CN118599394A - A two-component epoxy primer with ultra-long activation period and its preparation method and application - Google Patents
A two-component epoxy primer with ultra-long activation period and its preparation method and application Download PDFInfo
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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Abstract
Description
技术领域Technical Field
本发明涉及环氧涂料技术领域,尤其涉及一种超长活化期双组份环氧底漆及其制备方法和应用。The invention relates to the technical field of epoxy coatings, and in particular to a two-component epoxy primer with an ultra-long activation period, and a preparation method and application thereof.
背景技术Background Art
环氧底漆能够赋予涂层良好的粘接力,且具有优异的化学稳定性和机械性能,应用广泛。现有技术中环氧底漆的活化期大部分在4~6h,个别种类环氧底漆的活化期可达8h左右。采用某些工艺涂覆环氧底漆时要求其具有较长的活化期,如在变压器淋涂工艺中通常要求环氧底漆的活化期至少为12h,这主要是因为目前实际生产中普遍为3班倒班的工作环境,且需要至少预留1h交班,若环氧底漆的活化期较短,则无法满足实际应用,影响生产顺利进行。Epoxy primer can give the coating good adhesion, and has excellent chemical stability and mechanical properties, and is widely used. In the prior art, the activation period of epoxy primers is mostly 4 to 6 hours, and the activation period of some types of epoxy primers can reach about 8 hours. When using certain processes to apply epoxy primers, it is required to have a longer activation period. For example, in the transformer coating process, the activation period of epoxy primers is usually required to be at least 12 hours. This is mainly because the current actual production is generally a three-shift work environment, and at least 1 hour is required to be reserved for handover. If the activation period of the epoxy primer is short, it cannot meet the actual application and affect the smooth progress of production.
发明内容Summary of the invention
本发明的目的在于提供一种超长活化期双组份环氧底漆及其制备方法和应用,本发明提供的双组份环氧底漆具有超长活化期。The purpose of the present invention is to provide a two-component epoxy primer with an ultra-long activation period, a preparation method and an application thereof. The two-component epoxy primer provided by the present invention has an ultra-long activation period.
为了实现上述发明目的,本发明提供以下技术方案:In order to achieve the above-mentioned object of the invention, the present invention provides the following technical solutions:
本发明提供了一种超长活化期双组份环氧底漆,包括分装的A组分与B组分;所述A组分与B组分的质量比为1.5~2.5:1;The present invention provides a two-component epoxy primer with an ultra-long activation period, comprising a separately packaged component A and a component B; the mass ratio of the component A to the component B is 1.5-2.5:1;
所述B组分包括3986固化剂、丙二醇甲醚与水;The B component includes 3986 curing agent, propylene glycol methyl ether and water;
所述A组分包括以下质量份数的组分:JT-WBE522水性环氧乳液35~55份;分散剂1~3份;消泡剂0.3~0.5份;钛白粉5~10份;云母粉5~15份;硅灰石10~15份;滑石粉5~10份;炭黑0.1~0.5份;硅烷偶联剂0.2~0.5份;防闪锈助剂0.5~1份;增稠剂0.2~0.5份;润湿剂0.1~0.3份;助溶剂3~10份;水10~20份。The component A includes the following components in parts by mass: 35 to 55 parts of JT-WBE522 water-based epoxy emulsion; 1 to 3 parts of dispersant; 0.3 to 0.5 parts of defoamer; 5 to 10 parts of titanium dioxide; 5 to 15 parts of mica powder; 10 to 15 parts of wollastonite; 5 to 10 parts of talc; 0.1 to 0.5 parts of carbon black; 0.2 to 0.5 parts of silane coupling agent; 0.5 to 1 part of anti-flash rust additive; 0.2 to 0.5 parts of thickener; 0.1 to 0.3 parts of wetting agent; 3 to 10 parts of cosolvent; and 10 to 20 parts of water.
优选地,所述B组分中3986固化剂、丙二醇甲醚与水的质量比为20:4~6:18~22。Preferably, the mass ratio of 3986 curing agent, propylene glycol methyl ether and water in the B component is 20:4-6:18-22.
优选地,所述分散剂为BYK190分散剂,所述消泡剂为BYK-028消泡剂。Preferably, the dispersant is BYK190 dispersant, and the defoamer is BYK-028 defoamer.
优选地,所述钛白粉为R996金红石钛白粉;所述云母粉为GA-4云母粉;所述炭黑为MA-100炭黑。Preferably, the titanium dioxide is R996 rutile titanium dioxide; the mica powder is GA-4 mica powder; and the carbon black is MA-100 carbon black.
