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CN117703375A - Preparation system and method of coal-based high-density fuel - Google Patents

Preparation system and method of coal-based high-density fuel Download PDF

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Publication number
CN117703375A
CN117703375A CN202311867833.3A CN202311867833A CN117703375A CN 117703375 A CN117703375 A CN 117703375A CN 202311867833 A CN202311867833 A CN 202311867833A CN 117703375 A CN117703375 A CN 117703375A
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hydrogen
catalytic layer
coal
inlet
outlet
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吴志强
王晶
郭伟
杨盼曦
俞尊义
李红强
杨伯伦
李明杰
魏进家
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Xian Jiaotong University
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Xian Jiaotong University
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21CMINING OR QUARRYING
    • E21C37/00Other methods or devices for dislodging with or without loading
    • E21C37/16Other methods or devices for dislodging with or without loading by fire-setting or by similar methods based on a heat effect
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21CMINING OR QUARRYING
    • E21C37/00Other methods or devices for dislodging with or without loading
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21CMINING OR QUARRYING
    • E21C41/00Methods of underground or surface mining; Layouts therefor
    • E21C41/16Methods of underground mining; Layouts therefor
    • E21C41/18Methods of underground mining; Layouts therefor for brown or hard coal
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21FSAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
    • E21F17/00Methods or devices for use in mines or tunnels, not covered elsewhere

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  • Mining & Mineral Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention belongs to the technical field of underground coal pyrolysis, and particularly discloses a preparation system and a preparation method of coal-based high-density fuel, wherein a high-temperature mixed heat carrier is introduced into a coal seam for crack pyrolysis, an oil-gas mixture formed is enriched and then transported to a first catalyst layer for primary hydrogenation and upgrading to obtain a first product, and the first product is extracted to a first rectifying tower and is divided into a light fraction product, a heavy fraction product and an oil-gas product; introducing the heavy fraction product into a second catalytic layer, carrying out heavy fraction hydrogenation upgrading, and then conveying to a third catalytic layer for saturated hydrogenation to obtain an oil gas product; introducing the light fraction product into a third catalytic layer for tar saturation hydrogenation to obtain an oil gas product; the oil gas product enters a second rectifying tower, and the second rectifying tower is used for separating to obtain the high-density fuel. Solves the problems of shortage of petroleum resources, heavy weight and poor stability of pure coal-based jet fuel, and the obtained coal-based high-density fuel has the characteristics of coal-based and petroleum-based fuel oil and meets the requirements of future high-performance aircrafts.

Description

Preparation system and method of coal-based high-density fuel
Technical Field
The invention belongs to the technical field of underground pyrolysis of coal, and particularly relates to a preparation system and method of coal-based high-density fuel.
Background
With the continuous expansion of the international air transportation industry, the demand for aviation fuel is increasingly urgent. Currently aviation jet fuel is produced primarily from petroleum-based feedstocks. At present, the global situation is relatively unstable, and the energy safety is an important guarantee and demand for development in China.
The existing technology using coal-based oil as raw material is that after coal exploitation, hydrofining or hydrocracking is carried out, then distillation and cutting are carried out on the product, and jet fuel characteristic fraction is cut and taken as jet fuel or jet fuel blending component, and the stability of the jet fuel characteristic fraction obtained at this time is poor.
Disclosure of Invention
The invention aims to provide a preparation system and a preparation method of coal-based high-density fuel, which are used for solving the problem that the stability of the obtained jet fuel characteristic fraction serving as jet fuel or jet fuel blending component is poor when the product is distilled and cut after hydrofining or hydrocracking is carried out after coal exploitation.
In order to achieve the above purpose, the invention is realized by adopting the following technical scheme:
in a first aspect, the present invention provides a system for preparing a coal-based high density fuel, comprising:
the device comprises an injection well, a first catalytic layer, a second catalytic layer, a third catalytic layer, a pumping well, an enrichment well, a hybrid heater, a hybrid pressurizer, a gas separation device, a hydrogen supply module, a first rectifying tower, a second rectifying tower, a hydrogen pressurizer and a hydrogen heater;
the outlet of the mixing heater is connected with the inlet of the mixing pressurizer, the outlet of the mixing pressurizer is connected with the injection well, and the injection well, the third catalytic layer and the extraction well are arranged in the coal seam; the first catalytic layer and the second catalytic layer are arranged at the stratum below the lower boundary of the coal seam;
the enrichment well is closely arranged at the bottom of the lower boundary of the coal bed, the enrichment well is connected with a first inlet of the first catalytic layer, a first outlet of the first catalytic layer is connected with an inlet of the first rectifying tower, an outlet of the second catalytic layer is connected with an inlet of the third catalytic layer, and an outlet of the third catalytic layer is connected with an inlet of the second rectifying tower;
the first outlet of the first rectifying tower is connected with the first inlet of the second catalytic layer, the second outlet of the first rectifying tower is connected with the first inlet of the third catalytic layer, and the third outlet of the first rectifying tower is connected with the inlet of the second rectifying tower;
the outlet of the second catalytic layer is connected with the inlet of the third catalytic layer, the outlet of the third catalytic layer is connected with the inlet of the second rectifying tower, the outlet of the second rectifying tower is connected with the inlet of the gas separation device, the outlet of the gas separation device is respectively connected with the inlet of the hybrid heater and the inlets of the three hydrogen heaters, and the outlets of the three hydrogen heaters are respectively connected with the inlets of the corresponding hydrogen pressurizer; the outlets of the three hydrogen pressurizers are respectively connected with three hydrogen supply pipelines, and are respectively connected with the second inlet of the first catalytic layer, the second inlet of the second catalytic layer and the second inlet of the third catalytic layer through the three hydrogen supply pipelines; the outlet of the hydrogen supply module is connected with the gas separation device.
