CN116675717A - Palladium complex activator, nanocomposite material, finishing agent, textile fabric and its application - Google Patents
Palladium complex activator, nanocomposite material, finishing agent, textile fabric and its application Download PDFInfo
- Publication number
- CN116675717A CN116675717A CN202210161501.2A CN202210161501A CN116675717A CN 116675717 A CN116675717 A CN 116675717A CN 202210161501 A CN202210161501 A CN 202210161501A CN 116675717 A CN116675717 A CN 116675717A
- Authority
- CN
- China
- Prior art keywords
- palladium
- negative ion
- textile fabric
- nanocomposite
- emitting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title claims abstract description 104
- 229910052763 palladium Inorganic materials 0.000 title claims abstract description 48
- 239000012190 activator Substances 0.000 title claims abstract description 40
- 239000004744 fabric Substances 0.000 title claims description 79
- 239000004753 textile Substances 0.000 title claims description 79
- 239000000463 material Substances 0.000 title claims description 68
- 239000003795 chemical substances by application Substances 0.000 title claims description 61
- 239000002114 nanocomposite Substances 0.000 title claims description 60
- 238000000034 method Methods 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 26
- 150000001875 compounds Chemical class 0.000 claims abstract description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 15
- 150000002941 palladium compounds Chemical class 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims abstract description 10
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims abstract description 9
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000004985 diamines Chemical class 0.000 claims abstract description 8
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012454 non-polar solvent Substances 0.000 claims abstract description 8
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims abstract description 7
- 230000035484 reaction time Effects 0.000 claims abstract description 7
- 150000002940 palladium Chemical class 0.000 claims abstract description 5
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims abstract description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 4
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000002500 ions Chemical class 0.000 claims description 108
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- 239000000377 silicon dioxide Substances 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000000498 ball milling Methods 0.000 claims description 13
- 235000012239 silicon dioxide Nutrition 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 9
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 9
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 9
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims description 7
- 239000001263 FEMA 3042 Substances 0.000 claims description 7
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims description 7
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 claims description 7
- 229940033123 tannic acid Drugs 0.000 claims description 7
- 235000015523 tannic acid Nutrition 0.000 claims description 7
- 229920002258 tannic acid Polymers 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 6
- 239000002798 polar solvent Substances 0.000 claims description 6
- 238000010668 complexation reaction Methods 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 229920006243 acrylic copolymer Polymers 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims 1
- 230000005855 radiation Effects 0.000 abstract description 35
- 239000002131 composite material Substances 0.000 abstract description 11
- 125000004427 diamine group Chemical group 0.000 abstract description 7
- 230000005284 excitation Effects 0.000 abstract description 6
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 description 15
- 239000000047 product Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000008204 material by function Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000007721 medicinal effect Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- -1 oxygen ions Chemical class 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001303 quality assessment method Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/006—Palladium compounds
- C07F15/0066—Palladium compounds without a metal-carbon linkage
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/238—Tannins, e.g. gallotannic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/503—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms without bond between a carbon atom and a metal or a boron, silicon, selenium or tellurium atom
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明公开了一种钯配合物激发剂，由钯化合物与含有双胺基或羟基的化合物在非极性溶剂中进行络合反应制得。其中，所述钯化合物为可溶性钯盐，优选为氯化钯、硝酸钯或硫酸钯；所述含有双胺基或羟基的化合物包括邻苯二酚或邻苯二胺中的至少一种；所述非极性溶剂包括吡啶或正己烷中的至少一种；所述钯化合物中的钯元素与所述含有双胺基或羟基的化合物的质量比为1:5‑5:1；所述络合反应的反应温度为50～110℃，压力为0.1～0.3MPa，反应时间为2～5h。本发明的方法制得的钯配合物激发剂能够与负离子发射功能粉体复合，显著提高了复合材料的激发效率，同时能够降低有害辐射。
The invention discloses a palladium complex activator, which is prepared by performing a complex reaction between a palladium compound and a compound containing a diamine group or a hydroxyl group in a non-polar solvent. Wherein, the palladium compound is a soluble palladium salt, preferably palladium chloride, palladium nitrate or palladium sulfate; the compound containing diamine or hydroxyl includes at least one of catechol or o-phenylenediamine; The non-polar solvent includes at least one of pyridine or normal hexane; the mass ratio of the palladium element in the palladium compound to the compound containing diamine or hydroxyl is 1:5-5:1; the complex The reaction temperature of the synthesis reaction is 50-110° C., the pressure is 0.1-0.3 MPa, and the reaction time is 2-5 hours. The palladium complex activator prepared by the method of the invention can be compounded with the anion-emitting functional powder, which significantly improves the excitation efficiency of the composite material and can reduce harmful radiation at the same time.
Description
技术领域technical field
本发明属于负离子发射材料技术领域，具体涉及一种钯配合物激发剂，进一步地还涉及一种负离子发射纳米复合材料及其制备方法，更进一步地，还涉及一种纺织面料用后整理剂、纺织面料及其应用。The invention belongs to the technical field of negative ion emitting materials, and specifically relates to a palladium complex activator, further relates to a negative ion emitting nanocomposite material and a preparation method thereof, and further relates to a finishing agent for textile fabrics, Textile fabrics and their applications.
背景技术Background technique
负离子是指带负电荷的氧离子，无色无味。空气负离子的分子式是O2-(H2O)n，或OH-(H2O)n,或CO4-(H2O)n。负离子不仅能促成人体合成和储存维生素，强化和激活人体的生理活动，因此它又被称为"空气维生素"。负离子是空气质量优劣评定的重要指标，在公园和景区中会常见负离子浓度显示牌，通过测量此处的负离子含量对空气质量进行评定。国际卫生组织认为当负离子含量达到1000个/立方厘米以上时，空气质量为优，长期生活在这样的空气环境中，可以改善人的免疫系统，提高人体免疫力。当负离子含量达到3000个/立方厘米以上时，可以具有辅助医疗效果，对一些疾病的治疗和身体的康复具有积极作用。还有研究表明，负离子在空气污染治理上具有显著效果，例如可以与醛类等有害气体结合，通过增加局部浓度的作用增加其被氧化效率，可以在根本上去除醛类等有害物质的浓度；也有研究者对负离子沉降微尘进行研究，发现提高负离子浓度可以有效沉降空气中的微小颗粒，从而净化空气。负离子功能纺织产品的开发技术源于日本，在2000年前后引入中国，有大量的学者和专家对负离子发生及作用机理进行研究，也有企业对负离子功能产品进行了成果转化，具有较好的经济效益。Negative ions refer to negatively charged oxygen ions, which are colorless and odorless. The molecular formula of negative air ion is O 2- (H 2 O)n, or OH - (H 2 O)n, or CO 4- (H 2 O)n. Negative ions can not only promote the synthesis and storage of vitamins in the human body, but also strengthen and activate the physiological activities of the human body, so it is also called "air vitamin". Negative ions are an important indicator of air quality assessment. In parks and scenic spots, negative ion concentration display boards are common, and the air quality is assessed by measuring the negative ion content here. The International Health Organization believes that when the negative ion content reaches more than 1000/cubic centimeter, the air quality is excellent, and living in such an air environment for a long time can improve the human immune system and enhance human immunity. When the content of negative ions reaches more than 3000 per cubic centimeter, it can have an auxiliary medical effect, and have a positive effect on the treatment of some diseases and the rehabilitation of the body. Studies have also shown that negative ions have a significant effect on air pollution control. For example, they can combine with harmful gases such as aldehydes, increase their oxidation efficiency by increasing the local concentration, and can fundamentally remove the concentration of harmful substances such as aldehydes; Some researchers have also conducted research on the deposition of fine dust by negative ions, and found that increasing the concentration of negative ions can effectively settle tiny particles in the air, thereby purifying the air. The development technology of negative ion functional textile products originated from Japan and was introduced to China around 2000. A large number of scholars and experts have conducted research on the generation and mechanism of negative ions, and some enterprises have transformed the results of negative ion functional products, which have good economic benefits. .