优选地,所述硅烷偶联剂为MP-200硅烷偶联剂;所述防闪锈助剂为Raybo 60防闪锈助剂。Preferably, the silane coupling agent is MP-200 silane coupling agent; and the anti-flash rust agent is Raybo 60 anti-flash rust agent.
优选地,所述增稠剂为0620增稠剂;所述润湿剂为4100润湿剂;所述助溶剂为二丙二醇丁醚和/或二丙二醇甲醚。Preferably, the thickener is 0620 thickener; the wetting agent is 4100 wetting agent; and the cosolvent is dipropylene glycol butyl ether and/or dipropylene glycol methyl ether.
优选地,所述A组分的细度≤30μm,固体含量≥46wt%;所述B组分的固体含量≥20wt%。Preferably, the fineness of component A is ≤30 μm, and the solid content is ≥46 wt %; and the solid content of component B is ≥20 wt %.
本发明提供了上述技术方案所述超长活化期双组份环氧底漆的制备方法,包括以下步骤:The present invention provides a method for preparing the ultra-long active period two-component epoxy primer according to the above technical solution, comprising the following steps:
将水、分散剂、云母粉、钛白粉、硅灰石、滑石粉、炭黑与部分消泡剂混合后进行研磨,得到研磨料浆;将所述研磨料浆、JT-WBE522水性环氧乳液、助溶剂、增稠剂、润湿剂、硅烷偶联剂、防闪锈助剂与剩余消泡剂混合,得到所述A组分;Mix water, dispersant, mica powder, titanium dioxide, wollastonite, talc, carbon black and part of the defoamer and grind them to obtain a grinding slurry; mix the grinding slurry, JT-WBE522 water-based epoxy emulsion, cosolvent, thickener, wetting agent, silane coupling agent, anti-flash rust additive and the remaining defoamer to obtain the A component;
将3986固化剂、丙二醇甲醚与水混合,得到所述B组分。The 3986 curing agent, propylene glycol methyl ether and water are mixed to obtain the B component.
优选地,所述研磨的温度≤50℃,压力≤0.2MPa;所述研磨料浆的细度≤20μm。Preferably, the grinding temperature is ≤50°C, the pressure is ≤0.2MPa; and the fineness of the grinding slurry is ≤20μm.
本发明提供了上述技术方案所述超长活化期双组份环氧底漆或上述技术方案所述制备方法制备得到的超长活化期双组份环氧底漆在变压器淋涂中的应用。The present invention provides the use of the ultra-long activation period two-component epoxy primer described in the above technical solution or the ultra-long activation period two-component epoxy primer prepared by the preparation method described in the above technical solution in transformer spray coating.
本发明提供了一种超长活化期双组份环氧底漆,包括分装的A组分与B组分;所述A组分与B组分的质量比为1.5~2.5:1;所述B组分包括3986固化剂、丙二醇甲醚与水;所述A组分包括以下质量份数的组分:JT-WBE522水性环氧乳液35~55份;分散剂1~3份;消泡剂0.3~0.5份;钛白粉5~10份;云母粉5~15份;硅灰石10~15份;滑石粉5~10份;炭黑0.1~0.5份;硅烷偶联剂0.2~0.5份;防闪锈助剂0.5~1份;增稠剂0.2~0.5份;润湿剂0.1~0.3份;助溶剂3~10份;水10~20份。本发明利用JT-WBE522水性环氧乳液与3986固化剂分别作为A组分与B组分的主体组分,二者复配且在其它各组分综合作用下,保证所得双组份环氧底漆具有超长活化期。此外本发明中双组份环氧底漆还具有较好耐盐雾性。实施例的结果显示,本发明提供的双组份环氧底漆的活化期可达24h,耐盐雾可达800h。The invention provides a super-long active period two-component epoxy primer, comprising separately packaged component A and component B; the mass ratio of the component A to the component B is 1.5-2.5:1; the component B comprises a 3986 curing agent, propylene glycol methyl ether and water; the component A comprises the following components in parts by mass: 35-55 parts of JT-WBE522 water-based epoxy emulsion; 1-3 parts of a dispersant; 0.3-0.5 parts of a defoamer; 5-10 parts of titanium dioxide; 5-15 parts of mica powder; 10-15 parts of wollastonite; 5-10 parts of talc; 0.1-0.5 parts of carbon black; 0.2-0.5 parts of a silane coupling agent; 0.5-1 parts of an anti-flash rust additive; 0.2-0.5 parts of a thickener; 0.1-0.3 parts of a wetting agent; 3-10 parts of a cosolvent; and 10-20 parts of water. The present invention utilizes JT-WBE522 waterborne epoxy emulsion and 3986 curing agent as the main components of component A and component B respectively, and the two are compounded and under the comprehensive effect of other components, the obtained two-component epoxy primer is guaranteed to have an ultra-long activation period. In addition, the two-component epoxy primer in the present invention also has good salt spray resistance. The results of the embodiment show that the activation period of the two-component epoxy primer provided by the present invention can reach 24 hours, and the salt spray resistance can reach 800 hours.
