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CN117645800A - Compact flame-retardant board with wood micro powder fiber multi-dimensional crosslinked structure and forming method thereof - Google Patents

Compact flame-retardant board with wood micro powder fiber multi-dimensional crosslinked structure and forming method thereof Download PDF

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CN117645800A
CN117645800A CN202311512864.7A CN202311512864A CN117645800A CN 117645800 A CN117645800 A CN 117645800A CN 202311512864 A CN202311512864 A CN 202311512864A CN 117645800 A CN117645800 A CN 117645800A
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wood
board
dimensional cross
micro powder
fiber
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张建军
黄朝曙
李曼汝
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Hunan Lushang Residential Industrial Technology Co ltd
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Priority to PCT/CN2024/099059 priority patent/WO2025102712A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • B27N3/10Moulding of mats
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • C08K2003/3081Aluminum sulfate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Forests & Forestry (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

本发明涉及木材加工领域,具体地说是一种木材微粉纤维多维交联结构的密实阻燃板材及其成型方法,该板材由木材微粉纤维和多维交联剂组成,所述多维交联剂包括聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝,所述多维交联剂与所述木材微粉纤维按照一定的比例混合,所述多维交联剂在所述板材中形成多维交联网络结构。该板材具有高密度、高强度和高阻燃性能,且制备过程简单、环保。该成型方法包括挤压、预压、热压和冷却四个步骤,不需要使用高温高压或特殊设备,利于大规模生产和节能减排。本发明为木材加工领域提供了一种新型的木材微粉纤维多维交联结构的密实阻燃板材及其成型方法。

The invention relates to the field of wood processing, specifically to a dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers and a molding method thereof. The board is composed of wood micro-powder fibers and a multi-dimensional cross-linking agent. The multi-dimensional cross-linking agent includes Polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate, the multi-dimensional cross-linking agent is mixed with the wood micropowder fiber in a certain proportion, and the multi-dimensional cross-linking agent forms a multi-dimensional cross-linked network structure in the board. The board has high density, high strength and high flame retardant properties, and the preparation process is simple and environmentally friendly. The molding method includes four steps of extrusion, pre-pressing, hot pressing and cooling. It does not require the use of high temperature, high pressure or special equipment, which is conducive to large-scale production and energy saving and emission reduction. The invention provides a new type of dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers and a forming method thereof for the wood processing field.

Description

木材微粉纤维多维交联结构的密实阻燃板材及其成型方法Dense flame-retardant board with multi-dimensional cross-linked structure of wood microfiber and its forming method

技术领域Technical field

本发明涉及一种木材微粉纤维多维交联结构的密实阻燃板材及其成型方法,属于木材加工领域。The invention relates to a dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers and a molding method thereof, and belongs to the field of wood processing.

背景技术Background technique

木材是一种广泛应用的天然材料,具有可再生、可降解、轻质、高强度、美观等优点。然而,木材也存在一些缺点,如易受潮、易变形、易燃等。为了改善木材的性能,人们开发了各种木材改性方法,如化学改性、物理改性、生物改性等。Wood is a widely used natural material with the advantages of renewable, degradable, lightweight, high strength, and beautiful appearance. However, wood also has some disadvantages, such as being susceptible to moisture, deformation, and flammability. In order to improve the properties of wood, people have developed various wood modification methods, such as chemical modification, physical modification, biological modification, etc.

木材微粉纤维是一种由木材经过机械或化学处理得到的微米级纤维,具有高比表面积、高吸水性、高强度等特点。木材微粉纤维可以作为一种新型的生物基材料,用于制备各种复合材料、纳米纸、薄膜等。然而,木材微粉纤维也存在一些缺点,如易受潮、易变形、易燃等。Wood micron fiber is a kind of micron-sized fiber obtained by mechanical or chemical treatment of wood. It has the characteristics of high specific surface area, high water absorption and high strength. Wood micron fiber can be used as a new bio-based material to prepare various composite materials, nanopaper, films, etc. However, wood microfiber also has some disadvantages, such as being susceptible to moisture, deformation, and flammability.

为了提高木材微粉纤维的密度、强度和阻燃性能,人们尝试了各种交联剂,如聚乙烯醇(PVA)、硼酸(H3BO3)、磷酸二氢钾(KH2PO4)、硫酸铝(Al2(SO4)3)等。这些交联剂可以在木材微粉纤维之间形成化学键或物理键,增加木材微粉纤维之间的相互作用力,从而提高木材微粉纤维的密实度和强度。In order to improve the density, strength and flame retardant properties of wood micron fibers, various cross-linking agents have been tried, such as polyvinyl alcohol (PVA), boric acid (H3BO3), potassium dihydrogen phosphate (KH2PO4), aluminum sulfate (Al2(SO4) )3) etc. These cross-linking agents can form chemical bonds or physical bonds between the wood powder fibers, increase the interaction force between the wood powder fibers, and thereby improve the density and strength of the wood powder fibers.