现有技术的负离子功能产品应用在纺织工业、塑料产品、纸制品等领域，这些产品的负离子释放数量不足，还有待提高，因此，需要对负离子发射功能材料进行改进。The negative ion functional products in the prior art are used in the textile industry, plastic products, paper products and other fields. The negative ion release quantity of these products is insufficient and needs to be improved. Therefore, it is necessary to improve the negative ion emitting functional materials.
发明内容Contents of the invention
本发明是基于发明人对以下事实和问题的发现和认识做出的：目前对于负离子发射材料的制备技术，存在操作复杂，过程不可控，使用有害金属等缺点，不利于工业化应用，并且负离子释放量仍然不足，无法满足现有生活品质的需求。The present invention is based on the inventor's discovery and understanding of the following facts and problems: the current preparation technology for negative ion emitting materials has disadvantages such as complicated operation, uncontrollable process, and use of harmful metals, which is not conducive to industrial applications, and negative ion release The amount is still insufficient to meet the needs of the existing quality of life.
本发明旨在至少在一定程度上解决相关技术中的技术问题之一。为此，本发明的实施例提出一种钯配合物激发剂，将钯化合物与含有双胺基或羟基的化合物进行络合反应，制得钯配合物激发剂，该钯配合物激发剂能够与负离子发射功能材料粉体复合，并对其激发，进而提高负离子发射功能材料粉体的负离子发射量。The present invention aims to solve one of the technical problems in the related art at least to a certain extent. For this reason, the embodiment of the present invention proposes a kind of palladium complex activator, palladium compound and the compound containing diamine group or hydroxyl are carried out complex reaction, makes palladium complex activator, and this palladium complex activator can be combined with The negative ion emitting functional material powder is recombined and excited, thereby increasing the negative ion emitting amount of the negative ion emitting functional material powder.
另外，该钯配合物激发剂还能在一定程度上降低负离子发射功能材料的有害辐射量。In addition, the palladium complex activator can also reduce the amount of harmful radiation of negative ion emitting functional materials to a certain extent.
本发明实施例的钯配合物激发剂，由钯化合物与含有双胺基或羟基的化合物在非极性溶剂中进行络合反应制得。The palladium complex activator of the embodiment of the present invention is prepared by performing a complex reaction between a palladium compound and a compound containing a diamine group or a hydroxyl group in a non-polar solvent.
本发明实施例的钯配合物激发剂带来的优点和技术效果，1、本发明实施例中，通过将钯化合物与含有双胺基或羟基的化合物进行络合反应制得钯配合物激发剂，该钯化合物经过配合以后，增强了与负离子发射功能粉体的结合力，在与负离子发射功能粉体复合后，能够提高负离子发射功能材料粉体的负离子发射量；2、本发明实施例的钯配合物激发剂的制备工艺简单，易于工业化应用，具有广阔的前景。The advantages and technical effects brought by the palladium complex activator of the embodiment of the present invention, 1. In the embodiment of the present invention, the palladium complex activator is prepared by complexing a palladium compound with a compound containing a diamine group or a hydroxyl group , the palladium compound strengthens the bonding force with the negative ion emitting functional powder after being coordinated, and after compounding with the negative ion emitting functional powder, the negative ion emission amount of the negative ion emitting functional material powder can be improved; 2, the embodiment of the present invention The preparation process of the palladium complex activator is simple, easy for industrial application, and has broad prospects.
在一些实施例中，所述钯化合物为可溶性钯盐，优选为氯化钯、硝酸钯或硫酸钯中的至少一种；和/或，所述含有双胺基或羟基的化合物包括邻苯二酚或邻苯二胺中的至少一种；和/或，所述非极性溶剂包括吡啶或正己烷中的至少一种；所述钯化合物中的钯元素与所述含有双胺基或羟基的化合物的质量比为1:5-5:1；和/或，所述络合反应的反应温度为50～110℃，压力为0.1～0.3MPa，反应时间为2～5h。In some embodiments, the palladium compound is a soluble palladium salt, preferably at least one of palladium chloride, palladium nitrate or palladium sulfate; and/or, the compound containing diamine or hydroxyl includes phthalic di At least one of phenol or o-phenylenediamine; And/or, the non-polar solvent includes at least one of pyridine or normal hexane; The mass ratio of the compound is 1:5-5:1; and/or, the reaction temperature of the complexation reaction is 50-110°C, the pressure is 0.1-0.3MPa, and the reaction time is 2-5h.
本发明实施例还提供了一种负离子发射纳米复合材料，包括本发明实施例的钯配合物激发剂和负离子发射功能材料粉体；The embodiment of the present invention also provides an anion-emitting nanocomposite material, including the palladium complex activator of the embodiment of the present invention and anion-emitting functional material powder;
优选地，所述负离子发射功能材料包括质量比为1:4-4:1的二氧化硅和六环石；Preferably, the negative ion emitting functional material comprises silicon dioxide and hexacyclite with a mass ratio of 1:4-4:1;
优选地，所述钯配合物激发剂和负离子发射功能材料的质量比为1:50-500。Preferably, the mass ratio of the palladium complex activator to the negative ion emitting functional material is 1:50-500.
本发明实施例的负离子发射纳米复合材料，加入了本发明实施例的钯配合物激发剂，钯配合物激发剂与负离子发射功能材料具有优异的结合力，能够显著提高该负离子发射纳米复合材料的激发效率；另外还可以降低负离子发射纳米复合材料的有害辐射。The anion-emitting nanocomposite material of the embodiment of the present invention has added the palladium complex activator of the embodiment of the present invention, the palladium complex activator has excellent binding force with the anion-emitting functional material, and can significantly improve the anion-emitting nanocomposite material. Excitation efficiency; In addition, it can also reduce the harmful radiation of negative ion emitting nanocomposite materials.
