CN119978818A - A water-dispersible polyether-modified silicone elastomer gel and its preparation method and application - Google Patents

Abstract

The present invention provides a water-dispersible polyether-modified silicone elastomer gel and a preparation method and application thereof. The water-dispersible polyether-modified silicone elastomer gel is obtained by a reaction raw material mixture containing the following components: (A) polysilsesquioxane containing unsaturated groups, (B) organohydrogensiloxane, and (C) polyether containing unsaturated groups are catalyzed by (E) a silylation reaction catalyst in (D) a carrier fluid. The water-dispersible polyether-modified silicone elastomer gel has a hydrophilic polyether group and a lipophilic silicone elastic structure, and can be dispersed in an aqueous phase to form a stable aqueous emulsion gel with elastomer properties. At the same time, the water-dispersible polyether-modified silicone elastomer gel has a polysilsesquioxane resin structure, which can provide a special skin feel and film-forming effect in combination with a network siloxane chain; it can be widely used in cosmetics or personal care products.

Description

Water-dispersible polyether modified organic silicon elastomer gel and preparation method and application thereof

Technical Field

The invention belongs to the technical field of organic silicon, and particularly relates to a water-dispersible polyether modified organic silicon elastomer gel and a preparation method and application thereof.

Background

The organic silicon elastomer gel is a gel polymer formed by mixing an organic silicon elastomer and a fluid carrier, has unique velvet feel and powder feel, and is extremely widely applied in the cosmetic industry. However, unmodified silicone elastomers have poor film formation and poor compatibility with other ingredients, often requiring the addition of emulsifiers to the formulation. To improve the film forming properties and compatibility with other cosmetic ingredients, the silicone elastomer needs to be modified, such as by incorporating long chain alkyl groups, polyether groups, amino groups or other organic functional groups. The organosilicon elastomer connected with polyether group has certain hydrophilicity, and the self-emulsifying effect makes the emulsification in water-based or water-containing cosmetics simple and convenient, and stable water-dispersible elastomer gel can be easily formed. In addition, the polyether modified elastomer gel can play a good role in formula thickening and has great application value.

CN110028793a discloses a silicone elastomer, a preparation method thereof and a silicone elastomer gel containing the same, wherein the silicone elastomer is prepared from the raw materials of organohydrogen polysiloxane containing at least 3 Si-H units in a component molecule, unsaturated aliphatic hydrocarbon with average unsaturated group number of more than 1 in a component molecule, polysiloxane containing at least two unsaturated aliphatic hydrocarbon groups in a component molecule, unsaturated polyether in a component d and hydrosilylation catalyst in a component e. The silicone elastomer gel includes a carrier fluid and particles of the silicone elastomer dispersed therein. Although the silicone elastomer disclosed in the above patent has both good compatibility with oils and fats and can absorb moisture for self-emulsification in aqueous care products or cosmetics, the silicone elastomer gel does not provide good film-forming effect and is poor in skin-sticking property.

Disclosure of Invention

Aiming at the defects of the prior art, the invention aims to provide a water-dispersible polyether modified organosilicon elastomer gel and a preparation method and application thereof.

To achieve the purpose, the invention adopts the following technical scheme:

in a first aspect, the present invention provides a water-dispersible polyether-modified silicone elastomer gel comprising a reaction raw material mixture comprising:

(A) An unsaturated group-containing polysilsesquioxane containing at least two unsaturated hydrocarbon groups;

(B) An organohydrogensiloxane containing at least two silicon hydrogen bonds;

(C) An unsaturated group-containing polyether containing at least one unsaturated hydrocarbon group;

And (3) catalyzing and reacting in (D) carrier fluid through (E) hydrosilylation catalyst.

Preferably, the molar ratio of the unsaturated group in the component (A) to the silicon-hydrogen bond in the component (B) is (0.1-1.5): 1, and for example, may be 0.2:1, 0.3:1, 0.4:1, 0.5:1, 0.6:1, 0.7:1, 0.8:1, 0.9:1, 1:1, 1.1:1, 1.2:1, 1.31:1, 1.4:1, etc.

Preferably, the feeding molar ratio of the unsaturated group in the component (A) to the silicon-hydrogen bond in the component (B) is (0.4-1): 1.

