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CN116694999A - A kind of maglev track steel and its preparation method - Google Patents

A kind of maglev track steel and its preparation method Download PDF

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Publication number
CN116694999A
CN116694999A CN202310761629.7A CN202310761629A CN116694999A CN 116694999 A CN116694999 A CN 116694999A CN 202310761629 A CN202310761629 A CN 202310761629A CN 116694999 A CN116694999 A CN 116694999A
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CN116694999B (en
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霍喜伟
宋玉卿
李承�
刘昀嘉
孙晓庆
肖强
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Shandong Iron and Steel Co Ltd
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Shandong Iron and Steel Co Ltd
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    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
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    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
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    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
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    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
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    • C21C7/076Use of slags or fluxes as treating agents
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • C22C33/06Making ferrous alloys by melting using master alloys
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
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    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0006Adding metallic additives
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    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
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    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

The application provides a magnetic levitation track profile steel and a preparation method thereof, wherein the profile steel comprises the following chemical components in percentage by mass: c:0.08 to 0.13 percent of Si:0.20 to 0.50 percent of Mn:0.80 to 1.10 percent, less than or equal to 0.015 percent of P, less than or equal to 0.010 percent of S, and Als:0.020 to 0.060 percent, less than or equal to 0.20 percent of Cr, less than or equal to 0.20 percent of Cu, less than or equal to 0.30 percent of Ni, less than or equal to 0.005 percent of Ti, less than or equal to 40ppm of B, less than or equal to 1.5ppm of H, and the balance of iron and unavoidable impurities. The magnetic levitation track is directly rolled by adopting a one-step hot rolling forming process, and has excellent comprehensive properties such as magnetic permeability, strength, elongation, low-temperature impact toughness and the like. The Ti element content in the profile steel, which is unfavorable for the magnetic permeability, is obviously reduced, and the B content is controlled in a smaller fluctuation range. The smaller C element and Mn element are extremely bad, and the toughness of the deformation dead zone of the profile steel is improved.

Description

一种磁浮轨道型钢及制备方法A kind of maglev track steel and its preparation method

技术领域technical field

本发明涉及冶金技术领域,特别涉及一种磁浮轨道型钢及制备方法。The invention relates to the technical field of metallurgy, in particular to a magnetic levitation track steel and a preparation method.

背景技术Background technique

磁浮轨道作为磁浮列车悬浮控制的重要组成部分,既要有足够的导磁性能,又要满足结构承载能力,这给材料制造带来了挑战。As an important part of the levitation control of the maglev train, the maglev track must not only have sufficient magnetic permeability, but also meet the structural load-bearing capacity, which brings challenges to material manufacturing.

申请号为CN02136192.4的中国专利公开了一种软磁结构钢及其制造方法,用于磁悬浮轨道的软磁结构钢及其制造方法。技术方案是:软磁结构钢及其制造方法,组成元素包括:Fe、C、Si、Mn、P、S、Als、Cr、Cu、Ti、N、Ni、Ca,其特征是组成元素Ca可用REM替代,组成元素的重量百分比为:C:0.010%~0.040%,Si:1.0%~2.0%,Mn:0.60%~1.00%,P:≤0.015%,S:≤0.005%,Als:0.005%~0.020%,Cr:<0.60%,Cu:0.20%~0.60%,Ti:0.005%~0.02%,N:≤0.010%,Ni:≤1.00%,Ca或REM:≤0.010%,其余为铁和不可避免的夹杂。其轧制工艺包括:连铸工艺、热轧工艺和正火工艺,最终得到适合在北方用于磁悬浮列车轨道梁上的侧面导向软磁结构钢板。该技术涉及的钢板仅用于磁浮列车的侧面导向,不作为结构件承担列车重量,没有结构强度和韧性要求。The Chinese patent with the application number CN02136192.4 discloses a soft magnetic structural steel and a manufacturing method thereof, a soft magnetic structural steel used for a magnetic levitation track and a manufacturing method thereof. The technical solution is: soft magnetic structural steel and its manufacturing method, the constituent elements include: Fe, C, Si, Mn, P, S, Als, Cr, Cu, Ti, N, Ni, Ca, and the characteristic is that the constituent element Ca can be used REM replacement, the weight percentage of constituent elements is: C: 0.010% ~ 0.040%, Si: 1.0% ~ 2.0%, Mn: 0.60% ~ 1.00%, P: ≤0.015%, S: ≤0.005%, Als: 0.005% ~0.020%, Cr: <0.60%, Cu: 0.20%~0.60%, Ti: 0.005%~0.02%, N: ≤0.010%, Ni: ≤1.00%, Ca or REM: ≤0.010%, the rest are iron and Inevitable inclusion. Its rolling process includes: continuous casting process, hot rolling process and normalizing process, and finally obtains a side-guided soft magnetic structural steel plate suitable for use on the track beam of the magnetic levitation train in the north. The steel plate involved in this technology is only used for the side guidance of the maglev train, and is not used as a structural part to bear the weight of the train, and there is no requirement for structural strength and toughness.

申请号为CN200410017999.7的中国专利公开了一种低温韧性优良的软磁结构钢板,其成分为(质量百分比)C 0.010%~0.040%、Si 0.50%~1.00%、Mn 1.00%~1.50%、P≤0.015%、S≤0.005%、Als 0.50%~1.00%、Cr 0.20~0.50%、Cu 0.20%~0.60%、Ti 0.005%~0.02%、N 0.001%~0.008%、Ni0.30~0.80%、Ca 10ppm~60ppm、其余为铁和不可避免的夹杂,Pcm≤0.20%。优化再结晶控轧和加速冷却工艺及后续缓冷工艺,使成品软磁结构钢板的晶粒尺寸在10~30μm,获得优异的机械性能、电磁性能和焊接性,特别适用于磁悬浮列车轨道中的必须吸收承载力、导向力和驱动力的侧面导向板。该专利仅提供了一种软磁钢板,要制成磁悬浮轨道,还需要对钢板进行焊接、矫直、机械加工等工序,不仅工序复杂、成本高昂,而且效率低下,严重制约其工业化应用。The Chinese patent application number CN200410017999.7 discloses a soft magnetic structural steel plate with excellent low-temperature toughness. P≤0.015%, S≤0.005%, Als 0.50%~1.00%, Cr 0.20~0.50%, Cu 0.20%~0.60%, Ti 0.005%~0.02%, N 0.001%~0.008%, Ni0.30~0.80% , Ca 10ppm ~ 60ppm, the rest is iron and unavoidable inclusions, Pcm≤0.20%. Optimize the recrystallization controlled rolling and accelerated cooling process and the subsequent slow cooling process, so that the grain size of the finished soft magnetic structural steel plate is 10-30 μm, and obtain excellent mechanical properties, electromagnetic properties and weldability, especially suitable for magnetic levitation train tracks Side guides that must absorb load-carrying, guiding and driving forces. This patent only provides a soft magnetic steel plate. To make a magnetic levitation track, the steel plate needs to be welded, straightened, machined and other processes. Not only the process is complicated, the cost is high, but also the efficiency is low, which seriously restricts its industrial application.