具体实施方式DETAILED DESCRIPTION
本发明提供了一种超长活化期双组份环氧底漆,包括分装的A组分与B组分;所述A组分与B组分的质量比为1.5~2.5:1;The present invention provides a two-component epoxy primer with an ultra-long activation period, comprising a separately packaged component A and a component B; the mass ratio of the component A to the component B is 1.5-2.5:1;
所述B组分包括3986固化剂、丙二醇甲醚与水;The B component includes 3986 curing agent, propylene glycol methyl ether and water;
所述A组分包括以下质量份数的组分:JT-WBE522水性环氧乳液35~55份;分散剂1~3份;消泡剂0.3~0.5份;钛白粉5~10份;云母粉5~15份;硅灰石10~15份;滑石粉5~10份;炭黑0.1~0.5份;硅烷偶联剂0.2~0.5份;防闪锈助剂0.5~1份;增稠剂0.2~0.5份;润湿剂0.1~0.3份;助溶剂3~10份;水10~20份。The component A includes the following components in parts by mass: 35 to 55 parts of JT-WBE522 water-based epoxy emulsion; 1 to 3 parts of dispersant; 0.3 to 0.5 parts of defoamer; 5 to 10 parts of titanium dioxide; 5 to 15 parts of mica powder; 10 to 15 parts of wollastonite; 5 to 10 parts of talc; 0.1 to 0.5 parts of carbon black; 0.2 to 0.5 parts of silane coupling agent; 0.5 to 1 part of anti-flash rust additive; 0.2 to 0.5 parts of thickener; 0.1 to 0.3 parts of wetting agent; 3 to 10 parts of cosolvent; and 10 to 20 parts of water.
在本发明中,若无特殊说明,所用原料均为本领域技术人员熟知的市售商品。In the present invention, unless otherwise specified, the raw materials used are commercially available products well known to those skilled in the art.
本发明所述超长活化期双组份环氧底漆包括分装的A组分与B组分;所述A组分与B组分的质量比为1.5~2.5:1,优选为1.8~2.2:1,更优选为2:1。The ultra-long active period two-component epoxy primer of the present invention comprises separately packaged component A and component B; the mass ratio of component A to component B is 1.5-2.5:1, preferably 1.8-2.2:1, and more preferably 2:1.
本发明所述B组分包括3986固化剂、丙二醇甲醚(PM)与水;所述B组分中3986固化剂、丙二醇甲醚与水的质量比优选为20:4~6:18~22,更优选为20:5:20。The B component of the present invention includes 3986 curing agent, propylene glycol methyl ether (PM) and water; the mass ratio of 3986 curing agent, propylene glycol methyl ether and water in the B component is preferably 20:4-6:18-22, more preferably 20:5:20.