Preferably, the molar ratio of the unsaturated group in the component (C) to the silicon-hydrogen bond in the component (B) is (0.1-1.5): 1, and for example, may be 0.2:1, 0.3:1, 0.4:1, 0.5:1, 0.6:1, 0.7:1, 0.8:1, 0.9:1, 1:1, 1.1:1, 1.2:1, 1.3:1, 1.4:1, etc.

Preferably, the feeding molar ratio of the unsaturated group in the component (C) to the silicon-hydrogen bond in the component (B) is (0.3-1): 1.

Preferably, the molar ratio of the total unsaturated groups in the reaction raw material mixture to the silicon-hydrogen bonds is (0.8-2) 1, and for example, may be 0.9:1, 1:1, 1.1:1, 1.2:1, 1.3:1, 1.4:1, 1:5, 1.6:1, 1.7:1, 1.8:1, 1.9:1, etc.

Preferably, the unsaturated group-containing polysilsesquioxane of the formula (A) has a structure ：(CH₃)₂R¹SiO-[R²SiO_3/2]_x[CH₃SiO_3/2]_y-SiR³(CH₃)₂（Ⅰ）, shown in the chemical formula (I), wherein R ¹、R²、R³ is independently selected from substituted or unsubstituted alkane groups and at least one or more unsaturated aliphatic groups, R ⁴ is independently selected from substituted or unsubstituted saturated alkane groups (such as C1-C16 linear or branched alkyl groups, more preferably any one of methyl, propyl, octyl and hexadecyl groups), and the substituent substituted by R ¹、R²、R³、R⁴ is selected from any one of alkyl groups, alkenyl groups, aryl groups, hydroxyl groups, halogen groups, ether groups and ester groups, x=1-50, y=0-50, wherein (1-50) can be specifically selected from the values of 2, 4, 6, 10, 12, 14, 16, 18, 20, 22, 24, 26, 28, 30, 32, 34, 36, 38, 40, 42, 44, 46, 48 and the like, and (0-50) can be specifically selected from the values of 1, 2, 4, 6, 10, 14, 16, 18, 20, 22, 24, 26, 28, 30, 32, 34, 46, 48 and the like.

Preferably, x=2 to 14 and y=0 to 16.

Preferably, the molecular weight of the component (A) is 4000-6000 g/mol.

Preferably, the alkenyl group content of the component (A) is 2.4-4.5 wt%.

Preferably, the unsaturated aliphatic hydrocarbon is an olefinically unsaturated group, and may be, for example, a C2-C8 linear olefin or a C2-C8 branched olefin.

Preferably, the unsaturated aliphatic hydrocarbon group is selected from any one of CH ₂=CH-、CH₂=CH-CH₂-、CH₂=C(CH₃)-CH₂CH₂ -.

Preferably, said (B) organohydrogensiloxane said component (B) organohydrogensiloxane comprises a side hydrogen containing silicone oil and/or a terminal hydrogen containing silicone oil.

Preferably, the organohydrogensiloxane of component (B) has a structure ：(CH₃)₃SiO[(CH₃)HSiO]_x[(R₁)₂SiO]_y-Si(CH₃)₃（Ⅱ）, as shown in formula (II) wherein x is a natural number in the range of 2 to 20, and may be, for example, 3, 4, 5, 6, 7, 8, 9, 10, 12, 14, 15, 16, 18, etc., y is a natural number in the range of 0 to 500, and may be, for example, an alkyl or aryl group having a value of 1, 10, 50, 100, 150, 200, 250, 300, 350, 400, 450, etc., and R ₁ is C1-20, and may be, for example, methyl, ethyl, propyl, butyl, pentyl, octyl, phenyl, etc.

More preferably, x=4 to 10 and y=10 to 100.

Preferably, the molecular weight of the component (B) is 4000-5000 g/mol.

Preferably, the SiH content of the component (B) is 0.1% -2%.

Preferably, the unsaturated polyether (C) has a structure shown as a chemical formula (III) R ₄[(C₂H₄O)_a(C₃H₆O)_b H (III), wherein a and b are natural numbers of 0-50, a+b >2, and R ₄ is unsaturated aliphatic hydrocarbon.

Preferably, a=10 to 22, and may take values of 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, etc., for example.

B=0 to 12, and may be, for example, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, or the like.