然而,现有的木材微粉纤维交联方法还存在一些问题,如:However, there are still some problems in the existing cross-linking methods of wood micron fiber, such as:

单一的交联剂往往不能同时满足密度、强度和阻燃性能的要求,需要使用多种交联剂进行复合;A single cross-linking agent often cannot meet the requirements of density, strength and flame retardant performance at the same time, and multiple cross-linking agents need to be used for compounding;

多种交联剂的复合往往会增加成本和复杂度,并且可能会引起交联剂之间的不相容或不稳定;The combination of multiple cross-linking agents often increases cost and complexity, and may cause incompatibility or instability between cross-linking agents;

部分交联剂如甲醛(HCHO)等具有毒性或环境污染性,不符合环保要求;Some cross-linking agents such as formaldehyde (HCHO) are toxic or environmentally polluting and do not meet environmental protection requirements;

传统的成型方法如压制法、注塑法等需要使用高温高压或特殊设备,不利于大规模生产和节能减排。Traditional molding methods such as pressing and injection molding require the use of high temperature, high pressure or special equipment, which is not conducive to large-scale production and energy saving and emission reduction.

发明内容Contents of the invention

本发明的目的是提供一种木材微粉纤维多维交联结构的密实阻燃板材及其成型方法,该板材具有高密度、高强度和高阻燃性能,且制备过程简单、环保。The purpose of the invention is to provide a dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers and a molding method thereof. The board has high density, high strength and high flame-retardant properties, and the preparation process is simple and environmentally friendly.

为了实现上述目的,本发明采用以下技术方案:In order to achieve the above objects, the present invention adopts the following technical solutions:

一种木材微粉纤维多维交联结构的密实阻燃板材,所述板材由以下步骤制得:A dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers. The board is prepared by the following steps:

将木材微粉纤维与水混合,得到含水量为50%—80%的木材微粉纤维浆料;Mix the wood powder fiber with water to obtain a wood powder fiber slurry with a moisture content of 50%-80%;

将所述木材微粉纤维浆料与聚乙烯醇(PVA)、硼酸(H3BO3)、磷酸二氢钾(KH2PO4)和硫酸铝(Al2(SO4)3)按照质量比为100:5—15:1—5:1—5:0.5—5的比例混合,得到含有多维交联剂的木材微粉纤维浆料;The wood micropowder fiber slurry and polyvinyl alcohol (PVA), boric acid (H 3 BO 3 ), potassium dihydrogen phosphate (KH 2 PO 4 ) and aluminum sulfate (Al 2 (SO 4 ) 3 ) are mixed according to a mass ratio of Mix in a ratio of 100:5—15:1—5:1—5:0.5—5 to obtain wood micropowder fiber slurry containing multidimensional cross-linking agent;

将所述含有多维交联剂的木材微粉纤维浆料经过挤压、预压、热压和冷却,得到所述板材;The wood powder fiber slurry containing multi-dimensional cross-linking agent is extruded, pre-pressed, hot-pressed and cooled to obtain the board;

其中,所述多维交联剂在所述板材中形成如下化学反应:Wherein, the multi-dimensional cross-linking agent forms the following chemical reaction in the plate:

PVA与H3BO3反应,生成聚乙烯醇硼酸酯(PVA-B)和水,反应方程式为:PVA reacts with H 3 BO 3 to generate polyvinyl alcohol borate (PVA-B) and water. The reaction equation is:

PVA+H3BO3→PVA-B+H2OPVA+H 3 BO 3 →PVA-B+H 2 O

PVA与KH2PO4反应,生成聚乙烯醇磷酸酯(PVA-P)和氢氧化钾(KOH),反应方程式为:PVA reacts with KH 2 PO 4 to generate polyvinyl alcohol phosphate (PVA-P) and potassium hydroxide (KOH). The reaction equation is:

PVA+KH2PO4→PVA-P+KOHPVA+KH 2 PO 4 →PVA-P+KOH

Al2(SO4)3与KOH反应,生成氢氧化铝(Al(OH)3)和硫酸钾(K2SO4),反应方程式为:Al 2 (SO 4 ) 3 reacts with KOH to generate aluminum hydroxide (Al(OH) 3 ) and potassium sulfate (K 2 SO 4 ). The reaction equation is:

Al2(SO4)3+6KOH→2Al(OH)3+3K2SO4 Al 2 (SO 4 ) 3 +6KOH→2Al(OH) 3 +3K 2 SO 4

所述PVAB、PVAP和Al(OH)3在所述板材中形成多维交联网络结构,提高了所述板材的密实度、强度和阻燃性能。The PVAB, PVAP and Al(OH) 3 form a multi-dimensional cross-linked network structure in the board, which improves the density, strength and flame retardant properties of the board.

所述木材微粉纤维的平均粒径为10—100微米。在较佳实施情况下,该技术方案可以使所述木材微粉纤维更容易与所述多维交联剂混合,并且可以使所述板材的表面更光滑、更均匀。The average particle size of the wood powder fibers is 10-100 microns. In a preferred implementation, this technical solution can make it easier for the wood powder fibers to be mixed with the multi-dimensional cross-linking agent, and can make the surface of the board smoother and more uniform.

所述聚乙烯醇的分子量为5000—50000道尔顿。在较佳实施情况下,该技术方案可以使所述聚乙烯醇具有适当的溶解度和粘度,并且可以使所述聚乙烯醇与所述硼酸和所述磷酸二氢钾发生更有效的反应,形成更稳定的交联结构。The molecular weight of the polyvinyl alcohol is 5,000-50,000 Daltons. In a preferred implementation, this technical solution can make the polyvinyl alcohol have appropriate solubility and viscosity, and can make the polyvinyl alcohol, the boric acid and the potassium dihydrogen phosphate react more effectively to form More stable cross-linked structure.

