CN1168597C - Antibacterial composite aluminium-plastics pipe - Google Patents
Antibacterial composite aluminium-plastics pipe Download PDFInfo
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- CN1168597C CN1168597C CNB011062215A CN01106221A CN1168597C CN 1168597 C CN1168597 C CN 1168597C CN B011062215 A CNB011062215 A CN B011062215A CN 01106221 A CN01106221 A CN 01106221A CN 1168597 C CN1168597 C CN 1168597C
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- Prior art keywords
- plastic
- layer
- antibacterial
- antibacterial composite
- organic
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 49
- 229920003023 plastic Polymers 0.000 title claims abstract description 48
- 239000004033 plastic Substances 0.000 title claims abstract description 48
- 239000002131 composite material Substances 0.000 title claims abstract description 19
- 239000010410 layer Substances 0.000 claims abstract description 27
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 8
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 8
- 239000012790 adhesive layer Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- -1 titanate ester Chemical class 0.000 claims description 7
- 230000002421 anti-septic effect Effects 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000004831 Hot glue Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 238000000137 annealing Methods 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical group OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 2
- 229920001617 Vinyon Polymers 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- LHMODQOIWONTGO-UHFFFAOYSA-N diphenylantimony;2-ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O.C=1C=CC=CC=1[Sb]C1=CC=CC=C1 LHMODQOIWONTGO-UHFFFAOYSA-N 0.000 claims description 2
- 150000003949 imides Chemical class 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims description 2
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 229960003500 triclosan Drugs 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 241000894006 Bacteria Species 0.000 abstract description 4
- 241000222122 Candida albicans Species 0.000 abstract description 3
- 241000588724 Escherichia coli Species 0.000 abstract description 3
- 229940095731 candida albicans Drugs 0.000 abstract description 3
- 241000295644 Staphylococcaceae Species 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 230000036541 health Effects 0.000 description 9
- 239000004594 Masterbatch (MB) Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000003466 welding Methods 0.000 description 6
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 230000003115 biocidal effect Effects 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000004831 organic oxygen compounds Chemical class 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Rigid Pipes And Flexible Pipes (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to an antibacterial composite aluminium-plastic pipe which is orderly composed of a plastic outer layer, an outer adhesive layer, an aluminium alloy layer, an inner adhesive layer and a plastic inner layer containing organic antibacterial agents. Because the antibacterial aluminium-plastic composite tube has the antibacterial plastic inner layer and the antibacterial agents are added to the plastic inner layer, scores of cultures, such as bacteria, eumycetes, mildew, etc. can be killed, the bacteriostasis effects of escherichia coli, gold staphylococci, candida albicans, etc. are obvious, and the antibacterial effects are lasting. The present invention can satisfy the antibacterial requirement for water supply pipelines in daily life.
Description
The invention belongs to the building pipe technical field, relate to a kind of antibacterial composite aluminium-plastics pipe.
Galvanized iron conduit commonly used was made water supply pipeline in the home dwelling in the past, and its shortcoming is a polluted water, and the life-span is short, and PAP has overcome the galvanized iron conduit polluted water, and pure shortcoming of moulding the pipe intensity difference combines the high strength of metal tube, the advantage of the pollution-free water quality of plastic tube.
The newly-built dwelling house in many cities is forbidden galvanized iron conduit comprehensively and is made water supply pipeline, and the employing PAP, raising along with people's living standard, people are also more and more higher to the requirement of health and health, therefore, the plastic-aluminum pipe that meets health and health requirements has become the focus that people pay close attention to, in order to make PAP reach health and health requirements, usually the method that adopts is to select for use the avirulent material polyvinyl resin of high-purity to make PAP, though the PAP of Xiao Shouing can reach health and healthy requirement in the market, but can not kill the nuisances such as bacterium in the water, therefore a kind of both met health and healthy requirement are provided, can kill simultaneously the antiseptic aluminium-plastic material multiple tube of the nuisances such as bacterium in the water again, be the product that people institute is very expected.
The object of the present invention is to provide a kind of antibacterial composite aluminium-plastics pipe, utilize organic bactericide to combine the plastics of making PAP with plastics, to satisfy people water supply line health and healthy needs.
Technical scheme of the present invention is achieved in that
With the organic antibacterial agent is that antiseptic mixes with plastics after surperficial specially treated, extrude through twin-screw and to cause the organic anti-bacterial masterbatch, the organic anti-bacterial masterbatch is joined in the PAP inner plastic in proportion, produce the PAP that internal layer has the organic anti-bacterial effect by plastic-aluminum combined production line.