Preferably, R ₄ is selected from any one of CH ₂=CH-、CH₂=CH-CH₂-、CH₂=C(CH₃)-CH₂CH₂ -.

Preferably, the fluid carrier of the component (D) is one or more of low-viscosity polysiloxane, alkane or grease with the viscosity of 1-50 mPa.s.

Preferably, the low-viscosity polysiloxane is one or more than two of polydimethylsiloxane, C2-C16 fatty alkane modified silicone oil, natural oil modified silicone oil and cyclopenta-dimethylsiloxane.

Preferably, the component (D) accounts for 60-90 wt% of the total feeding ratio.

Preferably, the component (D) accounts for 70-85 wt% of the total feeding ratio.

Preferably, the alkane is isomerised dodecane and/or isomerised hexadecane.

Preferably, the grease is any one or more than two of coconut oil, white pool seed oleate and olive oil.

Preferably, the hydrosilylation catalyst of component (E) comprises a platinum metal-based catalyst.

Preferably, the platinum metal catalyst is selected from one or more of chloroplatinic acid, karstedt catalyst and Speier catalyst.

In a second aspect, the invention provides a preparation method of the water-dispersible polyether-modified organosilicon elastomer gel, which comprises the following steps of adding the reaction raw material mixture, the component (D) carrier fluid and the component (E) hydrosilylation catalyst into a dispersing machine for reaction, and grinding to obtain the water-dispersible polyether-modified organosilicon elastomer gel.

Preferably, the reaction temperature is 25-95 ℃.

Preferably, the reaction time is 3-8 hours.

Preferably, the apparatus for performing the grinding is selected from any one of a three-roll grinder, a colloid mill, and a ball mill.

Preferably, the preparation method further comprises the step of adding a polymerization inhibitor for mixing after grinding.

Preferably, the addition amount of the polymerization inhibitor is 1-5 parts by weight.

Preferably, the polymerization inhibitor may be one or more selected from tocopherol, vitamin a palmitate, triphenyl phosphate, olefin or silicone oil oligomer containing a single unsaturated bond.

In a third aspect, the present invention provides the use of a water-dispersible polyether modified silicone elastomer gel as described above in cosmetics or personal care products.

Compared with the prior art, the invention has the following beneficial effects:

The present invention provides water-dispersible polyether modified silicone elastomer gels formed by the catalytic addition of polysilsesquioxane containing at least two unsaturated hydrocarbons and polydimethylsiloxane containing a single unsaturated hydrocarbon polyether with at least two silicon-hydrogen bonds in a suitable fluid carrier. The water-dispersible polyether modified organosilicon elastomer gel has a hydrophilic polyether group and a lipophilic silicon elastomer structure, and can be dispersed in an aqueous phase to form a stable aqueous emulsion system gel with elastomer characteristics. Meanwhile, the water-dispersible polyether modified organosilicon elastomer gel has a polysilsesquioxane resin structure, can provide special skin feel and film forming effect by combining a reticular siloxane chain, and can be widely applied to the fields of daily chemical products, personal care products and the like.

Detailed Description

The technical scheme of the invention is further described by the following specific embodiments. It will be apparent to those skilled in the art that the examples are merely to aid in understanding the invention and are not to be construed as a specific limitation thereof. Unless specifically stated otherwise, the reagents, methods and apparatus employed in the present invention are those conventional in the art. In the present specification, "part" and "%" respectively mean "part by mass" and "% by mass" unless otherwise specified. And "molecular weight" is "number average molecular weight".

The following examples and comparative examples were tested using the following test methods.

The emulsifying effect is that 10g of water-dispersible polyether modified organic silicon elastomer gel is mixed with 5g of deionized water, then shearing and dispersing are carried out, the emulsifying effect of self-added water is observed, and another 10g of water-dispersible polyether modified organic silicon elastomer gel, 0.2g of hydrophilic surfactant (PEG-10 stearate) and 10g of deionized water are mixed, then shearing and dispersing are carried out, and the emulsifying effect of the hydrophilic surfactant is observed. The emulsion effect of adding water and hydrophilic surfactant is classified into three grades according to the emulsion effect, wherein ' excellent ' means that water can be added by itself to quickly form water-in-oil emulsion, hydrophilic surfactant can be added to quickly form stable oil-in-water emulsion, good ' means that water-in-oil emulsion can be formed, hydrophilic surfactant can be added to form stable oil-in-water emulsion, and ' poor ' means that water-in-oil emulsion is difficult to form, and the oil-in-water emulsion formed by adding hydrophilic surfactant stands to generate layering phenomenon.

