CN116652175A - A feed composition formula for metal powder injection molding and its part preparation method - Google Patents
A feed composition formula for metal powder injection molding and its part preparation method Download PDFInfo
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- CN116652175A CN116652175A CN202310711950.4A CN202310711950A CN116652175A CN 116652175 A CN116652175 A CN 116652175A CN 202310711950 A CN202310711950 A CN 202310711950A CN 116652175 A CN116652175 A CN 116652175A
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- 239000000843 powder Substances 0.000 title claims abstract description 62
- 239000002184 metal Substances 0.000 title claims abstract description 56
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 56
- 238000001746 injection moulding Methods 0.000 title claims abstract description 42
- 239000000203 mixture Substances 0.000 title claims description 6
- 238000002360 preparation method Methods 0.000 title claims description 6
- 239000011230 binding agent Substances 0.000 claims abstract description 31
- 238000005245 sintering Methods 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 29
- 239000000314 lubricant Substances 0.000 claims abstract description 14
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 36
- 238000005238 degreasing Methods 0.000 claims description 33
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 30
- 238000002156 mixing Methods 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 23
- 238000010438 heat treatment Methods 0.000 claims description 14
- 238000002347 injection Methods 0.000 claims description 13
- 239000007924 injection Substances 0.000 claims description 13
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 235000006408 oxalic acid Nutrition 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 11
- 230000003197 catalytic effect Effects 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229910052786 argon Inorganic materials 0.000 claims description 6
- 239000001569 carbon dioxide Substances 0.000 claims description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 6
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- -1 polyoxymethylene Polymers 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 3
- 230000002159 abnormal effect Effects 0.000 claims description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 229920006324 polyoxymethylene Polymers 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 238000000889 atomisation Methods 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 7
- 238000004663 powder metallurgy Methods 0.000 abstract description 5
- 229910000975 Carbon steel Inorganic materials 0.000 abstract description 3
- 239000010962 carbon steel Substances 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000003754 machining Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 18
- 239000000243 solution Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- 238000001354 calcination Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009689 gas atomisation Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000011800 void material Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000005495 investment casting Methods 0.000 description 1
- 210000001161 mammalian embryo Anatomy 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
- B22F1/103—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material containing an organic binding agent comprising a mixture of, or obtained by reaction of, two or more components other than a solvent or a lubricating agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/06—Metallic powder characterised by the shape of the particles
- B22F1/065—Spherical particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
- B22F1/108—Mixtures obtained by warm mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1017—Multiple heating or additional steps
- B22F3/1021—Removal of binder or filler
- B22F3/1025—Removal of binder or filler not by heating only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/14—Both compacting and sintering simultaneously
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/22—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
- B22F3/225—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip by injection molding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Powder Metallurgy (AREA)
Abstract
本发明提供一种金属粉末注射成型用喂料组分配方及其零件制备方法,属于粉末冶金注射成型技术领域,金属粉末注射成型用喂料组分配方包括金属粉末、粘结剂、润滑剂三部分,金属粉末、粘结剂和润滑剂在喂料中的质量百分比分别为84.5‑95.5%、3.5‑13.5%和1.0‑2.0%,金属粉末元素按质量分数占比计,与传统的滑块选用碳钢进行机加工制造相比,采用金属粉末注射成型技术通过优化定义喂料配方,优选工艺链中的关键参数,制得的微型导轨滑块具有高强度、高韧性、高耐磨性,以及耐蚀性,通过调整配方,调整烧结工艺参数,最终得到的烧结坯变形稳定,在所允许的公差范围内,保证了产品的精度。
The invention provides a feeding component formula for metal powder injection molding and a method for preparing parts thereof, which belong to the technical field of powder metallurgy injection molding. The feeding component formula for metal powder injection molding includes metal powder, binder and lubricant. Part, the mass percentage of metal powder, binder and lubricant in the feed is 84.5‑95.5%, 3.5‑13.5% and 1.0‑2.0%, respectively, and the metal powder element is calculated by mass fraction, which is different from the traditional slider Compared with carbon steel for machining and manufacturing, metal powder injection molding technology is used to optimize and define the feeding formula and optimize the key parameters in the process chain. The micro guide rail sliders produced have high strength, high toughness and high wear resistance As well as corrosion resistance, by adjusting the formula and adjusting the parameters of the sintering process, the final sintered compact is stable in deformation and within the allowable tolerance range, ensuring the accuracy of the product.
Description
技术领域technical field
本发明属于粉末冶金注射成型技术领域,具体涉及一种金属粉末注射成型用喂料组分配方及其零件制备方法。The invention belongs to the technical field of powder metallurgy injection molding, and in particular relates to a feed component formula for metal powder injection molding and a method for preparing parts thereof.
背景技术Background technique
金属粉末注射成形技术(MIM)是集高分子化学、粉末冶金工艺学、金属材料学等多学科相结合而形成的一种零部件新型近净成形技术,它的基本工艺过程是:首先将金属粉末与有机粘结剂均匀混合,用注射成型机成型,然后将成型坯中的粘结剂脱除,再经烧结致密化而得到最终产品。因其适合用来大批量生产力学性能好、尺寸精度高(IT7-IT6)的小型复杂零件,因此被誉为“当今最热门的零部件成型技术”。Metal powder injection molding technology (MIM) is a new type of near-net shape technology for parts and components formed by combining polymer chemistry, powder metallurgy technology, metal materials and other disciplines. Its basic process is: first, the metal The powder is uniformly mixed with an organic binder, molded by an injection molding machine, and then the binder in the molded body is removed, and then sintered and densified to obtain the final product. Because it is suitable for mass production of small and complex parts with good mechanical properties and high dimensional accuracy (IT7-IT6), it is known as "the most popular component forming technology today".