Furthermore, the injection well and the extraction well are perpendicular to the ground, and are arranged from the upper boundary of the coal bed to the lower boundary of the coal bed in the coal bed.
Further, the first catalytic layer and the second catalytic layer are parallel to the ground and are arranged at the stratum below the lower boundary of the coal seam, and the first catalytic layer is arranged at the lower part of the second catalytic layer; the third catalytic layer is perpendicular to the ground and is arranged in the coal seam.
Further, the first catalytic layer is an iron-molybdenum catalyst layer for primary hydrogenation upgrading; the second catalytic layer is a nickel-molybdenum catalyst layer for heavy fraction hydrogenation upgrading; the third catalytic layer is a nickel-molybdenum catalyst layer for tar saturation hydrogenation.
Further, the hydrogen heater comprises a first hydrogen heater, a second hydrogen heater and a third hydrogen heater; the hydrogen pressurizer comprises a first hydrogen pressurizer, a second hydrogen pressurizer and a third hydrogen pressurizer; the hydrogen supply pipeline comprises a first hydrogen supply pipeline, a second hydrogen supply pipeline and a third hydrogen supply pipeline; the outlet of the gas separation device is respectively connected with inlets of the mixing heater, the first hydrogen heater, the second hydrogen heater and the third hydrogen heater; the outlet of the first hydrogen heater is connected with the inlet of the first hydrogen pressurizer, the outlet of the first hydrogen pressurizer is connected with a first hydrogen supply pipeline, and the first hydrogen supply pipeline is connected with the first catalytic layer and is used for supplying hydrogen to the first catalytic layer; the outlet of the second hydrogen heater is connected with the inlet of the second hydrogen pressurizer, the outlet of the second hydrogen pressurizer is connected with a second hydrogen supply pipeline, and the second hydrogen supply pipeline is connected with the second catalytic layer and is used for supplying hydrogen to the second catalytic layer; the outlet of the third hydrogen heater is connected with the inlet of the third hydrogen pressurizer, the outlet of the third hydrogen pressurizer is connected with a third hydrogen supply pipeline, and the third hydrogen supply pipeline is connected with the third catalytic layer and is used for supplying hydrogen to the third catalytic layer.
Furthermore, the hydrogen production module comprises two vertical wells and the bottom of the two vertical wells, wherein the two vertical wells are communicated with the bottom of the two vertical wells through horizontal wells, a methanation catalyst filling layer is arranged in the horizontal wells, methane steam reforming catalyst filling layers are arranged in the middle parts of the two vertical wells, and air outlets of the two vertical wells are connected with an inlet of the gas separation device.
In a second aspect, the present invention provides a method for preparing a coal-based high density fuel, based on the preparation system of the coal-based high density fuel described in any one of the above, comprising:
the method comprises the steps of mining an injection well and a drainage well, arranging a hydrogen production module, and fracturing a coal bed to form a coal bed fracture; a third catalytic layer is vertically arranged in the coal seam, and a first catalytic layer and a second catalytic layer are arranged at the stratum below the lower boundary of the coal seam;
CO 2 and H 2 O is mixed and heated in a mixing heater, and then is introduced into a mixing pressurizer, a high-temperature mixed heat carrier is formed after pressurization, the high-temperature mixed heat carrier is introduced into a coal seam crack through an injection well, the coal seam is heated and pyrolyzed, and an oil-gas mixture is generated;
H 2 heating and pressurizing three sets of hydrogen heaters and hydrogen pressurizers which are mutually independent to working conditions, and then introducing 3 catalyst layers through respective hydrogen supply pipelines to supply hydrogen;
enriching the oil-gas mixture at an enrichment well, transporting the oil-gas mixture to a first catalyst layer for primary hydrogenation upgrading, extracting an obtained first product to a first rectifying tower for prefractionation, and dividing the first product into a light fraction product, a heavy fraction product and an oil-gas product;
conveying the heavy fraction product to a second catalytic layer, conveying the light fraction product to a third catalytic layer, and conveying the residual oil gas product to a second rectifying tower;
the heavy fraction product is fed into a second catalytic layer, heavy fraction hydrogenation upgrading is carried out firstly, and tar after heavy fraction hydrogenation upgrading is completed is conveyed to a third catalytic layer for saturated hydrogenation, so that an oil gas product is obtained;
introducing the light fraction product into a third catalytic layer for tar saturation hydrogenation to obtain an oil gas product;
the oil gas product enters a second rectifying tower, the second rectifying tower is used for separating to obtain diesel oil, high-density fuel, phenol oil and mixed gas, the mixed gas is continuously conveyed to a gas separation device for separation, pyrolysis gas is separated, and the separated pyrolysis gas is conveyed to a mixed heater and three hydrogen heaters for recycling;
and enabling gas phase products generated by coal bed pyrolysis to enter a hydrogen production module to perform methanation reaction and methane steam reforming reaction, extracting the gas to a gas separation device for separation, and enabling separated hydrogen to be used for subsequently introducing the first catalytic layer, the second catalytic layer and the third catalytic layer for reaction.
Further, the first catalyst layer is located 810-830 meters below the ground, the second catalyst layer is located 490 meters below the ground, and the third catalyst layer is located 170 meters below the ground.