本发明实施例还提供了一种负离子发射纳米复合材料的制备方法，包括，将设计配比的钯配合物激发剂、负离子发射功能材料粉体和溶剂混合分散，加热反应，优选地，反应温度为80～140℃，反应时间为3～6h，制得负离子发射纳米复合材料。本发明实施例的制备方法，将钯配合物激发剂与负离子发射功能材料粉体进行加热反应制得负离子发射纳米复合材料，显著提高了复合材料的激发效率，同时降低了有害辐射，并且，制备方法简单，易于大规模工业化应用。The embodiment of the present invention also provides a preparation method of an anion-emitting nanocomposite material, comprising: mixing and dispersing a designed ratio of palladium complex activator, anion-emitting functional material powder, and a solvent, and heating the reaction. Preferably, the reaction temperature The temperature is 80-140° C., and the reaction time is 3-6 hours, and the anion-emitting nanocomposite material is prepared. In the preparation method of the embodiment of the present invention, the palladium complex activator and the negative ion emitting functional material powder are heated and reacted to prepare the negative ion emitting nanocomposite material, which significantly improves the excitation efficiency of the composite material and reduces harmful radiation at the same time, and prepares The method is simple and easy for large-scale industrial application.
本发明实施例还提供了一种纺织面料用后整理剂，包括本发明实施例的负离子发射纳米复合材料。本发明实施例的后整理剂，能够应用于纺织面料的后整理处理中，赋予纺织面料负离子发射功能。The embodiment of the present invention also provides a finishing agent for textile fabrics, including the negative ion emitting nanocomposite material of the embodiment of the present invention. The finishing agent of the embodiment of the present invention can be applied in the finishing treatment of textile fabrics, and endows the textile fabrics with an anion emitting function.
在一些实施例中，将所述负离子发射纳米复合材料加入极性溶剂进行湿法球磨处理；In some embodiments, the anion-emitting nanocomposite material is added into a polar solvent for wet ball milling;
优选地，所述极性溶剂包括水、乙醇、乙二醇或丙三醇中的至少一种；Preferably, the polar solvent includes at least one of water, ethanol, ethylene glycol or glycerol;
优选地，所述湿法球磨中加入聚乙烯吡咯烷酮，进一步优选地，所述聚乙烯吡咯烷酮的加入量为负离子发射纳米复合材料的0.2-2wt％；Preferably, polyvinylpyrrolidone is added in the wet ball milling, further preferably, the amount of polyvinylpyrrolidone added is 0.2-2wt% of the anion-emitting nanocomposite;
优选地，所述负离子发射纳米复合材料的质量浓度为30-50％。Preferably, the mass concentration of the negative ion emitting nanocomposite material is 30-50%.
在一些实施例中，所述后整理剂还包括成膜剂，优选地，所述成膜剂包括聚氨酯、丙烯酸类共聚物或明胶中的至少一种；优选地，所述成膜剂与负离子发射纳米复合材料的质量比为(1-10):1；和/或，所述后整理剂还包括鞣酸，优选地，所述鞣酸的加入量为负离子发射纳米复合材料质量的5-15％。In some embodiments, the finishing agent also includes a film-forming agent, preferably, the film-forming agent includes at least one of polyurethane, acrylic copolymer or gelatin; preferably, the film-forming agent and anion The mass ratio of emission nanocomposite material is (1-10): 1; And/or, described finishing agent also comprises tannic acid, preferably, the addition of described tannic acid is negative ion emission nanocomposite quality 5- 15%.
本发明实施例还提供了一种纺织面料，所述纺织面料的制备方法包括，将待处理纺织面料采用本发明实施例的后整理剂通过浸轧处理进行后整理，制得纺织面料。本方面实施例的制备方法，对纺织面料采用后整理剂进行处理后，赋予了纺织面料负离子发射功能，使纺织面料能够应用于更多领域。The embodiment of the present invention also provides a textile fabric. The preparation method of the textile fabric includes: finishing the textile fabric to be treated by padding with the finishing agent according to the embodiment of the present invention to obtain the textile fabric. In the preparation method of the embodiment of this aspect, after the textile fabric is treated with a finishing agent, the textile fabric is endowed with an anion emitting function, so that the textile fabric can be applied in more fields.
在一些实施例中，将所述后整理剂稀释2-10倍进行浸轧处理。In some embodiments, the finishing agent is diluted 2-10 times for padding treatment.
本发明实施例还提供了一种纺织面料在汽车内饰中的应用。本发明实施例的纺织面料能够应用于汽车内饰中，纺织面料释放的负离子，有效改善了汽车内的空气环境，提高了汽车的舒适性。The embodiment of the invention also provides the application of a textile fabric in automobile interior decoration. The textile fabric of the embodiment of the present invention can be applied to the interior decoration of automobiles, and the negative ions released by the textile fabric can effectively improve the air environment in the automobile and improve the comfort of the automobile.
附图说明Description of drawings
图1是本发明实施例1制得的含有成膜剂的后整理剂干燥处理后的SEM图。Fig. 1 is an SEM image of a finishing agent containing a film-forming agent prepared in Example 1 of the present invention after drying treatment.
具体实施方式Detailed ways
下面详细描述本发明的实施例，所述实施例的示例在附图中示出。下面通过参考附图描述的实施例是示例性的，旨在用于解释本发明，而不能理解为对本发明的限制。Embodiments of the invention are described in detail below, examples of which are illustrated in the accompanying drawings. The embodiments described below by referring to the figures are exemplary and are intended to explain the present invention and should not be construed as limiting the present invention.
本发明实施例的钯配合物激发剂，由钯化合物与含有双胺基或羟基的化合物在非极性溶剂中进行络合反应制得。The palladium complex activator of the embodiment of the present invention is prepared by performing a complex reaction between a palladium compound and a compound containing a diamine group or a hydroxyl group in a non-polar solvent.
本发明实施例的钯配合物激发剂，通过将金属钯化合物与含有双胺基或羟基的化合物进行络合反应制得钯配合物激发剂，钯化合物经过配合以后，增强了与负离子发射功能粉体的结合力，在与负离子发射功能粉体复合后，能够显著提高复合材料的激发效率，同时降低了复合材料的有害辐射；本发明实施例的钯配合物激发剂的制备工艺简单，易于工业化应用，具有广阔的前景。The palladium complex activator of the embodiment of the present invention is prepared by carrying out a complexation reaction between a metal palladium compound and a compound containing a diamine group or a hydroxyl group. The binding force of the body, after compounding with the negative ion emitting functional powder, can significantly improve the excitation efficiency of the composite material, and reduce the harmful radiation of the composite material; application has broad prospects.
在一些实施例中，所述钯化合物为可溶性钯盐，优选为氯化钯、硝酸钯或硫酸钯中的至少一种；所述含有双胺基或羟基的化合物包括邻苯二酚或邻苯二胺中的至少一种；所述非极性溶剂包括吡啶或正己烷中的至少一种；优选地，所述钯化合物中的钯元素与所述含有双胺基或羟基的化合物的质量比为1:5-5:1，进一步优选为1:2-2:1，更优选为1:1。优选地，所述络合反应的反应温度为50～110℃，压力为0.1～0.3MPa，反应时间为2～5h。本发明实施例的方法中，优选了钯元素与所述含有双胺基或羟基的化合物的质量比，进一步提高了钯配合物激发剂与负离子发射功能粉体的结合能力，提高了钯配合物激发剂与负离子发射功能粉体复合后的负离子发射量。In some embodiments, the palladium compound is a soluble palladium salt, preferably at least one of palladium chloride, palladium nitrate or palladium sulfate; the compound containing diamine or hydroxyl group includes catechol or catechol At least one of diamines; the non-polar solvent includes at least one of pyridine or n-hexane; preferably, the mass ratio of the palladium element in the palladium compound to the compound containing diamine or hydroxyl 1:5-5:1, more preferably 1:2-2:1, more preferably 1:1. Preferably, the reaction temperature of the complexation reaction is 50-110° C., the pressure is 0.1-0.3 MPa, and the reaction time is 2-5 hours. In the method of the embodiment of the present invention, the mass ratio of palladium element to the compound containing diamine groups or hydroxyl groups is optimized, which further improves the binding ability of the palladium complex activator and the negative ion emitting functional powder, and improves the palladium complex activator. The amount of negative ion emission after the activator is compounded with the negative ion emitting functional powder.