粉末冶金注射成型与传统的机械加工、精密铸造相比,制品内部组织结构更均匀;与传统粉末冶金压制/烧结相比,产品性能更优异,产品尺寸精度高,表面光洁度好,不必进行再加工或只需少量精加工;Compared with traditional mechanical processing and precision casting, powder metallurgy injection molding has a more uniform internal structure of the product; compared with traditional powder metallurgy pressing/sintering, the product performance is better, the product has high dimensional accuracy and surface finish, and no reprocessing is required Or just a small amount of finishing;
在现有技术中,微型导轨滑块主要应用于小型化设备上的微型导轨,要求滑块和滑轨有高的配合精度,并且需要滑块有高强度、高刚性,更够承受一定的载荷抵抗变形,同时要求滑块的表面尽可能的光滑,与滑轨接触表面有低的摩擦因数,而传统的导轨滑块多使用碳钢采用机械加工的方式生产,随着产业对产品微小化、高密度化要求越来越高,已经不能够满足要求,急待采用一种更新的工艺从产品的根源材料配方上改进,力求生产出高品质的滑块。In the prior art, miniature guideway sliders are mainly used in miniature guideways on miniaturized equipment, requiring high matching precision between the slider and the slideway, and requiring the slider to have high strength and high rigidity, which is more capable of bearing a certain load To resist deformation, the surface of the slider is required to be as smooth as possible, and the contact surface with the slide rail has a low friction coefficient, while the traditional guide rail slider is mostly produced by carbon steel by machining. With the industry's miniaturization of products, The requirement for high density is getting higher and higher, and it can no longer meet the requirements. It is urgent to adopt a newer process to improve the original material formula of the product, and strive to produce high-quality sliders.
发明内容Contents of the invention
本发明的目的为了生产具有高强度、高刚性、高精度、低摩擦阻力的高性能滑块,而提出的一种金属粉末注射成型用喂料组分配方及其零件制备方法。The object of the present invention is to produce a high-performance slider with high strength, high rigidity, high precision and low frictional resistance, and proposes a formula of feeding components for metal powder injection molding and a method for preparing parts thereof.
为实现上述目的,本发明提供如下技术方案:所述金属粉末、所述粘结剂和所述润滑剂在所述喂料中的质量百分比分别为84.5-95.5%、3.5-13.5%和1.0-2.0%,所述金属粉末元素按质量分数占比计,包括16-18%的Cr、≤0.60%的Ni、1.0-2.0%的Nb、≤1.0%的Mn、≤1.0%的Si、0.9-1.0%的C、≤0.3%的S、≤0.75%的Mo,Fe作为平衡元素,以上组合百分比之和为100%。In order to achieve the above object, the present invention provides the following technical scheme: the mass percentages of the metal powder, the binder and the lubricant in the feed are respectively 84.5-95.5%, 3.5-13.5% and 1.0- 2.0%, the metal powder elements include 16-18% Cr, ≤0.60% Ni, 1.0-2.0% Nb, ≤1.0% Mn, ≤1.0% Si, 0.9- 1.0% of C, ≤0.3% of S, ≤0.75% of Mo, and Fe as balance elements, the sum of the above combination percentages is 100%.
作为本发明一种优选的方案,所述金属粉末是将熔融态的440C不锈钢用惰性气体气雾化生产制得。As a preferred solution of the present invention, the metal powder is produced by atomizing molten 440C stainless steel with inert gas.
作为本发明一种优选的方案,为了使喂料在模腔中有较好的流动性,完整填充模腔,所述金属粉末形态为球型。As a preferred solution of the present invention, in order to make the feed material have better fluidity in the mold cavity and completely fill the mold cavity, the shape of the metal powder is spherical.
作为本发明一种优选的方案,若金属粉末粒径过大,在后续脱脂过程中,坯体内部会产生大量空隙,降低坯体强度,并且在烧结过程中会产生大的形变,若金属粉末粒径过小,在后续脱脂过程中,坯体内部的粘结剂不易脱出,所述金属粉末粒径为10-20微米。As a preferred solution of the present invention, if the particle size of the metal powder is too large, a large number of voids will be generated inside the green body during the subsequent degreasing process, which will reduce the strength of the green body and cause large deformation during the sintering process. If the metal powder particles If the diameter is too small, the binder inside the green body is not easy to come out during the subsequent degreasing process, and the particle diameter of the metal powder is 10-20 microns.
作为本发明一种优选的方案,所述粘结剂、润滑剂按质量百分比计,包括50%的聚甲醛、33%的聚乙炔、16%聚乙烯、1%的硬脂酸。As a preferred solution of the present invention, the binder and lubricant include 50% polyoxymethylene, 33% polyacetylene, 16% polyethylene, and 1% stearic acid in terms of mass percentage.
一种金属粉末注射成型用喂料的制备方法,包括如下步骤:A preparation method for feeding material for metal powder injection molding, comprising the steps of:
S1、按配方称取一定量的金属粉末加入混炼机中进行搅拌加热;S1. Weigh a certain amount of metal powder according to the formula and add it to the mixer for stirring and heating;
S2、按照配比加入所述粘结剂、润滑剂,进行混炼,得到黏度适宜均匀一致的喂料;S2. Add the binder and lubricant according to the proportion, and knead to obtain a suitable and uniform feeding material;
S3、将喂料在造粒机中制成适用于注射成型的一定形状的颗粒。S3. Making the feed material into pellets of a certain shape suitable for injection molding in a granulator.
作为本发明一种优选的方案,在步骤S1中,将金属粉末提前预热至150-200℃。As a preferred solution of the present invention, in step S1, the metal powder is preheated to 150-200° C. in advance.
作为本发明一种优选的方案,在步骤S2中,将混炼机转速设置为15-35r/min,混炼温度设置为170-200℃,均匀搅拌60-120min。As a preferred solution of the present invention, in step S2, the kneader speed is set to 15-35r/min, the kneading temperature is set to 170-200°C, and the kneader is uniformly stirred for 60-120min.
作为本发明一种优选的方案,在步骤S2中,所得到的喂料熔融指数为1000-1500g/10min。As a preferred solution of the present invention, in step S2, the melt index of the obtained feed material is 1000-1500g/10min.
作为本发明一种优选的方案,在步骤S3中,所述适用于注射成型的颗粒为短而细的棒状颗粒。As a preferred solution of the present invention, in step S3, the particles suitable for injection molding are short and thin rod-shaped particles.
