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CN1172845A - Diesel oil, heavy oil and water fuel emulsion modified by biological enzyme - Google Patents

Diesel oil, heavy oil and water fuel emulsion modified by biological enzyme Download PDF

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Publication number
CN1172845A
CN1172845A CN 96109164 CN96109164A CN1172845A CN 1172845 A CN1172845 A CN 1172845A CN 96109164 CN96109164 CN 96109164 CN 96109164 A CN96109164 A CN 96109164A CN 1172845 A CN1172845 A CN 1172845A
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oil
diesel
fuel
diesel oil
water
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CN 96109164
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Chinese (zh)
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杨国光
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Individual
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Abstract

A fuel emulsion of diesel oil, heavy oil and water modified by biological enzyme is prepared from diesel oil (35-45 wt.%) heavy oil (35-45), water (15-25) and biological enzyme (0.1-0.5).

Description

A kind of diesel oil, heavy oil, water fuel emulsion with modified with bioenzyme
The present invention relates to a kind of diesel oil, heavy oil, water fuel emulsion with modified with bioenzyme.
China is high energy consumption country, power supply anxiety, oil price costliness.Upgrading is heavy, diesel oil has the excellent usefulness of bad oil sources, and energy-conservation of consumption reduction, the remarkable effect that reduces cost are the effective ways of the new oil sources of developing significantly.
World developed country generally is devoted to heavy generation light.The research and development of comprehensive utilization petroleum resources.Industrial countries such as Japan, Germany, use residual oil many especially, what the manufacturing price of not stinting was higher than China's several times uses the residual oil diesel engine.And upgrading oil uses on diesel engine and has very outstanding realistic meaning.
For many years, in order to save automotive fuel with oil, add at oil fuel both at home and abroad and do a lot of work aspect water (adding water) the preparation emulsion fuel, and obtained certain progress comprising diesel oil or low-grade oil.At present, mixed emulsion fuel and the fuel substitute oil with different methods and prepared has obtained application in various degree.But add at diesel engine of vehicle diesel oil or low-grade oil both at home and abroad at present that emulsifying water is technical still to exist certain problem: when being used for automobile, tractor for the emulsion fuel of diesel oil with water preparation, the diesel oil-saving rate is no more than 10%; And adding the emulsion fuel that water prepares for low-grade oil (or heavy oil), its use range only limits to slow speed diesel engines such as power plant or steamer.At present, still there is not the precedent of utilizing diesel oil, heavy oil, three kinds of basal component preparations of water to can be used for various model diesel engine both at home and abroad.
In recent years, biochemical engineering has been brought up to the arena of history, and organism plays the variation of matter by the activity of a series of enzymes to the tissue of material itself.But the document that biological enzyme is used for fuel oil is also rare.
The object of the present invention is to provide a kind of diesel oil, heavy oil, water fuel emulsion with modified with bioenzyme.
Another object of the present invention is to provide a kind of method with modified with bioenzyme diesel oil, heavy oil, water fuel emulsion.
In the present invention, said diesel oil is poor ignition quality fuel or No. zero diesel oil.Said heavy oil also can replace with sump oil or crude oil, and said biological enzyme is the Acarasiales of extracting in the cell by marine alga and sea-tangle and a kind of biological enzyme-sodium alginate (enzyme auxiliary agent factory in Lianyungang is on sale) of making.
Content of the present invention is that the diesel oil of certain proportioning, heavy oil, water and biological enzyme are mixed, and stirs the formulated a kind of fuel emulsion in circulation back.
Used material combination and the parts by weight of the emulsion of diesel oil of the present invention, heavy oil, water and biological enzyme preparation are as follows:
Component title parts by weight
Diesel oil 35-45
Heavy oil 35-45
Water 15-25
Biological enzyme 0.1-0.5
Above-mentioned diesel oil, heavy oil, water and biological enzyme fuel emulsion can adopt the mechanical cycles paddling process, the preparation of prior aries such as supersonic method.
The fuel oil emulsion of utilizing the present invention to prepare can replace No. 0 diesel oil to be used in various model diesel engine, the pure diesel oil-saving about 30% of comparable thus usefulness.This kind fuel oil emulsion can static placement 5 days in automotive oil tank even the longer time, need not to stir again still to make automobile travel as usual (but in oil depot or service station then long storage).Use fuel oil emulsion technology of the present invention easy, with low cost, and needn't on car engine, add any equipment, only the oil return pipeline need be changed a little thereby had simple, convenient, economical and practical characteristics the part diesel engine.
The following examples are to further specify of the present invention, but not limit the scope of the invention.