Film-forming effect and skin feel 9g of water-dispersible polyether modified organosilicon elastomer gel and 1g of toner are uniformly mixed, and then the mixture is directly smeared on the skin of the back of the palm, and after 30 minutes, the mixture is dried, the skin feel and film-forming effect are felt. The skin feel and film forming effect were judged to be good or bad in terms of 1-5 points, with 1 being the worst and 5 being the best.

The structural formulae of APEG-10, APEG-12 and APEG-15 in the following examples and comparative examples are respectively CH₂=CHCH₂O（CH₂CH₂O)n H,n=10、CH₂=CHCH₂O（CH₂CH₂O)n H,n=12、CH₂=CHCH₂O（CH₂CH₂O)n H,n=15.

The side hydrogen containing silicone oils employed in the following examples have the following general structural formula:

(CH₃)₃SiO[(CH₃)HSiO]_x[(CH₃)₂SiO]_y-Si(CH₃)₃（Ⅱ）,x=2~10,y=10~100.

In the following examples and comparative examples, n _A/n_B represents the molar ratio of unsaturated groups in the unsaturated group-containing polysilsesquioxane to the silanol groups in the organohydrogensiloxane, and n _C/n_B represents the molar ratio of unsaturated groups in the unsaturated group-containing polyether to the silanol groups in the organohydrogensiloxane.

Examples 1-3 preparation of Water-dispersible polyether-modified Silicone elastomer gels of different Carrier fluids

Table 1 shows the raw materials and the charged weights thereof of examples 1 to 3, and the results of the related performance tests are shown. Wherein the structural formula of the polysilsesquioxane containing unsaturated groups is (CH₃)₂R¹SiO-[R²SiO_3/2]_x[CH₃SiO_3/2]_y-SiR³(CH₃)₂,R¹, R ³ is vinyl, R ² is methyl, x=14, y=0, the molecular weight is 4500, the vinyl content is 2.4%, the molecular weight of the side hydrogen silicone oil is 5000, the SiH content is 0.2%, and the polyether containing unsaturated groups is APEG-12 (chemical formula CH ₂=CHCH₂O（CH₂CH₂ O) n H, n=12.

TABLE 1 Water-dispersible polyether-modified Silicone elastomer gels of different Carriers

Examples 1 to 3 were prepared by the following preparation methods, except that the respective carriers used were different.

The preparation method comprises the following steps:

The preparation method comprises the steps of putting the raw materials shown in the table 1 and containing unsaturated group polysilsesquioxane, APEG-12, side hydrogen silicone oil, platinum catalyst and carrier into a dispersing machine, mixing and stirring, heating to 80 ℃ for reaction for 8 hours, putting into a three-roller grinder for grinding for 2 times after the reaction is completed, and adding polymerization inhibitor tocopherol and stirring uniformly. The product is tested by infrared IR and no SiH bond exists, which indicates that the SiH bond has all reacted, and the application test shows that the example 2 has more excellent self-emulsifying effect, can quickly form water-in-oil emulsion by adding water, and can quickly form stable oil-in-water emulsion by adding hydrophilic surfactant.

Examples 4-6 preparation of Water-dispersible polyether-modified Silicone elastomer gels of different unsaturated group-containing polyethers

Table 2 shows the raw materials and the charged weights thereof of examples 4 to 6, and the results of the related performance tests are shown. Wherein the structural formula of the polysilsesquioxane containing unsaturated groups is (CH₃)₂R¹SiO-[R²SiO_3/2]_x[CH₃SiO_3/2]_y-SiR³(CH₃)₂, R¹, R ³ is vinyl, R ² is=propyl, x=2, y=10, the molecular weight is 4000, the vinyl content is 2.7%, the molecular weight of the side hydrogen silicone oil is 4600g/mol, the SiH content is 0.15%, and the polyether containing unsaturated groups is sequentially APEG-10（CH₂=CHCH₂O（CH₂CH₂O)nH,n=10）、APEG-12（CH₂=CHCH₂O（CH₂CH₂O)n H,n=12）、APEG-15 （CH₂=CHCH₂O（CH₂CH₂O)nH,n=15）.