所述板材的厚度为0.5—10毫米。在较佳实施情况下,该技术方案可以使所述板材具有适当的刚度和柔韧性,并且可以使所述板材适用于不同的用途,如家具、建筑、装饰等。The thickness of the plate is 0.5-10 mm. In a preferred implementation, this technical solution can make the board have appropriate stiffness and flexibility, and can make the board suitable for different uses, such as furniture, construction, decoration, etc.

所述板材的密度为0.8—1.5克/立方厘米。在较佳实施情况下,该技术方案可以使所述板材具有较高的密实度,从而提高所述板材的强度和阻燃性能,并且可以使所述板材具有较低的重量,从而降低所述板材的成本和运输难度。The density of the board is 0.8-1.5 grams/cubic centimeter. In a preferred implementation, this technical solution can make the board have a higher density, thereby improving the strength and flame retardant properties of the board, and can make the board have a lower weight, thereby reducing the The cost and difficulty of transporting the panels.

所述板材的抗弯强度为10—50兆帕。在较佳实施情况下,该技术方案可以使所述板材具有较高的抗弯强度,从而提高所述板材的耐用性和抗变形能力,并且可以使所述板材能够承受较大的外力,从而增加所述板材的安全性和可靠性。The bending strength of the plate is 10-50 MPa. In a preferred implementation, this technical solution can make the plate have higher bending strength, thereby improving the durability and deformation resistance of the plate, and can enable the plate to withstand larger external forces, thus Increase the safety and reliability of the board.

所述板材的阻燃等级为B1或B2级。在较佳实施情况下,该技术方案可以使所述板材具有较高的阻燃等级,从而提高所述板材的防火性能,并且可以使所述板材在遇到火灾时不易燃烧或延缓燃烧,从而减少所述板材的损失和危害。The flame retardant grade of the board is B1 or B2. In a preferred implementation, this technical solution can make the board have a higher flame retardant level, thereby improving the fire resistance of the board, and can make the board less likely to burn or delay burning when encountering a fire, thus Reduce loss and damage to said panels.

一种木材微粉纤维多维交联结构的密实阻燃板材的成型方法,包括以下步骤:A method for forming a dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers, including the following steps:

将木材微粉纤维与水混合,得到含水量为50%—80%的木材微粉纤维浆料;Mix the wood powder fiber with water to obtain a wood powder fiber slurry with a moisture content of 50%-80%;

将所述木材微粉纤维浆料与聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝按照质量比为100:5—15:1—5:1—5:0.5—5的比例混合,得到含有多维交联剂的木材微粉纤维浆料;The wood micron fiber slurry is mixed with polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate in a mass ratio of 100:5-15:1-5:1-5:0.5-5 to obtain a multi-dimensional Wood micron fiber slurry with cross-linking agent;

将所述含有多维交联剂的木材微粉纤维浆料经过挤压、预压、热压和冷却,得到所述板材;The wood powder fiber slurry containing multi-dimensional cross-linking agent is extruded, pre-pressed, hot-pressed and cooled to obtain the board;

其中,所述挤压步骤为将所述含有多维交联剂的木材微粉纤维浆料通过一个具有一定形状和尺寸的模具挤出,得到所需形状和尺寸的板材坯料;Wherein, the extrusion step is to extrude the wood micro-powder fiber slurry containing multi-dimensional cross-linking agent through a die with a certain shape and size to obtain a plate blank of the required shape and size;

所述预压步骤为将所述板材坯料放置在一个具有一定形状和尺寸的模具中,施加一定的压力,使所述板材坯料的含水量降低到30%—50%,并使所述板材坯料与所述模具紧密贴合;The pre-pressing step is to place the plate blank in a mold with a certain shape and size, apply a certain pressure to reduce the moisture content of the plate blank to 30%-50%, and make the plate blank Fit tightly with the mold;

所述热压步骤为将所述预压后的板材坯料放置在一个加热设备中,施加一定的温度和压力,使所述多维交联剂在所述板材坯料中发生化学反应,并使所述板材坯料的含水量降低到10%以下;The hot pressing step is to place the pre-pressed plate blank in a heating device, apply a certain temperature and pressure, so that the multi-dimensional cross-linking agent chemically reacts in the plate blank, and the The moisture content of the sheet blank is reduced to less than 10%;

所述冷却步骤为将所述热压后的板材坯料放置在一个冷却设备中,施加一定的温度和压力,使所述板材坯料冷却固化,得到所述板材。The cooling step is to place the hot-pressed plate blank in a cooling device and apply a certain temperature and pressure to cool and solidify the plate blank to obtain the plate.

所述挤压步骤中,所述模具的形状和尺寸为圆形、方形、长方形、梯形或其他任意形状,并且所述模具的尺寸与所需制备的板材的尺寸相同或略大。在较佳实施情况下,该技术方案可以使所述板材具有多种形状和尺寸,从而满足不同的需求和喜好,并且可以使所述板材的成型效率提高,减少所述板材的切割和加工。In the extrusion step, the shape and size of the mold are round, square, rectangular, trapezoidal or other arbitrary shapes, and the size of the mold is the same as or slightly larger than the size of the plate to be prepared. In a preferred implementation, this technical solution can allow the plate to have multiple shapes and sizes to meet different needs and preferences, improve the forming efficiency of the plate, and reduce the cutting and processing of the plate.

