CN116885032A - Waveguide integrated photodetector and preparation method thereof - Google Patents
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- H10F30/222—Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors the devices being sensitive to infrared, visible or ultraviolet radiation the devices having only one potential barrier, e.g. photodiodes the potential barrier being a PN heterojunction
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Abstract
本发明公开了一种波导集成型光电探测器及其制备方法。所述波导集成型光电探测器包括波导和范德华异质结;所述范德华异质结包括设置在所述波导一侧的p型二维半导体层、以及设置在所述p型二维半导体层背对所述波导一侧的n型二维半导体层。本发明中,电子和空穴的流动会在范德华异质结界面处形成电势突变而产生内建电场,该内建电场可作为无光照下器件中自由载流子运动的势垒,减小暗电流;同时也可加快光生载流子的分离,提升载流子提取率,进而提升光响应度和光响应速率。
The invention discloses a waveguide integrated photoelectric detector and a preparation method thereof. The waveguide integrated photodetector includes a waveguide and a van der Waals heterojunction; the van der Waals heterojunction includes a p-type two-dimensional semiconductor layer disposed on one side of the waveguide, and a p-type two-dimensional semiconductor layer disposed on the back of the waveguide. An n-type two-dimensional semiconductor layer on one side of the waveguide. In the present invention, the flow of electrons and holes will form a sudden change in potential at the van der Waals heterojunction interface to generate a built-in electric field. The built-in electric field can serve as a potential barrier for free carrier movement in the device without light, reducing dark spots. current; at the same time, it can also speed up the separation of photogenerated carriers, improve the carrier extraction rate, and thereby improve the photoresponsivity and photoresponse rate.
Description
技术领域Technical field
本发明涉及光通信器件技术领域,特别涉及一种波导集成型光电探测器及其制备方法。The invention relates to the technical field of optical communication devices, and in particular to a waveguide integrated photodetector and a preparation method thereof.
背景技术Background technique
在光通信领域中,光电探测器是将光信号转化成电信号的核心传感组件,其波长属于近红外波段的范围(0.76-3.00μm),在片上集成光回路中已经有大量的研究。In the field of optical communications, photodetectors are the core sensing component that converts optical signals into electrical signals. Its wavelength belongs to the near-infrared band (0.76-3.00μm), and there has been a lot of research on on-chip integrated optical circuits.
为了满足硅基光电子集成芯片发展的需求,已有研究采用2D(2dimensional,二维)材料,2D材料指在一个维度具有原子级厚度的材料,2D材料具有很高的机械灵活性和透明度,表面无悬挂键可任意堆叠,带隙覆盖宽,载流子迁移率高,可柔性集成的特性,因此能够满足硅光子芯片对宽光谱、高性能、集成化光电探测器的要求。从而可通过选择不同2D材料来构建工作在不同光谱范围的片上集成光电探测器,但对探测器的带宽、响应度和线性方面的优化还处于刚起步阶段;目前仍存在如何有效抑制暗电流、如何提升响应度和响应速率等诸多问题。In order to meet the needs of the development of silicon-based optoelectronic integrated chips, there have been studies using 2D (2dimensional, two-dimensional) materials. 2D materials refer to materials with atomic thickness in one dimension. 2D materials have high mechanical flexibility and transparency. The surface It can be stacked arbitrarily without dangling bonds, has wide band gap coverage, high carrier mobility, and can be flexibly integrated. Therefore, it can meet the requirements of silicon photonic chips for wide spectrum, high performance, and integrated photodetectors. Therefore, on-chip integrated photodetectors working in different spectral ranges can be constructed by selecting different 2D materials. However, the optimization of the bandwidth, responsivity and linearity of the detector is still in its infancy; there are still questions about how to effectively suppress dark current, How to improve responsiveness and response rate and many other issues.
发明内容Contents of the invention
本发明的主要目的是提出一种波导集成型光电探测器及其制备方法,旨在解决现有技术中如何有效抑制暗电流、如何提升响应度和响应速率等诸多问题。The main purpose of the present invention is to propose a waveguide integrated photodetector and a preparation method thereof, aiming to solve many problems in the existing technology such as how to effectively suppress dark current and how to improve the responsivity and response rate.
为实现上述目的,本发明提出一种波导集成型光电探测器,包括波导和范德华异质结;所述范德华异质结包括设置在所述波导一侧的p型二维半导体层、以及设置在所述p型二维半导体层背对所述波导一侧的n型二维半导体层。In order to achieve the above object, the present invention proposes a waveguide integrated photodetector, which includes a waveguide and a van der Waals heterojunction; the van der Waals heterojunction includes a p-type two-dimensional semiconductor layer disposed on one side of the waveguide, and a p-type two-dimensional semiconductor layer disposed on one side of the waveguide. The p-type two-dimensional semiconductor layer faces away from the n-type two-dimensional semiconductor layer on one side of the waveguide.