Furthermore, the gas phase product generated by pyrolysis enters the horizontal well to perform methanation reaction and methane steam reforming reaction with the methanation catalyst filling layer and the methane steam reforming catalyst filling layer.
Further, the reaction conditions of the primary hydrogenation upgrading are as follows: 320-420 ℃ and 20MPa, wherein the catalyst adopts an iron-molybdenum catalyst; the reaction conditions for hydrogenating and upgrading the heavy fraction are as follows: 180-300 ℃ and 12MPa, and a nickel-molybdenum catalyst is adopted as the catalyst; the reaction conditions of the tar saturation hydrogenation are as follows: 360-400 ℃ and 4.2MPa, and the catalyst adopts a nickel-molybdenum catalyst.
The invention has at least the following beneficial effects:
the invention exploits the injection well, set up multiple catalytic layers in coal seam and stratum, let the high-temperature mixed heat carrier into the seam fracture from the injection well, pyrolyze and form the oil-gas mixture, the oil-gas mixture is transported to the first catalytic layer and hydrogenated and upgraded in the first step after enriching the well and get the first product, the first product is extracted to the first rectifying tower, carry on the prefractionation, divide into light fraction product, heavy fraction product and oil-gas product; the heavy fraction product is fed into a second catalytic layer, heavy fraction hydrogenation upgrading is carried out firstly, and tar after heavy fraction hydrogenation upgrading is completed is conveyed to a third catalytic layer for saturated hydrogenation, so that an oil gas product is obtained; introducing the light fraction product into a third catalytic layer for tar saturation hydrogenation to obtain an oil gas product; the oil gas product enters a second rectifying tower, and the second rectifying tower is used for separating to obtain the high-density fuel. Solves the problems of shortage of petroleum resources, heavy weight and poor stability of pure coal-based jet fuel, and the obtained coal-based high-density fuel has the characteristics of coal-based and petroleum-based fuel oil and meets the requirements of future high-performance aircrafts.
2. The invention can directly upgrade tar underground without carrying out process operation on the ground after extraction and separation; avoiding the transportation and processing of tar products, improving the industrial process efficiency and reducing the energy consumption.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the invention.
In the drawings:
FIG. 1 is a schematic diagram of a system for preparing a coal-based high density fuel;
reference numerals: 1. an injection well; 2. an upper boundary of the coal seam; 3. a coal seam; 4. a lower boundary of the coal seam; 5. a first catalytic layer; 6. a second catalytic layer; 7. a third catalytic layer; 8. extracting well; 9. an enrichment well; 10. a hybrid heater; 11. a mixing pressurizer; 12. a gas separation device; 13. a hydrogen production module; 131. a methane steam reforming catalyst packing layer; 132. a methanation catalyst packing layer; 14. a first rectifying column; 15. a second rectifying column; 51. a first hydrogen heater; 61. a second hydrogen heater; 71. a third hydrogen heater; 52. a first hydrogen pressurizer; 62. a second hydrogen pressurizer; 72. a third hydrogen pressurizer; 53. a first hydrogen supply pipe; 63. a second hydrogen supply pipe; 73. and a third hydrogen supply pipeline.
Detailed Description
The invention will be described in detail below with reference to the drawings in connection with embodiments. It should be noted that, without conflict, the embodiments of the present invention and features of the embodiments may be combined with each other.
The following detailed description is exemplary and is intended to provide further details of the invention. Unless defined otherwise, all technical terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments in accordance with the invention.
Example 1
As shown in fig. 1, a system for preparing a coal-based high density fuel, comprising:
injection well 1, first catalytic layer 5, second catalytic layer 6, third catalytic layer 7, extraction well 8, enrichment well 9, mixing heater 10, mixing pressurizer 11, gas separation device 12, hydrogen supply module 13, first rectifying tower 14, second rectifying tower 15, hydrogen pressurizer and hydrogen heater;
the outlet of the mixing heater 10 is connected with the inlet of the mixing pressurizer 11, and the outlet of the mixing pressurizer 11 is connected with the injection well 1; CO 2 And H 2 O is mixed and heated in a mixing heater 10 and then is introduced into a mixing pressurizer 11, a high-temperature mixed heat carrier is formed after pressurization, the high-temperature mixed heat carrier is introduced into a coal seam crack through an injection well 1, and CO 2 For heating coal seams, H 2 O is used for providing a hydrogen-rich environment for pyrolysis of the coal seam; hybrid heater 10 is used for CO 2 And H 2 O is heated at high temperature, and the mixing pressurizer 11 is used for pressurizing the hydrogen and the water vapor heated at high temperature to form a high-temperature mixed heat carrier.
The injection well 1 and the extraction well 8 are vertical to the ground, and are arranged from the upper boundary 2 of the coal bed to the lower boundary 4 of the coal bed in the coal bed 3; fracturing the coal seam 3 to form cracks, and injecting a heated and pressurized high-temperature mixed heat carrier into the injection well 1, wherein the high-temperature mixed heat carrier is pyrolyzed in the cracks of the coal seam to obtain an oil-gas mixture; the extraction well 8 is used for extracting the catalyzed enriched product.