Embodiment 1: compound method is the paddling process of prior art.
It is as follows to fill a prescription:
Diesel oil 40kg
Heavy oil 40kg
Water 20kg
Sodium alginate 0.1kg.
Embodiment 2: compound method is the supersonic method of prior art.
It is as follows to fill a prescription:
Gas oil 35kg
Residual oil 45kg
Water 25kg
Sodium alginate 0.3kg.
Embodiment 3: compound method is a paddling process, and it is as follows to fill a prescription:
0# diesel oil 45kg
Sump oil 35kg
Water 20kg
Sodium alginate 0.5kg.
Through the test of general petrochemical works, Anqing refinery central laboratory, the physico-chemical property such as the following table 1 of upgrading diesel oil (sump oil type, embodiment 3).
Table 1
Project Unit Test-results
20 ℃ of kinematic viscosity ????mm 2/s ????56.02
Cetane value ????48
Zero pour ????℃ ????10
Flash-point ????℃ ????32
Moisture ????% ????0.20
Machine is assorted ????% ????0.0685
Carbon residue ????% ????2.2
Ash ????% ????0.296
Reaction Alkali
Corrosion Qualified
Acid number ????mgKOH/g ????0
50% recovered temperature ????℃ ????335
The physico-chemical property of upgrading diesel oil (residual oil type, embodiment 2) sees Table 2.
Table 2
Project Unit Test-results
20 ℃ of kinematic viscosity mm 2/s ????105.7
Cetane value ????35
Zero pour ????1
Flash-point ????>100
Moisture ????14.5
Machine is assorted ????0.0625
Carbon residue ????2.1
Ash ????0.289
Reaction Neutral
Corrosion Qualified
Acid number mgKOH/g ????0.25
50% recovered temperature ????332
Fuel oil emulsion of the present invention replaces the trial report of 0# diesel oil as follows:
The last ten-days period in August, 1989, the contriver has carried out heavy gas oil water blending fuel and 0# diesel oil, and to have done boats and ships operation contrast on probation.Promptly drag 401 to take turns (400 horsepowers-6300 C diesel engine) traction four barges of 2610 tons of yellow ground are housed, leave in the way of making a return journey in Shanghai all examinations by Anqing and burnt the heavy gas oil water blending fuel by the pond.Now trial state is reported as follows:
One, the preparation of oil product and analysis report:
(1) oil product preparation
Heavy oil 45kg+O #Diesel oil 40kg+ water 15kg+ biotic additives sodium alginate 0.04kg, about 70 ℃ of medial temperatures.In 700 rev/mins of agitators, stir and made in 10 minutes.The keeping of sample oil is since two months, and color and luster is bright, does not separate.
(2) chemically examine through petrochemical industry central laboratory: density G/cm 30.9221, kinematic viscosity mm/S11.73, ash content 0.013%, mechanical impurity 0.253%, moisture 6%, 6 ℃ at zero pour, calorie 9600/kg, main index is equivalent to 10# diesel oil.
Two, processing requirement and actual practice:
The contriver requires on the ship actual
1. oil product gives 80 ℃ 58-74 ℃ of heat
2. commutativity fuel tank filtering net 0.2mm does not have
3. purifier sawdust shaped metal type
4. fuel injection nozzle aperture 0.4mm 0.3mm
5. injection advance angle is 29 ° 24 °
Peace and quiet dispersion
6. agent 0.06% (25 yuan/ton) does not have
Pour point depressant
7. oil circuit repacking; Add put the heavy oil cylinder, add put the heavy oil cylinder, electricity adds
The hot device of hot device
Three, combustion case: see attached list
Four, estimate:
(1) to oil circuit heat improve after, the heavy gas oil water blending fuel.Can on big craft, promote the use of.Produce very big energy-saving effect and economic benefit.
1 Spring Festival holidays diesel oil:
Existing 1 year of 1500T/ consumption * (1-40%)=900T can be burnt 3 years with diesel oil.
2 Spring Festival holidays funds:
* 1400/ yuan/T=210 of 1500T/ consumption now burns diesel oil year expenditure for ten thousand yuan.
* 850 yuan/T=127.5 of 1500T/ consumption changes burning upgrading oil year expenditure for ten thousand yuan
Ten thousand yuan of Spring Festival holidays funds of 2,100,000 yuan-127.5=82.5
82.5 ten thousand yuan of ÷ 2,100,000 yuan=39.3% energy-conservation fund rates
(2) at water to unanimity, traction weight is identical, the speed of a ship or plane is constant.Per hour oil consumption:
Upgrading oil rate of economizing gasoline.
(3) during burning 0# diesel oil, chimney emits Dark grey, change burn upgrading oil after, be light mist look, discharging obviously improves, waste heat supply temperature improves 10 ℃, reaches 370 ° and can directly be used in upgrading oil and heat.
When (four) combustion time was longer, the main frame operating mode occurred slight uneven, and rotating speed decline 10 is changeed, and checks that when stopping in Nanjing bur is arranged on the purifier, is oily, influences oil inlet quantity.Problem is using this oil not filter out impurity on request with (one).(2) heat and also be lower than requirement 10-20 ℃.(3) do not bought peace and quiet decentralized additive, caused purifier partly to be obstructed, fuel feeding is not enough and cause slight imbalance.
(5) each cylinder detonation pressure is measured record (Instrument measuring top pressure)
The first cylinder 59kg; The second cylinder 58kg; The 3rd cylinder 58kg; The 4th cylinder 58kg; The 5th cylinder 58kg; The 6th cylinder 57kg; Than regulation detonation pressure 55kg, surpass 2-4kg, point out through consulting the engineers of making Diesel Engine Plant: be longer than 0# diesel oil slightly because of upgrading oil delay period and after burning period, reach correct compression ratio, should strengthen injection advance angle, with 29 °-32 ° for well, the change formality is simple.