TABLE 2

Examples 4 to 6 were each prepared by the following preparation method, except that the unsaturated group-containing polyethers used each were different.

The preparation method comprises the following steps:

The raw materials shown in the table 2, namely the polysilsesquioxane containing unsaturated groups, the polyether containing unsaturated groups, the hydrogen-containing silicone oil, the platinum catalyst and the 10CSt octyl silicone oil are put into a dispersing machine to be mixed and stirred, heated to 60 ℃ to react for 6 hours, and then put into a grinder to be ground for 2 times after the reaction is completed, and then the polymerization inhibitor tocopherol is added to be stirred uniformly. The product is tested by infrared IR and no SiH bond exists, which indicates that the SiH bond has all reacted, and the application test shows that the example 5 has more excellent self-emulsifying effect, can quickly form water-in-oil emulsion by adding water, and can quickly form stable oil-in-water emulsion by adding hydrophilic surfactant.

Examples 7-9 preparation of Water-dispersible polyether-modified Silicone elastomer gels with different olefin/SiH molar ratios

Table 3 shows the raw materials and the charged weights thereof for examples 7 to 9, and the results of the related performance tests are shown. Wherein the structural formula of the polysilsesquioxane containing unsaturated groups is (CH₃)₂R¹SiO-[R²SiO_3/2]_x[CH₃SiO_3/2]_y-SiR³(CH₃)₂, R¹, R ³ is methyl, R ² is=vinyl, x=2, y=16, the molecular weight is 6000, the vinyl content is 4.5%, the molecular weight of the side hydrogen silicone oil is 4600g/mol, the SiH content is 0.15%, and the polyether containing unsaturated groups is APEG-12 (chemical formula: CH ₂=CHCH₂O（CH₂CH₂ O) n H, n=12).

TABLE 3 Table 3

Examples 7-9 were all prepared using the following preparation methods, except that the molar ratios of olefin/SiH were different.

The preparation method comprises the following steps:

The raw materials shown in the table 3, namely, the polysilsesquioxane containing unsaturated groups, the polyether containing unsaturated groups, the hydrogen-containing silicone oil, the platinum catalyst and the 10CSt octyl silicone oil are put into a dispersing machine to be mixed and stirred, heated to 90 ℃ to react for 8 hours, and then put into a three-roller grinder to be ground for 2 times after the reaction is completed, and then the polymerization inhibitor tocopherol is added to be stirred uniformly. The product is tested by infrared IR and no SiH bond exists, which indicates that SiH bonds are fully reacted, and the application test shows that the example 8 has more excellent self-emulsifying effect, can quickly form water-in-oil emulsion by adding water, and can quickly form stable oil-in-water emulsion by adding hydrophilic surfactant.

Examples 10-14 preparation of Water-dispersible polyether modified Silicone elastomer gels of different n _A/n_B and n _C/n_B

Wherein the structural formula of the polysilsesquioxane containing unsaturated groups is (CH₃)₂R¹SiO-[R²SiO_3/2]_x[CH₃SiO_3/2]_y-SiR³(CH₃)₂, R¹, R ³ is vinyl, R ² is methyl, x=14, y=0, the molecular weight is 4500, the vinyl content is 2.4%, the molecular weight of the side hydrogen silicone oil is 5000, the SiH content is 0.2%, and the polyether containing unsaturated groups is APEG-12 (chemical formula CH ₂=CHCH₂O（CH₂CH₂ O) n H, n=12.

Table 4 shows the raw materials and the charged weights thereof for examples 10 to 14, and the results of the related performance tests are shown.

TABLE 4 Table 4

Examples 10 to 14 were prepared by the following preparation methods, with the difference that the amounts of the respective raw materials were different.

The preparation method comprises the following steps:

The raw materials shown in the table 4, namely, the polysilsesquioxane containing unsaturated groups, the polyether containing unsaturated groups, the hydrogen-containing silicone oil, the platinum catalyst and the 10CSt octyl silicone oil are put into a dispersing machine to be mixed and stirred, heated to 70 ℃ to react for 8 hours, and then put into a three-roller grinder to be ground for 2 times after the reaction is completed, and then the polymerization inhibitor tocopherol is added to be stirred uniformly. The product is tested by infrared IR that no SiH bond exists, which indicates that SiH bonds have all reacted, and the application test shows that example 10 and example 11 have more excellent self-emulsifying effect, water-in-oil cream can be quickly formed by self-adding water, and stable oil-in-water emulsion can be quickly formed by adding hydrophilic surfactant.

