a;The guide and positioning assembly 5 is used to turn each core material unit piece 30 after division and processing at a preset angle, so that the length direction L of the turned core material unit piece remains along the pipeline output direction X, and the width direction W of the core material unit piece is in line with An included angle a is formed between the broadside output directions Y of the flat sheet 10;
聚拢组件7,用于沿宽边输出方向Y收拢各个芯材单元片30;Gathering assembly 7, used for gathering each core material unit sheet 30 along the broadside output direction Y;
热熔连接组件8,用于加热各个芯材单元片30以熔融粘接成单元拼接体100。The hot-melt connection component 8 is used for heating each core material unit sheet 30 to melt and bond the unit assembly 100 .
其中,聚拢组件可单独设置,或者也可通过组件收窄的导轨侧壁等结构方式将各个芯材单元片30从两侧向中心收拢。热熔连接组件8可为加热箱、也可为超声焊或红外加热等设备,本发明不限于此。此时,热塑材料成型设备1、芯材单元片加工成型组件、导向定位组件5、聚拢组件7和热熔连接组件8沿流水线输出方向X依次布置。Wherein, the gathering component can be arranged separately, or each core material unit piece 30 can be gathered from both sides to the center through structural methods such as the narrowed guide rail side wall of the component. The hot-melt connection assembly 8 may be a heating box, or equipment such as ultrasonic welding or infrared heating, and the present invention is not limited thereto. At this time, the thermoplastic material forming equipment 1 , the core material unit piece processing and forming component, the guiding and positioning component 5 , the gathering component 7 and the hot-melt connection component 8 are arranged in sequence along the output direction X of the pipeline.
可选地,热塑性复合芯材的生产设备还可包括:Optionally, the production equipment for thermoplastic composite core materials may also include:
热塑材料成型设备1,用于在模内热复合成型具有结构层和功能层的平整片材10并沿流水线输出方向X持续输出;Thermoplastic material forming equipment 1, used for thermocombining forming a flat sheet 10 with a structural layer and a functional layer in a mold and continuously outputting along the output direction X of the pipeline;
芯材单元片加工成型组件,用于将平整片材10分割加工成沿宽边输出方向Y等宽且沿流水线输出方向X呈带状的多个芯材单元片30,其中至少部分的芯材单元片30的片材表面上加工有沿流水线输出方向X重复呈现的非闭合的几何体104;The core material unit piece processing and forming assembly is used to divide and process the flat sheet 10 into a plurality of core material unit pieces 30 with the same width along the broadside output direction Y and a strip shape along the pipeline output direction X, wherein at least part of the core material On the sheet surface of the unit sheet 30, an open geometry 104 repeatedly presented along the pipeline output direction X is processed;
胶枪,用于在各个芯材单元片30的接触表面涂覆胶接层;A glue gun, for coating the bonding layer on the contact surface of each core material unit piece 30;
导向定位组件5,用于将接触表面涂覆胶接层的各个芯材单元片30分别翻转预设角度,使得翻转后的芯材单元片长度方向L保持沿流水线输出方向X,芯材单元片宽度方向W与平整片材10的宽边输出方向Y之间形成夹角a;The guiding and positioning assembly 5 is used to turn each core material unit piece 30 coated with the adhesive layer on the contact surface at a preset angle, so that the length direction L of the turned core material unit piece remains along the output direction X of the pipeline, and the core material unit piece An angle a is formed between the width direction W and the broadside output direction Y of the flat sheet 10;
单元拼接体拼接组件,用于将多个芯材单元片30沿宽边输出方向Y层叠拼接成单元拼接体100,单元拼接体100包括沿流水线输出方向X依次分布并通过几何体104拼接形成的多个轴孔结构。The unit splicing body splicing assembly is used to stack and splice a plurality of core material unit pieces 30 along the wide-side output direction Y to form a unit splicing body 100. A shaft hole structure.
与图3所示的生产设备不同的是,该生产设备采用胶枪对芯材单元片30的相互接触位置进行涂胶胶粘以拼接粘接呈单元拼接体100。胶枪可为与几何体成型组件2的压辊组件形状结构相同的辊体胶枪(图中未显示),压辊组件和辊体胶枪的各自旋转轴线均沿宽边输出方向Y,辊体胶枪的辊体周壁形成有沿周向间隔的凹槽状的棱边涂胶部,压辊组件的辊体周壁形成有沿周向间隔的凸起状的棱边压接部,棱边压接部和棱边涂胶部沿周向相同布置且两者的个数相同。此外,热塑材料成型设备1、芯材单元片加工成型组件、胶枪和单元拼接体拼接组件沿流水线输出方向X依次布置。The difference from the production equipment shown in FIG. 3 is that this production equipment uses a glue gun to apply glue to the contact positions of the core material unit pieces 30 to splice and bond them to form a unit spliced body 100 . The glue gun can be a roller body glue gun (not shown) with the same shape and structure as the pressure roller assembly of the geometry forming assembly 2, and the respective rotation axes of the pressure roller assembly and the roller body glue gun are all along the broadside output direction Y, and the roller body The peripheral wall of the roller body of the glue gun is formed with groove-shaped edge gluing parts spaced along the circumferential direction, and the peripheral wall of the roller body of the pressure roller assembly is formed with convex-shaped edge crimping parts spaced along the circumferential direction. The connecting portion and the edge glued portion are arranged in the same circumferential direction and the number of the two is the same. In addition, the thermoplastic material molding equipment 1 , the core material unit piece processing and molding component, the glue gun and the unit splicing body splicing component are arranged in sequence along the output direction X of the pipeline.