按质量份数计,本发明所述A组分包括JT-WBE522水性环氧乳液35~55份,具体可以为35份、38份、40份、42份、45份、48份、50份、53份或55份。In parts by mass, the component A of the present invention includes 35 to 55 parts of JT-WBE522 water-based epoxy emulsion, specifically 35 parts, 38 parts, 40 parts, 42 parts, 45 parts, 48 parts, 50 parts, 53 parts or 55 parts.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括分散剂1~3份,优选为1.5~2.5份,更优选为2份。本发明所述分散剂优选为BYK190分散剂。本发明优选采用上述种类的分散剂,有利于各组分保持较好的分散效果。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 1 to 3 parts of dispersant, preferably 1.5 to 2.5 parts, and more preferably 2 parts. The dispersant of the present invention is preferably BYK190 dispersant. The present invention preferably uses the above-mentioned type of dispersant, which is conducive to maintaining a good dispersion effect of each component.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括消泡剂0.3~0.5份,优选为0.3~0.4份。本发明所述消泡剂优选为BYK-028消泡剂。本发明优选采用上述种类的消泡剂,具有较好的消泡效果。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 0.3 to 0.5 parts of defoamer, preferably 0.3 to 0.4 parts. The defoamer of the present invention is preferably BYK-028 defoamer. The present invention preferably uses the above-mentioned type of defoamer, which has a better defoaming effect.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括钛白粉5~10份,优选为5~8份,更优选为5~6份。本发明所述钛白粉优选为R996金红石钛白粉;所述钛白粉的粒度优选为0.1~0.45μm。本发明优选采用上述种类的钛白粉,粒径小,有利于分散和研磨。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 5 to 10 parts of titanium dioxide, preferably 5 to 8 parts, and more preferably 5 to 6 parts. The titanium dioxide of the present invention is preferably R996 rutile titanium dioxide; the particle size of the titanium dioxide is preferably 0.1 to 0.45 μm. The present invention preferably uses the above-mentioned type of titanium dioxide, which has a small particle size and is conducive to dispersion and grinding.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括云母粉5~15份,优选为8~12份,更优选为9~10份。本发明所述云母粉优选为GA-4云母粉;所述云母粉的粒度优选为5~10μm。本发明优选采用上述种类的云母粉,云母粉粒径小,耐盐雾性能更好,有利于提高涂料的耐盐雾性能。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 5 to 15 parts of mica powder, preferably 8 to 12 parts, and more preferably 9 to 10 parts. The mica powder of the present invention is preferably GA-4 mica powder; the particle size of the mica powder is preferably 5 to 10 μm. The present invention preferably uses the above-mentioned type of mica powder, which has a small particle size and better salt spray resistance, which is beneficial to improving the salt spray resistance of the coating.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括硅灰石10~15份,优选为10~13份,更优选为10~11份。本发明所述硅灰石的粒度优选为1250目。本发明优选采用上述种类的硅灰石,其针状结构有利于填充漆膜之间的空隙,达到更好的耐盐雾效果。Based on the mass fraction of the JT-WBE522 water-based epoxy emulsion, the component A of the present invention includes 10 to 15 parts of wollastonite, preferably 10 to 13 parts, and more preferably 10 to 11 parts. The particle size of the wollastonite of the present invention is preferably 1250 mesh. The present invention preferably uses the above-mentioned type of wollastonite, whose needle-like structure is conducive to filling the gaps between the paint films to achieve better salt spray resistance.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括滑石粉5~10份,优选为5~8份,更优选为5~6份。本发明所述滑石粉的粒度优选为1250目。本发明优选采用上述种类的滑石粉,有利于屏蔽水汽,提高涂料的耐盐雾性能。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 5 to 10 parts of talc, preferably 5 to 8 parts, and more preferably 5 to 6 parts. The particle size of the talc of the present invention is preferably 1250 mesh. The present invention preferably uses the above-mentioned type of talc, which is beneficial to shielding water vapor and improving the salt spray resistance of the coating.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括炭黑0.1~0.5份,优选为0.2~0.4份,更优选为0.3份。本发明所述炭黑优选为MA-100炭黑;所述炭黑的粒度优选为10~100μm。本发明中炭黑为着色颜料,起到调色作用。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 0.1 to 0.5 parts of carbon black, preferably 0.2 to 0.4 parts, and more preferably 0.3 parts. The carbon black of the present invention is preferably MA-100 carbon black; the particle size of the carbon black is preferably 10 to 100 μm. In the present invention, the carbon black is a coloring pigment and plays a role in coloring.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括硅烷偶联剂0.2~0.5份,优选为0.3~0.4份。本发明所述硅烷偶联剂优选为MP-200硅烷偶联剂。本发明优选采用上述种类的硅烷偶联剂,能够提高漆膜与基材的附着力,有利于提高涂料的耐水和耐盐雾性能。