The first catalytic layer 5 and the second catalytic layer 6 are parallel to the ground and are arranged at the stratum below the lower boundary 4 of the coal seam, and the first catalytic layer 5 is arranged at the lower part of the second catalytic layer 6; the third catalytic layer 7 is vertical to the ground and is arranged inside the coal seam 3; the first catalytic layer 5 is an iron-molybdenum catalyst layer for primary hydrogenation upgrading of tar; the second catalytic layer 6 is a nickel-molybdenum catalyst layer for hydrocracking the pyrolysis tar heavy fraction; the third catalytic layer 7 is a nickel-molybdenum catalyst layer for tar saturation hydrogenation;
the enrichment well 9 is arranged close to the bottom of the coal bed lower boundary 4 and is used for collecting the pyrolyzed oil-gas mixture; the enrichment well 9 is connected with a first inlet of the first catalytic layer 5, an outlet of the first catalytic layer 5 is connected with an inlet of the first rectifying tower 14, an outlet of the second catalytic layer 6 is connected with an inlet of the third catalytic layer 9, and an outlet of the third catalytic layer 9 is connected with an inlet of the second rectifying tower 15;
the first outlet of the first rectifying tower 14 is connected with the first inlet of the second catalytic layer 6, the second outlet of the first rectifying tower 14 is connected with the first inlet of the third catalytic layer 7, and the third outlet of the first rectifying tower 14 is connected with the inlet of the second rectifying tower 15; the first rectifying tower 14 is arranged at the bottom of the extraction well 8, and the second rectifying tower 15 is arranged on the ground.
The outlet of the second catalytic layer 6 is connected with the inlet of the third catalytic layer 7, the outlet of the third catalytic layer 7 is connected with the inlet of the second rectifying tower 15, the outlet of the second rectifying tower 15 is connected with the inlet of the gas separation device 12, the outlet of the gas separation device 12 is respectively connected with the inlet of the hybrid heater 10 and the inlets of the three hydrogen heaters, and the outlets of the three hydrogen heaters are respectively connected with the inlets of the corresponding hydrogen pressurizers; the outlets of the three hydrogen pressurizers are respectively connected with three hydrogen supply pipelines, and are respectively connected with the second inlet of the first catalytic layer 5, the second inlet of the second catalytic layer 6 and the second inlet of the third catalytic layer 7 through three hydrogen supply pipelines 11.
The hydrogen heaters include a first hydrogen heater 51, a second hydrogen heater 61, and a third hydrogen heater 71; the hydrogen pressurizer includes a first hydrogen pressurizer 52, a second hydrogen pressurizer 62 and a third hydrogen pressurizer 72; the hydrogen supply pipes include a first hydrogen supply pipe 53, a second hydrogen supply pipe 63, and a third hydrogen supply pipe 73; the outlets of the gas separation device 12 are respectively connected with inlets of the mixing heater 10, the first hydrogen heater 51, the second hydrogen heater 61 and the third hydrogen heater 71; the outlet of the first hydrogen heater 51 is connected with the inlet of the first hydrogen pressurizer 52, the outlet of the first hydrogen pressurizer 52 is connected with the first hydrogen supply pipeline 53, and the first hydrogen supply pipeline 53 is connected with the first catalytic layer 5 and is used for supplying hydrogen to the first catalytic layer 5; the outlet of the second hydrogen heater 61 is connected with the inlet of the second hydrogen pressurizer 62, the outlet of the second hydrogen pressurizer 62 is connected with a second hydrogen supply pipeline 63, and the second hydrogen supply pipeline 63 is connected with the second catalytic layer 6 and is used for supplying hydrogen to the second catalytic layer 6; the outlet of the third hydrogen heater 71 is connected to the inlet of the third hydrogen pressurizer 72, the outlet of the third hydrogen pressurizer 72 is connected to the third hydrogen supply pipe 73, and the third hydrogen supply pipe 73 is connected to the third catalytic layer 7 for supplying hydrogen to the third catalytic layer 7.
The methane gas separation device further comprises a hydrogen production module 13, the hydrogen production module 13 comprises two vertical wells, the bottoms of the two vertical wells are communicated through a horizontal well, a methanation catalyst filling layer 132 is arranged in the horizontal well, methane steam reforming catalyst filling layers 131 are arranged in the middle of the two vertical wells, and gas outlets of the two vertical wells are connected with an inlet of the gas separation device 12.
When the hydrogen production module 13 works, the coal bed 3 is heated by the heat released by the combustion of the coal bed, the gas phase products generated by the pyrolysis gather towards the upper part of the coal bed 3 due to the action of gravity, the gas phase products enter a horizontal well to perform methanation reaction and methane steam reforming reaction with the methanation catalyst filling layer 132 and the methane steam reforming catalyst filling layer 131, then are extracted to the gas separation device 12 for separation, and the separated hydrogen is used for subsequent reaction of the first catalytic layer 5, the second catalytic layer 6 and the third catalytic layer 7.