以上为根据本发明的热塑性复合芯材的生产方法和生产设备,以下将参见图4~图12,详细述及根据本发明的热塑性复合芯材的结构。The above is the production method and production equipment of the thermoplastic composite core material according to the present invention. The structure of the thermoplastic composite core material according to the present invention will be described in detail below with reference to FIGS. 4 to 12 .
本发明的热塑性复合芯材为蜂窝形芯材,即为图6中所示单元拼接体100,该单元组合100由多个沿第一方向D1延伸且沿第二方向D2层叠拼接的芯材单元片30组成,至少部分的芯材单元片30的片材表面形成有沿芯材单元片长度方向L依次分布且呈非闭合状的几何体104。其中,如图4、图5所示,芯材单元片30为包括结构层A和功能层B的双层片材结构,结构层A为用于形成承受载荷的结构材料,而功能层B则为用于提供各种功能的功能材料。结构层A的结构材料和功能层B的功能材料之间具有相容性,即两者之间产生物理和化学的相容性。如浸润性、反应性和互溶性等。由此,结构层A与功能B在模具内可不通过粘结剂直接热复合成型。在外型上,在本发明的单元拼接体100中形成有至少沿第一方向D1依次分布的多个由几何体104拼接形成轴孔结构,轴孔结构包括轴向沿第三方向D3的拼接轴孔101和围绕拼接轴孔101的周向封闭的轴孔周壁。The thermoplastic composite core material of the present invention is a honeycomb core material, that is, a unit splicing body 100 shown in FIG. sheet 30, at least part of the sheet surface of the core unit sheet 30 is formed with geometric bodies 104 that are distributed sequentially along the length direction L of the core unit sheet and are non-closed. Wherein, as shown in Fig. 4 and Fig. 5, the core unit sheet 30 is a double-layer sheet structure comprising a structural layer A and a functional layer B, the structural layer A is used to form a structural material for bearing loads, and the functional layer B is It is a functional material used to provide various functions. There is compatibility between the structural material of the structural layer A and the functional material of the functional layer B, that is, there is physical and chemical compatibility between the two. Such as wettability, reactivity and miscibility. Thus, the structural layer A and the functional layer B can be thermally compounded directly in the mold without using an adhesive. In terms of appearance, in the unit splicing body 100 of the present invention, there are a plurality of axial hole structures spliced by geometric bodies 104 that are distributed sequentially at least along the first direction D1, and the axial hole structure includes spliced axial holes axially along the third direction D3 101 and the circumferentially closed shaft hole peripheral wall surrounding the spliced shaft hole 101.
进一步地,功能层B可例如为阻燃层、抗紫外层、颜色层、阻热或传热层、透磁或阻磁层、防腐层、或隔音层中的一种或者多种功能组合层等功能材料层,本发明不限于此,还可为其他隔热层等功能材料层等。Further, the functional layer B can be, for example, one or more functional combination layers in a flame-retardant layer, an anti-ultraviolet layer, a color layer, a heat-resistant or heat-transfer layer, a magnetic-permeable or magnetic-resistant layer, an anti-corrosion layer, or a sound-insulating layer and other functional material layers, the present invention is not limited thereto, and may also be other functional material layers such as heat insulating layers.
其中,可选地,功能层B的材质包括阻燃填料填充聚合物、抗紫外填料填充聚合物、颜料填料填充聚合物、阻热或传热填料填充聚合物、透磁或阻磁填料填充聚合物、防腐填料填充聚合物、隔音填料填充聚合物中的一种或者多种组合物。Wherein, optionally, the material of the functional layer B includes a flame-retardant filler-filled polymer, an anti-ultraviolet filler-filled polymer, a pigment filler-filled polymer, a heat-resistant or heat-transfer filler-filled polymer, a magnetically permeable or magnetic-resistant filler-filled polymer One or more combinations of anti-corrosion filler-filled polymers and sound-insulating filler-filled polymers.
此外,为了保证结构层A具有足够的力学强度,结构层A的片层厚度不小于0.1mm。In addition, in order to ensure that the structural layer A has sufficient mechanical strength, the sheet thickness of the structural layer A is not less than 0.1 mm.
此外,可将任意形状的拼接轴孔101的外接圆的直径优选设置为不小于1mm;和/或,可将任意形状的拼接轴孔101的孔轴长与该拼接轴孔101的外接圆的直径之比优选设置为不大于200,以使得芯材获得更佳的重载轻质效果。In addition, the diameter of the circumscribed circle of the spliced shaft hole 101 of any shape can be preferably set to not less than 1mm; The ratio of the diameters is preferably set to be no greater than 200, so that the core material can achieve a better effect of heavy load and light weight.