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 0.2 to 0.5 parts of silane coupling agent, preferably 0.3 to 0.4 parts. The silane coupling agent of the present invention is preferably MP-200 silane coupling agent. The present invention preferably uses the above-mentioned type of silane coupling agent, which can improve the adhesion between the paint film and the substrate, and is beneficial to improve the water resistance and salt spray resistance of the coating.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括防闪锈助剂0.5~1份,优选为0.5~0.8份,更优选为0.5~0.6份。本发明所述防闪锈助剂优选为Raybo 60防闪锈助剂。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 0.5 to 1 part of an anti-flash rust additive, preferably 0.5 to 0.8 part, and more preferably 0.5 to 0.6 part. The anti-flash rust additive of the present invention is preferably Raybo 60 anti-flash rust additive.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括增稠剂0.2~0.5份,优选为0.2~0.3份。本发明所述增稠剂优选为0620增稠剂。本发明优选采用上述种类的增稠剂,有利于提高粘度,能够防止沉降,且能够防止施工时流挂,有利于提高漆膜厚度。Based on the mass fraction of the JT-WBE522 water-based epoxy emulsion, the component A of the present invention includes 0.2 to 0.5 parts of thickener, preferably 0.2 to 0.3 parts. The thickener of the present invention is preferably 0620 thickener. The present invention preferably uses the above-mentioned thickener, which is beneficial to increase viscosity, prevent sedimentation, and prevent sagging during construction, which is beneficial to increase the thickness of the paint film.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括润湿剂0.1~0.3份,优选为0.1~0.2份。本发明所述润湿剂优选为4100润湿剂。本发明优选采用上述种类的润湿剂,能够降低漆膜表面张力,有利于减少漆膜缩孔的弊病。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 0.1 to 0.3 parts of a wetting agent, preferably 0.1 to 0.2 parts. The wetting agent of the present invention is preferably a 4100 wetting agent. The present invention preferably uses the above-mentioned types of wetting agents, which can reduce the surface tension of the paint film and help reduce the drawbacks of shrinkage cavities of the paint film.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括助溶剂3~10份,优选为5~10份,更优选为8~10份。本发明所述助溶剂优选为二丙二醇丁醚(DPNB)和/或二丙二醇甲醚(DPM),更优选为二丙二醇丁醚和二丙二醇甲醚,所述二丙二醇丁醚和二丙二醇甲醚的质量比优选为6:3.5~4.5,更优选为6:4。本发明优选采用上述种类的助溶剂,能够使漆膜更好的成膜,有利于提高漆膜的耐盐雾性能。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 3 to 10 parts of a cosolvent, preferably 5 to 10 parts, and more preferably 8 to 10 parts. The cosolvent of the present invention is preferably dipropylene glycol butyl ether (DPNB) and/or dipropylene glycol methyl ether (DPM), more preferably dipropylene glycol butyl ether and dipropylene glycol methyl ether, and the mass ratio of dipropylene glycol butyl ether to dipropylene glycol methyl ether is preferably 6:3.5 to 4.5, more preferably 6:4. The present invention preferably uses the above-mentioned type of cosolvent, which can make the paint film form better, which is beneficial to improve the salt spray resistance of the paint film.
以所述JT-WBE522水性环氧乳液的质量份数为基准,本发明所述A组分包括水10~20份,优选为14~17份,更优选为15~16.5份。本发明所述水优选为去离子水。Based on the mass fraction of the JT-WBE522 waterborne epoxy emulsion, the component A of the present invention includes 10 to 20 parts of water, preferably 14 to 17 parts, and more preferably 15 to 16.5 parts. The water of the present invention is preferably deionized water.
在本发明中,所述A组分的细度优选≤30μm,固体含量优选≥46wt%。In the present invention, the fineness of the component A is preferably ≤30 μm, and the solid content is preferably ≥46 wt %.
本发明所述超长活化期双组份环氧底漆具体为灰色底漆。The ultra-long active period two-component epoxy primer of the present invention is specifically a gray primer.
本发明提供了上述技术方案所述超长活化期双组份环氧底漆的制备方法,包括以下步骤:The present invention provides a method for preparing the ultra-long active period two-component epoxy primer according to the above technical solution, comprising the following steps:
将水、分散剂、云母粉、钛白粉、硅灰石、滑石粉、炭黑与部分消泡剂混合后进行研磨,得到研磨料浆;将所述研磨料浆、JT-WBE522水性环氧乳液、助溶剂、增稠剂、润湿剂、硅烷偶联剂、防闪锈助剂与剩余消泡剂混合,得到所述A组分;Mix water, dispersant, mica powder, titanium dioxide, wollastonite, talc, carbon black and part of the defoamer and grind them to obtain a grinding slurry; mix the grinding slurry, JT-WBE522 water-based epoxy emulsion, cosolvent, thickener, wetting agent, silane coupling agent, anti-flash rust additive and the remaining defoamer to obtain the A component;
将3986固化剂、丙二醇甲醚与水混合,得到所述B组分。The 3986 curing agent, propylene glycol methyl ether and water are mixed to obtain the B component.