申请号为CN201811092935.1的中国专利公开了一种高磁通密度磁浮轨道用F型钢及其生产方法,包括以下组分及其重量百分比含量:C:0.04~0.07%、Si:0.08~0.20%、Mn:0.5~0.8%、P≤0.015%、S≤0.015%、Nb:0.015~0.030%、Als:0.03~0.05%,其余为Fe和杂质元素。本发明通过钢种成分设计及炼钢过程中控制夹杂物颗粒数目和大小,同时配以高温快轧,达到合金元素固溶于钢中并使得晶粒快速长大,获得具有高磁通密度并且力学性能优良的磁浮轨道用F型钢。该专利采用高温快轧工艺,使晶粒快速长大,虽然获得了较好的导磁性能,但材料的延伸率和低温冲击性能较差。The Chinese patent with the application number CN201811092935.1 discloses a F-shaped steel for high magnetic flux density maglev track and its production method, including the following components and their weight percentages: C: 0.04-0.07%, Si: 0.08-0.20% , Mn: 0.5-0.8%, P≤0.015%, S≤0.015%, Nb: 0.015-0.030%, Als: 0.03-0.05%, and the rest are Fe and impurity elements. The invention controls the number and size of inclusion particles through steel composition design and steelmaking process, and at the same time, it is equipped with high temperature and fast rolling to achieve solid solution of alloy elements in steel and rapid growth of crystal grains, and obtain high magnetic flux density and F-shaped steel for magnetic levitation track with excellent mechanical properties. This patent adopts a high-temperature fast rolling process to make the crystal grains grow rapidly. Although good magnetic permeability is obtained, the elongation and low-temperature impact properties of the material are poor.

现有技术主要针对型钢材料的导磁性能进行了改进与优化,在导磁和结构承载综合性能方面未进行系统改进,存在一定的不足。尤其是当材料被制成型钢后,由于型钢本身截面特点和冷却条件的限制,在变形死区位置,导磁性能、强度、延伸率和低温冲击韧性存在多个或单个性能参数显著降低的现象,难以达到良好的综合性能。The prior art mainly improves and optimizes the magnetic permeability of section steel materials, but there is no systematic improvement in the comprehensive performance of magnetic permeability and structural load bearing, and there are certain deficiencies. Especially when the material is made into shaped steel, due to the section characteristics of the shaped steel itself and the limitation of cooling conditions, in the dead zone of deformation, the magnetic permeability, strength, elongation and low temperature impact toughness have multiple or single performance parameters that are significantly reduced. , it is difficult to achieve good comprehensive performance.

因此,需要一种磁浮轨道型钢及制备方法。Therefore, there is a need for a magnetic levitation track steel and a preparation method.

发明内容Contents of the invention

本发明的目的在于提供一种磁浮轨道型钢及制备方法,采用一次热轧成型工艺直接轧制出磁浮轨道,避免了钢板的焊接与二次加工,降低了轨道制造过程的碳排放,导磁性、强度、延伸率和低温冲击韧性等综合性能优良。The purpose of the present invention is to provide a magnetic levitation track profile steel and its preparation method. The maglev track is directly rolled out by a hot rolling forming process, avoiding the welding and secondary processing of the steel plate, reducing the carbon emission in the track manufacturing process, magnetic permeability, Excellent comprehensive properties such as strength, elongation and low temperature impact toughness.

为了实现上述目的,本发明提供如下技术方案:In order to achieve the above object, the present invention provides the following technical solutions:

一种磁浮轨道型钢,所述型钢按质量百分比由以下化学成分组成:C:0.08%~0.13%、Si:0.20%~0.50%、Mn:0.80%~1.10%、P≤0.015%、S≤0.010%、Als:0.020%~0.060%、Cr≤0.20%、Cu≤0.20%、Ni≤0.30%、Ti≤0.005%、B≤40ppm、H≤1.5ppm、其余为铁和不可避免的杂质。A maglev rail profile steel, the profile steel is composed of the following chemical components in terms of mass percentage: C: 0.08% to 0.13%, Si: 0.20% to 0.50%, Mn: 0.80% to 1.10%, P≤0.015%, S≤0.010 %, Als: 0.020% to 0.060%, Cr≤0.20%, Cu≤0.20%, Ni≤0.30%, Ti≤0.005%, B≤40ppm, H≤1.5ppm, and the rest are iron and unavoidable impurities.

进一步地,在上述的磁浮轨道型钢中,所述型钢横断面C极差≤0.03%,Mn极差≤0.05%。Further, in the above-mentioned magnetic levitation track profiled steel, the cross-sectional C range of the profiled steel is ≤0.03%, and the Mn range is ≤0.05%.

另一方面,提供了一种上述的磁浮轨道型钢的制备方法,包括如下步骤:On the other hand, a kind of preparation method of above-mentioned magnetic levitation track section steel is provided, comprising the following steps:

步骤S1:采用转炉、LF精炼和VD真空炉冶炼,Step S1: using converter, LF refining and VD vacuum furnace for smelting,

步骤S2:采用连铸机铸造出钢坯,Step S2: using a continuous casting machine to cast a billet,

步骤S3:钢坯经加热、轧制、冷却后制成磁浮轨道型钢。Step S3: After the steel billet is heated, rolled and cooled, it is made into a maglev rail profile.

进一步地,在上述的制备方法中,在所述步骤S1中,高炉铁水在转炉炼钢的原料中占比不小于90%,将高炉铁水进行预脱磷,转炉出钢过程中采用滑动挡渣装置。Further, in the above preparation method, in the step S1, the blast furnace molten iron accounts for no less than 90% of the raw materials for converter steelmaking, the blast furnace molten iron is pre-dephosphorized, and sliding slag is used in the process of converter tapping device.

进一步地,在上述的制备方法中,在所述步骤S1中,LF精炼的钢包内衬、精炼渣和合金均采用低Ti低B材料,其中,按质量百分比Ti含量≤0.02%,按质量百分比B含量≤0.02%。Further, in the above preparation method, in the step S1, the ladle lining, refining slag and alloy of LF refining are all made of low-Ti and low-B materials, wherein the Ti content is ≤0.02% by mass percentage, and the Ti content is ≤0.02% by mass percentage. B content≤0.02%.

进一步地,在上述的制备方法中,在所述步骤S1中,在LF精炼过程中先加Al线,再加Ca线,最后加B线。Further, in the above preparation method, in the step S1, the Al wire is added first, then the Ca wire, and finally the B wire is added during the LF refining process.

进一步地,在上述的制备方法中,在所述步骤S2中,连铸机的连铸中间包设有自动控温装置,如果钢液温度T比液相线温度Tl高10℃以内,则盖上中间包的包盖并对钢液进行加热补温;如果钢液温度T比液相线温度Tl高20℃以上,则打开中间包的包盖散热,并停止加热,自动控温装置使中间包内钢液的温度波动控制在20℃以内。Further, in the above-mentioned preparation method, in the step S2, the continuous casting tundish of the continuous casting machine is equipped with an automatic temperature control device, if the temperature T of the molten steel is within 10°C higher than the liquidus temperature T1, then the cover Put on the cover of the tundish and heat the molten steel; if the temperature T of the molten steel is higher than the liquidus temperature Tl by more than 20°C, open the cover of the tundish to dissipate heat, and stop heating, and the automatic temperature control device makes the middle The temperature fluctuation of molten steel in the ladle is controlled within 20°C.

进一步地,在上述的制备方法中,连铸机设置有结晶器电磁搅拌和末端压下装置,对凝固过程的钢液进行均匀化,使铸坯断面C极差≤0.04%,Mn极差≤0.06%。Further, in the above-mentioned preparation method, the continuous casting machine is equipped with a crystallizer electromagnetic stirring device and an end pressing device to homogenize the molten steel in the solidification process, so that the cross-section C of the slab is less than or equal to 0.04%, and the Mn limit is less than or equal to 0.06%.

进一步地,在上述的制备方法中,在所述步骤S3中,钢坯的加热时间为3小时~6小时,加热温度1150℃~1230℃,轧制终轧前的坯料断面设置有非平衡补偿区,所述非平衡补偿区为终轧道次的变形死区带来额外的变形量,且大于其它区域的变形量2%以上。Further, in the above-mentioned preparation method, in the step S3, the heating time of the billet is 3 hours to 6 hours, the heating temperature is 1150°C to 1230°C, and the section of the billet before the final rolling is provided with an unbalanced compensation zone , the unbalanced compensation zone brings additional deformation to the deformation dead zone of the final rolling pass, which is more than 2% larger than the deformation in other zones.