本发明实施例还提供了一种负离子发射纳米复合材料，包括本发明实施例的钯配合物激发剂和负离子发射功能材料粉体。本发明实施例的负离子发射纳米复合材料，加入了本发明实施例的钯配合物激发剂，钯配合物激发剂与负离子发射功能材料具有优异的结合力，能够显著提高复合材料的激发效率，并降低了有害辐射。The embodiment of the present invention also provides a negative ion emitting nanocomposite material, including the palladium complex activator of the embodiment of the present invention and negative ion emitting functional material powder. The anion-emitting nanocomposite material of the embodiment of the present invention adds the palladium complex activator of the embodiment of the present invention, the palladium complex activator has excellent binding force with the anion-emitting functional material, can significantly improve the excitation efficiency of the composite material, and Harmful radiation is reduced.
在一些实施例中，优选地，所述负离子发射功能材料包括质量比为1:4-4:1的二氧化硅和六环石，进一步优选为2:1-1:2，更优选为1:2。本发明实施例中采用二氧化硅和六环石的混合物料为负离子发射功能材料，二氧化硅具有优异的吸附性能和分散性能，使负离子发射纳米复合材料不仅能够释放负离子，而且能够除味和去除甲醛。本发明实施例中优选了二氧化硅和六环石的配比，可以进一步提高复合材料的负离子发射量。In some embodiments, preferably, the negative ion emitting functional material comprises silicon dioxide and hexacyclite with a mass ratio of 1:4-4:1, more preferably 2:1-1:2, more preferably 1 :2. In the embodiment of the present invention, the mixed material of silicon dioxide and hexacyclite is used as the negative ion emitting functional material. Silicon dioxide has excellent adsorption performance and dispersion performance, so that the negative ion emitting nanocomposite material can not only release negative ions, but also deodorize and deodorize. Remove formaldehyde. In the embodiment of the present invention, the ratio of silicon dioxide and hexacyclite is optimized, which can further increase the negative ion emission of the composite material.
在一些实施例中，所述钯配合物激发剂和负离子发射功能材料的质量比为1:50-500，优选为1:100-400，更优选为1:200。本发明实施例中，优选了钯配合物激发剂和负离子发射功能材料的质量比，进一步提高了复合材料的负离子发射量。In some embodiments, the mass ratio of the palladium complex activator to the negative ion emitting functional material is 1:50-500, preferably 1:100-400, more preferably 1:200. In the embodiment of the present invention, the mass ratio of the palladium complex activator and the negative ion emitting functional material is optimized, which further increases the negative ion emission of the composite material.
本发明实施例还提供了一种负离子发射纳米复合材料的制备方法，包括，将设计配比的钯配合物激发剂、负离子发射功能材料粉体和溶剂混合分散，加热反应，优选地，反应温度为80～140℃，反应时间为3～6h，制得负离子发射纳米复合材料。本发明实施例的制备方法，将钯配合物激发剂与负离子发射功能材料粉体进行加热反应制得负离子发射纳米复合材料，显著提高了复合材料的激发效率，同时降低了有害辐射，并且，制备方法简单，易于大规模工业化应用。The embodiment of the present invention also provides a preparation method of an anion-emitting nanocomposite material, comprising: mixing and dispersing a designed ratio of palladium complex activator, anion-emitting functional material powder, and a solvent, and heating the reaction. Preferably, the reaction temperature The temperature is 80-140° C., and the reaction time is 3-6 hours, and the anion-emitting nanocomposite material is prepared. In the preparation method of the embodiment of the present invention, the palladium complex activator and the negative ion emitting functional material powder are heated and reacted to prepare the negative ion emitting nanocomposite material, which significantly improves the excitation efficiency of the composite material and reduces harmful radiation at the same time, and prepares The method is simple and easy for large-scale industrial application.
本发明实施例还提供了一种纺织面料用后整理剂，包括本发明实施例的负离子发射纳米复合材料。本发明实施例的后整理剂，能够应用于纺织面料的后整理处理中，赋予纺织面料负离子发射功能。The embodiment of the present invention also provides a finishing agent for textile fabrics, including the negative ion emitting nanocomposite material of the embodiment of the present invention. The finishing agent of the embodiment of the present invention can be applied in the finishing treatment of textile fabrics, and endows the textile fabrics with an anion emitting function.
在一些实施例中，将所述负离子发射纳米复合材料加入极性溶剂进行湿法球磨处理，优选地，所述极性溶剂包括水、乙醇、乙二醇或丙三醇中的至少一种。本发明实施例中，将负离子发射纳米复合材料进一步进行湿法球磨，可以进一步提高负离子发射纳米复合材料的分散性，同时可以提升复合材料在纺织面料上的成膜性，从而提高了后整理剂对纺织面料的后整理效果，提升了纺织面料的负离子发射量。In some embodiments, the anion-emitting nanocomposite material is added into a polar solvent for wet ball milling. Preferably, the polar solvent includes at least one of water, ethanol, ethylene glycol or glycerol. In the embodiment of the present invention, the anion-emitting nanocomposite material is further subjected to wet ball milling, which can further improve the dispersion of the anion-emitting nanocomposite material, and at the same time can improve the film-forming properties of the composite material on textile fabrics, thereby improving the finishing agent. The post-finishing effect on textile fabrics improves the negative ion emission of textile fabrics.
在一些实施例中，所述湿法球磨中加入聚乙烯吡咯烷酮，优选地，所述聚乙烯吡咯烷酮的加入量为负离子发射纳米复合材料的0.2-2wt％。本发明实施例中，在对负离子发射纳米复合材料进行湿法球磨过程中加入聚乙烯吡咯烷酮，进一步对负离子发射纳米复合材料进行表面改性，不仅提高了负离子发射纳米复合材料的分散性，而且提高了其与纺织面料表面的结合力，从而增强了后整理剂在纺织面料表面的粘度，使其具有更好的成膜性，提高了纺织面料的负离子发射量。In some embodiments, polyvinylpyrrolidone is added to the wet ball milling, preferably, the amount of polyvinylpyrrolidone added is 0.2-2wt% of the negative ion emitting nanocomposite material. In the embodiment of the present invention, polyvinylpyrrolidone is added during the wet ball milling process of the anion-emitting nanocomposite, and the surface of the anion-emitting nanocomposite is further modified, which not only improves the dispersibility of the anion-emitting nanocomposite, but also improves the Improve its binding force with the surface of the textile fabric, thereby enhancing the viscosity of the finishing agent on the surface of the textile fabric, making it have better film-forming properties, and improving the negative ion emission of the textile fabric.