Carried out the modulation work of fuel oil of the present invention on November 18th, 1.
One, trial-production place
Zhenjiang, Jiangsu Province ship affair main office seven numbering head blockships.
Two, weather condition
Weather cold, about 0 ℃ of outside air temperature.
Three, trial-manufacturing process
1, prescription: 0# bavin 50kg, 35kg residual oil (200-250 heavy oil), tap water 15kg, sodium alginate 0.4kg
2, tool using, self-control agitation vat (the old diesel bucket transformation of the way), 4 (wide 20mm of blade of rotating shaft (20 yuan of steel car systems of φ) axle leaf, thick 5mm), one in old drilling machine requires 750 rev/mins of rotating speeds to be used to drive rotating shaft and stirs, self-control two of strainers (wire cloth 200 orders), stove and oil holder.
3, process: earlier residual oil is heated about 80 ℃, tap water is heated to about 20 ℃, adds additive and stirring.Pour residual oil, tap water into agitation vat successively, stirred 3 minutes, again diesel oil is poured into to stir and the small amount of precipitate thing is arranged at the bottom of seeing after (25 ℃ of oil temperature) in 10 minutes barrel, on stove, heat to throw out and dissolve back restir 5 minutes, after stir finishing agitation vat lifted to stove and heat about 70 ℃, filter the back through filter and store stand-by.New system oil color and residual oil are homochromy-black.The oily 45.5kg of the finished product first time
Four, sample real machine test
1, after the mixing oil output after filtering immediately in Jiangsu the right S195 diesel engine of surveying of No. 24, (confession) oily motor vessels test, play menophania and start successfully not stop the analysis of experiments reason for several times, the chances are because the filter stamen of S195 diesel engine, because of the big and intransitable reason of mixing oil viscosity, so can't normal fuel injection and fail to start.
For test is proceeded, through trial-production group's research, decision directly enters injection pump with this fuel oil and carries out real machine test.And take the composite fuels emulsion heated earlier and after 70 ℃, add fuel tank again, in once success of hand starting in 35 fens in 11 o'clock on the 22nd.Open drive promptly enters after 20 minutes and operates at full capacity at full speed, and the exhaust colour of eating behind the load is denseer black smoke, changes light after ten minutes gradually.In reaching 5 hours commissioning process, exhaust occurred once that neglecting of short period of time is dense neglects light phenomenon, but the exhaust colour of overwhelming majority times all belongs to normally.Added composite fuels (not heating) at 13: 15 and continue test run, diesel engine runs to parking in 16: 30 always, and test run total time is 5 hours 5 minutes.Once occurred auto stop in operational process No. one time, oil circuit enters that air causes through due to looking into non-fuel oil but because of the supply fuel oil time, and the oil circuit air is got rid of back one push start and worked well.Real machine (8.8kws1 95 diesel engines) at full speed load running after 6 hours situation and novel composite fuels without filtering the actual preliminary brief summary that directly enters injection pump work for down:
One, novel mixing oil is energy-conservation product, and rate of economizing gasoline can reach 45-50%.
Two, novel fuel has value for applications but draws a conclusion after full scale test again, and the market outlook after estimating to promote the use of still are wide.(this fuel oil can be used as the substitute products of 0# bavin)
Three, have this problem of abnormal phenomenon (dense suddenly, light suddenly) entering ordinary production during exhaust colour, stir back or climatope can be resolved when suitable.
Four, compare use with the 0# bavin on same machine: vibration had deflagration phenomenon greatly when machine used 0# diesel oil during with mixing, and it is more rough to work.(may be to break out the strong reason of power, the further research of still needing.)
Viscosity was big when five, winter was owing to the fuel oil cold conditions, and the starting cold difficulty is normal as if electric cranking use cold oil starting cold when filtering stamen temperature 0 ℃ of left and right sides for needing to improve diesel fuel filter in use on the S195 type machine, then needs preheating as hand starting.(oil, machine all need give heat)
Six, made fuel oil uses after depositing eight days and does not find oily water separation.
Upgrading fuel oil outward appearance is the bright liquid of black, compares tasteless with standard 0# diesel oil.Deposit 1 year outward appearance no change.
Specify Anqing Petrochemical Company central laboratory its quality of determination and analysis through economizing standard Weights and Measures Bureau
22 ℃ of kg/m of density 30.3033 carbon content % 6.34
Mechanical impurity 0.625
Cetane value 45 alum content PPH 1.1
Low heat value kilocalorie/kg 3.210 moisture % 14.5
20 ℃ of 105.7 flash-point of kinematic viscosity ℃>100
Carbon residue % 2.1 acid number % 0.25
Reaction is neutral
Ash content 0.289 glue value is blown injustice
Corrode qualified condensation point ℃ 1
Color 3 cold filter clogging temperatures ℃>15
Oxidation stability is filtered not get off (pressing SV2125%2)