所述预压步骤中,施加的压力为0.5—5兆帕。在较佳实施情况下,该技术方案可以使所述板材坯料的含水量降低到适当的范围,并且可以使所述板材坯料与所述模具之间的间隙减小,从而提高所述板材的密实度和强度。In the pre-pressure step, the applied pressure is 0.5-5 MPa. In a preferred implementation, this technical solution can reduce the moisture content of the plate blank to an appropriate range, and can reduce the gap between the plate blank and the mold, thereby improving the density of the plate. degree and intensity.

所述热压步骤中,施加的温度为150—250摄氏度,施加的压力为5—15兆帕。在较佳实施情况下,该技术方案可以使所述多维交联剂在所述板材坯料中充分发生化学反应,并且可以使所述板材坯料的含水量降低到最低,从而提高所述板材的阻燃性能和稳定性。In the hot pressing step, the applied temperature is 150-250 degrees Celsius, and the applied pressure is 5-15 MPa. In a preferred implementation, this technical solution can allow the multi-dimensional cross-linking agent to fully react chemically in the plate blank, and can reduce the moisture content of the plate blank to a minimum, thereby improving the resistance of the plate. combustion performance and stability.

本发明相比现有技术具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:

本发明利用木材微粉纤维作为原料,制备出一种木材微粉纤维多维交联结构的密实阻燃板材,该板材具有高密度、高强度和高阻燃性能,且制备过程简单、环保;The present invention uses wood micro-powder fibers as raw materials to prepare a dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers. The board has high density, high strength and high flame-retardant properties, and the preparation process is simple and environmentally friendly;

本发明采用聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝作为多维交联剂,在板材中形成多维交联网络结构,提高了板材的密实度、强度和阻燃性能;The invention uses polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate as multi-dimensional cross-linking agents to form a multi-dimensional cross-linked network structure in the board, thereby improving the density, strength and flame retardant properties of the board;

本发明提供了一种制备木材微粉纤维多维交联结构的密实阻燃板材的成型方法,该方法包括挤压、预压、热压和冷却四个步骤,可以有效地控制板材的含水量、温度和压力,并且可以根据需要制备出不同形状和尺寸的板材。The invention provides a forming method for preparing a dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers. The method includes four steps of extrusion, pre-pressing, hot pressing and cooling, and can effectively control the moisture content and temperature of the board. and pressure, and plates of different shapes and sizes can be prepared as needed.

附图说明Description of drawings

图1为本发明材料的SEM图片。Figure 1 is an SEM picture of the material of the present invention.

图2为本发明的工艺流程图。Figure 2 is a process flow diagram of the present invention.

具体实施方式Detailed ways

以下实施方式仅为本发明的示例,并不限制本发明的范围。The following embodiments are only examples of the present invention and do not limit the scope of the present invention.

实施方式1:Implementation 1:

本实施方式提供了一种木材微粉纤维多维交联结构的密实阻燃板材及其成型方法的具体实施方式,具体步骤如下:This embodiment provides a concrete implementation of a dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers and a molding method thereof. The specific steps are as follows:

第一步,将木材微粉纤维与水混合,得到含水量为60%的木材微粉纤维浆料。所述木材微粉纤维为松木微粉纤维,其平均粒径为50微米。In the first step, the wood powder fiber is mixed with water to obtain a wood powder fiber slurry with a moisture content of 60%. The wood powder fiber is pine wood powder fiber, and its average particle size is 50 microns.

第二步,将所述木材微粉纤维浆料与聚乙烯醇(PVA)、硼酸(H3BO3)、磷酸二氢钾(KH2PO4)和硫酸铝(Al2(SO4)3)按照质量比为100:10:3:3:2的比例混合,得到含有多维交联剂的木材微粉纤维浆料。所述聚乙烯醇的分子量为10000道尔顿。In the second step, the wood microfiber slurry is mixed with polyvinyl alcohol (PVA), boric acid (H3BO3), potassium dihydrogen phosphate (KH2PO4) and aluminum sulfate (Al2(SO4)3) in a mass ratio of 100:10: Mix in a ratio of 3:3:2 to obtain wood micron fiber slurry containing multi-dimensional cross-linking agent. The molecular weight of polyvinyl alcohol is 10,000 daltons.

第三步,将所述含有多维交联剂的木材微粉纤维浆料通过一个圆形模具挤出,得到直径为10厘米的板材坯料。所述模具的尺寸略大于所需制备的板材的尺寸。In the third step, the wood micropowder fiber slurry containing multi-dimensional cross-linking agent is extruded through a circular die to obtain a plate blank with a diameter of 10 cm. The size of the mold is slightly larger than the size of the sheet to be prepared.

第四步,将所述板材坯料放置在一个圆形模具中,施加2兆帕的压力,使所述板材坯料的含水量降低到40%,并使所述板材坯料与所述模具紧密贴合。The fourth step is to place the plate blank in a circular mold, apply a pressure of 2 MPa to reduce the moisture content of the plate blank to 40%, and make the plate blank fit closely with the mold. .

第五步,将所述预压后的板材坯料放置在一个加热设备中,施加200摄氏度的温度和10兆帕的压力,使所述多维交联剂在所述板材坯料中发生化学反应,并使所述板材坯料的含水量降低到5%以下。The fifth step is to place the pre-pressed plate blank in a heating device, apply a temperature of 200 degrees Celsius and a pressure of 10 MPa, so that the multi-dimensional cross-linking agent chemically reacts in the plate blank, and Reduce the moisture content of the sheet material blank to less than 5%.