进一步地,在上述的制备方法中,冷却为轧制后空冷至环境温度,成品组织为多边形铁素体和珠光体,型钢的横断面上变形死区的晶粒度和其它区域的晶粒度之间的差别不大于1级。Further, in the above-mentioned preparation method, the cooling is air cooling to ambient temperature after rolling, the finished product structure is polygonal ferrite and pearlite, the grain size of the deformation dead zone and the grain size of other areas on the cross section of the steel The difference between them is not more than 1 grade.

分析可知,本发明公开一种磁浮轨道型钢及制备方法,采用一次热轧成型工艺直接轧制出磁浮轨道,避免了钢板的焊接与二次加工,降低了轨道制造过程的碳排放,导磁性、强度、延伸率和低温冲击韧性等综合性能优良。钢包内衬和精炼渣、合金均采用低Ti低B含量材料的设计显著降低了型钢中对导磁性不利的Ti元素含量,并使B含量控制在较小的波动范围,为LF精炼后期添加B线,稳定钢中的B含量起到了辅助作用,在获得较好的低温冲击性能的同时,避免了过量添加B导致的钢材裂纹、疲劳性能降低等不足。自动控温装置使中间包内钢液的温度波动控制在20℃以内,减小了中间包钢液温度波动,降低了结晶器钢液过热度,有利于减轻钢坯的偏析,较小C元素和Mn元素极差,提高型钢的变形死区的韧性。型钢的H含量的控制从源头上减少了H原子的聚集数量。终轧前坯料断面的非平衡补偿区和额外压下量大于2%的设计,增大了变形死区的变形量,带来了晶粒细化效果,且使变形死区的应力状态转变为压应力状态,消除了变形死区H原子聚集,防止氢致裂纹引起的韧性下降。It can be seen from the analysis that the present invention discloses a maglev track profile steel and its preparation method. The maglev track is directly rolled out by a hot rolling forming process, avoiding the welding and secondary processing of the steel plate, reducing the carbon emission in the track manufacturing process, magnetic permeability, Excellent comprehensive properties such as strength, elongation and low temperature impact toughness. The ladle lining, refining slag, and alloys are all designed with low Ti and low B content materials, which significantly reduces the content of Ti element in the steel that is unfavorable to magnetic permeability, and keeps the B content within a small fluctuation range, which is the best way to add B in the later stage of LF refining. The B content in the stabilized steel plays an auxiliary role. While obtaining better low-temperature impact properties, it avoids the cracks and fatigue performance reduction of steel caused by excessive addition of B. The automatic temperature control device controls the temperature fluctuation of the molten steel in the tundish within 20°C, which reduces the temperature fluctuation of the molten steel in the tundish, reduces the superheat of the molten steel in the mold, and is beneficial to reduce the segregation of the billet, and the C element and The Mn element is extremely poor, and improves the toughness of the deformation dead zone of the section steel. The control of the H content of the section steel reduces the aggregation of H atoms from the source. The unbalanced compensation area of the billet section before final rolling and the design of the additional reduction greater than 2% increase the deformation amount in the dead zone of deformation, bring about the effect of grain refinement, and change the stress state of the dead zone of deformation to The compressive stress state eliminates the accumulation of H atoms in the deformation dead zone and prevents the toughness reduction caused by hydrogen-induced cracks.

附图说明Description of drawings

构成本申请的一部分的说明书附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。其中:The accompanying drawings constituting a part of the present application are used to provide a further understanding of the present invention, and the schematic embodiments and descriptions of the present invention are used to explain the present invention, and do not constitute an improper limitation of the present invention. in:

图1为本发明一实施例的型钢的断面结构示意图。Fig. 1 is a schematic cross-sectional structure diagram of a section steel according to an embodiment of the present invention.

图2为本发明一实施例的终轧前坯料的断面结构示意图。Fig. 2 is a schematic cross-sectional structure diagram of a billet before final rolling according to an embodiment of the present invention.

附图标记说明:1型钢;11侧腿;12腹板;13中间腿;14外翼缘;2变形死区;3原终轧前坯料断面形状;4非平衡补偿区。Explanation of reference signs: 1 section steel; 11 side leg; 12 web; 13 middle leg; 14 outer flange; 2 deformation dead zone;

具体实施方式Detailed ways

下面将参考附图并结合实施例来详细说明本发明。各个示例通过本发明的解释的方式提供而非限制本发明。实际上,本领域的技术人员将清楚,在不脱离本发明的范围或精神的情况下,可在本发明中进行修改和变型。例如,示为或描述为一个实施例的一部分的特征可用于另一个实施例,以产生又一个实施例。因此,所期望的是,本发明包含归入所附权利要求及其等同物的范围内的此类修改和变型。The present invention will be described in detail below with reference to the accompanying drawings and examples. Each example is provided by way of explanation of the invention, not limitation of the invention. In fact, those skilled in the art will recognize that modifications and variations can be made in the present invention without departing from the scope or spirit of the invention. For example, features illustrated or described as part of one embodiment can be used on another embodiment to yield a still further embodiment. Therefore, it is intended that the present invention includes such modifications and variations as come within the scope of the appended claims and their equivalents.

所附附图中示出了本发明的一个或多个示例。详细描述使用了数字和字母标记来指代附图中的特征。附图和描述中的相似或类似标记的已经用于指代本发明的相似或类似的部分。One or more examples of the invention are illustrated in the accompanying drawings. The detailed description uses numerical and letter designations to refer to features in the drawings. Like or analogous numerals in the drawings and description have been used to refer to like or analogous parts of the present invention.

根据本发明的实施例,提供了一种磁浮轨道型钢,型钢按质量百分比由以下化学成分组成:C:0.08%~0.13%、Si:0.20%~0.50%、Mn:0.80%~1.10%、P≤0.015%、S≤0.010%、Als:0.020%~0.060%、Cr≤0.20%、Cu≤0.20%、Ni≤0.30%、Ti≤0.005%、B≤40ppm、H≤1.5ppm、其余为铁和不可避免的杂质,型钢同一横断面C极差≤0.03%、Mn极差≤0.05%。According to an embodiment of the present invention, a magnetic levitation track profile steel is provided. The profile steel is composed of the following chemical components in terms of mass percentage: C: 0.08% to 0.13%, Si: 0.20% to 0.50%, Mn: 0.80% to 1.10%, P ≤0.015%, S≤0.010%, Als: 0.020%~0.060%, Cr≤0.20%, Cu≤0.20%, Ni≤0.30%, Ti≤0.005%, B≤40ppm, H≤1.5ppm, the rest are iron and Unavoidable impurities, C range ≤ 0.03% and Mn range ≤ 0.05% in the same cross-section of steel.

极差是指规定区域内检测到的成分的变化范围,等于最大值与最小值的差,例如:在型钢(或铸坯)同一横断面上,从靠近表面到心部检测5个点的C含量,分别为0.08%、0.10%、0.09%、0.12%、0.11%,则该断面的C极差为0.12%-0.08%=0.04%。较低的极差能够降低成分偏析,改善磁浮轨道型钢变形死区的综合性能。Extreme difference refers to the variation range of the composition detected in the specified area, which is equal to the difference between the maximum value and the minimum value, for example: on the same cross-section of the section steel (or slab), detect the C of 5 points from the surface to the center content, respectively 0.08%, 0.10%, 0.09%, 0.12%, 0.11%, then the C range of this section is 0.12%-0.08%=0.04%. The lower extreme difference can reduce the composition segregation and improve the comprehensive performance of the deformation dead zone of the maglev track steel.