在一些实施例中，负离子发射纳米复合材料在湿法球磨后可以蒸发溶剂进行浓缩处理，优选地，所述负离子发射纳米复合材料的质量浓度为30-50％。本发明实施例的方法中，优选了负离子发射纳米复合材料的浓度，使制得的后整理剂能够直接用于纺织面料的后整理工艺中。In some embodiments, the anion-emitting nanocomposite material can be concentrated by evaporating the solvent after wet ball milling. Preferably, the mass concentration of the anion-emitting nanocomposite material is 30-50%. In the method of the embodiment of the present invention, the concentration of the anion-emitting nanocomposite material is optimized, so that the finished finishing agent can be directly used in the finishing process of textile fabrics.
在一些实施例中，所述后整理剂还包括成膜剂，优选地，所述成膜剂包括聚氨酯、丙烯酸类共聚物或明胶中的至少一种；和/或，所述成膜剂与负离子发射纳米复合材料的质量比为(1-10):1，优选为(2-10):1，进一步优选为(4-10):1，更优选为(6-8):1。本发明实施例中还可以加入成膜剂并优选了成膜剂的加入量，进一步提升了后整理剂与纺织面料的成膜性能，提高了纺织面料的负离子发射量。本发明实施例中，如果成膜剂加入量太少，成膜效应不明显，但如果成膜剂加入量过多，成膜效应太好，会使负离子被完全覆盖，导致与空气中的水汽接触不够充分，从而造成负离子的释放量下降。In some embodiments, the finishing agent also includes a film-forming agent, preferably, the film-forming agent includes at least one of polyurethane, acrylic copolymer or gelatin; and/or, the film-forming agent and The mass ratio of the negative ion emitting nanocomposite is (1-10):1, preferably (2-10):1, more preferably (4-10):1, more preferably (6-8):1. In the embodiment of the present invention, a film-forming agent can also be added and the addition amount of the film-forming agent is optimized, which further improves the film-forming performance of the finishing agent and the textile fabric, and improves the negative ion emission of the textile fabric. In the embodiment of the present invention, if the film-forming agent is added in too little amount, the film-forming effect is not obvious, but if the film-forming agent is added in too much, the film-forming effect is too good, and the negative ions will be completely covered, resulting in a mixture with the water vapor in the air. Insufficient contact, resulting in a decrease in the release of negative ions.
在一些实施例中，所述后整理剂还包括鞣酸，优选地，所述鞣酸的加入量为负离子发射纳米复合材料质量的5-15％。本发明实施例的方法中，还可以加入鞣酸，增强纺织面料的柔软度。In some embodiments, the finishing agent further includes tannic acid, preferably, the added amount of the tannic acid is 5-15% of the mass of the negative ion emitting nanocomposite material. In the method of the embodiment of the present invention, tannic acid can also be added to enhance the softness of the textile fabric.
本发明实施例还提供了一种纺织面料，所述纺织面料的制备方法包括，将待处理纺织面料采用本发明实施例的后整理剂通过浸轧处理进行后整理，优选采用两浸两轧工艺，制得纺织面料。本方面实施例的制备方法，对纺织面料采用后整理剂进行处理后，赋予了纺织面料负离子发射功能，使纺织面料能够应用于更多领域。The embodiment of the present invention also provides a textile fabric. The preparation method of the textile fabric comprises: finishing the textile fabric to be treated by padding with the finishing agent of the embodiment of the present invention, preferably using a double-dipping and two-rolling process , to produce textile fabrics. In the preparation method of the embodiment of this aspect, after the textile fabric is treated with a finishing agent, the textile fabric is endowed with an anion emitting function, so that the textile fabric can be applied in more fields.
在一些实施例中，可以将后整理剂直接用于浸轧工艺，也可以将后整理剂稀释2-10倍后进行浸轧处理，优选为2-8倍，更有选为2-6倍。本发明实施例中，将后整理进行稀释处理并优选了稀释倍数，进一步优化了后整理剂的成膜性能和分散性能，提高了后整理处理后纺织面料的负离子发射量。本发明实施例中，如果稀释倍数过高，成膜性能不够，稀释倍数过低，会使粉体出现团聚，从而降低了纺织面料的负离子释放量。In some embodiments, the finishing agent can be directly used in the padding process, and the finishing agent can also be diluted 2-10 times and then subjected to padding treatment, preferably 2-8 times, more preferably 2-6 times . In the embodiment of the present invention, the after-finishing is diluted and the dilution ratio is optimized, the film-forming performance and dispersing performance of the finishing agent are further optimized, and the negative ion emission of the textile fabric after the finishing treatment is improved. In the embodiment of the present invention, if the dilution factor is too high, the film-forming performance is insufficient, and if the dilution factor is too low, the powder will be agglomerated, thereby reducing the amount of negative ions released from the textile fabric.
本发明实施例还提供了一种纺织面料在汽车内饰中的应用。本发明实施例的纺织面料能够应用与汽车内饰中，纺织面料释放的负离子，有效改善了汽车内的空气环境，提高了汽车的舒适性。The embodiment of the invention also provides the application of a textile fabric in automobile interior decoration. The textile fabric of the embodiment of the present invention can be applied to the interior decoration of automobiles, and the negative ions released by the textile fabric can effectively improve the air environment in the automobile and improve the comfort of the automobile.
下面结合实施例和附图详细描述本发明。The present invention will be described in detail below in conjunction with the embodiments and accompanying drawings.
实施例1Example 1
一、制备钯配合物激发剂1. Preparation of Palladium Complex Stimulator
将氯化钯过饱和溶解在正己烷中，离心分离提纯，将提纯后的氯化钯与邻苯二胺在吡啶中混合溶解，其中，钯元素与邻苯二胺的质量比为1:5，在0.2MPa，100℃下反应2h，得到沉淀物，经丙酮洗涤、真空干燥后得到产物钯配合物激发剂。Supersaturated palladium chloride is dissolved in n-hexane, centrifuged and purified, and the purified palladium chloride and o-phenylenediamine are mixed and dissolved in pyridine, wherein the mass ratio of palladium element to o-phenylenediamine is 1:5 , reacted at 0.2MPa, 100°C for 2h to obtain a precipitate, which was washed with acetone and vacuum-dried to obtain the product palladium complex activator.
二、制备负离子发射纳米复合材料2. Preparation of negative ion emitting nanocomposites
将质量比为4:1的二氧化硅和六环石混合物机械粉碎至1μm以下，得到负离子发射功能材料粉体，将钯配合物激发剂与二氧化硅/六环石粉体按照质量比1:500混合，溶剂为水，超声分散30min，之后在120℃氮气保护下反应4h，制得负离子发射纳米复合材料。Mechanically pulverize the mixture of silica and hexacyclite with a mass ratio of 4:1 to less than 1 μm to obtain anion-emitting functional material powder, and mix the palladium complex activator with the silica/hexacyclite powder at a mass ratio of 1 : 500 mixed, the solvent is water, ultrasonically dispersed for 30min, and then reacted at 120°C for 4h under nitrogen protection to prepare anion-emitting nanocomposites.