一种金属粉末注射成型喂料制备微型导轨滑块的方法,包括如下步骤:A kind of metal powder injection molding feed material prepares the method for miniature guide rail slider, comprises the following steps:
S1、将制得的喂料加入注射成型机的料仓中,喂料在注射料筒内受到外部加热器和螺杆机械化的热作用完全塑化,由喷嘴经流道注入模腔,经保压、冷却、脱模得到成型坯;S1. Put the prepared feed into the silo of the injection molding machine. The feed is completely plasticized in the injection barrel by the heat of the external heater and screw mechanization. , cooling, and demoulding to obtain a molded blank;
S2、采用草酸催化脱脂炉催化脱脂,将成型坯放入炉内的仓斗上,调节脱脂温度到110±5℃,在风机作用下,草酸在氮气的携带下被吹入炉腔,坯体内的粘结剂分解为甲醛,燃烧生成二氧化碳和水,尾气得到绿色排放;S2. Use the oxalic acid catalytic degreasing furnace to catalyze degreasing, put the molded billet on the hopper in the furnace, adjust the degreasing temperature to 110±5°C, and under the action of the fan, the oxalic acid is blown into the furnace cavity under the nitrogen gas, and the billet body The binder decomposes into formaldehyde, burns to generate carbon dioxide and water, and the tail gas is greenly discharged;
S3、将脱脂坯放入真空烧结炉,通入氮气,调节炉内温度,通过负压脱脂,将坯体通过催化脱脂后内部残留的少量粘结剂脱除干净;S3. Put the degreased body into a vacuum sintering furnace, feed nitrogen gas, adjust the temperature in the furnace, degrease through negative pressure, and remove a small amount of binder remaining inside the body after catalytic degreasing;
S4、将炉内的氮气抽出,升高温度,通过真空内烧,坯体内部原子间形成烧结颈,坯体致密化;S4. Extract the nitrogen in the furnace, increase the temperature, and sinter in vacuum to form a sintering neck between the atoms inside the green body, and the green body is densified;
S5、进一步升高炉内温度,通入氩气,增加炉内压力,通过分压烧结,坯体原子进一步致密化,最终全致密。S5. Further increase the temperature in the furnace, feed argon gas, increase the pressure in the furnace, and through partial pressure sintering, the atoms of the green body are further densified, and finally fully densified.
作为本发明一种优选的方案,在步骤S2中,脱脂后的坯体不应在外久放,由于坯体容易吸收空气中的水分,对脱脂件产生氧化,从而导致脱脂异常和影响脱脂率判断。As a preferred solution of the present invention, in step S2, the degreased green body should not be placed outside for a long time, because the green body easily absorbs moisture in the air, which will oxidize the degreasing parts, resulting in abnormal degreasing and affecting the judgment of degreasing rate .
与现有技术相比,本发明的有益效果是:Compared with prior art, the beneficial effect of the present invention is:
1、本发明中,采用金属粉末注射成型技术通过优化定义喂料配方,优选工艺链中的关键参数,制得的微型导轨滑块具有高强度、高韧性、高耐磨性,以及耐蚀性,通过调整配方,调整烧结工艺参数,最终得到的烧结坯变形稳定,在所允许的公差范围内,保证了产品的精度。1. In the present invention, the metal powder injection molding technology is used to optimize and define the feeding formula, optimize the key parameters in the process chain, and the micro-rail sliders obtained have high strength, high toughness, high wear resistance, and corrosion resistance , by adjusting the formula and adjusting the parameters of the sintering process, the final sintered billet is stable in deformation, and the accuracy of the product is guaranteed within the allowable tolerance range.
2、本发明中,通过控制脱脂后的坯体不应在外久放,避免由于坯体容易吸收空气中的水分,对脱脂件产生氧化,从而导致脱的脂异常和影响脱脂率判断。2. In the present invention, the green body after degreasing should not be placed outside for a long time, so as to avoid the oxidation of the degreasing parts due to the easy absorption of moisture in the air by the green body, resulting in abnormal degreasing and affecting the judgment of degreasing rate.
附图说明Description of drawings
附图用来提供对本发明的进一步理解,并且构成说明书的一部分,与本发明的实施例一起用于解释本发明,并不构成对本发明的限制。在附图中:The accompanying drawings are used to provide a further understanding of the present invention, and constitute a part of the description, and are used together with the embodiments of the present invention to explain the present invention, and do not constitute a limitation to the present invention. In the attached picture:
图1为本发明中混炼机的立体图;Fig. 1 is the perspective view of kneader among the present invention;
图2为本发明中搅拌组件的立体图;Fig. 2 is the perspective view of stirring assembly among the present invention;
图3为本发明中混炼机的主视图;Fig. 3 is the front view of kneader among the present invention;
图4为本发明中混炼机的侧视图;Fig. 4 is the side view of kneader among the present invention;
图5为本发明中混炼机的第一剖视图;Fig. 5 is the first sectional view of kneader among the present invention;
图6为本发明中混炼机的第二剖视图;Fig. 6 is the second sectional view of kneader among the present invention;
图7为本发明中金属粉末注射成型用喂料的制备流程框图;Fig. 7 is the preparation flow diagram of feeding material for metal powder injection molding in the present invention;
图8为本发明中金属粉末注射成型喂料制备微型导轨滑块的流程框图;Fig. 8 is the process block diagram of the preparation of miniature rail slide block by metal powder injection molding feeding material in the present invention;
图9为本发明中注射得到的成型胚体的实物图。Fig. 9 is an actual picture of the molded embryo obtained by injection in the present invention.