可选地,所述p型二维半导体层的材料包括黑磷;和/或,所述n型二维半导体层的材料包括MoTe2、MoSe2、WSe2中的一种。Optionally, the material of the p-type two-dimensional semiconductor layer includes black phosphorus; and/or the material of the n-type two-dimensional semiconductor layer includes one of MoTe 2 , MoSe 2 , and WSe 2 .
可选地,所述p型二维半导体层的厚度为1~200nm;和/或,所述n型二维半导体层的厚度为1~200nm。Optionally, the thickness of the p-type two-dimensional semiconductor layer is 1 to 200 nm; and/or the thickness of the n-type two-dimensional semiconductor layer is 1 to 200 nm.
可选地,所述波导的材料包括硅、氮化硅、铌酸锂中的一种;和/或,所述波导包括矩形波导、脊型波导或槽型波导。Optionally, the material of the waveguide includes one of silicon, silicon nitride, and lithium niobate; and/or, the waveguide includes a rectangular waveguide, a ridge waveguide, or a groove waveguide.
可选地,所述波导具有第一侧端部以及连接第一侧端部的第二侧端部,其中一所述第一侧端部用以接收入射光;Optionally, the waveguide has a first side end and a second side end connected to the first side end, wherein one of the first side ends is used to receive incident light;
所述范德华异质结在所述波导的周侧超出所述波导设置,以形成位于所述波导的外周的第一外围区域;The van der Waals heterojunction is disposed beyond the waveguide on a peripheral side of the waveguide to form a first peripheral region located on the outer periphery of the waveguide;
所述波导集成型光电探测器还包括:The waveguide integrated photodetector also includes:
衬底,所述衬底设置在所述波导的另一侧,且所述衬底在所述波导的周侧超出所述波导设置,以形成位于所述波导的外周的第二外围区域;A substrate, the substrate is disposed on the other side of the waveguide, and the substrate is disposed beyond the waveguide on the peripheral side of the waveguide to form a second peripheral area located on the outer periphery of the waveguide;
第一金属电极,设置在所述衬底上的第二外围区域,且位于所述波导的第二侧端部的外围,所述第一金属电极与波导之间间隔预设距离,所述第一金属电极与所述范德华异质结的第一外围区域接触;以及,A first metal electrode is provided in the second peripheral area on the substrate and is located at the periphery of the second side end of the waveguide. The first metal electrode is separated from the waveguide by a preset distance. a metal electrode in contact with the first peripheral region of the van der Waals heterojunction; and,
第二金属电极,所述第二金属电极设置于所述范德华异质结背对所述波导的一侧。A second metal electrode is provided on a side of the van der Waals heterojunction facing away from the waveguide.
可选地,所述第二金属电极的宽度d1小于所述第一金属电极的宽度d2。Optionally, the width d1 of the second metal electrode is smaller than the width d2 of the first metal electrode.
可选地,所述第一金属电极与所述波导之间的预设距离为0.2~5μm。Optionally, the preset distance between the first metal electrode and the waveguide is 0.2-5 μm.
可选地,所述波导厚度为200~500nm,宽度为500~1500nm。Optionally, the thickness of the waveguide is 200-500nm, and the width is 500-1500nm.
可选地,所述第一金属电极和所述第二金属电极的厚度均为40~100nm;和/或,所述衬底的厚度为0.4~0.7mm。Optionally, the thickness of the first metal electrode and the second metal electrode is both 40-100 nm; and/or the thickness of the substrate is 0.4-0.7 mm.
本发明还提供了一种波导集成型光电探测器的制备方法,所述范德华异质结中p型二维半导体层和n型二维半导体层通过机械剥离法制备得到。The invention also provides a method for preparing a waveguide integrated photodetector. The p-type two-dimensional semiconductor layer and the n-type two-dimensional semiconductor layer in the van der Waals heterojunction are prepared by mechanical stripping.
本发明的技术方案中,波导集成型光电探测器包括波导和范德华异质结;所述范德华异质结包括设置在所述波导一侧的p型二维半导体层、以及设置在所述p型二维半导体层背对所述波导一侧的n型二维半导体层。由此,电子和空穴的流动会在范德华异质结界面处形成电势突变而产生内建电场,该内建电场可作为无光照下器件中自由载流子运动的势垒,减小暗电流;同时也可加快光生载流子的分离,提升载流子提取率,进而提升光响应度和光响应速率。In the technical solution of the present invention, the waveguide-integrated photodetector includes a waveguide and a van der Waals heterojunction; the van der Waals heterojunction includes a p-type two-dimensional semiconductor layer provided on one side of the waveguide, and a p-type two-dimensional semiconductor layer provided on one side of the waveguide. The two-dimensional semiconductor layer faces away from the n-type two-dimensional semiconductor layer on one side of the waveguide. As a result, the flow of electrons and holes will form a sudden change in potential at the van der Waals heterojunction interface to generate a built-in electric field. This built-in electric field can serve as a potential barrier for free carrier movement in the device without light, reducing dark current. ; At the same time, it can also speed up the separation of photogenerated carriers, improve the carrier extraction rate, and thereby improve the photoresponsivity and photoresponse rate.