Claims (4)

1. the diesel oil with modified with bioenzyme, heavy oil, water fuel emulsion, it is characterized in that: this emulsion is composed as follows:
Diesel oil accounts for 35-45 part (weight)
Heavy oil accounts for 35-45 part (weight)
Water accounts for 15-25 part (weight)
Biological enzyme accounts for 0.1-0.5 part (weight).
2. emulsion according to claim 1 is characterized in that: said biological enzyme is a sodium alginate.
3. emulsion according to claim 1 is characterized in that: said diesel oil is selected from 0# diesel oil or gas oil.
4. emulsion according to claim 1 is characterized in that: also available residual oil of said heavy oil or sump oil substitute.
CN 96109164 1996-08-05 1996-08-05 Diesel oil, heavy oil and water fuel emulsion modified by biological enzyme Pending CN1172845A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 96109164 CN1172845A (en) 1996-08-05 1996-08-05 Diesel oil, heavy oil and water fuel emulsion modified by biological enzyme

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 96109164 CN1172845A (en) 1996-08-05 1996-08-05 Diesel oil, heavy oil and water fuel emulsion modified by biological enzyme

Publications (1)

Publication Number Publication Date
CN1172845A true CN1172845A (en) 1998-02-11

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Country Status (1)

Country Link
CN (1) CN1172845A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100319241A1 (en) * 2009-06-19 2010-12-23 Cyubu Enzyme Ltd. Fuel production method, fuel production apparatus, and fuel oil
CN101928615A (en) * 2009-06-19 2010-12-29 有限会社中部酵素 Fuel production method, fuel production device, and fuel oil
CN103194283A (en) * 2013-04-15 2013-07-10 东木奥森科技(天津)有限公司 Micell activity bio-enzyme fuel oil synergist
CN103409178A (en) * 2013-06-27 2013-11-27 英杰惠能(北京)能源新技术有限公司 Diesel fuel additive composition containing biological enzyme
CN103421552A (en) * 2013-07-30 2013-12-04 英杰惠能(北京)能源新技术有限公司 Diesel oil improver component containing biological enzyme and preparation method and application thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100319241A1 (en) * 2009-06-19 2010-12-23 Cyubu Enzyme Ltd. Fuel production method, fuel production apparatus, and fuel oil
CN101928615A (en) * 2009-06-19 2010-12-29 有限会社中部酵素 Fuel production method, fuel production device, and fuel oil
CN101928615B (en) * 2009-06-19 2013-11-06 有限会社中部酵素 Fuel production method, fuel production apparatus, and fuel oil
US9023120B2 (en) * 2009-06-19 2015-05-05 Cyuba Enzyme Ltd. Fuel production method, fuel production apparatus, and fuel oil
CN103194283A (en) * 2013-04-15 2013-07-10 东木奥森科技(天津)有限公司 Micell activity bio-enzyme fuel oil synergist
CN103409178A (en) * 2013-06-27 2013-11-27 英杰惠能(北京)能源新技术有限公司 Diesel fuel additive composition containing biological enzyme
CN103409178B (en) * 2013-06-27 2015-11-04 英杰惠能(北京)能源新技术有限公司 A kind of composition of additive for diesel oil containing biological enzyme
CN103421552A (en) * 2013-07-30 2013-12-04 英杰惠能(北京)能源新技术有限公司 Diesel oil improver component containing biological enzyme and preparation method and application thereof
CN103421552B (en) * 2013-07-30 2015-06-17 英杰惠能(北京)能源新技术有限公司 Diesel oil improver component containing biological enzyme and preparation method and application thereof

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