相对于传统钢和铝等金属成型材料,热塑性材料具有质量轻、绝缘性好、耐腐蚀、易粘结和焊接等优点。此外,塑料板材可回收利用,便于二次加工,节约资源。其中,结构层A的材质可包括热塑性聚合物、填料填充的热塑性聚合物、纤维增强的热塑性树脂基复合材料、塑性形变纸张和/或钢塑复合物。具体地,热塑性聚合物可为聚丙烯、聚乙烯、聚酰胺、热塑性聚酯、聚氯乙烯、聚苯乙烯、聚碳酸酯、聚苯醚、热塑性弹性体、多元共聚热塑性塑料、聚甲基丙烯酸甲酯、聚苯硫醚、聚醚醚酮和聚酰亚胺中的一种或其中多种的共混物。Compared with traditional metal forming materials such as steel and aluminum, thermoplastic materials have the advantages of light weight, good insulation, corrosion resistance, and easy bonding and welding. In addition, the plastic sheet can be recycled, which is convenient for secondary processing and saves resources. Wherein, the material of the structural layer A may include thermoplastic polymers, filled thermoplastic polymers, fiber-reinforced thermoplastic resin-based composite materials, plastically deformable paper and/or steel-plastic composites. Specifically, the thermoplastic polymer can be polypropylene, polyethylene, polyamide, thermoplastic polyester, polyvinyl chloride, polystyrene, polycarbonate, polyphenylene ether, thermoplastic elastomer, multi-component copolymerized thermoplastic, polymethacrylic acid One of methyl ester, polyphenylene sulfide, polyether ether ketone and polyimide or a blend of more than one of them.
此外,填料填充的热塑性聚合物中的填料可为蜡、滑石粉、炭黑、白炭黑、高岭土、碳酸钙、硬脂酸、硬脂酸钙、晶须、二氧化钛、氧化铁、颜料、阻燃剂和抗氧剂中的一种或其中多种的组合物。而纤维增强的热塑性树脂基复合材料中的纤维可为有机纤维、无机纤维、金属纤维、高分子纤维、植物纤维中的一种或多种。具体地,纤维增强的热塑性树脂基复合材料中的纤维可为玻璃纤维、碳纤维、玄武岩纤维、钢丝纤维、聚丙烯纤维、聚酯纤维、超高分子量聚乙烯纤维、聚酰亚胺纤维和麻纤维中的一种或者其中多种的组合物。In addition, fillers in filler-filled thermoplastic polymers can be waxes, talc, carbon black, silica, kaolin, calcium carbonate, stearic acid, calcium stearate, whiskers, titanium dioxide, iron oxides, pigments, barrier One or more combinations of fuel and antioxidant. The fibers in the fiber-reinforced thermoplastic resin-based composite material can be one or more of organic fibers, inorganic fibers, metal fibers, polymer fibers, and plant fibers. Specifically, the fibers in fiber-reinforced thermoplastic resin matrix composites can be glass fibers, carbon fibers, basalt fibers, steel fibers, polypropylene fibers, polyester fibers, ultra-high molecular weight polyethylene fibers, polyimide fibers and hemp fibers One or a combination of several of them.
在本发明的热塑性复合芯材中,根据芯材单元片30组合拼接的方式不同,可分为两种组合拼接方式。如图10、图11所示的第一种组合拼接方式,任意相邻的两个芯材单元片30的翻转方向相反并依次层叠拼接,此时芯材单元片30之间的拼接位置的组合方式为A-A-B-B接触,即相邻两个芯材单元片的拼接位置的两侧均为功能层B或均为结构层A。换言之,当单元拼接体100至少包括沿第二方向D2依次层叠拼接的第一芯材单元片、第二芯材单元片和第三芯材单元片时,第二芯材单元片的结构层A与一侧的第一芯材单元片的结构层A抵接相连,第二芯材单元片的功能层B与另一侧的第三芯材单元片的功能层B抵接相连。In the thermoplastic composite core material of the present invention, according to the different ways of combining and splicing the core material unit pieces 30, it can be divided into two ways of combining and splicing. In the first combined splicing method shown in Figures 10 and 11, the turning directions of any adjacent two core material unit pieces 30 are opposite and sequentially stacked and spliced. At this time, the combination of the splicing positions between the core material unit pieces 30 The method is A-A-B-B contact, that is, both sides of the splicing position of two adjacent core material unit sheets are both functional layer B or structural layer A. In other words, when the unit assembly 100 at least includes the first core material unit, the second core material unit and the third core material unit that are sequentially stacked and spliced along the second direction D2, the structural layer A of the second core material unit The structural layer A of the first core material unit piece on one side is abutted and connected, and the functional layer B of the second core material unit piece is abutted and connected with the functional layer B of the third core material unit piece on the other side.