Example 2
A method for preparing a coal-based high density fuel, comprising:
s1: the method comprises the steps of (1) mining an injection well and a drainage well, wherein a hydrogen production module 13 is arranged, and fracturing a coal seam 3 to form a coal seam crack; a third catalytic layer 7 is vertically arranged in the coal seam 3, a first catalytic layer 5 and a second catalytic layer 6 are arranged below the lower boundary 4 of the coal seam, and the first catalytic layer 5 is arranged below the second catalytic layer 6;
the first catalytic layer 5 is an iron-molybdenum catalyst layer 1 for primary hydrogenation upgrading of tar; the second catalytic layer 6 is a nickel-molybdenum catalyst layer 2 for hydrocracking pyrolysis tar heavy fraction; the third catalytic layer 7 is a nickel-molybdenum catalyst layer 3 for tar saturation hydrogenation;
S2:CO 2 and H 2 O is mixed and heated in a mixing heater 10 at 600 ℃, then is introduced into a mixing pressurizer 11, a high-temperature mixed heat carrier is formed after the pressure is increased to 4MPa-6MPa, the high-temperature mixed heat carrier is introduced into a coal seam crack through an injection well 1, and a coal seam 3 undergoes an in-situ pyrolysis reaction under the heating of the high-temperature mixed heat carrier to generate an oil-gas mixture; CO 2 For heating coal seams, H 2 O is used for providing a hydrogen-rich environment for pyrolysis of the coal seam;
S3:H 2 from three sets of hydrogen heaters and hydrogen pressurizers which are independent to each other to heat and pressurizeAfter working conditions, 3 catalyst layers are introduced through respective hydrogen supply pipelines to supply hydrogen;
specific: h 2 The first hydrogen heater 51, the second hydrogen heater 61, the third hydrogen heater 71, the first hydrogen pressurizer 52, the second hydrogen pressurizer 62 and the third hydrogen pressurizer 72 are heated and pressurized, and then are conveyed into the first hydrogen supply pipeline 53, the second hydrogen supply pipeline 63 and the third hydrogen supply pipeline 73, and are correspondingly conveyed into the first catalytic layer 5, the second catalytic layer 6 and the third catalytic layer 7 through different hydrogen supply pipelines;
the oil-gas mixture is enriched at an enrichment well 9 at the bottom of the coal bed and transported to a first catalyst layer 5 for primary hydrogenation and upgrading, the obtained first product is extracted to a first rectifying tower 14 for prefractionation, the heavy fraction product is transported to a second catalyst layer 6, the light fraction product is transported to a third catalyst layer 7, and the residual oil-gas product is transported to a second rectifying tower 15;
the first catalyst layer 5 is positioned at 810-830 m underground, and the reaction conditions of primary hydrogenation and upgrading are as follows: 320-420 ℃ and 20MPa, and the catalyst adopts an iron-molybdenum catalyst, namely H 2 Heating to 320-420 ℃ in the corresponding first hydrogen heater 51 and first hydrogen pressurizer 52 to 20MPa before being transported to the first catalyst layer 5;
the first product is cut in the first rectifying column 14, with the main products being three parts, a light fraction product, a heavy fraction product and an oil and gas product.
S4: the heavy fraction product is firstly subjected to heavy fraction hydrogenation upgrading by being led into a second catalytic layer 6; the second catalytic layer 6 is positioned under the ground by about 490 meters, and the heavy fraction hydrogenation and upgrading reaction conditions are as follows: 180-300 ℃ and 12MPa, and a nickel-molybdenum catalyst is adopted as the catalyst; conveying the tar after heavy fraction hydrogenation and upgrading to a third catalytic layer 7 for saturated hydrogenation to obtain an oil gas product, namely H 2 The second hydrogen heater 61 and the second hydrogen pressurizer 62 are heated to 180-300 ℃ and pressurized to 12MPa before being fed to the second catalytic layer 6.
Introducing the light fraction product into a third catalytic layer 7 for tar saturation hydrogenation to obtain an oil gas product; the third catalytic layer 7 is located about 170 m below the ground and is saturated with tarThe reaction conditions of hydrogenation are as follows: 360-400 ℃ and 4.2MPa, and the catalyst adopts nickel-molybdenum catalyst, namely H 2 Heating to 360-400 ℃ in the corresponding second heater 15 and second presser 16 to 4.2MPa before conveying to the third catalyst layer 7;
the oil gas product enters a second rectifying tower 15, the second rectifying tower 15 is used for separation to obtain diesel oil, high-density fuel, phenol oil and mixed gas, and the mixed gas is continuously conveyed into a gas separation device 12; the mixed gas is mainly micromolecular alkane and H 2 、H 2 O and CO 2 The gas is separated by the gas separator 12 to separate CO 2 、H 2 O and H 2 Wherein the separated CO 2 And H 2 O is conveyed to the mixing heater 10 for recycling, and the separated H is separated 2 Conveying the waste gas to three hydrogen heaters for recycling;
s5: when the hydrogen production module 13 works, the coal bed 3 is heated by the heat released by the combustion of the coal bed, the gas phase products generated by the pyrolysis gather towards the upper part of the coal bed 3 due to the action of gravity, the gas phase products enter a horizontal well to perform methanation reaction and methane steam reforming reaction with the methanation catalyst filling layer 132 and the methane steam reforming catalyst filling layer 131, then are extracted to the gas separation device 12 for separation, and the separated hydrogen is used for subsequent reaction of the first catalytic layer 5, the second catalytic layer 6 and the third catalytic layer 7.
Example 3
The rest structures of the preparation system of the coal-based high-density fuel are unchanged, and the first catalytic layer 5, the second catalytic layer 6 and the third catalytic layer 7 are arranged in the extraction well 8 to prepare the coal-based high-density fuel.
It will be appreciated by those skilled in the art that the present invention can be carried out in other embodiments without departing from the spirit or essential characteristics thereof. Accordingly, the above disclosed embodiments are illustrative in all respects, and not exclusive. All changes that come within the scope of the invention or equivalents thereto are intended to be embraced therein.
Finally, it should be noted that: the above embodiments are only for illustrating the technical aspects of the present invention and not for limiting the same, and although the present invention has been described in detail with reference to the above embodiments, it should be understood by those of ordinary skill in the art that: modifications and equivalents may be made to the specific embodiments of the invention without departing from the spirit and scope of the invention, which is intended to be covered by the claims.