三、制备后整理剂3. Preparation of finishing agent
将负离子发射纳米复合材料进行湿法球磨，液相球磨介质为乙醇，同时添加分子量为10000的聚乙烯吡咯烷酮作为表面修饰剂，加入量为负离子发射纳米复合材料质量的0.2％，球磨处理后，得到的负离子发射纳米复合材料的浓度为20wt％，粉体平均粒径为90nm，继续浓缩处理溶剂挥发得到浓度为40wt％的负离子发射纳米复合材料。Anion-emitting nanocomposites are wet-milled, the liquid-phase ball-milling medium is ethanol, and polyvinylpyrrolidone with a molecular weight of 10,000 is added as a surface modifier at the same time. The amount added is 0.2% of the mass of anion-emitting nanocomposites. After ball milling, the obtained The concentration of the anion-emitting nanocomposite material is 20wt%, and the average particle size of the powder is 90nm. The concentration of the anion-emitting nanocomposite material is 40wt%.
将浓缩后的负离子发射纳米复合材料与聚氨酯成膜剂进行复合，其中，成膜剂与负离子发射纳米复合材料的质量比为1:1，制得后整理剂。Composite the concentrated anion-emitting nanocomposite material with a polyurethane film-forming agent, wherein the mass ratio of the film-forming agent to the anion-emitting nanocomposite material is 1:1 to prepare a finishing agent.
四、纺织面料的制备Fourth, the preparation of textile fabrics
将制得的后整理剂稀释10倍，通过浸轧再干燥的方式对克重为200g/m2的涤纶针织面料进行后整理，制得纺织面料。The finished finishing agent was diluted 10 times, and the polyester knitted fabric with a grammage of 200 g/ m2 was finished by padding and then dried to obtain a textile fabric.
对本实施例制得的纺织面料进行测试，负离子发射量为1500个/立方厘米，辐射值为0.002ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 1500/cubic centimeter, and the radiation value was 0.002ucV.
本实施例制得的后整理剂经干燥处理后的SEM图见图1，在后整理剂中加入成膜剂后，负离子复合材料不再以颗粒状存在，而是一种薄膜形式附着，这种结构形式提高了后整理剂与面料的结合力，增强了其耐磨性，不会因为使用时的摩擦而脱落，导致负离子释放功能衰减。The SEM image of the drying treatment of the finishing agent obtained in this embodiment is shown in Fig. 1. After adding the film-forming agent in the finishing agent, the negative ion composite material no longer exists in granular form, but is attached in a thin film form. This structural form improves the binding force between the finishing agent and the fabric, enhances its wear resistance, and will not fall off due to friction during use, resulting in attenuation of the negative ion release function.
实施例2Example 2
与实施例1的方法相同，不同之处在于，步骤一中，钯元素与邻苯二胺的质量比为1:2。The same as the method of Example 1, the difference is that in step one, the mass ratio of palladium element to o-phenylenediamine is 1:2.
对本实施例制得的纺织面料进行测试，负离子发射量为1700个/立方厘米，辐射值为0.002ucV。The textile fabric prepared in this embodiment is tested, and the negative ion emission is 1700/cubic centimeter, and the radiation value is 0.002ucV.
实施例3Example 3
与实施例1的方法相同，不同之处在于，步骤一中，钯元素与邻苯二胺的质量比为1:1。The same as the method of Example 1, except that in step one, the mass ratio of palladium element to o-phenylenediamine is 1:1.
对本实施例制得的纺织面料进行测试，负离子发射量为2100个/立方厘米，辐射值为0.002ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 2100/cubic centimeter, and the radiation value was 0.002ucV.
实施例4Example 4
与实施例1的方法相同，不同之处在于，步骤一中，钯元素与邻苯二胺的质量比为2:1。The same as the method of Example 1, except that in step one, the mass ratio of palladium element to o-phenylenediamine is 2:1.
对本实施例制得的纺织面料进行测试，负离子发射量为1800个/立方厘米，辐射值为0.002ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 1800/cubic centimeter, and the radiation value was 0.002ucV.
实施例5Example 5
与实施例1的方法相同，不同之处在于，步骤一中，钯元素与邻苯二胺的质量比为5:1。The same as the method of Example 1, except that, in step one, the mass ratio of palladium element to o-phenylenediamine is 5:1.
对本实施例制得的纺织面料进行测试，负离子发射量为1400个/立方厘米，辐射值为0.002ucV。The textile fabric prepared in this embodiment is tested, and the negative ion emission is 1400/cubic centimeter, and the radiation value is 0.002ucV.
实施例6Example 6
与实施例3的方法相同，不同之处在于，步骤二中，二氧化硅和六环石的质量比为2:1。The method is the same as in Example 3, except that in step 2, the mass ratio of silicon dioxide and hexacyclite is 2:1.
对本实施例制得的纺织面料进行测试，负离子发射量为2400个/立方厘米，辐射值为0.003ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 2400/cubic centimeter, and the radiation value was 0.003ucV.
实施例7Example 7
与实施例3的方法相同，不同之处在于，步骤二中，二氧化硅和六环石的质量比为1:1。The same method as in Example 3, except that in step 2, the mass ratio of silicon dioxide and hexacyclite is 1:1.
对本实施例制得的纺织面料进行测试，负离子发射量为2700个/立方厘米，辐射值为0.003ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 2700/cubic centimeter, and the radiation value was 0.003ucV.
实施例8Example 8
与实施例3的方法相同，不同之处在于，步骤二中，二氧化硅和六环石的质量比为1:2。The method is the same as that of Example 3, except that in step 2, the mass ratio of silicon dioxide and hexacyclite is 1:2.
对本实施例制得的纺织面料进行测试，负离子发射量为2900个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 2900/cubic centimeter, and the radiation value was 0.004ucV.
实施例9Example 9
与实施例3的方法相同，不同之处在于，步骤二中，二氧化硅和六环石的质量比为1:4。The method is the same as in Example 3, except that in step 2, the mass ratio of silicon dioxide and hexacyclite is 1:4.
对本实施例制得的纺织面料进行测试，负离子发射量为2500个/立方厘米，辐射值为0.005ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 2500/cubic centimeter, and the radiation value was 0.005 ucV.
实施例10Example 10
与实施例8的方法相同，不同之处在于，步骤二中，钯配合物激发剂与二氧化硅/六环石粉体的质量比为1:400。The method is the same as in Example 8, except that in step 2, the mass ratio of the palladium complex activator to the silica/hexacyclite powder is 1:400.
对本实施例制得的纺织面料进行测试，负离子发射量为3100个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 3100/cubic centimeter, and the radiation value was 0.004ucV.
实施例11Example 11
与实施例8的方法相同，不同之处在于，步骤二中，钯配合物激发剂与二氧化硅/六环石粉体的质量比为1:300。The same method as in Example 8, except that in step 2, the mass ratio of the palladium complex activator to the silica/hexacyclite powder is 1:300.
对本实施例制得的纺织面料进行测试，负离子发射量为3300个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 3300/cubic centimeter, and the radiation value was 0.004ucV.
实施例12Example 12
与实施例8的方法相同，不同之处在于，步骤二中，钯配合物激发剂与二氧化硅/六环石粉体的质量比为1:200。The method is the same as in Example 8, except that in step 2, the mass ratio of the palladium complex activator to the silica/hexacyclite powder is 1:200.