Comparative example 1

The comparative example differs from example 2 only in that the molecular weight of the comparative example was about 4500, the vinyl content was 2.4% by replacing the unsaturated group-containing polysilsesquioxane with an equivalent mass of vinyl silicone oil （（CH₂=CH(CH₃)₂SiO[(CH₃)₂ SiO]_x-Si(CH₃)₂CH=CH₂）,.

The obtained water-dispersible polyether modified organosilicon elastomer gel has no SiH bond after infrared IR test, which indicates that the SiH bond has reacted completely. And emulsion effect, film forming effect and skin feel were measured, and the obtained results are shown in table 5.

Comparative example 2

This comparative example differs from example 2 only in that this comparative example replaces the side-hydrogen silicone oil with an equivalent mass of hydrogen-containing polysilsesquioxane (CH ₃)₂HSiO-[CH₃SiO_3/2]_x-SiH(CH₃)₂ (molecular weight about 5000, siH content 0.2%)) and the unsaturated group-containing polysilsesquioxane with an equivalent mass of vinyl silicone oil （CH₂=CH(CH₃)₂SiO[(CH₃)₂SiO]_x-Si(CH₃)₂CH=CH₂）（ (molecular weight about 4500, vinyl content 2.4%).

The obtained water-dispersible polyether modified organosilicon elastomer gel has no SiH bond after infrared IR test, which indicates that the SiH bond has reacted completely. And emulsion effect, film forming effect and skin feel were measured, and the obtained results are shown in table 5.

Comparative example 3

The comparative example differs from example 2 only in that the unsaturated group-containing silsesquioxane used in the comparative example was prepared by the following preparation method:

after reacting 100g of vinyltriethoxysilane, 48g of tetrahydrofuran, 24g of distilled water and 1g of dibutyltin dilaurate at 70 ℃ for 5 hours, small molecular substances are removed by spin evaporation, and vinyl-containing silsesquioxane is obtained.

N _A/n_B and other conditions remain unchanged.

TABLE 5

As can be seen from tables 1 to 4, the water-dispersible polyether-modified silicone elastomer gel provided by the invention has excellent emulsifying effect, film forming effect and skin feel.

The applicant states that the invention is illustrated by the above embodiments, but the invention is not limited to, i.e. it does not mean that the invention has to be carried out in dependence of the above embodiments. It should be apparent to those skilled in the art that any modification of the present invention, equivalent substitution of raw materials for the product of the present invention, addition of auxiliary components, selection of specific modes, etc., falls within the scope of the present invention and the scope of disclosure.

Claims (10)