Claims (10)

1.一种煤基高密度燃料的制备系统,其特征在于,包括:1. A preparation system for coal-based high-density fuel, which is characterized by including: 注入井(1)、第一催化层(5)、第二催化层(6)、第三催化层(7)、抽采井(8)、富集井(9)、混合加热器(10)、混合加压器(11)、气体分离装置(12)、供氢模块(13)、第一精馏塔(14)、第二精馏塔(15)、氢气加压器和氢气加热器;Injection well (1), first catalytic layer (5), second catalytic layer (6), third catalytic layer (7), extraction well (8), enrichment well (9), mixing heater (10) , mixing pressurizer (11), gas separation device (12), hydrogen supply module (13), first rectification tower (14), second rectification tower (15), hydrogen pressurizer and hydrogen heater; 混合加热器(10)的出口连接混合加压器(11)的入口,混合加压器(11)的出口连接注入井(1),注入井(1)、第三催化层(7)和抽采井(8)设置在煤层(3)内部;第一催化层(5)和第二催化层(6)开设在煤层下边界(4)以下地层处;The outlet of the mixing heater (10) is connected to the inlet of the mixing pressurizer (11), and the outlet of the mixing pressurizer (11) is connected to the injection well (1), the injection well (1), the third catalytic layer (7) and the extraction pump. The production well (8) is set inside the coal seam (3); the first catalytic layer (5) and the second catalytic layer (6) are set up in the stratum below the lower boundary of the coal seam (4); 富集井(9)紧贴煤层下边界(4)的底部设置,富集井(9)连接第一催化层(5)的第一入口,第一催化层(5)的第一出口连接第一精馏塔(14)的入口,第二催化层(6)的出口连接第三催化层(9)的入口,第三催化层(9)的出口连接第二精馏塔(15)的入口;The enrichment well (9) is arranged close to the bottom of the lower boundary (4) of the coal seam. The enrichment well (9) is connected to the first inlet of the first catalytic layer (5), and the first outlet of the first catalytic layer (5) is connected to the first catalytic layer (5). The inlet of a rectification tower (14), the outlet of the second catalytic layer (6) are connected with the inlet of the third catalytic layer (9), and the outlet of the third catalytic layer (9) is connected with the inlet of the second rectification tower (15) ; 第一精馏塔(14)的第一出口连接第二催化层(6)的第一入口相连,第一精馏塔(14)的第二出口连接第三催化层(7)的第一入口,第一精馏塔(14)的第三出口连接第二精馏塔(15)的入口;The first outlet of the first distillation tower (14) is connected to the first inlet of the second catalytic layer (6), and the second outlet of the first distillation tower (14) is connected to the first inlet of the third catalytic layer (7). , the third outlet of the first rectification tower (14) is connected to the inlet of the second rectification tower (15); 第二催化层(6)的出口连接第三催化层(7)的入口,第三催化层(7)的出口与第二精馏塔(15)的入口相连,第二精馏塔(15)的出口连接气体分离装置(12)的入口,气体分离装置(12)的出口分别连接混合加热器(10)的入口和三个氢气加热器的入口,三个氢气加热器的出口分别与对应的氢气加压器的入口相连;三个氢气加压器的出口分别连接三个供氢管道,通过三个供氢管道(11)分别与第一催化层(5)的第二入口、第二催化层(6)的第二入口、第三催化层(7)的第二入口相连;供氢模块(13)的出口与气体分离装置(12)相连。The outlet of the second catalytic layer (6) is connected with the inlet of the third catalytic layer (7), and the outlet of the third catalytic layer (7) is connected with the inlet of the second rectification tower (15). The second rectification tower (15) The outlet of the gas separation device (12) is connected to the inlet of the gas separation device (12). The outlet of the gas separation device (12) is respectively connected to the inlet of the mixing heater (10) and the inlet of the three hydrogen heaters. The outlets of the three hydrogen heaters are respectively connected with the corresponding ones. The inlets of the hydrogen pressurizers are connected; the outlets of the three hydrogen pressurizers are respectively connected to three hydrogen supply pipes, and are respectively connected to the second inlet of the first catalytic layer (5) and the second catalytic converter through the three hydrogen supply pipes (11). The second inlet of the layer (6) and the second inlet of the third catalytic layer (7) are connected; the outlet of the hydrogen supply module (13) is connected with the gas separation device (12). 2.根据权利要求1所述的一种煤基高密度燃料的制备系统,其特征在于,所述注入井(1)和抽采井(8)垂直于地面,在煤层(3)内部由煤层上边界(2)开设至煤层下边界(4)位置处。2. A kind of coal-based high-density fuel preparation system according to claim 1, characterized in that the injection well (1) and the extraction well (8) are perpendicular to the ground, and the coal seam (3) is formed by the coal seam. The upper boundary (2) is opened to the position of the lower boundary (4) of the coal seam. 3.根据权利要求1所述的一种煤基高密度燃料的制备系统,其特征在于,所述第一催化层(5)和第二催化层(6)平行于地面,开设在煤层下边界(4)以下地层处,第一催化层(5)设置在第二催化层(6)下部;第三催化层(7)垂直于地面,设置在煤层(3)内部。3. A coal-based high-density fuel preparation system according to claim 1, characterized in that the first catalytic layer (5) and the second catalytic layer (6) are parallel to the ground and are located at the lower boundary of the coal seam. (4) In the lower strata, the first catalytic layer (5) is arranged under the second catalytic layer (6); the third catalytic layer (7) is perpendicular to the ground and is arranged inside the coal seam (3). 