附图说明Description of the drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图示出的结构获得其他的附图。In order to explain the embodiments of the present invention or the technical solutions in the prior art more clearly, the drawings needed to be used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings in the following description are only These are some embodiments of the present invention. For those of ordinary skill in the art, other drawings can be obtained based on the structures shown in these drawings without exerting creative efforts.
图1为本发明一实施例所提供的波导集成型光电探测器截面结构示意图;Figure 1 is a schematic cross-sectional structural diagram of a waveguide integrated photodetector provided by an embodiment of the present invention;
图2为本发明一实施例所提供的波导集成型光电探测器立体结构示意图;Figure 2 is a schematic three-dimensional structural diagram of a waveguide integrated photodetector provided by an embodiment of the present invention;
图3为本发明一实施例所提供的波导集成型光电探测器采用BP/MoTe2范德华异质结,波导集成型光电探测器热平衡时BP/MoTe2的能带图;Figure 3 is a waveguide-integrated photodetector provided by an embodiment of the present invention using a BP/MoTe 2 van der Waals heterojunction, and the energy band diagram of the BP/MoTe 2 at thermal equilibrium of the waveguide-integrated photodetector;
图4为本发明一实施例所提供的波导集成型光电探测器中BP/MoTe2范德华异质结与矩形硅波导直接接触部分的模场分布图。Figure 4 is a mode field distribution diagram of the direct contact portion between the BP/MoTe 2 van der Waals heterojunction and the rectangular silicon waveguide in the waveguide integrated photodetector provided by an embodiment of the present invention.
附图标号说明:Explanation of reference numbers:
本发明目的的实现、功能特点及优点将结合实施例,参照附图做进一步说明。The realization of the purpose, functional features and advantages of the present invention will be further described with reference to the embodiments and the accompanying drawings.
具体实施方式Detailed ways
为使本发明实施例的目的、技术方案和优点更加清楚,下面将对本发明实施例中的技术方案进行清楚、完整地描述。实施例中未注明具体条件者,按照常规条件或制造商建议的条件进行。所用试剂或仪器未注明生产厂商者,均为可以通过市售购买获得的常规产品。另外,全文中出现的“和/或”的含义,包括三个并列的方案,以“A和/或B”为例,包括A方案、或B方案、或A和B同时满足的方案。此外,各个实施例之间的技术方案可以相互结合,但是必须是以本领域普通技术人员能够实现为基础,当技术方案的结合出现相互矛盾或无法实现时应当认为这种技术方案的结合不存在,也不在本发明要求的保护范围之内。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the objectives, technical solutions, and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be described clearly and completely below. If the specific conditions are not specified in the examples, the conditions should be carried out according to the conventional conditions or the conditions recommended by the manufacturer. If the manufacturer of the reagents or instruments used is not indicated, they are all conventional products that can be purchased commercially. In addition, the meaning of "and/or" appearing in the entire text includes three parallel solutions. Taking "A and/or B" as an example, it includes solution A, or solution B, or a solution that satisfies both A and B at the same time. In addition, the technical solutions in the various embodiments can be combined with each other, but it must be based on what a person of ordinary skill in the art can implement. When the combination of technical solutions is contradictory or cannot be realized, it should be considered that such a combination of technical solutions does not exist. , nor within the protection scope required by the present invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without making creative efforts fall within the scope of protection of the present invention.
为了满足硅基光电子集成芯片发展的需求,波导集成型光电探测器逐渐成为硅基光电探测器的研究重点,且具有更优异的产业化价值。在波导集成型2D材料光电探测器的典型研究中,基于石墨烯的光电探测器的带宽可以达到150GHz,但石墨烯零带隙的特性会造成较大的暗电流,以及器件中较大的金属接触面积会带来大的损耗。也有采用基于2D材料p-n同质结构筑场效应晶体管,虽然器件在零偏置下具有>10GHz的带宽响应,但在抑制热噪声(减小暗电流)和提升光响应度方面仍存在缺陷。In order to meet the development needs of silicon-based optoelectronic integrated chips, waveguide integrated photodetectors have gradually become the focus of research on silicon-based photodetectors and have better industrialization value. In typical research on waveguide-integrated 2D material photodetectors, the bandwidth of graphene-based photodetectors can reach 150GHz, but the zero-bandgap characteristics of graphene will cause larger dark currents and larger metal components in the device. The contact area will cause large losses. There are also field-effect transistors based on p-n homogeneous structures of 2D materials. Although the devices have a bandwidth response of >10GHz under zero bias, they still have shortcomings in suppressing thermal noise (reducing dark current) and improving photoresponsivity.
鉴于此,参阅图1-2,本发明提出一种波导集成型光电探测器100,包括波导1和范德华异质结2;所述范德华异质结2包括设置在所述波导1一侧的p型二维半导体层21、以及设置在所述p型二维半导体层21背对所述波导1一侧的n型二维半导体层22。In view of this, referring to Figures 1-2, the present invention proposes a waveguide integrated photodetector 100, which includes a waveguide 1 and a van der Waals heterojunction 2; the van der Waals heterojunction 2 includes a p disposed on one side of the waveguide 1 type two-dimensional semiconductor layer 21, and an n-type two-dimensional semiconductor layer 22 provided on the side of the p-type two-dimensional semiconductor layer 21 facing away from the waveguide 1.