C:C是钢材中用于提升强度的最经济元素,但随着C含量增加,钢材的韧性会恶化。对本发明涉及的型钢来说,既要改善变形死区的韧性,又要避免C含量过低带来的钢水过氧化降低钢包寿命问题,确定将C含量控制在0.08%~0.13%范围内。C: C is the most economical element in steel to increase strength, but as the C content increases, the toughness of steel will deteriorate. For the section steel involved in the present invention, it is necessary to improve the toughness of the deformation dead zone and to avoid the problem of lowering the service life of the ladle caused by the peroxidation of molten steel caused by too low C content, and it is determined to control the C content within the range of 0.08% to 0.13%.

Si:Si是炼钢过程必须加入的脱氧剂,脱氧完成后会有少量残留在钢液中,冷却后固溶在铁素体中起到提升强度的作用,但含量过多会形成夹杂物,降低塑性和疲劳性能。本发明综合考虑脱氧控制和强度提升的需要,将Si含量控制在0.20%~0.50%范围内。Si: Si is a deoxidizer that must be added in the steelmaking process. After the deoxidation is completed, a small amount will remain in the molten steel. After cooling, it will dissolve in the ferrite to improve the strength, but if the content is too much, it will form inclusions. Reduce plasticity and fatigue properties. The present invention comprehensively considers the needs of deoxidation control and strength improvement, and controls the Si content within the range of 0.20% to 0.50%.

Mn:具有固溶强化作用,本发明中Mn用于弥补C含量降低带来的强度损失。Mn含量与S含量的比例大于80可显著降低铸坯裂纹,但Mn含量过高会导致磁浮轨道剩磁增加,增大矫顽力,提升列车运行能耗,因此本发明将Mn的含量控制在0.80%~1.10%范围内。Mn: It has a solid solution strengthening effect. In the present invention, Mn is used to make up for the loss of strength caused by the reduction of C content. The ratio of the Mn content to the S content is greater than 80, which can significantly reduce the slab cracks, but the excessively high Mn content will cause the remanence of the maglev track to increase, increase the coercive force, and improve the energy consumption of the train. Therefore, the present invention controls the Mn content at In the range of 0.80% to 1.10%.

Ti:易生成高熔点夹杂物,恶化钢水的可浇性,且影响导磁性,在经济化生产的前提下,控制在较低含量(≤0.005%)可改善导磁性。Ti: It is easy to form inclusions with high melting point, which deteriorates the castability of molten steel and affects the magnetic permeability. Under the premise of economical production, controlling the content at a low level (≤0.005%) can improve the magnetic permeability.

B:对钢材的韧性影响较大,微量添加能显著提高钢材韧性,但添加量大于40ppm,又会导致低温性能急剧恶化。通过添加B元素且稳定控制含量,可在成本较低的情况下,提升钢材韧性。B: It has a great influence on the toughness of steel, and a small amount of addition can significantly improve the toughness of steel, but the addition of more than 40ppm will lead to a sharp deterioration of low temperature performance. By adding element B and stably controlling the content, the toughness of steel can be improved at a low cost.

H:对本发明来说,由于磁浮轨道型钢变形死区对应着铸坯中心,H原子容易聚集,除了要通过电磁搅拌减少H原子在铸坯心部的聚集外,将钢中的H含量控制在1.5ppm以下能从整体上减少铸坯心部的H原子数量。H: For the present invention, since the deformation dead zone of the maglev track steel corresponds to the center of the slab, H atoms are easy to gather. In addition to reducing the aggregation of H atoms at the center of the slab by electromagnetic stirring, the H content in the steel is controlled at Below 1.5ppm can reduce the number of H atoms in the core of the slab as a whole.

Al:具有深脱氧功能,在Si脱氧的基础上,通过添加Al能进一步将氧含量控制到30ppm以下。Al还具有细化晶粒的作用,可整体提高钢的韧性。将Als控制在0.020%~0.060%范围内可实现提高韧性的同时,不影响钢液的可浇性。Al: It has a deep deoxidation function. On the basis of Si deoxidation, the oxygen content can be further controlled below 30ppm by adding Al. Al also has the effect of refining grains, which can improve the toughness of steel as a whole. Controlling Als in the range of 0.020% to 0.060% can improve the toughness without affecting the castability of molten steel.

Ni:能够降低钢材的韧脆转变温度,但需较高的添加量(6%以上)才能达到效果,Ni元素价格昂贵,通过大量添加Ni提高耐低温性能成本上不经济。本发明通过与B元素联合作用,在较低Ni添加量(≤0.30%)的情况下可实现对低温冲击性能的稳定提升。Ni: It can reduce the ductile-brittle transition temperature of steel, but it needs a relatively high addition amount (above 6%) to achieve the effect. The Ni element is expensive, and it is not economical to increase the low temperature resistance by adding a large amount of Ni. The present invention can achieve stable improvement of low-temperature impact performance under the condition of low Ni addition (≤0.30%) through the joint action of B element.

Cr:为钢中不可避免的残余元素,Cr含量较多的情况下会改变钢的冷却组织,生成贝氏体、马氏体等脆性相,降低低温冲击性能,控制在本发明要求范围内不会对韧性造成明显影响。Cr: It is an unavoidable residual element in the steel. When the Cr content is high, the cooling structure of the steel will be changed, brittle phases such as bainite and martensite will be formed, and the low-temperature impact performance will be reduced. It is not controlled within the scope of the present invention. have a noticeable effect on toughness.

Cu:为钢中不可避免的残余元素,含量过多会导致铸坯加热后出现表面裂纹,并遗传到成品形成表面缺陷,控制在本发明要求范围内不会造成表面裂纹缺陷。Cu: an unavoidable residual element in steel, too much content will cause surface cracks to appear after the slab is heated, and will be inherited to the finished product to form surface defects, which will not cause surface crack defects if controlled within the scope of the present invention.

如图1所示,型钢1包括侧腿11、腹板12、中间腿13和外翼缘14,侧腿11的一端与腹板12的一端连接,中间腿13的一端与腹板12的另一端连接,侧腿11的另一端和中间腿13的另一端向腹板的同一侧延伸,外翼缘14的一端与腹板12的另一端连接,外翼缘14的另一端沿腹板12的轴线向远离腹板12的方向延伸。As shown in Figure 1, section steel 1 comprises side leg 11, web 12, middle leg 13 and outer flange 14, and one end of side leg 11 is connected with one end of web 12, and one end of middle leg 13 is connected with the other end of web 12 One end is connected, the other end of the side leg 11 and the other end of the middle leg 13 extend to the same side of the web, one end of the outer flange 14 is connected with the other end of the web 12, and the other end of the outer flange 14 is along the web 12 The axis of the shaft extends away from the web 12.

本发明还公开了一种上述的磁浮轨道型钢的制备方法,包括如下步骤:The present invention also discloses a method for preparing the above-mentioned maglev track steel, comprising the following steps:

步骤S1:采用转炉、LF精炼和VD真空炉冶炼。Step S1: smelting using converter, LF refining and VD vacuum furnace.

高炉铁水在转炉炼钢的原料中占比不小于90%,将高炉铁水进行预脱磷,转炉出钢过程中采用滑动挡渣装置。高炉铁水在转炉炼钢的原料中占比不小于90%,能够提高钢质纯净度,减少废钢加入带来的有害元素。The blast furnace hot metal accounts for no less than 90% of the raw materials for converter steelmaking. The blast furnace hot metal is pre-dephosphorized, and a sliding slag blocking device is used during the converter tapping process. Blast furnace molten iron accounts for no less than 90% of the raw materials for converter steelmaking, which can improve the purity of steel and reduce harmful elements brought about by the addition of scrap steel.