4.根据权利要求3所述的一种煤基高密度燃料的制备系统,其特征在于,所述第一催化层(5)为用于初步加氢提质的铁钼催化剂层;第二催化层(6)为用于重馏分加氢提质的镍钼催化剂层;第三催化层(7)为用于焦油饱和加氢的镍钼催化剂层。4. A coal-based high-density fuel preparation system according to claim 3, characterized in that the first catalytic layer (5) is an iron-molybdenum catalyst layer used for preliminary hydrogenation and upgrading; the second catalytic layer Layer (6) is a nickel-molybdenum catalyst layer used for hydrogenation and upgrading of heavy distillates; the third catalytic layer (7) is a nickel-molybdenum catalyst layer used for tar saturated hydrogenation. 5.根据权利要求1所述的一种煤基高密度燃料的制备系统,其特征在于,所述氢气加热器包括第一氢气加热器(51)、第二氢气加热器(61)和第三氢气加热器(71);所述氢气加压器包括第一氢气加压器(52)、第二氢气加压器(62)和第三氢气加压器(72);供氢管道包括第一供氢管道(53)、第二供氢管道(63)和第三供氢管道(73);气体分离装置(12)的出口分别连接混合加热器(10)、第一氢气加热器(51)、第二氢气加热器(61)和第三氢气加热器(71)的入口;第一氢气加热器(51)的出口连接第一氢气加压器(52)的入口,第一氢气加压器(52)的出口连接第一供氢管道(53),第一供氢管道(53)连接第一催化层(5),用于给第一催化层(5)供氢;第二氢气加热器(61)的出口连接第二氢气加压器(62)的入口,第二氢气加压器(62)的出口连接第二供氢管道(63),第二供氢管道(63)连接第二催化层(6),用于给第二催化层(6)供氢;第三氢气加热器(71)的出口连接第三氢气加压器(72)的入口,第三氢气加压器(72)的出口连接第三供氢管道(73),第三供氢管道(73)连接第三催化层(7),用于给第三催化层(7)供氢。5. A coal-based high-density fuel preparation system according to claim 1, characterized in that the hydrogen heater includes a first hydrogen heater (51), a second hydrogen heater (61) and a third Hydrogen heater (71); the hydrogen pressurizer includes a first hydrogen pressurizer (52), a second hydrogen pressurizer (62) and a third hydrogen pressurizer (72); the hydrogen supply pipeline includes the first Hydrogen supply pipeline (53), second hydrogen supply pipeline (63) and third hydrogen supply pipeline (73); the outlet of the gas separation device (12) is connected to the mixing heater (10) and the first hydrogen heater (51) respectively. , the inlet of the second hydrogen heater (61) and the third hydrogen heater (71); the outlet of the first hydrogen heater (51) is connected to the inlet of the first hydrogen pressurizer (52), and the first hydrogen pressurizer The outlet of (52) is connected to the first hydrogen supply pipeline (53), and the first hydrogen supply pipeline (53) is connected to the first catalytic layer (5) for supplying hydrogen to the first catalytic layer (5); the second hydrogen heater The outlet of (61) is connected to the inlet of the second hydrogen pressurizer (62), the outlet of the second hydrogen pressurizer (62) is connected to the second hydrogen supply pipeline (63), and the second hydrogen supply pipeline (63) is connected to the second hydrogen supply pipeline (63). The catalytic layer (6) is used to supply hydrogen to the second catalytic layer (6); the outlet of the third hydrogen heater (71) is connected to the inlet of the third hydrogen pressurizer (72), and the third hydrogen pressurizer (72) ) is connected to the third hydrogen supply pipeline (73), and the third hydrogen supply pipeline (73) is connected to the third catalytic layer (7) for supplying hydrogen to the third catalytic layer (7). 6.根据权利要求1所述的一种煤基高密度燃料的制备系统,其特征在于,所述制氢模块(13)包括两根竖直井和底部之间通过水平井相连通,所述水平井内设有甲烷化催化剂填充层(132),两根所述竖直井的中部均设有甲烷水蒸气重整催化剂填充层(131),两根所述竖直井的出气口与气体分离装置(12)的入口相连。6. A coal-based high-density fuel preparation system according to claim 1, characterized in that the hydrogen production module (13) includes two vertical wells connected to the bottom by a horizontal well, and the A methanation catalyst filling layer (132) is provided in the horizontal well, and a methane steam reforming catalyst filling layer (131) is provided in the middle of the two vertical wells. The gas outlets of the two vertical wells are connected to the gas. The inlet of the separation device (12) is connected. 7.一种煤基高密度燃料的制备方法,其特征在于,基于权利要求1-6中任一项所述的一种煤基高密度燃料的制备系统,包括:7. A method for preparing coal-based high-density fuel, characterized in that, based on the preparation system of a coal-based high-density fuel according to any one of claims 1-6, it includes: 开采注入井(1)和抽采井(8),设置制氢模块(13),压裂煤层(3)形成煤层裂隙;在煤层(3)内部垂直安装第三催化层(7),在煤层下边界(4)以下地层处安装第一催化层(5)和第二催化层(6);The injection well (1) and extraction well (8) are mined, and a hydrogen production module (13) is installed to fracturing the coal seam (3) to form coal seam cracks; a third catalytic layer (7) is vertically installed inside the coal seam (3), and the The first catalytic layer (5) and the second catalytic layer (6) are installed at the stratum below the lower boundary (4); CO2和H2O在混合加热器(10)里混合加热后通入混合加压器(11),加压后形成高温混合热载体,高温混合热载体通过注入井(1)通入煤层裂隙,加热煤层并进行热解,生成油气混合物;CO 2 and H 2 O are mixed and heated in the mixing heater (10) and then passed into the mixing pressurizer (11). After pressurization, a