本发明将水、分散剂、云母粉、钛白粉、硅灰石、滑石粉、炭黑与部分消泡剂混合后进行研磨,得到研磨料浆。在本发明中,所述部分消泡剂优选为消泡剂总质量的30~35%。本发明优选将分散剂、云母粉、钛白粉、硅灰石、滑石粉、炭黑、部分水与部分消泡剂混合后研磨,然后采用剩余水冲磨,将研磨后以及冲磨后物料作为研磨料浆进行后续处理。在本发明中,所述部分水优选为水总质量的85~95%,更优选为88~91%。本发明优选在搅拌转速为300~500rpm(优选为400rpm)条件下,向所述部分水中依次加入分散剂与部分消泡剂,然后提高搅拌速率为500~700rpm(优选为600rpm),依次加入云母粉、钛白粉、硅灰石、滑石粉与炭黑,每加完一种试剂搅拌3~5min(优选为4min)再加下一种试剂,最后一种试剂加料完毕搅拌15~25min(优选为20min),之后将所得料浆置于研磨机中进行研磨。在本发明中,所述研磨过程中优选控制研磨温度≤50℃且研磨压力≤0.2MPa,每20min取样检测,研磨至细度≤20μm结束研磨,将所得料浆打入调和缸,并采用所述剩余水冲磨,将所得冲磨料浆打入所述调和缸,于所述调和缸中进行后续处理。The present invention mixes water, dispersant, mica powder, titanium dioxide, wollastonite, talc, carbon black and part of the defoamer and grinds them to obtain a grinding slurry. In the present invention, the part of the defoamer is preferably 30-35% of the total mass of the defoamer. The present invention preferably mixes dispersant, mica powder, titanium dioxide, wollastonite, talc, carbon black, part of the water and part of the defoamer and grinds them, then uses the remaining water to grind, and uses the ground and washed materials as grinding slurry for subsequent treatment. In the present invention, the part of the water is preferably 85-95% of the total mass of the water, and more preferably 88-91%. The present invention preferably adds dispersant and part of defoamer to the water in sequence under the condition of stirring speed of 300-500rpm (preferably 400rpm), then increases stirring speed to 500-700rpm (preferably 600rpm), adds mica powder, titanium dioxide, wollastonite, talcum powder and carbon black in sequence, stirs for 3-5min (preferably 4min) after adding each reagent, and then adds the next reagent, stirs for 15-25min (preferably 20min) after the last reagent is added, and then places the obtained slurry in a grinder for grinding. In the present invention, the grinding process preferably controls the grinding temperature ≤50°C and the grinding pressure ≤0.2MPa, samples are taken for detection every 20min, and grinding is terminated when the fineness is ≤20μm, the obtained slurry is put into a blending cylinder, and the remaining water is used for grinding, the obtained grinding slurry is put into the blending cylinder, and subsequent treatment is carried out in the blending cylinder.
得到研磨料浆后,本发明将将所述研磨料浆、JT-WBE522水性环氧乳液、助溶剂、增稠剂、润湿剂、硅烷偶联剂、防闪锈助剂与剩余消泡剂混合,得到所述A组分。本发明优选向所述研磨浆料中加入JT-WBE522水性环氧乳液,在400~500rm(优选为450rpm)条件下搅拌5~15min(优选为10min),之后依次加入剩余消泡剂、全部润湿剂、全部助溶剂、全部增稠剂、全部硅烷偶联剂以及全部防闪锈助剂,每加完一种试剂搅拌3~5min(优选为4min)再加下一种试剂,最后一种试剂加料完毕搅拌10~20min(优选为15min),之后经100目滤网过滤,得到所述A组分。After obtaining the grinding slurry, the present invention mixes the grinding slurry, JT-WBE522 water-based epoxy emulsion, cosolvent, thickener, wetting agent, silane coupling agent, anti-flash rust aid and remaining defoamer to obtain the A component. The present invention preferably adds JT-WBE522 water-based epoxy emulsion to the grinding slurry, stirs for 5 to 15 minutes (preferably 10 minutes) at 400 to 500 rm (preferably 450 rpm), and then sequentially adds the remaining defoamer, all wetting agents, all cosolvents, all thickeners, all silane coupling agents and all anti-flash rust aids, stirs for 3 to 5 minutes (preferably 4 minutes) after each reagent is added, and then adds the next reagent, stirs for 10 to 20 minutes (preferably 15 minutes) after the last reagent is added, and then filtered through a 100-mesh filter to obtain the A component.