LF精炼的钢包内衬、精炼渣和合金均采用低Ti低B材料,其中,按质量百分比Ti含量≤0.02%,按质量百分比B含量≤0.02%。在LF精炼工序中,钢包内衬和精炼渣、合金均采用低Ti低B含量材料的设计显著降低了型钢中对导磁性不利的Ti元素含量,使型钢具有较好的导磁性,并使B含量控制在较小的波动范围,为LF精炼后期准确添加B线,稳定B含量起到了辅助作用,在获得较好的低温冲击值的同时,避免了添加B导致的钢材裂纹、疲劳性能降低等不足。The ladle lining, refining slag and alloy of LF refining are all made of low-Ti and low-B materials, wherein the Ti content is ≤0.02% by mass percentage, and the B content is ≤0.02% by mass percentage. In the LF refining process, the ladle lining, refining slag, and alloys are all designed with low Ti and low B content materials, which significantly reduces the content of Ti element in the section steel that is unfavorable to magnetic permeability, so that the section steel has better magnetic permeability and B. The content is controlled within a small fluctuation range, which plays an auxiliary role in accurately adding B line in the later stage of LF refining and stabilizing the B content. While obtaining a better low-temperature impact value, it avoids steel cracks and fatigue performance reduction caused by adding B. insufficient.

在LF精炼过程中先加Al线,再加Ca线,最后加B线,通过Al线对钢液深脱氧,形成的Al2O3在Ca的作用下快速上浮到钢渣中,不仅降低了O含量,而且不增加钢液中的夹杂物,最后添加B线,可以尽量避免B元素被氧化失效和生成含B的氧化物夹杂,达到B含量的稳定控制。In the LF refining process, the Al line is added first, followed by the Ca line, and finally the B line is added to deoxidize the molten steel through the Al line. The formed Al 2 O 3 floats quickly into the steel slag under the action of Ca, which not only reduces content, and does not increase the inclusions in the molten steel, and finally add the B line, which can avoid the oxidation failure of the B element and the formation of B-containing oxide inclusions, and achieve the stable control of the B content.

步骤S2:采用连铸机铸造出钢坯。Step S2: using a continuous casting machine to cast a billet.

如图1所示,型钢的变形死区2对应钢坯的中心,即,型钢的变形死区2位于腹板12与中间腿13连接的位置处,现有技术中的磁浮轨道型钢C、Mn等元素偏析严重,导致型钢的变形死区韧性明显低于其它区域。在本发明的实施例中,连铸机的连铸中间包设有自动控温装置,自动控温装置包括自动加热装置和散热装置,如果钢液温度T比液相线温度Tl高10℃以内,则盖上中间包的包盖并利用自动加热装置对钢液进行加热补温;如果钢液温度T比液相线温度Tl高20℃以上,则打开中间包的包盖并利用散热装置进行散热,自动加热装置停止加热,自动控温装置使中间包内钢液的温度波动控制在20℃以内。如此设置减小了中间包钢液温度波动,降低了结晶器钢液过热度,有利于减轻钢坯的偏析,提高型钢的变形死区2的韧性。连铸机设置有结晶器电磁搅拌和末端压下装置,对凝固过程的钢液进行均匀化,使铸坯断面C极差≤0.04%、Mn极差≤0.06%。结晶器电磁搅拌和末端压下装置的设计降低了钢坯C极差、Mn极差,进一步减轻钢坯的偏析,提高型钢的变形死区2的韧性。As shown in Figure 1, the deformation dead zone 2 of the shaped steel corresponds to the center of the billet, that is, the deformed dead zone 2 of the shaped steel is located at the position where the web 12 and the middle leg 13 are connected, and the magnetic levitation track shaped steel C, Mn, etc. in the prior art Severe element segregation leads to significantly lower toughness in the deformation dead zone of the section steel than in other zones. In an embodiment of the present invention, the continuous casting tundish of the continuous casting machine is provided with an automatic temperature control device, the automatic temperature control device includes an automatic heating device and a heat dissipation device, if the molten steel temperature T is within 10°C higher than the liquidus temperature T1 , then cover the cover of the tundish and use the automatic heating device to heat and supplement the temperature of the molten steel; if the temperature T of the molten steel is higher than the liquidus temperature Tl by more than 20°C, open the cover of the tundish and use the cooling device to For heat dissipation, the automatic heating device stops heating, and the automatic temperature control device controls the temperature fluctuation of the molten steel in the tundish within 20°C. Such setting reduces the temperature fluctuation of the molten steel in the tundish, reduces the superheat of the molten steel in the crystallizer, is beneficial to reduce the segregation of the billet, and improves the toughness of the deformation dead zone 2 of the section steel. The continuous casting machine is equipped with mold electromagnetic stirring and terminal pressing device to homogenize the molten steel in the solidification process, so that the cross-section C of the slab is less than or equal to 0.04%, and the Mn limit is less than or equal to 0.06%. The design of the electromagnetic stirring of the mold and the terminal pressing device reduces the C range and Mn range of the billet, further reduces the segregation of the billet, and improves the toughness of the deformation dead zone 2 of the section steel.

步骤S3:钢坯经加热、轧制、冷却后制成磁浮轨道型钢。Step S3: After the steel billet is heated, rolled and cooled, it is made into a maglev rail profile.

钢坯的加热时间为3小时~6小时(比如:3小时、3.5小时、4小时、4.5小时、5小时、5.5小时、6小时),加热温度1150℃~1230℃(比如:1150℃、1160℃、1170℃、1180℃、1190℃、1200℃、1210℃、1220℃、1230℃),轧制终轧前的坯料断面设置有非平衡补偿区4。如图2所示,在原终轧前坯料断面形状3上,终轧前的坯料的非平衡补偿区4位于坯料的上方,相对于成品型钢,非平衡补偿区位于腹板12的上方且与中间腿13相对的位置,非平衡补偿区4为终轧道次的变形死区2带来额外的变形量,使型钢的变形死区2大于其它区域的变形量2%以上。加热时间和加热温度的设计,可对钢坯中的偏析元素起到扩散和均匀化作用,更进一步提高变形死区成分和组织均匀性,使型钢具有良好的导磁性能的同时,提高型钢整体的抗拉强度和延伸率。The heating time of the billet is 3 hours to 6 hours (for example: 3 hours, 3.5 hours, 4 hours, 4.5 hours, 5 hours, 5.5 hours, 6 hours), and the heating temperature is 1150°C to 1230°C (for example: 1150°C, 1160°C , 1170°C, 1180°C, 1190°C, 1200°C, 1210°C, 1220°C, 1230°C), the section of the billet before the final rolling is provided with an unbalanced compensation zone 4. As shown in Figure 2, on the cross-sectional shape 3 of the billet before final rolling, the unbalanced compensation area 4 of the billet before final rolling is located above the billet, and relative to the finished section steel, the unbalanced compensation area is located above the web 12 and in the middle In the relative position of the legs 13, the unbalance compensation zone 4 brings additional deformation to the deformation dead zone 2 of the final rolling pass, making the deformation dead zone 2 of the section steel more than 2% larger than the deformation in other zones. The design of heating time and heating temperature can diffuse and homogenize the segregated elements in the billet, further improve the composition of the deformation dead zone and the uniformity of the structure, so that the section steel has good magnetic permeability and at the same time improve the overall strength of the section steel. Tensile strength and elongation.

冷却为轧制后空冷至环境温度,成品组织为多边形铁素体和珠光体,型钢的横断面上变形死区的晶粒度和其它区域的晶粒度之间的差别不大于1级。现有技术的型钢的变形死区轧制过程应变量很小,晶粒比型钢断面其它区域粗大2级以上,应力为拉应力状态,造成H原子聚集,导致型钢的韧性较差。在本发明的实施例中,型钢的H含量的控制从源头上减少了H原子的聚集数量。终轧前坯料断面的非平衡补偿区4和额外压下量大于2%的设计,增大了变形死区2的变形量,带来了晶粒细化效果,且使变形死区2的应力状态转变为压应力状态,消除了变形死区H原子聚集,防止氢致裂纹引起的韧性下降。Cooling is air cooling to ambient temperature after rolling, the finished product structure is polygonal ferrite and pearlite, and the difference between the grain size of the deformation dead zone and the grain size of other areas on the cross section of the section steel is not more than 1 grade. In the prior art, the strain in the deformation dead zone rolling process is very small, the grains are more than 2 grades thicker than other areas of the steel section, and the stress is in a state of tensile stress, which causes H atoms to gather, resulting in poor toughness of the steel. In the embodiment of the present invention, the control of the H content of the section steel reduces the aggregation number of H atoms from the source. The unbalanced compensation zone 4 of the billet section before final rolling and the design of the extra reduction greater than 2% increase the deformation amount of the deformation dead zone 2, bring about the effect of grain refinement, and make the stress of the deformation dead zone 2 The state is transformed into a compressive stress state, which eliminates the accumulation of H atoms in the deformation dead zone and prevents the decrease in toughness caused by hydrogen-induced cracks.