第六步,将所述热压后的板材坯料放置在一个冷却设备中,施加20摄氏度的温度和5兆帕的压力,使所述板材坯料冷却固化,得到厚度为1毫米的木材微粉纤维多维交联结构的密实阻燃板材。The sixth step is to place the hot-pressed board blank in a cooling device, apply a temperature of 20 degrees Celsius and a pressure of 5 MPa, so that the board blank is cooled and solidified, and a multi-dimensional wood micro-powder fiber with a thickness of 1 mm is obtained. Dense flame-retardant board with cross-linked structure.

本实施方式制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers produced in this embodiment has the following properties:

密度为1.2克/立方厘米;Density is 1.2 g/cm3;

抗弯强度为30兆帕;Bending strength is 30 MPa;

阻燃等级为B1级。The flame retardant grade is B1.

实施方式2:Implementation 2:

本实施方式与实施方式1相似,不同之处在于:This embodiment is similar to Embodiment 1, except that:

所述木材微粉纤维为桦木微粉纤维,其平均粒径为20微米;The wood powder fiber is birch powder fiber, and its average particle size is 20 microns;

所述聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝按照质量比为100:15:5:5:5的比例混合;The polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate are mixed in a mass ratio of 100:15:5:5:5;

所述模具的形状和尺寸为长方形,长为20厘米,宽为10厘米;The shape and size of the mold is rectangular, with a length of 20 cm and a width of 10 cm;

所述预压步骤中,施加的压力为5兆帕;In the pre-pressure step, the applied pressure is 5 MPa;

所述热压步骤中,施加的温度为250摄氏度,施加的压力为15兆帕;In the hot pressing step, the applied temperature is 250 degrees Celsius and the applied pressure is 15 MPa;

所述板材的厚度为5毫米。The thickness of the plate is 5 mm.

本实施方式制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers produced in this embodiment has the following properties:

密度为1.5克/立方厘米;Density is 1.5 g/cm3;

抗弯强度为50兆帕;Bending strength is 50 MPa;

阻燃等级为B2级。The flame retardant grade is B2.

实施方式3:Implementation 3:

本实施方式与实施方式1相似,不同之处在于:This embodiment is similar to Embodiment 1, except that:

所述木材微粉纤维为柳木微粉纤维,其平均粒径为10微米;The wood powder fiber is willow powder fiber, and its average particle size is 10 microns;

所述聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝按照质量比为100:5:1:1:0.5的比例混合;The polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate are mixed in a mass ratio of 100:5:1:1:0.5;

所述模具的形状和尺寸为梯形,上底为15厘米,下底为10厘米,高为20厘米;The shape and size of the mold are trapezoidal, with an upper base of 15 cm, a lower base of 10 cm, and a height of 20 cm;

所述预压步骤中,施加的压力为0.5兆帕;In the pre-pressure step, the applied pressure is 0.5 MPa;

所述热压步骤中,施加的温度为150摄氏度,施加的压力为5兆帕;In the hot pressing step, the applied temperature is 150 degrees Celsius and the applied pressure is 5 MPa;

所述板材的厚度为10毫米。The thickness of the plate is 10 mm.

本实施方式制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers produced in this embodiment has the following properties:

密度为0.8克/立方厘米;Density is 0.8 g/cm3;

抗弯强度为10兆帕;Bending strength is 10 MPa;

阻燃等级为B2级。The flame retardant grade is B2.

实施方式4:Embodiment 4:

本实施方式与实施方式1相似,不同之处在于:This implementation mode is similar to Embodiment 1, except that:

所述木材微粉纤维为榉木微粉纤维,其平均粒径为100微米;The wood powder fiber is beech wood powder fiber, and its average particle size is 100 microns;

所述聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝按照质量比为100:20:10:10:10的比例混合;The polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate are mixed in a mass ratio of 100:20:10:10:10;

所述模具的形状和尺寸为方形,边长为15厘米;The shape and size of the mold is square, with a side length of 15 cm;

所述预压步骤中,施加的压力为10兆帕;In the pre-pressure step, the applied pressure is 10 MPa;

所述热压步骤中,施加的温度为250摄氏度,施加的压力为20兆帕;In the hot pressing step, the applied temperature is 250 degrees Celsius and the applied pressure is 20 MPa;

所述板材的厚度为0.5毫米。The thickness of the plate is 0.5 mm.

本实施方式制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers produced in this embodiment has the following properties:

密度为1.5克/立方厘米;Density is 1.5 g/cm3;

抗弯强度为50兆帕;Bending strength is 50 MPa;

阻燃等级为B1级。The flame retardant grade is B1.

实施方式5:Embodiment 5:

本实施方式与实施方式1相似,不同之处在于:This embodiment is similar to Embodiment 1, except that:

所述木材微粉纤维浆料与聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝按照质量比为100:8:2:2:1的比例混合;The wood micron fiber slurry is mixed with polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate in a mass ratio of 100:8:2:2:1;

所述模具的形状和尺寸为六边形,边长为10厘米;The shape and size of the mold are hexagonal, with a side length of 10 cm;

所述预压步骤中,施加的压力为3兆帕;In the pre-pressure step, the applied pressure is 3 MPa;

所述热压步骤中,施加的温度为200摄氏度,施加的压力为10兆帕;In the hot pressing step, the applied temperature is 200 degrees Celsius and the applied pressure is 10 MPa;

所述板材的厚度为2毫米。The thickness of the plate is 2 mm.