1. A water-dispersible polyether-modified silicone elastomer gel, characterized in that it is composed of a reaction raw material mixture comprising the following components: (A) an unsaturated group-containing polysilsesquioxane containing at least two unsaturated hydrocarbon groups; (B) an organohydrogensiloxane containing at least two silicon-hydrogen bonds; (C) an unsaturated group-containing polyether containing at least one unsaturated hydrocarbon group; It is obtained by catalytic reaction of (E) hydrosilylation reaction catalyst in (D) carrier fluid. 2. The water-dispersible polyether-modified silicone elastomer gel according to claim 1, characterized in that the molar ratio of the unsaturated groups in the component (A) to the silicon-hydrogen bonds in the component (B) is (0.1-1.5):1; Preferably, the molar ratio of the unsaturated groups in the component (A) to the silicon-hydrogen bonds in the component (B) is (0.4-1):1; Preferably, the molar ratio of the unsaturated groups in the component (C) to the silicon-hydrogen bonds in the component (B) is (0.1-1.5):1; Preferably, the molar ratio of the unsaturated groups in the component (C) to the silicon-hydrogen bonds in the component (B) is (0.3-1):1; Preferably, the molar ratio of the total unsaturated groups in the reaction raw material mixture to the silicon-hydrogen bonds is (0.8-2):1. 3. The water-dispersible polyether-modified silicone elastomer gel according to claim 1, characterized in that the unsaturated group-containing polysilsesquioxane of component (A) has a structure as shown in chemical formula (I): (CH ₃ ) ₂ R ¹ SiO-[R ² SiO _3/2 ] _x [R ⁴ SiO _3/2 ] _y -SiR ³ (CH ₃ ) ₂ (I), wherein R ¹ , R ² , and R ³ are each independently selected from substituted or unsubstituted alkane groups, and at least one of them is an unsaturated aliphatic hydrocarbon group; R ⁴ is independently selected from substituted or unsubstituted saturated alkane groups, and the substituents substituted by R ¹ , R ² , R ^{3 , and} R ⁴ are selected from any one of alkyl, alkenyl, aryl, hydroxyl, halogen, ether, and ester groups; x=1-50, y=0-50; preferably, x=2-14; y=0-16; Preferably, the unsaturated aliphatic hydrocarbon group is an olefin unsaturated group; Preferably, the unsaturated aliphatic hydrocarbon group is selected from any one of CH ₂ ═CH—, CH ₂ ═CH—CH ₂ —, and CH ₂ ═C(CH ₃ )—CH ₂ CH ₂ —. 4. The water-dispersible polyether-modified silicone elastomer gel according to claim 1, characterized in that the component (B) organohydrogensiloxane comprises side hydrogen-containing silicone oil and/or terminal hydrogen-containing silicone oil; Preferably, the organohydrogensiloxane of component (B) has a structure as shown in chemical formula (II): (CH ₃ ) ₃ SiO[(CH ₃ )HSiO] _x [(R ₁ ) ₂ SiO] _y -Si(CH ₃ ) ₃ (II), wherein x is a natural number from 2 to 20, y is a natural number from 0 to 500, and R ¹ is a C1-20 alkyl or aryl group; Preferably, x=4~10, y=10~100. 5. The water-dispersible polyether-modified silicone elastomer gel according to claim 1, characterized in that the unsaturated polyether of component (C) has a structure as shown in chemical formula (III): R ₄ [(C ₂ H ₄ O) _a (C ₃ H ₆ O) _b ]H (III), wherein a and b are natural numbers of 0 to 50, and a+b＞2, and R ₄ is an unsaturated aliphatic hydrocarbon; Preferably, a=10~22, b=0~12; Preferably, R ₄ is selected from any one of CH ₂ ═CH—, CH ₂ ═CH—CH ₂ —, and CH ₂ ═C(CH ₃ )—CH ₂ CH ₂ —. 6. The water-dispersible polyether-modified silicone elastomer gel according to claim 1, characterized in that the fluid carrier of component (D) is one or more of low-viscosity polysiloxane, alkane or oil with a viscosity of 1 to 50 mPa·s; Preferably, the low-viscosity polysiloxane is one or more of polydimethylsiloxane, C2-C16 fatty alkane-modified silicone oil, and natural oil-modified silicone oil; Preferably, the component (D) accounts for 60-90wt% of the total feed ratio; Preferably, the component (D) accounts for 70-85wt% of the total feed ratio. 7. The water-dispersible polyether-modified silicone elastomer gel according to claim 1, characterized in that the (E) hydrosilylation reaction catalyst comprises a platinum metal catalyst; Preferably, the platinum metal catalyst is selected from one or more of chloroplatinic acid, Karstedt catalyst and Speier catalyst. 8. A method for preparing a water-dispersible polyether-modified silicone elastomer gel according to any one of claims 1 to 7, characterized in that it comprises the following steps: reacting the reaction raw material mixture, component (D) carrier fluid and component (E) hydrosilylation reaction catalyst, and then grinding to obtain the water-dispersible polyether-modified silicone elastomer gel. 9. The preparation method according to claim 8, characterized in that the reaction temperature is 25-95°C; Preferably, the reaction time is 3 to 8 hours; Preferably, the grinding equipment is selected from any one of a three-roll mill, a colloid mill and a ball mill; Preferably, the preparation method further comprises the steps of: after grinding, adding a polymerization inhibitor and mixing; Preferably, the amount of the polymerization inhibitor added is 1 to 5 parts by weight based on 100 parts by weight of the total weight of the reaction raw material mixture and component (D). 10. Use of the water-dispersible polyether-modified silicone elastomer gel according to any one of claims 1 to 9 in cosmetics or personal care products.