The structure of the said antibacterial composite aluminium-plastics pipe of the present invention, form by plastic outer layer, outer adhesive layer, aluminium alloy layer, inner binder layer and the inner plastic that contains organic antibacterial agent successively, it is characterized in that used material of antibacterial composite aluminium-plastics pipe and percentage by weight are:
1) contain the inner plastic 40～60% of antiseptic, wherein inner plastic contains 0.2～3% organic antibacterial agent, 97～99.8% vinyon;
The agent of inorganic sodium nano antibacterial be a kind of contain with argent, zinc or copper be main antimicrobial component with organic oxygen compound, titanium oxide, silica, zeolite, clay etc. be the mixture of the inorganic powder of carrier, have this product on the market;
2) outer layer plastic 10～30%, and said plastic outer layer is made by polyvinyl resin;
3) aluminium alloy layer 10～40%, and the said aluminium alloy layer trade mark is 8011A, 1145,1235,1100,1200,1050,1060, and state is the high-grade soft aluminium of H22 or 0 state, the annealing degrease;
4) inside and outside adhesive phase 0.5～15%, said inside and outside adhesive phase are to be made by a kind of hot melt adhesive that is prepared by the polyvinyl resin of maleic anhydride or maleic acid graft modification.
The plastic-aluminum combined tube preparation method that now contains antibiotic pulvis is as follows:
(1) preparation of organic anti-bacterial active powder:
Titanate ester or silane coupling agent are pressed in organic anti-bacterial powder total amount 0.2～2% and low sub-weight northylen wax 0.2～2% adding organic anti-bacterial powder, and impregnation process was carried out in low-medium speed stirring at normal temperatures in 1～2 minute, dried 1～2 hour down at 90～120 ℃ then, promptly make the organic anti-bacterial active powder;
Above-mentioned organic anti-bacterial powder is Triclosan, N-(trihalomethyl sulfo-) phthalimide and corresponding tetrahydro derivative thereof, N-(trichloromethylthio)-4-cyclohexene-1,2-dicarbapentaborane acid imide, diphenyl antimony-2 ethyl hexanoic acid ester, 10, the two phenoxazine arsines of 10-oxo, two (oxine) copper.
(2) preparation of organic anti-bacterial masterbatch:
Above-mentioned organic anti-bacterial active powder is added in the resin in 5～30% ratio of weight resin, mixes with homogenizer, melt extrudes granulation through twin-screw, can make the organic anti-bacterial masterbatch.
(3) preparation of antibacterial composite aluminium-plastics pipe:
The organic anti-bacterial masterbatch is added in the PAP inner layer polyethylene resin, addition is 1～10% (in weight resin), the best is 2～6%, adopts butt welding or overlap welding plastic-aluminum pipe production line to prepare PAP, and products obtained therefrom is the said antibacterial composite aluminium-plastics pipe of the present invention.
Antibacterial composite aluminium-plastics pipe of the present invention, based on having one deck organic anti-bacterial inner plastic, can kill bacteria, tens kinds of bacterial classifications such as fungi, mould, obvious to the fungistatic effect of Escherichia coli, gold-coloured staphylococci, Candida albicans etc.; Antibacterial effect is lasting, can satisfy the antibiotic requirement of people's daily life, compares with inorganic antiseptic composite aluminium-plastic pipe, and organic antibacterial agent and resin compatible are good, are uniformly dispersed, and antibacterial effect is higher than inorganic antiseptic.
Below in conjunction with embodiment the present invention is further described below.
Embodiment 1
Raw material: get polyvinyl resin HDPE, 6100M
Titante coupling agent NDZ-1
Antimicrobial powder
Low molecular weight polyethylene is cured
Equipment: high-speed mixer, double screw extruder, overlap welding formula production line of aluminum plastic.
Manufacture process: in high-speed mixer, be 1.0% by the percentage of organic anti-bacterial pulvis weight with coupling agent NDZ-1, low molecular weight polyethylene is cured to be in the 0.5% adding organic anti-bacterial powder, in the normal temperature high-speed stirring mixer, mixed 2 minutes, and under 100～130 ℃, dried 2 hours, make the organic anti-bacterial active powder.
With percentage by weight 80% HDPE, 6100M, 19% organic anti-bacterial active powder and 1% Ployethylene Wax mixed in mixer 2 minutes, then, adding the double screw extruder melt blending extrudes, processing temperature is 190～240 ℃, and rotating speed is 120～180 rev/mins, and extruding pelletizing, to make the organic anti-bacterial active component content be 19% organic anti-bacterial master batch.