本发明的技术方案中,电子和空穴的流动会在范德华异质结2界面处形成电势突变而产生内建电场,该内建电场可作为无光照下器件中自由载流子运动的势垒,异质结界面处形成的势垒,会抑制随机载流子的传输,进而降低器件中的暗电流和噪声水平;同时异质结界面处势垒产生的内建电场可以有效地分离光生载流子分离,从而导致更快速的光响应,拓展有效带宽,提升光响应度和光响应速率。In the technical solution of the present invention, the flow of electrons and holes will form a sudden change in potential at the interface of the van der Waals heterojunction 2 to generate a built-in electric field. The built-in electric field can serve as a potential barrier for free carrier movement in the device without light. , the potential barrier formed at the heterojunction interface will inhibit the transmission of random carriers, thereby reducing the dark current and noise level in the device; at the same time, the built-in electric field generated by the potential barrier at the heterojunction interface can effectively separate the photogenerated carriers. The separation of carriers leads to faster optical response, expands the effective bandwidth, and improves photoresponsivity and photoresponse rate.
在本发明的一些实施例中,所述p型二维半导体层21的材料包括黑磷。所述n型二维半导体层22的材料包括MoTe2、MoSe2、WSe2中的一种。In some embodiments of the present invention, the material of the p-type two-dimensional semiconductor layer 21 includes black phosphorus. The material of the n-type two-dimensional semiconductor layer 22 includes one of MoTe 2 , MoSe 2 , and WSe 2 .
异质结的特性主要由界面的能带匹配情况决定,根据界面能带匹配特点,可将异质结分为Ⅰ型跨能隙,Ⅱ型交错能隙和Ⅲ型无重叠型。其中Ⅰ型和Ⅱ型均能拓展有效带隙,并且会在界面处由于电势突变形成内建电场。黑磷是一种窄带隙、高载流子迁移率的直接带隙2D材料,其具有面内各向异性,使用该材料作为探测器的光敏层,具有很强的光吸收并且可直接与硅波导异质集成。本发明实施例中n型二维半导体层22例如MoTe2、MoSe2、WSe2与黑磷直接通过范德华力紧密结合形成Ⅰ型范德华异质结,其接触界面能带弯曲会形成内建电场,该内建电场具有高效抑制自由载流子运动(减小暗电流)和加速光生载流子界面分离的作用。The characteristics of heterojunctions are mainly determined by the energy band matching of the interface. According to the energy band matching characteristics of the interface, heterojunctions can be divided into type I spanning energy gap, type II staggered energy gap and type III non-overlapping type. Among them, both type I and type II can expand the effective band gap, and will form a built-in electric field at the interface due to a sudden change in potential. Black phosphorus is a direct band gap 2D material with narrow band gap and high carrier mobility. It has in-plane anisotropy. This material is used as the photosensitive layer of the detector. It has strong light absorption and can be directly combined with silicon. Waveguide heterogeneous integration. In the embodiment of the present invention, the n-type two-dimensional semiconductor layer 22 such as MoTe 2 , MoSe 2 , WSe 2 and black phosphorus are directly tightly combined through van der Waals forces to form a type I van der Waals heterojunction, and the energy band bending of the contact interface will form a built-in electric field. The built-in electric field has the effect of effectively suppressing the movement of free carriers (reducing dark current) and accelerating the interface separation of photogenerated carriers.
参见图3,图3为少层2D半导体黑磷/MoTe2范德华异质结的能带图,其中黑磷和MoTe2的带隙分别为~0.3eV和~0.9eV,该范德华异质结构成覆盖了通信波段的Ⅰ型有效能带隙。热平衡状态下费米能级EF靠近p型半导体黑磷的价带(EV)和n型半导体MoTe2的导带(EC),形成一个典型的PN结。由于电子(图3中黑色圆圈“-”标记)、空穴(图3中黑色圆圈“+”标记)的流动会在异质结界面处形成电势突变而产生内建电场(图3阴影区域),该内建电场可作为无光照下器件中自由载流子运动的势垒,减小暗电流;同时也可加快光生载流子的分离,提升载流子提取率,进而提升光响应度。See Figure 3. Figure 3 is an energy band diagram of the few-layer 2D semiconductor black phosphorus/MoTe 2 van der Waals heterojunction. The band gaps of black phosphorus and MoTe 2 are ~0.3eV and ~0.9eV respectively. The van der Waals heterostructure is composed of Type I effective energy band gap covering the communication band. In the thermal equilibrium state, the Fermi level EF is close to the valence band (EV) of the p-type semiconductor black phosphorus and the conduction band (EC) of the n-type semiconductor MoTe2, forming a typical PN junction. Due to the flow of electrons (marked by the black circle "-" in Figure 3) and holes (marked by the black circle "+" in Figure 3), a sudden change in potential is formed at the heterojunction interface, resulting in a built-in electric field (shaded area in Figure 3) , the built-in electric field can serve as a potential barrier for free carrier movement in the device without light, reducing dark current; it can also speed up the separation of photogenerated carriers, improve the carrier extraction rate, and thereby improve the photoresponsivity.