本发明将3986固化剂、丙二醇甲醚与水混合,得到所述B组分。本发明优选在搅拌速率为350~450rpm(优选为400rpm)条件下,向所述水中依次加入丙二醇甲醚与3986固化剂,每加完一种试剂搅拌3~5min(优选为4min)再加下一种试剂,最后一种试剂加料完毕搅拌15~25min(优选为20min),之后经100目滤网过滤,得到所述B组分。The present invention mixes 3986 curing agent, propylene glycol methyl ether and water to obtain the B component. The present invention preferably adds propylene glycol methyl ether and 3986 curing agent to the water in sequence under the condition of a stirring rate of 350 to 450 rpm (preferably 400 rpm), stirs for 3 to 5 minutes (preferably 4 minutes) after adding each reagent, and then adds the next reagent, stirs for 15 to 25 minutes (preferably 20 minutes) after the last reagent is added, and then filters through a 100-mesh filter to obtain the B component.
本发明提供了上述技术方案所述超长活化期双组份环氧底漆或上述技术方案所述制备方法制备得到的超长活化期双组份环氧底漆在变压器淋涂中的应用。The present invention provides the use of the ultra-long activation period two-component epoxy primer described in the above technical solution or the ultra-long activation period two-component epoxy primer prepared by the preparation method described in the above technical solution in transformer spray coating.
下面将结合本发明中的实施例,对本发明中的技术方案进行清楚、完整地描述。显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the present invention will be described clearly and completely below in conjunction with the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
以下实施例中所用试剂来源如表1所示:The sources of the reagents used in the following examples are shown in Table 1:
表1实施例中所用试剂来源Table 1 Sources of reagents used in the examples
实施例1~5Embodiments 1 to 5
实施例1~5中双组份环氧底漆的配方如表2所示,制备方法如下:The formula of the two-component epoxy primer in Examples 1 to 5 is shown in Table 2, and the preparation method is as follows:
在搅拌转速为400rpm条件下,向部分去离子水(记为1#)中依次加入分散剂(记为2#)与部分消泡剂(记为3#),提高搅拌转速为600rpm,依次加入云母粉(记为4#)、钛白粉(记为5#)、硅灰石(记为6#)、滑石粉(记为7#)与炭黑(记为8#),每加完一种试剂搅拌4min再加下一种试剂,最后一种试剂加料完毕搅拌20min,得到前练料浆;Under the condition of stirring speed of 400rpm, dispersant (denoted as 2#) and part of defoamer (denoted as 3#) were added to part of deionized water (denoted as 1#) in sequence, and the stirring speed was increased to 600rpm. Mica powder (denoted as 4#), titanium dioxide (denoted as 5#), wollastonite (denoted as 6#), talcum powder (denoted as 7#) and carbon black (denoted as 8#) were added in sequence. After adding each reagent, the mixture was stirred for 4min before adding the next reagent. After the last reagent was added, the mixture was stirred for 20min to obtain the pre-training slurry.
将所述前练料浆置于研磨机中进行研磨,控制研磨温度小于50℃且研磨压力小于0.2MPa,每20min取样检测,研磨至细度≤20μm结束研磨,将所得料浆打入调和缸,并采用剩余去离子水(记为9#)冲磨,将所得冲磨料浆打入所述调和缸;The pre-refined slurry is placed in a grinder for grinding, the grinding temperature is controlled to be less than 50°C and the grinding pressure is less than 0.2MPa, sampling is performed every 20 minutes, and grinding is completed when the fineness is ≤20μm. The obtained slurry is put into a blending tank, and the remaining deionized water (recorded as 9#) is used for grinding, and the obtained ground slurry is put into the blending tank;
向所述调和缸中加入JTWBE522环氧乳液(记为10#),在450rpm条件下搅拌10min,然后依次加入剩余消泡剂(记为11#)、全部润湿剂(记为12#)、全部助溶剂DPNB(记为13#)、全部助溶剂DPM(记为14#)、全部增稠剂(记为15#)、全部硅烷偶联剂(记为16#)以及全部防闪锈助剂(记为17#),每加完一种试剂搅拌4min再加下一种试剂,最后一种试剂加料完毕搅拌15min,之后经100目滤网过滤,得到A组分(质控项目:外观要求表面色调均匀一致,无颗粒;固体含量≥46wt%;细度≤30μm);Add JTWBE522 epoxy emulsion (recorded as 10#) to the blending cylinder, stir at 450rpm for 10min, then add the remaining defoamer (recorded as 11#), all wetting agents (recorded as 12#), all cosolvents DPNB (recorded as 13#), all cosolvents DPM (recorded as 14#), all thickeners (recorded as 15#), all silane coupling agents (recorded as 16#) and all anti-flash rust additives (recorded as 17#) in sequence, stir for 4min after adding each reagent and then add the next reagent, stir for 15min after adding the last reagent, and then filter through a 100-mesh filter to obtain component A (quality control items: appearance requires uniform surface color without particles; solid content ≥46wt%; fineness ≤30μm);
在搅拌转速为400rpm条件下,按照3986固化剂、丙二醇甲醚(PM)与去离子水的质量比为20:5:20,向去离子水中依次加入丙二醇甲醚与3986固化剂,每加完一种试剂搅拌4min再加下一种试剂,最后一种试剂加料完毕搅拌20min,之后经100目滤网过滤,得到B组分(质控项目:外观要求表面色调均匀一致,无颗粒;固体含量≥20wt%)。Under the condition of stirring speed of 400rpm, according to the mass ratio of 3986 curing agent, propylene glycol methyl ether (PM) and deionized water of 20:5:20, propylene glycol methyl ether and 3986 curing agent were added to deionized water in sequence. After adding each reagent, stir for 4min before adding the next reagent. After adding the last reagent, stir for 20min, and then filter through a 100-mesh filter to obtain component B (quality control items: appearance requires uniform surface color and no particles; solid content ≥20wt%).