图中:1、底板;101、支杆;102、顶板;2、滑轨;201、第一电动推杆;202、第一滑块;203、第二电动推杆;204、第二滑块;3、混炼箱;301、加热卸料板;302、固定杆;303、第一固定板;304、第二固定板;305、第三电动推杆;306、第一电机;4、顶盖;401、连接板;402、转盘;403、L型架;404、第二电机;405、转动杆;406、第一齿轮;407、第二齿轮;408、安装架;409、第三电机;410、搅拌叶。In the figure: 1, bottom plate; 101, pole; 102, top plate; 2, slide rail; 201, first electric push rod; 202, first slider; 203, second electric push rod; 204, second slider ;3, mixing box; 301, heating unloading plate; 302, fixed rod; 303, first fixed plate; 304, second fixed plate; 305, third electric push rod; 306, first motor; 4, top Cover; 401, connecting plate; 402, turntable; 403, L-shaped frame; 404, second motor; 405, rotating rod; 406, first gear; 407, second gear; 408, mounting frame; 409, third motor ; 410, stirring blade.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
实施例1Example 1
请参阅图1-图9,本发明提供以下技术方案:Referring to Fig. 1-Fig. 9, the present invention provides the following technical solutions:
步骤一:将熔融态的SUS440C不锈钢通过水气联合雾化法制成球形或近球形粉末颗粒;Step 1: The molten SUS440C stainless steel is made into spherical or nearly spherical powder particles through the combined water-gas atomization method;
步骤二:将占总质量85%的不锈钢粉末投入混炼机中进行搅拌,预热到150℃;Step 2: put stainless steel powder accounting for 85% of the total mass into a mixer for stirring, and preheat to 150°C;
步骤三:将占总质量13%的粘结剂,占总质量2%的硬脂酸投入混炼机中和金属粉末充分搅拌混合,将混炼机的转速设为15r/min,混炼温度设为170℃,均匀搅拌60min;Step 3: Put the binder accounting for 13% of the total mass and the stearic acid accounting for 2% of the total mass into the mixer to fully stir and mix with the metal powder, set the speed of the mixer to 15r/min, and the mixing temperature Set at 170°C and stir evenly for 60 minutes;
步骤四:将均匀一致的喂料投入制粒机中制成小圆柱状的颗粒,冷却成固态小圆柱棒;Step 4: Put the uniform feeding material into the granulator to make small cylindrical granules, and cool them into solid small cylindrical rods;
步骤五:将制粒得到的喂料投入注射成型机的料斗中,注射压力设定为9MPa,以5℃/min的升温速度依次升温至170℃、175℃、180℃,185℃、190℃。喂料在注射机的料筒中阶段性的由螺杆经喷嘴注射入浇口,喂料充分填充模腔,模具温度设定为120℃,保压压力设定为10MPa,保压1s;Step 5: Put the feed obtained by granulation into the hopper of the injection molding machine, set the injection pressure at 9MPa, and raise the temperature to 170°C, 175°C, 180°C, 185°C, and 190°C at a heating rate of 5°C/min. . The feeding material is injected into the gate by the screw through the nozzle in stages in the barrel of the injection machine, and the feeding material fully fills the mold cavity. The mold temperature is set at 120°C, the holding pressure is set at 10MPa, and the holding pressure is 1s;
步骤六:开启模具的水冷却系统,对注射坯进行冷却,然后从模腔中脱出成型坯;Step 6: Turn on the water cooling system of the mold to cool the injection billet, and then take out the molded billet from the cavity;
步骤七:将成型坯放入草酸催化脱脂炉中,草酸在氮气的携带下,与成型坯中的粘结剂发生接触,反应生成甲醛,甲醛燃烧后生成二氧化碳和水排放,成型坯得到有效脱脂,脱脂率达到90%,坯体此时为连通空隙结构;Step 7: Put the molded body into the oxalic acid catalytic degreasing furnace. The oxalic acid is carried by nitrogen, and contacts with the binder in the molded body, and the reaction generates formaldehyde. After the formaldehyde is burned, carbon dioxide and water are emitted, and the molded body is effectively degreased. , the degreasing rate reaches 90%, and the green body is a connected void structure at this time;
步骤八:将脱脂坯体在氮气保护气氛下放入真空烧结炉中进行烧结,坯体先经预烧结阶段,烧结温度由5℃/min升高到360℃保温30min,再由10℃/min升高到480℃保温60min,再由15℃/min升高到600℃保温90min,再由20℃/min升高到750℃,通过负压脱脂,将坯体内部剩余的粘结剂脱除干净;Step 8: Put the degreased green body into a vacuum sintering furnace for sintering under a nitrogen protective atmosphere. The green body first goes through the pre-sintering stage, and the sintering temperature is raised from 5°C/min to 360°C for 30 minutes, and then 10°C/min Raise to 480°C for 60 minutes, then raise from 15°C/min to 600°C for 90 minutes, then rise from 20°C/min to 750°C, degrease with negative pressure to remove the remaining binder inside the green body clean;
步骤九:进一步以10℃/min升温到1050℃保温1h,将炉内的氮气抽出,通过真空烧结,原子之间形成烧结颈,坯体致密化;再以15℃/min升高到1248℃,通入氩气,增加炉内压力到20KPa,通过加压煅烧,原子结合更紧密,坯体进一步致密化,最终全致密;Step 9: Further raise the temperature at 10°C/min to 1050°C for 1 hour, pump out the nitrogen in the furnace, and vacuum sinter to form a sintering neck between the atoms and densify the green body; then raise the temperature to 1248°C at 15°C/min , enter argon gas, increase the pressure in the furnace to 20KPa, through pressurized calcination, the atoms are bonded more closely, the green body is further densified, and finally fully densified;
步骤十:以20℃/min降温到900℃,保温1h,然后强制冷却到30℃;Step 10: Cool down to 900°C at 20°C/min, keep warm for 1 hour, and then force-cool to 30°C;
步骤十一:对烧结冷却后的滑块进行整形处理,得到最终成品零件。Step 11: Reshape the sintered and cooled slider to obtain the final finished part.