在本发明的一些实施例中,所述p型二维半导体层21的厚度为1~200nm;所述n型二维半导体层22的厚度为1~200nm。在该厚度下的p型二维半导体层21或n型二维半导体层22可以为单层,也可以为少层。此处,少层是指二维半导体材料的厚度较薄(例如小于200nm),厚度较薄的少层半导体的形成原因是:半导体层与层之间是依靠结合力较弱的范德华力结合在一起,能够轻易的使用外力来打破层间束缚,从而形成厚度较薄的少层半导体。In some embodiments of the present invention, the thickness of the p-type two-dimensional semiconductor layer 21 is 1-200 nm; the thickness of the n-type two-dimensional semiconductor layer 22 is 1-200 nm. The p-type two-dimensional semiconductor layer 21 or the n-type two-dimensional semiconductor layer 22 with this thickness may be a single layer or a few layers. Here, few-layer refers to the thin thickness of the two-dimensional semiconductor material (for example, less than 200nm). The reason for the formation of the thinner few-layer semiconductor is that the semiconductor layers are bonded together by the weak van der Waals force. At the same time, external force can be easily used to break the interlayer constraints, thereby forming a thinner few-layer semiconductor.
在一种可行的方式中,所述波导1的材料包括硅、氮化硅、铌酸锂中的一种;所述波导1包括矩形波导、脊型波导或槽型波导波导。In a feasible manner, the material of the waveguide 1 includes one of silicon, silicon nitride, and lithium niobate; the waveguide 1 includes a rectangular waveguide, a ridge waveguide, or a groove waveguide.
在本发明的一些实施例中,所述波导1具有第一侧端部11以及连接第一侧端部11的第二侧端部12,其中一所述第一侧端部11用以接收入射光;所述范德华异质结2在所述波导1的周侧超出所述波导1设置,以形成位于所述波导1的外周的第一外围区域23;所述波导1集成型光电探测器还包括:衬底3、第一金属电极4和第二金属电极5。其中,所述衬底3设置在所述波导1的另一侧,且所述衬底3在所述波导1的周侧超出所述波导1设置,以形成位于所述波导1的外周的第二外围区域31;所述第一金属电极4设置在所述衬底3上的第二外围区域31,且位于所述波导1的第二侧端部12的外围,所述第一金属电极4与波导1之间间隔预设距离,所述第一金属电极4与所述范德华异质结2的第一外围区域23接触;所述第二金属电极5设置于所述范德华异质结2背对所述波导1的一侧。In some embodiments of the present invention, the waveguide 1 has a first side end 11 and a second side end 12 connected to the first side end 11 , wherein one of the first side end 11 is used to receive incident light. Light; the van der Waals heterojunction 2 is arranged beyond the waveguide 1 on the peripheral side of the waveguide 1 to form a first peripheral area 23 located on the outer periphery of the waveguide 1; the waveguide 1 integrated photodetector also It includes: substrate 3, first metal electrode 4 and second metal electrode 5. Wherein, the substrate 3 is disposed on the other side of the waveguide 1 , and the substrate 3 is disposed beyond the waveguide 1 on the peripheral side of the waveguide 1 to form a third layer located on the outer periphery of the waveguide 1 . Two peripheral areas 31; the first metal electrode 4 is provided in the second peripheral area 31 on the substrate 3 and is located at the periphery of the second side end 12 of the waveguide 1. The first metal electrode 4 Separated from the waveguide 1 by a preset distance, the first metal electrode 4 is in contact with the first peripheral region 23 of the van der Waals heterojunction 2; the second metal electrode 5 is disposed on the back of the van der Waals heterojunction 2. to one side of the waveguide 1.