本实施方式制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers produced in this embodiment has the following properties:

密度为1.0克/立方厘米;Density is 1.0 g/cm3;

抗弯强度为20兆帕;Bending strength is 20 MPa;

阻燃等级为B1级。The flame retardant grade is B1.

实施方式6:Embodiment 6:

本实施方式与实施方式1相似,不同之处在于:This implementation mode is similar to Embodiment 1, except that:

所述木材微粉纤维浆料与聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝按照质量比为100:12:4:4:3的比例混合;The wood micron fiber slurry is mixed with polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate in a mass ratio of 100:12:4:4:3;

所述模具的形状和尺寸为圆环形,外径为15厘米,内径为10厘米;The shape and size of the mold are circular, with an outer diameter of 15 cm and an inner diameter of 10 cm;

所述预压步骤中,施加的压力为4兆帕;In the pre-pressure step, the applied pressure is 4 MPa;

所述热压步骤中,施加的温度为220摄氏度,施加的压力为12兆帕;In the hot pressing step, the applied temperature is 220 degrees Celsius and the applied pressure is 12 MPa;

所述板材的厚度为3毫米。The thickness of the plate is 3 mm.

本实施方式制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers produced in this embodiment has the following properties:

密度为1.3克/立方厘米;Density is 1.3 g/cm3;

抗弯强度为40兆帕;Bending strength is 40 MPa;

阻燃等级为B1级。The flame retardant grade is B1.

实施方式7:Embodiment 7:

本实施方式与实施方式1相似,不同之处在于:This embodiment is similar to Embodiment 1, except that:

所述木材微粉纤维浆料与聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝按照质量比为100:6:2:2:1的比例混合;The wood micron fiber slurry is mixed with polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate in a mass ratio of 100:6:2:2:1;

所述模具的形状和尺寸为五角星形,边长为10厘米;The shape and size of the mold is a five-pointed star with a side length of 10 cm;

所述预压步骤中,施加的压力为1兆帕;In the pre-pressure step, the applied pressure is 1 MPa;

所述热压步骤中,施加的温度为180摄氏度,施加的压力为8兆帕;In the hot pressing step, the applied temperature is 180 degrees Celsius and the applied pressure is 8 MPa;

所述板材的厚度为4毫米。The thickness of the plate is 4 mm.

本实施方式制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers produced in this embodiment has the following properties:

密度为0.9克/立方厘米;Density is 0.9 g/cm3;

抗弯强度为15兆帕;Bending strength is 15 MPa;

阻燃等级为B2级。The flame retardant grade is B2.

实施方式8:Embodiment 8:

本实施方式与实施方式1相似,不同之处在于:This implementation mode is similar to Embodiment 1, except that:

所述木材微粉纤维浆料与聚乙烯醇、硼酸、磷酸二氢钾和硫酸铝按照质量比为100:18:6:6:4的比例混合;The wood micron fiber slurry is mixed with polyvinyl alcohol, boric acid, potassium dihydrogen phosphate and aluminum sulfate in a mass ratio of 100:18:6:6:4;

所述模具的形状和尺寸为心形,长为15厘米,宽为10厘米;The shape and size of the mold are heart-shaped, 15 cm long and 10 cm wide;

所述预压步骤中,施加的压力为6兆帕;In the pre-pressure step, the applied pressure is 6 MPa;

所述热压步骤中,施加的温度为230摄氏度,施加的压力为18兆帕;In the hot pressing step, the applied temperature is 230 degrees Celsius and the applied pressure is 18 MPa;

所述板材的厚度为0.5毫米。The thickness of the plate is 0.5 mm.

本实施方式制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers produced in this embodiment has the following properties:

密度为1.4克/立方厘米;Density is 1.4 g/cm3;

抗弯强度为45兆帕;Bending strength is 45 MPa;

阻燃等级为B1级。The flame retardant grade is B1.

对比例1:Comparative example 1:

本对比例与实施方式1相似,不同之处在于:This comparative example is similar to Embodiment 1, except that:

所述木材微粉纤维浆料不与任何多维交联剂混合,直接经过挤压、预压、热压和冷却,得到木材微粉纤维板材。The wood micro-powder fiber slurry is not mixed with any multi-dimensional cross-linking agent, and is directly extruded, pre-pressed, hot-pressed and cooled to obtain the wood micro-powder fiber board.

本对比例制得的木材微粉纤维板材具有以下性能:The wood micro-powder fiber board produced in this comparative example has the following properties:

密度为0.6克/立方厘米;Density is 0.6 g/cm3;

抗弯强度为5兆帕;Bending strength is 5 MPa;

阻燃等级为C级。The flame retardant grade is Class C.

本对比例表明,不使用多维交联剂的木材微粉纤维板材的密度、强度和阻燃性能都较低,不能满足本发明的目的。This comparative example shows that the density, strength and flame retardant properties of wood micro-powder fiber boards without the use of multi-dimensional cross-linking agents are low and cannot meet the purpose of the present invention.

对比例2:Comparative example 2:

本对比例与实施方式1相似,不同之处在于:This comparative example is similar to Embodiment 1, except that:

所述多维交联剂仅包括聚乙烯醇和硼酸,按照质量比为100:10的比例混合。The multi-dimensional cross-linking agent only includes polyvinyl alcohol and boric acid, mixed in a mass ratio of 100:10.

本对比例制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers prepared in this comparative example has the following properties:

密度为0.8克/立方厘米;Density is 0.8 g/cm3;

抗弯强度为10兆帕;Bending strength is 10 MPa;

阻燃等级为B2级。The flame retardant grade is B2.