如图8、图9所示的第二种组合拼接方式,任意相邻的两个片材单元带20的翻转方向相同并依次层叠拼接,此时芯材单元片30之间的拼接位置的组合方式为A-B-A-B接触,即相邻两个芯材单元片30的拼接位置的其中一侧为功能层B,另一侧为结构层A。换言之,当单元拼接体100至少包括沿第二方向D2依次层叠拼接的第一芯材单元片、第二芯材单元片和第三芯材单元片,第二芯材单元片的结构层A与一侧的第一芯材单元片的功能层B抵接相连,第二芯材单元片的功能层B与另一侧的第三芯材单元片的结构层A抵接相连。In the second combined splicing method shown in Figures 8 and 9, any adjacent two sheet unit belts 20 have the same overturn direction and are stacked and spliced sequentially. The method is A-B-A-B contact, that is, one side of the splicing positions of two adjacent core material unit pieces 30 is the functional layer B, and the other side is the structural layer A. In other words, when the unit assembly 100 at least includes the first core material unit sheet, the second core material unit sheet and the third core material unit sheet sequentially stacked and spliced along the second direction D2, the structural layer A of the second core material unit sheet and The functional layer B of the first core material unit piece on one side is abutted and connected, and the functional layer B of the second core material unit piece is abutted and connected with the structural layer A of the third core material unit piece on the other side.
在本发明的热塑性复合芯材中,参见图12,芯材单元片30可分为几何芯材单元片32和平整芯材单元片31,几何芯材单元片32表面加工有几何体104,平整芯材单元片31表面未加工有几何体104。其中,如图6、图7所示的单元拼接体100沿第二方向D2层叠拼接的芯材单元片30均相同,每个芯材单元片30的片材表面上形成的几何体104均相同且沿第一方向D1等间隔分布。但本发明不限于此,如图12所示,单元拼接体100沿第二方向D2层叠拼接的几何芯材单元片32可不相同。或者,几何芯材单元片32的片材表面上形成的几何体104可不相同。或者,几何芯材单元片32的片材表面上形成的几何体104沿第一方向非等间隔分布等。In the thermoplastic composite core material of the present invention, referring to Fig. 12, the core material unit piece 30 can be divided into a geometric core material unit piece 32 and a flat core material unit piece 31, the surface of the geometric core material unit piece 32 is processed with a geometric body 104, and the flat core material unit piece No geometry 104 is processed on the surface of the material unit sheet 31 . Wherein, the core material units 30 stacked and spliced along the second direction D2 in the unit splicing body 100 shown in FIGS. distributed at equal intervals along the first direction D1. But the present invention is not limited thereto. As shown in FIG. 12 , the geometrical core material unit pieces 32 of the unit splicing body 100 stacked and spliced along the second direction D2 may be different. Alternatively, the geometries 104 formed on the sheet surfaces of the geometric core element sheets 32 may be different. Alternatively, the geometric bodies 104 formed on the sheet surface of the geometric core unit sheet 32 are not equally spaced along the first direction, or the like.
其中,几何体104形成为从几何芯材单元片32的片材表面沿第二方向D2隆起的几何凸起部,几何凸起部内形成有轴向沿第三方向D3的几何体第一内孔105,该几何体第一内孔105沿第二方向D2呈单侧开口状,几何体第一内孔105的单侧开口端由邻接的芯材单元片30封闭以构成至少部分的拼接轴孔101,其几何内孔中心线OO'沿第三方向D3。此外,相邻的几何体104之间还可形成非封闭的几何体第二内孔106,几何体第一内孔105与几何体第二内孔106的非封闭开口朝向相反。几何体104可为压制成型结构,几何体第一内孔105可为压制成型孔且可为正六边形孔、菱形孔、腰形孔或不规则的异型孔的半分孔等各种形状。Wherein, the geometric body 104 is formed as a geometric raised portion raised from the sheet surface of the geometric core unit sheet 32 along the second direction D2, and a first inner hole 105 of the geometric body axially along the third direction D3 is formed in the geometric raised portion, The first inner hole 105 of the geometric body is open on one side along the second direction D2, and the one-sided opening end of the first inner hole 105 of the geometric body is closed by the adjacent core material unit piece 30 to form at least part of the spliced shaft hole 101. The bore centerline OO' is along the third direction D3. In addition, a non-closed second inner hole 106 may be formed between adjacent geometric bodies 104 , and the non-closed openings of the first inner hole 105 and the second inner hole 106 of the geometric body face opposite to each other. The geometric body 104 can be a press-formed structure, and the first inner hole 105 of the geometric body can be a press-formed hole and can be in various shapes such as regular hexagonal holes, diamond-shaped holes, waist-shaped holes, or irregular shaped holes.