本发明提供的波导1集成型光电探测器中,一方面黑磷作为吸光层材料,在无光通过波导1的情况下,范德华异质结2面内建电场可作为自由载流子运动的势垒,因此器件中将会有小于基于单一2D材料光电探测器的暗电流。当波导1中有光(例如波长范围为850nm-2000nm的光)通过时,波导1中光场模式的倏逝波在空间上与黑磷有重叠部分,如图4所示。黑磷会吸收光子的能量将其价带的电子激发至导带上而形成电子-空穴对,此时在2D材料特有的面外纳米级尺寸产生的量子受限效应下,这些光生电子-空穴对会通过很强的库伦相互作用束缚在一起具有局域的特性(激子特性)。该特性会延长载流子寿命,使得在其复合前有足够的时间对光生载流子进行提取形成光电流,从而拥有高的光增益。这个过程完成了光信号到电信号的转换。另一方面,该波导1集成型光电探测器中载流子收集方向是垂直于波导1方向的,光的入射方向与载流子的输运方向垂直,从而可以基本解除响应度与带宽的相互制约,在提高带宽的同时也可以保证相对较高的器件响应度。与现有技术中的平行于波导1方向收集载流子的策略相比,可有效弥补载流子在2D材料中较长的传输时间,从而拥有更小的渡越时间和更快的响应速度。In the waveguide 1 integrated photodetector provided by the present invention, on the one hand, black phosphorus is used as the light-absorbing layer material. When no light passes through the waveguide 1, the built-in electric field on the two surfaces of the van der Waals heterojunction can serve as a potential for free carrier movement. barrier, so there will be less dark current in the device than a photodetector based on a single 2D material. When light (for example, light with a wavelength range of 850nm-2000nm) passes through the waveguide 1, the evanescent wave of the light field mode in the waveguide 1 has a spatial overlap with the black phosphorus, as shown in Figure 4. Black phosphorus absorbs the energy of photons and excites electrons in its valence band to the conduction band to form electron-hole pairs. At this time, under the quantum confinement effect caused by the unique out-of-plane nanoscale size of 2D materials, these photogenerated electrons - The hole pairs are bound together through strong Coulomb interactions and have localized properties (exciton properties). This feature will extend the carrier lifetime, allowing enough time to extract the photogenerated carriers before recombination to form a photocurrent, thus having a high optical gain. This process completes the conversion of optical signals into electrical signals. On the other hand, the carrier collection direction in the waveguide 1 integrated photodetector is perpendicular to the direction of the waveguide 1, and the incident direction of light is perpendicular to the carrier transport direction, so that the interaction between responsivity and bandwidth can be basically eliminated. Constraint, while increasing the bandwidth, it can also ensure a relatively high device responsivity. Compared with the existing strategy of collecting carriers parallel to the waveguide 1 direction, it can effectively compensate for the longer transmission time of carriers in 2D materials, resulting in smaller transit time and faster response speed. .
需要说明的是,本发明实施例中,第二金属电极5设置于所述范德华异质结2背对所述波导1的一侧,而第一金属电极4设置在所述衬底3上的第二外围区域31,且位于所述波导1的第二侧端部12的外围,与所述范德华异质结2的第一外围区域23接触,第一金属电极4与波导1之间间隔预设距离。第一金属电极4作为漏极(Drain),第二金属电极5作为源极(Source),衬底3作为栅极(Gate)。如此设置的电极结构可施加沿垂直于波导1中光入射方向的电场,采用垂直于波导1方向施加偏压并沿此方向收集光生载流子,可以减小载流子的渡越时间。于此同时,本发明中采用沿垂直于波导1方向制作不对称的金属电极,能够有效减小金属-2D半导体间的接触电阻,使得电极的有效区域非常小,进而减小了整个回路的电阻电容。It should be noted that in the embodiment of the present invention, the second metal electrode 5 is disposed on the side of the van der Waals heterojunction 2 facing away from the waveguide 1 , and the first metal electrode 4 is disposed on the substrate 3 The second peripheral region 31 is located at the periphery of the second side end 12 of the waveguide 1 and is in contact with the first peripheral region 23 of the van der Waals heterojunction 2 . The first metal electrode 4 and the waveguide 1 are separated by a predetermined distance. Set distance. The first metal electrode 4 serves as a drain, the second metal electrode 5 serves as a source, and the substrate 3 serves as a gate. The electrode structure thus arranged can apply an electric field perpendicular to the direction of light incidence in the waveguide 1. By applying a bias voltage perpendicular to the direction of the waveguide 1 and collecting photogenerated carriers along this direction, the transit time of the carriers can be reduced. At the same time, in the present invention, asymmetric metal electrodes are made in the direction perpendicular to the waveguide 1, which can effectively reduce the contact resistance between the metal and the 2D semiconductor, making the effective area of the electrode very small, thereby reducing the resistance of the entire loop. capacitance.
本发明实施例中衬底3可以为重掺杂衬底3,例如重掺入硼的硅衬底,用Si(p++)表示。第一金属电极4和第二金属电极5可由金、钛、铬等导电金属制成。第一金属电极4和第二金属电极5可以是相同金属材料,也可以是不同金属材料。第一金属电极4和第二金属电极5可以是单一金属材料如金,也可以是复合金属材料,如铬和金的合金。In the embodiment of the present invention, the substrate 3 may be a heavily doped substrate 3, such as a silicon substrate heavily doped with boron, represented by Si(p++). The first metal electrode 4 and the second metal electrode 5 may be made of conductive metals such as gold, titanium, and chromium. The first metal electrode 4 and the second metal electrode 5 may be made of the same metal material or different metal materials. The first metal electrode 4 and the second metal electrode 5 may be a single metal material such as gold, or a composite metal material such as an alloy of chromium and gold.