4% the ratio of organic anti-bacterial master batch in the inner plastic gross weight joined in the HDPE inner layer resin, in mixer, mix mixing in 2 minutes, can obtain the special-purpose antibiotic material of plastic-aluminum combined effective internal layer.
On overlap welding formula production line of aluminum plastic, raw materials used as follows:
Plastic outer layer HDPE 6100M
Outer adhesive layer hot melt adhesive LE500T
Aluminium alloy layer 8011-O, the annealing degrease
Outer adhesive layer hot melt adhesive LE500T
The special-purpose antibiotic material of the above-mentioned internal layer of inner plastic
Processing temperature is controlled at 190～240 ℃, and producing caliber is Φ 1216, and extruded velocity is at 8～10 meters/minute.
Welding manner is ultrasonic wave butt welding.
Above-mentioned raw materials just can be produced antibacterial composite Al-plastic tube by technological requirement on production line of aluminum plastic.
According to GB GB15979-1995 method of testing, the antibacterial composite Al-plastic tube of embodiment 1 is carried out antibacterial tests, the results are shown in table 1.
Table 1
| Testing time (hour) | 6 hours | 12 hours | 24 hours | After half a year | After 1 year | After 2 years | |
| Sterilizing rate | Escherichia coli | 50％ | 72％ | 94％ | 90.4％ | 90％ | 90％ |
| Staphylococcus aureus | 45％ | 68％ | 91％ | 86.3％ | 86％ | 86％ | |
| Candida albicans | 30％ | 55％ | 80.5％ | 75.2％ | 75％ | 75％ | |
Claims (4)
1. antibacterial composite Al-plastic tube comprises plastic outer layer, outer adhesive layer, aluminium alloy layer, inner binder layer and contains the inner plastic of antiseptic, it is characterized in that used material of said antibacterial composite Al-plastic tube and percentage by weight are:
1) contain the inner plastic 40～60% of organic antibacterial agent, wherein: inner plastic closes 0.2～3% organic antibacterial agent, and 97～99.8% vinyon is made;
2) outer layer plastic 10～30%;
3) aluminium alloy layer 10～40%;
4) inside and outside adhesive phase 0.5～15%, form by the titanate ester of organic anti-bacterial powder total amount 0.2～2% or the low molecular weight polyethylene wax and the oven dry of organic anti-bacterial powder of silane coupling agent and organic anti-bacterial powder total amount 0.2～2%, wherein organic dust is Triclosan, N-(trihalomethyl sulfo-) phthalimide and corresponding tetrahydro derivative thereof, N-(trichloromethylthio)-4-cyclohexene-1,2-dicarbapentaborane acid imide, diphenyl antimony-2 ethyl hexanoic acid ester, 10, the two phenoxazine arsines of 10-oxo, two (oxine) copper.
2. according to the described antibacterial composite Al-plastic tube of claim 1, it is characterized in that: said plastic outer layer is prepared by polyvinyl resin.
3. according to the described antibacterial composite Al-plastic tube of claim 1, it is characterized in that: the said aluminium alloy layer trade mark is 8011A, 1145,1235,1100,1200,1050,1060, and state is the high-grade soft aluminium of H22 or 0 state, the annealing degrease.
4. according to the described antibacterial composite Al-plastic tube of claim 1, it is characterized in that: said outer adhesive layer and inner binder layer are a kind of hot melt adhesives, by the preparation of the polyvinyl resin of maleic anhydride or maleic acid graft modification.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011062215A CN1168597C (en) | 2001-02-27 | 2001-02-27 | Antibacterial composite aluminium-plastics pipe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011062215A CN1168597C (en) | 2001-02-27 | 2001-02-27 | Antibacterial composite aluminium-plastics pipe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1370676A CN1370676A (en) | 2002-09-25 |
| CN1168597C true CN1168597C (en) | 2004-09-29 |
Family
ID=4655260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011062215A Expired - Fee Related CN1168597C (en) | 2001-02-27 | 2001-02-27 | Antibacterial composite aluminium-plastics pipe |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1168597C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102062264A (en) * | 2010-11-10 | 2011-05-18 | 杭州联通管业有限公司 | Silver-free antibacterial water supply pipe and production method thereof |
| CN107641748A (en) * | 2017-08-31 | 2018-01-30 | 巢湖鹏远金属焊管有限公司 | A kind of antibacterial anticorrosion pipeline and preparation method thereof |
-
2001
- 2001-02-27 CN CNB011062215A patent/CN1168597C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1370676A (en) | 2002-09-25 |
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