high-temperature mixed heat carrier is formed, and the high-temperature mixed heat carrier is passed into the coal seam fissures through the injection well (1). , heating the coal seam and performing pyrolysis to generate an oil and gas mixture; H2从三套相互独立的氢气加热器和氢气加压器加热加压到工作条件后,经各自的供氢管道通入3个催化剂层供氢;After H2 is heated and pressurized to working conditions from three independent sets of hydrogen heaters and hydrogen pressurizers, it is passed into three catalyst layers to supply hydrogen through their respective hydrogen supply pipelines; 油气混合物在富集井(9)处进行富集并运输到第一催化剂层(5)进行初步加氢提质,获得的第一产物抽采至第一精馏塔(14),进行初步分馏,分为轻质馏分产品、重馏分产品和油气产品;The oil and gas mixture is enriched in the enrichment well (9) and transported to the first catalyst layer (5) for preliminary hydrogenation and upgrading. The obtained first product is extracted to the first distillation tower (14) for preliminary fractionation. , divided into light distillate products, heavy distillate products and oil and gas products; 将重馏分产品输送至第二催化层(6),将轻质馏分产品输送至第三催化层(7),剩余油气产品输送至第二精馏塔(15);Transport the heavy fraction products to the second catalytic layer (6), transport the light fraction products to the third catalytic layer (7), and transport the remaining oil and gas products to the second distillation tower (15); 重馏分产品通过通入第二催化层(6),先进行重馏分加氢提质,完成重馏分加氢提质后的焦油输送至第三催化层(7)进行饱和加氢,获得油气产品;The heavy fraction products pass through the second catalytic layer (6), and the heavy fraction is first hydrogenated and upgraded. After completing the heavy fraction hydrogenation and upgrading, the tar is transported to the third catalytic layer (7) for saturated hydrogenation to obtain oil and gas products. ; 轻质馏分产品通入第三催化层(7),进行焦油饱和加氢,获得油气产品;The light distillate products are passed into the third catalytic layer (7) to perform saturated hydrogenation of tar to obtain oil and gas products; 油气产品进入第二精馏塔(15),第二精馏塔(15)进行分离,获得柴油、高密度燃料、酚油和混合气体,混合气体继续输送至气体分离装置(12)中进行分离,分离出热解气,输送至混合加热器(10)和三个氢气加热器进行回收利用;The oil and gas products enter the second distillation tower (15), and the second distillation tower (15) performs separation to obtain diesel, high-density fuel, phenolic oil and mixed gas. The mixed gas is continued to be transported to the gas separation device (12) for separation. , separate the pyrolysis gas and transport it to the mixing heater (10) and three hydrogen heaters for recycling; 煤层(3)热解产生的气相产物进入制氢模块(13)发生甲烷化反应和甲烷水蒸气重整反应,采出至气体分离装置(12)进行分离,分离得到的氢气用于后续通入第一催化层(5)、第二催化层(6)和第三催化层(7)进行反应。The gas phase product produced by the pyrolysis of the coal seam (3) enters the hydrogen production module (13) to undergo methanation reaction and methane steam reforming reaction, and is extracted to the gas separation device (12) for separation. The separated hydrogen is used for subsequent injection. The first catalytic layer (5), the second catalytic layer (6) and the third catalytic layer (7) react. 8.根据权利要求7所述的一种煤基高密度燃料的制备方法,其特征在于,所述第一催化剂层(5)位于地下810-830米,所述第二催化层(6)位于地下490米,所述第三催化层(9)位于地下170米。8. A method for preparing coal-based high-density fuel according to claim 7, characterized in that the first catalyst layer (5) is located 810-830 meters underground, and the second catalytic layer (6) is located 810-830 meters underground. 490 meters underground, and the third catalytic layer (9) is located 170 meters underground. 9.根据权利要求7所述的一种煤基高密度燃料的制备方法,其特征在于,所述热解产生的气相产物进入水平井内与甲烷化催化剂填充层(132)和甲烷水蒸气重整催化剂填充层(131)发生甲烷化反应和甲烷水蒸气重整反应。9. A method for preparing coal-based high-density fuel according to claim 7, characterized in that the gas phase product produced by pyrolysis enters a horizontal well and is reformed with a methanation catalyst filling layer (132) and methane steam reforming Methanation reaction and methane steam reforming reaction occur in the catalyst packed layer (131). 10.根据权利要求7所述的一种煤基高密度燃料的制备方法,其特征在于,所述初步加氢提质的反应条件为:320-420℃,20MPa,催化剂采用铁钼催化剂;所述重馏分加氢提质的反应条件为:180-300℃,12MPa,催化剂采用镍钼催化剂;所述焦油饱和加氢的反应条件为:360-400℃,4.2MPa,催化剂采用镍钼催化剂。10. A method for preparing coal-based high-density fuel according to claim 7, characterized in that the reaction conditions of the preliminary hydrogenation and upgrading are: 320-420°C, 20MPa, and the catalyst adopts an iron-molybdenum catalyst; The reaction conditions for the hydrogenation and upgrading of the heavy fraction are: 180-300°C, 12MPa, and the catalyst is a nickel-molybdenum catalyst; the reaction conditions for the tar saturated hydrogenation are: 360-400°C, 4.2MPa, and the catalyst is a nickel-molybdenum catalyst.
CN202311867833.3A 2023-12-29 2023-12-29 Preparation system and method of coal-based high-density fuel Pending CN117703375A (en)

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