上述制备方法采用一次热轧成型工艺直接轧制出磁浮轨道,避免了钢板的焊接与二次加工,降低了轨道制造过程的碳排放,工艺简洁,降低了成本,提高了效率。磁浮轨道的屈服强度≥270MPa、延伸率≥28%、饱和磁感应强度B100≥1.78T、低温冲击性能≥200J。The above preparation method adopts a hot rolling forming process to directly roll out the maglev track, which avoids the welding and secondary processing of the steel plate, reduces the carbon emission in the track manufacturing process, has a simple process, reduces the cost, and improves the efficiency. The yield strength of the maglev track is ≥270MPa, the elongation is ≥28%, the saturation magnetic induction intensity B100 is ≥1.78T, and the low temperature impact performance is ≥200J.

需要说明的是,本发明的工艺参数区间上下限取值以及区间值都能实现本法,在此不一一列举实施例。本发明未详细说明的内容均可采用本领域的常规技术知识。It should be noted that the upper and lower limits of the process parameter interval and the interval value of the present invention can realize this method, and the examples are not listed here. The conventional technical knowledge in this field can be used for the contents not described in detail in the present invention.

实施例1:Example 1:

一种磁浮轨道型钢,型钢按质量百分比由以下化学成分组成:C:0.08%、Si:0.50%、Mn:0.80%、P:0.013%、S:0.010%、Als:0.024%、Cr:0.1%、Cu:0.2%、Ni:0.30%、Ti:0.003%、B:30ppm、H:1.2ppm、其余为铁和不可避免的夹杂。型钢横断面C极差为0.03%、Mn极差为0.05%。A maglev rail profile steel, the profile steel is composed of the following chemical components in terms of mass percentage: C: 0.08%, Si: 0.50%, Mn: 0.80%, P: 0.013%, S: 0.010%, Als: 0.024%, Cr: 0.1% , Cu: 0.2%, Ni: 0.30%, Ti: 0.003%, B: 30ppm, H: 1.2ppm, and the rest are iron and unavoidable inclusions. The cross-section C of the section steel is 0.03%, and the Mn is 0.05%.

制备上述的磁浮轨道型钢的方法为:钢坯采用转炉、LF精炼和VD真空炉冶炼,采用连铸机铸造出钢坯,钢坯经加热、轧制、冷却后制成磁浮轨道型钢。LF精炼的钢包内衬和精炼渣、合金采用低Ti低B含量材料,Ti含量(质量百分比)为0.02%,B含量(质量百分比)为0.01%。LF精炼过程中先加Al线,再加Ca线,最后加B线。The method for preparing the above-mentioned magnetic levitation track section steel is as follows: the steel billet is smelted in a converter, LF refining and VD vacuum furnace, and the steel billet is cast by a continuous casting machine, and the steel billet is made into a magnetic levitation track section steel after heating, rolling and cooling. The ladle lining, refining slag and alloy of LF refining are made of low Ti and low B content materials, the Ti content (mass percentage) is 0.02%, and the B content (mass percentage) is 0.01%. During the refining process of LF, the Al line is added first, then the Ca line, and finally the B line.

转炉炼钢原料为高炉铁水比例为90%,并进行预脱磷。The raw material for converter steelmaking is 90% blast furnace molten iron, which is pre-dephosphorized.

如钢液温度T比液相线温度Tl高10℃以内,则降下中间包包盖并对钢液进行加热补温;如钢液温度T比液相线温度Tl高20℃以上,则打开中间包包盖散热,并关闭自动加热装置。自动控制装置使包内钢液温度波动控制在20℃以内。If the molten steel temperature T is within 10°C higher than the liquidus temperature Tl, lower the tundish cover and heat the molten steel; if the molten steel temperature T is more than 20°C higher than the liquidus temperature Tl, open the tundish The bag lid dissipates heat and turns off the automatic heating mechanism. The automatic control device controls the temperature fluctuation of molten steel in the ladle within 20°C.

连铸机设置的结晶器电磁搅拌和末端压下装置对凝固过程的钢液进行均匀化,使铸坯断面C极差≤0.04%,Mn极差≤0.06%。The mold electromagnetic stirring and terminal pressing device installed in the continuous casting machine can homogenize the molten steel in the solidification process, so that the cross-section C of the slab is less than or equal to 0.04%, and the Mn limit is less than or equal to 0.06%.

钢坯加热时间6小时,加热温度1150℃。利用非平衡补偿区为终轧道次的变形死区带来额外的变形量,且大于其它区域的变形量3%。The billet heating time is 6 hours, and the heating temperature is 1150°C. Using the unbalanced compensation zone brings additional deformation to the deformation dead zone in the final rolling pass, which is 3% larger than the deformation in other zones.

冷却为空冷至环境温度,成品组织为多边形铁素体和珠光体,型钢横断面上变形死区和其它区域的晶粒度差不大于1级。Cooling is air cooling to ambient temperature, the finished product structure is polygonal ferrite and pearlite, and the grain size difference between the deformation dead zone and other zones on the section steel section is not more than 1 grade.

实施例2:Example 2:

一种磁浮轨道型钢,型钢按质量百分比由以下化学成分组成:C:0.10%、Si:0.20%、Mn:1.0%、P:0.010%、S:0.005%、Als:0.045%、Cr:0.2%、Cu:0.1%、Ni:0.20%、Ti:0.001%、B:20ppm、H:1.0ppm、其余为铁和不可避免的夹杂。型钢横断面C极差为0.02%,Mn极差为0.05%。A magnetic levitation rail profile steel, the profile steel is composed of the following chemical components in terms of mass percentage: C: 0.10%, Si: 0.20%, Mn: 1.0%, P: 0.010%, S: 0.005%, Als: 0.045%, Cr: 0.2% , Cu: 0.1%, Ni: 0.20%, Ti: 0.001%, B: 20ppm, H: 1.0ppm, and the rest are iron and unavoidable inclusions. The extreme difference of C in the cross section of the section steel is 0.02%, and the extreme difference of Mn is 0.05%.

制备上述的磁浮轨道型钢的方法为:钢坯采用转炉、LF精炼和VD真空炉冶炼,采用连铸机铸造出钢坯,钢坯经加热、轧制、冷却后制成磁浮轨道型钢。LF精炼的钢包内衬和精炼渣、合金采用低Ti低B含量材料,Ti含量(质量百分比)为0.01%,B含量(质量百分比)为0.02%。LF精炼过程中先加Al线,再加Ca线,最后加B线。The method for preparing the above-mentioned magnetic levitation track section steel is as follows: the steel billet is smelted in a converter, LF refining and VD vacuum furnace, and the steel billet is cast by a continuous casting machine, and the steel billet is made into a magnetic levitation track section steel after heating, rolling and cooling. The ladle lining, refining slag and alloy of LF refining are made of low Ti and low B content materials, the Ti content (mass percentage) is 0.01%, and the B content (mass percentage) is 0.02%. During the refining process of LF, the Al line is added first, then the Ca line, and finally the B line.