步骤二中的混炼机由机架组件、混炼组件、搅拌组件和升降组件组成;The mixing machine in the step 2 is made up of a frame assembly, a mixing assembly, a stirring assembly and a lifting assembly;
机架组件包括底板1、支杆101和顶板102,支杆101设有四个,四个支杆101分别固定连接于底板1的上端四角处,顶板102固定连接于四个支杆101的上端;The frame assembly includes a bottom plate 1, a pole 101 and a top plate 102. There are four poles 101. The four poles 101 are respectively fixedly connected to the four corners of the upper end of the bottom plate 1. The top plate 102 is fixedly connected to the upper ends of the four poles 101. ;
混炼组件包括混炼箱3、加热卸料板301、固定杆302、第一固定板303、第二固定板304和第三电动推杆305,第一固定板303、第二固定板304和第三电动推杆305均设有两个,固定杆302设有四个,混炼箱3设于底板1的上侧,混炼箱3与滑动组件连接,两个第二固定板304均固定连接于混炼箱3的圆周表面,两个第三电动推杆305分别固定连接于两个第二固定板304的下端,两个第一固定板303分别固定连接于两个第三电动推杆305的伸长端,四个固定杆302分别固定连接于两个第一固定板303的上端,加热卸料板301固定连接于四个固定杆302的上端,加热卸料板301与混炼箱3相匹配;The mixing assembly comprises a mixing box 3, a heating discharge plate 301, a fixed rod 302, a first fixed plate 303, a second fixed plate 304 and a third electric push rod 305, the first fixed plate 303, the second fixed plate 304 and There are two third electric push rods 305, four fixed rods 302, the mixing box 3 is arranged on the upper side of the bottom plate 1, the mixing box 3 is connected with the sliding assembly, and the two second fixing plates 304 are fixed Connected to the circumferential surface of the mixing box 3, the two third electric push rods 305 are respectively fixedly connected to the lower ends of the two second fixed plates 304, and the two first fixed plates 303 are respectively fixedly connected to the two third electric push rods 305, the four fixed rods 302 are respectively fixedly connected to the upper ends of the two first fixed plates 303, the heating unloading plate 301 is fixedly connected to the upper ends of the four fixed rods 302, and the heating unloading plate 301 and the mixing box 3 matches;
搅拌组件包括顶盖4、连接板401、转盘402、L型架403、第二电机404、转动杆405、第一齿轮406、第二齿轮407、安装架408、第三电机409和搅拌叶410,连接板401和L型架403均设有两个,转动杆405、第一齿轮406、第二齿轮407和搅拌叶410均设有四个,顶盖4与混炼箱3相匹配,两个连接板401均固定连接于顶盖4的上端,两个顶盖4与升降组件连接,转盘402转动连接于顶盖4内,两个L型架403均固定连接于顶盖4的上端,第二电机404固定连接于两个L型架403的相靠近端,第二电机404的输出端固定连接于转盘402的上端,四个转动杆405均转动连接于转盘402内,四个搅拌叶410分别固定连接于四个转动杆405的圆周表面,四个第一齿轮406分别固定连接于四个转动杆405的圆周表面,四个第二齿轮407分别通过转轴转动连接于转盘402的上端,每个第二齿轮407分别与相邻的两个第一齿轮406相啮合,安装架408固定连接于转盘402的上端,第三电机409固定连接于安装架408的表面,第三电机409的输出端与其中一个转动杆405的上端固定;The stirring assembly includes a top cover 4, a connecting plate 401, a turntable 402, an L-shaped frame 403, a second motor 404, a rotating rod 405, a first gear 406, a second gear 407, a mounting frame 408, a third motor 409 and a stirring blade 410 , there are two connecting plates 401 and L-shaped frame 403, four rotating rods 405, the first gear 406, the second gear 407 and stirring blades 410, the top cover 4 matches the mixing box 3, and the two Each connecting plate 401 is fixedly connected to the upper end of the top cover 4, the two top covers 4 are connected to the lifting assembly, the turntable 402 is rotatably connected in the top cover 4, and the two L-shaped frames 403 are fixedly connected to the upper end of the top cover 4, The second motor 404 is fixedly connected to the adjacent ends of the two L-shaped frames 403, the output end of the second motor 404 is fixedly connected to the upper end of the turntable 402, and the four rotating rods 405 are all rotatably connected in the turntable 402, and the four stirring blades 410 are respectively fixedly connected to the circumferential surfaces of the four rotating rods 405, the four first gears 406 are respectively fixedly connected to the circumferential surfaces of the four rotating rods 405, and the four second gears 407 are respectively connected to the upper end of the turntable 402 through rotating shafts. Each second gear 407 meshes with two adjacent first gears 406 respectively, the mounting frame 408 is fixedly connected to the upper end of the rotating disk 402, the third motor 409 is fixedly connected to the surface of the mounting frame 408, and the output of the third motor 409 The end is fixed with the upper end of one of the rotating rods 405;