表2实施例1~5中双组份环氧底漆的配方Table 2 Formulation of two-component epoxy primer in Examples 1 to 5
对比例1~5Comparative Examples 1 to 5
对比例1~5中双组份环氧底漆的配方如表3所示,制备方法与实施例1相似,主要区别在于将实施例1中“JTWBE522环氧乳液”替换为“联固化学2092环氧乳液”。The formula of the two-component epoxy primer in Comparative Examples 1 to 5 is shown in Table 3. The preparation method is similar to that in Example 1, the main difference being that the "JTWBE522 epoxy emulsion" in Example 1 is replaced by "United Curing Science 2092 epoxy emulsion".
表3对比例1~5中双组份环氧底漆的配方Table 3 Formula of two-component epoxy primer in Comparative Examples 1 to 5
测试例1Test Example 1
将各实施例以及对比例制备的双组份环氧底漆的活化期与耐盐雾性进行测试,其中活化期依据双组份环氧底漆的粘度变化和漆膜性能改变确定(具体是当双组份环氧底漆的粘度翻倍且漆膜的耐酸性、耐碱性、附着力、弯曲、冲击、光泽与耐盐雾性能降低,则判断到达活化期),耐盐雾性依据GB/T 1771-2007方法测试,结果如表4所示。由表4可知,实施例1~5中双组份环氧底漆的活化期长,且耐盐雾性能够满足要求,考虑性价比,实施例2中双组份环氧底漆为最佳配方。而各对比例中双组份环氧底漆的耐盐雾性虽然也能够基本满足要求,但活化期明显低于相应的实施例。The activation period and salt spray resistance of the two-component epoxy primers prepared in each embodiment and comparative example were tested, wherein the activation period was determined based on the viscosity change of the two-component epoxy primer and the change in the performance of the paint film (specifically, when the viscosity of the two-component epoxy primer doubles and the acid resistance, alkali resistance, adhesion, bending, impact, gloss and salt spray resistance of the paint film decrease, it is judged that the activation period has been reached), and the salt spray resistance was tested according to the GB/T 1771-2007 method, and the results are shown in Table 4. As can be seen from Table 4, the activation period of the two-component epoxy primers in Examples 1 to 5 is long, and the salt spray resistance can meet the requirements. Considering the cost-effectiveness, the two-component epoxy primer in Example 2 is the best formula. Although the salt spray resistance of the two-component epoxy primers in each comparative example can basically meet the requirements, the activation period is significantly lower than that of the corresponding embodiment.
表4各实施例与对比例中双组份环氧底漆的性能测试数据Table 4 Performance test data of two-component epoxy primer in each embodiment and comparative example
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention. It should be pointed out that for ordinary technicians in this technical field, several improvements and modifications can be made without departing from the principle of the present invention. These improvements and modifications should also be regarded as the scope of protection of the present invention.
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| CN115353795A (en) * | 2022-09-05 | 2022-11-18 | 深圳职业技术学院 | High-resistance water-based epoxy zinc-rich primer and preparation method thereof |
| CN116694189A (en) * | 2023-06-30 | 2023-09-05 | 聚涂科技(东莞)有限公司 | Wet-on-wet waterborne epoxy primer and preparation method thereof |
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