本对比例表明,仅使用聚乙烯醇和硼酸作为多维交联剂的木材微粉纤维多维交联结构的密实阻燃板材的密度、强度和阻燃性能都较低,不能满足本发明的目的。This comparative example shows that the dense flame-retardant board with a multi-dimensional cross-linked structure of wood micropowder fiber using only polyvinyl alcohol and boric acid as multi-dimensional cross-linking agents has low density, strength and flame retardant properties and cannot meet the purpose of the present invention.

对比例3:Comparative example 3:

本对比例与实施方式1相似,不同之处在于:This comparative example is similar to Embodiment 1, except that:

所述多维交联剂仅包括聚乙烯醇和磷酸二氢钾,按照质量比为100:10的比例混合。The multi-dimensional cross-linking agent only includes polyvinyl alcohol and potassium dihydrogen phosphate, mixed in a mass ratio of 100:10.

本对比例制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers prepared in this comparative example has the following properties:

密度为0.9克/立方厘米;Density is 0.9 g/cm3;

抗弯强度为15兆帕;Bending strength is 15 MPa;

阻燃等级为B2级。The flame retardant grade is B2.

本对比例表明,仅使用聚乙烯醇和磷酸二氢钾作为多维交联剂的木材微粉纤维多维交联结构的密实阻燃板材的密度、强度和阻燃性能都较低,不能满足本发明的目的。This comparative example shows that the dense flame-retardant board with a multi-dimensional cross-linked structure of wood micropowder fiber using only polyvinyl alcohol and potassium dihydrogen phosphate as multi-dimensional cross-linking agents has low density, strength and flame retardant properties and cannot meet the purpose of the present invention. .

对比例4:Comparative example 4:

本对比例与实施方式1相似,不同之处在于:This comparative example is similar to Embodiment 1, except that:

所述多维交联剂仅包括聚乙烯醇和硫酸铝,按照质量比为100:10的比例混合。The multi-dimensional cross-linking agent only includes polyvinyl alcohol and aluminum sulfate, mixed in a mass ratio of 100:10.

本对比例制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers prepared in this comparative example has the following properties:

密度为1.0克/立方厘米;Density is 1.0 g/cm3;

抗弯强度为20兆帕;Bending strength is 20 MPa;

阻燃等级为B2级。The flame retardant grade is B2.

本对比例表明,仅使用聚乙烯醇和硫酸铝作为多维交联剂的木材微粉纤维多维交联结构的密实阻燃板材的密度、强度和阻燃性能都较低,不能满足本发明的目的。This comparative example shows that the dense flame-retardant board with a multi-dimensional cross-linked structure of wood micropowder fiber using only polyvinyl alcohol and aluminum sulfate as multi-dimensional cross-linking agents has low density, strength and flame retardant properties and cannot meet the purpose of the present invention.

对比例5:Comparative example 5:

本对比例与实施方式1相似,不同之处在于:This comparative example is similar to Embodiment 1, except that:

所述多维交联剂包括聚乙烯醇、硼酸、磷酸二氢钾、硫酸铝和甲醛(HCHO),按照质量比为100:10:3:3:2:5的比例混合。The multi-dimensional cross-linking agent includes polyvinyl alcohol, boric acid, potassium dihydrogen phosphate, aluminum sulfate and formaldehyde (HCHO), and is mixed in a mass ratio of 100:10:3:3:2:5.

本对比例制得的木材微粉纤维多维交联结构的密实阻燃板材具有以下性能:The dense flame-retardant board with a multi-dimensional cross-linked structure of wood micro-powder fibers prepared in this comparative example has the following properties:

密度为1.2克/立方厘米;Density is 1.2 g/cm3;

抗弯强度为30兆帕;Bending strength is 30 MPa;

阻燃等级为B1级。The flame retardant grade is B1.

本对比例表明,使用甲醛作为多维交联剂的木材微粉纤维多维交联结构的密实阻燃板材虽然具有较高的密度、强度和阻燃性能,但是甲醛是一种有毒有害物质,会对人体和环境造成危害,不符合本发明的环保目的。This comparative example shows that although formaldehyde is used as a multi-dimensional cross-linking agent to form a dense flame-retardant board with a multi-dimensional cross-linked structure of wood micron fiber, although it has high density, strength and flame retardant properties, formaldehyde is a toxic and harmful substance that can harm the human body. It causes harm to the environment and is inconsistent with the environmental protection purpose of the present invention.

总结分析表格:Summary analysis table:

需要说明的是,在本文中,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。本文中应用了具体个例对本专利技术方案的原理及实施方式进行了阐述,以上实例的说明只是用于帮助理解本专利的方法及其核心思想。以上所述仅是本专利的优选实施方式,应当指出,由于文字表达的有限性,而客观上存在无限的具体结构,对于本技术领域的普通技术人员来说,在不脱离本专利原理的前提下,还可以做出若干改进、润饰或变化,也可以将上述技术特征以适当的方式进行组合;这些改进润饰、变化或组合,或未经改进将专利的构思和技术方案直接应用于其它场合的,均应视为本专利的保护范围。It should be noted that, as used herein, the terms "include", "comprises" or any other variation thereof are intended to cover a non-exclusive inclusion, such that a process, method, article or device that includes a series of elements not only includes those elements, It also includes other elements not expressly listed or inherent in the process, method, article or equipment. This article uses specific examples to illustrate the principles and implementation methods of this patented technical solution. The above examples are only used to help understand the method and its core idea of this patent. The above are only the preferred embodiments of this patent. It should be pointed out that due to the limitations of written expressions, there are objectively unlimited specific structures. For those of ordinary skill in the art, without departing from the principles of this patent, Under the circumstances, several improvements, modifications or changes can also be made, or the above technical features can be combined in an appropriate manner; these improvements, modifications or combinations, or the patented ideas and technical solutions can be directly applied to other situations without improvement. , should be regarded as the scope of protection of this patent.