其中,单元拼接体100沿第二方向D2层叠拼接的任意相邻的两个芯材单元片30中至少包括一个几何芯材单元片32。任意相邻的两个芯材单元片30拼接形成的轴孔结构中,每个拼接轴孔101至少包括一个几何体第一内孔105或一个几何体第二内孔106,用于沿周向封闭至少一个几何体第一内孔105或一个几何体第二内孔106的内孔周向闭合结构可为平整壁或包括至少部分的几何体104。如图12所示,拼接轴孔101可包括一个几何体第一内孔105或一个几何体第二内孔106,也可包括多个几何体第一内孔105或多个几何体第二内孔106。内孔周向闭合结构可为平整芯材单元片31的平整片材壁也可为几何芯材单元片32的至少部分的几何体104。Wherein, at least one geometric core material unit piece 32 is included in any two adjacent core material unit pieces 30 of the unit assembly 100 stacked and spliced along the second direction D2. In the axial hole structure formed by splicing any two adjacent core material unit pieces 30, each spliced axial hole 101 includes at least one geometric first inner hole 105 or one geometric second inner hole 106, which is used to seal at least The inner bore circumferential closure of a first geometric body bore 105 or a second geometric body bore 106 may be a flat wall or comprise at least part of the geometric body 104 . As shown in FIG. 12 , the splicing shaft hole 101 may include one geometrically first inner hole 105 or one geometrically second inner hole 106 , or may include multiple geometrically first inner holes 105 or multiple geometrically second inner holes 106 . The inner hole circumferential closure structure may be a flat sheet wall of the flat core cell 31 or at least part of the geometric body 104 of the geometric core cell 32 .
在一些具体实施例中,在每个几何芯材单元片32中,相同的各个几何体104沿第一方向D1等步距分布,由各个几何形状高点102构成的几何形状高点面和由各个几何形状低点103构成的几何形状低点面形成为沿第一方向D1的平行平面。In some specific embodiments, in each geometric core material unit piece 32, the same respective geometric bodies 104 are distributed with equidistant steps along the first direction D1, and the geometric shape high point surface formed by each geometric shape high point 102 and the geometric shape high point surface composed of each geometric shape high point 102 The geometric low points formed by the geometric low points 103 are formed as parallel planes along the first direction D1.
可选地,如图6、图7所示,单元拼接体100为长方体形状,第一方向D1与第二方向D2垂直且分别为单元拼接体100的两个边长方向,第二方向D2垂直于芯材单元片30的片材表面,第三方向D3为单元拼接体100的厚度方向。此时,拼接轴孔101沿单元拼接体100的厚度方向贯通,即几何内孔中心线OO'沿单元拼接体100的厚度方向。当然,,本发明不限于此,各方向定位可以互换。此外,第一方向D1、第二方向D2与第三方向D3中彼此两两之间也不限于形成直角夹角,也可例如为锐角等。Optionally, as shown in Fig. 6 and Fig. 7, the unit splicing body 100 is in the shape of a cuboid, the first direction D1 and the second direction D2 are perpendicular to the two side length directions of the unit splicing body 100, and the second direction D2 is vertical On the sheet surface of the core unit sheet 30 , the third direction D3 is the thickness direction of the unit assembly 100 . At this time, the splicing shaft hole 101 penetrates along the thickness direction of the unit splicing body 100 , that is, the centerline OO′ of the geometric inner hole is along the thickness direction of the unit splicing body 100 . Of course, the present invention is not limited thereto, and the orientations of various directions can be interchanged. In addition, the angles between the first direction D1 , the second direction D2 and the third direction D3 are not limited to forming right angles, and may also be, for example, acute angles.
具体地,单元拼接体100可至少包括沿第二方向D2依次层叠拼接的第一芯材单元片、第二芯材单元片和第三芯材单元片,第二芯材单元片通过几何形状高点102与一侧的第一芯材单元片的几何形状低点103抵接相连,且通过几何形状低点103与另一侧的第三芯材单元片的几何形状高点102抵接相连,从而拼接成整个单元拼接体100。在相邻的芯材单元片中,抵接相连的几何形状高点102与几何形状低点103之间形成为热复合连接的弧面接触、尖端接触或平面接触。其中,如图8、图10所示,抵接相连的几何形状高点102与几何形状低点103之间形成为热复合连接的弧面接触;如图12所示,抵接相连的几何形状高点102与几何形状低点103之间形成为热复合连接的尖端接触或平面接触。Specifically, the unit assembly 100 may at least include a first core material unit piece, a second core material unit piece and a third core material unit piece sequentially stacked and spliced along the second direction D2, and the second core material unit piece adopts a geometric shape height The point 102 abuts and connects with the geometrically low point 103 of the first core material cell on one side, and abuts and connects with the geometrically high point 102 of the third core material cell on the other side through the geometrically low point 103, Thereby splicing into the whole unit splicing body 100 . In the adjacent core material unit pieces, the geometrically high point 102 and the geometrically low point 103 that are abutting to each other form arc surface contact, point contact or planar contact of thermal composite connection. Among them, as shown in Fig. 8 and Fig. 10, the arc surface contact of thermal compound connection is formed between the geometric shape high point 102 and the geometric shape low point 103 connected by abutting connection; as shown in Fig. 12, the geometric shape of abutting connection The high point 102 and the geometrically low point 103 form a point contact or planar contact for a thermal compound connection.