转炉炼钢原料为高炉铁水比例为92%,并进行预脱磷。The raw material for converter steelmaking is 92% blast furnace molten iron, which is pre-dephosphorized.

连铸中间包设有自动加热和散热装置。如钢液温度T比液相线温度Tl高10℃以内,则降下中间包的包盖并对钢液进行加热补温;如钢液温度T比液相线温度Tl高20℃以上,则打开中间包的包盖散热,并关闭加热装置。自动控制装置使包内钢液温度波动控制在15℃以内。Continuous casting tundish is equipped with automatic heating and cooling device. If the molten steel temperature T is within 10°C higher than the liquidus temperature Tl, lower the cover of the tundish and heat the molten steel; if the molten steel temperature T is higher than the liquidus temperature Tl by more than 20°C, open it The cover of the tundish dissipates heat and turns off the heating device. The automatic control device controls the temperature fluctuation of molten steel in the ladle within 15°C.

连铸设置有结晶器电磁搅拌和末端压下装置,对凝固过程的钢液进行均匀化,使铸坯断面C极差≤0.04%,Mn极差≤0.06%。The continuous casting is equipped with mold electromagnetic stirring and terminal pressing device to homogenize the molten steel in the solidification process, so that the cross-section C of the slab is less than or equal to 0.04%, and the Mn limit is less than or equal to 0.06%.

钢坯加热时间3小时,加热温度1230℃。非平衡补偿区为终轧道次的变形死区带来额外的变形量,且大于其它区域的变形量5%。The billet heating time is 3 hours, and the heating temperature is 1230°C. The unbalanced compensation zone brings additional deformation to the deformation dead zone in the final rolling pass, which is 5% larger than the deformation in other zones.

冷却为空冷至环境温度,成品组织为多边形铁素体和珠光体,型钢横断面上变形死区和其它区域的晶粒度差不大于1级。Cooling is air cooling to ambient temperature, the finished product structure is polygonal ferrite and pearlite, and the grain size difference between the deformation dead zone and other zones on the section steel section is not more than 1 grade.

实施例3:Example 3:

一种磁浮轨道型钢,型钢按质量百分比由以下化学成分组成:C:0.12%、Si:0.40%、Mn:0.9%、P:0.012%、S:0.007%、Als:0.055%、Cr:0.10%、Cu:0.10%、Ni:0.20%、Ti:0.001%、B:20ppm、H:1.5ppm、其余为铁和不可避免的夹杂。型钢横断面C极差为0.02%,Mn极差为0.02%。A magnetic levitation rail profile steel, the profile steel is composed of the following chemical components in terms of mass percentage: C: 0.12%, Si: 0.40%, Mn: 0.9%, P: 0.012%, S: 0.007%, Als: 0.055%, Cr: 0.10% , Cu: 0.10%, Ni: 0.20%, Ti: 0.001%, B: 20ppm, H: 1.5ppm, and the rest are iron and unavoidable inclusions. The extreme difference of C in the cross section of the section steel is 0.02%, and the extreme difference of Mn is 0.02%.

制备上述的磁浮轨道型钢的方法为:钢坯采用转炉、LF精炼和VD真空炉冶炼,采用连铸机铸造出钢坯,钢坯经加热、轧制、冷却后制成磁浮轨道型钢。LF精炼的钢包内衬和精炼渣、合金采用低Ti低B含量材料,Ti含量(质量百分比)为0.01%,B含量(质量百分比)为0.01%。LF精炼过程中先加Al线,再加Ca线,最后加B线。The method for preparing the above-mentioned magnetic levitation track section steel is as follows: the steel billet is smelted in a converter, LF refining and VD vacuum furnace, and the steel billet is cast by a continuous casting machine, and the steel billet is made into a magnetic levitation track section steel after heating, rolling and cooling. The ladle lining, refining slag and alloy of LF refining are made of low Ti and low B content materials, the Ti content (mass percentage) is 0.01%, and the B content (mass percentage) is 0.01%. During the refining process of LF, the Al line is added first, then the Ca line, and finally the B line.

转炉炼钢原料为高炉铁水比例为98%,并进行预脱磷,出钢过程中采用滑动挡渣装置。The raw material for converter steelmaking is blast furnace molten iron with a ratio of 98%, and pre-dephosphorization is carried out, and a sliding slag blocking device is used in the tapping process.

连铸中间包设有自动加热和散热装置。如钢液温度T比液相线温度Tl高10℃以内,则降下中间包包盖并对钢液进行加热补温;如钢液温度T比液相线温度Tl高20℃以上,则打开中间包包盖散热,并关闭加热装置。自动控制装置使包内钢液温度波动控制在15℃以内。Continuous casting tundish is equipped with automatic heating and cooling device. If the molten steel temperature T is within 10°C higher than the liquidus temperature Tl, lower the tundish cover and heat the molten steel; if the molten steel temperature T is more than 20°C higher than the liquidus temperature Tl, open the tundish The bag lid dissipates heat and turns off the heating. The automatic control device controls the temperature fluctuation of molten steel in the ladle within 15°C.

连铸设置有结晶器电磁搅拌和末端压下装置,对凝固过程的钢液进行均匀化,使铸坯断面C极差≤0.04%,Mn极差≤0.06%。The continuous casting is equipped with mold electromagnetic stirring and terminal pressing device to homogenize the molten steel in the solidification process, so that the cross-section C of the slab is less than or equal to 0.04%, and the Mn limit is less than or equal to 0.06%.

钢坯加热时间5小时,加热温度1200℃。非平衡补偿区为终轧道次的变形死区带来额外的变形量,且大于其它区域的变形量5%。The billet heating time is 5 hours, and the heating temperature is 1200°C. The unbalanced compensation zone brings additional deformation to the deformation dead zone in the final rolling pass, which is 5% larger than the deformation in other zones.

冷却为空冷至环境温度,成品组织为多边形铁素体和珠光体,型钢横断面上变形死区和其它区域的晶粒度差不大于1级。Cooling is air cooling to ambient temperature, the finished product structure is polygonal ferrite and pearlite, and the grain size difference between the deformation dead zone and other zones on the section steel section is not more than 1 grade.

表1:本发明实施例1-3所制备出的型钢的性能:Table 1: Properties of the shaped steel prepared in Examples 1-3 of the present invention:

由表1可见,实施例1~3所制备的磁浮轨道型钢具有优异的屈服强度、延伸率和低温冲击韧性,较高的饱和磁感应强度,从整体上提高了磁浮轨道型钢的综合性能。It can be seen from Table 1 that the maglev track-shaped steel prepared in Examples 1-3 has excellent yield strength, elongation and low-temperature impact toughness, and high saturation magnetic induction, which improves the comprehensive performance of the maglev track-shaped steel as a whole.

从以上的描述中,可以看出,本发明上述的实施例实现了如下技术效果:From the above description, it can be seen that the above-mentioned embodiments of the present invention have achieved the following technical effects:

1)采用一次热轧成型工艺直接轧制出磁浮轨道,避免了钢板的焊接与二次加工,降低了轨道制造过程的碳排放,导磁性、强度、延伸率和低温冲击韧性等综合性能优良。1) The maglev track is directly rolled out by a hot rolling forming process, which avoids welding and secondary processing of the steel plate, reduces carbon emissions in the track manufacturing process, and has excellent comprehensive properties such as magnetic permeability, strength, elongation, and low-temperature impact toughness.

2)钢包内衬和精炼渣、合金均采用低Ti低B含量材料的设计显著降低了型钢中对导磁性不利的Ti元素含量,并使B含量控制在较小的波动范围,为LF精炼后期添加B线,稳定钢中的B含量起到了辅助作用,在获得较好的低温冲击性能的同时,避免了过量添加B导致的钢材裂纹、疲劳性能降低等不足。2) The ladle lining, refining slag, and alloys are all designed with low Ti and low B content materials, which significantly reduces the Ti element content in the section steel that is unfavorable to magnetic permeability, and controls the B content within a small fluctuation range, which is the best choice for the later stage of LF refining. Adding the B line, the B content in the stabilized steel plays an auxiliary role. While obtaining better low-temperature impact performance, it avoids the defects of steel cracks and fatigue performance reduction caused by excessive addition of B.