升降组件包括两个滑轨2、第一电动推杆201、第一滑块202、第二电动推杆203和第二滑块204,两个滑轨2均固定连接于底板1和顶板102的相靠近端,两个第一滑块202分别固定连接于两个连接板401的相远离端,两个第一滑块202分别滑动连接于两个滑轨2内,两个第一电动推杆201均固定连接于顶板102的下端,两个第一电动推杆201的伸长端分别固定连接于两个第一滑块202的上端,两个第二滑块204分别滑动连接于两个滑轨2内,两个第二电动推杆203均固定连接于底板1的上端,两个第二电动推杆203的伸长端分别固定连接于两个第二滑块204的下端;The lifting assembly includes two slide rails 2, a first electric push rod 201, a first slide block 202, a second electric push rod 203 and a second slide block 204, and the two slide rails 2 are fixedly connected to the bottom plate 1 and the top plate 102. Close to the end, the two first sliders 202 are respectively fixedly connected to the remote ends of the two connecting plates 401, the two first sliders 202 are respectively slidably connected in the two slide rails 2, and the two first electric push rods 201 are fixedly connected to the lower end of the top plate 102, the extension ends of the two first electric push rods 201 are respectively fixedly connected to the upper ends of the two first sliders 202, and the two second sliders 204 are respectively slidably connected to the two sliders. In the rail 2, the two second electric push rods 203 are fixedly connected to the upper end of the base plate 1, and the extension ends of the two second electric push rods 203 are respectively fixedly connected to the lower ends of the two second sliders 204;
混炼箱3的两个侧端均固定连接有转轴,两个转轴分别转动连接于两个第二滑块204内,其中一个第二滑块204内固定连接有第一电机306,第一电机306的输出端与其中一个转轴的一端连接;Both side ends of the mixing box 3 are fixedly connected with rotating shafts, and the two rotating shafts are respectively connected in two second sliders 204 in rotation, and one of the second sliders 204 is fixedly connected with a first motor 306, the first motor The output end of 306 is connected with one end of one of the rotating shafts;
混炼机的运行流程,首先控制第三电动推杆305运行带动其输出端连接的第一固定板303移动,第一固定板303带动固定杆302移动,固定杆302带动加热卸料板301滑动至混炼箱3内下部的位置,然后在混炼箱3内依次加入金属粉末、粘结剂和润滑剂,由升降组件中的第一电动推杆201运行带动其伸长端连接的第一滑块202向下移动,第一滑块202带动连接板401向下移动,连接板401带动顶盖4向下移动,并覆盖在混炼箱3的上表面,控制第二电机404和第三电机409同时运行,第二电机404带动转盘402转动,转盘402表面以及其内部设置的零件转动,第三电机409带动转动杆405转动,转动杆405带动其表面的第一齿轮406转动,相邻的两个第一齿轮406通过第二齿轮407连接,四个转动杆405同时转动,由转动杆405带动搅拌叶410转动,搅拌叶410转动以及转盘402转动过程中对混炼箱3内加入的金属粉末、粘结剂和润滑剂进行混炼搅拌,搅拌过程中由加热卸料板301内部设置的加热丝对混炼箱3内的金属粉末、粘结剂和润滑剂进行加热,混炼完成后,有第一电动推杆201运行,间接带动搅拌组件向上移动,随后控制第一电机306运行带动转轴转动,转轴带动混炼箱3转动至一定角度,混炼箱3产生倾斜便于卸料,控制第三电动推杆305运行,间接带动加热卸料板301在混炼箱3内向上移动,将混炼箱3内混炼完成的原料推出,完成卸料,通过使用本装置混炼完成后由加热卸料板301在混炼箱3内滑动,快速完成卸料操作,相较于传统混炼机,便于对混炼机内进行清理,维护设备更为方便。The operation process of the mixing machine, firstly, the operation of the third electric push rod 305 is controlled to drive the first fixed plate 303 connected to its output end to move, the first fixed plate 303 drives the fixed rod 302 to move, and the fixed rod 302 drives the heating unloading plate 301 to slide to the lower part of the kneading box 3, then add metal powder, binder and lubricant in the kneading box 3 in sequence, and the first electric push rod 201 in the lifting assembly drives the first The slider 202 moves downward, the first slider 202 drives the connecting plate 401 to move downward, the connecting plate 401 drives the top cover 4 to move downward, and covers the upper surface of the mixing box 3 to control the second motor 404 and the third Motor 409 runs simultaneously, and second motor 404 drives turntable 402 to rotate, and the part that is arranged on the surface of turntable 402 and its inside rotates, and the 3rd motor 409 drives rotation rod 405 to rotate, and rotation rod 405 drives the first gear 406 on its surface to rotate, adjacent The two first gears 406 are connected through the second gear 407, and the four rotating rods 405 rotate at the same time. The rotating rods 405 drive the stirring blade 410 to rotate, and the stirring blade 410 rotates and the rotating disc 402 rotates during the rotation of the mixing box 3. The metal powder, binder and lubricant are mixed and stirred. During the stirring process, the metal powder, binder and lubricant in the mixing box 3 are heated by the heating wire installed inside the heating unloading plate 301, and the mixing is completed. Finally, the first electric push rod 201 runs, which indirectly drives the stirring assembly to move upwards, and then controls the operation of the first motor 306 to drive the rotating shaft to rotate, and the rotating shaft drives the mixing box 3 to rotate to a certain angle, and the mixing box 3 is inclined to facilitate unloading. Control the operation of the third electric push rod 305, indirectly drive the heating unloading plate 301 to move upward in the mixing box 3, push out the raw materials that have been mixed in the mixing box 3, and complete the unloading. After the mixing is completed by using this device The heated unloading plate 301 slides in the mixing box 3 to quickly complete the unloading operation. Compared with the traditional mixing machine, it is convenient to clean the inside of the mixing machine and maintain the equipment more conveniently.
实施例2Example 2
步骤一:将熔融态的SUS440C不锈钢通过水气联合雾化法制成球形或近球形粉末颗粒;Step 1: The molten SUS440C stainless steel is made into spherical or nearly spherical powder particles through the combined water-gas atomization method;
步骤二:将占总质量90%的不锈钢粉末投入混炼机中进行搅拌,预热到170℃;Step 2: put stainless steel powder accounting for 90% of the total mass into a mixer for stirring, and preheat to 170°C;
步骤三:将占总质量9%的粘结剂,占总质量1%的硬脂酸投入混炼机中和金属粉末充分搅拌混合,将混炼机的转速设为25r/min,混炼温度设为180℃,均匀搅拌100min;Step 3: Put 9% of the total mass of the binder and 1% of the total mass of stearic acid into the mixer and fully stir and mix the metal powder, set the speed of the mixer to 25r/min, and the mixing temperature Set at 180°C and stir evenly for 100 minutes;
步骤四:将均匀一致的喂料投入制粒机中制成小圆柱状的颗粒,冷却成固态小圆柱棒;Step 4: Put the uniform feeding material into the granulator to make small cylindrical granules, and cool them into solid small cylindrical rods;
步骤五:将制粒得到的喂料投入注射成型机的料斗中,注射压力设定为11MPa,以5℃/min的升温速度依次升温至170℃、175℃、180℃,185℃、190℃、195℃,喂料在注射机的料筒阶段性的由螺杆经喷嘴注射入浇口,喂料充分填充模腔,模具温度设定为125℃,保压压力设定为12MPa,保压2s;Step 5: Put the feed obtained from granulation into the hopper of the injection molding machine, set the injection pressure to 11MPa, and raise the temperature to 170°C, 175°C, 180°C, 185°C, and 190°C in sequence at a heating rate of 5°C/min , 195°C, the feeding material is injected into the gate by the screw through the nozzle in stages in the barrel of the injection machine, and the feeding material fully fills the mold cavity, the mold temperature is set at 125°C, the holding pressure is set at 12MPa, and the holding pressure is 2s ;
步骤六:开启模具的水冷却系统,对注射坯进行冷却,然后从模腔中脱出成型坯;Step 6: Turn on the water cooling system of the mold to cool the injection billet, and then take out the molded billet from the cavity;
步骤七:将成型坯放入草酸催化脱脂炉中,草酸在氮气的携带下,与成型坯中的粘结剂发生接触,反应生成甲醛,甲醛燃烧后生成二氧化碳和水排放,成型坯得到有效脱脂,脱脂率达到90%,坯体此时为连通空隙结构;Step 7: Put the molded body into the oxalic acid catalytic degreasing furnace. The oxalic acid is carried by nitrogen, and contacts with the binder in the molded body, and the reaction generates formaldehyde. After the formaldehyde is burned, carbon dioxide and water are emitted, and the molded body is effectively degreased. , the degreasing rate reaches 90%, and the green body is a connected void structure at this time;
步骤八:将脱脂坯体在氮气保护气氛下放入真空烧结炉中进行烧结,坯体先经预烧结阶段,烧结温度由5℃/min升高到350℃保温30min,再由10℃/min升高到470℃保温60min,再由15℃/min升高到590℃保温90min,再由20℃/min升高到740℃,通过负压脱脂,将坯体内部剩余的粘结剂脱除干净;Step 8: Put the degreased green body into a vacuum sintering furnace for sintering under a nitrogen protective atmosphere. The green body first goes through the pre-sintering stage, and the sintering temperature is raised from 5°C/min to 350°C for 30 minutes, and then 10°C/min Raise it to 470°C for 60 minutes, then raise it from 15°C/min to 590°C and hold it for 90 minutes, then raise it from 20°C/min to 740°C, and remove the remaining binder inside the green body through negative pressure degreasing clean;
步骤九:进一步以10℃/min升温到1040℃保温1h,将炉内的氮气抽出,通过真空烧结,原子之间形成烧结颈,坯体致密化;再以15℃/min升高到1238℃,通入氩气,增加炉内压力到20KPa,通过加压煅烧,原子结合更紧密,坯体进一步致密化,最终全致密;Step 9: Further raise the temperature at 10°C/min to 1040°C for 1 hour, pump out the nitrogen in the furnace, and vacuum sinter to form a sintering neck between the atoms and densify the green body; then raise the temperature to 1238°C at 15°C/min , enter argon gas, increase the pressure in the furnace to 20KPa, through pressurized calcination, the atoms are bonded more closely, the green body is further densified, and finally fully densified;
步骤十:以20℃/min降温到890℃,保温1h,然后强制冷却到30℃;Step 10: Cool down to 890°C at 20°C/min, keep warm for 1 hour, and then force-cool to 30°C;
步骤十一:对烧结冷却后的滑块进行整形处理,得到最终成品零件。Step 11: Reshape the sintered and cooled slider to obtain the final finished part.
实施例3Example 3
步骤一:将熔融态的SUS440C不锈钢通过水气联合雾化法制成球形或近球形粉末颗粒;Step 1: The molten SUS440C stainless steel is made into spherical or nearly spherical powder particles through the combined water-gas atomization method;
步骤二:将占总质量95%的不锈钢粉末投入混炼机中进行搅拌,预热到200℃;Step 2: put stainless steel powder accounting for 95% of the total mass into a mixer for stirring, and preheat to 200°C;
步骤三:将占总质量4.5%的粘结剂,占总质量0.5%的硬脂酸投入混炼机中和金属粉末充分搅拌混合,将混炼机的转速设为35r/min,混炼温度设为190℃,均匀搅拌120min;Step 3: put the binder accounting for 4.5% of the total mass and the stearic acid accounting for 0.5% of the total mass into the mixer and fully stir and mix the metal powder, set the speed of the mixer to 35r/min, and the mixing temperature Set at 190°C and stir evenly for 120 minutes;
步骤四:将均匀一致的喂料投入制粒机中制成小圆柱状的颗粒,冷却成固态小圆柱棒;Step 4: Put the uniform feeding material into the granulator to make small cylindrical granules, and cool them into solid small cylindrical rods;
步骤五:将制粒得到的喂料投入注射成型机的料斗中,注射压力设定为12MPa,以5℃/min的升温速度依次升温至170℃、175℃、180℃,185℃、190℃、195℃、200℃,喂料在注射机的料筒中慢慢由推杆注射入浇口,喂料充分填充模腔,模具温度设定为130℃,保压压力设定为13MPa,保压3s;Step 5: Put the feed obtained by granulation into the hopper of the injection molding machine, set the injection pressure to 12MPa, and raise the temperature to 170°C, 175°C, 180°C, 185°C, and 190°C in sequence at a heating rate of 5°C/min , 195°C, 200°C, the feed material is slowly injected into the gate by the push rod in the barrel of the injection machine, and the feed material fully fills the mold cavity. The mold temperature is set at 130°C, and the holding pressure is set at 13MPa. 3s;
步骤六:开启模具的水冷却系统,对成型坯进行冷却,然后从模具中脱出成型坯;Step 6: Turn on the water cooling system of the mold, cool the forming blank, and then remove the forming blank from the mold;
步骤七:将成型坯放入草酸催化脱脂炉中,草酸在氮气的携带下,与成型坯中的粘结剂发生接触,反应生成甲醛,甲醛燃烧后生成二氧化碳和水排放,注射坯得到有效脱脂,脱脂率达到90%,坯体此时为连通空隙结构;Step 7: Put the molded body into the oxalic acid catalytic degreasing furnace. Under the nitrogen gas, the oxalic acid comes into contact with the binder in the molded body, and the reaction generates formaldehyde. After the formaldehyde is burned, carbon dioxide and water are emitted, and the injection mold is effectively degreased. , the degreasing rate reaches 90%, and the green body is a connected void structure at this time;
步骤八:将脱脂坯体在氮气保护气氛下放入真空烧结炉中进行烧结,坯体先经预烧结阶段,烧结温度由5℃/min升高到340℃保温30min,再由10℃/min升高到460℃保温60min,再由15℃/min升高到580℃保温90min,再由20℃/min升高到730℃,通过负压脱脂,将坯体内部剩余的粘结剂脱除干净;Step 8: Put the degreased green body into a vacuum sintering furnace for sintering under a nitrogen protective atmosphere. The green body first goes through the pre-sintering stage, and the sintering temperature is raised from 5°C/min to 340°C for 30 minutes, and then 10°C/min Raise it to 460°C for 60 minutes, then raise it from 15°C/min to 580°C and hold it for 90 minutes, then raise it from 20°C/min to 730°C, and remove the remaining binder inside the green body through negative pressure degreasing clean;
步骤九:进一步以10℃/min升温到1030℃保温1h,将炉内的氮气抽出,通过真空烧结,原子之间形成烧结颈,坯体致密化;再以15℃/min升高到1228℃,通入氩气,增加炉内压力到20KPa,通过加压煅烧,原子结合更紧密,坯体进一步致密化,最终全致密;Step 9: Further raise the temperature to 1030°C at 10°C/min and keep it warm for 1 hour, pump out the nitrogen in the furnace, and vacuum sinter to form a sintering neck between the atoms and densify the green body; then raise the temperature to 1228°C at 15°C/min , enter argon gas, increase the pressure in the furnace to 20KPa, through pressurized calcination, the atoms are bonded more closely, the green body is further densified, and finally fully densified;
步骤十:以20℃/min降温到880℃,保温1h,然后强制冷却到30℃;Step 10: Cool down to 880°C at 20°C/min, keep warm for 1 hour, and then force-cool to 30°C;
步骤十一:对烧结冷却后的滑块进行整形处理,得到最终成品零件。Step 11: Reshape the sintered and cooled slider to obtain the final finished part.
本发明的使用流程:本发明在使用时,首先按配方称取一定量的金属粉末加入混炼机中进行搅拌加热;按照配比加入粘结剂、润滑剂,进行混炼,得到黏度适宜均匀一致的喂料;将喂料在造粒机中制成适用于注射成型的一定形状的颗粒;将制得的喂料加入注射成型机的料仓中,喂料在注射料筒内受到外部加热器和螺杆机械化的热作用完全塑化,由喷嘴经流道注入模腔,经保压、冷却、脱模得到成型坯;采用草酸催化脱脂炉催化脱脂,将成型坯放入炉内的仓斗上,调节脱脂温度到110±5℃,在风机作用下,草酸在氮气的携带下被吹入炉腔,坯体内的粘结剂分解为甲醛,燃烧生成二氧化碳和水,尾气得到绿色排放;将脱脂坯放入真空烧结炉,通入氮气,调节炉内温度,通过负压脱脂,将坯体通过催化脱脂后内部残留的少量粘结剂脱除干净;将炉内的氮气抽出,升高温度,通过真空内烧,坯体内部原子间形成烧结颈,坯体致密化;最后进一步升高炉内温度,通入氩气,增加炉内压力,通过分压烧结,坯体原子进一步致密化,最终全致密;通过使用本方案,与传统的滑块选用碳钢进行机加工制造相比,采用金属粉末注射成型技术通过优化定义喂料配方,优选工艺链中的关键参数,制得的微型导轨滑块具有高强度、高韧性、高耐磨性,以及耐蚀性,通过调整配方,调整烧结工艺参数,最终得到的烧结坯变形稳定,在所允许的公差范围内,保证了产品的精度。The use process of the present invention: when the present invention is in use, firstly weigh a certain amount of metal powder according to the formula and add it to the mixer for stirring and heating; add binder and lubricant according to the proportion, and carry out mixing to obtain a suitable and uniform viscosity. Consistent feeding; the feed is made into shaped pellets suitable for injection molding in the pelletizer; the prepared feed is fed into the silo of the injection molding machine, and the feed is externally heated in the injection barrel The thermal effect of the machine and screw mechanization is completely plasticized, and the nozzle is injected into the mold cavity through the flow channel, and the molded blank is obtained after pressure maintaining, cooling, and demoulding; the oxalic acid catalytic degreasing furnace is used for catalytic degreasing, and the molded blank is put into the hopper in the furnace First, adjust the degreasing temperature to 110±5°C. Under the action of the fan, oxalic acid is blown into the furnace cavity under the nitrogen gas, and the binder in the green body is decomposed into formaldehyde, which is burned to generate carbon dioxide and water, and the tail gas is discharged greenly; Put the degreased billet into the vacuum sintering furnace, feed nitrogen, adjust the temperature in the furnace, degrease through negative pressure, remove the small amount of binder remaining inside the billet after catalytic degreasing; pump out the nitrogen in the furnace, and raise the temperature , through vacuum internal sintering, a sintering neck is formed between the atoms inside the green body, and the green body is densified; finally, the temperature in the furnace is further increased, argon gas is introduced, and the pressure in the furnace is increased. Through partial pressure sintering, the atoms of the green body are further densified, and finally Full density; by using this scheme, compared with the traditional slider made of carbon steel for machining, the metal powder injection molding technology is used to optimize and define the feeding formula and optimize the key parameters in the process chain. The block has high strength, high toughness, high wear resistance, and corrosion resistance. By adjusting the formula and adjusting the sintering process parameters, the final sintered billet is stable in deformation, and the accuracy of the product is guaranteed within the allowable tolerance range.
最后应说明的是:以上所述仅为本发明的优选实施例而已,并不用于限制本发明,尽管参照前述实施例对本发明进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。Finally, it should be noted that: the above is only a preferred embodiment of the present invention, and is not intended to limit the present invention. Although the present invention has been described in detail with reference to the foregoing embodiments, for those skilled in the art, it still The technical solutions recorded in the foregoing embodiments may be modified, or some technical features thereof may be equivalently replaced. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included within the protection scope of the present invention.
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