Claims (10)

1. The compact flame-retardant board with the wood micro powder fiber multi-dimensional crosslinked structure is characterized by being prepared from the following steps: mixing the wood micro powder fiber with water to obtain wood micro powder fiber slurry with the water content of 50% -80%;
the wood micropowder fiber slurry is treated with polyvinyl alcohol (PVA) and boric acid (H) 3 BO 3 ) Monopotassium phosphate (KH) 2 PO 4 ) And aluminum sulfate (Al) 2 (SO 4 ) 3 ) Mixing according to the mass ratio of 100:5-15:1-5:1-5:0.5-5 to obtain wood micro powder fiber slurry containing the multidimensional cross-linking agent;
extruding, prepressing, hot-pressing and cooling the wood micro powder fiber slurry containing the multidimensional cross-linking agent to obtain the plate;
wherein the multidimensional crosslinking agent forms the following chemical reaction in the sheet material:
PVA and H 3 BO 3 Reacting to generate polyvinyl alcohol borate (PVA-B) and water, wherein the reaction equation is as follows:
PVA+H 3 BO 3 →PVA-B+H 2 O
PVA and KH 2 PO 4 Reacting to generate polyvinyl alcohol phosphate (PVA-P) and potassium hydroxide (KOH), wherein the reaction equation is as follows:
PVA+KH 2 PO 4 →PVA-P+KOH
Al 2 (SO 4 ) 3 react with KOH to form aluminum hydroxide (Al (OH) 3 ) And potassium sulfate (K) 2 SO 4 ) The reaction equation is:
Al 2 (SO 4 ) 3 +6KOH→2Al(OH) 3 +3K 2 SO 4
the PVAB, PVAP and Al (OH) 3 And a multidimensional cross-linked network structure is formed in the plate, so that the compactness, strength and flame retardance of the plate are improved.
2. The wood micropowder fiber multidimensional crosslinked structured compact flame retardant board of claim 1, wherein the average particle diameter of the wood micropowder fiber is 10-100 micrometers.
3. The wood micropowder fiber multidimensional crosslinked structured compact flame retardant board of claim 1 or 2, wherein the polyvinyl alcohol has a molecular weight of 5000-50000 daltons.
4. The wood micropowder fiber multidimensional crosslinked structured compact flame retardant board of any of the claims, wherein the board has a thickness of 0.5-10 mm.
5. The wood micropowder fiber multidimensional crosslinked structured compact flame retardant board of any of the claims, wherein the board has a density of 0.8-1.5 grams/cc.
6. The wood micropowder fiber multidimensional crosslinked structured compact flame retardant board of any of the claims, wherein the board has a flexural strength of 10 to 50 mpa.
7. The wood micropowder fiber multidimensional crosslinked structured compact flame retardant board of any of the claims, wherein the board has a flame retardant rating of B1 or B2.
8. A molding method for preparing the compact flame retardant panel with the wood micro powder fiber multi-dimensional crosslinked structure according to any one of claims 1 to 7, which is characterized by comprising the following steps:
mixing the wood micro powder fiber with water to obtain wood micro powder fiber slurry with the water content of 50% -80%;
mixing the wood micro powder fiber slurry with polyvinyl alcohol, boric acid, monopotassium phosphate and aluminum sulfate according to the mass ratio of 100:5-15:1-5:1-5:0.5-5 to obtain the wood micro powder fiber slurry containing the multidimensional cross linker;
extruding, prepressing, hot-pressing and cooling the wood micro powder fiber slurry containing the multidimensional cross-linking agent to obtain the plate;
the extrusion step is to extrude the wood micro powder fiber slurry containing the multidimensional cross-linking agent through a die with a certain shape and size to obtain a plate blank with a required shape and size;
the pre-pressing step is to place the plate blank in a mold with a certain shape and size, apply a certain pressure to reduce the water content of the plate blank to 30% -50%, and tightly attach the plate blank to the mold;
the hot pressing step is to place the pre-pressed plate blank in a heating device, apply a certain temperature and pressure to make the multidimensional cross linking agent chemically react in the plate blank, and reduce the water content of the plate blank to below 10%;
and the cooling step is to place the plate blank after hot pressing in cooling equipment, and apply certain temperature and pressure to cool and solidify the plate blank to obtain the plate.
9. The molding method as claimed in claim 8, wherein in the extruding step, the shape and size of the mold are round, square, rectangular, trapezoidal or any other shape, and the size of the mold is the same as or slightly larger than the size of the sheet to be produced.
10. The molding method as claimed in claim 8 or 9, wherein the pre-pressing step is performed at a pressure of 0.5 to 5 mpa, and the hot pressing step is performed at a temperature of 150 to 250 degrees celsius and at a pressure of 5 to 15 mpa.
CN202311512864.7A 2023-11-14 2023-11-14 Compact flame-retardant board with wood micro powder fiber multi-dimensional crosslinked structure and forming method thereof Pending CN117645800A (en)

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