3)自动控温装置使中间包内钢液的温度波动控制在20℃以内,减小了中间包钢液温度波动,降低了结晶器钢液过热度,有利于减轻钢坯的偏析,较小C元素和Mn元素极差,提高型钢的变形死区2的韧性。3) The automatic temperature control device controls the temperature fluctuation of the molten steel in the tundish within 20°C, which reduces the temperature fluctuation of the molten steel in the tundish, reduces the superheat of the molten steel in the mold, and is beneficial to reduce the segregation of the billet, and the smaller C Elements and Mn elements are extremely poor, and improve the toughness of the deformation dead zone 2 of the steel.

4)型钢的H含量的控制从源头上减少了H原子的聚集数量。终轧前坯料断面的非平衡补偿区和额外压下量大于2%的设计,增大了变形死区2的变形量,带来了晶粒细化效果,且使变形死区2的应力状态转变为压应力状态,消除了变形死区H原子聚集,防止氢致裂纹引起的韧性下降。4) The control of the H content of the section steel reduces the aggregation of H atoms from the source. The unbalanced compensation area of the billet section before final rolling and the design of the additional reduction greater than 2% increase the deformation amount of the deformation dead zone 2, bring about the effect of grain refinement, and make the stress state of the deformation dead zone 2 Transforming into a compressive stress state eliminates the accumulation of H atoms in the deformation dead zone and prevents the toughness reduction caused by hydrogen-induced cracks.

以上所述仅为本发明的优选实施例,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included within the protection scope of the present invention.

Claims (10)

1.一种磁浮轨道型钢,其特征在于,1. A magnetic levitation track shaped steel, characterized in that, 所述型钢按质量百分比由以下化学成分组成:C:0.08%~0.13%、Si:0.20%~0.50%、Mn:0.80%~1.10%、P≤0.015%、S≤0.010%、Als:0.020%~0.060%、Cr≤0.20%、Cu≤0.20%、Ni≤0.30%、Ti≤0.005%、B≤40ppm、H≤1.5ppm、其余为铁和不可避免的杂质。The section steel is composed of the following chemical components in terms of mass percentage: C: 0.08%-0.13%, Si: 0.20%-0.50%, Mn: 0.80%-1.10%, P≤0.015%, S≤0.010%, Als: 0.020% ~0.060%, Cr≤0.20%, Cu≤0.20%, Ni≤0.30%, Ti≤0.005%, B≤40ppm, H≤1.5ppm, and the rest are iron and unavoidable impurities. 2.根据权利要求1所述的磁浮轨道型钢,其特征在于,2. The magnetic levitation track section steel according to claim 1, characterized in that, 所述型钢横断面C极差≤0.03%,Mn极差≤0.05%。The cross-section C of the profiled steel has a range of ≤0.03%, and a Mn range of ≤0.05%. 3.一种权利要求1~2任一项所述的磁浮轨道型钢的制备方法,其特征在于,包括如下步骤:3. A preparation method for the magnetic levitation track profiled steel according to any one of claims 1 to 2, characterized in that, comprising the steps of: 步骤S1:采用转炉、LF精炼和VD真空炉冶炼,Step S1: using converter, LF refining and VD vacuum furnace for smelting, 步骤S2:采用连铸机铸造出钢坯,Step S2: using a continuous casting machine to cast a billet, 步骤S3:钢坯经加热、轧制、冷却后制成磁浮轨道型钢。Step S3: After the steel billet is heated, rolled and cooled, it is made into a maglev rail profile. 4.根据权利要求3所述的制备方法,其特征在于,4. preparation method according to claim 3, is characterized in that, 在所述步骤S1中,高炉铁水在转炉炼钢的原料中占比不小于90%,In the step S1, the blast furnace molten iron accounts for not less than 90% of the raw materials for converter steelmaking, 将高炉铁水进行预脱磷,转炉出钢过程中采用滑动挡渣装置。Pre-dephosphorize the blast furnace molten iron, and use a sliding slag blocking device during the tapping process of the converter. 5.根据权利要求3所述的制备方法,其特征在于,5. preparation method according to claim 3, is characterized in that, 在所述步骤S1中,LF精炼的钢包内衬、精炼渣和合金均采用低Ti低B材料,其中,按质量百分比Ti含量≤0.02%,按质量百分比B含量≤0.02%。In the step S1, the ladle lining, refining slag and alloys refined by LF are all made of low Ti and low B materials, wherein the Ti content is ≤0.02% by mass percentage, and the B content is ≤0.02% by mass percentage. 6.根据权利要求3所述的制备方法,其特征在于,6. preparation method according to claim 3, is characterized in that, 在所述步骤S1中,在LF精炼过程中先加Al线,再加Ca线,最后加B线。In the step S1, during the LF refining process, the Al wire is added first, then the Ca wire is added, and finally the B wire is added. 7.根据权利要求3所述的制备方法,其特征在于,7. preparation method according to claim 3, is characterized in that, 在所述步骤S2中,连铸机的连铸中间包设有自动控温装置,In said step S2, the continuous casting tundish of the continuous casting machine is provided with an automatic temperature control device, 如果钢液温度T比液相线温度Tl高10℃以内,则盖上中间包的包盖并对钢液进行加热补温;If the molten steel temperature T is within 10°C higher than the liquidus temperature T1, cover the tundish cover and heat the molten steel; 如果钢液温度T比液相线温度Tl高20℃以上,则打开中间包的包盖散热,并停止加热,If the temperature T of the molten steel is higher than the liquidus temperature Tl by more than 20°C, open the cover of the tundish to dissipate heat and stop heating. 自动控温装置使中间包内钢液的温度波动控制在20℃以内。The automatic temperature control device controls the temperature fluctuation of the molten steel in the tundish within 20°C. 8.根据权利要求3所述的制备方法,其特征在于,8. preparation method according to claim 3, is characterized in that, 连铸机设置有结晶器电磁搅拌和末端压下装置,对凝固过程的钢液进行均匀化,使铸坯断面C极差≤0.04%,Mn极差≤0.06%。The continuous casting machine is equipped with mold electromagnetic stirring and terminal pressing device to homogenize the molten steel in the solidification process, so that the cross-section C of the slab is less than or equal to 0.04%, and the Mn limit is less than or equal to 0.06%. 9.根据权利要求3所述的制备方法,其特征在于,9. preparation method according to claim 3, is characterized in that, 在所述步骤S3中,钢坯的加热时间为3小时~6小时,加热温度1150℃~1230℃,In the step S3, the heating time of the billet is 3 hours to 6 hours, and the heating temperature is 1150°C to 1230°C, 轧制终轧前的坯料断面设置有非平衡补偿区,所述非平衡补偿区为终轧道次的变形死区带来额外的变形量,且大于其它区域的变形量2%以上。The section of the billet before the final rolling is provided with an unbalanced compensation area, and the unbalanced compensation area brings additional deformation to the deformation dead zone of the final rolling pass, which is more than 2% larger than the deformation in other areas. 10.根据权利要求3所述的制备方法,其特征在于,10. preparation method according to claim 3, is characterized in that, 冷却为轧制后空冷至环境温度,成品组织为多边形铁素体和珠光体,型钢的横断面上变形死区的晶粒度和其它区域的晶粒度之间的差别不大于1级。Cooling is air cooling to ambient temperature after rolling, the finished product structure is polygonal ferrite and pearlite, and the difference between the grain size of the deformation dead zone and the grain size of other areas on the cross section of the section steel is not more than 1 grade.
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