在本发明的一些实施例中,所述第二金属电极5的宽度d1小于所述第一金属电极4的宽度d2。如此,顶部的第二金属电极5具有狭窄的接触点,该设计可有效减小整个回路的电容和电阻,进而提升器件的工作带宽。In some embodiments of the present invention, the width d1 of the second metal electrode 5 is smaller than the width d2 of the first metal electrode 4 . In this way, the second metal electrode 5 on the top has a narrow contact point. This design can effectively reduce the capacitance and resistance of the entire loop, thereby improving the operating bandwidth of the device.
在本发明的一些实施例中,所述第一金属电极4与所述波导1之间的预设距离为0.2~5μm。该预设距离控制在合适的范围内,在对第二金属电极5外加电压时,该器件产生的外电场能够存在垂直方向上穿过范德华异质结的垂直分量电场。该垂直方向是指由第二金属电极5指向波导1的方向。In some embodiments of the present invention, the preset distance between the first metal electrode 4 and the waveguide 1 is 0.2-5 μm. The preset distance is controlled within an appropriate range. When a voltage is applied to the second metal electrode 5, the external electric field generated by the device can have a vertical component electric field that passes through the van der Waals heterojunction in the vertical direction. The vertical direction refers to the direction from the second metal electrode 5 to the waveguide 1 .
在本发明的一些实施例中,所述波导1厚度为200~500nm,宽度为500~1500nm。In some embodiments of the present invention, the thickness of the waveguide 1 is 200-500 nm, and the width is 500-1500 nm.
在本发明的一些实施例中,所述第一金属电极4和所述第二金属电极5的厚度均为40~100nm;所述衬底3的厚度为0.4~0.7mm。In some embodiments of the present invention, the thickness of the first metal electrode 4 and the second metal electrode 5 is both 40 to 100 nm; the thickness of the substrate 3 is 0.4 to 0.7 mm.
本发明实施例还提供一种波导1集成型光电探测器的制备方法,所述范德华异质结2中p型二维半导体层21和n型二维半导体层22通过机械剥离法制备得到。Embodiments of the present invention also provide a method for preparing a waveguide 1 integrated photodetector. The p-type two-dimensional semiconductor layer 21 and the n-type two-dimensional semiconductor layer 22 in the van der Waals heterojunction 2 are prepared by a mechanical peeling method.
本发明提出的制备方法步骤简单,制备效率高;此外,本发明提出的波导1集成型光电探测器的制备方法,制备得到的波导1集成型光电探测器,具备了上述波导1集成型光电探测器的全部有益效果,在此不再一一赘述。The preparation method proposed by the present invention has simple steps and high preparation efficiency; in addition, the preparation method of the waveguide 1 integrated photodetector proposed by the present invention, the prepared waveguide 1 integrated photodetector has the above-mentioned waveguide 1 integrated photodetector All the beneficial effects of the device will not be repeated here.
以下结合具体实施例和附图对本发明的技术方案作进一步详细说明,应当理解,以下实施例仅仅用以解释本发明,并不用于限定本发明。The technical solution of the present invention will be further described in detail below with reference to specific embodiments and drawings. It should be understood that the following embodiments are only used to explain the present invention and are not intended to limit the present invention.
实施例1Example 1
参见图1,本实施例提供一种波导集成型光电探测器,其自下而上依次是:衬底、波导、少层黑磷层、少层MoTe2、第二金属电极,其中,少层黑磷层和少层MoTe2构成范德华异质结,波导具有第一侧端部以及连接第一侧端部的第二侧端部,其中一第一侧端部用以接收入射光;范德华异质结在波导的周侧超出所述波导设置,以形成位于波导的外周的第一外围区域。衬底在波导的周侧超出波导设置,以形成位于波导的外周的第二外围区域;第一金属电极设置在衬底上的第二外围区域,且位于波导的第二侧端部的外围,第一金属电极与波导之间间隔预设距离,第一金属电极与范德华异质结的第一外围区域接触。Referring to Figure 1, this embodiment provides a waveguide-integrated photodetector, which from bottom to top is: substrate, waveguide, few-layer black phosphorus layer, few-layer MoTe 2 , and second metal electrode, wherein the few-layer The black phosphorus layer and few-layer MoTe 2 form a van der Waals heterojunction. The waveguide has a first side end and a second side end connected to the first side end. One of the first side ends is used to receive incident light; the van der Waals heterojunction The mass junction is disposed beyond the waveguide on the circumferential side of the waveguide to form a first peripheral region located on the outer circumference of the waveguide. The substrate is disposed beyond the waveguide on the peripheral side of the waveguide to form a second peripheral area located on the outer periphery of the waveguide; the first metal electrode is disposed in the second peripheral area on the substrate and is located on the periphery of the second side end of the waveguide, The first metal electrode is separated from the waveguide by a preset distance, and the first metal electrode is in contact with the first peripheral region of the van der Waals heterojunction.