需要说明的是,从图12可见,不同形状结构的几何芯材单元片32进行组合拼接时,并非各个几何形状高点102和几何形状低点103均能对应相接,部分的几何形状高点102或几何形状低点103可呈悬空状。当各个芯材单元片30的形状结构都相同时,只需在沿第一方向D1的两端对齐的多个芯材单元片30的基础上,使得任意相邻的两个芯材单元片30围绕平行于第一方向D1的旋转轴线翻转相反的方向,由此,一个芯材单元片30上的几何体104与反向翻转后的另一芯材单元片30上的几何体104沿第二方向D2对齐并一体连接。其中,反向翻转后的芯材单元片30中,几何形状低点103和几何形状高点102的位置发生互换。当然,也可使得任意相邻的两个芯材单元片30围绕平行于第一方向D1的旋转轴线翻转且翻转方向相同,并沿第一方向D1移动调节以错开一定距离,由此,第一芯材单元片上的第一几何体与相邻的第二芯材单元片上的第二几何体沿第一方向D1依次交替布置并一体连接。基于上述两种排列翻转规则,可对应地形成整个单元拼接体100。It should be noted that, as can be seen from FIG. 12 , when the geometric core material unit pieces 32 of different shapes and structures are combined and spliced, not all geometric high points 102 and geometric low points 103 can be connected correspondingly, and some geometric high points 102 or geometric low point 103 can be suspended. When the shapes and structures of each core material unit piece 30 are the same, it is only necessary to make any two adjacent core material unit pieces 30 Flipping in opposite directions about an axis of rotation parallel to the first direction D1, whereby the geometry 104 on one core element 30 is reversely flipped with the geometry 104 on the other core element 30 in the second direction D2 Align and connect in one piece. Wherein, in the inverted core material unit piece 30 , the positions of the geometrically low point 103 and the geometrically high point 102 are exchanged. Of course, it is also possible to make any two adjacent core material unit pieces 30 turn over around the rotation axis parallel to the first direction D1 in the same turning direction, and move and adjust along the first direction D1 to stagger a certain distance, thus, the first The first geometric bodies on the core material unit piece and the second geometric bodies on the adjacent second core material unit piece are alternately arranged in sequence along the first direction D1 and integrally connected. Based on the above two arrangement and inversion rules, the entire unit mosaic 100 can be formed correspondingly.
为获得符合要求的能够实现轻质重载的热塑性复合芯材,在图6所示的成型后的单元拼接体100中,可通过设置较多的作为减质孔的拼接轴孔101以实现轻量化。参照图6,在单元拼接体100的由第一方向D1与第二方向D2定义且与单元拼接体100实体相交的任一平面,即单元拼接体100的任一横截面平面中,平面空隙率应不低于40%,进一步的,平面空隙率应不低于60%。在单元拼接体100的上述横截面平面中,平面空隙率即各个拼接轴孔101的孔截面面积总和与横截面平面的总平面面积之比。In order to obtain a thermoplastic composite core material that meets the requirements and can realize light weight and heavy load, in the formed unit splicing body 100 shown in FIG. Quantify. Referring to Fig. 6, in any plane defined by the first direction D1 and the second direction D2 of the unit splicing body 100 and intersecting with the unit splicing body 100 entity, that is, in any cross-sectional plane of the unit splicing body 100, the plane void ratio It should not be lower than 40%, and further, the planar void ratio should not be lower than 60%. In the above-mentioned cross-sectional plane of the unit splicing body 100 , the plane porosity is the ratio of the sum of the hole cross-sectional areas of each spliced shaft hole 101 to the total plane area of the cross-sectional plane.
在轻量化的同时,为实现重载,除了材料选择,还应提高材料体积利用率,即沿载荷受力方向,能够承受载荷的有效部分与整体部分的质量比或体积比。通俗而言,沿载荷受力方向真实受力部分为承受载荷的有效部分,而垂直于载荷受力方向的材料部分或空洞部分则为承受载荷的无效部分,无效部分的材料体积利用率为0。作为示例,在图6中,当第三方向D3为承受压缩载荷方向时,单元拼接体100的材料体积利用率不低于60%,优选的,材料体积利用率不低于80%。其中,关于材料体积利用率的定义,当材料承受压缩载荷时,沿着载荷方向具备实体材料且实体材料累计高度大于等于95%该方向材料的最高高度部分的材料体积与材料总体积之比即为材料体积利用率。While reducing weight, in order to achieve heavy loads, in addition to material selection, the volume utilization of materials should also be improved, that is, the mass ratio or volume ratio of the effective part that can bear the load to the overall part along the direction of the load force. Generally speaking, the real force-bearing part along the load-bearing direction is the effective part bearing the load, while the material part or hollow part perpendicular to the load-bearing direction is the invalid part bearing the load, and the material volume utilization rate of the invalid part is 0 . As an example, in FIG. 6 , when the third direction D3 is the direction of bearing the compressive load, the material volume utilization rate of the unit assembly 100 is not lower than 60%, preferably, the material volume utilization rate is not lower than 80%. Among them, regarding the definition of material volume utilization rate, when the material is subjected to compressive load, the ratio of the material volume of the highest height part of the material along the load direction to the total material volume is is the material volume utilization.