对本实施例制得的纺织面料进行测试，负离子发射量为3700个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 3700/cubic centimeter, and the radiation value was 0.004ucV.
实施例13Example 13
与实施例8的方法相同，不同之处在于，步骤二中，钯配合物激发剂与二氧化硅/六环石粉体的质量比为1:100。The same method as in Example 8, except that in step 2, the mass ratio of the palladium complex activator to the silica/hexacyclite powder is 1:100.
对本实施例制得的纺织面料进行测试，负离子发射量为3400个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 3400/cubic centimeter, and the radiation value was 0.004ucV.
实施例14Example 14
与实施例8的方法相同，不同之处在于，步骤二中，钯配合物激发剂与二氧化硅/六环石粉体的质量比为1:50。The method is the same as in Example 8, except that in step 2, the mass ratio of the palladium complex activator to the silica/hexacyclite powder is 1:50.
对本实施例制得的纺织面料进行测试，负离子发射量为2900个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 2900/cubic centimeter, and the radiation value was 0.004ucV.
实施例15Example 15
与实施例12的方法相同，不同之处在于，步骤三中，成膜剂与负离子发射纳米复合材料的质量比为2:1。The method is the same as in Example 12, except that in step 3, the mass ratio of the film-forming agent to the anion-emitting nanocomposite material is 2:1.
对本实施例制得的纺织面料进行测试，负离子发射量为4900个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 4900/cubic centimeter, and the radiation value was 0.004ucV.
实施例16Example 16
与实施例12的方法相同，不同之处在于，步骤三中，成膜剂与负离子发射纳米复合材料的质量比为4:1。The method is the same as that of Example 12, except that in step 3, the mass ratio of the film-forming agent to the anion-emitting nanocomposite material is 4:1.
对本实施例制得的纺织面料进行测试，负离子发射量为6300个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 6300/cubic centimeter, and the radiation value was 0.004ucV.
实施例17Example 17
与实施例12的方法相同，不同之处在于，步骤三中，成膜剂与负离子发射纳米复合材料的质量比为6:1。The same method as in Example 12, except that in step 3, the mass ratio of the film-forming agent to the anion-emitting nanocomposite material is 6:1.
对本实施例制得的纺织面料进行测试，负离子发射量为7900个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 7900/cubic centimeter, and the radiation value was 0.004ucV.
实施例18Example 18
与实施例12的方法相同，不同之处在于，步骤三中，成膜剂与负离子发射纳米复合材料的质量比为8:1。The method is the same as in Example 12, except that in step 3, the mass ratio of the film-forming agent to the anion-emitting nanocomposite material is 8:1.
对本实施例制得的纺织面料进行测试，负离子发射量为7200个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 7200/cubic centimeter, and the radiation value was 0.004ucV.
实施例19Example 19
与实施例12的方法相同，不同之处在于，步骤三中，成膜剂与负离子发射纳米复合材料的质量比为10:1。The method is the same as that of Example 12, except that in step 3, the mass ratio of the film-forming agent to the anion-emitting nanocomposite material is 10:1.
对本实施例制得的纺织面料进行测试，负离子发射量为6400个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 6400/cubic centimeter, and the radiation value was 0.004ucV.
实施例20Example 20
与实施例17的方法相同，不同之处在于，步骤四中，将制得的后整理剂稀释8倍后再进行浸轧处理。The method is the same as in Example 17, except that in step 4, the prepared finishing agent is diluted 8 times before padding treatment.
对本实施例制得的纺织面料进行测试，负离子发射量为9300个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 9300/cubic centimeter, and the radiation value was 0.004ucV.
实施例21Example 21
与实施例17的方法相同，不同之处在于，步骤四中，将制得的后整理剂稀释6倍后再进行浸轧处理。The method is the same as that of Example 17, except that in step 4, the prepared finishing agent is diluted 6 times before padding treatment.
对本实施例制得的纺织面料进行测试，负离子发射量为12300个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 12300/cubic centimeter, and the radiation value was 0.004ucV.
实施例22Example 22
与实施例17的方法相同，不同之处在于，步骤四中，将制得的后整理剂稀释4倍后再进行浸轧处理。The method is the same as in Example 17, except that in step 4, the prepared finishing agent is diluted 4 times before padding treatment.
对本实施例制得的纺织面料进行测试，负离子发射量为12700个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 12700/cubic centimeter, and the radiation value was 0.004ucV.
实施例23Example 23
与实施例17的方法相同，不同之处在于，步骤四中，将制得的后整理剂稀释2倍后再进行浸轧处理。The method is the same as in Example 17, except that in step 4, the prepared finishing agent is diluted by 2 times before padding treatment.
对本实施例制得的纺织面料进行测试，负离子发射量为11600个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 11600/cubic centimeter, and the radiation value was 0.004ucV.
实施例24Example 24
与实施例17的方法相同，不同之处在于，步骤四中，将制得的后整理剂不进行稀释，直接进行浸轧处理。The method is the same as that of Example 17, except that in step 4, the prepared finishing agent is directly subjected to padding treatment without dilution.
对本实施例制得的纺织面料进行测试，负离子发射量为9200个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 9200/cubic centimeter, and the radiation value was 0.004ucV.
实施例25Example 25
与实施例22的方法相同，不同之处在于，步骤三中，湿法球磨时不加入聚乙烯吡咯烷酮。The method is the same as in Example 22, except that in step 3, no polyvinylpyrrolidone is added during wet ball milling.
对本实施例制得的纺织面料进行测试，负离子发射量为10400个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment is tested, and the negative ion emission is 10400/cubic centimeter, and the radiation value is 0.004ucV.
实施例26Example 26
与实施例22的方法相同，不同之处在于，步骤三中，负离子发射纳米复合材料不进行湿法球磨，将负离子发射纳米复合材料与乙醇配制成40wt％的溶液后与成膜剂复合。The method is the same as that of Example 22, except that in step 3, the anion-emitting nanocomposite material is not subjected to wet ball milling, and the anion-emitting nanocomposite material and ethanol are prepared into a 40wt% solution and then compounded with a film-forming agent.
对本实施例制得的纺织面料进行测试，负离子发射量为6400个/立方厘米，辐射值为0.004ucV。The textile fabric prepared in this embodiment was tested, and the negative ion emission was 6400/cubic centimeter, and the radiation value was 0.004ucV.
对比例1Comparative example 1
与实施例1的方法相同，不同之处在于，取消步骤一，步骤二中不加入钯配合物激发剂，负离子发射纳米复合材料为质量比为4:1的二氧化硅和六环石混合物。The method is the same as in Example 1, except that Step 1 is cancelled, no palladium complex activator is added in Step 2, and the anion-emitting nanocomposite material is a mixture of silicon dioxide and hexacyclite with a mass ratio of 4:1.
将对比例1制得的纺织面料进行测试，负离子发射量为600个/立方厘米，辐射值为0.0025ucV。The textile fabric prepared in Comparative Example 1 was tested, and the negative ion emission was 600 per cubic centimeter, and the radiation value was 0.0025 ucV.