本实施例中少层黑磷层为100nm,少层MoTe2的厚度为100nm。波导的材料为硅,波导为矩形波导,波导厚度为200nm,宽度为500nm。第一金属电极和所述第二金属电极的材质均为金,第一金属电极和所述第二金属电极的厚度均为80nm;第二金属电极的宽度为500nm,所述第一金属电极的宽度为1μm,第一金属电极与所述波导之间的预设距离为0.2μm。衬底材料为标准SOI(Silicon On Insulator)晶圆,该晶圆自下而上依次是重掺杂硅衬底,厚度为0.4毫米,其主要起支撑整个器件和作为器件栅极(Gate)的作用。掺杂硅衬底上的埋氧层为二氧化硅,厚度为2μm,其主要起支撑整个器件的作用。In this embodiment, the thickness of the few-layer black phosphorus layer is 100 nm, and the thickness of the few-layer MoTe 2 is 100 nm. The material of the waveguide is silicon, the waveguide is a rectangular waveguide, the thickness of the waveguide is 200nm, and the width is 500nm. The first metal electrode and the second metal electrode are both made of gold, and the thickness of the first metal electrode and the second metal electrode is 80nm; the width of the second metal electrode is 500nm, and the thickness of the first metal electrode is 500nm. The width is 1 μm, and the preset distance between the first metal electrode and the waveguide is 0.2 μm. The substrate material is a standard SOI (Silicon On Insulator) wafer, which is a heavily doped silicon substrate from bottom to top with a thickness of 0.4 mm. It mainly supports the entire device and serves as the gate of the device. effect. The buried oxide layer on the doped silicon substrate is silicon dioxide with a thickness of 2 μm, which mainly plays the role of supporting the entire device.
实施例2-18Example 2-18
实施例2-18提供的波导集成型光电探测器与实施例1基本相同,不同之处在于材料或尺寸不同,该些不同之处具体请参见表1。The waveguide integrated photodetector provided in Embodiment 2-18 is basically the same as that in Embodiment 1, except that the materials or sizes are different. Please refer to Table 1 for details of these differences.
表1Table 1
表2Table 2
实施例19Example 19
本实施例提供波导集成型光电探测器的制备方法,该方法包括:This embodiment provides a method for preparing a waveguide integrated photodetector, which method includes:
本实施例衬底采用标准SOI(Silicon On Insulator)晶圆,该晶圆自下而上依次是重掺杂硅衬底,厚度为0.4毫米,其主要起支撑整个器件和作为器件栅极(Gate)的作用。掺杂硅衬底上的埋氧层为二氧化硅,厚度为2μm,其主要起支撑整个器件的作用。The substrate in this embodiment uses a standard SOI (Silicon On Insulator) wafer, which is a heavily doped silicon substrate from bottom to top with a thickness of 0.4 mm. It mainly supports the entire device and serves as the gate of the device. ) function. The buried oxide layer on the doped silicon substrate is silicon dioxide with a thickness of 2 μm, which mainly plays the role of supporting the entire device.
采用电子束曝光技术(Electron Beam Lithography,EBL)和电感耦合等离子体刻蚀(Inductively Coupled Plasma etching,ICP)技术,得到厚度为200nm、宽度为500nm的矩形硅波导。Using Electron Beam Lithography (EBL) and Inductively Coupled Plasma etching (ICP) technology, a rectangular silicon waveguide with a thickness of 200nm and a width of 500nm was obtained.
通过标准光刻工艺和电子束蒸镀技术沉积第一金属电极。The first metal electrode is deposited by standard photolithography processes and electron beam evaporation techniques.
将通过机械剥离法得到的少层2D半导体黑磷和少层2D半导体MoTe2依次转移到波导上,并将波导覆盖,且使得少层2D半导体黑磷和少层2D半导体MoTe2覆盖部分第一金属电极。The few-layer 2D semiconductor black phosphorus and the few-layer 2D semiconductor MoTe2 obtained by the mechanical stripping method are sequentially transferred to the waveguide, and the waveguide is covered, and the few-layer 2D semiconductor black phosphorus and the few-layer 2D semiconductor MoTe2 cover part of the first metal electrode .
通过标准光刻工艺和电子束蒸镀技术沉积第二金属电极,得到波导集成型光电探测器。The second metal electrode is deposited through standard photolithography process and electron beam evaporation technology to obtain a waveguide integrated photodetector.
以上实施例提供的波导集成型光电探测器均包括波导和范德华异质结。由此,电子和空穴的流动会在范德华异质结界面处形成电势突变而产生内建电场,该内建电场可作为无光照下器件中自由载流子运动的势垒,减小暗电流;同时也可加快光生载流子的分离,提升载流子提取率,进而提升光响应度。The waveguide integrated photodetectors provided in the above embodiments all include waveguides and van der Waals heterojunctions. As a result, the flow of electrons and holes will form a sudden change in potential at the van der Waals heterojunction interface to generate a built-in electric field. This built-in electric field can serve as a potential barrier for free carrier movement in the device without light, reducing dark current. ; At the same time, it can also speed up the separation of photogenerated carriers, improve the carrier extraction rate, and thereby improve the photoresponsivity.
以上仅为本发明的优选实施例,并非因此限制本发明的专利范围,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包括在本发明的专利保护范围内。The above are only preferred embodiments of the present invention, which do not limit the patent scope of the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention shall be included in the patent protection scope of the present invention.
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