综上可见,本发明提供了一种热塑性复合芯材及其生产方法和生产设备,本发明的热塑性复合芯材可适应性地将不同的功能材料与结构材料热复合成型为蜂窝形芯材,由此不仅保持了原有结构材料的轻质重载的优点,还能通过与功能性材料结合获得单一组成材料所不能达到的综合性能,如阻燃性能、屏蔽性能、吸音性能等。此外,本发明的热塑性复合芯材的蜂窝壁为结构层复合功能层的双层片材热复合结构,功能层连续分布、功能效果显著,且采用的功能层和结构层相容性好,结合强度高,可应用在对轻质高强要求较高的各个领域中,同时还可针对各个不同领域的特殊要求来增加阻燃功能、防腐功能、隔音功能等,满足了实际应用中的多样化的需求。In summary, the present invention provides a thermoplastic composite core material and its production method and production equipment. The thermoplastic composite core material of the present invention can adaptively thermally composite different functional materials and structural materials into a honeycomb core material. This not only maintains the advantages of light weight and heavy load of the original structural materials, but also obtains comprehensive properties that cannot be achieved by a single component material by combining with functional materials, such as flame retardancy, shielding performance, and sound absorption performance. In addition, the honeycomb wall of the thermoplastic composite core material of the present invention is a double-layer sheet thermal composite structure in which the structural layer is combined with the functional layer. The functional layer is continuously distributed and has remarkable functional effects. High strength, can be used in various fields that require high light weight and high strength. At the same time, it can also add flame retardant function, anti-corrosion function, sound insulation function, etc. according to the special requirements of various fields, to meet the diversification of practical applications. need.
与此同时,本发明的生产方法和生产设备解决了传统蜂窝芯材的制造成本高、不可添加功能填料及增强填料、物料浪费的问题,实现了蜂窝芯低成本、可填充等优点以及节约型的生产制造,有效拓展了热塑性复合材料的应用领域。At the same time, the production method and production equipment of the present invention solve the problems of high manufacturing cost of traditional honeycomb core materials, the inability to add functional fillers and reinforcing fillers, and waste of materials, and realize the advantages of low cost and filling of the honeycomb core and energy-saving The production and manufacturing of thermoplastic composite materials have effectively expanded the application field of thermoplastic composite materials.
综上所述,本发明的带有填充材料的较大壁厚的双层结构热塑性复合芯材可应用于对轻质高强要求较高的各个领域中,例如载重越来越大的各种运载车辆中,尤其是重载电力运煤火车,或续航能力不足而需减轻车体的电动物流车等。由此,本发明还提供了一种设备,该设备采用根据本发明上述的热塑性复合芯材。具体地,该设备可为铁路车辆、公路车辆、建筑以及风电、矿用及航空航天领域等等领域中的相关设备或装置。To sum up, the double-layer thermoplastic composite core material with filler material and thicker wall thickness of the present invention can be applied in various fields that require high light weight and high strength, such as various types of vehicles with increasingly heavy loads. Vehicles, especially heavy-duty electric coal trains, or electric logistics vehicles that need to reduce the body due to insufficient battery life. Thus, the present invention also provides a device using the above-mentioned thermoplastic composite core material according to the present invention. Specifically, the equipment may be related equipment or devices in the fields of railway vehicles, road vehicles, construction, wind power, mining, aerospace and the like.
以上结合附图详细描述了本发明实施例的可选实施方式,但是,本发明实施例并不限于上述实施方式中的具体细节,在本发明实施例的技术构思范围内,可以对本发明实施例的技术方案进行多种简单变型,这些简单变型均属于本发明实施例的保护范围。The optional implementations of the embodiments of the present invention have been described in detail above in conjunction with the accompanying drawings. However, the embodiments of the present invention are not limited to the specific details in the above-mentioned embodiments. Within the scope of the technical concept of the embodiments of the present invention, the embodiments of the present invention can be Various simple modifications are made to the technical solution, and these simple modifications all belong to the protection scope of the embodiments of the present invention.
另外需要说明的是,在上述具体实施方式中所描述的各个具体技术特征,在不矛盾的情况下,可以通过任何合适的方式进行组合,为了避免不必要的重复,本发明实施例对各种可能的组合方式不再另行说明。In addition, it should be noted that the various specific technical features described in the above specific implementation manners can be combined in any suitable way if there is no contradiction. In order to avoid unnecessary repetition, the embodiments of the present Possible combinations are not described separately.
此外,本发明实施例的各种不同的实施方式之间也可以进行任意组合,只要其不违背本发明实施例的思想,其同样应当视为本发明实施例所公开的内容。In addition, various implementations of the embodiments of the present invention can also be combined arbitrarily, as long as they do not violate the idea of the embodiments of the present invention, they should also be regarded as the content disclosed in the embodiments of the present invention.
Claims (19)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910390534.2A CN110171145A (en) | 2019-05-10 | 2019-05-10 | The production method and production equipment of thermoplastic composite core material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910390534.2A CN110171145A (en) | 2019-05-10 | 2019-05-10 | The production method and production equipment of thermoplastic composite core material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110171145A true CN110171145A (en) | 2019-08-27 |
Family
ID=67690865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910390534.2A Pending CN110171145A (en) | 2019-05-10 | 2019-05-10 | The production method and production equipment of thermoplastic composite core material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110171145A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1204803B (en) * | 1961-01-02 | 1965-11-11 | Ernst Peter Matthiass Dr | Method and device for the production of corrugated sheets as intermediate layers for blockboards or the like. |
| US3912573A (en) * | 1971-07-28 | 1975-10-14 | Bernard P Kunz | Apparatus for producing core material for honeycomb panels |
| US5789060A (en) * | 1996-07-29 | 1998-08-04 | Specialty Cellular Products Company | Heat conduction honeycomb core |
| CN1393336A (en) * | 2001-06-20 | 2003-01-29 | 张弘根 | Thermoplastic resin lamination structural member and preparing process and use thereof |
| CN101084108A (en) * | 2004-11-19 | 2007-12-05 | 鲁汶天主教大学研究开发部 | Semi-closed thermoplastic honeycomb body and its production method and production equipment |
| CN102990934A (en) * | 2012-11-27 | 2013-03-27 | 常州悦诚新材料有限公司 | Method for producing continuous glass fiber fabric reinforced thermoplastic plastic honeycomb plate |
| CN105835484A (en) * | 2015-01-15 | 2016-08-10 | 广州金发碳纤维新材料发展有限公司 | Hexagonal honeycomb, preparation method and application thereof |
-
2019
- 2019-05-10 CN CN201910390534.2A patent/CN110171145A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1204803B (en) * | 1961-01-02 | 1965-11-11 | Ernst Peter Matthiass Dr | Method and device for the production of corrugated sheets as intermediate layers for blockboards or the like. |
| US3912573A (en) * | 1971-07-28 | 1975-10-14 | Bernard P Kunz | Apparatus for producing core material for honeycomb panels |
| US5789060A (en) * | 1996-07-29 | 1998-08-04 | Specialty Cellular Products Company | Heat conduction honeycomb core |
| CN1393336A (en) * | 2001-06-20 | 2003-01-29 | 张弘根 | Thermoplastic resin lamination structural member and preparing process and use thereof |
| CN101084108A (en) * | 2004-11-19 | 2007-12-05 | 鲁汶天主教大学研究开发部 | Semi-closed thermoplastic honeycomb body and its production method and production equipment |
| CN102990934A (en) * | 2012-11-27 | 2013-03-27 | 常州悦诚新材料有限公司 | Method for producing continuous glass fiber fabric reinforced thermoplastic plastic honeycomb plate |
| CN105835484A (en) * | 2015-01-15 | 2016-08-10 | 广州金发碳纤维新材料发展有限公司 | Hexagonal honeycomb, preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 沢田慶司: "《塑料异型和复合挤出技术及制品开发》", 31 October 1987, 化学工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6004652A (en) | Structural dimple panel | |
| CN111098559A (en) | A kind of honeycomb core sandwich composite board and its preparation method and equipment | |
| EP2477809A1 (en) | Honeycomb structure element | |
| CN111503386B (en) | Production method of HDPE rectangular high-strength winding pipe | |
| CN111497357A (en) | Honeycomb core sandwich composite board and preparation method and equipment thereof | |
| CA2663107A1 (en) | Composite board with open honeycomb structure | |
| CN110315805A (en) | Thermoplastic core and device comprising the same | |
| CN110181844A (en) | The production method and production equipment of thermoplastic composite core material | |
| CN110228210A (en) | The production method and production equipment of thermoplasticity core material | |
| CN110171145A (en) | The production method and production equipment of thermoplastic composite core material | |
| CN110154490A (en) | Thermoplasticity core material with multi-layer compound structure and the equipment including the core material | |
| CN110242849B (en) | Thermoplastic composite core and device comprising same | |
| CN110154493A (en) | The production method and production equipment of thermoplasticity core material with multi-layer compound structure | |
| CN110154433A (en) | The production method and production equipment of thermoplastic composite core material | |
| CN212636772U (en) | Multilayer corrugated composite material sandwich structure | |
| CN110228220A (en) | The production method and production equipment of thermoplastic composition core material | |
| CN110154497A (en) | The production method and production equipment of thermoplasticity core material with multi-layer compound structure | |
| CN110185915B (en) | Method and apparatus for producing thermoplastic composite core material | |
| CN110216972A (en) | The production method and production equipment of thermoplasticity core material with multi-layer compound structure | |
| CN110216969A (en) | The production method and production equipment of thermoplasticity core material with multi-layer compound structure | |
| CN110242848B (en) | Thermoplastic composite core material | |
| CN205767781U (en) | A kind of cellular board | |
| CN110216908A (en) | The production method and production equipment of thermoplasticity core material | |
| CN211493031U (en) | Thermoplastic composite sheet | |
| CN110181843A (en) | The production method and production equipment of thermoplastic composition core material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190827 |
|
| RJ01 | Rejection of invention patent application after publication |