对比例2Comparative example 2
与实施例1的方法相同，不同之处在于，取消步骤一，步骤二中将钯配合物激发剂替换为氯化钯。The method is the same as in Example 1, except that step 1 is canceled, and the palladium complex activator is replaced by palladium chloride in step 2.
将对比例2制得的纺织面料进行测试，负离子发射量为750个/立方厘米，辐射值为0.0023ucV。The textile fabric prepared in Comparative Example 2 was tested, and the negative ion emission was 750 per cubic centimeter, and the radiation value was 0.0023ucV.
在本发明中，术语“一个实施例”、“一些实施例”、“示例”、“具体示例”、或“一些示例”等意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中，对上述术语的示意性表述不必须针对的是相同的实施例或示例。而且，描述的具体特征、结构、材料或者特点可以在任一个或多个实施例或示例中以合适的方式结合。此外，在不相互矛盾的情况下，本领域的技术人员可以将本说明书中描述的不同实施例或示例以及不同实施例或示例的特征进行结合和组合。As used herein, the terms "one embodiment," "some embodiments," "example," "specific examples," or "some examples" mean specific features, structures, materials, or features described in connection with the embodiment or example. A feature is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the described specific features, structures, materials or characteristics may be combined in any suitable manner in any one or more embodiments or examples. In addition, those skilled in the art can combine and combine different embodiments or examples and features of different embodiments or examples described in this specification without conflicting with each other.
尽管上面已经示出和描述了本发明的实施例，可以理解的是，上述实施例是示例性的，不能理解为对本发明的限制，本领域的普通技术人员在本发明的范围内可以对上述实施例进行变化、修改、替换和变型。Although the embodiments of the present invention have been shown and described above, it can be understood that the above embodiments are exemplary and should not be construed as limiting the present invention, those skilled in the art can make the above-mentioned The embodiments are subject to changes, modifications, substitutions and variations.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210161501.2A CN116675717A (en) | 2022-02-22 | 2022-02-22 | Palladium complex activator, nanocomposite material, finishing agent, textile fabric and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210161501.2A CN116675717A (en) | 2022-02-22 | 2022-02-22 | Palladium complex activator, nanocomposite material, finishing agent, textile fabric and its application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116675717A true CN116675717A (en) | 2023-09-01 |
Family
ID=87777457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210161501.2A Pending CN116675717A (en) | 2022-02-22 | 2022-02-22 | Palladium complex activator, nanocomposite material, finishing agent, textile fabric and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116675717A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1430683A (en) * | 2000-04-06 | 2003-07-16 | 法国梅塔勒科技公司 | Electrolytic solution for electrochemical deposit of palladium or its alloys |
| CN107353307A (en) * | 2017-06-07 | 2017-11-17 | 昆明理工大学 | A kind of dichloro（Ethylenediamine）Close the preparation method of palladium |
-
2022
- 2022-02-22 CN CN202210161501.2A patent/CN116675717A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1430683A (en) * | 2000-04-06 | 2003-07-16 | 法国梅塔勒科技公司 | Electrolytic solution for electrochemical deposit of palladium or its alloys |
| CN107353307A (en) * | 2017-06-07 | 2017-11-17 | 昆明理工大学 | A kind of dichloro（Ethylenediamine）Close the preparation method of palladium |
Non-Patent Citations (4)
| Title |
|---|
| H. FUKUI ET AL.: "Control of third-order nonlinear optical properties of singlet diradical square planar metal complexes involving o-semiquinonato type ligands", 《SYNTHETIC METALS》, 9 September 2009 (2009-09-09), pages 2416 * |
| TIANLEI WANG ET AL.: "Palladium alloys used as electrocatalysts for the oxygen reduction reaction", 《ENERGY & ENVIRONMENTAL SCIENCE》, 15 March 2021 (2021-03-15), pages 2639 - 2669 * |
| TOSHIKI KITAMORI ET AL.: "Ambipolar Transistor Properties of Metal Complexes Derived from 1, 2-Phenylenediamines", 《ACS APPL. ELECTRON. MATER.》, 25 July 2019 (2019-07-25), pages 1633 * |
| YOSUKE KONNO ET AL.: "Dichlorido(o-phenylenediamine)palladium(II)", 《IUCRDATA》, 31 December 2017 (2017-12-31), pages 1 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106540658B (en) | A kind of graphene oxide covalent bond coated magnetic nano composition and preparation method thereof | |
| CN102602883B (en) | Preparation method of silica-coated iron oxide nano-core-shell structural material | |
| CN103310935A (en) | Silicon dioxide nano magnetic microsphere and preparation method thereof | |
| CN104248981B (en) | The spherical complex carrier in three-dimensional cubic duct and catalyst and its preparation method and application and the preparation method of ethyl acetate | |
| CN104353472A (en) | Preparation method of BiOBr/RGO nanometer composite and application thereof in reaction of degrading rhodamine | |
| Miralinaghi et al. | Non-linear kinetic, equilibrium, and thermodynamic studies of 5-fluorouracil adsorption onto chitosan–functionalized graphene oxide | |
| CN113385143B (en) | A kind of magnetic nano carbon dot/ferric oxide composite material and its preparation method and application | |
| CN108817416A (en) | A kind of preparation method and application of Pt nanoparticle | |
| CN107899540A (en) | Fe is prepared using sol-gal process3O4The method of 41 magnetic composites of@MCM | |
| CN114479158B (en) | Preparation method of a highly dispersed foaming agent and its composite foaming agent | |
| CN104722313A (en) | Copper oxide-gold nano composite material, preparation method and application thereof | |
| CN109950014A (en) | A method for preparing magnetic mesoporous silica composite microspheres by weak hydrolysis system | |
| CN114210276A (en) | Magnetic carbon-based composite aerogel with fire early warning and flame retardant functions and preparation method thereof | |
| CN114539855B (en) | Preparation method of a stable superamphiphobic coating with "sea-island" structure | |
| CN108393088B (en) | Preparation method of γ-iron trioxide/rGO composite material with flower-like microsphere structure | |
| CN111013600B (en) | Shallow surface layer metal monatomic catalyst and preparation method and application thereof | |
| CN107837792A (en) | A kind of preparation method of cyclodextrin modified magnetic hollow microcapsules sorbing material | |
| CN116675717A (en) | Palladium complex activator, nanocomposite material, finishing agent, textile fabric and its application | |
| CN101927147B (en) | Nano-scale magnetic silicon dioxide composite microsphere and preparation method thereof | |
| CN107851807A (en) | Carrier-nanoparticle composite, method for its preparation, and membrane electrode assembly comprising the same | |
| CN109680486A (en) | The preparation method and anion generation fabric of fabric occur for a kind of anion | |
| CN112044392A (en) | Preparation method of magnesium modified nano silicon dioxide hollow sphere | |
| CN114275770B (en) | Carbon-based aerogel with fire early warning and high compression performance and preparation method thereof | |
| CN110302752A (en) | A kind of graphene oxide coated Fe3O4 nano-cluster composite material and preparation method thereof | |
| Ghasemzadeh et al. | Preparation and Catalytic Study on a Novel Amino-functionalized Silica-coated Cobalt Oxide Nanocomposite for the Synthesis of Some Indazoles. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |