CN116613407A - A continuous and high-efficiency anaerobic cracking furnace for recycling waste lithium batteries - Google Patents
A continuous and high-efficiency anaerobic cracking furnace for recycling waste lithium batteries Download PDFInfo
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- CN116613407A CN116613407A CN202310480632.1A CN202310480632A CN116613407A CN 116613407 A CN116613407 A CN 116613407A CN 202310480632 A CN202310480632 A CN 202310480632A CN 116613407 A CN116613407 A CN 116613407A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
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- B01D46/10—Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
- B01D46/12—Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces in multiple arrangements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
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- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
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Abstract
本发明公开了一种废旧锂电池回收用连续高效的无氧裂解炉,涉及废旧锂电池回收技术领域,包括裂解箱和传动箱,裂解箱的一侧通过螺栓固定有传动箱,裂解箱内安装有输送排料机构;本发明通过第一电机转动带动转轴转动,转轴转动带动加热罩内反应罩转动,使得从输料筒中掉落到反应罩中的裂解物料可以在反应罩旋转作用下裂解,由于整个反应罩的转动,使得物料与高温的接触更加充分,物料裂解效果提升的同时,裂解速率提高,同时物料裂解过程中存在部分物料粘连在反应罩内壁,而整个输料筒顶部固定的刮板可以及时将反应罩内壁粘连物料刮落,避免了物料粘连反应罩内壁导致物料裂解整体效率降低的问题出现。
The invention discloses a continuous and high-efficiency oxygen-free cracking furnace for recycling waste lithium batteries, which relates to the technical field of recycling waste lithium batteries, and includes a cracking box and a transmission box. There is a conveying and discharging mechanism; in the present invention, the rotation of the first motor drives the rotation of the rotating shaft, and the rotation of the rotating shaft drives the rotation of the reaction cover in the heating cover, so that the cracked material dropped from the feeding cylinder into the reaction cover can be cracked under the rotation of the reaction cover. Due to the rotation of the entire reaction hood, the contact between the material and the high temperature is more sufficient, the cracking effect of the material is improved, and the cracking rate is increased. At the same time, some materials are adhered to the inner wall of the reaction hood during the cracking process of the material, and the scraper fixed on the top of the entire feeding tube The plate can scrape off the material adhered to the inner wall of the reaction hood in time, avoiding the problem that the material adheres to the inner wall of the reaction hood and causes the overall efficiency of material cracking to decrease.
Description
技术领域technical field
本发明涉及废旧锂电池回收技术领域,具体为一种废旧锂电池回收用连续高效的无氧裂解炉。The invention relates to the technical field of recycling waste lithium batteries, in particular to a continuous and efficient anaerobic cracking furnace for recycling waste lithium batteries.
背景技术Background technique
随着锂电池的使用日益增多,锂电池经过近上千次充放电循环后,内部工作离子就会丧失活性;锂离子使用范围的日益广泛势必会带来大量的废旧电池,若随意丢弃不但对环境造成威胁,也是对资源的一种浪费;With the increasing use of lithium batteries, the internal working ions of lithium batteries will lose their activity after nearly thousands of charge and discharge cycles; the increasing use of lithium ions will inevitably bring a large number of waste batteries. A threat to the environment and a waste of resources;
废旧锂电池回收处理设备可以分选出铜铝,正负极粉等有价金属,可以让稀缺的原材料得到一些缓和;通常一条完整的废旧锂电池回收主要有收上料破碎系统、(干燥)热解系统、分选系统、尾气处理系统四部分组成,无氧裂解系统主要设备是无氧裂解炉,它裂解温度常规在250-600度之间,锂电池未注液正极片破碎进无氧裂解,经高温正极片中的有机类粘接剂聚乙烯吡咯烷酮PVP、聚偏氟乙烯PVDF、聚乙烯醇PVA、丁苯橡胶SBR等,在无氧高温将较大的高分子化合物分解转变成低小分子化合物,因无氧状高温裂解,裂解过程中无二噁英生成,在无氧条件下同时也抑制氮氧化合物的产生;通常裂解物料经过挤压闭风给料输送设备进入到无氧裂解炉中裂解,裂解过程中,物料处于静置状态,导致物料整体裂解速率降低,同时部分物料在裂解过程中粘连在炉壁上,影响裂解炉的热传导,降低了物料的裂解效率,而且在裂解过程中存在的废气直接进行净化处理,导致部分可燃气体浪费;Waste lithium battery recycling equipment can sort out copper, aluminum, positive and negative electrode powder and other valuable metals, which can relieve the scarce raw materials; usually a complete waste lithium battery recycling mainly includes a feeding and crushing system, (drying) The pyrolysis system, sorting system, and tail gas treatment system are composed of four parts. The main equipment of the anaerobic cracking system is an anaerobic cracking furnace. Its cracking temperature is usually between 250-600 degrees. Cracking, through the organic binders polyvinylpyrrolidone PVP, polyvinylidene fluoride PVDF, polyvinyl alcohol PVA, styrene-butadiene rubber SBR, etc. in the high-temperature positive plate, the larger polymer compounds are decomposed and transformed into low-temperature Small molecular compounds, due to anaerobic high-temperature pyrolysis, no dioxins are generated during the cracking process, and the production of nitrogen oxides is also suppressed under anaerobic conditions; usually the cracked materials enter the anaerobic Cracking in the cracking furnace. During the cracking process, the material is in a static state, resulting in a decrease in the overall cracking rate of the material. At the same time, part of the material sticks to the furnace wall during the cracking process, which affects the heat conduction of the cracking furnace and reduces the cracking efficiency of the material. The waste gas existing in the pyrolysis process is directly purified, resulting in the waste of part of the combustible gas;
为此,我们提出一种废旧锂电池回收用连续高效的无氧裂解炉。To this end, we propose a continuous and efficient anaerobic cracking furnace for recycling waste lithium batteries.
发明内容Contents of the invention
本发明的目的在于提供一种废旧锂电池回收用连续高效的无氧裂解炉,以解决上述背景技术中提出问题:The object of the present invention is to provide a kind of continuous high-efficiency anaerobic pyrolysis furnace for waste lithium battery recycling, to solve the problems raised in the above-mentioned background technology:
1、通过第一电机转动带动转轴转动,转轴转动带动加热罩内反应罩转动,使得整个物料在运动翻滚中进行裂解操作,避免了物料静置裂解速率低的问题;1. The rotating shaft is driven by the rotation of the first motor, and the rotation of the rotating shaft drives the reaction cover in the heating cover to rotate, so that the whole material is cracked while moving and tumbling, avoiding the problem of low cracking rate of the material;
2、通过转轴和转套的转动带动气腔和裂解箱中第二扇叶、第一扇叶转动,加速废气在炉体内流通速率,避免了物料裂解过程中排料速率低的问题;2. Through the rotation of the rotating shaft and the rotating sleeve, the second fan blade and the first fan blade in the air cavity and the cracking box are driven to rotate, so as to accelerate the flow rate of exhaust gas in the furnace body, and avoid the problem of low discharge rate during the material cracking process;
为实现上述目的,本发明提供如下技术方案:To achieve the above object, the present invention provides the following technical solutions:
一种废旧锂电池回收用连续高效的无氧裂解炉,包括裂解箱和传动箱,所述裂解箱的一侧通过螺栓固定有传动箱,所述裂解箱内安装有输送排料机构;A continuous and high-efficiency anaerobic cracking furnace for recycling waste lithium batteries, comprising a cracking box and a transmission box, one side of the cracking box is fixed with a transmission box by bolts, and a conveying and discharging mechanism is installed in the cracking box;
所述输送排料机构包括加热罩、气腔、通气孔、导气管和转板,所述裂解箱内安装有加热罩,且位于加热罩内开设有气腔,所述气腔的一侧均匀开设有通气孔,且位于通气孔的一侧与加热罩相连通,所述气腔的一侧且位于加热罩的顶部连通有导气管,所述加热罩的底部内壁转动连接有转板;The conveying and discharging mechanism includes a heating mantle, an air chamber, a vent hole, an air guide pipe and a rotating plate. A heating mantle is installed in the cracking box, and an air chamber is provided in the heating mantle. One side of the air chamber is uniform. A ventilation hole is provided, and one side of the ventilation hole is connected with the heating cover, one side of the air cavity and the top of the heating cover is connected with an air guide tube, and the bottom inner wall of the heating cover is rotatably connected with a rotating plate;
所述传动箱内通过螺栓固定有第一电机,且位于第一电机的输出端通过点焊固定有转轴,所述转轴的一端依次贯穿裂解箱一侧、气腔和加热罩后通过点焊固定有反应罩,所述转轴的外壁通过轴承套设活动连接有转套,且位于转套的一侧贯穿裂解箱的一侧并通过轴承与加热罩活动连接,所述转轴位于气腔内的外壁套设固定有第二扇叶,所述转套位于裂解箱内的外壁套设固定有第一扇叶。The first motor is fixed by bolts in the transmission box, and the output end of the first motor is fixed with a rotating shaft by spot welding, and one end of the rotating shaft passes through one side of the cracking box, the air cavity and the heating mantle in sequence and is fixed by spot welding There is a reaction cover, the outer wall of the rotating shaft is movably connected with a rotating sleeve through a bearing sleeve, and one side of the rotating sleeve runs through the side of the cracking box and is movably connected with the heating cover through a bearing. The rotating shaft is located on the outer wall of the air cavity The second fan blade is sleeved and fixed, and the outer wall of the rotary sleeve located in the cracking box is sleeved and fixed with the first fan blade.
进一步的,所述传动箱内通过螺栓固定有第二电机,且位于第二电机的输出端上套设固定有第一轮盘,所述转套位于传动箱内的一侧外壁套设固定有第二轮盘,且第二轮盘与第一轮盘通过皮带连接,所述传动箱内通过螺栓固定有保护气输送装置,且位于保护气输送装置的一侧与裂解箱相连通。Further, the second motor is fixed by bolts in the transmission box, and the output end of the second motor is sleeved and fixed with a first disc, and the outer wall of one side of the transmission box is sleeved and fixed with a The second wheel, and the second wheel is connected to the first wheel through a belt, and the protective gas delivery device is fixed by bolts in the transmission box, and is located on one side of the protective gas delivery device and communicates with the cracking box.
进一步的,所述裂解箱的一侧安装有输料筒,且位于输料筒的一侧贯穿裂解箱并延伸至反应罩内,所述输料筒的一侧通过螺栓固定有第三电机,且位于第三电机的输出端贯穿输料筒的一侧并通过点焊固定有螺旋叶片,所述输料筒位于反应罩内的外壁通过点焊固定有刮板,所述输料筒位于裂解箱外侧的顶部安装有定量仓。Further, a feeding tube is installed on one side of the cracking box, and one side of the feeding tube runs through the cracking box and extends into the reaction cover, and a third motor is fixed on one side of the feeding tube by bolts, And the output end of the third motor runs through one side of the feeding tube and is fixed with a spiral blade by spot welding, and the outer wall of the feeding tube in the reaction hood is fixed with a scraper by spot welding, and the feeding tube is located in the pyrolyzer. Quantitative bins are installed on the top of the outside of the box.
进一步的,所述裂解箱的顶部通过螺栓固定有过滤箱,且位于过滤箱的一侧安装有燃烧炉,所述燃烧炉内安装有储气箱,且位于储气箱的底部均匀连通有铜管,所述储气箱内均匀安装有火花塞管,且位于火花塞管的一侧延伸至铜管内,所述导气管的一端贯穿裂解箱的顶部并与过滤箱的一侧相连通,所述过滤箱的另一侧连通有排气管,且位于排气管的一端贯穿燃烧轮并与储气箱相连通。Further, the top of the cracking box is fixed with a filter box by bolts, and a combustion furnace is installed on one side of the filter box, a gas storage box is installed in the combustion furnace, and the bottom of the gas storage box is evenly connected with copper A spark plug tube is evenly installed in the gas storage box, and one side of the spark plug tube extends into the copper tube. One end of the air guide tube runs through the top of the cracking box and communicates with one side of the filter box. The other side of the filter box is communicated with an exhaust pipe, and one end of the exhaust pipe passes through the combustion wheel and communicates with the gas storage box.
进一步的,所述裂解炉的底部安装有电动推杆,且位于电动推杆的一端贯穿裂解炉并与转板滑动连接,所述裂解炉的底部开设有排料通道,所述传动箱的一侧连通有废气管,且位于传动箱底部内壁安装有第一滤板,所述第一滤板的底部安装有第一灰斗,所述传动箱的底部内壁安装有第二滤板,且位于第二滤板的底部安装有第二灰斗。Further, an electric push rod is installed at the bottom of the cracking furnace, and one end of the electric push rod runs through the cracking furnace and is slidably connected with the rotating plate. The side is connected with an exhaust pipe, and a first filter plate is installed on the inner wall of the bottom of the transmission box, and a first ash hopper is installed on the bottom of the first filter plate. A second ash hopper is installed at the bottom of the second filter plate.
一种废旧锂电池回收用连续高效的无氧裂解炉工作方法:A continuous and efficient anaerobic cracking furnace working method for recycling waste lithium batteries:
包括以下步骤:Include the following steps:
S1:上料及物料的翻动裂解,通过将破碎后的物料加入定量仓中,并通过输料筒内螺旋叶片将碎料推入反应罩内,此时保护气输送装置开始工作,将保护气通入整个裂解箱中,同时外部抽取真空装置同时运转,通保护气之前,整个导气管与排料通道处于密封状态;S1: Feeding and cracking of the material, by adding the crushed material into the quantitative bin, and pushing the broken material into the reaction hood through the spiral blade in the feeding tube, the protective gas conveying device starts to work at this time, and the protective gas is ventilated into the entire cracking box, while the external vacuum device is running at the same time, before the protective gas is passed, the entire air guide pipe and discharge channel are in a sealed state;
待裂解箱中保护气补充结束后,加热罩开始工作,并对裂解炉中氧气含量进行测量,当炉体内含氧量在小于5%左右时,加热罩开始加热,在加热过程中抽取真空系统和注入惰性气体交替运行,温度控制在150℃以下,炉体内达到含氧量在小于2%时开始升温在300℃以上,此时启动第一电机,第一电机通过转轴带动加热罩内反应罩转动,同时导气管开始通气;After the supplement of protective gas in the cracking box is completed, the heating mantle starts to work, and the oxygen content in the cracking furnace is measured. When the oxygen content in the furnace body is less than about 5%, the heating mantle starts to heat, and the vacuum system is drawn during the heating process. Alternate operation with injection of inert gas, the temperature is controlled below 150°C, when the oxygen content in the furnace body reaches less than 2%, the temperature starts to rise above 300°C, at this time, the first motor is started, and the first motor drives the reaction hood in the heating hood through the rotating shaft Turn, and at the same time the airway begins to ventilate;
S2:有机气体的燃烧及废气的排放,由于转轴转动的同时带动气腔中第二扇叶转动,使得物料裂解过程中产生的有机废气顺着导气管进入到过滤箱中,经过过滤箱初步过滤后的有机气体再进入到燃烧炉中对铜管进行燃烧加热,生成的废气来到整个加热罩外围的裂解箱中,此时整个第二电机开始工作并带动第一扇叶转动,此时排料通道打开,经过第一扇叶的吹动将保护气和废气同时吹入到传动箱内,废气夹杂着保护气一起通过废气管排入净化设备中处理;S2: Combustion of organic gas and emission of waste gas. Since the rotating shaft rotates and drives the second fan blade in the air chamber to rotate, the organic waste gas generated during the material cracking process enters the filter box along the air guide pipe and is initially filtered by the filter box. The final organic gas enters the combustion furnace to burn and heat the copper tube, and the waste gas generated enters the cracking box around the entire heating mantle. At this time, the entire second motor starts to work and drives the first fan blade to rotate. The material channel is opened, and the protective gas and exhaust gas are blown into the transmission box at the same time through the blowing of the first fan blade, and the exhaust gas mixed with the protective gas is discharged into the purification equipment through the exhaust pipe for processing;
S3:裂解残留物的排出,当整个反应罩内物料裂解结束后,此时第一电机反转使得反应罩内壁上的导料叶将裂解残留物卷至加热罩底部一侧,此时电动推杆带动转板展开,裂解残留物掉落至传动箱底部,此时废气管开始鼓气,并将裂解残留物吹至第一滤板和第二滤板上,最终裂解残留物落入第一灰斗和第二灰斗中。S3: Discharge of pyrolysis residue. When the pyrolysis of the material in the entire reaction hood is completed, the first motor reverses at this time so that the guide leaf on the inner wall of the reaction hood rolls the pyrolysis residue to the bottom side of the heating hood. At this time, the electric push The rod drives the rotary plate to expand, and the cracked residue falls to the bottom of the transmission box. At this time, the exhaust pipe starts to blow air, blowing the cracked residue to the first filter plate and the second filter plate, and finally the cracked residue falls into the first filter plate. Ash hopper and second ash hopper.
与现有技术相比,本发明的有益效果是:Compared with prior art, the beneficial effect of the present invention is:
1、本发明中,通过第一电机转动带动转轴转动,转轴转动带动加热罩内反应罩转动,使得从输料筒中掉落到反应罩中的裂解物料可以在反应罩旋转作用下裂解,由于整个反应罩的转动,使得物料与高温的接触更加充分,物料裂解效果提升的同时,裂解速率提高,同时物料裂解过程中存在部分物料粘连在反应罩内壁,而整个输料筒顶部固定的刮板可以及时将反应罩内壁粘连物料刮落,避免了物料粘连反应罩内壁导致物料裂解整体效率降低的问题出现;1. In the present invention, the rotation of the first motor drives the rotating shaft to rotate, and the rotation of the rotating shaft drives the reaction hood in the heating hood to rotate, so that the cracked material dropped from the feed tube into the reaction hood can be cracked under the rotation of the reaction hood. The rotation of the reaction hood makes the contact between the material and the high temperature more sufficient. While the cracking effect of the material is improved, the cracking rate is increased. At the same time, some materials stick to the inner wall of the reaction hood during the cracking process of the material, and the fixed scraper on the top of the entire feeding tube can Scrape off the adhered material on the inner wall of the reaction hood in time, avoiding the problem that the overall efficiency of material cracking is reduced due to the adhesion of the material to the inner wall of the reaction hood;
2、本发明中,通过转轴和转套的转动带动气腔和裂解箱中第二扇叶、第一扇叶转动,其中第一扇叶的转动使得加热罩内裂解出来的有机气体顺着通气孔进入到过滤箱中,通过过滤箱过滤后的有机气体统一在燃烧炉中燃烧并对整个输料筒周围的铜管进行加热,起到辅助物料高温裂解的作用,而有机气体中剩余废气则通过第一扇叶的转动快速从废气管排入净化设备中处理,使得整个废旧锂电池无氧裂解更加高效。2. In the present invention, the second fan blade and the first fan blade in the air cavity and the cracking box are driven by the rotation of the rotating shaft and the rotating sleeve, and the rotation of the first fan blade makes the organic gas cracked in the heating mantle flow along the passage. The pores enter the filter box, and the organic gas filtered through the filter box is burned in the combustion furnace and heats the copper pipes around the entire feeding tube, which plays the role of assisting the pyrolysis of the material, while the remaining waste gas in the organic gas is Through the rotation of the first fan blade, it is quickly discharged from the exhaust pipe into the purification equipment for treatment, making the anaerobic cracking of the entire waste lithium battery more efficient.
附图说明Description of drawings
图1为本发明的废旧锂电池回收用连续高效的无氧裂解炉结构示意图;Fig. 1 is the continuous and efficient anaerobic cracking furnace structure schematic diagram of waste lithium battery recycling of the present invention;
图2为本发明的废旧锂电池回收用连续高效的无氧裂解炉主视剖面结构示意图;Fig. 2 is the schematic cross-sectional structure schematic diagram of the front view of the continuous and efficient anaerobic cracking furnace for recycling waste lithium batteries of the present invention;
图3为本发明的废旧锂电池回收用连续高效的无氧裂解炉内气体流向示意图;Fig. 3 is the schematic diagram of gas flow in the continuous and efficient anaerobic cracking furnace for recycling waste lithium batteries of the present invention;
图4为本发明的第一电机与反应罩连接结构示意图;4 is a schematic diagram of the connection structure between the first motor and the reaction cover of the present invention;
图5为本发明的过滤箱整体结构示意图;Fig. 5 is a schematic diagram of the overall structure of the filter box of the present invention;
图6为本发明的燃烧炉主视剖面结构示意图。Fig. 6 is a schematic cross-sectional structure schematic diagram of the front view of the combustion furnace of the present invention.
图中:1、裂解箱;2、传动箱;3、保护气输送装置;4、第一电机;5、第二电机;6、第一轮盘;7、转轴;8、转套;9、第二轮盘;10、第一扇叶;11、第二扇叶;12、反应罩;13、输送排料机构;131、加热罩;132、气腔;133、通气孔;134、导气管;135、转板;14、第三电机;15、输料筒;16、螺旋叶片;17、刮板;18、导料叶;19、过滤箱;20、排气管;21、燃烧炉;22、储气箱;23、铜管;24、火花塞管;25、电动推杆;26、排料通道;27、废气管;28、第一滤板;29、第一灰斗;30、第二滤板;31、第二灰斗;32、定量仓。In the figure: 1. cracking box; 2. transmission box; 3. protective gas delivery device; 4. first motor; 5. second motor; 6. first wheel disc; 7. rotating shaft; 8. rotary sleeve; 10. The first fan blade; 11. The second fan blade; 12. The reaction cover; 13. The conveying and discharging mechanism; 131. The heating cover; 132. The air cavity; 133. The air hole; 134. The air duct ; 135, rotating plate; 14, the third motor; 15, feeding cylinder; 16, spiral blade; 17, scraper; 18, guide vane; 19, filter box; 20, exhaust pipe; 21, combustion furnace; 22. Gas storage box; 23. Copper tube; 24. Spark plug tube; 25. Electric push rod; 26. Discharging channel; 27. Waste gas pipe; 28. First filter plate; 29. First ash hopper; Two filter plates; 31, the second ash hopper; 32, quantitative warehouse.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
请参阅图1-6,本发明提供一种技术方案:Referring to Fig. 1-6, the present invention provides a technical solution:
实施例1:Example 1:
通常二次风选出的轻物经过旋风集料器收尘后留下的塑膜类物料通过闭风排料排出,二次风选留下的重物、正负极片和塑胶类组成混合物料通过挤压闭风给料输送到高温无氧裂解炉进行裂解,高温无氧裂解炉在加入物料前进行抽真空且保持封闭,混合物料中的塑胶类及粘合剂在高温无氧裂解炉内裂解产生可燃气,可燃气进行降温过滤净化后回用对高温无氧裂解炉进行加热,裂解后的混合物料通过冷却挤压闭风上料输送到筛选设备,筛选出粒度较小的纯净正负极粉和粒度较大的且掺杂有正负极粉的铜铝混合物;具体操作时,破碎后的物料加入定量仓32中,并通过第三电机14带动输料筒15内螺旋叶片16将碎料推入反应罩12内,此时保护气输送装置3在输送排料机构13内工作,将保护气通入整个裂解箱1中,同时外部抽取真空装置同时运转,通保护气之前,整个导气管134与排料通道26处于密封状态,待裂解箱1中保护气补充结束后,加热罩131开始工作,并对裂解炉中氧气进行测量,当炉体内含氧量在小于5%左右时,加热罩131开始加热,在加热过程中抽取真空系统和注入惰性气体交替运行,温度控制在150度以下,炉体内达到含氧量在小于2%时开始升温在300度以上,此时启动第一电机4,第一电机4通过转轴7带动加热罩131内反应罩12转动,同时导气管134开始通气;Usually, the light objects selected by the secondary wind are collected by the cyclone collector, and the plastic film materials left behind are discharged through closed air discharge, and the heavy objects left by the secondary air separation, positive and negative electrodes and plastics form a mixture The material is conveyed to the high-temperature anaerobic cracking furnace for cracking through extrusion and closed-air feeding. The high-temperature anaerobic cracking furnace is vacuumed and kept closed before adding materials. Internal cracking produces combustible gas. The combustible gas is cooled, filtered and purified, and then reused to heat the high-temperature anaerobic cracking furnace. The cracked mixture is conveyed to the screening equipment through cooling, extrusion and closed-air feeding, and the pure normal with small particle size is screened out. Negative electrode powder and copper-aluminum mixture with large particle size and doped with positive and negative electrode powder; during specific operation, the crushed material is added to the quantitative bin 32, and the third motor 14 drives the screw blade 16 in the feeding barrel 15 The scrap is pushed into the reaction hood 12, and now the protective gas conveying device 3 is working in the conveying and discharging mechanism 13, and the protective gas is passed into the whole cracking box 1, and the external vacuum device is simultaneously operated, and before the protective gas is passed, The whole air guide pipe 134 and the discharge channel 26 are in a sealed state. After the protective gas supplement in the cracking box 1 is completed, the heating mantle 131 starts to work, and the oxygen in the cracking furnace is measured. When the oxygen content in the furnace body is less than about 5% At this time, the heating mantle 131 starts to heat. During the heating process, the vacuum system is extracted and the inert gas is injected alternately. The temperature is controlled below 150 degrees. When the oxygen content in the furnace reaches less than 2%, the temperature starts to rise above 300 degrees. The first motor 4, the first motor 4 drives the reaction cover 12 in the heating cover 131 to rotate through the rotating shaft 7, and the air guide tube 134 starts to ventilate at the same time;
如图4所示,整个反应罩12的靠近第二扇叶11一侧处于裂解区,处于裂解区的反应罩12内壁未安装导料叶18,当整个转轴7带动反应罩12顺时针转动后,物料在不断滚动中进行裂解,也就不存在反应罩12底部物料裂解结束而顶层物料才开始裂解,使得物料裂解速率大大降低,同时由于物料中存在塑胶类组成混合物,在反应罩12内裂解过程中会粘连在罩壁上,导致整个反应罩12导热效率降低,而输料筒15的顶部且位于反应罩12裂解区安装有刮板17,当整个反应罩12转动后,粘连在反应罩12上的物料就会被刮板17铲落,避免了反应罩12内壁厚度增加,导致的物料裂解速率降低问题出现;As shown in Figure 4, the side of the whole reaction cover 12 near the second fan blade 11 is in the cracking zone, and the inner wall of the reaction cover 12 in the cracking zone is not equipped with a guide vane 18, when the whole rotating shaft 7 drives the reaction cover 12 to rotate clockwise , the material is pyrolyzed in continuous rolling, so there is no reaction hood 12 where the bottom material cracking ends and the top layer material begins to crack, so that the rate of material cracking is greatly reduced. During the process, it will stick to the cover wall, causing the heat conduction efficiency of the whole reaction cover 12 to decrease, while the top of the feeding tube 15 and the cracking area of the reaction cover 12 are equipped with a scraper 17. The material on the 12 will be scooped off by the scraper 17, avoiding the increase of the thickness of the inner wall of the reaction hood 12, resulting in the problem of a decrease in the cracking rate of the material;
整个转轴7转动的同时带动气腔132中第二扇叶11转动,转动的第二扇叶11又将物料裂解产出的有机废气从通气孔133送入到导气管134中,如图1所示,整个导气管134的一端连接着过滤箱19,而整个过滤箱19中滤板会对有机废气进行初步过滤,避免夹杂粉尘的有机废气进入到燃烧炉21中燃烧,容易出现粉尘爆炸,经过过滤箱19处理后的有机废气成功进入到燃烧炉21中,如图6所示,整个燃烧炉21中安装有储气箱22,排气管20与储气箱22连通,有机废气先进入到储气箱22中,而储气箱22底部均匀连通有铜管23,而整个铜管23延伸至加热罩131的底部,同时包围整个反应罩12,有机废气进入到铜管23中后,铜管23中安装的火花塞管24端部打火,将整个铜管23内有机废气点燃,使得整个铜管23的表面温度上升,起到辅助物料裂解的作用,而有机废气中部分无法点燃的气体则会进入到裂解箱1的底部,等待物料裂解结束后排出。When the whole rotating shaft 7 rotates, it drives the second fan blade 11 in the air chamber 132 to rotate, and the rotating second fan blade 11 sends the organic waste gas produced by cracking the material into the air duct 134 through the vent hole 133, as shown in Figure 1 As shown, one end of the entire air duct 134 is connected to the filter box 19, and the filter plate in the entire filter box 19 will initially filter the organic waste gas to prevent the organic waste gas mixed with dust from entering the combustion furnace 21 for combustion, which is prone to dust explosion. The organic waste gas treated by the filter box 19 successfully enters the combustion furnace 21, as shown in Figure 6, the gas storage box 22 is installed in the entire combustion furnace 21, and the exhaust pipe 20 communicates with the gas storage box 22, and the organic waste gas first enters the In the gas storage box 22, the bottom of the gas storage box 22 is uniformly connected with a copper tube 23, and the entire copper tube 23 extends to the bottom of the heating cover 131, and surrounds the entire reaction cover 12 at the same time. After the organic waste gas enters the copper tube 23, the copper tube 23 The end of the spark plug tube 24 installed in the tube 23 is ignited, and the organic waste gas in the entire copper tube 23 is ignited, so that the surface temperature of the entire copper tube 23 rises, which plays a role in assisting the cracking of materials, while some of the gases in the organic waste gas that cannot be ignited Then it will enter the bottom of the cracking box 1, and wait for the material to be cracked and then discharged.
实施例2:Example 2:
如图3所示,为了将燃烧后的废气排出裂解箱1,此时第二电机5开始工作,第二电机5通过第一轮盘6和转套8上第二轮盘9皮带连接使得第二电机5带动位于裂解箱1中第一扇叶10转动,此时排料通道26开启,废气顺着排料通道26进入到传动箱2底部,而位于传动箱2一侧连通有废气管27,废气成功通过废气管27排入净化设备中;As shown in Figure 3, in order to discharge the exhaust gas after combustion into the pyrolysis box 1, the second motor 5 starts to work at this moment, and the second motor 5 is connected by the second wheel disc 9 belts on the first wheel disc 6 and the rotary sleeve 8 so that the second The second motor 5 drives the first fan blade 10 located in the cracking box 1 to rotate. At this time, the discharge channel 26 is opened, and the exhaust gas enters the bottom of the transmission box 2 along the discharge channel 26, and an exhaust gas pipe 27 is connected to one side of the transmission box 2. , the waste gas is successfully discharged into the purification equipment through the waste gas pipe 27;
由于整个无氧裂解炉中充有保护气,同样可以通过废气管27将裂解箱1中剩余保护气排出,防止工作人员在第一灰斗29、第二灰斗31开启后,下料的过程用有保护气泄露,待整个裂解箱1中废气排完后,需要将反应罩12内正负极粉和粒度较大的且掺杂有正负极粉的铜铝混合物排出,此时位于加热罩131底部的电动推杆25带动转板135展开,第一电机4带动转轴7反向转动,此时反应罩12内部分混合物料开始与导料叶18接触,并被导料叶18成功卷落到裂解箱1底部转板135位置,混合物料顺着排料通道26落到传动箱2底部内壁上,待混合物料成功排入到传动箱2底部后,排料通道26关闭,废气管27内开始将外部空气吹入到传动箱2中,气流带动混合物料在传动箱2底部内壁上移动,而如图2所示,整个传动箱2底部内壁自左向右依次安装有第一滤板28和第二滤板30,且第一滤板28的孔径大于第二滤板30,使得混合物料在传动箱2底部进行过滤筛分操作,第一滤板28的底部安装有第一灰斗29,正负极粉等颗粒较小的物料成功落到第一灰斗29中,而铜铝混合物等颗粒较大的物料无法通过第一滤板28和第二滤板30并从传动箱2的底部排出,整个传动箱2底部加装的滤板起到初步过滤提取的作用,使得后期在对铜铝混合物表面正负粉料分离时,整体分离速率更高。Since the entire anaerobic cracking furnace is filled with protective gas, the remaining protective gas in the cracking box 1 can also be discharged through the waste gas pipe 27, preventing the staff from cutting the material after the first ash hopper 29 and the second ash hopper 31 are opened. If the protective gas leaks, after the waste gas in the whole cracking box 1 is exhausted, it is necessary to discharge the positive and negative electrode powder in the reaction hood 12 and the copper-aluminum mixture with larger particle size and mixed with positive and negative electrode powder. The electric push rod 25 at the bottom of the cover 131 drives the rotating plate 135 to unfold, and the first motor 4 drives the rotating shaft 7 to rotate in the reverse direction. At this time, part of the mixed material in the reaction cover 12 starts to contact with the guide vane 18 and is successfully rolled by the guide vane 18. Falling to the position of the rotating plate 135 at the bottom of the cracking box 1, the mixed material falls on the inner wall of the bottom of the transmission box 2 along the discharge channel 26. After the mixed material is successfully discharged into the bottom of the transmission box 2, the discharge channel 26 is closed, and the waste gas pipe 27 Start to blow the external air into the transmission box 2, and the air flow drives the mixed material to move on the bottom inner wall of the transmission box 2, and as shown in Figure 2, the entire bottom inner wall of the transmission box 2 is sequentially installed with the first filter plate from left to right 28 and the second filter plate 30, and the aperture of the first filter plate 28 is larger than that of the second filter plate 30, so that the mixed material is filtered and screened at the bottom of the transmission box 2, and the bottom of the first filter plate 28 is equipped with a first ash hopper 29. Materials with smaller particles such as positive and negative electrode powders successfully fall into the first ash hopper 29, while materials with larger particles such as copper-aluminum mixture cannot pass through the first filter plate 28 and the second filter plate 30 and are discharged from the transmission box 2 The bottom of the transmission box 2 is discharged from the bottom, and the filter plate installed at the bottom of the entire transmission box 2 plays the role of preliminary filtration and extraction, so that the overall separation rate is higher when the positive and negative powders on the surface of the copper-aluminum mixture are separated later.
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those skilled in the art can understand that various changes, modifications and substitutions can be made to these embodiments without departing from the principle and spirit of the present invention. and modifications, the scope of the invention is defined by the appended claims and their equivalents.
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